US20060226473A1 - Gate electrode stack and use of a gate electrode stack - Google Patents
Gate electrode stack and use of a gate electrode stack Download PDFInfo
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- US20060226473A1 US20060226473A1 US11/101,378 US10137805A US2006226473A1 US 20060226473 A1 US20060226473 A1 US 20060226473A1 US 10137805 A US10137805 A US 10137805A US 2006226473 A1 US2006226473 A1 US 2006226473A1
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- 229910021420 polycrystalline silicon Inorganic materials 0.000 claims abstract description 52
- 229920005591 polysilicon Polymers 0.000 claims abstract description 49
- 239000004020 conductor Substances 0.000 claims abstract description 29
- 238000000034 method Methods 0.000 claims abstract description 17
- 239000000463 material Substances 0.000 claims abstract description 12
- 230000008569 process Effects 0.000 claims abstract description 11
- 239000000758 substrate Substances 0.000 claims abstract description 10
- 238000001514 detection method Methods 0.000 claims abstract description 8
- 239000004065 semiconductor Substances 0.000 claims abstract 4
- 239000010410 layer Substances 0.000 claims description 120
- 229910006990 Si1-xGex Inorganic materials 0.000 claims description 44
- 229910007020 Si1−xGex Inorganic materials 0.000 claims description 44
- 239000002184 metal Substances 0.000 claims description 17
- 238000005538 encapsulation Methods 0.000 claims description 7
- 238000004519 manufacturing process Methods 0.000 claims description 7
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 5
- 229910052710 silicon Inorganic materials 0.000 claims description 5
- 239000010703 silicon Substances 0.000 claims description 5
- 238000001312 dry etching Methods 0.000 claims description 4
- 239000002355 dual-layer Substances 0.000 claims description 4
- 238000000151 deposition Methods 0.000 claims description 3
- 238000005530 etching Methods 0.000 description 6
- 230000008901 benefit Effects 0.000 description 5
- 229910052581 Si3N4 Inorganic materials 0.000 description 4
- 150000004767 nitrides Chemical class 0.000 description 4
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 description 4
- 229910000577 Silicon-germanium Inorganic materials 0.000 description 3
- 230000000694 effects Effects 0.000 description 2
- 238000001459 lithography Methods 0.000 description 2
- 238000005240 physical vapour deposition Methods 0.000 description 2
- 230000009977 dual effect Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- CJNBYAVZURUTKZ-UHFFFAOYSA-N hafnium(IV) oxide Inorganic materials O=[Hf]=O CJNBYAVZURUTKZ-UHFFFAOYSA-N 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 229920002120 photoresistant polymer Polymers 0.000 description 1
- 229910021332 silicide Inorganic materials 0.000 description 1
- FVBUAEGBCNSCDD-UHFFFAOYSA-N silicide(4-) Chemical compound [Si-4] FVBUAEGBCNSCDD-UHFFFAOYSA-N 0.000 description 1
- 238000009966 trimming Methods 0.000 description 1
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- H01L21/28061—Making conductor-insulator-semiconductor electrodes the insulator being formed after the semiconductor body, the semiconductor being silicon characterised by the conductor the final conductor layer next to the insulator being silicon, e.g. polysilicon, with or without impurities the conductor comprising at least another non-silicon conductive layer the conductor comprising a metal or metal silicide formed by deposition, e.g. sputter deposition, i.e. without a silicidation reaction
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- H01L29/4941—Metal-insulator-semiconductor electrodes, e.g. gates of MOSFET the conductor material next to the insulator being a silicon layer, e.g. polysilicon doped with boron, phosphorus or nitrogen with a multiple layer structure, e.g. several silicon layers with different crystal structure or grain arrangement with a barrier layer between the silicon and the metal or metal silicide upper layer, e.g. Silicide/TiN/Polysilicon
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Definitions
- This invention relates generally to a gate electrode stack and the use of the gate conductor stack.
- a gate electrode stack in a conventional DRAM device can comprise the following layers (from substrate (bottom) up):
- the polysilicon layer and the W/WN/Ti (or other materials such as WSi x ) layer comprise the gate conductor (GC) stack in the gate electrode stack.
- GC gate conductor
- a thin Ti flash layer in the W/WN/Ti metal stack is used to guarantee good contact properties between the metal stack and the polysilicon layer, since Ti silicide is formed at the interface after full processing.
- the etching of a GC stack is challenging since after the etching of the metal stack, an over-etch into the polysilicon layer must be performed. This over-etch is difficult to control since the end-point of the over-etch is primarily controllable only through fixed time. There is no end-point signal generated when the over-etch is performed into the polysilicon layer.
- Typical etch chemistries for plasma dry-etching of a W/WN/Ti stack are Cl 2 , NF 3 , O 2 and HBr, which are quite aggressive chemistries, while Cl 2 , O 2 and NF 3 are typically used etch chemistries for WiSi x etch.
- the invention provides a design of a gate electrode stack that is easy to produce. In another aspect, the invention provides a process for the manufacturing of a gate electrode stack. The use of a gate electrode stack is also disclosed.
- a polysilicon layer and a poly-Si 1 ⁇ x Ge x layer form a GC-stack, the relative position of the layers, i.e., which is above the other one, can vary.
- the introduction of the poly-Si 1 ⁇ x Ge x layer has the effect that end-point detection can be achieved between the etching of the polysilicon layer and the poly-Si 1 ⁇ x Ge x .
- the physical mechanism for end-point detection is related to the optical emission from excited molecules, which identifies directly or indirectly Ge.
- the poly-Si 1 ⁇ x Ge x layer (x ⁇ 0.8) has similar electrical and structural properties as polysilicon and is compatible with the overall processing.
- FIGS. 1 to 6 show process steps in the manufacturing of a first embodiment of the invention
- FIG. 7 shows schematically a first embodiment of a GC-stack according to the invention
- FIG. 8 shows schematically a second embodiment of a GC-stack according to the invention.
- FIG. 9 shows schematically a third embodiment of a GC-stack according to the invention.
- FIG. 10 shows schematically a fourth embodiment of a GC-stack according to the invention.
- a W/WN/Ti/polysilicon (or WSi x /polysilicon) gate conductor stack is usually deposited by a physical vapor deposition (PVD) after gate oxide is grown on the silicon substrate.
- PVD physical vapor deposition
- a typical GC (gate conductor) structuring process then follows: the cap nitride layer is structured by lithography and nitride etch. The structured cap nitride layer is then served as a hard mask for the subsequent gate stack etch. The metal stack is first etched and a fixed time over-etch into polysilicon is then performed.
- An encapsulation liner usually silicon nitride, is deposited and structured if W/WN/Ti metal stack is used. No encapsulation liner is necessary if the WSi x is used. Finally, the remaining polysilicon is etched with end-point detection on the underlying gate oxide.
- FIGS. 1 to 6 the process steps for manufacturing a first embodiment of the invention are described.
- FIG. 1 shows a sectional view of different layers based on a substrate.
- the substrate 1 is typically a silicon wafer as used, e.g., in the production of DRAM memory chips. Alternatively, this could also be a silicon chip as used in the production of logic processors especially when self-aligned source/drain contacts are needed.
- the substrate is covered by a thin layer of gate dielectric 2 , preferably a gate oxide.
- This first embodiment will have a dual layer poly gate conductor 3 , 4 within the gate electrode stack 10 . Therefore, a polysilicon layer 3 is positioned on the gate oxide layer 2 .
- the polysilicon layer 3 has thickness in the range of 3 to 100 nm, preferably 30-50 nm.
- a poly Si 1 ⁇ x Ge x layer 4 is positioned with a thickness in the range of 3 to 100 nm, preferably 30-50 nm.
- the metal layer W/WN/Ti (or WSi x ) 5 is positioned above the Si 1 ⁇ x Ge x layer 4 .
- the Si 1 ⁇ x Ge x layer 4 and the metal layer W/WN/Ti (or WSi x ) 5 are covered with a cap layer 21 , here made of silicon nitride.
- the thickness of Ti flash layer is preferably in the range of 1 to 15 nm.
- the thickness of W/WN layer is in the range of 10-100 nm, preferably 30-50 nm. In principle, there is no strict limitation for the layer thicknesses in the usual range.
- FIG. 2 depicts the structuring of a photo resist layer 50 using a standard lithography method.
- the resist layer 50 forms the mask for a dry etching of the underneath lying cap layer 21 ( FIG. 3 ). Following this, the resist layer 50 is stripped ( FIG. 4 ).
- the metal stack with the metal stack layer 5 (W/WN/Ti) is etched and over-etch into poly Si 1 ⁇ x Ge x layer 4 is performed, while using the cap layer 21 as hard mask.
- An end-point detection is obtained when the over-etch of the poly Si 1 ⁇ x Ge x layer 4 is reaching the underlying poly-Si layer 3 . Since the etch rate of the polysilicon layer 3 is significantly lower than that of the Si 1 ⁇ x Ge x layer 4 , the polysilicon layer 3 can serve as an etch stop.
- FIG. 6 shows an encapsulation liner layer 20 , made of silicon nitride in this case.
- the liner is produced by depositing silicon nitride, which is then anisotropically etched.
- the purpose of the encapsulation liner 20 is to prevent shorts between the W/WN/Ti stack and a bitline via, which will be manufactured later. In case WSi x is used, the encapsulation liner 20 can be omitted.
- the GC etching process can detect an end-point between the Si 1 ⁇ x Ge x layer 4 and the polysilicon layer 3 . Due to the high etch selectivity between the Si 1 ⁇ x Ge x layer 4 and the polysilicon layer 3 an effective etch stop is achieved. Consequently, an improved dry etch process window can be obtained and etch uniformity and controllability can be improved.
- FIG. 8 , FIG. 9 and FIG. 10 have in principle the same structure as the first embodiment so that the above-mentioned end-point detection applies. Furthermore, the process in achieving this structure follows the same principles as discussed in connection with FIGS. 1 to 7 .
- FIG. 8 has an inverted poly stack and, therefore, an effective etch stop cannot be achieved, while the benefit of this embodiment is depicted in the following two paragraphs.
- the difference of the second embodiment ( FIG. 8 ) to the first embodiment is that the order of the layers in the dual layer gate conductor stack comprising the Si 1 ⁇ x Ge x layer 4 and the polysilicon layer 3 is inverted.
- the Si 1 ⁇ x Ge x layer 4 is positioned on the gate oxide layer 2 and the polysilicon layer 3 is positioned on top of the Si 1 ⁇ x Ge x layer 4 .
- this embodiment has a Si 1 ⁇ x Ge x layer 4 /gate oxide layer 2 interface, the p-type poly gate depletion is improved. This effect is described in connection with a very specific gate dielectric in the article by Lu et al. “Improved Performance of Ultra-Thin HfO 2 CMOSFETs Using Poly-SiGe Gates”, IEEE 2002 Symposium on VLSI Technology, which article is incorporated herein by reference.
- the third embodiment ( FIG. 9 ) and fourth embodiment ( FIG. 10 ) utilize a laminate with a triple GC stack and a quadruple GC stack respectively.
- the third embodiment has a triple layer structure (from bottom up):
- the thicknesses of the layers are 3-100, 3-100 and 3-100 nm, respectively.
- This embodiment keeps the benefits from the first embodiment, while the interface between the poly and metal stack is still Ti/Si instead of Ti/Si 1 ⁇ x Ge x as is the case in the first embodiment. This removes the possible risk due to complicated Ti ⁇ Si 1 ⁇ x Ge x interaction.
- the fourth embodiment depicted in FIG. 10 has a quadruple GC stack, with the following layering:
- the thicknesses of the layers are 3-100, 3-100, 3-100 and 3-100 nm, respectively. (Again there is no strict limitation.)
- This embodiment inherits the benefits from the second and third embodiment, while enabling the possibility to trim poly gate length.
- the trimming can be realized by isotropic etching of the poly Si 1 ⁇ x Ge x layer 41 , which is selective to the polysilicon layer 31 and the underlying gate oxide layer 2 .
- the process flow for producing the embodiments is similar to the case of metal/polysilicon gate stack, which is described earlier.
- the main difference lies in the metal stack over-etch into the polysilicon.
- the poly-Si 1 ⁇ x Ge x layer is etched during the metal stack over-etch.
- the end-point signal can be observed when poly-Si 1 ⁇ x Ge x layer is etched away and the underlying polysilicon starts to be etched. Since the dry etch rate of polysilicon is usually much lower than that of the Si 1 ⁇ x Ge x layer, the polysilicon layer can serve as an etch stop.
- the improvement of the gate electrode in terms of uniformity and controllability can therefore be obtained because of the capability of an end-point detection during metal over-etch into the poly layer and the etch rate difference between the poly Si 1 ⁇ x Ge x and polysilicon layers.
- One application for an embodiment of the invention is a dual workfunction DRAM.
Abstract
A gate electrode stack is disposed on a substrate in a semiconductor device. A gate conductor includes at least one layer of polysilicon and at least one layer of poly-Si1−x,Gex material. The invention is also concerned with a process. This structure can be etched effectively since an end point detection is enabled.
Description
- This invention relates generally to a gate electrode stack and the use of the gate conductor stack.
- A gate electrode stack in a conventional DRAM device can comprise the following layers (from substrate (bottom) up):
-
- Silicon (usually substrate material)
- Gate oxide
- Polysilicon (e.g. N+ doped or P+ doped)
- W/WN/Ti or WSix
- Cap and/or encapsulation layer
- The polysilicon layer and the W/WN/Ti (or other materials such as WSix) layer comprise the gate conductor (GC) stack in the gate electrode stack. A thin Ti flash layer in the W/WN/Ti metal stack is used to guarantee good contact properties between the metal stack and the polysilicon layer, since Ti silicide is formed at the interface after full processing.
- In principle such a gate electrode stack is described in U.S. Pat. No. 6,716,734 B2, which is incorporated herein by reference.
- The etching of a GC stack is challenging since after the etching of the metal stack, an over-etch into the polysilicon layer must be performed. This over-etch is difficult to control since the end-point of the over-etch is primarily controllable only through fixed time. There is no end-point signal generated when the over-etch is performed into the polysilicon layer.
- Typical etch chemistries for plasma dry-etching of a W/WN/Ti stack are Cl2, NF3, O2 and HBr, which are quite aggressive chemistries, while Cl2, O2 and NF3 are typically used etch chemistries for WiSix etch.
- In one aspect, the invention provides a design of a gate electrode stack that is easy to produce. In another aspect, the invention provides a process for the manufacturing of a gate electrode stack. The use of a gate electrode stack is also disclosed.
- Within the gate electrode stack, according to embodiments of the invention, a polysilicon layer and a poly-Si1−xGex layer form a GC-stack, the relative position of the layers, i.e., which is above the other one, can vary. The introduction of the poly-Si1−xGex layer has the effect that end-point detection can be achieved between the etching of the polysilicon layer and the poly-Si1−xGex. The physical mechanism for end-point detection is related to the optical emission from excited molecules, which identifies directly or indirectly Ge. The poly-Si1−xGex layer (x<0.8) has similar electrical and structural properties as polysilicon and is compatible with the overall processing.
- Properties of poly-SiGe and utilization of poly-SiGe as a gate material can be referred to Dongping Wu's PhD thesis ‘Novel concepts for advanced CMOS: Materials, process and device architecture’ (ISRN KTH/EKT/FR-2004/3-SE and ISSN 1650-8599), which thesis is incorporated herein by reference.
- Given the GC-stack according to embodiments of the invention it is possible to reduce the total thickness of the poly layers. Furthermore this improves the uniformity of the etch process.
- Other features and advantages of the invention become apparent upon reading of the detailed description of the invention, and the appended claims provided below, and upon reference to the drawings.
- For a more complete understanding of the present invention, and the advantages thereof, reference is now made to the following descriptions taken in conjunction with the accompanying drawing, in which:
- FIGS. 1 to 6 show process steps in the manufacturing of a first embodiment of the invention;
-
FIG. 7 shows schematically a first embodiment of a GC-stack according to the invention; -
FIG. 8 shows schematically a second embodiment of a GC-stack according to the invention; -
FIG. 9 shows schematically a third embodiment of a GC-stack according to the invention; and -
FIG. 10 shows schematically a fourth embodiment of a GC-stack according to the invention. - In a conventional DRAM fabrication process, it is known that a W/WN/Ti/polysilicon (or WSix/polysilicon) gate conductor stack is usually deposited by a physical vapor deposition (PVD) after gate oxide is grown on the silicon substrate. An insulation cap, which is usually nitride, is then deposited atop. A typical GC (gate conductor) structuring process then follows: the cap nitride layer is structured by lithography and nitride etch. The structured cap nitride layer is then served as a hard mask for the subsequent gate stack etch. The metal stack is first etched and a fixed time over-etch into polysilicon is then performed. An encapsulation liner, usually silicon nitride, is deposited and structured if W/WN/Ti metal stack is used. No encapsulation liner is necessary if the WSix is used. Finally, the remaining polysilicon is etched with end-point detection on the underlying gate oxide.
- In the following FIGS. 1 to 6 the process steps for manufacturing a first embodiment of the invention are described.
-
FIG. 1 shows a sectional view of different layers based on a substrate. Thesubstrate 1 is typically a silicon wafer as used, e.g., in the production of DRAM memory chips. Alternatively, this could also be a silicon chip as used in the production of logic processors especially when self-aligned source/drain contacts are needed. - The substrate is covered by a thin layer of gate dielectric 2, preferably a gate oxide.
- This first embodiment will have a dual layer
poly gate conductor gate electrode stack 10. Therefore, apolysilicon layer 3 is positioned on thegate oxide layer 2. Thepolysilicon layer 3 has thickness in the range of 3 to 100 nm, preferably 30-50 nm. On the polysilicon layer 3 a poly Si1−xGex layer 4 is positioned with a thickness in the range of 3 to 100 nm, preferably 30-50 nm. - Above the Si1−xGex layer 4 the metal layer W/WN/Ti (or WSix) 5 is positioned. The Si1−xGex
layer 4 and the metal layer W/WN/Ti (or WSix) 5 are covered with acap layer 21, here made of silicon nitride. - The thickness of Ti flash layer is preferably in the range of 1 to 15 nm. The thickness of W/WN layer is in the range of 10-100 nm, preferably 30-50 nm. In principle, there is no strict limitation for the layer thicknesses in the usual range.
- The next step (
FIG. 2 ) depicts the structuring of aphoto resist layer 50 using a standard lithography method. Theresist layer 50 forms the mask for a dry etching of the underneath lying cap layer 21 (FIG. 3 ). Following this, theresist layer 50 is stripped (FIG. 4 ). - Now (
FIG. 5 ) the metal stack with the metal stack layer 5 (W/WN/Ti) is etched and over-etch into poly Si1−xGex layer 4 is performed, while using thecap layer 21 as hard mask. An end-point detection is obtained when the over-etch of the poly Si1−xGex layer 4 is reaching the underlying poly-Si layer 3. Since the etch rate of thepolysilicon layer 3 is significantly lower than that of the Si1−xGex layer 4, thepolysilicon layer 3 can serve as an etch stop. -
FIG. 6 shows anencapsulation liner layer 20, made of silicon nitride in this case. The liner is produced by depositing silicon nitride, which is then anisotropically etched. The purpose of theencapsulation liner 20 is to prevent shorts between the W/WN/Ti stack and a bitline via, which will be manufactured later. In case WSix is used, theencapsulation liner 20 can be omitted. - Finally a polysilicon etch is performed using the
cap layer 21 as hard mask (FIG. 7 ). The etching is stopped on thegate oxide layer 2. - Given this first embodiment the GC etching process can detect an end-point between the Si1−xGex layer 4 and the
polysilicon layer 3. Due to the high etch selectivity between the Si1−xGex layer 4 and thepolysilicon layer 3 an effective etch stop is achieved. Consequently, an improved dry etch process window can be obtained and etch uniformity and controllability can be improved. - The other embodiments, depicted in
FIG. 8 ,FIG. 9 andFIG. 10 have in principle the same structure as the first embodiment so that the above-mentioned end-point detection applies. Furthermore, the process in achieving this structure follows the same principles as discussed in connection with FIGS. 1 to 7. -
FIG. 8 has an inverted poly stack and, therefore, an effective etch stop cannot be achieved, while the benefit of this embodiment is depicted in the following two paragraphs. - The difference of the second embodiment (
FIG. 8 ) to the first embodiment is that the order of the layers in the dual layer gate conductor stack comprising the Si1−xGex layer 4 and thepolysilicon layer 3 is inverted. The Si1−xGex layer 4 is positioned on thegate oxide layer 2 and thepolysilicon layer 3 is positioned on top of the Si1−xGex layer 4. - Since this embodiment has a Si1−xGex layer 4/
gate oxide layer 2 interface, the p-type poly gate depletion is improved. This effect is described in connection with a very specific gate dielectric in the article by Lu et al. “Improved Performance of Ultra-Thin HfO2 CMOSFETs Using Poly-SiGe Gates”, IEEE 2002 Symposium on VLSI Technology, which article is incorporated herein by reference. - The third embodiment (
FIG. 9 ) and fourth embodiment (FIG. 10 ) utilize a laminate with a triple GC stack and a quadruple GC stack respectively. - The third embodiment has a triple layer structure (from bottom up):
-
-
first polysilicon layer 31 on thegate oxide layer 2 - Si1−xGex layer 4 on the
first polysilicon layer 31 -
second polysilicon layer 32 on the Si1−xGex layer 4.
-
- The thicknesses of the layers are 3-100, 3-100 and 3-100 nm, respectively.
- This embodiment keeps the benefits from the first embodiment, while the interface between the poly and metal stack is still Ti/Si instead of Ti/Si1−xGex as is the case in the first embodiment. This removes the possible risk due to complicated Ti−Si1−xGex interaction.
- The fourth embodiment depicted in
FIG. 10 has a quadruple GC stack, with the following layering: -
-
first polysilicon layer 31 on the first Si1−xGex layer 41 - second Si1−xGex layer 42 on the
first polysilicon layer 31 -
second polysilicon layer 32 on the second Si1−xGex layer 42.
-
- The thicknesses of the layers are 3-100, 3-100, 3-100 and 3-100 nm, respectively. (Again there is no strict limitation.)
- This embodiment inherits the benefits from the second and third embodiment, while enabling the possibility to trim poly gate length. The trimming can be realized by isotropic etching of the poly Si1−xGex layer 41, which is selective to the
polysilicon layer 31 and the underlyinggate oxide layer 2. - In general the process flow for producing the embodiments is similar to the case of metal/polysilicon gate stack, which is described earlier. The main difference lies in the metal stack over-etch into the polysilicon. Taking the first embodiment as an example: the poly-Si1−xGex layer is etched during the metal stack over-etch. The end-point signal can be observed when poly-Si1−xGex layer is etched away and the underlying polysilicon starts to be etched. Since the dry etch rate of polysilicon is usually much lower than that of the Si1−xGex layer, the polysilicon layer can serve as an etch stop. The improvement of the gate electrode in terms of uniformity and controllability can therefore be obtained because of the capability of an end-point detection during metal over-etch into the poly layer and the etch rate difference between the poly Si1−xGex and polysilicon layers.
- One application for an embodiment of the invention is a dual workfunction DRAM.
Claims (20)
1. A gate electrode stack on a substrate in a semiconductor device comprising a gate conductor with:
at least one layer of polysilicon; and
at least one layer of poly-Si1−xGex material.
2. The gate electrode stack according to claim 1 , further comprising at least one layer of metal gate material above the gate conductor.
3. The gate electrode stack according to claim 1 , wherein the gate conductor comprises a dual layer gate conductor stack with:
one polysilicon layer; and
one poly-Si1−xGex layer positioned on the polysilicon layer.
4. The gate electrode stack according to claim 1 , wherein the gate conductor comprises a dual layer gate conductor stack with:
one Poly-Si1−xGex layer; and
one polysilicon layer positioned on the poly-Si1−xGex layer.
5. The gate electrode stack according to claim 1 , wherein the gate conductor comprises a triple layer gate conductor stack with:
a first polysilicon layer;
a poly-Si1−xGex layer positioned on the first polysilicon layer; and
a second polysilicon layer positioned on the poly-Si1−xGex layer.
6. The gate electrode stack according to claim 1 , wherein the gate conductor comprises a quadruple layer gate conductor stack with:
a first poly-Si1−xGex layer;
a first polysilicon layer positioned on the first poly-Si1−xGex layer;
a second poly-Si1−xGex layer positioned on the polysilicon layer; and
a second polysilicon layer positioned on the second poly-Si1−xGex layer.
7. The gate electrode stack according to claim 1 , wherein the gate conductor includes a poly-silicon layer with a thickness greater than 1 nm.
8. The gate electrode stack according to claim 7 , wherein the gate conductor includes a poly-silicon layer with a thickness greater than 3 nm.
9. The gate electrode stack according to claim 1 , wherein the gate conductor comprises a poly-Si1−xGex layer with a thickness greater than 3 nm.
10. The gate electrode stack according to claim 2 , wherein the metal gate material comprises at least one material selected from the group consisting of W/WN/Ti and WSix.
11. The gate electrode stack according to claim 1 , wherein the Si1−xGex x is less than 0.8 in the layer of poly-Si1−xGex.
12. The gate electrode stack according to claim 1 , wherein the gate conductor overlies a silicon substrate.
13. The gate electrode stack according to claim 1 , further comprising at least one encapsulation liner at least partially covering the gate conductor.
14. The gate conductor stack according to claim 1 , further comprising a gate oxide layer overlying the substrate, wherein the gate conductor overlies the gate oxide layer.
15. The gate conductor stack according to claim 1 , wherein the gate conductor is part of a memory chip.
16. The gate conductor stack according to claim 1 , wherein the memory chip comprises a DRAM chip.
17. The gate conductor stack according to claim 1 , wherein the gate conductor is part of a semiconductor logic device.
18. A method for producing a semiconductor device, the method comprising:
depositing a stack that comprises at least one layer of polysilicon and at least one layer of poly-Si1−xGex material;
performing a dry etching on the at least one layer of polysilicon and at least one layer of poly-Si1−xGex material, wherein an over-etch into the lower lying layer of polysilicon or poly-Si1−xGex material is performed, this over-etch being used as an end-point detection for the process.
19. The method according to claim 18 , further comprising a metal layer over the stack.
20. The method according to claim 18 , further comprising depositing a hard mask layer over the stack, wherein the dry etching is performed using the hard mask as a mask.
Priority Applications (4)
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US11/101,378 US20060226473A1 (en) | 2005-04-07 | 2005-04-07 | Gate electrode stack and use of a gate electrode stack |
TW095112268A TW200711134A (en) | 2005-04-07 | 2006-04-06 | Gate electrode stack and use of a gate electrode stack |
JP2006105042A JP2006295170A (en) | 2005-04-07 | 2006-04-06 | Gate electrode lamination and method using gate electrode lamination |
CNA2006100743419A CN1845336A (en) | 2005-04-07 | 2006-04-07 | Gate electrode stack and use of a gate electrode stack |
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US11/101,378 US20060226473A1 (en) | 2005-04-07 | 2005-04-07 | Gate electrode stack and use of a gate electrode stack |
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US11/101,378 Abandoned US20060226473A1 (en) | 2005-04-07 | 2005-04-07 | Gate electrode stack and use of a gate electrode stack |
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JP (1) | JP2006295170A (en) |
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US8268712B2 (en) | 2010-05-27 | 2012-09-18 | United Microelectronics Corporation | Method of forming metal gate structure and method of forming metal gate transistor |
Citations (2)
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US6716734B2 (en) * | 2001-09-28 | 2004-04-06 | Infineon Technologies Ag | Low temperature sidewall oxidation of W/WN/poly-gatestack |
US20050151165A1 (en) * | 2004-01-06 | 2005-07-14 | International Business Machines Corporation | Structure and method of making heterojunction bipolar transistor having self-aligned silicon-germanium raised extrinsic base |
-
2005
- 2005-04-07 US US11/101,378 patent/US20060226473A1/en not_active Abandoned
-
2006
- 2006-04-06 TW TW095112268A patent/TW200711134A/en unknown
- 2006-04-06 JP JP2006105042A patent/JP2006295170A/en not_active Abandoned
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Patent Citations (2)
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US6716734B2 (en) * | 2001-09-28 | 2004-04-06 | Infineon Technologies Ag | Low temperature sidewall oxidation of W/WN/poly-gatestack |
US20050151165A1 (en) * | 2004-01-06 | 2005-07-14 | International Business Machines Corporation | Structure and method of making heterojunction bipolar transistor having self-aligned silicon-germanium raised extrinsic base |
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CN1845336A (en) | 2006-10-11 |
TW200711134A (en) | 2007-03-16 |
JP2006295170A (en) | 2006-10-26 |
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