US20080210565A1 - Method of Surface Treatment for Metal and Nonmetal Surfaces - Google Patents
Method of Surface Treatment for Metal and Nonmetal Surfaces Download PDFInfo
- Publication number
- US20080210565A1 US20080210565A1 US12/119,217 US11921708A US2008210565A1 US 20080210565 A1 US20080210565 A1 US 20080210565A1 US 11921708 A US11921708 A US 11921708A US 2008210565 A1 US2008210565 A1 US 2008210565A1
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- Prior art keywords
- objects
- electro
- coating solution
- coating
- metal
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C28/00—Coating for obtaining at least two superposed coatings either by methods not provided for in a single one of groups C23C2/00 - C23C26/00 or by combinations of methods provided for in subclasses C23C and C25C or C25D
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D13/00—Electrophoretic coating characterised by the process
- C25D13/04—Electrophoretic coating characterised by the process with organic material
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D13/00—Electrophoretic coating characterised by the process
- C25D13/22—Servicing or operating apparatus or multistep processes
Definitions
- the invention relates to surface treatment for metal or nonmetal materials and more particularly to a method of surface treatment involving steps of depositing a metal coat on a surface of metal or nonmetal object by evaporation and depositing an outer layer on the metal coat by electro-coating.
- a conventional method for electroplating a metal layer on an object such as a drawer handle, a door handle, or a lock generally involves immersing an object to be treated in an electrolytic tank, employing a strong acid solution to remove foreign particles and dust from the surface of the object, electroplating a desired metal layer on the surface of the object, and coating a lacquer on the metal layer as protection.
- the chemical solution such as the strong acid solution may pollute the environment and equipment for processing the waste solution is very expensive. As a result, the manufacturing cost is increased greatly. Moreover, only the objects having a metal surface can be electroplated and this inevitably limits the applications.
- the lacquer does not have good corrosion resistant property which is important in some circumstances. The lacquer also lacks durability and luster thereof is difficult to maintain as time passes. Usually, the object is coated with copper, nickel and silver sequentially so as to be rustproof. However, many processes are required, resulting in a further increase of the manufacturing cost. Thus, the need for improvement still exists.
- It is therefore one object of the invention to provide a method of treating a metal or nonmetal object comprising the steps of depositing a metal coat on a surface of the metal or nonmetal object by evaporation and coating an outer layer on the metal coat by electro-coating so that the surface of the produced metal or nonmetal object can be resistant to rust and smooth.
- Another object of the invention is to provide a cost effective method of surface treatment capable of reducing pollution to the environment.
- FIG. 1 is a flowchart depicting a process of surface treatment for metal or nonmetal object according to the invention
- FIG. 2 is an exploded perspective view showing an object to be positioned on a structural member for surface treatment according to the invention
- FIG. 3 is a top plan view of the objects positioned on the structural member
- FIG. 4 is a top plan view schematically depicting the objects on the structural members put in a tank for evaporation
- FIG. 5 is a longitudinal sectional view of FIG. 4 showing the objects on the structural members being immersed in the electro-coating solution
- FIG. 6 is a detailed view of the area in circle A in FIG. 3 showing the object after the surface treatment.
- FIGS. 1 to 6 a process of surface treatment for metal or nonmetal object in accordance with of the invention is illustrated.
- the process comprises the following steps:
- a plurality of objects e.g., ones made of metal material
- the objects 11 may be made of nonmetal material in other embodiments.
- step 20 the objects 11 are positioned on a pole shaped structural member (e.g., metal or insulative one) 21 .
- a pole shaped structural member e.g., metal or insulative one
- a thin coating e.g., acrylic resin, epoxy resin, or nylon resin
- the thin coating 31 is adapted to fill any small cavities on the surface of the object 11 so as to make the surface of the object 11 flat.
- step 40 the thin coating 31 is hardened by drying in room temperature or by heating in a temperature between about 70° C. and 180° C. for a time period between about 20 minutes and about 70 minutes.
- step 50 the objects 11 together with the structural members 21 are put on a tray 521 in a heating chamber 52 in place.
- An electric heating unit 53 is provided in the heating chamber 52 and comprises two electrodes 522 of opposite polarities and a tungsten filament (not numbered) interconnecting the electrodes 522 .
- the tungsten filament is wrapped by metal for evaporation.
- air in the heating chamber 52 is evacuated to vacuum.
- the heating unit 53 is energized by flowing electric current thereto.
- the tungsten filament is heated by current flowing from one electrode 522 to the other electrode 522 and the metal on the tungsten filament thus is evaporated to become very fine particles which are adapted to adhere to the thin coating 31 on each object 11 and the structural members 21 .
- first metal coat 51 is formed on the thin coating 31 of the object 11 by coating and a second metal coat 54 is formed on each of a plurality of branches 213 of the structural member 21 by coating.
- first metal coat 51 and the second metal coat 54 has a thickness in a range of about 0.1 ⁇ m to about 1.0 ⁇ m.
- step 60 place the objects 11 together with the structural members 21 in a tank 62 filled with electro-coating solution 63 .
- the electro-coating solution 63 conducts by the conductive structural members 21 and dissociated positive or negative ions of the electro-coating solution 63 move to the surfaces of the objects 11 for adhesion (i.e., electro-coating).
- an outer layer 61 is coated on each object 11 .
- the electro-coating solution 63 may decompose into positive ions if it is formed of positive acrylic resin, positive epoxy resin, or positive polyurethane resin.
- the electro-coating solution 63 may decompose into negative ions if it is formed of negative acrylic resin or negative polyurethane resin.
- step 70 drying is done.
- step 80 the objects 11 are removed from each structural member 21 .
- each structural member 21 is provided with a top mating member 212 adapted to secure to a corresponding mating member (not shown) of the heating chamber 52 for securing the structural member 21 to the heating chamber 52 , an upper hook 211 adapted to hang on a conveyor (not shown), and a plurality of branches 213 adapted to position the objects 11 thereon. Note that the structural members 21 are removed from the conveyor only in the evaporation step (i.e., step 50 ).
- the process (i.e., electro-coating) of the invention can be applied to coating the metal objects 11 with a color outer layer in which one such process comprises the following steps:
- the weight of the coloring agent in the electro-coating solution is about 6% to 14% of the weight of the electro-coating solution.
- An anode and a cathode are provided in the tank.
- a direct current is applied to the electro-coating solution in the tank for a period of time between about 10 seconds to about 50 seconds. Further, the operating voltage is in a range of about 40V to 190V.
- the other electro-coating process comprises the following steps:
- the invention has the following advantages. No strong chemical solution is involved in the evaporation step (i.e., step 50 ). Further, the electro-coating solution involved in step 60 causes no pollution to the environment.
- the invention applies to both metal and nonmetal materials. To the contrary, conventional electroplating is applicable to metal objects only.
- the surface of each object is deposited with a first metal coat and that of each structural member is deposited with a second metal coat respectively (i.e., both being conductive).
- the objects and the structural members are placed in a tank for electro-coating after the evaporation step.
- acrylic ions in the tank filled with electro-coating solution move to the metal coats.
- an outer layer is coated on the object.
- the outer layer has the properties of corrosion resistance, being aesthetic, wear resistance, etc.
- the plating of the invention is far much better than the typical lacquer.
Abstract
A method of treating the surface of each of a plurality of objects comprising washing the objects; positioning the objects on each of a plurality of structural members; depositing a thin coating on each object; drying the thin coatings; placing the objects and the structural members on a tray in a heating chamber wherein an electric heating unit is disposed in the heating chamber for forming a first metal coat on the thin coating of each object and a second metal coat on each structural member by evaporation; placing the objects and the structural members in a tank filled with electro-coating solution such that after conducting the electro-coating solution positive or negative ions of the electro-coating solution are dissociated and move to the surfaces of the objects for depositing an outer layer thereon; and removing the objects from each structural member.
Description
- This application is a continuation-in-part of my application Ser. No. 11/199,027 filed Aug. 8, 2005 for “Method of Surface Treatment for Metal and Nonmetal Surfaces”, now abandoned.
- 1. Field of Invention
- The invention relates to surface treatment for metal or nonmetal materials and more particularly to a method of surface treatment involving steps of depositing a metal coat on a surface of metal or nonmetal object by evaporation and depositing an outer layer on the metal coat by electro-coating.
- 2. Description of Related Art
- A conventional method for electroplating a metal layer on an object such as a drawer handle, a door handle, or a lock generally involves immersing an object to be treated in an electrolytic tank, employing a strong acid solution to remove foreign particles and dust from the surface of the object, electroplating a desired metal layer on the surface of the object, and coating a lacquer on the metal layer as protection.
- However, the chemical solution such as the strong acid solution may pollute the environment and equipment for processing the waste solution is very expensive. As a result, the manufacturing cost is increased greatly. Moreover, only the objects having a metal surface can be electroplated and this inevitably limits the applications. In addition, the lacquer does not have good corrosion resistant property which is important in some circumstances. The lacquer also lacks durability and luster thereof is difficult to maintain as time passes. Usually, the object is coated with copper, nickel and silver sequentially so as to be rustproof. However, many processes are required, resulting in a further increase of the manufacturing cost. Thus, the need for improvement still exists.
- It is therefore one object of the invention to provide a method of treating a metal or nonmetal object comprising the steps of depositing a metal coat on a surface of the metal or nonmetal object by evaporation and coating an outer layer on the metal coat by electro-coating so that the surface of the produced metal or nonmetal object can be resistant to rust and smooth.
- Another object of the invention is to provide a cost effective method of surface treatment capable of reducing pollution to the environment.
- The above and other objects, features and advantages of the invention will become apparent from the following detailed description taken with the accompanying drawings.
-
FIG. 1 is a flowchart depicting a process of surface treatment for metal or nonmetal object according to the invention; -
FIG. 2 is an exploded perspective view showing an object to be positioned on a structural member for surface treatment according to the invention; -
FIG. 3 is a top plan view of the objects positioned on the structural member; -
FIG. 4 is a top plan view schematically depicting the objects on the structural members put in a tank for evaporation; -
FIG. 5 is a longitudinal sectional view ofFIG. 4 showing the objects on the structural members being immersed in the electro-coating solution; and -
FIG. 6 is a detailed view of the area in circle A inFIG. 3 showing the object after the surface treatment. - Referring to
FIGS. 1 to 6 , a process of surface treatment for metal or nonmetal object in accordance with of the invention is illustrated. - The process comprises the following steps:
- In
step 10, a plurality of objects (e.g., ones made of metal material) 11 are prepared after being washed. Note that theobjects 11 may be made of nonmetal material in other embodiments. - In
step 20, theobjects 11 are positioned on a pole shaped structural member (e.g., metal or insulative one) 21. - In
step 30, a thin coating (e.g., acrylic resin, epoxy resin, or nylon resin) 31 is coated on eachobject 11. Thethin coating 31 is adapted to fill any small cavities on the surface of theobject 11 so as to make the surface of theobject 11 flat. - In
step 40, thethin coating 31 is hardened by drying in room temperature or by heating in a temperature between about 70° C. and 180° C. for a time period between about 20 minutes and about 70 minutes. - In
step 50, theobjects 11 together with thestructural members 21 are put on atray 521 in aheating chamber 52 in place. Anelectric heating unit 53 is provided in theheating chamber 52 and comprises twoelectrodes 522 of opposite polarities and a tungsten filament (not numbered) interconnecting theelectrodes 522. The tungsten filament is wrapped by metal for evaporation. In operation, air in theheating chamber 52 is evacuated to vacuum. Next, theheating unit 53 is energized by flowing electric current thereto. Hence, the tungsten filament is heated by current flowing from oneelectrode 522 to theother electrode 522 and the metal on the tungsten filament thus is evaporated to become very fine particles which are adapted to adhere to thethin coating 31 on eachobject 11 and thestructural members 21. As a result, afirst metal coat 51 is formed on thethin coating 31 of theobject 11 by coating and asecond metal coat 54 is formed on each of a plurality ofbranches 213 of thestructural member 21 by coating. Thus, thestructural members 21 and theobjects 11 become conductive. Each of thefirst metal coat 51 and thesecond metal coat 54 has a thickness in a range of about 0.1 μm to about 1.0 μm. - In
step 60, place theobjects 11 together with thestructural members 21 in atank 62 filled with electro-coating solution 63. Hence, the electro-coating solution 63 conducts by the conductivestructural members 21 and dissociated positive or negative ions of the electro-coating solution 63 move to the surfaces of theobjects 11 for adhesion (i.e., electro-coating). As a result, anouter layer 61 is coated on eachobject 11. The electro-coating solution 63 may decompose into positive ions if it is formed of positive acrylic resin, positive epoxy resin, or positive polyurethane resin. The electro-coating solution 63 may decompose into negative ions if it is formed of negative acrylic resin or negative polyurethane resin. - In
step 70 drying is done. - In
step 80 theobjects 11 are removed from eachstructural member 21. - For conveying the structural members 21 (i.e., objects 11) between different manufacturing steps each
structural member 21 is provided with atop mating member 212 adapted to secure to a corresponding mating member (not shown) of theheating chamber 52 for securing thestructural member 21 to theheating chamber 52, anupper hook 211 adapted to hang on a conveyor (not shown), and a plurality ofbranches 213 adapted to position theobjects 11 thereon. Note that thestructural members 21 are removed from the conveyor only in the evaporation step (i.e., step 50). - The process (i.e., electro-coating) of the invention can be applied to coating the
metal objects 11 with a color outer layer in which one such process comprises the following steps: - a1) Mix a coloring agent with electro-coating solution prior to pouring same in a tank.
- b1) Place objects processed by evaporation in the tank.
- c1) Remove the objects, wash it, and dry it. As a result, a dyed outer layer is coated on each object.
- The weight of the coloring agent in the electro-coating solution is about 6% to 14% of the weight of the electro-coating solution. An anode and a cathode are provided in the tank. In electro-coating, a direct current is applied to the electro-coating solution in the tank for a period of time between about 10 seconds to about 50 seconds. Further, the operating voltage is in a range of about 40V to 190V.
- The other electro-coating process comprises the following steps:
- a2) Pour electro-coating solution mixed with water into a tank.
- b2) Place objects processed by electro-coating in the tank.
- c2) Remove the objects, wash it, and dry it.
- d2) Pour dying agent into a second tank.
- e2) Place the objects in the second tank for dying.
- f2) Remove the objects, wash it, and dry it. As a result, a dyed outer layer is coated on each object.
- The invention has the following advantages. No strong chemical solution is involved in the evaporation step (i.e., step 50). Further, the electro-coating solution involved in
step 60 causes no pollution to the environment. The invention applies to both metal and nonmetal materials. To the contrary, conventional electroplating is applicable to metal objects only. For electro-coating objects formed of a nonmetal material, the surface of each object is deposited with a first metal coat and that of each structural member is deposited with a second metal coat respectively (i.e., both being conductive). The objects and the structural members are placed in a tank for electro-coating after the evaporation step. Next, for example, acrylic ions in the tank filled with electro-coating solution move to the metal coats. As a result, an outer layer is coated on the object. The outer layer has the properties of corrosion resistance, being aesthetic, wear resistance, etc. The plating of the invention is far much better than the typical lacquer. - While the invention herein disclosed has been described by means of specific embodiments, numerous modifications and variations could be made thereto by those skilled in the art without departing from the scope and spirit of the invention set forth in the claims.
Claims (15)
1. A method of treating the surface of each of a plurality of objects comprising the steps of:
(a) washing the objects;
(b) positioning the objects on each of a plurality of structural members;
(c) depositing a thin coating on each object wherein the thin coating is made of acrylic resin, epoxy resin, or nylon resin, and the thin coating is adapted to fill cavities on the surface of each object;
(d) drying the thin coatings;
(e) placing the objects together with the structural members on a tray in a heating chamber wherein an electric heating unit is disposed in the heating chamber and comprises two electrodes of opposite polarities and a tungsten filament interconnecting the electrodes, the tungsten filament being wrapped by metal for evaporation such that evacuating the air in the heating chamber to be vacuum and energizing the heating unit by flowing electric current thereto will evaporate the metal on the tungsten filament into fine particles which are adapted to adhere to the thin coating on each object and each structural member, thereby forming a first metal coat on the thin coating of each object and a second metal coat on each structural member so as to be conductive;
(f) placing the objects and the structural members in a tank filled with electro-coating solution such that after conducting the electro-coating solution positive or negative ions of the electro-coating solution are dissociated and move to the surfaces of the objects for depositing an outer layer thereon wherein the electro-coating solution is either positive electro-coating solution or negative electro-coating solution; and
(g) removing the objects from each structural member;
the method further comprising a conveying device, and wherein the structural member comprises a mating member adapted to secure to a corresponding mating member of the heating chamber for securing the structural member to the heating chamber, a hook adapted to hang on the conveying device, and a plurality of branches adapted to position the objects.
2. The method of claim 1 , wherein the objects are metal.
3. The method of claim 1 , wherein the objects are nonmetal.
4. The method of claim 1 , further comprising a step of drying between steps (f) and (g).
5. The method of claim 1 , wherein the thin coatings are dried by heating in a temperature between about 70° C. and 180° C. for a time period between about 20 minutes and about 70 minutes.
6. The method of claim 1 , wherein the positive electro-coating solution is formed of positive acrylic resin, positive epoxy resin, or positive polyurethane resin.
7. The method of claim 1 , wherein the negative electro-coating solution is formed of negative acrylic resin or negative polyurethane resin.
8. The method of claim 1 , wherein each of the first metal coat and the second metal coat has a thickness in a range of about 0.1 μm to about 1.0 μm.
9. The method of claim 1 , wherein step (f) is adapted to be replaced by the substeps of:
(f-1) mixing a coloring agent with the electro-coating solution prior to pouring same into a vessel;
(f-2) placing the objects processed in step (e) in the vessel for dying; and
(f-3) removing the objects to wash and dry so as to form a dyed outer layer on each object.
10. The method of claim 9 , wherein the weight of the coloring agent in the electro-coating solution is about 6% to 14% of the weight of the electro-coating solution.
11. The method of claim 9 , wherein the vessel is provided with an anode and a cathode, and wherein in electro-coating a direct current is applied to the electro-coating solution for a predetermined period of time and an operating voltage of the electro-coating is in a range of about 40 volts to 190 volts.
12. The method of claim 11 , wherein the predetermined period of time is between about 10 seconds to about 50 seconds.
13. The method of claim 1 , wherein step (f) is adapted to be replaced by the substeps of:
(f-4) mixing the electro-coating solution with water and pouring same into a first vessel;
(f-5) placing the objects processed in step (e) in the first vessel;
(f-6) removing the objects to wash and dry;
(f-7) pouring dying agent into a second vessel;
(f-8) placing the objects in the second vessel for dying; and
(f-9) removing the objects to wash and dry so as to form a dyed outer layer on each object.
14. The method of claim 1 , wherein the structural members are metal.
15. The method of claim 1 , wherein the structural members are nonmetal.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US12/119,217 US20080210565A1 (en) | 2005-08-08 | 2008-05-12 | Method of Surface Treatment for Metal and Nonmetal Surfaces |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US11/199,027 US20070029205A1 (en) | 2005-08-08 | 2005-08-08 | Method of surface treatment for metal and nonmetal surfaces |
US12/119,217 US20080210565A1 (en) | 2005-08-08 | 2008-05-12 | Method of Surface Treatment for Metal and Nonmetal Surfaces |
Related Parent Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US11/199,027 Continuation-In-Part US20070029205A1 (en) | 2005-08-08 | 2005-08-08 | Method of surface treatment for metal and nonmetal surfaces |
Publications (1)
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US20080210565A1 true US20080210565A1 (en) | 2008-09-04 |
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Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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US12/119,217 Abandoned US20080210565A1 (en) | 2005-08-08 | 2008-05-12 | Method of Surface Treatment for Metal and Nonmetal Surfaces |
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Citations (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3988955A (en) * | 1972-12-14 | 1976-11-02 | Engel Niels N | Coated steel product and process of producing the same |
US4071639A (en) * | 1975-10-22 | 1978-01-31 | Combustion Engineering, Inc. | Coating material and method |
US4217855A (en) * | 1974-10-23 | 1980-08-19 | Futaba Denshi Kogyo K.K. | Vaporized-metal cluster ion source and ionized-cluster beam deposition device |
US4505948A (en) * | 1983-05-13 | 1985-03-19 | Wedtech Corp. | Method of coating ceramics and quartz crucibles with material electrically transformed into a vapor phase |
US4746399A (en) * | 1986-06-18 | 1988-05-24 | Ciba-Geigy Corporation | Method for making metallic patterns |
US4837090A (en) * | 1987-11-05 | 1989-06-06 | Whyco Chromium Company, Inc. | Corrosion resistant coating for fasteners |
US6436474B2 (en) * | 1999-01-13 | 2002-08-20 | Illinois Tool Works Inc. | Method of chemically coating fasteners having improved penetration and withdrawal resistance |
US7166330B2 (en) * | 2004-03-29 | 2007-01-23 | Nippon Paint Co., Ltd. | Method for forming a glittering coating film |
US7273337B2 (en) * | 2003-06-30 | 2007-09-25 | Illinois Tool Works Inc. | Partially coated fastener assembly and method for coating |
US7579082B2 (en) * | 2001-08-20 | 2009-08-25 | Basf Aktiengesellschaft | Films coated with paint |
-
2008
- 2008-05-12 US US12/119,217 patent/US20080210565A1/en not_active Abandoned
Patent Citations (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3988955A (en) * | 1972-12-14 | 1976-11-02 | Engel Niels N | Coated steel product and process of producing the same |
US4217855A (en) * | 1974-10-23 | 1980-08-19 | Futaba Denshi Kogyo K.K. | Vaporized-metal cluster ion source and ionized-cluster beam deposition device |
US4071639A (en) * | 1975-10-22 | 1978-01-31 | Combustion Engineering, Inc. | Coating material and method |
US4609564C2 (en) * | 1981-02-24 | 2001-10-09 | Masco Vt Inc | Method of and apparatus for the coating of a substrate with material electrically transformed into a vapor phase |
US4609564A (en) * | 1981-02-24 | 1986-09-02 | Wedtech Corp. | Method of and apparatus for the coating of a substrate with material electrically transformed into a vapor phase |
US4609564B1 (en) * | 1981-02-24 | 1998-04-14 | Masco Vt Inc | Method of and apparatus for the coating of a substrate with material electrically transformed into a vapor phase |
US4505948A (en) * | 1983-05-13 | 1985-03-19 | Wedtech Corp. | Method of coating ceramics and quartz crucibles with material electrically transformed into a vapor phase |
US4746399A (en) * | 1986-06-18 | 1988-05-24 | Ciba-Geigy Corporation | Method for making metallic patterns |
US4837090A (en) * | 1987-11-05 | 1989-06-06 | Whyco Chromium Company, Inc. | Corrosion resistant coating for fasteners |
US6436474B2 (en) * | 1999-01-13 | 2002-08-20 | Illinois Tool Works Inc. | Method of chemically coating fasteners having improved penetration and withdrawal resistance |
US7579082B2 (en) * | 2001-08-20 | 2009-08-25 | Basf Aktiengesellschaft | Films coated with paint |
US7273337B2 (en) * | 2003-06-30 | 2007-09-25 | Illinois Tool Works Inc. | Partially coated fastener assembly and method for coating |
US7166330B2 (en) * | 2004-03-29 | 2007-01-23 | Nippon Paint Co., Ltd. | Method for forming a glittering coating film |
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