US20070034050A1 - Process for the use of metal carbonyls for the production of nano-scale metal particles formed of non-noble metals - Google Patents
Process for the use of metal carbonyls for the production of nano-scale metal particles formed of non-noble metals Download PDFInfo
- Publication number
- US20070034050A1 US20070034050A1 US11/201,354 US20135405A US2007034050A1 US 20070034050 A1 US20070034050 A1 US 20070034050A1 US 20135405 A US20135405 A US 20135405A US 2007034050 A1 US2007034050 A1 US 2007034050A1
- Authority
- US
- United States
- Prior art keywords
- reactor vessel
- nano
- metal
- scale
- carbonyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 title claims abstract description 126
- 239000002184 metal Substances 0.000 title claims abstract description 100
- 229910052751 metal Inorganic materials 0.000 title claims abstract description 99
- 239000002923 metal particle Substances 0.000 title claims abstract description 62
- 238000000034 method Methods 0.000 title claims abstract description 48
- 230000008569 process Effects 0.000 title claims abstract description 42
- 229910000510 noble metal Inorganic materials 0.000 title claims description 22
- 238000004519 manufacturing process Methods 0.000 title description 19
- 238000000151 deposition Methods 0.000 claims abstract description 12
- 238000000354 decomposition reaction Methods 0.000 claims description 46
- 239000002105 nanoparticle Substances 0.000 claims description 44
- 239000000463 material Substances 0.000 claims description 34
- 230000003197 catalytic effect Effects 0.000 claims description 16
- 239000000758 substrate Substances 0.000 claims description 8
- 238000001816 cooling Methods 0.000 claims description 7
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 4
- 239000001301 oxygen Substances 0.000 claims description 4
- 229910052760 oxygen Inorganic materials 0.000 claims description 4
- 230000003647 oxidation Effects 0.000 claims description 3
- 238000007254 oxidation reaction Methods 0.000 claims description 3
- 239000002245 particle Substances 0.000 description 36
- 239000003054 catalyst Substances 0.000 description 35
- 238000006555 catalytic reaction Methods 0.000 description 15
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 14
- 239000011261 inert gas Substances 0.000 description 13
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 12
- 229910002091 carbon monoxide Inorganic materials 0.000 description 12
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 11
- 150000002739 metals Chemical class 0.000 description 11
- 238000006243 chemical reaction Methods 0.000 description 10
- 230000015572 biosynthetic process Effects 0.000 description 9
- 239000000376 reactant Substances 0.000 description 9
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 8
- 229910052759 nickel Inorganic materials 0.000 description 8
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 8
- -1 platinum group metals Chemical class 0.000 description 8
- 230000008021 deposition Effects 0.000 description 7
- 239000000446 fuel Substances 0.000 description 7
- 239000007789 gas Substances 0.000 description 6
- 239000007858 starting material Substances 0.000 description 6
- 230000008901 benefit Effects 0.000 description 5
- 229910052742 iron Inorganic materials 0.000 description 5
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 5
- 238000003786 synthesis reaction Methods 0.000 description 5
- 229910052786 argon Inorganic materials 0.000 description 4
- 239000006229 carbon black Substances 0.000 description 4
- 235000019241 carbon black Nutrition 0.000 description 4
- 229910052697 platinum Inorganic materials 0.000 description 4
- 239000000956 alloy Substances 0.000 description 3
- 229910045601 alloy Inorganic materials 0.000 description 3
- 230000003466 anti-cipated effect Effects 0.000 description 3
- 125000004429 atom Chemical group 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 239000002826 coolant Substances 0.000 description 3
- 239000011521 glass Substances 0.000 description 3
- 238000011068 loading method Methods 0.000 description 3
- 239000012528 membrane Substances 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 241000894007 species Species 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- RZVAJINKPMORJF-UHFFFAOYSA-N Acetaminophen Chemical compound CC(=O)NC1=CC=C(O)C=C1 RZVAJINKPMORJF-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
- 230000015556 catabolic process Effects 0.000 description 2
- 239000003638 chemical reducing agent Substances 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 238000009833 condensation Methods 0.000 description 2
- 230000005494 condensation Effects 0.000 description 2
- QFEOTYVTTQCYAZ-UHFFFAOYSA-N dimanganese decacarbonyl Chemical compound [Mn].[Mn].[O+]#[C-].[O+]#[C-].[O+]#[C-].[O+]#[C-].[O+]#[C-].[O+]#[C-].[O+]#[C-].[O+]#[C-].[O+]#[C-].[O+]#[C-] QFEOTYVTTQCYAZ-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005868 electrolysis reaction Methods 0.000 description 2
- 229910002804 graphite Inorganic materials 0.000 description 2
- 239000010439 graphite Substances 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 230000006698 induction Effects 0.000 description 2
- 229910052741 iridium Inorganic materials 0.000 description 2
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 239000005297 pyrex Substances 0.000 description 2
- 239000010453 quartz Substances 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 238000004544 sputter deposition Methods 0.000 description 2
- 229910052723 transition metal Inorganic materials 0.000 description 2
- 150000003624 transition metals Chemical class 0.000 description 2
- 239000012780 transparent material Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- XMWRBQBLMFGWIX-UHFFFAOYSA-N C60 fullerene Chemical class C12=C3C(C4=C56)=C7C8=C5C5=C9C%10=C6C6=C4C1=C1C4=C6C6=C%10C%10=C9C9=C%11C5=C8C5=C8C7=C3C3=C7C2=C1C1=C2C4=C6C4=C%10C6=C9C9=C%11C5=C5C8=C3C3=C7C1=C1C2=C4C6=C2C9=C5C3=C12 XMWRBQBLMFGWIX-UHFFFAOYSA-N 0.000 description 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- 229910017147 Fe(CO)5 Inorganic materials 0.000 description 1
- 229910016660 Mn2(CO)10 Inorganic materials 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- 238000003915 air pollution Methods 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 229910052792 caesium Inorganic materials 0.000 description 1
- TVFDJXOCXUVLDH-UHFFFAOYSA-N caesium atom Chemical compound [Cs] TVFDJXOCXUVLDH-UHFFFAOYSA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 230000006315 carbonylation Effects 0.000 description 1
- 238000005810 carbonylation reaction Methods 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 239000012159 carrier gas Substances 0.000 description 1
- 239000012876 carrier material Substances 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 150000004770 chalcogenides Chemical class 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000003889 chemical engineering Methods 0.000 description 1
- 238000012993 chemical processing Methods 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 238000011437 continuous method Methods 0.000 description 1
- 230000001351 cycling effect Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- JCXLZXJCZPKTBW-UHFFFAOYSA-N diiron nonacarbonyl Chemical group [Fe].[Fe].[O+]#[C-].[O+]#[C-].[O+]#[C-].[O+]#[C-].[O+]#[C-].[O+]#[C-].[O+]#[C-].[O+]#[C-].[O+]#[C-] JCXLZXJCZPKTBW-UHFFFAOYSA-N 0.000 description 1
- 229910001882 dioxygen Inorganic materials 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000002360 explosive Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 229910003472 fullerene Inorganic materials 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000007210 heterogeneous catalysis Methods 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 230000003116 impacting effect Effects 0.000 description 1
- 238000012994 industrial processing Methods 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- 229940087654 iron carbonyl Drugs 0.000 description 1
- UGKDIUIOSMUOAW-UHFFFAOYSA-N iron nickel Chemical compound [Fe].[Ni] UGKDIUIOSMUOAW-UHFFFAOYSA-N 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 150000001247 metal acetylides Chemical class 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical group 0.000 description 1
- 238000005649 metathesis reaction Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 239000002071 nanotube Substances 0.000 description 1
- 150000004767 nitrides Chemical class 0.000 description 1
- 150000002902 organometallic compounds Chemical class 0.000 description 1
- 229910052762 osmium Inorganic materials 0.000 description 1
- SYQBFIAQOQZEGI-UHFFFAOYSA-N osmium atom Chemical compound [Os] SYQBFIAQOQZEGI-UHFFFAOYSA-N 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000010970 precious metal Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
- 229910052761 rare earth metal Inorganic materials 0.000 description 1
- 150000002910 rare earth metals Chemical class 0.000 description 1
- 239000003507 refrigerant Substances 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000012260 resinous material Substances 0.000 description 1
- 229910052702 rhenium Inorganic materials 0.000 description 1
- WUAPFZMCVAUBPE-UHFFFAOYSA-N rhenium atom Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 description 1
- 229910052703 rhodium Inorganic materials 0.000 description 1
- 239000010948 rhodium Substances 0.000 description 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 1
- 229910052707 ruthenium Inorganic materials 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 230000005476 size effect Effects 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- 238000003911 water pollution Methods 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F9/00—Making metallic powder or suspensions thereof
- B22F9/16—Making metallic powder or suspensions thereof using chemical processes
- B22F9/30—Making metallic powder or suspensions thereof using chemical processes with decomposition of metal compounds, e.g. by pyrolysis
- B22F9/305—Making metallic powder or suspensions thereof using chemical processes with decomposition of metal compounds, e.g. by pyrolysis of metal carbonyls
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/20—Catalysts, in general, characterised by their form or physical properties characterised by their non-solid state
- B01J35/23—Catalysts, in general, characterised by their form or physical properties characterised by their non-solid state in a colloidal state
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
- B01J35/45—Nanoparticles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/08—Heat treatment
- B01J37/082—Decomposition and pyrolysis
- B01J37/086—Decomposition of an organometallic compound, a metal complex or a metal salt of a carboxylic acid
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F2998/00—Supplementary information concerning processes or compositions relating to powder metallurgy
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/90—Selection of catalytic material
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
Definitions
- the present invention relates to a process for the production of non-noble metal nano-scale particles using metal carbonyls.
- non-noble metal is meant a metal other than one of the noble metals (generally considered to be gold, silver, platinum, palladium, iridium, rhenium, mercury, ruthenium and osmium).
- the resulting nano-scale particles are useful for catalysis and other purposes.
- nano-scale particles can be produced from metal carbonyls and collected with greater speed, precision and flexibility than can be accomplished with conventional processing.
- the invention provides a practical and cost-effective means for preparing such nano-scale particles.
- Catalysts are becoming ubiquitous in modern chemical processing. Catalysts are used in the production of materials such as fuels, lubricants, refrigerants, polymers, drugs, etc., as well as playing a role in water and air pollution mediation processes. Indeed, catalysts have been ascribed as having a role in fully one third of the material gross national product of the United States, as discussed by Alexis T. Bell in “The Impact of Nanoscience on Heterogeneous Catalysis” (Science, Vol. 299, pg. 1688, 14 Mar. 2003).
- catalysts can be described as small particles deposited on high surface area solids. Traditionally, catalyst particles can range from the sub-micron up to tens of microns.
- One example described by Bell is the catalytic converter of automobiles, which consist of a honeycomb whose walls are coated with a thin coating of porous aluminum oxide (alumina).
- an aluminum oxide wash coat is impregnated with nanoparticles of a platinum group metal catalyst material.
- platinum group metals especially platinum, rhodium and iridium or alkaline metals like cesium, at times in combination with other metals such as iron or nickel.
- catalysts are prepared in two ways.
- One such process involves catalyst materials being deposited on the surface of carrier particles such as carbon blacks or other like materials, with the catalyst-loaded particles then themselves being loaded on the surface at which catalysis is desired.
- carrier particles such as carbon blacks or other like materials
- the catalyst-loaded particles then themselves being loaded on the surface at which catalysis is desired.
- This is in the fuel cell arena, where carbon black or other like particles loaded with platinum group metal catalysts are then themselves loaded at the membrane/electrode interface to catalyze the breakdown of molecular hydrogen into monatomic hydrogen, for its separation into its component protons and electrons, with the resulting electrons passed through a circuit as the current generated by the fuel cell; on the opposing surface, molecular oxygen is separated into monatomic oxygen for eventual combination with the proton and electron to form water.
- One major drawback to the preparation of catalyst materials through loading on a carrier particle is in the amount of time the loading reactions take, which can be measured in hours in some cases.
- Yadav and Pfaffenbach describe the dispersing of nano-scale powders on coarser carrier powders in order to provide catalyst materials.
- the carrier particles of Yadav and Pfaffenbach include oxides, carbides, nitrides, borides, chalcogenides, metals and alloys.
- the nanoparticles dispersed on the carriers can be any of many different materials according to Yadav and Pfaffenbach, including precious metals such as platinum group metals, rare earth metals, the so-called semi-metals, as well as non-metallic materials, and even clusters such as fullerenes, alloys and nanotubes.
- the second common methods for preparing catalyst materials involves directly loading catalyst metals such as platinum group metals on a support without the use of carrier particles which can interfere with the catalytic reaction.
- catalyst metals such as platinum group metals
- many automotive catalytic converters as discussed above, have catalyst particles directly loaded on the aluminum oxide honeycomb which forms the converter structure.
- the processes needed for direct deposition of catalytic metals on support structures are generally operated at extremes of temperature and/or pressures. For instance, one such process is chemical sputtering at temperatures in excess of 1,500° C. and under conditions of high vacuum. Thus, these processes are difficult and expensive to operate and also involve line-of-sight reactions, precluding fully utilization of the support structure.
- Bert and Bianchini in International Patent Application Publication No. WO 2004/036674, suggest a process using a templating resin to produce nano-scale particles for fuel cell applications. Even if technically feasible, however, the Bert and Bianchini methods require high temperatures (on the order of 300° C. to 800° C.), and require several hours. Accordingly, these processes are of limited value.
- Metal carbonyls have also been used as, for instance, anti-knock compounds in unleaded gasolines. However, more significant uses of metal carbonyls are in the production and/or deposition of the metals present in the carbonyl, since metal carbonyls are generally viewed as easily decomposed and volatile resulting in deposition of the metal and carbon monoxide.
- carbonyls are transition metals combined with carbon monoxide and have the general formula M x (CO) y , where M is a metal in the zero oxidation state and where x and y are both integers. While many consider metal carbonyls to be coordination compounds, the nature of the metal to carbon bond leads some to classify them as organometallic compounds. In any event, the metal carbonyls have been used to prepare high purity metals, although not for the production of nano-scale metal particles. As noted, metal carbonyls have also been found useful for their catalytic properties such as for the synthesis of organic chemicals in gasoline antiknock formulations.
- catalyst materials are traditionally formed of noble metals, such as the platinum group metals, the formation of nano-scale particles, with the resulting surface area and surface effect advantages, may permit the use of non-noble metals, such as nickel, iron, etc., as catalyst materials.
- non-noble metals such as nickel, iron, etc.
- non-noble metal nano-scale particles for use as, e.g., catalyst materials.
- the desired process can be used for the preparation of nano-scale particles loaded on a carrier particle but, significantly, can also be used for the deposit of catalytic non-noble metal nano-scale particles directly on a surface without the requirement for extremes in temperature and/or pressures.
- nano-scale particles particles having an average diameter of no greater than about 1,000 nanometers (nm), e.g., no greater than about one micron. More preferably, the particles produced by the inventive system have an average diameter no greater than about 250 nm, most preferably no greater than about 20 nm.
- the particles produced by the invention can be roughly spherical or isotropic, meaning they have an aspect ratio of about 1.4 or less, although particles having a higher aspect ratio can also be prepared and used as catalyst materials.
- Aspect ratio refers to the ratio of the largest dimension of the particle to the smallest dimension of the particle (thus, a perfect sphere has an aspect ratio of 1.0).
- the diameter of a particle for the purposes of this invention is taken to be the average of all of the diameters of the particle, even in those cases where the aspect ratio of the particle is greater than 1.4.
- a non-noble metal carbonyl is fed into a reactor vessel and sufficient energy to decompose the carbonyl applied, such that the carbonyl decomposes and nano-scale metal particles are deposited on a support or collected in a collector.
- the carbonyl employed in the invention depends on the nano-scale metal particles desired to be produced. In other words, if the desired nano-scale particles comprise nickel and iron, the metal carbonyls employed can be nickel carbonyl, Ni(CO) 4 , and iron carbonyl, Fe(CO) 5 .
- polynuclear metal carbonyls such as diiron nonacarbonyl, Fe 2 (CO) 9 , triiron dodecocarbonyl, Fe 3 (CO) 12 , decacarbonyldimanganese, Mn 2 (CO) 10 can be employed in the production of nano-scale metal particles in accordance with the present invention.
- the polynuclear metal carbonyls can be particularly useful where the nano-scale metal particles desired are alloys or combinations of more than one metallic specie.
- the metal carbonyls useful in producing nano-scale metal particles in accordance with the present invention can be prepared by a variety of methods, many of which are described in “Kirk-Othmer Encyclopedia of Chemical Technology,” Vol. 5, pp. 131-135 (Wiley Interscience 1992). For instance, metallic nickel and iron can readily react with carbon monoxide to form nickel and iron carbonyls, and it has been reported that cobalt, molybdenum and tungsten can also react carbon monoxide, albeit under conditions of higher temperature and pressure.
- metal carbonyls include the synthesis of the carbonyls from salts and oxides in the presence of a suitable reducing agent (indeed, at times, the carbon monoxide itself can act as the reducing agent), and the synthesis of metal carbonyls in solvent systems such as ammonia.
- a suitable reducing agent indeed, at times, the carbon monoxide itself can act as the reducing agent
- metal carbonyls in solvent systems such as ammonia.
- condensation of lower molecular weight metal carbonyls can also be used for the preparation of higher molecular weight species, and carbonylation by carbon monoxide exchange can also be employed.
- polynuclear and heteronuclear metal carbonyls are usually effected by metathesis or addition. Generally, these materials can be synthesized by a condensation process involving either a reaction induced by coordinatively unsaturated species or a reaction between coordinatively unsaturated species in different oxidation states.
- high pressures are normally considered necessary for the production of polynuclear and heteronuclear carbonyls (indeed, for any metal carbonyls other than those of transition metals), the synthesis of polynuclear carbonyls, including manganese carbonyls, under atmospheric pressure conditions is also believed feasible.
- nickel carbonyl is considered to be one of the more poisonous inorganic industrial compounds. While other metal carbonyls are not as toxic as nickel carbonyl, care still needs to be exercised in handling them.
- the processing of the metal carbonyls to form nano-scale metal particles utilizes an apparatus comprising a reactor vessel, at least one feeder for feeding or supplying the non-noble metal carbonyl into the reactor vessel, a support or collector which is operatively connected to the reactor vessel for deposit or collection of nano-scale metal particles produced on decomposition of the carbonyl, and a source of energy capable of decomposing the carbonyl.
- the source of energy should act on the metal carbonyl(s) employed such that the carbonyl(s) decompose to provide nano-scale metal particles which are deposited on the support or or collected by the collector.
- the reactor vessel can be formed of any material which can withstand the conditions under which the decomposition of the carbonyl occurs.
- the vessel can be under subatmospheric pressure, by which is meant pressures as low as about 250 millimeters (mm).
- subatmospheric pressures as low as about 1 mm of pressure
- one advantage of the inventive process is the ability to produce nano-scale particles at generally atmospheric pressure, i.e., about 760 mm.
- the reactor vessel is a “flow-through” reactor vessel, that is, a conduit through which the reactants flow while reacting
- the flow of the reactants can be facilitated by drawing a partial vacuum on the conduit, although no lower than about 250 mm is necessary in order to draw the reactants through the conduit towards the vacuum apparatus, or a flow of an inert gas such as argon can be pumped through the conduit to thus carry the reactants along the flow of the inert gas.
- the flow-through reactor vessel can be a fluidized bed reactor, where the reactants are borne through the reactor on a stream of a fluid.
- This type of reactor vessel may be especially useful where the nano-scale metal particles produced are intended to be loaded on support materials, like carbon blacks or the like, or where the metal particles are to be loaded on an ion exchange or similar powdered resinous material.
- the at least one feeder supplying the carbonyl into the reactor vessel can be any feeder sufficient for the purpose, such as an injector which carries the metal carbonyl along with a jet of a gas such as an inert gas like argon, to thereby carry the carbonyl along the jet of gas through the injector nozzle and into the reactor vessel.
- the gas employed can be a reactant, like oxygen or ozone, rather than an inert gas.
- This type of feeder can be used whether the reactor vessel is a closed system or a flow-through reactor.
- Supports useful in the practice of the invention can be any material on which the nano-scale metal particles produced from decomposition of the metal carbonyl can be deposited.
- the support is the material on which the catalyst metal is ultimately destined, such as the aluminum oxide honeycomb of a catalytic converter in order to deposit nano-scale particles on catalytic converter components without the need for extremes of temperature and pressure required by sputtering and like techniques.
- a collector suitable for collecting the nano-scale particles for re-use such as a cyclonic or centrifugal collector, is employed.
- the support or collector can be disposed within the reactor vessel (indeed this is required in a closed system and is practical in a flow-through reactor).
- the flow of reactants can be directed at a support positioned outside the vessel, at its terminus, especially where the flow through the flow-through reactor vessel is created by a flow of an inert gas.
- the flow of nano-scale metal particles produced by decomposition of the carbonyl can be directed into a centrifugal or cyclonic collector which collects the nano-scale particles in a suitable container for future use.
- the energy employed to decompose the carbonyl can be any form of energy capable of accomplishing this function; indeed, the type or intensity of energy employed can depend on the type of carbonyl being decomposed. For instance, electromagnetic energy such as infrared, visible, or ultraviolet light of the appropriate wavelengths can be employed. Additionally, microwave and/or radio wave energy, or other forms of sonic energy can also be employed (example, a spark to initiate “explosive” decomposition assuming suitable moiety and pressure), provided the metal carbonyl is decomposed by the energy employed.
- microwave energy at a frequency of about 2.4 gigahertz (GHz) or induction energy, at a frequency which can range from as low as about 180 hertz (Hz) up to as high as about 13 mega Hz, can be employed.
- GHz gigahertz
- Hz hertz
- a skilled artisan would readily be able to determine the form of energy useful for decomposing the metal carbonyls which can be employed in the inventive process.
- one preferred form of energy which can be employed to decompose the carbonyl is heat energy supplied by, e.g., heat lamps, radiant heat sources, or the like.
- the temperatures needed are no greater than about 250° C. to ensure effective decomposition of a high percentage of the metal carbonyls in the reactor vessel.
- temperatures no greater than about 200° C. are needed to decompose the carbonyl to effectively produce nano-scale metal particles therefrom.
- the reactor vessel should be designed so as to not cause deposit of the nano-scale metal particles on the vessel itself (as opposed to the support or collector) as a result of the application of the source of energy.
- the source of energy employed is heat
- the reactor vessel itself becomes heated to a temperature at or somewhat higher than the decomposition temperature of the carbonyl during the process of applying heat to the carbonyl to effect decomposition
- the carbonyl will decompose at the walls of the reactor vessel, thus coating the reactor vessel walls with nano-scale metal particles or even bulk metal deposits rather than depositing or collecting the nano-scale metal particles with the support or collector (one exception to this general rule occurs if the walls of the vessel are so hot that the decomposable carbonyl decomposes within the reactor vessel and not on the vessel walls, as discussed in more detail below).
- the support or collector can be equipped with a source of heat itself, such as a resistance heater in or at a surface of the support or collector such that the support or collector is at the temperature needed for decomposition of the carbonyl and the reactor vessel itself is not.
- a source of heat such as a resistance heater in or at a surface of the support or collector such that the support or collector is at the temperature needed for decomposition of the carbonyl and the reactor vessel itself is not.
- the source of energy employed is other than heat
- the source of energy can be chosen such that the energy couples with the support or collector, such as when microwave or induction energy is employed.
- the reactor vessel should be formed of a material which is relatively transparent to the source of energy, especially as compared to the support or collector.
- the decomposition of the decomposable carbonyl occurs as the metal carbonyl is flowing through the flow-through reactor vessel and the reactor vessel should be transparent to the energy employed to decompose the carbonyl.
- the reactor vessel can be maintained at a temperature below the temperature of decomposition of the carbonyl, where heat is the energy employed.
- a cooling medium can maintain the walls of the reactor vessel below the decomposition temperatures of the carbonyl, yet permit heat to pass within the reactor vessel to heat the metal carbonyl and cause decomposition of the carbonyl and production of nano-scale metal particles in the designed manner.
- heating the walls of the reactor vessel, when the reactor vessel is a flow-through reactor vessel, to a temperature substantially higher than the decomposition temperature of the decomposable moiety can permit the reactor vessel walls to themselves act as the source of heat.
- the heat radiating from the reactor walls will heat the inner spaces of the reactor vessel to temperatures at least as high as the decomposition temperature of the decomposable moiety.
- the moiety decomposes before impacting the vessel walls, forming nano-scale particles which are then carried along with the gas flow within the reactor vessel, especially where the gas velocity is enhanced by a vacuum.
- This method of generating decomposition heat within the reactor vessel is also useful where the nano-scale particles formed from decomposition of the decomposable moiety are being attached to carrier materials (like carbon black) also being carried along with the flow within the reactor vessel.
- the walls of the reactor vessel are preferably heated to a temperature which is significantly higher than the temperature desired for decomposition of the decomposable moiety(ies) being fed into the reactor vessel, which can be the decomposition temperature of the decomposable moiety having the highest decomposition temperature of those being fed into the reactor vessel, or a temperature selected to achieve a desired decomposition rate for the moieties present.
- the walls of the reactor vessel should preferably be heated to a temperature such that the moiety would be heated to its decomposition temperature several (at least three) millimeters from the walls of the reactor vessel.
- the specific temperature is selected based on internal pressure, composition and type of moiety, but generally is not greater than about 250° C. and is typically less than about 200° C. to ensure that the internal spaces of the reactor vessel are heated to at least 50° C.
- the reactor vessel can be formed of any material which meets the requirements of temperature and pressure discussed above.
- materials include a metal, graphite, high density plastics or the like.
- the reactor vessel and related components are formed of a transparent material, such as quartz or other forms of glass, including high temperature glass commercially available as Pyrex® materials.
- At least one non-noble metal carbonyl is fed into a reactor vessel where it is exposed to a source of energy sufficient to decompose the carbonyl and produce nano-scale metal particles.
- the metal carbonyl is fed into a closed-system reactor under vacuum or in the presence of an inert gas; similarly, the carbonyl is fed into a flow-through reactor where the flow is created by drawing a vacuum or flowing an inert gas through the flow-through reactor.
- the energy applied is sufficient to decompose the carbonyl in the reactor or as it as flowing through the reactor, and free the metal from the carbonyl and thus create nano-scale metal particles which are deposited on a support or collected in a collector.
- temperatures no greater than about 250° C., more preferably no greater than about 200° C. are required to produce nano-scale metal particles, which at the surface of the substrate for which they are ultimately intended without the use of carrier particles and in a process requiring only seconds and not under extreme conditions of temperature and pressure.
- a single feeder feeds a single carbonyl into the reactor vessel for formation of nano-scale metal particles.
- a plurality of feeders each feeds metal carbonyls into the reactor vessel.
- all feeders can feed the same carbonyl or different feeders can feed different carbonyls, such as additional metal carbonyls, so as to provide nano-scale particles containing different metals such as nickel-iron combinations as desired, in proportions determined by the amount of the carbonyl fed into the reactor vessel by each feeder. For instance, by feeding different carbonyls through different feeders, one can produce a nano-scale particle having a core of a first metal, with domains of a second or third, etc. metal coated thereon.
- altering the carbonyl fed into the reactor vessel by each feeder can alter the nature and/or constitution of the nano-scale particles produced.
- altering the metal carbonyl fed into the reactor vessel by each feeder can produce such different proportions or different orientations.
- each of the feeders can be arrayed about the circumference of the conduit forming the reactor vessel at approximately the same location, or the feeders can be arrayed along the length of the conduit so as to feed metal carbonyls into the reactor vessel at different locations along the flow path of the conduit to provide further control of the nano-scale particles produced.
- inventive process and apparatus may also produce particles that are larger than nano-scale in size along with the nano-scale particles desired, the larger particles can be separated from the sought-after nano-scale particles through the use of the cyclonic separator or because of their differing deposition rates on a collector.
- the metal is a non-noble metal
- the temperature within the reactor vessel is no greater than about 250° C.
- the pressure within the reactor vessel is preferably generally atmospheric, but pressures which vary between about 1 mm to about 2000 mm can be employed.
- the reactor vessel is advantageously formed of a material which is relatively transparent to the energy supplied by the source of energy, as compared to either the support or collector or the metal carbonyl, such as where the source of energy is a source of radiant heat.
- the support or collector can have incorporated therein a resistance heater, or the source of energy can be a heat lamp.
- a cooling medium such as cooling coils or a cooling jacket can be disposed about the reactor vessel to cool the vessel.
- the support can be the end use substrate for the nano-scale metal particles produced, such as a component of an automotive catalytic converter or a fuel cell or electrolysis membrane or electrode.
- the support or collector can be positioned within the reactor vessel.
- the reactor vessel can be a flow-through reactor vessel comprising a conduit, in which case the support or collector can be disposed either external to the reactor vessel or within the reactor vessel.
- FIG. 1 is a side plan view of an apparatus for the production of nano-scale metal particles from metal carbonyl starting materials utilizing a “closed system” reactor vessel in accordance with the process of the present invention.
- FIG. 2 is a side plan view of an alternate embodiment of the apparatus of FIG. 1 .
- FIG. 3 is a side plan view of an apparatus for the production of nano-scale metal particles from metal carbonyl starting materials utilizing a “flow-through” reactor vessel in accordance with the process of the present invention.
- FIG. 4 is an alternative embodiment of the apparatus of FIG. 3 .
- FIG. 5 is another alternative embodiment of the apparatus of FIG. 3 , using a support external to the flow-through reactor vessel.
- apparatus 10 for the production of non-noble metal nano-scale particles is generally designated by the numeral 10 or 100.
- apparatus 10 is a closed system comprising closed reactor vessel 20 whereas in FIGS. 3-5 apparatus 100 is a flow-through reaction apparatus comprising flow-through reactor vessel 120 .
- FIGS. 1-5 show apparatus 10 , 100 in a certain orientation. However, it will be recognized that other orientations are equally applicable for apparatus 10 .
- reactor vessel 20 when under vacuum, reactor vessel 20 can be in any orientation for effectiveness.
- flow-through reactor vessel 120 the flow of inert carrier gas and metal carbonyls or the flow of metal carbonyls as drawn by a vacuum (or combinations thereof in FIGS. 3-5 can be in any particular direction or orientation and still be effective.
- the terms “up” “down” “right” and “left” as used herein refer to the orientation of apparatus 10 , 100 shown in FIGS. 1-5 .
- apparatus 10 comprises a closed-system reactor vessel 20 formed of any material suitable for the purpose and capable of withstanding the exigent conditions for the reaction to proceed inside including conditions of temperature and/or pressure.
- Reactor vessel 20 includes an access port 22 for providing an inert gas such as argon to fill the internal spaces of reactor vessel 20 , the inert gas being provided by a conventional pump or the like (not shown).
- port 22 can be used to provide a vacuum in the internal spaces of reactor vessel 20 by using a vacuum pump or similar device (not shown).
- Reactor vessel 20 has disposed therein a support 30 which can be attached directly to reactor vessel 20 or can be positioned on legs 32 a and 32 b within reactor vessel 20 .
- Reactor vessel 20 also comprises a sealable opening shown at 24 , in order to permit reactor vessel 20 to be opened after the reaction is completed to remove support 30 or remove nano-scale metal particles deposited on support 30 .
- Closure 24 can be a threaded closure or a pressure closure or other types of closing systems, provided they are sufficiently air tight to maintain inert gas or the desired level of vacuum within reactor vessel 20 .
- Apparatus 10 further comprises at least one feeder 40 , and preferably a plurality of feeders 40 a and 40 b , for feeding reactants, more specifically the carbonyl starting materials, into reactor vessel 20 .
- at least one feeder 40 and preferably a plurality of feeders 40 a and 40 b , for feeding reactants, more specifically the carbonyl starting materials, into reactor vessel 20 .
- two feeders 40 a and 40 b are provided, although it is anticipated that other feeders can be employed depending on the nature of the carbonyl(s) introduced into vessel 20 and/or end product nano-scale metal particles desired.
- Feeders 40 a and 40 b can be fed by suitable pumping apparatus for the carbonyl such as venturi pumps or the like (not shown).
- apparatus 10 further comprises a source of energy capable of causing decomposition of the metal carbonyl.
- the source of energy comprises a source of heat, such as a heat lamp 50 , although other radiant heat sources can also be employed.
- the source of energy can be a source of electromagnetic energy, such as infrared, visible or ultraviolet light, microwave energy, radio waves or other forms of sonic energy, as would be familiar to the skilled artisan, provided the energy employed is capable of causing decomposition of the carbonyl.
- the source of energy can provide energy that is preferentially couple-able to support 30 so as to facilitate deposit of nano-scale metal particles produced by decomposition of the carbonyl on support 30 .
- a source of energy such as heat
- support 30 itself comprises the source of energy for decomposition of the carbonyl.
- a resistance heater powered by connection 34 can be incorporated into support 30 such that only support 30 is at the temperature of decomposition of the metal carbonyl, such that the carbonyl decomposes on support 30 and thus produces nano-scale metal particles deposited on support 30 .
- other forms of energy for decomposition of the carbonyl can be incorporated into support 30 .
- Support 30 can be formed of any material sufficient to have deposit thereon of nano-scale metal particles produced by decomposition of the carbonyl.
- support 30 comprises the end use substrate on which the nano-scale metal particles are intended to be employed, such as the aluminum oxide or other components of an automotive catalytic converter, or the electrode or membrane of a fuel cell or electrolysis cell.
- the source of energy is itself embedded in or focused on and associated with support 30 , selective deposition of the catalytic nano-scale metal particles can be obtained to increase the efficiency of the catalytic reaction and reduce inefficiencies or wasted catalytic metal placement.
- the source of energy can be embedded within support 30 in the desired pattern for deposition of catalyst metal, such that deposition of the catalyst nano-scale metal can be placed where catalytic reaction is desired.
- apparatus 100 comprises a flow-through reactor vessel 120 which includes a port, denoted 122 , for either providing an inert gas or drawing a vacuum from reactor vessel 120 to thus create flow for the metal carbonyls to be reacted to produce nano-scale metal particles.
- apparatus 100 includes feeders 140 a , 140 b , 140 c , which can be disposed about the circumference of reactor vessel 102 , as shown in FIG. 3 , or, in the alternative, sequentially along the length of reactor vessel 120 , as shown in FIG. 4 .
- Apparatus 100 also comprises support 130 on which nano-scale metal particles are collected.
- Support 130 can be positioned on legs 132 a and 132 b or, in the event a source of energy is incorporated into support 130 , as a resistance heater, the control and wiring for the source of energy in support 130 can be provided through line 134 .
- a port 124 is also provided for removal of support 130 or the nano-scale metal particles deposited thereon.
- port 124 should be structured such that it permits the inert gas fed through port 122 and flowing through reactor vessel 120 to egress reactor vessel 120 (as shown in FIG. 3 ).
- Port 124 can be sealed in the same manner as closure 24 discussed above with respect to closed system apparatus 10 .
- port 124 can be sealed by a threaded closure or pressure closure or other types of closing structures as would be familiar to the skilled artisan.
- support 130 can be disposed external to reactor vessel 120 in flow-through reactor apparatus 100 , and can also be a structural support 130 as illustrated in FIG. 5 .
- flow-through reactor vessel 120 comprises a port 124 through which are impinged on support 130 to thus form and deposit the nano-scale metal particles on support 130 .
- port 124 through which are impinged on support 130 to thus form and deposit the nano-scale metal particles on support 130 .
- either port 126 or support 130 can be moved in order to provide for the formation of the produced nano-scale metal particles on certain specific areas of support 130 .
- support 130 comprises the end use substrate for the nano-scale metal particles such as the component of a catalytic converter or electrode for fuel cells.
- the nano-scale metal particles are only deposited where desired and efficiency and decrease of wasted catalytic metal is facilitated.
- reactor vessel 20 , 120 can be formed of any suitable material for use in the reaction provided it can withstand the temperature and/or pressure at which decomposition of the carbonyl starting materials occurs.
- the reactor vessel should be able to withstand temperatures up to about 250° C. where heat is the energy used to decompose the carbonyl.
- reactor vessels 20 , 120 are formed of a transparent material to provide for observation of the reaction as it is proceeding.
- reactor vessel 20 , 120 is preferably formed of quartz or a glass such as Pyrex® brand material available from Corning, Inc. of Corning, N.Y.
- either a flow of an inert gas such as argon or a vacuum is drawn on reactor vessel 20 , 120 and a stream of metal carbonyl(s) fed into reactor vessel 20 , 120 via feeders 40 a , 40 b , 140 a , 140 b , 140 c .
- the carbonyl(s) should be subject to decomposition and production of nano-scale metal particles at temperatures no greater than 250° C., more preferably no greater than 200° C.
- Other materials, such as oxygen can also be fed into reactor 20 , 120 to partially oxidize the nano-scale metal particles produced by decomposition of the carbonyl, to modify the nano-scale particles and limit subsequent degradation.
- a reducing material such as hydrogen can be fed into reactor 20 , 120 to facilitate the decomposition of the metal carbonyl into very pure metal nano-scale particles.
- reactor vessel 20 , 120 The energy for decomposition of the carbonyl is then provided to the carbonyl within reactor vessel 20 , 120 by, for instance, heat lamp 50 , 150 .
- reactor vessel 120 can also be cooled by cooling coils 52 , 152 to avoid deposit of nano-scale metal particles on the surface of reactor vessel 20 , 120 as opposed to support 30 , 130 .
- Nano-scale metal particles produced by the decomposition of the metal carbonyls are then deposited on support 30 , 130 or, in a cyclonic or centrifugal or other type collector (not shown), for storage and/or use.
- the present invention provides a facile and continuous method for producing nano-scale metal particles which permits selective placement of the particles, direct deposit of the particles on the end use substrate, without the need for extremes of temperature and pressure required by prior art processes.
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Manufacture Of Metal Powder And Suspensions Thereof (AREA)
- Catalysts (AREA)
Abstract
Description
- The present invention relates to a process for the production of non-noble metal nano-scale particles using metal carbonyls. By “non-noble metal” is meant a metal other than one of the noble metals (generally considered to be gold, silver, platinum, palladium, iridium, rhenium, mercury, ruthenium and osmium). The resulting nano-scale particles are useful for catalysis and other purposes. By the practice of the present invention, nano-scale particles can be produced from metal carbonyls and collected with greater speed, precision and flexibility than can be accomplished with conventional processing. Thus, the invention provides a practical and cost-effective means for preparing such nano-scale particles.
- Catalysts are becoming ubiquitous in modern chemical processing. Catalysts are used in the production of materials such as fuels, lubricants, refrigerants, polymers, drugs, etc., as well as playing a role in water and air pollution mediation processes. Indeed, catalysts have been ascribed as having a role in fully one third of the material gross national product of the United States, as discussed by Alexis T. Bell in “The Impact of Nanoscience on Heterogeneous Catalysis” (Science, Vol. 299, pg. 1688, 14 Mar. 2003).
- Generally speaking, catalysts can be described as small particles deposited on high surface area solids. Traditionally, catalyst particles can range from the sub-micron up to tens of microns. One example described by Bell is the catalytic converter of automobiles, which consist of a honeycomb whose walls are coated with a thin coating of porous aluminum oxide (alumina). In the production of the internal components of catalytic converters, an aluminum oxide wash coat is impregnated with nanoparticles of a platinum group metal catalyst material. In fact, most industrial catalysts used today include platinum group metals especially platinum, rhodium and iridium or alkaline metals like cesium, at times in combination with other metals such as iron or nickel.
- The size of these particles has been recognized as extremely significant in their catalytic function. Indeed it is also noted by Bell that the performance of a catalyst can be greatly affected by the particle size of the catalyst particles, since properties such as surface structure and the electronic properties of the particles can change as the size of the catalyst particles changes.
- In his study on nanotechnology of catalysis presented at the Frontiers in Nanotechnology Conference on May 13, 2003, Eric M. Stuve of the Department of Chemical Engineering of the University of Washington, described how the general belief is that the advantage of the use of nano-sized particles in catalysis is due to the fact that the available surface area of small particles is greater than that of larger particles, thus providing more metal atoms at the to optimize catalysis using such nano-sized catalyst materials. However, Stuve points out that the advantages of the use of nano-sized catalyst particles may be more than simply due to the size effect. Rather, the use of nanoparticles can exhibit modified electronic structure and a different shape with actual facets being present in the nanoparticles, which provide for interactions which can facilitate catalysis. Indeed, Cynthia Friend, in “Catalysis On Surfaces” (Scientific American, April 1993, p. 74), posits catalyst shape, and, more specifically, the orientation of atoms on the surface of the catalyst particles, as important in catalysis. In addition, differing mass transport resistances may also improve catalyst function. Thus, the production of nano-sized metal particles for use as catalysts on a more flexible and commercially efficacious platform is being sought. Moreover, other applications for nano-scale particles are being sought, whether for the platinum group metals traditionally used for catalysis or other metal particles.
- Conventionally, however, catalysts are prepared in two ways. One such process involves catalyst materials being deposited on the surface of carrier particles such as carbon blacks or other like materials, with the catalyst-loaded particles then themselves being loaded on the surface at which catalysis is desired. One example of this is in the fuel cell arena, where carbon black or other like particles loaded with platinum group metal catalysts are then themselves loaded at the membrane/electrode interface to catalyze the breakdown of molecular hydrogen into monatomic hydrogen, for its separation into its component protons and electrons, with the resulting electrons passed through a circuit as the current generated by the fuel cell; on the opposing surface, molecular oxygen is separated into monatomic oxygen for eventual combination with the proton and electron to form water. One major drawback to the preparation of catalyst materials through loading on a carrier particle is in the amount of time the loading reactions take, which can be measured in hours in some cases.
- To wit, in U.S. Pat. No. 6,716,525, Yadav and Pfaffenbach describe the dispersing of nano-scale powders on coarser carrier powders in order to provide catalyst materials. The carrier particles of Yadav and Pfaffenbach include oxides, carbides, nitrides, borides, chalcogenides, metals and alloys. The nanoparticles dispersed on the carriers can be any of many different materials according to Yadav and Pfaffenbach, including precious metals such as platinum group metals, rare earth metals, the so-called semi-metals, as well as non-metallic materials, and even clusters such as fullerenes, alloys and nanotubes.
- Alternatively, the second common methods for preparing catalyst materials involves directly loading catalyst metals such as platinum group metals on a support without the use of carrier particles which can interfere with the catalytic reaction. For example, many automotive catalytic converters, as discussed above, have catalyst particles directly loaded on the aluminum oxide honeycomb which forms the converter structure. The processes needed for direct deposition of catalytic metals on support structures, however, are generally operated at extremes of temperature and/or pressures. For instance, one such process is chemical sputtering at temperatures in excess of 1,500° C. and under conditions of high vacuum. Thus, these processes are difficult and expensive to operate and also involve line-of-sight reactions, precluding fully utilization of the support structure.
- In an attempt to provide nano-scale catalyst particles, Bert and Bianchini, in International Patent Application Publication No. WO 2004/036674, suggest a process using a templating resin to produce nano-scale particles for fuel cell applications. Even if technically feasible, however, the Bert and Bianchini methods require high temperatures (on the order of 300° C. to 800° C.), and require several hours. Accordingly, these processes are of limited value.
- Taking a different approach, Sumit Bhaduri, in “Catalysis With Platinum Carbonyl Clusters,” Current Science, Vol. 78, No. 11, 10 Jun. 2000, asserts that platinum carbonyl clusters, by which is meant polynuclear metal carbonyl complexes with three or more metal atoms, have potential as redox catalysts, although the Bhaduri publication acknowledges that the behavior of such carbonyl clusters as redox catalysts is not understood in a comprehensive manner. Indeed, metal carbonyls have been recognized for use in catalysis in other applications.
- Metal carbonyls have also been used as, for instance, anti-knock compounds in unleaded gasolines. However, more significant uses of metal carbonyls are in the production and/or deposition of the metals present in the carbonyl, since metal carbonyls are generally viewed as easily decomposed and volatile resulting in deposition of the metal and carbon monoxide.
- Generally speaking, carbonyls are transition metals combined with carbon monoxide and have the general formula Mx(CO)y, where M is a metal in the zero oxidation state and where x and y are both integers. While many consider metal carbonyls to be coordination compounds, the nature of the metal to carbon bond leads some to classify them as organometallic compounds. In any event, the metal carbonyls have been used to prepare high purity metals, although not for the production of nano-scale metal particles. As noted, metal carbonyls have also been found useful for their catalytic properties such as for the synthesis of organic chemicals in gasoline antiknock formulations.
- While, as noted, catalyst materials are traditionally formed of noble metals, such as the platinum group metals, the formation of nano-scale particles, with the resulting surface area and surface effect advantages, may permit the use of non-noble metals, such as nickel, iron, etc., as catalyst materials. The resulting cost savings can be significant, and can permit the more widespread use of catalytic reactions in industrial processing.
- Accordingly, what is needed is a process for the production of non-noble metal nano-scale particles for use as, e.g., catalyst materials. The desired process can be used for the preparation of nano-scale particles loaded on a carrier particle but, significantly, can also be used for the deposit of catalytic non-noble metal nano-scale particles directly on a surface without the requirement for extremes in temperature and/or pressures.
- A process for the production of non-noble metal nano-scale particles using metal carbonyl starting materials is presented. By nano-scale particles is meant particles having an average diameter of no greater than about 1,000 nanometers (nm), e.g., no greater than about one micron. More preferably, the particles produced by the inventive system have an average diameter no greater than about 250 nm, most preferably no greater than about 20 nm.
- The particles produced by the invention can be roughly spherical or isotropic, meaning they have an aspect ratio of about 1.4 or less, although particles having a higher aspect ratio can also be prepared and used as catalyst materials. Aspect ratio refers to the ratio of the largest dimension of the particle to the smallest dimension of the particle (thus, a perfect sphere has an aspect ratio of 1.0). The diameter of a particle for the purposes of this invention is taken to be the average of all of the diameters of the particle, even in those cases where the aspect ratio of the particle is greater than 1.4.
- In the practice of the present invention, a non-noble metal carbonyl is fed into a reactor vessel and sufficient energy to decompose the carbonyl applied, such that the carbonyl decomposes and nano-scale metal particles are deposited on a support or collected in a collector. The carbonyl employed in the invention depends on the nano-scale metal particles desired to be produced. In other words, if the desired nano-scale particles comprise nickel and iron, the metal carbonyls employed can be nickel carbonyl, Ni(CO)4, and iron carbonyl, Fe(CO)5. In addition, polynuclear metal carbonyls such as diiron nonacarbonyl, Fe2(CO)9, triiron dodecocarbonyl, Fe3(CO)12, decacarbonyldimanganese, Mn2(CO)10 can be employed in the production of nano-scale metal particles in accordance with the present invention. Indeed, the polynuclear metal carbonyls can be particularly useful where the nano-scale metal particles desired are alloys or combinations of more than one metallic specie.
- The metal carbonyls useful in producing nano-scale metal particles in accordance with the present invention can be prepared by a variety of methods, many of which are described in “Kirk-Othmer Encyclopedia of Chemical Technology,” Vol. 5, pp. 131-135 (Wiley Interscience 1992). For instance, metallic nickel and iron can readily react with carbon monoxide to form nickel and iron carbonyls, and it has been reported that cobalt, molybdenum and tungsten can also react carbon monoxide, albeit under conditions of higher temperature and pressure. Other methods for forming metal carbonyls include the synthesis of the carbonyls from salts and oxides in the presence of a suitable reducing agent (indeed, at times, the carbon monoxide itself can act as the reducing agent), and the synthesis of metal carbonyls in solvent systems such as ammonia. In addition, the condensation of lower molecular weight metal carbonyls can also be used for the preparation of higher molecular weight species, and carbonylation by carbon monoxide exchange can also be employed.
- The synthesis of polynuclear and heteronuclear metal carbonyls, including those discussed above, is usually effected by metathesis or addition. Generally, these materials can be synthesized by a condensation process involving either a reaction induced by coordinatively unsaturated species or a reaction between coordinatively unsaturated species in different oxidation states. Although high pressures are normally considered necessary for the production of polynuclear and heteronuclear carbonyls (indeed, for any metal carbonyls other than those of transition metals), the synthesis of polynuclear carbonyls, including manganese carbonyls, under atmospheric pressure conditions is also believed feasible.
- It must be borne in mind in working with the metal carbonyls, that care in handling must be used at all times, since exposure to metal carbonyls can be a serious health threat. Indeed, nickel carbonyl is considered to be one of the more poisonous inorganic industrial compounds. While other metal carbonyls are not as toxic as nickel carbonyl, care still needs to be exercised in handling them.
- The processing of the metal carbonyls to form nano-scale metal particles utilizes an apparatus comprising a reactor vessel, at least one feeder for feeding or supplying the non-noble metal carbonyl into the reactor vessel, a support or collector which is operatively connected to the reactor vessel for deposit or collection of nano-scale metal particles produced on decomposition of the carbonyl, and a source of energy capable of decomposing the carbonyl. The source of energy should act on the metal carbonyl(s) employed such that the carbonyl(s) decompose to provide nano-scale metal particles which are deposited on the support or or collected by the collector.
- The reactor vessel can be formed of any material which can withstand the conditions under which the decomposition of the carbonyl occurs. Generally, where the reactor vessel is a closed system, that is, where it is not an open ended vessel permitting reactants to flow into and out of the vessel, the vessel can be under subatmospheric pressure, by which is meant pressures as low as about 250 millimeters (mm). Indeed, the use of subatmospheric pressures, as low as about 1 mm of pressure, can accelerate decomposition of the carbonyl and provide smaller nano-scale particles. However, one advantage of the inventive process is the ability to produce nano-scale particles at generally atmospheric pressure, i.e., about 760 mm. Alternatively, there may be advantage in cycling the pressure, such as from sub-atmospheric to generally atmospheric or above, to encourage nano-deposits within the structure of the carrier particles or supports. Of course, even in a so-called “closed system,” there needs to be a valve or like system for relieving pressure build-up caused, for instance, by the generation of carbon monoxide (CO) from decomposition of the metal carbonyl or other by-products. Accordingly, the use of the expression “closed system” is meant to distinguish the system from a flow-through type of system as discussed hereinbelow.
- When the reactor vessel is a “flow-through” reactor vessel, that is, a conduit through which the reactants flow while reacting, the flow of the reactants can be facilitated by drawing a partial vacuum on the conduit, although no lower than about 250 mm is necessary in order to draw the reactants through the conduit towards the vacuum apparatus, or a flow of an inert gas such as argon can be pumped through the conduit to thus carry the reactants along the flow of the inert gas.
- Indeed, the flow-through reactor vessel can be a fluidized bed reactor, where the reactants are borne through the reactor on a stream of a fluid. This type of reactor vessel may be especially useful where the nano-scale metal particles produced are intended to be loaded on support materials, like carbon blacks or the like, or where the metal particles are to be loaded on an ion exchange or similar powdered resinous material.
- The at least one feeder supplying the carbonyl into the reactor vessel can be any feeder sufficient for the purpose, such as an injector which carries the metal carbonyl along with a jet of a gas such as an inert gas like argon, to thereby carry the carbonyl along the jet of gas through the injector nozzle and into the reactor vessel. The gas employed can be a reactant, like oxygen or ozone, rather than an inert gas. This type of feeder can be used whether the reactor vessel is a closed system or a flow-through reactor.
- Supports useful in the practice of the invention can be any material on which the nano-scale metal particles produced from decomposition of the metal carbonyl can be deposited. In a preferred embodiment, the support is the material on which the catalyst metal is ultimately destined, such as the aluminum oxide honeycomb of a catalytic converter in order to deposit nano-scale particles on catalytic converter components without the need for extremes of temperature and pressure required by sputtering and like techniques. Alternatively, a collector suitable for collecting the nano-scale particles for re-use, such as a cyclonic or centrifugal collector, is employed.
- The support or collector can be disposed within the reactor vessel (indeed this is required in a closed system and is practical in a flow-through reactor). However, in a flow-through reactor vessel, the flow of reactants can be directed at a support positioned outside the vessel, at its terminus, especially where the flow through the flow-through reactor vessel is created by a flow of an inert gas. Alternatively, in a flow-through reactor, the flow of nano-scale metal particles produced by decomposition of the carbonyl can be directed into a centrifugal or cyclonic collector which collects the nano-scale particles in a suitable container for future use.
- The energy employed to decompose the carbonyl can be any form of energy capable of accomplishing this function; indeed, the type or intensity of energy employed can depend on the type of carbonyl being decomposed. For instance, electromagnetic energy such as infrared, visible, or ultraviolet light of the appropriate wavelengths can be employed. Additionally, microwave and/or radio wave energy, or other forms of sonic energy can also be employed (example, a spark to initiate “explosive” decomposition assuming suitable moiety and pressure), provided the metal carbonyl is decomposed by the energy employed. Thus, microwave energy, at a frequency of about 2.4 gigahertz (GHz) or induction energy, at a frequency which can range from as low as about 180 hertz (Hz) up to as high as about 13 mega Hz, can be employed. A skilled artisan would readily be able to determine the form of energy useful for decomposing the metal carbonyls which can be employed in the inventive process.
- Because of the relatively low decomposition temperature of metal carbonyls, generally less than about 150° C., and often less than about 80° C., one preferred form of energy which can be employed to decompose the carbonyl is heat energy supplied by, e.g., heat lamps, radiant heat sources, or the like. In such case, the temperatures needed are no greater than about 250° C. to ensure effective decomposition of a high percentage of the metal carbonyls in the reactor vessel. Indeed, generally, temperatures no greater than about 200° C. are needed to decompose the carbonyl to effectively produce nano-scale metal particles therefrom.
- Depending on the source of energy employed, the reactor vessel should be designed so as to not cause deposit of the nano-scale metal particles on the vessel itself (as opposed to the support or collector) as a result of the application of the source of energy. In other words, if the source of energy employed is heat, and the reactor vessel itself becomes heated to a temperature at or somewhat higher than the decomposition temperature of the carbonyl during the process of applying heat to the carbonyl to effect decomposition, then the carbonyl will decompose at the walls of the reactor vessel, thus coating the reactor vessel walls with nano-scale metal particles or even bulk metal deposits rather than depositing or collecting the nano-scale metal particles with the support or collector (one exception to this general rule occurs if the walls of the vessel are so hot that the decomposable carbonyl decomposes within the reactor vessel and not on the vessel walls, as discussed in more detail below).
- One way to avoid this is to direct the energy directly at the support or collector. For instance, if heat is the energy applied for decomposition of the metal carbonyl, the support or collector can be equipped with a source of heat itself, such as a resistance heater in or at a surface of the support or collector such that the support or collector is at the temperature needed for decomposition of the carbonyl and the reactor vessel itself is not. Thus, decomposition occurs at the support or collector and formation of nano-scale particles occurs principally at the support or collector. When the source of energy employed is other than heat, the source of energy can be chosen such that the energy couples with the support or collector, such as when microwave or induction energy is employed. In this instance, the reactor vessel should be formed of a material which is relatively transparent to the source of energy, especially as compared to the support or collector.
- Similarly, especially in situations when the support or collector is disposed outside the reactor vessel when a flow-through reactor vessel is employed with a support collector at its terminus (whether a solid substrate collector for depositing of nano-scale metal particles thereon or a cyclonic or like collector for collecting the nano-scale metal particles for deposit in a suitable container), the decomposition of the decomposable carbonyl occurs as the metal carbonyl is flowing through the flow-through reactor vessel and the reactor vessel should be transparent to the energy employed to decompose the carbonyl. Alternatively, whether or not the support or collector is inside the reactor vessel, or outside it, the reactor vessel can be maintained at a temperature below the temperature of decomposition of the carbonyl, where heat is the energy employed. One way in which the reactor vessel can be maintained below the decomposition temperatures of the metal carbonyl is through the use of a cooling medium like cooling coils or a cooling jacket. A cooling medium can maintain the walls of the reactor vessel below the decomposition temperatures of the carbonyl, yet permit heat to pass within the reactor vessel to heat the metal carbonyl and cause decomposition of the carbonyl and production of nano-scale metal particles in the designed manner.
- In an alternative embodiment which is especially applicable where both the walls of the reactor vessel and the gases in the reactor vessel are generally equally susceptible to the heat energy applied (such as when both are relatively transparent), heating the walls of the reactor vessel, when the reactor vessel is a flow-through reactor vessel, to a temperature substantially higher than the decomposition temperature of the decomposable moiety can permit the reactor vessel walls to themselves act as the source of heat. In other words, the heat radiating from the reactor walls will heat the inner spaces of the reactor vessel to temperatures at least as high as the decomposition temperature of the decomposable moiety. Thus, the moiety decomposes before impacting the vessel walls, forming nano-scale particles which are then carried along with the gas flow within the reactor vessel, especially where the gas velocity is enhanced by a vacuum. This method of generating decomposition heat within the reactor vessel is also useful where the nano-scale particles formed from decomposition of the decomposable moiety are being attached to carrier materials (like carbon black) also being carried along with the flow within the reactor vessel. In order to heat the walls of the reactor vessel to a temperature sufficient to generate decomposition temperatures for the decomposable moiety within the reactor vessel, the walls of the reactor vessel are preferably heated to a temperature which is significantly higher than the temperature desired for decomposition of the decomposable moiety(ies) being fed into the reactor vessel, which can be the decomposition temperature of the decomposable moiety having the highest decomposition temperature of those being fed into the reactor vessel, or a temperature selected to achieve a desired decomposition rate for the moieties present. For instance, if the decomposable moiety having the highest decomposition temperature of those being fed into the reactor vessel is nickel carbonyl, having a decomposition temperature of about 50° C., then the walls of the reactor vessel should preferably be heated to a temperature such that the moiety would be heated to its decomposition temperature several (at least three) millimeters from the walls of the reactor vessel. The specific temperature is selected based on internal pressure, composition and type of moiety, but generally is not greater than about 250° C. and is typically less than about 200° C. to ensure that the internal spaces of the reactor vessel are heated to at least 50° C.
- In any event, the reactor vessel, as well as the feeders, can be formed of any material which meets the requirements of temperature and pressure discussed above. Such materials include a metal, graphite, high density plastics or the like. Most preferably the reactor vessel and related components are formed of a transparent material, such as quartz or other forms of glass, including high temperature glass commercially available as Pyrex® materials.
- Thus, in the process of the present invention, at least one non-noble metal carbonyl is fed into a reactor vessel where it is exposed to a source of energy sufficient to decompose the carbonyl and produce nano-scale metal particles. The metal carbonyl is fed into a closed-system reactor under vacuum or in the presence of an inert gas; similarly, the carbonyl is fed into a flow-through reactor where the flow is created by drawing a vacuum or flowing an inert gas through the flow-through reactor. The energy applied is sufficient to decompose the carbonyl in the reactor or as it as flowing through the reactor, and free the metal from the carbonyl and thus create nano-scale metal particles which are deposited on a support or collected in a collector. Where heat is the energy used to decompose the carbonyl, temperatures no greater than about 250° C., more preferably no greater than about 200° C. are required to produce nano-scale metal particles, which at the surface of the substrate for which they are ultimately intended without the use of carrier particles and in a process requiring only seconds and not under extreme conditions of temperature and pressure.
- In one embodiment of the inventive process, a single feeder feeds a single carbonyl into the reactor vessel for formation of nano-scale metal particles. In another embodiment, however, a plurality of feeders each feeds metal carbonyls into the reactor vessel. In this way, all feeders can feed the same carbonyl or different feeders can feed different carbonyls, such as additional metal carbonyls, so as to provide nano-scale particles containing different metals such as nickel-iron combinations as desired, in proportions determined by the amount of the carbonyl fed into the reactor vessel by each feeder. For instance, by feeding different carbonyls through different feeders, one can produce a nano-scale particle having a core of a first metal, with domains of a second or third, etc. metal coated thereon. Indeed, altering the carbonyl fed into the reactor vessel by each feeder can alter the nature and/or constitution of the nano-scale particles produced. In other words, if different proportions of metals making up the nano-scale particles, or different orientations of the metals making up the nano-scale particles is desired, altering the metal carbonyl fed into the reactor vessel by each feeder can produce such different proportions or different orientations.
- Indeed, in the case of the flow-through reactor vessel, each of the feeders can be arrayed about the circumference of the conduit forming the reactor vessel at approximately the same location, or the feeders can be arrayed along the length of the conduit so as to feed metal carbonyls into the reactor vessel at different locations along the flow path of the conduit to provide further control of the nano-scale particles produced.
- While it is anticipated that the inventive process and apparatus may also produce particles that are larger than nano-scale in size along with the nano-scale particles desired, the larger particles can be separated from the sought-after nano-scale particles through the use of the cyclonic separator or because of their differing deposition rates on a collector.
- Therefore it is an object of the present invention to provide a process for the production of nano-scale metal particles using metal carbonyl starting materials.
- It is another object of the present invention to provide a process capable of producing non-noble metal nano-scale particles under conditions of temperature and/or pressure less extreme than conventional processes.
- It is still another object of the present invention to provide a process for preparing non-noble metal nano-scale particles which can be formed on the end use substrate.
- It is yet another object of the present invention to provide a process for preparing non-noble metal nano-scale particles which can be collected for further use or treatment.
- These objects and others which will be apparent to the skilled artisan upon reading the following description, can be achieved by feeding at least one metal carbonyl into a reactor vessel, wherein the metal is a non-noble metal; exposing the non-noble metal carbonyl within the reactor vessel to a source of energy sufficient to decompose the non-noble metal carbonyl and produce nano-scale metal particles; and depositing or collecting the nano-scale metal particles. Preferably, the temperature within the reactor vessel is no greater than about 250° C. The pressure within the reactor vessel is preferably generally atmospheric, but pressures which vary between about 1 mm to about 2000 mm can be employed.
- The reactor vessel is advantageously formed of a material which is relatively transparent to the energy supplied by the source of energy, as compared to either the support or collector or the metal carbonyl, such as where the source of energy is a source of radiant heat. In fact, the support or collector can have incorporated therein a resistance heater, or the source of energy can be a heat lamp. Where the energy is heat, a cooling medium such as cooling coils or a cooling jacket can be disposed about the reactor vessel to cool the vessel.
- The support can be the end use substrate for the nano-scale metal particles produced, such as a component of an automotive catalytic converter or a fuel cell or electrolysis membrane or electrode. The support or collector can be positioned within the reactor vessel. However, the reactor vessel can be a flow-through reactor vessel comprising a conduit, in which case the support or collector can be disposed either external to the reactor vessel or within the reactor vessel.
- It is to be understood that both the foregoing general description and the following detailed description present embodiments of the invention, and are intended to provide an overview or framework for understanding the nature and character of the invention as it is claimed. The accompanying drawings are included to provide a further understanding of the invention, and are incorporated in and constitute a part of this specification. The drawings illustrate various embodiments of the invention, and together with the description serve to explain the principles and operations of the invention.
-
FIG. 1 is a side plan view of an apparatus for the production of nano-scale metal particles from metal carbonyl starting materials utilizing a “closed system” reactor vessel in accordance with the process of the present invention. -
FIG. 2 is a side plan view of an alternate embodiment of the apparatus ofFIG. 1 . -
FIG. 3 is a side plan view of an apparatus for the production of nano-scale metal particles from metal carbonyl starting materials utilizing a “flow-through” reactor vessel in accordance with the process of the present invention. -
FIG. 4 is an alternative embodiment of the apparatus ofFIG. 3 . -
FIG. 5 is another alternative embodiment of the apparatus ofFIG. 3 , using a support external to the flow-through reactor vessel. - Referring now to the drawings, an apparatus for the production of non-noble metal nano-scale particles is generally designated by the numeral 10 or 100. In
FIGS. 1 and 2 apparatus 10 is a closed system comprisingclosed reactor vessel 20 whereas inFIGS. 3-5 apparatus 100 is a flow-through reaction apparatus comprising flow-throughreactor vessel 120. - It will be noted that
FIGS. 1-5 show apparatus 10, 100 in a certain orientation. However, it will be recognized that other orientations are equally applicable for apparatus 10. For instance, when under vacuum,reactor vessel 20 can be in any orientation for effectiveness. Likewise, in flow-throughreactor vessel 120, the flow of inert carrier gas and metal carbonyls or the flow of metal carbonyls as drawn by a vacuum (or combinations thereof inFIGS. 3-5 can be in any particular direction or orientation and still be effective. In addition, the terms “up” “down” “right” and “left” as used herein refer to the orientation ofapparatus 10, 100 shown inFIGS. 1-5 . - Referring now to
FIGS. 1 and 2 , as discussed above apparatus 10 comprises a closed-system reactor vessel 20 formed of any material suitable for the purpose and capable of withstanding the exigent conditions for the reaction to proceed inside including conditions of temperature and/or pressure.Reactor vessel 20 includes anaccess port 22 for providing an inert gas such as argon to fill the internal spaces ofreactor vessel 20, the inert gas being provided by a conventional pump or the like (not shown). Similarly, as illustrated inFIG. 2 ,port 22 can be used to provide a vacuum in the internal spaces ofreactor vessel 20 by using a vacuum pump or similar device (not shown). In order for the reaction to successfully proceed under vacuum inreactor vessel 20, it is not necessary that an extreme vacuum condition be created. Rather negative pressures no less than about 1 mm, preferably no less than about 250 mm, are all that are required. -
Reactor vessel 20 has disposed therein asupport 30 which can be attached directly toreactor vessel 20 or can be positioned onlegs reactor vessel 20.Reactor vessel 20 also comprises a sealable opening shown at 24, in order to permitreactor vessel 20 to be opened after the reaction is completed to removesupport 30 or remove nano-scale metal particles deposited onsupport 30.Closure 24 can be a threaded closure or a pressure closure or other types of closing systems, provided they are sufficiently air tight to maintain inert gas or the desired level of vacuum withinreactor vessel 20. - Apparatus 10 further comprises at least one feeder 40, and preferably a plurality of
feeders reactor vessel 20. As illustrated inFIGS. 1 and 2 , twofeeders vessel 20 and/or end product nano-scale metal particles desired.Feeders - As illustrated in
FIG. 1 , apparatus 10 further comprises a source of energy capable of causing decomposition of the metal carbonyl. In the embodiment illustrated inFIG. 1 , the source of energy comprises a source of heat, such as aheat lamp 50, although other radiant heat sources can also be employed. In addition, as discussed above, the source of energy can be a source of electromagnetic energy, such as infrared, visible or ultraviolet light, microwave energy, radio waves or other forms of sonic energy, as would be familiar to the skilled artisan, provided the energy employed is capable of causing decomposition of the carbonyl. - In one preferred embodiment, the source of energy can provide energy that is preferentially couple-able to support 30 so as to facilitate deposit of nano-scale metal particles produced by decomposition of the carbonyl on
support 30. However, where a source of energy such as heat is employed, which would also heatreactor vessel 20, it may be desirable tocool reactor vessel 20 using, e.g., cooling tubes 52 (shown partially broken away) such thatreactor vessel 20 is maintained at a temperature below the decomposition temperature of the carbonyl. In this way, the metal carbonyl does not decompose at the surfaces ofreactor vessel 20 but rather onsupport 30. - In an alternative embodiment illustrated in
FIG. 2 ,support 30 itself comprises the source of energy for decomposition of the carbonyl. For instance, a resistance heater powered byconnection 34 can be incorporated intosupport 30 such thatonly support 30 is at the temperature of decomposition of the metal carbonyl, such that the carbonyl decomposes onsupport 30 and thus produces nano-scale metal particles deposited onsupport 30. Likewise, other forms of energy for decomposition of the carbonyl can be incorporated intosupport 30. -
Support 30 can be formed of any material sufficient to have deposit thereon of nano-scale metal particles produced by decomposition of the carbonyl. In a preferred embodiment,support 30 comprises the end use substrate on which the nano-scale metal particles are intended to be employed, such as the aluminum oxide or other components of an automotive catalytic converter, or the electrode or membrane of a fuel cell or electrolysis cell. Indeed, where the source of energy is itself embedded in or focused on and associated withsupport 30, selective deposition of the catalytic nano-scale metal particles can be obtained to increase the efficiency of the catalytic reaction and reduce inefficiencies or wasted catalytic metal placement. In other words, the source of energy can be embedded withinsupport 30 in the desired pattern for deposition of catalyst metal, such that deposition of the catalyst nano-scale metal can be placed where catalytic reaction is desired. - In another embodiment of the invention, as illustrated in
FIGS. 3-5 ,apparatus 100 comprises a flow-throughreactor vessel 120 which includes a port, denoted 122, for either providing an inert gas or drawing a vacuum fromreactor vessel 120 to thus create flow for the metal carbonyls to be reacted to produce nano-scale metal particles. In addition,apparatus 100 includesfeeders FIG. 3 , or, in the alternative, sequentially along the length ofreactor vessel 120, as shown inFIG. 4 . -
Apparatus 100 also comprisessupport 130 on which nano-scale metal particles are collected.Support 130 can be positioned onlegs support 130, as a resistance heater, the control and wiring for the source of energy insupport 130 can be provided throughline 134. - As illustrated in
FIGS. 3 and 4 , whensupport 130 is disposed within flow-throughreactor vessel 120, aport 124 is also provided for removal ofsupport 130 or the nano-scale metal particles deposited thereon. In addition,port 124 should be structured such that it permits the inert gas fed throughport 122 and flowing throughreactor vessel 120 to egress reactor vessel 120 (as shown inFIG. 3 ).Port 124 can be sealed in the same manner asclosure 24 discussed above with respect to closed system apparatus 10. In other words,port 124 can be sealed by a threaded closure or pressure closure or other types of closing structures as would be familiar to the skilled artisan. - As illustrated in
FIG. 5 , however,support 130 can be disposed external toreactor vessel 120 in flow-throughreactor apparatus 100, and can also be astructural support 130 as illustrated inFIG. 5 . In this embodiment, flow-throughreactor vessel 120 comprises aport 124 through which are impinged onsupport 130 to thus form and deposit the nano-scale metal particles onsupport 130. In this way it is no longer necessary to gain access toreactor vessel 120 to collect eithersupport 130 or the nano-scale metal particles deposited thereon. In addition, during the impingement onsupport 130, either port 126 orsupport 130 can be moved in order to provide for the formation of the produced nano-scale metal particles on certain specific areas ofsupport 130. This is especially useful ifsupport 130 comprises the end use substrate for the nano-scale metal particles such as the component of a catalytic converter or electrode for fuel cells. Thus, the nano-scale metal particles are only deposited where desired and efficiency and decrease of wasted catalytic metal is facilitated. - As discussed above,
reactor vessel reactor vessels reactor vessel - In the practice of the invention, either a flow of an inert gas such as argon or a vacuum is drawn on
reactor vessel reactor vessel feeders reactor reactor - The energy for decomposition of the carbonyl is then provided to the carbonyl within
reactor vessel heat lamp reactor vessel 120 can also be cooled by coolingcoils reactor vessel support - Thus the present invention provides a facile and continuous method for producing nano-scale metal particles which permits selective placement of the particles, direct deposit of the particles on the end use substrate, without the need for extremes of temperature and pressure required by prior art processes.
- All cited patents, patent applications and publications referred to herein are incorporated by reference.
- The invention thus being described, it will be apparent that it can be varied in many ways. Such variations are not to be regarded as a departure from the spirit and scope of the present invention and all such modifications as would be apparent to one skilled in the art are intended to be included within the scope of the following claims.
Claims (15)
Priority Applications (6)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US11/201,354 US20070034050A1 (en) | 2005-08-10 | 2005-08-10 | Process for the use of metal carbonyls for the production of nano-scale metal particles formed of non-noble metals |
CA002618824A CA2618824A1 (en) | 2005-08-10 | 2006-08-09 | Process for the use of metal carbonyls for the production of nano-scale metal particles |
CN2006800350259A CN101495256B (en) | 2005-08-10 | 2006-08-09 | Process for the use of metal carbonyls for the production ofnano-scale metal particles |
BRPI0614683-0A BRPI0614683A2 (en) | 2005-08-10 | 2006-08-09 | process for the use of metallic carbonyls in the production of nanoscale metallic particles |
PCT/US2006/030999 WO2007136389A2 (en) | 2005-08-10 | 2006-08-09 | Process for the use of metal carbonyls for the production of nano-scale metal particles |
EP06851270A EP1922169B1 (en) | 2005-08-10 | 2006-08-09 | Process for the use of metal carbonyls for the production of nano-scale metal particles |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US11/201,354 US20070034050A1 (en) | 2005-08-10 | 2005-08-10 | Process for the use of metal carbonyls for the production of nano-scale metal particles formed of non-noble metals |
Publications (1)
Publication Number | Publication Date |
---|---|
US20070034050A1 true US20070034050A1 (en) | 2007-02-15 |
Family
ID=37741383
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US11/201,354 Abandoned US20070034050A1 (en) | 2005-08-10 | 2005-08-10 | Process for the use of metal carbonyls for the production of nano-scale metal particles formed of non-noble metals |
Country Status (1)
Country | Link |
---|---|
US (1) | US20070034050A1 (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20070036913A1 (en) * | 2005-08-10 | 2007-02-15 | Mercuri Robert A | Process and apparatus for the production of engineered catalyst materials formed of non-noble metals |
US20070036911A1 (en) * | 2005-08-10 | 2007-02-15 | Mercuri Robert A | Process and apparatus for the production of catalyst-coated support materials formed of non-noble metals |
Citations (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1836732A (en) * | 1929-03-05 | 1931-12-15 | Ig Farbenindustrie Ag | Production of finely divided metals |
US2935394A (en) * | 1956-04-16 | 1960-05-03 | Commw Engineering Corp | Method and apparatus for producing micron and sub-micron metals |
US2938781A (en) * | 1957-12-27 | 1960-05-31 | Gen Aniline & Film Corp | Production of magnetic iron particles |
US5064464A (en) * | 1988-11-10 | 1991-11-12 | Mitsubishi Petrochemical Company Limited | Process for producing ultrafine metal particles |
US5145716A (en) * | 1989-10-19 | 1992-09-08 | Inco Limited | Infrared window |
US5358695A (en) * | 1993-01-21 | 1994-10-25 | Physical Sciences, Inc. | Process for producing nanoscale ceramic powders |
US5885321A (en) * | 1996-07-22 | 1999-03-23 | The United States Of America As Represented By The Secretary Of The Navy | Preparation of fine aluminum powders by solution methods |
US5897945A (en) * | 1996-02-26 | 1999-04-27 | President And Fellows Of Harvard College | Metal oxide nanorods |
US20030097903A1 (en) * | 2000-02-10 | 2003-05-29 | Deegan David Edward | Plasma arc reactor for the production of fine powders |
US6716525B1 (en) * | 1998-11-06 | 2004-04-06 | Tapesh Yadav | Nano-dispersed catalysts particles |
US6761870B1 (en) * | 1998-11-03 | 2004-07-13 | William Marsh Rice University | Gas-phase nucleation and growth of single-wall carbon nanotubes from high pressure CO |
US20050166934A1 (en) * | 2003-10-27 | 2005-08-04 | Philip Morris Usa Inc. | In situ synthesis of composite nanoscale particles |
-
2005
- 2005-08-10 US US11/201,354 patent/US20070034050A1/en not_active Abandoned
Patent Citations (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1836732A (en) * | 1929-03-05 | 1931-12-15 | Ig Farbenindustrie Ag | Production of finely divided metals |
US2935394A (en) * | 1956-04-16 | 1960-05-03 | Commw Engineering Corp | Method and apparatus for producing micron and sub-micron metals |
US2938781A (en) * | 1957-12-27 | 1960-05-31 | Gen Aniline & Film Corp | Production of magnetic iron particles |
US5064464A (en) * | 1988-11-10 | 1991-11-12 | Mitsubishi Petrochemical Company Limited | Process for producing ultrafine metal particles |
US5145716A (en) * | 1989-10-19 | 1992-09-08 | Inco Limited | Infrared window |
US5358695A (en) * | 1993-01-21 | 1994-10-25 | Physical Sciences, Inc. | Process for producing nanoscale ceramic powders |
US5897945A (en) * | 1996-02-26 | 1999-04-27 | President And Fellows Of Harvard College | Metal oxide nanorods |
US5885321A (en) * | 1996-07-22 | 1999-03-23 | The United States Of America As Represented By The Secretary Of The Navy | Preparation of fine aluminum powders by solution methods |
US6761870B1 (en) * | 1998-11-03 | 2004-07-13 | William Marsh Rice University | Gas-phase nucleation and growth of single-wall carbon nanotubes from high pressure CO |
US6716525B1 (en) * | 1998-11-06 | 2004-04-06 | Tapesh Yadav | Nano-dispersed catalysts particles |
US20030097903A1 (en) * | 2000-02-10 | 2003-05-29 | Deegan David Edward | Plasma arc reactor for the production of fine powders |
US20050166934A1 (en) * | 2003-10-27 | 2005-08-04 | Philip Morris Usa Inc. | In situ synthesis of composite nanoscale particles |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20070036913A1 (en) * | 2005-08-10 | 2007-02-15 | Mercuri Robert A | Process and apparatus for the production of engineered catalyst materials formed of non-noble metals |
US20070036911A1 (en) * | 2005-08-10 | 2007-02-15 | Mercuri Robert A | Process and apparatus for the production of catalyst-coated support materials formed of non-noble metals |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US20100222212A1 (en) | Production Of Chain Agglomerations Of Nano-Scale Metal Particles | |
US20070036913A1 (en) | Process and apparatus for the production of engineered catalyst materials formed of non-noble metals | |
US20070286778A1 (en) | Apparatus for the continuous production of nano-scale metal particles | |
US20070283782A1 (en) | Continuous process for the production of nano-scale metal particles | |
EP1922144B1 (en) | Process for the production of engineered catalyst materials | |
EP1922169B1 (en) | Process for the use of metal carbonyls for the production of nano-scale metal particles | |
US20070034049A1 (en) | Continuous process for the use of metal carbonyls for the production of nano-scale metal particles | |
EP1937404B1 (en) | Process for the production of catalyst-coated support materials | |
US7794521B2 (en) | Production of chain agglomerations of nano-scale metal particles | |
EP1928624B1 (en) | Continuous production of nano-scale metal particles | |
EP2266729B1 (en) | Production of chain agglomerations of nano-scale metal particles | |
US20070036689A1 (en) | Production of nano-scale metal particles | |
US20070037701A1 (en) | Process and apparatus for the production of catalyst-coated support materials | |
US20070036912A1 (en) | Continuous process and apparatus for the production of engineered catalyst materials | |
US20070034051A1 (en) | Process for the use of metal carbonyls for the production of nano-scale metal particles | |
US20070034050A1 (en) | Process for the use of metal carbonyls for the production of nano-scale metal particles formed of non-noble metals | |
US20070036911A1 (en) | Process and apparatus for the production of catalyst-coated support materials formed of non-noble metals | |
US20070283784A1 (en) | Continuous process for the use of metal carbonyls for the production of nano-scale metal particles formed of non-noble metals | |
US20070037700A1 (en) | Continuous process and apparatus for the production of catalyst-coated support materials | |
US20070283783A1 (en) | Process for the production of nano-scale metal particles | |
CN101300070A (en) | Process and apparatus for the production of engineered catalyst materials |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
AS | Assignment |
Owner name: DIRECTA PLUS PATENT & TECHNOLOGY LIMITED, CYPRUS Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNOR:MERCURI, ROBERT A.;REEL/FRAME:017416/0211 Effective date: 20050806 |
|
AS | Assignment |
Owner name: DIRECTA PLUS SRL, ITALY Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNOR:DIRECTA PLUS PATENT & TECHNOLOGY LIMITED;REEL/FRAME:022404/0519 Effective date: 20090317 Owner name: DIRECTA PLUS SRL,ITALY Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNOR:DIRECTA PLUS PATENT & TECHNOLOGY LIMITED;REEL/FRAME:022404/0519 Effective date: 20090317 |
|
AS | Assignment |
Owner name: DIRECTA PLUS SRL, ITALY Free format text: CORRECTIVE ASSIGNMENT TO CORRECT THE TYPOGRAPHICAL ERRORS IN THE TEXT MISLABELING THE ASSIGNOR AND ASSIGNEE PREVIOUSLY RECORDED ON REEL 022404 FRAME 0519;ASSIGNOR:DIRECTA PLUS PATENT & TECHNOLOGY LIMITED;REEL/FRAME:022426/0009 Effective date: 20090317 Owner name: DIRECTA PLUS SRL,ITALY Free format text: CORRECTIVE ASSIGNMENT TO CORRECT THE TYPOGRAPHICAL ERRORS IN THE TEXT MISLABELING THE ASSIGNOR AND ASSIGNEE PREVIOUSLY RECORDED ON REEL 022404 FRAME 0519. ASSIGNOR(S) HEREBY CONFIRMS THE ASSIGNMENT OF THE PATENT APPLICATIONS FROM ASSIGNOR DIRECTA PLUS PATENT & TECHNOLOGY LIMITED TO ASSIGNEE DIRECTA PLUS SRL;ASSIGNOR:DIRECTA PLUS PATENT & TECHNOLOGY LIMITED;REEL/FRAME:022426/0009 Effective date: 20090317 Owner name: DIRECTA PLUS SRL, ITALY Free format text: CORRECTIVE ASSIGNMENT TO CORRECT THE TYPOGRAPHICAL ERRORS IN THE TEXT MISLABELING THE ASSIGNOR AND ASSIGNEE PREVIOUSLY RECORDED ON REEL 022404 FRAME 0519. ASSIGNOR(S) HEREBY CONFIRMS THE ASSIGNMENT OF THE PATENT APPLICATIONS FROM ASSIGNOR DIRECTA PLUS PATENT & TECHNOLOGY LIMITED TO ASSIGNEE DIRECTA PLUS SRL;ASSIGNOR:DIRECTA PLUS PATENT & TECHNOLOGY LIMITED;REEL/FRAME:022426/0009 Effective date: 20090317 |
|
STCB | Information on status: application discontinuation |
Free format text: ABANDONED -- AFTER EXAMINER'S ANSWER OR BOARD OF APPEALS DECISION |