US20070120284A1

US20070120284A1 - Wood composite panel containing diiodomethyl-p-tolylsulfone

Info

Publication number: US20070120284A1
Application number: US11/288,526
Authority: US
Inventors: Eric Lawson; Federico Cecilio
Original assignee: Huber Engineered Woods LLC
Current assignee: Huber Engineered Woods LLC
Priority date: 2005-11-29
Filing date: 2005-11-29
Publication date: 2007-05-31
Also published as: TW200734148A; WO2007064561A3; AR057206A1; WO2007064561A2; PE20070746A1

Abstract

Disclosed is a method for the production of a wood composite board comprising the steps of: providing a quantity of wood in the form of wood strands; drying the wood strands; coating the wood strands with a binder composition and diiodomethyl-p-tolylsulfone to from coated and treated strands; forming a mat from the coated and treated strands; pressing the mat, at a high temperature, to form the wood composite board having a final thickness.

Description

BACKGROUND OF THE INVENTION

Wood can be used to construct almost any part of a home from the roofing and exterior walls to the floor and interior architectural elements as well as basic domestic items like furniture and cabinets. However, in recent years the cost of solid timber wood has increased dramatically as its supply shrinks due to the gradual depletion of old-growth and virgin forests. Indeed, it is particularly expensive to manufacture solid hardwood furniture and architectural features from such material because typically less than half of harvested timber wood is converted to natural solid wood lumber, the remainder being discarded as scrap.
Accordingly, because of both the cost of high-grade timber wood as well as a heightened emphasis on conserving natural resources, wood-based alternatives to natural solid wood lumber have been developed that make more efficient use of harvested wood and reduce the amount of wood discarded as scrap. Plywood, particle board and oriented strand board (“OSB”) are examples of wood-based composite alternatives to natural solid wood lumber that have replaced natural solid wood lumber in many structural applications in the last seventy-five years. These wood-based composites not only use the available supply of timber wood more efficiently, but they can also be formed from lower-grade wood species, and even from wood wastes.
However, like conventional solid wood lumber, these wood composite materials also suffer from unwanted wood consumers, namely fungus and microbial parasites. A variety of techniques have been developed to address the issue of fungus and rot in wood composite materials. Unfortunately, most of these techniques involve compounds that are either extremely poisonous or are not suitable for use in manufacturing wood-based composites. Additionally, many of these same techniques are rather expensive.
Yet an additional difficulty is that the organic solvents used in processes of dip coating or spray treatment may have the undesirable side effect of dissolving the water-resistant wax that is applied to a wood composite material.
Given the foregoing, there is a need in the art for a wood composite panel containing a fungicide that imparts a resistance to insect and fungus infestations without the use of toxic or potentially harmful chemicals.

BRIEF SUMMARY OF THE INVENTION

The present invention relates to a method for the production of a wood composite board comprising the steps of: providing a quantity of wood in the form of wood strands; drying the wood strands; coating the wood strands with a binder composition and diiodomethyl-p-tolylsulfone to from coated and treated strands; forming a mat from the coated and treated strands; pressing the mat, at a high temperature, to form the wood composite board having a final thickness.

DETAILED DESCRIPTION OF THE INVENTION

All parts, percentages and ratios used herein are expressed by weight unless otherwise specified. All documents cited herein are incorporated by reference.
As used herein, “wood” is intended to mean a cellular structure, having cell walls composed of cellulose and hemicellulose fibers bonded together by lignin polymer.
By “laminated”, it is meant material composed of layers and bonded together using resin binders.
By “wood composite material” or “wood composite component” it is meant a composite material that comprises wood and one or more other additives, such as adhesives or waxes. Non-limiting examples of wood composite materials include oriented strand board (“OSB”), structural composite lumber (“SCL”), waferboard, particle board, chipboard, medium-density fiberboard, plywood, and boards that are a composite of strands and ply veneers. As used herein, “flakes”, “strands”, and “wafers” are considered equivalent to one another and are used interchangeably. A non-exclusive description of wood composite materials may be found in the Supplement Volume to the Kirk-Othmer Encyclopedia of Chemical Technology, pp 765-810, 6 ^thEdition, which is hereby incorporated by reference.
The present invention is directed to wood composite panels that incorporate an antimicrobial and fungicide compound, diiodomethyl-p-tolylsulfone. When diiodomethyl-p-tolylsulfone is applied to surface of a wood board by dipping the board in diiodomethyl-p-tolylsulfone or sprayng diiodomethyl-p-tolylsulfone on the board, the diiodomethyl-p-tolylsulfone is effective at repelling fungus and microbial pests and yet at the same time is so safe and non-toxic that it is a common additive in children's finger paints.
Unfortunately, while diiodomethyl-p-tolylsulfone is an effective fungicide, it has been discovered in the present invention that it is not the most robust compound when applied to wood composite products that may be treated roughly during their installation and use in construction. For example, these wood composite panels are often cut during installation and then fasteners (such as a nail) are driven through them to attach them firmly in place. Both the acts of cutting and nailing the wood board expose unprotected area of the wood board, leaving it susceptible to fungal or microbial attack. Applying the diiodomethyl-p-tolylsulfone using pressure treatment is more effective, but also significantly more costly.
Accordingly, to address this problem the diiodomethyl-p-tolylsulfone is added to the wood composite panel, not at the completion of panel manufacture, but during the blending and mixing stages (discussed in greater detail below) so that the fungicide is applied directly to the strands and fully penetrates into the strands and is integrated into the wood composite panel. Diiodomethyl-p-tolylsulfone is effective both as a fungicide and as a microbial agent against bacteria, and yet at the same time it is so sufficiently safe and non-toxic that it has been approved for use in children's finger paint. By incorporating the diiodomethyl-p-tolylsulfone during the blending and mixing stages, the diiodomethyl-p-tolylsulfone remains effective even when the integrity of the material is compromised by cutting it or driving a fastener through it. Nor does application in this way damage the protective, water-resistant wax layer.
Methods for applying the diiodomethyl-p-tolylsulfone are discussed in greater detail, below. Preferably the diiodomethyl-p-tolylsulfone is present in a concentration range of about 0.25 wt % to about 1.50 wt %.
The wood composite panels are made from a starting material that is naturally occurring hard or soft woods, singularly or mixed, whether such wood is dry (having a moisture content of between 2 wt % and 12 wt %) or green (having a moisture content of between 30 wt % and 200 wt %). Typically, the raw wood starting materials, either virgin or reclaimed, are cut into strands, wafers or flakes of desired size and shape, which are well known to one of ordinary skill in the art.
After the strands are cut they are dried in a drying oven (such as a tumbling oven) to a moisture content of about 2 wt % to 5 wt %. The strands are then subsequently coated with a special formulation of one or more polymeric thermosetting binder resins, waxes and other additives in a blending step. The binder resin and the other various additives that are applied to the wood materials are referred to herein as a coating, even though the binder and additives may be in the form of small particles, such as atomized particles or solid particles, which do not form a continuous coating upon the wood material. Conventionally, the binder, wax and any other additives are applied to the wood materials by one or more spraying, blending or mixing techniques, a preferred technique is to spray the wax, resin and other additives upon the wood strands as the strands are tumbled in a drum blender.
After being coated and treated with the desired coating and treatment chemicals, these coated strands are used to form a multi-layered mat, preferably a three layered mat. This layering may be done in the following fashion. The coated flakes are spread on a conveyor belt to provide a first ply or layer having flakes oriented substantially in line, or parallel, to the conveyor belt, then a second ply is deposited on the first ply, with the flakes of the second ply oriented substantially perpendicular to the conveyor belt. Finally, a third ply having flakes oriented substantially in line with the conveyor belt, similar to the first ply, is deposited on the second ply such that plies built-up in this manner have flakes oriented generally perpendicular to a neighboring ply. Alternatively, but less preferably, all plies can have strands oriented in random directions. The multiple plies or layers can be deposited using generally known multi-pass techniques and strand orienter equipment. In the case of a three ply or three layered mat, the first and third plys are surface layers, while the second ply is a core layer. The surface layers each have an exterior face.
The above example may also be done in different relative directions, so that the first ply has flakes oriented substantially perpendicular to conveyor belt, then a second ply is deposited on the first ply, with the flakes of the second ply oriented substantially parallel to the conveyor belt. Finally, a third ply having flakes oriented substantially perpendicular with the conveyor belt, similar to the first ply, is deposited on the second ply.
Various polymeric resins, preferably thermosetting resins, may be employed as binders for the wood flakes or strands. Suitable polymeric binders include isocyanate resin, urea-formaldehyde, polyvinyl acetate (“PVA”), phenol formaldehyde, melamine formaldehyde, melamine urea formaldehyde (“MUF”) and the co-polymers thereof. Isocyanates are the preferred binders, and preferably the isocyanates are selected from the diphenylmethane-p,p′-diisocyanate group of polymers, which have NCO-functional groups that can react with other organic groups to form polymer groups such as polyurea, —NCON—, and polyurethane, —NCOON—; a binder with about 50 wt % 4,4-diphenyl-methane diisocyanate (“MDI”) or in a mixture with other isocyanate oligomers (“pMDI”) is preferred. A suitable commercial pMDI product is Rubinate 1840 available from Huntsman, Salt Lake City, Utah, and Mondur 541 available from Bayer Corporation, North America, of Pittsburgh, Pa. Other suitable resins useful as adhesive binders either separately or in combination with pMDI are the formaldehyde-based liquid PF, powder PF, UF MUF binders, and combinations of these. Suitable commercial MUF binders are the LS 2358 and LS 2250 products from the Dynea corporation.
The binder concentration is preferably in the range of about 3 wt % to about 8 wt %. A wax additive is commonly employed to enhance the resistance of the OSB panels to moisture penetration. Preferred waxes are slack wax or an emulsion wax. The wax solids loading level is preferably in the range of about 0.1 wt % to about 3.0 wt % (based on the weight of the wood).
The diiodomethyl-p-tolylsulfone compound may be used either in powdered form or may be dissolved in a liquid. As previously mentioned the diiodomethyl-p-tolylsulfone is preferably applied after the drying step during the blending step (these steps are described in greater detail below, but are well-known to persons of ordinary skill in the wood composite arts). After being dried, if the diiodomethyl-p-tolylsulfone is meant to be applied in powdered form, the powder can be added to the strands as they enter the blender with the tumbling action of the blender ensuring that the powder is evenly distributed over most or all of the strands. If meant to be applied in liquid form, the material is sprayed through a spray nozzle that evenly distributes the diiodomethyl-p-tolylsulfone over the surface of the strands.
Other methods of application are also possible if also less preferred. For example, rather than applying the diiodomethyl-p-tolylsulfone after the drying step (as discussed above) powdered diiodomethyl-p-tolylsulfone may be applied to the wet flakes before the drying step, further relying on the tumbling action of the dryer to distribute the powder evenly over the strands. Liquid resin could also be applied to the wet flakes. In each case, care should be taken to ensure that all surfaces of the strands are exposed to the diiodomethyl-p-tolylsulfone.
Diiodomethyl-P-Tolylsulfone is commercially available under the tradename AMICAL® and is available from Angus Chemical Company Corporation, Buffalo, Grove, Ill.. Diiodomethyl-p-tolylsulfone is also available under the name “Paracide”.
After the multi-layered mats are formed according to the process discussed above, they are compressed under a hot press machine that fuses and binds together the wood materials, binder, and other additives to form consolidated OSB panels of various thickness and sizes. The high temperature also acts to cure the binder material. Preferably, the panels of the invention are pressed for 2-15 minutes at a temperature of about 175° C. to about 240° C. The resulting composite panels will have a density in the range of about 35 lbs/ft³to about 48 lbs/ft³(as measured by ASTM standard D1037-98). The density ranges from 40 lbs/ft³to 48 lbs/ft³for southern pine, and 35 lbs lbs/ft³to 42 lbs/ft³for Aspen. The thickness of the OSB panels will be from about 0.6 cm (about ¼′) to about 5 cm (about 2′), such as about 1.25 cm to about 6 cm, such as about 2.8 cm to about 3.8 cm.
The invention will now be described in more detail with respect to the following, specific, non-limiting examples.

EXAMPLES

OSB Panels having a target thickness of ¾′ and a target density of 42 pcf were prepared with Mondur G541 pMDI resin at a concentration of 5 wt % (based on the weight of the wood flakes), wax at a concentration of 2.5 wt %, and with diiodomethyl-p-tolylsulfone added during blending at concentrations of 0.0 wt %, 0.25 wt %, 0.5 wt %, 1 wt % and 1.25 wt % (again based on the weight of the wood flakes).

Cubes were then cut from these panels and then tested for fungal resistance according to the test WDMA/INWWDA TM 1 test protocol. In this test, the OSB samples were exposed to the brown rot decay fungus (Gloeophyllum trabeum) and the white rot fungus (Trametes versicolor) under ideal fungal growing conditions for twelve weeks. Before testing, some of the cubes were “weathered” according to Window and Door Standard NWWDA-TM-1 (“Soil Block Test”), while others were not weathered. After exposure is completed the samples are removed and are weighed to determine the percentage of weight loss due to decay. The amount of weight loss is set forth in tables I-III, below.

TABLE I


	Fungicide	Weathered/	Fungus	Weight
Fungicide	Concentration	Non-Weathered	Species	Loss (%)

Paracide	0.0	Non-Weathered	G. trabeum	31.41
Paracide	0.0	Non-Weathered	G. trabeum	41.4
Paracide	0.0	Non-Weathered	G. trabeum	39.8
Paracide	0.0	Non-Weathered	G. trabeum	42.55
Paracide	0.25	Non-Weathered	G. trabeum	25.97
Paracide	0.25	Non-Weathered	G. trabeum	37.44
Paracide	0.5	Non-Weathered	G. trabeum	16.51
Paracide	0.5	Non-Weathered	G. trabeum	10.94
Paracide	0.75	Non-Weathered	G. trabeum	15.81
Paracide	0.75	Non-Weathered	G. trabeum	11.09
Paracide	1.0	Non-Weathered	G. trabeum	1.64
Paracide	1.0	Non-Weathered	G. trabeum	3.76
Paracide	1.0	Non-Weathered	G. trabeum	4.98
Paracide	1.5	Non-Weathered	G. trabeum	1.73
Paracide	1.5	Non-Weathered	G. trabeum	1.28
Paracide	0.0	Weathered	G. trabeum	47.17
Paracide	0.0	Weathered	G. trabeum	41.6
Paracide	0.0	Weathered	G. trabeum	41.25
Paracide	0.0	Weathered	G. trabeum	47.68
Paracide	.25	Weathered	G. trabeum	19.95
Paracide	.25	Weathered	G. trabeum	25.12
Paracide	.5	Weathered	G. trabeum	17.26
Paracide	.5	Weathered	G. trabeum	11.37
Paracide	.75	Weathered	G. trabeum	9.81
Paracide	.75	Weathered	G. trabeum	6.51
Paracide	1.0	Weathered	G. trabeum	4.09
Paracide	1.0	Weathered	G. trabeum	4.75
Paracide	1.0	Weathered	G. trabeum	15.8
Paracide	1.5	Weathered	G. trabeum	0.45
Paracide	1.5	Weathered	G. trabeum	0.94

TABLE II


	Fungicide	Weathered/	Fungus	Weight
Fungicide	Concentration	Non-Weathered	Species	Loss (%)

Paracide	0.0	Non-Weathered	T. versicolor	27.32
Paracide	0.0	Non-Weathered	T. versicolor	24.14
Paracide	0.0	Non-Weathered	T. versicolor	20.55
Paracide	0.0	Non-Weathered	T. versicolor	22.61
Paracide	0.25	Non-Weathered	T. versicolor	0.42
Paracide	0.25	Non-Weathered	T. versicolor	5.96
Paracide	0.5	Non-Weathered	T. versicolor	0.35
Paracide	0.5	Non-Weathered	T. versicolor	0.87
Paracide	0.75	Non-Weathered	T. versicolor	0.0
Paracide	0.75	Non-Weathered	T. versicolor	0.0
Paracide	1.0	Non-Weathered	T. versicolor	0.0
Paracide	1.0	Non-Weathered	T. versicolor	0.0
Paracide	1.5	Non-Weathered	T. versicolor	0.0
Paracide	1.5	Non-Weathered	T. versicolor	0.0

TABLE III


	Fungicide	Weathered/	Fungus	Weight
Fungicide	Concentration	Non-Weathered	Species	Loss (%)

Paracide	0.0	Weathered	T. versicolor	28.34
Paracide	0.0	Weathered	T. versicolor	21.51
Paracide	0.0	Weathered	T. versicolor	24.19
Paracide	0.0	Weathered	T. versicolor	17.99
Paracide	0.25	Weathered	T. versicolor	2.73
Paracide	0.25	Weathered	T. versicolor	2.86
Paracide	0.5	Weathered	T. versicolor	0.0
Paracide	0.5	Weathered	T. versicolor	1.21
Paracide	0.75	Weathered	T. versicolor	0.46
Paracide	0.75	Weathered	T. versicolor	0.88
Paracide	1.0	Weathered	T. versicolor	0.53
Paracide	1.0	Weathered	T. versicolor	0.94
Paracide	1.5	Weathered	T. versicolor	1.18
Paracide	1.5	Weathered	T. versicolor	0.53

As can be seen in tables I-III, the amount of wood lost to rot declined dramatically and in almost direct proportion to the concentration of the diiodomethyl-p-tolylsulfone included in the wood composite panel as described in the present invention. This indicates diiodomethyl-p-tolylsulfone provided excellent fungicide performance.
It will be appreciated by those skilled in the art that changes could be made to the embodiments described above without departing from the broad inventive concept thereof. It is understood, therefore, that this invention is not limited to the particular embodiments disclosed, but it is intended to cover modifications within the spirit and scope of the present invention as defined by the appended claims.

Claims

1. A method for the production of a wood composite board comprising the steps of:

providing a quantity of wood in the form of wood strands;

drying the wood strands;

coating the wood strands with a binder composition and diiodomethyl-p-tolylsulfone to from coated and treated strands;

forming a mat from the coated and treated strands;

pressing the mat, at a high temperature, to form the wood composite board having a final thickness.

2. The method according to claim 1, wherein the high temperature is from about 175° C. to about 260° C.

3. The method according to claim 1, wherein the mat is formed from alternating layers, with the coated strands in adjacent layers being oriented substantially perpendicular to each other.

4. The method according to claim 1, wherein the mat is formed from layers, wherein in each layer the strands are aligned in substantially the same direction.

5. The method according to claim 1, wherein the binder composition includes an isocyanate binder resin.

6. The method according to claim 1, wherein the wood board is in the form of OSB.

7. The panel according to claim 1, wherein the diiodomethyl-p-tolylsulfone is present in a concentration range of about 0.25 wt % to about 1.50 wt %.