US20070071667A1 - Thermal treatment of functionalized carbon nanotubes in solution to effect their functionalization - Google Patents
Thermal treatment of functionalized carbon nanotubes in solution to effect their functionalization Download PDFInfo
- Publication number
- US20070071667A1 US20070071667A1 US10/573,902 US57390204A US2007071667A1 US 20070071667 A1 US20070071667 A1 US 20070071667A1 US 57390204 A US57390204 A US 57390204A US 2007071667 A1 US2007071667 A1 US 2007071667A1
- Authority
- US
- United States
- Prior art keywords
- carbon nanotubes
- defunctionalized
- functionalized
- cnts
- defunctionalization
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y40/00—Manufacture or treatment of nanostructures
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B32/00—Carbon; Compounds thereof
- C01B32/15—Nano-sized carbon materials
- C01B32/158—Carbon nanotubes
- C01B32/168—After-treatment
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2202/00—Structure or properties of carbon nanotubes
- C01B2202/02—Single-walled nanotubes
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2202/00—Structure or properties of carbon nanotubes
- C01B2202/04—Nanotubes with a specific amount of walls
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2202/00—Structure or properties of carbon nanotubes
- C01B2202/06—Multi-walled nanotubes
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2202/00—Structure or properties of carbon nanotubes
- C01B2202/20—Nanotubes characterized by their properties
- C01B2202/22—Electronic properties
Definitions
- the present invention was made with support from the National Aeronautics and Space Administration, Grant Nos. JSC-NCC-9-77 and URETI NCC-01-0203; the National Science Foundation, Grant No. NSR-DMR-0073046; and the Air Force Office of Scientific Research, Grant No. F49620-01-1-0364.
- the present invention relates generally to carbon nanotube materials. More specifically, the invention relates to methods of defunctionalizing previously functionalized carbon nanotubes.
- Carbon nanotubes comprising multiple concentric shells and termed multi-wall carbon nanotubes (MWNTs), were discovered by Iijima in 1991 [Iijima, Nature 1991, 354, 56-58].
- single-wall carbon nanotubes comprising single graphene sheets rolled up on themselves to form cylindrical tubes with nanoscale diameters, were synthesized in an arc-discharge process using carbon electrodes doped with transition metals [Iijima et al., Nature 1993, 363, 603-605; and Bethune et al., Nature 1993, 363, 605-607].
- These carbon nanotubes possess unique mechanical, electrical, thermal and optical properties, and such properties make them attractive for a wide variety of applications. See Baughman et al., Science, 2002, 297, 787-792.
- Methods of making CNTs include the following techniques: arc discharge [Ebbesen, Annu. Rev. Mater. Sci. 1994, 24, 235-264]; laser oven [Thess et al., Science 1996, 273, 483-487]; flame synthesis [Vander Wal et al., Chem. Phys. Lett. 2001, 349, 178-184]; and chemical vapor deposition [U.S. Pat. No. 5,374,415], wherein a supported [Hafner et al., Chem. Phys. Left. 1998, 296, 195-202] or an unsupported [Cheng et al., Chem. Phys. Lett. 1998, 289, 602-610; Nikolaev et al., Chem. Phys. Lett. 1999, 313, 91-97] metal catalyst may also be used.
- CNTs chemically functionalizing CNTs
- tube end functionalization see, e.g., Liu et al., Science, 1998, 280, 1253-1256; Chen et al., Science, 1998, 282, 95-98
- sidewall functionalization see, e.g., PCT publication WO 02/060812 by Tour et al.; Khabashesku et al., Acc. Chem.
- Carbon nanotube chemistry has been described using a pyramidization angle formalism [Niyogi et al., Acc. of Chem. Res., 2002, 35, 1105-1113].
- chemical reactivity and kinetic selectivity are related to the extent of s character due to the curvature-induced strain of the sp 2 -hybridized graphene sheet.
- strain energy per carbon is inversely related to nanotube diameter, this model predicts smaller diameter nanotubes to be the most reactive, with the enthalpy of reaction decreasing as the curvature becomes infinite.
- the diameter and chirality of individual CNTs are described by integers “n” and “m,” where (n,m) is a vector along a graphene sheet which is conceptually rolled up to form a tube.
- 3q, where q is an integer, the CNT is a semi-metal (bandgaps on the order of milli eV).
- Regeneration of the pristine-like nanotube structure becomes of paramount importance if covalent functionalization is used as a handle for separation or for controlled manipulation of material, particularly when the original extended ⁇ -electron-derived optical or electronic properties are required for the ultimate desired function. It has been shown that functionalized material treated thermally, in the dry state, in an inert atmosphere, defunctionalizes to regenerate the pristine-like SWNT structure [Dyke et al., J. Am. Chem. Soc. 2003, 125, 1156-1157; Dyke et al., Nano Lett. 2003, 3, 1215-1218; Bahr et al., J. Am. Chem. Soc.
- nanotubes have a reported van der Waals attraction of 0.5 eV per nanometer of tube-tube contact [O'Connell et al., Chem. Phys. Lett. 2001, 342, 265-271; and Thess et al., Science 1996, 273, 483-487].
- the present invention is directed towards methods of thermally defunctionalizing functionalized (derivatized) carbon nanotubes (CNTs) in solution or while suspended in a liquid medium.
- Such defunctionalization largely comprises the removal of sidewall functionality from the CNTs, but can also serve to remove functionality from the CNT ends.
- Such methods allow for the resuspension of such defunctionalized CNTs in various solvents and permit the defunctionalization of functionalized CNTs that would normally decompose (or partially decompose) upon thermal treatment.
- Such methods of defunctionalization can typically lead to defunctionalized CNTs that are essentially pristine (or nearly pristine), and which, in contrast to prior art methods of thermal defunctionalization, can be easily resuspended in a variety of solvents.
- the methods of the present invention generally comprise the steps of: (a) suspending/dissolving a quantity of functionalized CNTs in a solvent to form a suspension/solution of functionalized CNTs; and (b) heating said suspension/solution to a temperature that will thermally defunctionalize the functionalized CNTs yielding a defunctionalized product. Temperatures exceeding the atmospheric pressure boiling point of the solvent are easily achieved by sealing the mixture in a closed pressure vessel.
- the methods of the present invention are flexible in that they work with a variety of different kinds of functionalized CNTs, and they can employ a variety of different solvents.
- the functionalized CNTs have been partially and/or selectively functionalized (e.g., by electronic type).
- the solvent selection is directed by the kinds of functionalized CNTs being defunctionalized.
- the defunctionalization is used to render a partially defunctionalized product.
- the defunctionalization can be homogeneous.
- Such partial defunctionalization can lead to functionalized CNTs with stoichiometries that might otherwise be unattainable with direct functionalization methods.
- one or more analytical techniques are used to evaluate the defunctionalized product. Such techniques can be used to determine the extent of defunctionalization and the extent to which the defunctionalized CNTs have been returned to their pristine (original) state.
- SWNTs single-wall carbon nanotubes
- FIG. 1 illustrates two reaction schemes by which SWNTs can be functionalized by diazonium species, where in reaction 1 the diazonium species is generated in situ under solvent free conditions, and where in reaction 2 the diazonium species is added directly to a surfactant-aided suspension of SWNTs;
- FIG. 2 depicts a thermogravimetric analysis (TGA) plot of the thermal defunctionalization of heavily functionalized (4-chlorophenyl) SWNTs in the dry state;
- FIGS. 3 A-E depict Raman spectra (taken with 633 nm excitation) of (A) pristine (unreacted) SWNTs, (B) heavily functionalized SWNTs containing 4-chlorophenyl addends by treatment of micelle-coated SWNTs with 4-chlorobenzenediazonium tetrafluoroborate and corresponding to the material used for the TGA in FIG. 2 , (C) the same material as in 3 B, but after neat thermal treatment at 10° C./min to 650° C. in Ar, (D) the same material as in 3 B, but after neat thermal treatment at 10° C./min to 450° C. and holding at 450° C. for 2 hours, and (E) the same material as in 3 B, but after thermal defunctionalization in ortho-dichlorobenzene (ODCB) at 450° C. for 3 hours; and
- FIG. 4 illustrates the thermolysis of 4-tert-butylphenyl-functionalized SWNTs (prepared by the SDS-coated SWNT/H 2 O protocol) in ODCB (solvent) that affords defunctionalized SWNTs and two discernable volatile products, the biphenyls 1 and 2, as determined by a GC-MS analysis of the reaction mixture.
- ODCB solvent
- the present invention is directed towards methods of thermally defunctionalizing functionalized (derivatized) carbon nanotubes (CNTs) in solution or suspended in a liquid medium.
- Such defunctionalization is largely directed to the removal of sidewall functionality from the CNTs, but can also serve to remove functionality from the CNT ends.
- Such methods allow for the resuspension of such defunctionalized CNTs in various solvents and permit the defunctionalization of functionalized CNTs that would normally decompose (or partially decompose) upon thermal treatment.
- Such methods of defunctionalization can typically lead to defunctionalized CNTs that are essentially pristine (or nearly pristine), and which, in contrast to prior art methods of thermal defunctionalization, can be easily resuspended in a variety of solvents. Additionally, such solvent-based defunctionalization can partially defunctionalize functionalized CNTs in a generally homogeneous manner.
- the methods of the present invention generally comprise the steps of: (a) dissolving or suspending a quantity of functionalized CNTs in a solvent to form a solution/suspension of functionalized CNTs; and (b) heating said solution/suspension to a temperature that will thermally defunctionalize the functionalized CNTs to yield a defunctionalized product.
- CNTs include, but are not limited to, single-wall carbon nanotubes (SWNTs), multi-wall carbon nanotubes (MWNTs), double-wall carbon nanotubes (DWNTs), buckytubes, fullerene tubes, tubular fullerenes, graphite fibrils, and combinations thereof.
- SWNTs single-wall carbon nanotubes
- MWNTs multi-wall carbon nanotubes
- DWNTs double-wall carbon nanotubes
- buckytubes fullerene tubes, tubular fullerenes, graphite fibrils, and combinations thereof.
- Such CNTs can initially be of a variety and range of lengths, diameters, number of tube walls, chiralities (helicities), etc., and can generally be made by any known technique.
- the terms “carbon nanotube” and “nanotube” will be used interchangeably herein.
- Such CNTs are often subjected to one or more purification steps [see, e.g., Chiang et al.,
- Functionalized CNTs can be chemically functionalized derivatives of any of the above-mentioned kinds or types of CNTs.
- Chemically functionalized is the chemical attachment (typically via covalent bonding) of functional moieties to the sidewalls and/or ends of CNTs.
- suitably functionalized CNTs include, but are not limited to, those described in the following references: Liu et al., Science, 1998, 280, 1253-1256; Chen et al., Science, 1998, 282, 95-98; Holzinger et al., Angew. Chem. Int. Ed., 2001, 40, 4002-4005; Khabashesku et al., Acc. Chem.
- solvents employed in the methods of the present invention are thermally stable at the temperatures required for defunctionalization of the functionalized CNTs.
- the solvent selection is directed by the kinds of functionalized CNTs being defunctionalized.
- Suitable solvents include, but are not limited to, o-dichlorobenzene (ODCB), benzene, toluene, water, sulfuric acid, oleum (sulfuric acid with dissolved sulfur trioxide), sulfuric acid with dissolved potassium persulfate or other radical initiator such as peroxide, liquid ammonia, liquid ammonia with dissolved alkali metals, alkanes, parafins, thiophene, and combinations thereof.
- ODCB o-dichlorobenzene
- benzene toluene
- water sulfuric acid
- oleum sulfuric acid with dissolved sulfur trioxide
- sulfuric acid with dissolved potassium persulfate or other radical initiator such as peroxide, liquid ammonia,
- the functionalized CNTs are further polymer-wrapped and/or surfactant suspended in the solvent or liquid medium prior to being defunctionalized.
- such polymer wrapping and/or surfactants can serve to keep the CNTs in suspension after they have been completely or partially defunctionalized. See O'Connell et al., Chem. Phys. Lett., 2001, 342, 265-271; and O'Connell et al., Science, 2002, 297, 593-596 for exemplary methods of polymer wrapping and surfactant suspending CNTs, respectively.
- the solvent includes a polymer such that the defunctionalization is carried out while in a polymer matrix and thereby provides a blended polymer/pristine nanotube sample after defunctionalization and upon removal of the solvent.
- the functionalized CNTs are dispersed directly in a polymer matrix, then defunctionalized to yield a product blend comprising unfunctionalized CNTs in a polymer host. Such product blends benefit from the greater dispersability of the functionalized CNTs (relative to unfunctionalized CNTs) in the polymer host.
- temperatures required for thermal defunctionalization vary depending on the type(s) of functionalized CNTs being defunctionalized. Typically, such defunctionalization temperatures range from about 100° C. to about 700° C., and more typically from about 250° C. to about 400° C. In some embodiments, a ramped or variable heating process is used.
- Heating a solution or suspension of functionalized CNTs to a temperature required for complete or partial thermal defunctionalization can be accomplished via a variety of heating methods. Suitable heating methods include, but are not limited to, heating mantles, immersion heaters, microwave heating, and combinations thereof.
- the heating is carried out with stirring, or some other kind of agitation, to ensure homogeneous thermolysis by minimizing thermal gradients within the suspension.
- the thermal defunctionalization process entails a defunctionalization duration, lasting between about 3 minutes and about 2 days, and more typically between about 30 minutes and about 3 hours, during which time the functionalized CNTs are heated.
- the functionalized CNTs are only partially defunctionalized. This permits product stoichiometries of such partially defunctionalized CNTs that might otherwise not be achievable.
- partial defunctionalization is a result of selective thermal defunctionalization according to (n,m) type, with differing types having differing propensities to defunctionalize.
- the CNTs upon being fully or partially defunctionalized, flocculate or fall out of suspension/solution.
- the defunctionalization is carried out in a sealed reaction vessel.
- these sealed reaction vessels permit the use of temperatures that exceed the atmospheric pressure boiling point of the solvent.
- some of the defunctionalization products are volatile.
- the defunctionalization products react with the suspension/solution medium.
- one or more analytical techniques are used to evaluate the defunctionalized product and/or byproducts. Such techniques can be used to determine the extent of defunctionalization and the extent to which the defunctionalized carbon nanotubes have been returned to their pristine (original) state.
- the liquid defunctionalization medium can be analyzed with gas chromatography-mass spectrometry (GC-MS) or other suitable analytical techniques.
- GC-MS gas chromatography-mass spectrometry
- the defunctionalized product is only partially defunctionalized, whereas in other embodiments it is completely defunctionalized.
- the completely defunctionalized CNTs are essentially in their pristine (or nearly pristine) state.
- An important aspect of the methods described herein is that the defunctionalized CNTs of the present invention (i.e., solvent defunctionalized CNTs) can be redispersed much more easily than CNTs that have been thermally defunctionalized in the dry state.
- the wholly or partially defunctionalized CNTs of the present invention are redispersed in solvents with the aid of surfactants and/or polymers.
- such wholly or partially defunctionalized CNTs can be manipulated in essentially any manner in which pristine CNTs can be manipulated.
- carbon nanotubes (CNTs) chemically modified by bonding (e.g., covalently) functional groups to their sidewalls and/or ends can be thermally defunctionalized in solution, returning the previously functionalized CNTs to their original state.
- bonding e.g., covalently
- the present invention does not render the defunctionalized carbon nanotubes unsuspendable/insoluble from that point on.
- solvent-based defunctionalization methods of the present invention mitigate both the packing of the CNTs into ordered bundles and, possibly, cross-linking which is thought to occur between such funcetionalized CNTs when they are heated in the dry state.
- This Example serves to illustrate how CNTs can be functionalized with diazonium chemistry in accordance with some embodiments of the present invention.
- diazonium species can be generated in situ (reaction 1 ), or added directly (reaction 2 ), to SWNTs to render them functionalized.
- Reaction 1 is carried out without any solvent [see Dyke et al., J. Am. Chem. Soc., 2003, 125, 1156-1157], and in reaction 2 , the SWNTs are first dispersed in water with sodium dodecylsulfate (SDS) [see Dyke et al., Nano Lett. 2003, 3, 1215-1218].
- SDS sodium dodecylsulfate
- SWNTs were functionalized with 4-clorophenylene addends in accordance with reaction 2 in FIG. 1 .
- This Example serves to illustrate how functionalized CNTs can be thermally defunctionalized in solution/suspension in accordance with embodiments of the present invention.
- SWNTs purified HiPco, obtained from Rice University's Carbon Nanotechnology Laboratory
- ODCB ortho-dichlorobenzene
- the reaction vessel was purged with nitrogen and sealed with a TEFLON cap.
- the solution was heated in a sand bath placed inside a heating mantle at approximately 450° C. with stirring for about 3 hours. After such time, the solution was cooled to room temperature.
- the regenerated, defunctionalized SWNTs were then filtered through a TEFLON membrane and collected. Defunctionalization was confirmed by absorption and Raman spectroscopies. Subsequent to their defunctionalization, these solvent-defunctionalized SWNTs can be resuspended in any of a number of different solvents (unlike those defunctionalized in the dry state).
- This Example serves to illustrate prior art methods of thermally defunctionalizing functionalized CNTs in the dry state.
- thermogravimetric analysis (TGA) of heavily functionalized (4-chlorophenyl) nanotubes showed 49% weight loss, which corresponds to 1 in 9 carbons on the nanotube bearing an aryl moiety.
- the addends appear to be removed in two separate thermal regions, one at 200-400° C. and a second at 475-550° C. While not intending to be bound by theory, this might be indicative of compressed bands of functionalization vs. dispersed addend regions, or of the defunctionalization temperatures needed for addend expulsion on semiconducting vs. metallic tubes.
- This Example serves to illustrate how Raman spectroscopy can be used to probe the defunctionalization of functionalized CNTs in both the solvent-based and dry state methods.
- This Examples serves to illustrate how byproducts from some of the solvent-based defunctionalization method of the present invention can be analyzed.
- the thermal treatment of functionalized CNT material while dispersed in a solvent such as ODCB possibly prevents nanotube radicals from combining to form nanotube dimers; instead, two radicals on the same nanotube might combine by extended conjugation to regenerate the C—C double-bond. Conversely, extensive rebundling might be minimized under such solvent-based conditions.
- solvent-based thermal defunctionalization the byproducts of a ODCB-thermalized reaction of 4-tert-butylphenyl functionalized SWNTs were examined by GC-MS analysis of the ODCB solution. Referring to FIG.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Nanotechnology (AREA)
- Materials Engineering (AREA)
- Physics & Mathematics (AREA)
- Organic Chemistry (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- General Physics & Mathematics (AREA)
- Crystallography & Structural Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Composite Materials (AREA)
- Carbon And Carbon Compounds (AREA)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US10/573,902 US20070071667A1 (en) | 2003-10-31 | 2004-10-28 | Thermal treatment of functionalized carbon nanotubes in solution to effect their functionalization |
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US51639203P | 2003-10-31 | 2003-10-31 | |
PCT/US2004/035894 WO2005049488A2 (fr) | 2003-10-31 | 2004-10-28 | Traitement thermique de nanotubes de carbone fonctionnalises en solution pour effectuer leur defonctionnalisation |
US10/573,902 US20070071667A1 (en) | 2003-10-31 | 2004-10-28 | Thermal treatment of functionalized carbon nanotubes in solution to effect their functionalization |
Publications (1)
Publication Number | Publication Date |
---|---|
US20070071667A1 true US20070071667A1 (en) | 2007-03-29 |
Family
ID=34619319
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US10/573,902 Abandoned US20070071667A1 (en) | 2003-10-31 | 2004-10-28 | Thermal treatment of functionalized carbon nanotubes in solution to effect their functionalization |
Country Status (2)
Country | Link |
---|---|
US (1) | US20070071667A1 (fr) |
WO (1) | WO2005049488A2 (fr) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2932794A1 (fr) * | 2008-06-18 | 2009-12-25 | Commissariat Energie Atomique | Procede de preparation d'une suspension de nanotubes de carbone, suspension ainsi obtenue et kit pour la mise en oeuvre d'un tel procede |
US8986576B1 (en) * | 2010-11-08 | 2015-03-24 | Sandia Corporation | Carbon nanotube composite materials |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1852863A (zh) * | 2003-07-29 | 2006-10-25 | 威廉马歇莱思大学 | 碳纳米管的选择性官能化 |
KR102447011B1 (ko) | 2021-03-15 | 2022-09-23 | 주식회사 비츠로셀 | 캡슐화된 활물질을 갖는 리튬 이차전지용 전극 및 그 제조 방법 |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6645455B2 (en) * | 1998-09-18 | 2003-11-11 | William Marsh Rice University | Chemical derivatization of single-wall carbon nanotubes to facilitate solvation thereof; and use of derivatized nanotubes to form catalyst-containing seed materials for use in making carbon fibers |
US20040038251A1 (en) * | 2002-03-04 | 2004-02-26 | Smalley Richard E. | Single-wall carbon nanotubes of precisely defined type and use thereof |
US7407640B2 (en) * | 2002-11-27 | 2008-08-05 | William Marsh Rice University | Functionalized carbon nanotube-polymer composites and interactions with radiation |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2413123B (en) * | 2001-01-29 | 2005-12-07 | Univ Rice William M | Process for derivatizing carbon nanotubes with diazonium species and compositions thereof |
-
2004
- 2004-10-28 WO PCT/US2004/035894 patent/WO2005049488A2/fr active Application Filing
- 2004-10-28 US US10/573,902 patent/US20070071667A1/en not_active Abandoned
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6645455B2 (en) * | 1998-09-18 | 2003-11-11 | William Marsh Rice University | Chemical derivatization of single-wall carbon nanotubes to facilitate solvation thereof; and use of derivatized nanotubes to form catalyst-containing seed materials for use in making carbon fibers |
US20040038251A1 (en) * | 2002-03-04 | 2004-02-26 | Smalley Richard E. | Single-wall carbon nanotubes of precisely defined type and use thereof |
US20040040834A1 (en) * | 2002-03-04 | 2004-03-04 | Smalley Richard E. | Method for separating single-wall carbon nanotubes and compositions thereof |
US7407640B2 (en) * | 2002-11-27 | 2008-08-05 | William Marsh Rice University | Functionalized carbon nanotube-polymer composites and interactions with radiation |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2932794A1 (fr) * | 2008-06-18 | 2009-12-25 | Commissariat Energie Atomique | Procede de preparation d'une suspension de nanotubes de carbone, suspension ainsi obtenue et kit pour la mise en oeuvre d'un tel procede |
US8986576B1 (en) * | 2010-11-08 | 2015-03-24 | Sandia Corporation | Carbon nanotube composite materials |
Also Published As
Publication number | Publication date |
---|---|
WO2005049488A3 (fr) | 2005-07-28 |
WO2005049488A2 (fr) | 2005-06-02 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
Tasis et al. | Soluble carbon nanotubes | |
US7459137B2 (en) | Process for functionalizing carbon nanotubes under solvent-free conditions | |
Shen et al. | Double-walled carbon nanotubes: challenges and opportunities | |
US7632481B2 (en) | Sidewall functionalization of nanotubes with hydroxyl terminated moieties | |
Jeon et al. | Functionalization of carbon nanotubes | |
Grossiord et al. | Strategies for dispersing carbon nanotubes in highly viscous polymers | |
Mathur et al. | Co-synthesis, purification and characterization of single-and multi-walled carbon nanotubes using the electric arc method | |
US7939047B2 (en) | Bulk separation of carbon nanotubes by bandgap | |
Tran et al. | Thermal oxidative cutting of multi-walled carbon nanotubes | |
Kim et al. | Double-walled carbon nanotubes: synthesis, structural characterization, and application | |
Chen et al. | A brief introduction of carbon nanotubes: history, synthesis, and properties | |
Fujisawa et al. | Chirality-dependent transport in double-walled carbon nanotube assemblies: The role of inner tubes | |
Lee et al. | Short carbon nanotubes produced by cryogenic crushing | |
Komarov et al. | Carbon nanotubes: present and future | |
Makama et al. | Recent developments in purification of single wall carbon nanotubes | |
US8562935B2 (en) | Amplification of carbon nanotubes via seeded-growth methods | |
Doyle et al. | Environmentally friendly functionalization of single walled carbon nanotubes in molten urea | |
US8980216B2 (en) | Covalently functionalized carbon nanostructures and methods for their separation | |
US20070071667A1 (en) | Thermal treatment of functionalized carbon nanotubes in solution to effect their functionalization | |
US7906558B2 (en) | Reversible biogel for manipulation and separation of single-walled carbon nanotubes | |
US7470417B2 (en) | Ozonation of carbon nanotubes in fluorocarbons | |
Okamoto et al. | Synthesis and characterization of multi-and single-wall carbon nanotubes by the catalytic vapor deposition method | |
Vigolo et al. | Processing carbon nanotubes | |
Deng et al. | Outerwall selective alkylcarboxylation and enrichment of double-walled carbon nanotubes | |
Long et al. | Ultra-fast and scalable sidewall functionalisation of single-walled carbon nanotubes with carboxylic acid |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
AS | Assignment |
Owner name: NASA, DISTRICT OF COLUMBIA Free format text: CONFIRMATORY LICENSE;ASSIGNOR:RICE UNIVERSITY;REEL/FRAME:018569/0980 Effective date: 20061013 |
|
STCB | Information on status: application discontinuation |
Free format text: ABANDONED -- FAILURE TO RESPOND TO AN OFFICE ACTION |
|
AS | Assignment |
Owner name: NATIONAL SCIENCE FOUNDATION, VIRGINIA Free format text: CONFIRMATORY LICENSE;ASSIGNOR:RICE UNIVERSITY;REEL/FRAME:026747/0494 Effective date: 20110713 |
|
AS | Assignment |
Owner name: NATIONAL SCIENCE FOUNDATION, VIRGINIA Free format text: CONFIRMATORY LICENSE;ASSIGNOR:RICE UNIVERSITY;REEL/FRAME:045284/0422 Effective date: 20180320 |