US20080217302A1 - Nanospot Welder and Method - Google Patents

Nanospot Welder and Method Download PDF

Info

Publication number
US20080217302A1
US20080217302A1 US11/928,422 US92842207A US2008217302A1 US 20080217302 A1 US20080217302 A1 US 20080217302A1 US 92842207 A US92842207 A US 92842207A US 2008217302 A1 US2008217302 A1 US 2008217302A1
Authority
US
United States
Prior art keywords
electron
canceled
funnel
current
electron beam
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
US11/928,422
Inventor
Richard Lee Fink
Zvi Yaniv
Igor Pavlovsky
Leif Thuesen
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Applied Nanotech Holdings Inc
Original Assignee
Applied Nanotech Holdings Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Applied Nanotech Holdings Inc filed Critical Applied Nanotech Holdings Inc
Priority to US11/928,422 priority Critical patent/US20080217302A1/en
Publication of US20080217302A1 publication Critical patent/US20080217302A1/en
Abandoned legal-status Critical Current

Links

Images

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K15/00Electron-beam welding or cutting
    • B23K15/0006Electron-beam welding or cutting specially adapted for particular articles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K15/00Electron-beam welding or cutting
    • B23K15/0013Positioning or observing workpieces, e.g. with respect to the impact; Aligning, aiming or focusing electronbeams
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K15/00Electron-beam welding or cutting
    • B23K15/0046Welding
    • B23K15/008Spot welding
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K15/00Electron-beam welding or cutting
    • B23K15/06Electron-beam welding or cutting within a vacuum chamber
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01QSCANNING-PROBE TECHNIQUES OR APPARATUS; APPLICATIONS OF SCANNING-PROBE TECHNIQUES, e.g. SCANNING PROBE MICROSCOPY [SPM]
    • G01Q80/00Applications, other than SPM, of scanning-probe techniques
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S977/00Nanotechnology
    • Y10S977/84Manufacture, treatment, or detection of nanostructure
    • Y10S977/849Manufacture, treatment, or detection of nanostructure with scanning probe
    • Y10S977/855Manufacture, treatment, or detection of nanostructure with scanning probe for manufacture of nanostructure
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S977/00Nanotechnology
    • Y10S977/84Manufacture, treatment, or detection of nanostructure
    • Y10S977/901Manufacture, treatment, or detection of nanostructure having step or means utilizing electromagnetic property, e.g. optical, x-ray, electron beamm

Abstract

A method and apparatus for assembly of small structures is disclosed. The present invention discloses electron beams created from one or more nanotips in an array operated in a field emission mode that can be controlled to apply heat to very well defined spots. The multiple electron beams may be generated and deflected and applied to electron beam heating and welding applications.

Description

    CROSS-REFERENCE TO RELATED APPLICATIONS
  • The present invention claims priority to the following:
  • Provisional Patent Application Ser. No. 60/469,381, entitled “CARBON NANOTUBE HIGH CURRENT DENSITY ELECTRON SOURCE,” filed on May 9, 2003;
  • Provisional Patent Application Ser. No. 60/508,815, entitled “NANOSPOT WELDER AND METHOD,” filed on Oct. 3, 2003; and
  • Provisional Patent Application Ser. No. 60/549,200, entitled “NANOSPOT WELDER AND METHOD FIELD OF THE INVENTION,” filed on Mar. 2, 2004.
  • TECHNICAL FIELD
  • The present invention relates in general to the creation of weld joints in small structures.
  • BACKGROUND INFORMATION
  • 1. Electron Sources
  • Researchers have been working on developing electron sources using carbon nanotubes (CNTs) for about ten years. One of the earliest references to this work is the patent of Keesmann et al. (U.S. Pat. No. 5,773.921). Some examples of the applications of using CNT electron sources are for displays (field emission displays and cathode ray tubes are two examples), e-beam lithography, x-ray sources and microwave devices (traveling wave tubes, klystrons, magnetrons, etc.). Some of these applications require high currents and high current densities. in the range of 1-100 Amps/cm2, in both pulsed and continuous wave (CW) or direct current (DC) modes. Many of these applications requiring high current densities are now being met using hot (thermal) cathodes of various types. All of these hot cathodes require power to heat the cathode and maintain its temperature in the range of 1000° C.
  • Other cold cathode technologies exist, but many of these require fabricating arrays of micron-size microtips. These are expensive to fabricate and not very reliable in extreme environments. This is evidenced by the fact that several companies that have made an effort to make microtip-based field emission displays have recently abandoned their efforts. Trying to incorporate microtip cathodes into microwave and x-ray devices has also met with limited success. On the other hand, carbon nanotube electron sources have been made with very inexpensive processes (such as printing or dispensing) over large areas.
  • Gated microtip electron sources, despite their weaknesses, did have an advantage of generating high current densities. (SRI International claimed 11.6 Amps/cm2 at 250V, “Application of Field Emitter Arrays to Microwave Power Amplifiers,” D. R. Whaley et al., Abstracts of the International Vacuum Electronics Conf., May 2-4, 2000, Monterey, Calif.; NEC Corporation claimed 1.27 Amps/cm2 from a Si microtip gated device “Field-Emitter-Array Cathode-Ray-Tube (FEA-CRT),” K. Konuma et al., SID 99 Digest p. 1151, 1999; Extreme Devices claimed 4 Amps/cm2 using what they claim as “diamond cathode technology,” Spec sheet for E-Chip ED138-250 dated March 2003-Rev. 2; see also “A Micromachined Vacuum Triode Using a Carbon Nanotube Cold Cathode,” C. Bower, et al., IEEE Trans on Electron Devices, Vol. 49, No. 8, p. 1478, August, 2002.)
  • The literature of carbon nanotube electron sources has examples of achievement of a few Amps/cm2. (E.g., claim of 4 Amp/cm2 with total current of only 0.4 mA in “Large current density from carbon nanotube field emitters,” W. Zhu et al., App. Phys. Let, Vol. 75, No. 6, p. 873, August, 1999.) Most of these claims were sources operated in a diode mode (ungated, anode and cathode only) and thus are of limited use for the applications of interest. What is needed is a gated electron source using carbon nanotube cathodes that can achieve high current densities. Some attempts have been made to make a gated source using carbon nanotubes (one example is D. S. Y. Hsu, et al., “Integrally Gated Carbon Nanotube-on-Post Field Emitter Arrays”, App. Phys. Lett., Vol. 80, p 118, 2002). The best that has been achieved is on the order of 0.1 Amps/cm2.
  • There are a couple of reasons why gated, high current density electron sources have not been made. The CNT cathodes are not regular arrays of nanotubes that are positioned in an exact
  • Other cold cathode technologies exist, but many of these require fabricating arrays of micron-size microtips. These are expensive to fabricate and not very reliable in extreme environments. This is evidenced by the fact that several companies that have made an effort to make microtip-based field emission displays have recently abandoned their efforts. Trying to incorporate microtip cathodes into microwave and x-ray devices has also met with limited success. On the other hand, carbon nanotube electron sources have been made with very inexpensive processes (such is printing or dispensing) over large areas.
  • Gated Microtip electron sources, despite their weaknesses, did have an advantage of generating high current densities. (SRI International claimed 11.6 Amps/cm2 at 250V, “Application of Field Emitter Arrays to Microwave Power Amplifiers,” D. R. Whaley et al., Abstracts of the International Vacuum Electronics Conf., May 2-4, 2000, Monterey, Calif.; NEC Corporation claimed 1.27 Amps/cm2 from a Si microtip gated device “Field-Emitter-Array Cathode-Ray-Tube (FEA-CRT),” K. Konuma et al., SID 99 Digest p. 1151, 1999; Extreme Devices claimed 4 Amps/cm2 using what they claim as “diamond cathode technology,” Spec sheet for E-Chip ED138-250 dated March 2003-Rev. 2; see also “A Micromachined Vacuum Triode Using a Carbon. Nanotube Cold Cathode,” C. Bower, et al., IEEE Trans on Electron Devices, Vol. 49, No. 8, p. 1478, August, 2002.)
  • The literature of carbon nanotube electron sources has examples of achievement of a few Amps/cm2. (E.g., claim of 4 Amp/cm2 with total current of only 0.4 mA in “Large current density from carbon nanotube field emitters,” W. Zhu et al., App. Phys. Let. Vol. 75, No. 6, p. 873, August, 1999.) Most of these claims were sources operated in a diode mode (ungated, anode and cathode only) and thus are of limited use for the applications of interest. What is needed is a gated electron source using carbon nanotube cathodes that can achieve high current densities. Some attempts have been made to make a gated source using carbon nanotubes (one example is D. S. Y. Hsu, et al., “Integrally Gated Carbon Nanotube-on-Post Field Emitter Arrays”, App. Phys. Lett., Vol. 80, p 118, 2002). The best that has been achieved is on the order of 0.1 Amps/cm2.
  • There are a couple of reasons why gated, high current density electron sources have not been made. The CNT cathodes are not regular arrays of nanotubes that are positioned in an exact
  • 2. Welding
  • With smaller and smaller structures and assemblies required for many applications, there is a need for assembly and welding technologies for the smaller structures. As just one example, there is a need for welding fine hydrogen separation membranes into very small reactors (micro-reactors). There is also a need for heat treatment on a fine scale and with high resolution. High throughput is also required for product manufacturing. There are several methods for welding two pieces of material together.
  • Contact welding (tack welding)—This involves forcing high current in a short pulse though the two parts. Typically, the joint between the two parts is highly resistive compared to the bulk of the materials and this area is heated rapidly by the pulse current. The temperature can rise to near or over the melting point of one or more of the materials and a bond is created between the materials. Typically, the size scale for this type of welding is on the order of 1 mm or larger. In this case, both parts must be metallic.
  • Wire bonding—Wire bonding is similar to contact welding. Ultra-sound can be applied in addition to high pulse current to create a bond. The size scale is on the order of 0.1 mm and can be highly automated. This is good for making interconnects to integrated circuits and printed circuit boards, but limited in making other assemblies.
  • Laser bonding—A laser can be focused to a small spot and create local heating to make a, bond. Mirrors on micropositioners can direct the beam to many different spots. This approach is flexible but it is difficult to make a multibeam system to increase the throughput. In addition, metals reflect a large percentage of the light, decreasing the efficiency of the welder. The size of the spot is on the order of 0.1 mm to 0.01 mm.
  • Focused Ion Beam (FIB)—stems are much like scanning electron microscopes (SEMs). FIBs can focus a beam to nano-scale sizes; 10 nanometer features have been demonstrated. This approach can achieve the fine resolution required for many applications, but FIB machines are expensive systems and the throughput is very low because only one beam is available to do all the machining. FIB systems are typically used for micromachining by etching material away and are not used for welding.
  • Electron beam welders or Scanning Electron Microscopes (SEMs—Electron beam welders use a electron gun to weld joints in a vacuum environment. Typically, the focus of the electron beam is 0.1 mm to 1.0 nm. SEMs can focus to much finer resolutions, but typically have very small currents, not sufficient for welding or bonding. Both systems use only one beam to perform all the processes. The size of the beam (welding spot) and the through put of standard electron beam welders and SEM machines are not sufficient for many nanospot welding and heat treatment applications. An e-beam welder is needed that can be sealed to an array for multibeam approaches and also achieve small beam sizes.
  • It is therefore a desire to provide a nanospot welder and method that addresses the need for assembly apparatus and methods for very small structures.
  • BRIEF DESCRIPTION OF THE DRAWINGS
  • The foregoing and other features and aspects of the present invention will be best understood with reference to the following detailed description of a specific embodiment of the invention, when read in conjunction with the accompanying drawings, wherein:
  • FIG. 1 illustrates a prior art hopping electron cathode (HEC);
  • FIG. 2 illustrates a gated HEC;
  • FIG. 3 illustrates a graph of current versus hopping electron blades potential,
  • FIG. 4 illustrates anode and grid currents allotted as a function of an extraction field,
  • FIG. 5 illustrates a HEC with electrostatic focusing elements;
  • FIG. 6 illustrates an image created by an electron beam using the embodiment illustrated in FIG. 5;
  • FIG. 7 illustrates an array of HEC sources;
  • FIG. 8 is a representative view of a nanospot welder;
  • FIG. 9 is an image of a CNT fiber on the end of an AFM tip;
  • FIG. 10 is a an image of a carbon nanotip on the end of a tungsten needle;
  • FIG. 11 is a representative side view of a nanospot welder;
  • FIG. 12 is a representative view of another embodiment of a nanospot welder utilizing a multiple electron beam;
  • FIG. 13 is a representative cross-sectional view of a gated CNT electron source;
  • FIG. 14 is a representative view of another embodiment of the present invention;
  • FIG. 15 is an image of a result of using an embodiment of the present invention; and
  • FIG. 16 is an image of an array of HEC sources and a work piece isolated in two separate chambers by the funnel array of the HEC source.
  • DETAILED DESCRIPTION
  • In the following description, numerous specific details are set forth such as specific display configurations, etc. to provide a thorough understanding of the present invention. However, it will be obvious to those skilled in the art that the present invention may be practiced without such specific details. In other instances, well-known circuits have been shown in block diagram form in order not to obscure the present invention in unnecessary detail. For the most part, details concerning timing considerations and the like have been omitted in as much as such details are not necessary to obtain a complete understanding of the present invention and are within the skills of persons of ordinary skill in the relevant art.
  • Referring to FIG. 2, the funnel is two blades of alumina 201 that are shaped to form a slit funnel. A cylindrical funnel can also be used, such as described in the Philips papers.
  • FIG. 3 shows the efficiency of the HEC 204 vs. the blades 201 potential. The prior art literature mentions the potential on the funnel electrodes of nearly 500-700V is needed. However, it is seen that the potential of 150-200V is good enough to force the electrons to come out from the slit 202. The efficiency of the source (the ratio of emitted current from the cathode 204 to the current collected at the anode 203) increased from 0 to about 67% when the potential on the funnel electrode was increased. The beam image on the phosphor screen 203 also changed: from a small single spot at low voltage to a two-lobe structure at higher voltage on the blades.
  • It should be noted that the current in the blade electrodes 201 was much lower then the grid and anode currents. Furthermore, the anode current can be modulated with the bias on the funnel electrode. The modulation is linear with funnel potential from 0 to about 140V. Additional experiments showed that this modulation potential from 0 to 100% swing is roughly independent of the current that is delivered from the cathode/grid assembly (e-gun). In other words, the graph shows that the 140V swing on the potential will modulate the current from the electron gun from 0 to 2.2 mA. If the grid voltage on the electron gun was increased, then the electron gun would be capable of emitting higher currents (the grid current at 0V on the funnel electrode would be higher) and the anode current with 140V on the funnel electrode would also be proportionally higher.
  • In FIG. 3, at zero potential on the funnel electrode, the entire cathode current goes to the extraction grid. As the funnel electrode potential (HEC blade potential) increases, more of the emitted current is condensed and passes through the funnel 202 and is then collected by the anode 203. Efficiency is the ratio of the anode current to the total current emitted from the cathode 204 and is plotted as a fraction 100%=1.0 in the graph.
  • The graph in FIG. 4 measures the I-V curve at constant voltage on the funnel electrode. The objective of this task is to obtain a peak anode current of ˜25 mA in a pulse mode. The pulse width was 10 μs, frequency 100 Hz, ballast resistor of 25 kOhm in series with the phosphor anode. The potential on the funnel electrodes was held at 500V constant and the extraction grid voltage in the electron gun 204 was ramped up.
  • In FIG. 4, the anode 203 and grid currents are plotted as a function of the extraction field generated between the cathode and the grid 204. The funnel electrode 201 potentials were held constant at 500V. Efficiency is also plotted as the percentage of total emitted current from the cathode collected at the anode. A value of 35 on the plot corresponds to 70% efficiency.
  • This shows that the current through the funnel 202 and collected at the anode 203 is about 30 mA. Since the gap 202 in the funnel is only 0.005 cm×0.4 cm, then the current density of electrodes flowing through the gap is about 15 Amps/cm2. The current along the length of the slit 202 is not uniform, the current in the center is much higher because the electron gun source is round and not rectangular. Thus the current density in the center of the slit 202 is probably 30 Amps/cm2 or higher.
  • A method of overcoming the inherent current density limitations of gated electron sources is performed using carbon nanotube emitters by condensing the beam from a CNT gated electron source into a narrower beam of electrons. Current densities as high as 15 Amps/cm2 were demonstrated. By making the funnel a cylindrical funnel and not the slit, it is expected that current densities as high as 1000 Amp/cm2 can be achieved. This current can be modulated with voltages between 0 and 150V; the current modulation is linear in proportion to the potential on the funnel electrode. This was demonstrated by operating a test circuit as shown in FIG. 2 in a pulsed mode (duty factor of 0.1%). Similar performance is expected with operating in a CW or DC mode.
  • The beam coming from the funnel can be accelerated, focused with electrostatic or magnetic focusing elements or deflected using electrostatic or magnetic deflection elements similar to what is used in standard CRT electron guns. FIG. 5 shows how the electrostatic focusing lens 507, 508 can be used to focus the electrons coming through the funnel.
  • FIG. 6 shows an image on anode 503 where the beam can indeed be focused to a narrow beam using the focusing elements 507, 508.
  • Referring to FIG. 7, it is also possible to make an integrated array of funnels for pixilated electron sources. This array can be x-y addressable. This can be done in a couple of ways. The electron sources before the funnel can be x-y addressed or a control line that also acts as the funnel electrode can be patterned on the exit side of the funnel array. The funnel array can be made out of alumina, glass or other insulator. It can be coated with MgO in the funnel openings to improve the secondary electron performance of the funnel. The funnel exit holes can be circular, rectangular or other shapes. The funnel array can then be placed on a patterned electron source (a CNT source is illustrated, but the source can be microtips, a thermal cathode, or other sources), the pattern of the electron source aligning with the openings (large end) of the funnel. Each funnel in the array condenses the electrons that enter it from the large opening. An unpatterned electron source may also be used if a flood of electrons is needed
  • It is also possible to make just a linear array of sources, similar to what is shown in FIG. 7, but aligned only in one row. Each of these sources can be independently controlled in intensity. The focus and deflection of the each of the sources can be together (in tandem) or separately. The openings of the sources can be as small as 0.5 microns for fine-focus x-ray sources or multibeam e-beam lithography applications. Display applications can have much larger dimensions. The hopping electron cathode or funnel approach also has the advantage in that the work piece and the electron source can be isolated from each other by the funnel array. The holes of the funnel can be made very small (as small as 0.5 micron as noted earlier) so the opening area through the funnel array to the electron sources can be a very small percentage of the total array area. Gasses created in the work area where the electrons hit the work piece can be blocked from entering the area of the electron sources, increasing the stability and life of the electron sources. FIG. 16 shows the work piece in a separate chamber from the electron sources, separated by the funnel array. (The funnel array can have as few as one funnel in principle.) Different vacuum or gas environments can be placed in each of the chambers. For example, a strong vacuum pump (not shown in FIG. 16) can be used to evacuate the electron source chamber to a better vacuum than the work piece chamber (e.g. 10−7 Torr in electron source chamber and 10−3 Torr in work piece chamber). Different gas environments can also be used to in the work piece chamber than in the electron source chamber. For example, a high partial pressure of Ar gas can be used in the work piece chamber and a high partial pressure of H2 gas can be used in the electron source chamber. Other gasses and arrangements are also possible. The small openings of the funnel will allow some gases to mix between the chambers but this will be limited by the size of the openings and to a smaller degree by the shape of the funnel. Small funnel openings and long, narrow funnels will limit the gas mixing between the two chambers.
  • The work piece is show in FIG. 16 without any support. In fact, supports will be needed to control the gap (z direction) between the funnel and the work piece and also to allow the work piece to move laterally with respect to the funnel (x and y, y is out of the paper). These supports are not shown to simplify the figure; these supports are well known in the state of the art.
  • FIG. 8 is a representative view of a nanospot welder in accordance with an embodiment of the present invention. The nanospot welder includes a modified Atomic Force Microscope (AFM) or a Scanning Tunneling Microscope (STM) machine to make a beam of electrons that are accelerated at high energy in a beam to heat a small spot. Atomic Force Microscopes and Scanning Tunneling Microscopes are also described under the term Scanning Probe Microscopes (SPM). The AFM or STM tip is not in contact with the work piece during the welding process. The tip is operated in a field emission (FE) mode such that electrons are extracted from the tip. The electrons are accelerated to the work piece to locally heat and bond material. The tip may remain stationary during the bonding process or it can be scanning. Before the bonding process, the tip may be used in a AFM or STM mode to locate the bond site accurately. When the bond site is located, the tip may be withdrawn to a distance and operated in a field emission mode.
  • The expected operating mode of this device would be to place the welder tip a small distance away from the sample. These gap distances are on the order of 10 nm to as large as 100 microns, depending on the spot size of the beam required and how much voltage one would like to put on the welder tip. Since the device operates in a diode mode (no gate structure), the beam current, welder tip voltage and gap are variables that are interdependent. If the gap is 100 microns, then 1000V could be placed on the welder tip to draw about 2 micro-Amps of current from the tip to the work piece. This creates a bean power of 2 mWatts and a local power density of 100 Watts/cm2 for a spot size expected to be about 50 microns in diameter. These numbers are estimates and serve only as a description of the expected mode of operation. Smaller gaps may lead to lower voltage on the needle, but in turn may lead to smaller spot size. Even though the total power in the beam may decrease, the power density may not change nearly as much.
  • The tip can be coated with a carbon film to increase durability. The tip may be a carbon-based microtip. Tips made of alloys or compounds of carbon are also good for this application. A carbon nanotube fiber can be grown from the tip end of the microtip as described in (U.S. Pat. No. 5,773,921). An image of a CNT fiber grown on the end of an AFM tip is shown in U.S. Pat. No. 6,146,227 and included as FIG. 9.
  • It is also possible to fabricate a smaller tip on the end of a larger tip or needle. In the publication by S. D. Johnson et al. (“Carbon Nanotips for Field-Emission Electron Guns” Abstracts of the 47th International Conference on Electron, Ion and Photon Beam Technology and Nanofabrication, Tampa, Fla., , May 27-May 30, 2003, p 274), a carbon nanotip is grown on the end of a tungsten needle. This is shown in FIG. 10.
  • Referring to FIG. 11, the nanospot welder may include one tip or a gang of tips on a single or multiple boards. The gang of tips can be in an array on a printed circuit board. Each tip can be independently addressable in both gap (displacement) and/or voltage on the tip. Either one will regulate the current emitted from the tip. Driver chips mounted on the PCB can drive each tip individually or two or more in tandem. The PCB is displaced from the work piece by a small gap that is controlled by supports and actuators on the work piece and PCB (not shown). The PCB and/or the work piece can be moved relative to each other in order to allow the tips to address the full area of the work piece. Current is drawn from each of the tips by increasing the voltage to the tip of by changing the gap of the tip to the work piece. The gap between the work piece and each of the tips may be individually controlled.
  • FIG. 12 is a representative view of another embodiment of the nanospot welder of the present invention. This embodiment of the nanospot welder includes a multiple electron beam In this embodiment, several electron beams are used to provide heat treatment or to perform welding tasks. Typically, the beams would be in an array. The current and voltage of each beam may be independently controlled although the typical mode of operation would be to keep the beam voltage the same for each and modulate the current of each beam as a function of time and position of the beam on the work piece.
  • The beam current can be modulated by a control or extraction grid over the cathode. The cathode can be thermal (hot cathode) or cold (microtips or carbon nanotubes or photocathodes). The beam currents can also be pulse-width modulated to control the duty factor of the beam ON time. The electron source may be a hopping electron cathode using either a thermal electron source or a cold electron source (including carbon nanotubes) to achieve electron source current densities as high as 15 Amps/cm2 or higher. The position of each beam can be controlled by electrostatic deflection. An example of such a structure for a display application is shown in FIG. 13, which also shows electrostatic focusing of the electron beam. A similar approach was taken for a display device was recently disclosed in “Flat CRT Display” and is incorporated into this disclosure by reference to U.S. Pat. No. 6,411,020 and PCT/US99/01841-WO 99/39361. The beam focus can be controlled by the relative potential applied to focus electron and aperture electrodes relative to the cathode and extraction grids.
  • The beams can also be controlled (deflected and focused) using magnetic fields. This is not shown, but similar methods are used to control the electron beams in cathode ray tubes (CRTs) used as TVs, scanning electron microscopes and multiple-beam and projection e-beam lithography approaches (e.g., DiVa approach of Timothy Groves: T. K. Groves and R. A. Kendall; Journal of Vacuum Science and Technology, B16(6), November 1998, p. 3168). Using a magnetic field parallel to the directed electron beams as in the DiVa approach allows one to focus the beams to very small spots (sub-micron) at periodic distances away from the source without using electrostatic lenses, making the system fabrication much more simple. The magnetic fields can be generated using standard electro-magnets in a Helmholz coil configuration as described in most elementary physics texts. It is also possible in the embodiments to move the work piece during the welding process. The movement can be continuous or stop-and-go, depending on the application.
  • Yet another approach to making a nanospot welder is to use an electron gun with a concentrator of electrons utilizing a mechanism of electrons hopping over the surface of a funnel-shaped or tapered hole made in a dielectric, where the electron drift toward the hole outlet is maintained by applying an electric field oriented along the axis of the hole. Prior art of such an electron gun design includes, for example, Patent Applications US 2002/0053867, WO 00/79558, and WO 01/26131.
  • Referring to FIG. 14, the electric field is induced by applying a potential to a welded part that becomes an accelerating electrode and a target at the same time. The energy of electrons is determined by the potential on the target. It is possible to bring the target temperature to a melting point or adjust the target temperature either by changing the electron beam current, target potential, or use pulse-width or pulse frequency modulation. More specifically, it is possible to bring the target temperature to a specified value by making a certain number of electron beam pulses.
  • Since the electrons diverge as they exit the hole, it is necessary either to place the welded part close to the hole outlet or use focusing electrodes. FIG. 14 depicts a concept where no focusing electrodes are used, and spacers are used to ensure that melted metal does not interfere with the dielectric concentrator. The concentrator may have the hole of any geometrical shape, e.g., cone, square pyramid, or rectangular pyramid.
  • A part of the welder is an electron gun. The electron gun is a source of electrons, and it may be a gated source. It may be either a thermionic cathode or cold cathode that uses field emission of electrons. In the described embodiment, a gated carbon nanotube cold cathode was used, which was capable of reaching up to 1 Amp/cm2 of electron current. With such an electron gun and a rectangular shaped hole in a ceramic electron concentrator, the effect of melting a metal foil was achieved where the welding spot has a diameter of nearly 50 microns. FIG. 15 shows the photograph of the foil with a spot of melted and then solidified metal.
  • The spot size that can be achieved depends on the design of the nanospot welder parts that, in turn, specifies an electron optics configuration. Also, the spot size can be changed by varying the hole exit size. It is possible to make the size of the hole outlet of sub-micron dimensions. As in previous two concepts, it is possible to move the work piece during welding in a certain manner, either stop-and-go or continuously.
  • This concept can take a multiple-beam approach as well. A welding array can utilize either one electron gun with a mosaic concentrator, where the electron beam will split over multiple concentrators, or a multiple gun-concentrator system. A mosaic concentrator for a single-gun design can be made of a single piece of dielectric, or a mosaic where seams between parts are made in such a way that they do not result in significant loss (or leak) of electron current. A multiple gun design is used where the beam configuration often needs to be changed, and/or the system is used for sub-millimeter (or larger scale), rather then sub-micron, welding.
  • From the foregoing detailed description of specific embodiments of the invention, it should be apparent that a nanospot welder and method that is novel has been disclosed. Although specific embodiments of the invention have been disclosed herein in some detail, this has been done solely for the purposes of describing various features and aspects of the invention, and is not intended to be limiting with respect to the scope of the invention. It is contemplated that various substitutions, alterations, and/or modifications, including but not limited to those implementation variations which may have been suggested herein, may be made to the disclosed embodiments without departing from the spirit and scope of the invention as defined by the appended claims which follow.

Claims (19)

1. (canceled)
2. (canceled)
3. (canceled)
4. (canceled)
5. (canceled)
6. An apparatus comprising:
a work piece;
a printed circuit board supporting a plurality of electron beam sources; and
circuitry for activating the plurality of electron beam sources to each emit an electron beam with sufficient energy to create a plurality of weld joints on the work piece positioned a distance from the printed circuit board.
7. The apparatus as recited in claim 6, wherein the electron beam source is a scanning probe microscope.
8. The apparatus as recited in claim 6, wherein the electron beam source is an AFM microtip probe.
9. The apparatus as recited in claim 6, wherein the election beam source is a STM microtip probe.
10. The apparatus as recited in claim 6, wherein the electron beam source is a hopping electron cathode.
11. The apparatus as recited in claim 6, wherein the work piece is movable relative to the printed circuit board.
12. The apparatus as recited in claim 6, wherein the plurality of electron beam sources are activated in parallel.
13. The apparatus as recited in claim 6, wherein the plurality of electron beam sources are arranged in an array on the printed circuit board.
14. (canceled)
15. (canceled)
16. (canceled)
17. (canceled)
18. (canceled)
19. (canceled)
US11/928,422 2003-05-09 2007-10-30 Nanospot Welder and Method Abandoned US20080217302A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
US11/928,422 US20080217302A1 (en) 2003-05-09 2007-10-30 Nanospot Welder and Method

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US46938103P 2003-05-09 2003-05-09
US50881503P 2003-10-03 2003-10-03
US54920004P 2004-03-02 2004-03-02
US10/838,698 US20040245224A1 (en) 2003-05-09 2004-05-04 Nanospot welder and method
US11/928,422 US20080217302A1 (en) 2003-05-09 2007-10-30 Nanospot Welder and Method

Related Parent Applications (1)

Application Number Title Priority Date Filing Date
US10/838,698 Division US20040245224A1 (en) 2003-05-09 2004-05-04 Nanospot welder and method

Publications (1)

Publication Number Publication Date
US20080217302A1 true US20080217302A1 (en) 2008-09-11

Family

ID=33494280

Family Applications (4)

Application Number Title Priority Date Filing Date
US10/838,698 Abandoned US20040245224A1 (en) 2003-05-09 2004-05-04 Nanospot welder and method
US11/176,100 Abandoned US20060213877A1 (en) 2003-05-09 2005-07-07 Nanospot welder and method
US11/176,101 Active 2028-04-27 US7786402B2 (en) 2003-05-09 2005-07-07 Nanospot welder and method
US11/928,422 Abandoned US20080217302A1 (en) 2003-05-09 2007-10-30 Nanospot Welder and Method

Family Applications Before (3)

Application Number Title Priority Date Filing Date
US10/838,698 Abandoned US20040245224A1 (en) 2003-05-09 2004-05-04 Nanospot welder and method
US11/176,100 Abandoned US20060213877A1 (en) 2003-05-09 2005-07-07 Nanospot welder and method
US11/176,101 Active 2028-04-27 US7786402B2 (en) 2003-05-09 2005-07-07 Nanospot welder and method

Country Status (2)

Country Link
US (4) US20040245224A1 (en)
WO (1) WO2004102601A2 (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20080169429A1 (en) * 2005-01-27 2008-07-17 Commissariat A L'energie Atomique Microelectronic Multiple Electron Beam Emitting Device
WO2015042022A1 (en) * 2013-09-20 2015-03-26 Applied Materials, Inc. Method and apparatus for direct formation of nanometer scaled features
EP3563399A4 (en) * 2016-12-29 2020-07-29 The University of British Columbia Optically addressed, thermionic electron beam device

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8958917B2 (en) 1998-12-17 2015-02-17 Hach Company Method and system for remote monitoring of fluid quality and treatment
US7454295B2 (en) 1998-12-17 2008-11-18 The Watereye Corporation Anti-terrorism water quality monitoring system
US9056783B2 (en) 1998-12-17 2015-06-16 Hach Company System for monitoring discharges into a waste water collection system
US8920619B2 (en) 2003-03-19 2014-12-30 Hach Company Carbon nanotube sensor
US20080020499A1 (en) * 2004-09-10 2008-01-24 Dong-Wook Kim Nanotube assembly including protective layer and method for making the same
US7868850B2 (en) * 2004-10-06 2011-01-11 Samsung Electronics Co., Ltd. Field emitter array with split gates and method for operating the same
US7928343B2 (en) * 2007-12-04 2011-04-19 The Board Of Trustees Of The University Of Illinois Microcantilever heater-thermometer with integrated temperature-compensated strain sensor
US8719960B2 (en) * 2008-01-31 2014-05-06 The Board Of Trustees Of The University Of Illinois Temperature-dependent nanoscale contact potential measurement technique and device
US8931950B2 (en) 2008-08-20 2015-01-13 The Board Of Trustees Of The University Of Illinois Device for calorimetric measurement
US8387443B2 (en) * 2009-09-11 2013-03-05 The Board Of Trustees Of The University Of Illinois Microcantilever with reduced second harmonic while in contact with a surface and nano scale infrared spectrometer
US8914911B2 (en) 2011-08-15 2014-12-16 The Board Of Trustees Of The University Of Illinois Magnetic actuation and thermal cantilevers for temperature and frequency dependent atomic force microscopy
US8533861B2 (en) 2011-08-15 2013-09-10 The Board Of Trustees Of The University Of Illinois Magnetic actuation and thermal cantilevers for temperature and frequency dependent atomic force microscopy
US20160247657A1 (en) * 2015-02-25 2016-08-25 Ho Seob Kim Micro-electron column having nano structure tip with easily aligning

Citations (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4446373A (en) * 1981-01-12 1984-05-01 Sony Corporation Process and apparatus for converged fine line electron beam treatment objects
US5021672A (en) * 1989-12-22 1991-06-04 E. I. Du Pont De Nemours And Company Etching of nanoscale structures
US5194780A (en) * 1990-06-13 1993-03-16 Commissariat A L'energie Atomique Electron source with microtip emissive cathodes
US5196707A (en) * 1991-03-04 1993-03-23 Etec Systems, Inc. Low aberration field emission electron gun
US5210425A (en) * 1991-08-30 1993-05-11 E. I. Du Pont De Nemours And Company Etching of nanoscale structures
US5214347A (en) * 1990-06-08 1993-05-25 The United States Of America As Represented By The Secretary Of The Navy Layered thin-edged field-emitter device
US5294465A (en) * 1989-10-10 1994-03-15 The United States Of America As Represented By The Secretary Of Commerce Microtip-controlled nanostructure fabrication and multi-tipped field emission tool for parallel-process nanostructure fabrication
US5894058A (en) * 1995-03-02 1999-04-13 Ebara Corporation Ultra-fine microfabrication method using a fast atomic energy beam
US6146227A (en) * 1998-09-28 2000-11-14 Xidex Corporation Method for manufacturing carbon nanotubes as functional elements of MEMS devices
US6369385B1 (en) * 1999-05-05 2002-04-09 Applied Materials, Inc. Integrated microcolumn and scanning probe microscope arrays
US6469433B1 (en) * 2000-01-28 2002-10-22 Extreme Devices Incorporated Package structure for mounting a field emitting device in an electron gun
US6528807B1 (en) * 1997-08-05 2003-03-04 Hans Wilfried Peter Koops Method for applying or removing material
US6660959B2 (en) * 2001-11-21 2003-12-09 University Of Kentucky Research Foundation Processes for nanomachining using carbon nanotubes
US6815877B2 (en) * 2002-07-11 2004-11-09 Hon Hai Precision Ind. Co., Ltd. Field emission display device with gradient distribution of electrical resistivity
US6906470B2 (en) * 2001-06-04 2005-06-14 Trepton Research Group, Inc. Method and system for controlling electron beams from field emission cathodes
US6921575B2 (en) * 2001-05-21 2005-07-26 Fuji Xerox Co., Ltd. Carbon nanotube structures, carbon nanotube devices using the same and method for manufacturing carbon nanotube structures
US7183548B1 (en) * 2004-02-25 2007-02-27 Metadigm Llc Apparatus for modifying and measuring diamond and other workpiece surfaces with nanoscale precision
US7279686B2 (en) * 2003-07-08 2007-10-09 Biomed Solutions, Llc Integrated sub-nanometer-scale electron beam systems

Family Cites Families (36)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3592995A (en) * 1968-11-18 1971-07-13 Smith Corp A O Automated electron beam welding
US3896258A (en) * 1973-09-04 1975-07-22 Charles W Hanks Electron beam gun system
US4070597A (en) * 1976-04-22 1978-01-24 General Electric Company Multi-apertured single plate matrix lens
DE2632548C2 (en) * 1976-07-20 1985-06-13 Ibm Deutschland Gmbh, 7000 Stuttgart Arrangement and method for establishing connections between subcircuits
US4560856A (en) * 1982-09-01 1985-12-24 Westinghouse Electric Corp. Pulsed laser machining apparatus
US4541055A (en) * 1982-09-01 1985-09-10 Westinghouse Electric Corp. Laser machining system
US4564736A (en) * 1984-05-07 1986-01-14 General Electric Company Industrial hand held laser tool and laser system
GB2192751B (en) * 1986-07-14 1991-02-13 Denki Kagaku Kogyo Kk Method of making a thermionic cathode structure.
JP3126409B2 (en) * 1991-06-05 2001-01-22 キヤノン株式会社 Information recording and playback method
US5591312A (en) * 1992-10-09 1997-01-07 William Marsh Rice University Process for making fullerene fibers
DE4405768A1 (en) * 1994-02-23 1995-08-24 Till Keesmann Field emission cathode device and method for its manufacture
US5455420A (en) * 1994-07-12 1995-10-03 Topometrix Scanning probe microscope apparatus for use in a scanning electron
US5869801A (en) * 1995-02-15 1999-02-09 The E.O. Paton Electric Welding Institute Of The National Academy Of Sciences Of Ukraine, Device for manual electron beam processing of materials in space
US20030135971A1 (en) * 1997-11-12 2003-07-24 Michael Liberman Bundle draw based processing of nanofibers and method of making
US6441543B1 (en) * 1998-01-30 2002-08-27 Si Diamond Technology, Inc. Flat CRT display that includes a focus electrode as well as multiple anode and deflector electrodes
DE69935422T2 (en) * 1998-12-03 2007-11-29 Daiken Chemical Co. Ltd. SURFACE SIGNAL COMMAND PROBE OF ELECTRONIC DEVICE AND METHOD FOR THE PRODUCTION THEREOF
TW464903B (en) 1999-06-22 2001-11-21 Koninkl Philips Electronics Nv Cathode ray tube
GB9919737D0 (en) * 1999-08-21 1999-10-20 Printable Field Emitters Limit Field emitters and devices
CN1322371A (en) 1999-10-01 2001-11-14 皇家菲利浦电子有限公司 Cathode ray tube
US6989631B2 (en) * 2001-06-08 2006-01-24 Sony Corporation Carbon cathode of a field emission display with in-laid isolation barrier and support
US6669256B2 (en) * 2000-03-08 2003-12-30 Yoshikazu Nakayama Nanotweezers and nanomanipulator
US6874668B2 (en) * 2000-07-25 2005-04-05 The Regents Of The University Of California Telescoped multiwall nanotube and manufacture thereof
US6709566B2 (en) * 2000-07-25 2004-03-23 The Regents Of The University Of California Method for shaping a nanotube and a nanotube shaped thereby
CN1397085A (en) * 2000-09-27 2003-02-12 皇家菲利浦电子有限公司 Cathode-ray tube
AU2001294876A1 (en) * 2000-09-29 2002-04-08 President And Fellows Of Harvard College Direct growth of nanotubes, and their use in nanotweezers
US6354133B1 (en) * 2000-10-25 2002-03-12 Advanced Micro Devices, Inc. Use of carbon nanotubes to calibrate conventional tips used in AFM
US20020074317A1 (en) * 2000-12-18 2002-06-20 Johnson Eric Orace NanoEDM: an apparatus for machining and building atomic sized structures
US20040128016A1 (en) * 2001-03-22 2004-07-01 Stewart David H. Method for manufacturing a near net-shape mold
US7441444B2 (en) * 2001-03-30 2008-10-28 The Johns Hopkins University AFM cantilevers and methods for making and using same
AU2002339597A1 (en) * 2001-11-09 2003-05-19 Koninklijke Philips Electronics N.V. Vacuum display device
US20050081363A1 (en) * 2002-01-03 2005-04-21 Malshe Ajay P. Apparatus and method for nanoscale and microscale mechanical machining and processing
CA2499370A1 (en) * 2002-09-20 2004-06-05 The Trustees Of Boston College Nanotube cantilever probes for nanoscale magnetic microscopy
US6918982B2 (en) * 2002-12-09 2005-07-19 International Business Machines Corporation System and method of transfer printing an organic semiconductor
GB0304623D0 (en) * 2003-02-28 2003-04-02 Univ Surrey Methods for the fabrication of nanoscale structures and semiconductor devices
WO2004104568A1 (en) * 2003-05-23 2004-12-02 Japan Science And Technology Agency Single-electron transistor, field-effect transistor, sensor, method for producing sensor, and sensing method
US20050067936A1 (en) * 2003-09-25 2005-03-31 Lee Ji Ung Self-aligned gated carbon nanotube field emitter structures and associated methods of fabrication

Patent Citations (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4446373A (en) * 1981-01-12 1984-05-01 Sony Corporation Process and apparatus for converged fine line electron beam treatment objects
US5294465A (en) * 1989-10-10 1994-03-15 The United States Of America As Represented By The Secretary Of Commerce Microtip-controlled nanostructure fabrication and multi-tipped field emission tool for parallel-process nanostructure fabrication
US5021672A (en) * 1989-12-22 1991-06-04 E. I. Du Pont De Nemours And Company Etching of nanoscale structures
US5214347A (en) * 1990-06-08 1993-05-25 The United States Of America As Represented By The Secretary Of The Navy Layered thin-edged field-emitter device
US5194780A (en) * 1990-06-13 1993-03-16 Commissariat A L'energie Atomique Electron source with microtip emissive cathodes
US5196707A (en) * 1991-03-04 1993-03-23 Etec Systems, Inc. Low aberration field emission electron gun
US5210425A (en) * 1991-08-30 1993-05-11 E. I. Du Pont De Nemours And Company Etching of nanoscale structures
US5894058A (en) * 1995-03-02 1999-04-13 Ebara Corporation Ultra-fine microfabrication method using a fast atomic energy beam
US6007969A (en) * 1995-03-02 1999-12-28 Ebara Corporation Ultra-fine microfabrication method using an energy beam
US6010831A (en) * 1995-03-02 2000-01-04 Ebara Corporation Ultra-fine microfabrication method using an energy beam
US6528807B1 (en) * 1997-08-05 2003-03-04 Hans Wilfried Peter Koops Method for applying or removing material
US6146227A (en) * 1998-09-28 2000-11-14 Xidex Corporation Method for manufacturing carbon nanotubes as functional elements of MEMS devices
US6369385B1 (en) * 1999-05-05 2002-04-09 Applied Materials, Inc. Integrated microcolumn and scanning probe microscope arrays
US6469433B1 (en) * 2000-01-28 2002-10-22 Extreme Devices Incorporated Package structure for mounting a field emitting device in an electron gun
US6921575B2 (en) * 2001-05-21 2005-07-26 Fuji Xerox Co., Ltd. Carbon nanotube structures, carbon nanotube devices using the same and method for manufacturing carbon nanotube structures
US6906470B2 (en) * 2001-06-04 2005-06-14 Trepton Research Group, Inc. Method and system for controlling electron beams from field emission cathodes
US6660959B2 (en) * 2001-11-21 2003-12-09 University Of Kentucky Research Foundation Processes for nanomachining using carbon nanotubes
US6815877B2 (en) * 2002-07-11 2004-11-09 Hon Hai Precision Ind. Co., Ltd. Field emission display device with gradient distribution of electrical resistivity
US7279686B2 (en) * 2003-07-08 2007-10-09 Biomed Solutions, Llc Integrated sub-nanometer-scale electron beam systems
US7183548B1 (en) * 2004-02-25 2007-02-27 Metadigm Llc Apparatus for modifying and measuring diamond and other workpiece surfaces with nanoscale precision

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20080169429A1 (en) * 2005-01-27 2008-07-17 Commissariat A L'energie Atomique Microelectronic Multiple Electron Beam Emitting Device
US7800085B2 (en) * 2005-01-27 2010-09-21 Commissariat A L'energie Atomique Microelectronic multiple electron beam emitting device
WO2015042022A1 (en) * 2013-09-20 2015-03-26 Applied Materials, Inc. Method and apparatus for direct formation of nanometer scaled features
TWI637902B (en) * 2013-09-20 2018-10-11 應用材料股份有限公司 Method and apparatus for direct formation of nanometer scaled features
EP3563399A4 (en) * 2016-12-29 2020-07-29 The University of British Columbia Optically addressed, thermionic electron beam device
US10741352B2 (en) 2016-12-29 2020-08-11 The Board Of Trustees Of The Leland Stanford Junior University Optically addressed, thermionic electron beam device

Also Published As

Publication number Publication date
US7786402B2 (en) 2010-08-31
US20070125753A1 (en) 2007-06-07
US20040245224A1 (en) 2004-12-09
WO2004102601A3 (en) 2005-06-30
US20060213877A1 (en) 2006-09-28
WO2004102601A2 (en) 2004-11-25

Similar Documents

Publication Publication Date Title
US7786402B2 (en) Nanospot welder and method
US7332736B2 (en) Article comprising gated field emission structures with centralized nanowires and method for making the same
US7233101B2 (en) Substrate-supported array having steerable nanowires elements use in electron emitting devices
US6858521B2 (en) Method for fabricating spaced-apart nanostructures
KR100686294B1 (en) Emission source having carbon nanotube, electronic microscope and electronic beam lithographic device using the same
US7868850B2 (en) Field emitter array with split gates and method for operating the same
Milne et al. Carbon nanotubes as field emission sources
US7465210B2 (en) Method of fabricating carbide and nitride nano electron emitters
US20020097204A1 (en) Electron emission device with gap between electron emission electrode and substrate
JP2007087676A (en) Field emission type electron gun and electron beam device using it
JPH02186545A (en) Charged-particle beam generator
EP1412961A2 (en) Mobile miniature x-ray source
EP0958592A1 (en) Digital direct write electron beam lithography
KR20090065108A (en) The compactive x-ray tube with triode structure using cnt
JP3982558B2 (en) Electron source having carbon nanotubes, electron microscope and electron beam drawing apparatus using the same
GB2374979A (en) A field ionisation source
JP4317779B2 (en) Field emission electron gun and electron beam application apparatus using the same
JP2003513407A (en) Improved thermal field emission alignment
JP3198362B2 (en) Electron emitting device and image forming apparatus
JPH07296755A (en) Electron beam source, and electron beam applying device using it
KR101227258B1 (en) Triode cold cathode electron source for x-ray generation using array of multiple carbon nano-tube tips
CA2280234C (en) Device comprising carbon nanotube field emitter structure and process for forming device
JP3524737B2 (en) Electron gun and electron beam device
Fratini et al. Carbon-nanotubes field emitter to be used in advanced X-ray source
KR20070056610A (en) Electron emission device and electron emission display device using the same

Legal Events

Date Code Title Description
STCB Information on status: application discontinuation

Free format text: ABANDONED -- FAILURE TO RESPOND TO AN OFFICE ACTION