US20070029694A1 - Apertured material for use in absorbent articles - Google Patents

Apertured material for use in absorbent articles Download PDF

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Publication number
US20070029694A1
US20070029694A1 US11/546,151 US54615106A US2007029694A1 US 20070029694 A1 US20070029694 A1 US 20070029694A1 US 54615106 A US54615106 A US 54615106A US 2007029694 A1 US2007029694 A1 US 2007029694A1
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US
United States
Prior art keywords
film
method
micro
heat shield
material
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
US11/546,151
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US8182728B2 (en
Inventor
James Cree
Lino Iulianetti
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
JOSEPH TESSARI
Tredegar Film Products Corp
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Tredegar Film Products Corp
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Filing date
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Priority to US43594202P priority Critical
Priority to US10/744,152 priority patent/US20040161586A1/en
Application filed by Tredegar Film Products Corp filed Critical Tredegar Film Products Corp
Assigned to JOSEPH TESSARI reassignment JOSEPH TESSARI ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: CREE, JAMES W., LULIANETTI, LINO
Priority to US11/546,151 priority patent/US8182728B2/en
Publication of US20070029694A1 publication Critical patent/US20070029694A1/en
Publication of US8182728B2 publication Critical patent/US8182728B2/en
Application granted granted Critical
Application status is Expired - Fee Related legal-status Critical
Anticipated expiration legal-status Critical

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    • A61FFILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
    • A61F13/00Bandages or dressings; Absorbent pads
    • A61F13/15Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
    • A61F13/51Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators characterised by the outer layers
    • A61F13/511Topsheet, i.e. the permeable cover or layer facing the skin
    • A61F13/512Topsheet, i.e. the permeable cover or layer facing the skin characterised by its apertures, e.g. perforations
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    • A61F13/15Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
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    • B29C43/22Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor of articles of indefinite length
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    • B29C59/02Surface shaping of articles, e.g. embossing; Apparatus therefor by mechanical means, e.g. pressing
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T156/00Adhesive bonding and miscellaneous chemical manufacture
    • Y10T156/10Methods of surface bonding and/or assembly therefor
    • Y10T156/1052Methods of surface bonding and/or assembly therefor with cutting, punching, tearing or severing
    • Y10T156/1056Perforating lamina
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/24Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24273Structurally defined web or sheet [e.g., overall dimension, etc.] including aperture
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/24Structurally defined web or sheet [e.g., overall dimension, etc.]
    • Y10T428/24273Structurally defined web or sheet [e.g., overall dimension, etc.] including aperture
    • Y10T428/24322Composite web or sheet
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/249921Web or sheet containing structurally defined element or component

Abstract

A method of thermo-mechanically forming macrotextures in a microtextured film wherein a heat shield is utilized to thermally insulate the microtexture during the forming process.

Description

  • This application claims the benefit of U.S. Provisional Application No. 60/435,942, filed Dec. 20, 2002. The disclosure of the prior application is considered part of (and is incorporated by reference in) the disclosure of this application.
  • TECHNICAL FIELD
  • This invention relates to the formation of three-dimensional thermoplastic films, and more particularly those with both micro-texture and macro-apertures.
  • BACKGROUND Description of Related Art
  • There has always been a need to create cloth-like textures in poly-olefin films that can in turn become three-dimensionally apertured fluid transporting structures. In the past this texturing was achieved through the creation of a plurality of micro-apertures that stick out from the surface of film. This fragile micro-texture can be created through the use of water forming or vacuum forming as described in the prior art. However, once micro-texturing is completed, it is difficult to create the three-dimensional (“3D”) funnel-shaped aperture that allows the fluid to pass through the film into the absorbent layer underneath without destroying the micro-texture. Water or needle perforation has been attempted, however, the water approach is not at a high enough temperature to create a permanently deformed and stress annealed aperture. Thus, a large 3D aperture formed using water perforation could have the tendency to become flat again if subjected to stress or to pressure at the time the aperture is formed. Use of a hot needle is not effective either, because the heat from the hot needle will melt the surrounding, very delicate micro-texture if the needle is hot enough to impart any permanent deformation into the cone. If the micro-texture is micro-apertures, the heat of the needle causes the edges of the micro-apertures to “crisp” or become very stiff as a result of the exposure to the heat. This sort of stiffening of the edges makes the final product rough to the touch.
  • A novel method of using thermo-mechanical perforation with a matching set of needles, grooves and protective surface to create such product is disclosed herein. Further, this invention teaches how, in one pass, a product can have large 3D fluid transport holes imparted into a micro-textured film and how a fluid transport layer may be attached under the fluid transport sheets to direct the fluid away from the 3D funnel of the micro-textured film. The final product produced via such process is primarily intended for use as a body-contacting, textured formed film top sheet in an absorbent hygienic product or wound dressing. Further, this product can be used as a sub-layer in such an absorbent article or as a top layer in a baby diaper.
  • SUMMARY
  • A film is first microscopically textured and then macroscopically textured while maintaining the microscopic texture. The micro-texturing may be done by a variety of means including vacuum forming, and may include micro-apertures. The macroscopic texture may be done by a variety of means including thermo-mechanical means with a heat shielding means. Where heated pins are used, the heat shielding means protects the micro-texture from the heat so that the heat does not deform the micro-texture.
  • The details of one or more embodiments of the invention are set forth in the accompanying drawings and the description below. Other features, objects, and advantages of the invention will be apparent from the description and drawings, and from the claims.
  • DESCRIPTION OF DRAWINGS
  • FIG. 1 is a schematic view of a method of forming a micro-texture in a film.
  • FIG. 2 is a cross sectional view of a film with micro-texture formed by the process shown in FIG. 1.
  • FIG. 3 is a schematic view of a method of forming a macro-texture in a film.
  • FIG. 4 is a cross sectional view of a film with both a micro-texture and a macro-texture as formed by the processes of FIG. 1 and FIG. 3.
  • FIG. 5 is a schematic view of a method of forming a macro-texture in a film while combining a nonwoven layer with the film.
  • FIG. 6 is a cross sectional view of a film adjacent to a nonwoven layer and with both a microtexture and a macro-texture as formed by the processes of FIG. 1 and FIG. 5.
  • FIG. 7 is a schematic view of a method of forming a macro-texture in a film.
  • FIG. 8 is a cross sectional view of a film with both a micro-texture and a macro-texture as formed by the processes of FIG. 1 and FIG. 7.
  • FIG. 9 is a schematic view of a method of forming a macro-texture in a film while combining a nonwoven layer with the film.
  • FIG. 10 is a cross sectional view of a film adjacent to a nonwoven layer and with both a microtexture and a macro-texture as formed by the processes of FIG. 1 and FIG. 9.
  • Like reference symbols in the various drawings indicate like elements.
  • DETAILED DESCRIPTION
  • As used herein, “micro” refers to individual features that are not individually discernable, when viewed by the human eye from about 18 inches, although a change in texture on a whole may be discernable, while “macro” refers to features that are individually discernable when viewed by the human eye from about 18 inches. For example, micro-apertures with a mesh of between about 30 apertures per linear inch and 100 apertures per linear inch will change the surface texture of a film, but the individual apertures will not be individually discernable by the human eye from a distance of about 18 inches. Likewise, macro-apertures with a spacing of about 5 to about 11 holes per square centimeter will be individually discernable by the human eye from a distance of about 18 inches.
  • A film material 10, which is typically thermoplastic, is extruded onto a forming screen 12. Forming screen 12 contains a micro-texture. The forming screen 12 may have a variety of micro-texture patterns. The film material 10 is thereby formed into a microscopically three-dimensional film 14. The film material 10 may be apertured as part of the vacuum forming or may be allowed to stay intact.
  • The film material 10 may be a thin film consisting of a 50/50 blend of LDPE and LLDPE extruded from a cast die 16 or a blown die. While the film material 10 is still in a semi-molten, malleable state a pressure is applied by differential pressure means, such as a vacuum, blown air, etc., to the film material 10 to have the film material 10 form to a screen 12. The pressure may be applied by known vacuum forming techniques as shown in FIG. 1, although other means may be acceptable. The screen 12 imparts a micro-texture 16 to the film material 10. The resultant micro-textured film 14 will have a micro-texture 16, which may include micro-apertures, micro-ridges, micro-dots, or other micro-textures known in the art, as it is removed from the screen 12 as shown in FIG. 2. If the micro-texture 16 is micro-apertures, the micro-apertures may have a density of between about 30 holes per linear inch and about 100 holes per linear inch, also known as about 30 mesh to about 100 mesh, and preferably between about 40 mesh and about 60 mesh. Where micro-textures 16 are formed of micro-apertures, they may be three-dimensional micro-funnels to increase their effect on tactile response as well as fluid handling properties. Where micro-textures 16 are formed of micro-apertures they may be round;. elongated, octagonal, oval, hexagonal, ellipsoid, rectangular, square, or any other shape or pattern depending on the preferred texture or fluid handling properties.
  • The film material 10 may contain surfactants in the resin, or surfactants may be added to the micro-textured film 14. Surfactants increase the philicity of the normally phobic film material 10 and may affect the performance of the finished product as discussed below. Alternatively, surfactants may not be added, resulting in a phobic film material 10.
  • In a preferred embodiment, the micro-textured film 14 is then thermo-mechanically perforated to produce a macroscopic three-dimensional aperture 18. The macro-aperture 18 forms a macroscopic texture on the film, and therefore the terms macro-texture and macro-aperture 18 are used throughout. Heat shielding 22 allows the use of heated pins 20 to perforate the micro-textured film 14 without destroying the micro-texture 16. Without heat shielding 22, the heated pins 20 may soften the material of film 14 such that micro-texture 16 is destroyed or the heated pins 20 may crisp the edges of the micro-texture 16 as described above. If micro-textured film 14 is sufficiently heated by heated pins 20, the micro-texture 16 will melt back to a film, thus losing the texture created by screen 12. The heat shield 22, shown in FIGS. 3, 5, 7, and 9, is a shielding material 26 having a higher melting point than the film, such as a nonwoven polypropylene, which passes through the perforating nip 30 between the micro-textured film 14 and a drum 24 carrying heated perforating pins 22. Two effective examples of shielding material 26 are nonwovens known in the art as Spun-Meltblown-Spun 19 gsm and Thermo-bonded Carded 24 gsm. The selection of an appropriate nonwoven material to be used as shielding material 26 should be based on finding a nonwoven that has a melting point higher than the film material 10. Other heat shields would include various other materials, which may be able to run on a continuous loop with a cooling cycle, a cooled drum/heated pin arrangement, and various fluid-cooling means.
  • The thermo-mechanical perforating unit shown in FIG. 3 uses heated pins 20 mated into an unheated female roll 28 to form a nip 30. The micro-textured film 14 and above-mentioned shielding material 26 are fed into the nip 30 such that the heated pins 20 form macroscopic three-dimensional apertures 18 in the micro-textured film 14. The shape of the apertures is determined by the relationship between pins 20 and roll 28. The macro-apertures 18 of this preferred embodiment have a density of between about 4 holes per square centimeter and about 15 holes per square centimeter, and preferably between about 5 holes per square centimeter and about 12 holes per square centimeter. The macro-apertures 18 may be formed into a cone that extends from an upper surface of the film 14 to a lower surface spaced apart by a distance greater than the initial thickness of film 14. The taper of the cone will depend on the shape of female roll 28 and heated pins 20. Depending on the relative speed at which the film 14, heated pins 20, and female roll 28 are moving, the macro-apertures 18 may be round or elongated.
  • Female roll 28 may be temperature controlled to maintain a consistency to the macro-apertures 18 formed at the nip 30. The temperature control may include cooling or heating as needed for the desired results. For example, an operating temperature of 30 degrees Celsius may require cooling in some environments, heating in others.
  • The film 32 of the preferred embodiment will have a vacuum formed micro-texture 16 and a thermo-mechanically formed macro-texture 18, as shown in FIGS. 4 and 8. The micro-textured film 14 of FIG. 2 has a caliper of about 25 microns while the caliper of the film 32 of FIGS. 4 and 6 is about 400 microns to about 1500 microns, preferably between about 800 microns and 1300 microns. The film 32 of this preferred embodiment will have a desirable texture provided by the micro-texture 16 and a resilient structure provided by the macro-texture 18.
  • As shown in FIGS. 5 and 9, a second material 34, such as a wicking nonwoven, may be fed into the nip 30 of the thermo-mechanical forming means to simultaneously bond the second material 34 to the film layer 14 thus creating a composite material 36. The second material 34 may be positioned between the film layer 14 and female roll 28 so that the micro-texture 16 is still exposed. Heated pins 20 would puncture second material 34 at macro-apertures 18. In this manner, a composite, material 36 may be formed having the tactile impression and fluid handling abilities of a micro-apertured film backed by a wicking material and the fluid handling abilities of macro-apertures 18 unobstructed by the second material 34 as shown in FIG. 6. The second material 34 is effective in wicking moisture away from the film layer 14, thus improving the wetback performance.
  • As can be seen by comparison of FIGS. 4 and 8 or FIGS. 6 and 10 where the micro-textures 16 are micro-apertures, the micro-apertures may extend in the same direction as the macro-apertures 18, FIGS. 8 and 10, or in the opposite direction as the macro-apertures 18, FIGS. 4 and 6.
  • Absorbent articles typically have a body facing topsheet, a backsheet opposite the topsheet, and an absorbent core between the topsheet and backsheet. Additionally, modem absorbent articles may contain an intermediate layer between the topsheet and the absorbent core. The film 32 or composite material 36 may be used as a topsheet or an intermediate layer in an absorbent article.
  • Performance Measures
  • Various materials were tested as topsheets against comparative topsheet materials. One of the comparative materials is a hydro-formed topsheet used in the Procter & Gamble sanitary napkin product “Lines Petalo Blu” and referred to herein as “HFF”. Another of the comparative materials is the nonwoven phobic topsheet used in the SCA sanitary napkin product “Nuvenia Libresse” and referred to herein as “NW”. The materials used for the different examples are as follows:
  • Example 1: A micro-texture 16 of 60 mesh micro-apertures in a philic film material 10 and macro-apertures 18 with a spacing of about 5.6 apertures per square centimeter.
  • Example 2: Similar to Example 1, but with a micro-texture 16 of 40 mesh micro-apertures.
  • Example 3: Similar to Example 1, but with a phobic film material 10.
  • Example 4: Similar to Example 2, but with a phobic film material 10.
  • Example 5: Similar to Example 1, but with a second material 34 of 25 gsm air through bonded nonwoven (ATB 25 RAM).
  • Example 6: Similar to Example 2, but with a second material 34 of 25 gsm air through bonded nonwoven (ATB 25 RAM).
  • Example 7: Similar to Example 5, but with macro-apertures 18 with a spacing of about 11 apertures per square centimeter.
  • Example 8: Similar to Example 6, but with macro-apertures 18 with a spacing of about 11 apertures per square centimeter.
  • Strikethrough is a measure of the rate of absorption through a topsheet into an absorbent article and was conducted on finished articles as indicated below. In order to test strikethrough the original topsheet material is removed from the article and replaced with the topsheet material to be tested, except when testing the sample of the original material. The article is then insulted with a 10 ml sample of Menstrual Internal Synthetic Solution (MISS) and the strikethrough time is recorded using a Lister apparatus as described in EDANA Recommended Test Method ERT 150.5-02 Liquid Strike Through Time Test Method. Lower strikethrough numbers reflect a fast absorption and are desired in most absorbent articles.
  • Wetback is measured on the same samples used in the strikethrough test described above. After the strikethrough is measured the samples are carefully removed from the test apparatus and positioned on a flat surface. A 4 kg weight with a surface of 10 cm by 10 cm is placed on the insult area of the sample for three minutes. At three minutes the weight is removed and 5 pre-weighed pick up papers are placed over the insult area and the weight is placed over the pickup paper. At two minutes the weight is removed and the pickup paper is removed and reweighed The weight gained by the pickup paper is reported as the wetback. This method is based on EDANA Recommended Test Method ERT 151.3-02 Wetback. Lower wetback numbers reflect more complete absorption and less leakage to the insult surface and are desired in most absorbent articles.
  • The following data refers to the tests performed on “Lines Petalo Blu” articles tested under the method described above:
    Topsheet Strikethrough (seconds) Rewet (grams)
    HFF 49.0 0.93
    Example 1 38.7 0.72
    Example 2 13.0 0.36
    Example 5 54.8 0.43
    Example 6 27.8 0.27
    Example 7 47.0 0.42
    Example 8 32.0 0.26
  • The following data refers to the tests performed on “Nuvenia” articles tested under the method described above:
    Topsheet Strikethrough (seconds) Rewet (grams)
    NW >500 1.3
    Example 1 143.6 1.2
    Example 2 73.4 1.2
    Example 3 325.3 1.1
    Example 4 164.0 1.1
    Example 7 91.78 0.465
    Example 8 61.13 0.570
  • As can be seen from the above results, all of the Examples showed improvement over the original topsheet material used in the absorbent article.
  • While particular embodiments of the present invention have been illustrated and described, it would be obvious to those skilled in the art that various other changes and modifications can be made without departing from the spirit and scope of the invention. The appended claims are therefore intended to cover all such changes and modifications that are within the scope of this invention.

Claims (20)

1. A method of manufacturing a formed film comprising:
a. providing a micro-textured thermoplastic film;
b. disposing a removable heat shield between said film and at least a portion of a heated pin roller; and
c. macro-texturing said film by urging pins of said heated pin roller toward said film wherein said heat shield thermally insulates said micro-texture.
2. The method of claim 1 wherein said pins penetrate said heat shield and contact said film.
3. The method of claim 2 wherein said heat shield contacts said film.
4. The method of claim 3 further comprising separating said heat shield from said film after said macro-texturing.
5. The method of claim 1 wherein said macro-texture is macroscopic embossment.
6. The method of claim 1 wherein said macro-texture is macroscopic three-dimensional apertures.
7. The method of claim 6 wherein said macroscopic three-dimensional apertures are conically shaped.
8. The method of claim 6 wherein said macroscopic three-dimensional apertures have a spacing of about 4 to about 15 apertures per square centimeter.
9. The method of claim 6 wherein said macro-textured film has a caliper of about 400 microns to about 1500 microns.
10. The method of claim 1 wherein said micro-texture is selected from the group consisting of microscopic three-dimensional apertures, micro-ridges, and micro-dots.
11. The method of claim 10 wherein said microscopic three-dimensional apertures are micro-funnels.
12. The method of claim 11 wherein said microscopic three-dimensional apertures have a spacing of about 30 to about 100 apertures per linear inch.
13. The method of claim 1 wherein said heat shield comprises a nonwoven material having a higher melting point than said film.
14. The method of claim 13 wherein said nonwoven material is a polypropylene.
15. The method of claim 1 wherein said thermo-mechanically texturing is accomplished by passing said micro-textured film through a nip existing between a heated pin drum and a cooled drum.
16. The method of claim 15 wherein said heat shield is passed through said nip in conjunction with said film.
17. The method of claim 16 further comprising passing a second material through said nip wherein said heat shield in on a first side of said film and said second material is on a second side of said film.
18. The method of claim 17 wherein said second material is a nonwoven.
19. The method of claim 18 wherein said second material is bonded to and co-apertured with said film via said thermo-mechanical texturing to form a composite material.
20. An apparatus for producing a formed film comprising:
a. a thermo-mechanical perforating unit having a heated pin roller and a female roller, wherein said rollers are disposed to form a nip;
b. means for feeding a heat shield through said nip;
c. means for feeding a film through said nip such that said film is disposed between said heat shield and said female roller.
US11/546,151 2002-12-20 2006-10-11 Apertured material for use in absorbent articles Expired - Fee Related US8182728B2 (en)

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US8182728B2 (en) 2012-05-22
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ES2300662T3 (en) 2008-06-16

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