US20050124508A1 - Compositions for improved friction durability in power transmission fluids - Google Patents
Compositions for improved friction durability in power transmission fluids Download PDFInfo
- Publication number
- US20050124508A1 US20050124508A1 US10/727,950 US72795003A US2005124508A1 US 20050124508 A1 US20050124508 A1 US 20050124508A1 US 72795003 A US72795003 A US 72795003A US 2005124508 A1 US2005124508 A1 US 2005124508A1
- Authority
- US
- United States
- Prior art keywords
- steel
- thiadiazole
- fluid
- amount
- transmission
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 0 *CSc1nnc(SC*)s1 Chemical compound *CSc1nnc(SC*)s1 0.000 description 3
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
- C10M169/04—Mixtures of base-materials and additives
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16H—GEARING
- F16H57/00—General details of gearing
- F16H57/04—Features relating to lubrication or cooling or heating
- F16H57/041—Coatings or solid lubricants, e.g. antiseize layers or pastes
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M135/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing sulfur, selenium or tellurium
- C10M135/32—Heterocyclic sulfur, selenium or tellurium compounds
- C10M135/36—Heterocyclic sulfur, selenium or tellurium compounds the ring containing sulfur and carbon with nitrogen or oxygen
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/10—Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring
- C10M2219/104—Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring containing sulfur and carbon with nitrogen or oxygen in the ring
- C10M2219/106—Thiadiazoles
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/04—Oil-bath; Gear-boxes; Automatic transmissions; Traction drives
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/04—Oil-bath; Gear-boxes; Automatic transmissions; Traction drives
- C10N2040/045—Oil-bath; Gear-boxes; Automatic transmissions; Traction drives for continuous variable transmission [CVT]
Definitions
- the present invention relates to transmission fluid compositions and methods for use in transmissions having steel-on-steel contact. Further, the present invention relates to compositions and methods for improving steel-on-steel friction.
- CVTs continuously variable transmissions
- CVTs may contain a steel push-belt, chain and pulley assembly, or disk assembly (in the case of toroidal CVTs), in combination with a torque converter or some other form of a start-up device.
- Torque is transmitted through metal-metal contact between the pulley and the belt or chain or disk.
- Efficient transmission of torque requires relatively high steel-on-steel friction with minimal wear between, for example, the belt and pulley or chain and the pulley. Low friction can lead to belt slippage or even catastrophic wear.
- Steel-on-steel friction is therefore a critical requirement for transmission of torque, and thus, compositions and methods for improving steel-on-steel friction are increasingly desirable.
- a power transmitting fluid for use in a transmission having steel-on-steel contact may comprise a major amount of a base oil and at least one thiadiazole or derivative thereof, wherein the fluid has improved steel-on-steel friction properties.
- the thiadiazole may be present in an amount of about 0.05 wt % or more.
- a continuously variable transmission may be lubricated with a fluid as described herein.
- a method of lubricating a transmission having steel-on-steel contact may comprise adding to, and operating in, the transmission a fluid as described herein.
- an additive composition for use in a transmission having steel-on-steel contact may comprise at least one thiadiazole or derivative thereof, wherein the fluid has improved steel-on-steel friction.
- the thiadiazole may be present in an amount of about 0.05 wt % or more.
- a method of making a power transmitting fluid having steel-on-steel friction-improving capabilities may comprise adding to a major amount of a base oil a thiadiazole or derivative thereof in an amount of about 0.05 wt % or more.
- a power transmitting fluid for use in a transmission having a steel-on-steel contact may comprise a major amount of a base oil and at least one thiadiazole or derivative thereof present in an amount sufficient to provide a coefficient of friction of about 0.085 or greater in a steel-on-steel application.
- compositions and methods that optimize performance requirements for steel-on-steel friction Compositions and methods for using thiadiazoles to improve steel-on-steel friction are presented herein, providing an improved delivery of high steel-on-steel friction.
- a power transmitting fluid according to the present disclosure may be used in a transmission having a steel-on-steel contact.
- suitable transmissions may include various types of continuously variable transmissions (CVTs), such as push-belt, chain, and disk-type CVTs.
- CVTs continuously variable transmissions
- other such transmissions may include automated manuals, manual transmissions, or dual clutch assemblies.
- Power transmitting fluids may comprise at least one thiadiazole or derivative thereof.
- Suitable thiadiazoles or derivatives thereof may include thiadiazole, alkylated thiadiazoles, mono- and/or di-substituted thiadiazoles, as well as mercapto- and other substituted thiadiazoles, such as (a) 2-hydrocarbyldithio-5-mercapto-1,3,4-thiadiazole or 2,5-bis-(hydrocarbyldithio)-1,3,4-thiadiazole and mixtures thereof; (b) 2-hydrocarbylthio-5-mercapto-1,3,4-thiadiazole; and (c) products from combining an oil soluble dispersant with 2,5-dimercapto-1,3,4-thiadiazole (DMTD); and mixtures thereof.
- DMTD 2,5-dimercapto-1,3,4-thiadiazole
- 2,5-bis-(hydrocarbyldithio)-1,3,4-thiadiazole and its mono-substituted equivalent 2-hydrocarbylthio-5-mercapto-1,3,4-thiadiazole are commercially available as a mixture of the two compounds in a ratio of about 85 percent bis-hydrocarbyl to about 15 percent monohydrocarbyl from the Ethyl Corporation as HiTECTM 4313 performance additive.
- U.S. Pat. Nos. 2,719,125; 2,719,126; and 3,087,937 describe the preparation of various 2,5-bis(hydrocarbyl dithio)-1,3,4-thiadiazoles, that is, wherein each hydrocarbyl group can be linked to the thiadiazole through multiple (e.g., 2) sulfur atoms.
- the hydrocarbon group may be aliphatic or aromatic, including cyclic, alicyclic, aralkyl, aryl, and alkaryl.
- Such compositions are effective corrosion-inhibitors for silver, copper, silver alloys and similar metals.
- Such polysulfides which can be represented by the following general formula: wherein R and R′ may be the same or different hydrocarbon groups, and x and y be integers from 0 to about 8, and the sum of x and y being at least 1.
- a process for preparing such derivatives is described in U.S. Pat. No. 2,191,125 and comprising the reaction of DMTD with a suitable sulfenyl chloride or by reacting the dimercapto thiadiazole with chlorine and reacting the resulting disulfenyl chloride with a primary or tertiary mercaptan.
- DMTD is chlorinated to form the desired bissulfenyl chloride which is then reacted with at least one mercaptan (RSH and/or R′ SH).
- RSH and/or R′ SH mercaptan
- U.S. Pat. No. 3,087,932 describes a one-step process for preparing 2,5-bis(hydrocarbyldithio)-1,3,4-thiadiazole. Compositions prepared in this manner are described in U.S. Pat. No. 2,749,311. It will be understood by those skilled in the art that the reactions referenced and described above may produce some amounts of the monohydrocarbyldithio-thiadiazole as well as the bis-hydrocarbyl compounds. The ratio of the two can be adjusted by varying the amounts of the reactants.
- a peroxy compound, hypohalide, or air, or mixtures thereof, can be utilized to promote the oxidative coupling.
- the mono-mercaptan include methyl mercaptan, isopropyl mercaptan, hexyl mercaptan, decyl mercaptan, and long chain alkyl mercaptans, for example, mercaptans derived from propene polymers and isobutylene polymers especially polyisobutylenes, having about 3 to about 70 propene or isobutylene units per molecule.
- the thiadiazole or derivative thereof may be present in an amount of about 0.05 wt % or more. As a further example, the thiadiazole may be present in an amount of about 0.095 wt % to about 5 wt %, or in an amount of about 0.095 wt % to about 1 wt %, or in an amount of about 0.3 wt % to about 0.5 wt %. Further, the thiadiazole or derivative thereof may be present in an amount sufficient to provide a coefficient of friction of about 0.085 or greater in a steel-on-steel application. As a further example, the thiadiazole or derivative thereof may be present in an amount sufficient to provide a coefficient of friction of about 0.09 or greater in a steel-on-steel application.
- the embodiments of the present disclosure may provide a fluid or additive composition that has improved steel-on-steel properties. Such properties may be compared to a fluid comprising less than the disclosed amount of thiadiazole or derivative thereof.
- the thiadiazole may be directly added to a power transmission fluid to improve steel-on-steel friction.
- a process for preparing the transmission fluid additives of the present invention may comprise combining in any sequence a thiadiazole with a transmission fluid at room temperature.
- Embodiments of the present invention may comprise a major amount of a base oil.
- Base or lubricating oils contemplated in preparing the power transmission fluids of the present invention may be derived from natural lubricating oils, synthetic lubricating oils, and mixtures thereof. Further, the base oil may comprise any suitable base oil or mixture of base oils for a particular application.
- additives may be provided in an additive package concentrate. Further, some embodiments may comprise a diluent, e.g., a diluent oil. A diluent may be included to ease blending, solubilizing, and transporting the additive package. The diluent may be compatible with a base oil and/or the additive package. The diluent may be present in any suitable amount in the concentrate.
- a suitable diluent may comprise a process oil of lubricating viscosity.
- the base oil may comprise a mineral oil, mixture of mineral oils, a synthetic oil, mixture of synthetic oils, or mixtures thereof.
- Suitable base oils may comprise a Group I, Group II, Group III, Group IV, or Group V base stock. Suitable base oils may be manufactured from the gas-to-liquid process.
- the lubricating fluids of the present invention may include other optional components. These may include, for example, one or more of an extreme pressure agent; an antiwear agent; an antioxidant or an antioxidant system, such as an amine antioxidant or phenolic antioxidant; a corrosion inhibitor or a corrosion inhibitor system; a metal deactivator; an anti-rust agent; a friction modifier; a dispersant; a detergent; a dye; a seal swell agent; an anti-foam agent; a surfactant; a viscosity index improver; a perfume or odor mask; and any suitable combinations thereof.
- an extreme pressure agent an antiwear agent
- an antioxidant or an antioxidant system such as an amine antioxidant or phenolic antioxidant
- a corrosion inhibitor or a corrosion inhibitor system such as an amine antioxidant or phenolic antioxidant
- a corrosion inhibitor or a corrosion inhibitor system such as an amine antioxidant or phenolic antioxidant
- a corrosion inhibitor or a corrosion inhibitor system such as an amine antioxidant or phenolic antioxidant
- friction modifiers may be routinely added to lubricating fluids
- the particular type and amount of friction modifier is unique and specific to the needs of each particular application.
- the embodiments of the present invention have been found to be effective when used in conjunction with a variety of these additives.
- nitrogen-containing ashless dispersants are well known as supplemental lubricating oil additives.
- Suitable ashless dispersants that may be used in the present invention include hydrocarbyl succinimides, hydrocarbyl succinamides, mixed ester/amides of hydrocarbyl-substituted succinic acid, hydroxyesters of hydrocarbyl-substituted succinic acid, and Mannich condensation products of hydrocarbyl-substituted phenols, formaldehyde and amines.
- condensation products of polyamines and hydrocarbyl-substituted phenyl acids are also be used.
- Table 1 The data shown in Table 1 was acquired using a push-belt CVT dynamometer test developed by Van Doome Transmissie. Table 1 shows steel-on-steel friction results measured at low pulley ratios for two different concentrations of thiadiazole. The standard deviation of measurement at the low ratio was 0.0016, which was established through reference runs taken over an extended period of time with a reference fluid, as recommended by Van Doorne.
- the present disclosure thus provides a composition for increasing steel-on-steel friction using thiadiazole or a derivative thereof.
- the compositions and methods described herein will allow the formulation of transmission fluids with applications in continuously variable transmissions as well as conventional automatic transmissions and with different kinds of start-up clutches.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- General Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Mechanical Engineering (AREA)
- Lubricants (AREA)
- General Details Of Gearings (AREA)
Abstract
Description
- The present invention relates to transmission fluid compositions and methods for use in transmissions having steel-on-steel contact. Further, the present invention relates to compositions and methods for improving steel-on-steel friction.
- There has been a steady growth in the number of automobile manufacturers using or planning to use continuously variable transmissions (CVTs) in place of conventional automatic transmissions. CVTs have been shown to impart improved fuel efficiency and driving performance as well as reduced emissions compared to conventional automatic transmissions.
- CVTs may contain a steel push-belt, chain and pulley assembly, or disk assembly (in the case of toroidal CVTs), in combination with a torque converter or some other form of a start-up device. Torque is transmitted through metal-metal contact between the pulley and the belt or chain or disk. Efficient transmission of torque requires relatively high steel-on-steel friction with minimal wear between, for example, the belt and pulley or chain and the pulley. Low friction can lead to belt slippage or even catastrophic wear. Steel-on-steel friction is therefore a critical requirement for transmission of torque, and thus, compositions and methods for improving steel-on-steel friction are increasingly desirable.
- In an embodiment, a power transmitting fluid for use in a transmission having steel-on-steel contact may comprise a major amount of a base oil and at least one thiadiazole or derivative thereof, wherein the fluid has improved steel-on-steel friction properties. The thiadiazole may be present in an amount of about 0.05 wt % or more.
- In another embodiment, a continuously variable transmission may be lubricated with a fluid as described herein.
- In another embodiment, a method of lubricating a transmission having steel-on-steel contact may comprise adding to, and operating in, the transmission a fluid as described herein.
- In another embodiment, an additive composition for use in a transmission having steel-on-steel contact may comprise at least one thiadiazole or derivative thereof, wherein the fluid has improved steel-on-steel friction. The thiadiazole may be present in an amount of about 0.05 wt % or more.
- In another embodiment, a method of making a power transmitting fluid having steel-on-steel friction-improving capabilities may comprise adding to a major amount of a base oil a thiadiazole or derivative thereof in an amount of about 0.05 wt % or more.
- In another embodiment, a power transmitting fluid for use in a transmission having a steel-on-steel contact may comprise a major amount of a base oil and at least one thiadiazole or derivative thereof present in an amount sufficient to provide a coefficient of friction of about 0.085 or greater in a steel-on-steel application.
- The present disclosure describes compositions and methods that optimize performance requirements for steel-on-steel friction. Compositions and methods for using thiadiazoles to improve steel-on-steel friction are presented herein, providing an improved delivery of high steel-on-steel friction.
- In an embodiment, a power transmitting fluid according to the present disclosure may be used in a transmission having a steel-on-steel contact. Such suitable transmissions may include various types of continuously variable transmissions (CVTs), such as push-belt, chain, and disk-type CVTs. Further, other such transmissions may include automated manuals, manual transmissions, or dual clutch assemblies.
- Power transmitting fluids according to the present disclosure may comprise at least one thiadiazole or derivative thereof. Suitable thiadiazoles or derivatives thereof may include thiadiazole, alkylated thiadiazoles, mono- and/or di-substituted thiadiazoles, as well as mercapto- and other substituted thiadiazoles, such as (a) 2-hydrocarbyldithio-5-mercapto-1,3,4-thiadiazole or 2,5-bis-(hydrocarbyldithio)-1,3,4-thiadiazole and mixtures thereof; (b) 2-hydrocarbylthio-5-mercapto-1,3,4-thiadiazole; and (c) products from combining an oil soluble dispersant with 2,5-dimercapto-1,3,4-thiadiazole (DMTD); and mixtures thereof.
- 2,5-bis-(hydrocarbyldithio)-1,3,4-thiadiazole and its mono-substituted equivalent 2-hydrocarbylthio-5-mercapto-1,3,4-thiadiazole are commercially available as a mixture of the two compounds in a ratio of about 85 percent bis-hydrocarbyl to about 15 percent monohydrocarbyl from the Ethyl Corporation as HiTEC™ 4313 performance additive.
- U.S. Pat. Nos. 2,719,125; 2,719,126; and 3,087,937 describe the preparation of various 2,5-bis(hydrocarbyl dithio)-1,3,4-thiadiazoles, that is, wherein each hydrocarbyl group can be linked to the thiadiazole through multiple (e.g., 2) sulfur atoms. The hydrocarbon group may be aliphatic or aromatic, including cyclic, alicyclic, aralkyl, aryl, and alkaryl. Such compositions are effective corrosion-inhibitors for silver, copper, silver alloys and similar metals. Such polysulfides which can be represented by the following general formula:
wherein R and R′ may be the same or different hydrocarbon groups, and x and y be integers from 0 to about 8, and the sum of x and y being at least 1. A process for preparing such derivatives is described in U.S. Pat. No. 2,191,125 and comprising the reaction of DMTD with a suitable sulfenyl chloride or by reacting the dimercapto thiadiazole with chlorine and reacting the resulting disulfenyl chloride with a primary or tertiary mercaptan. In another procedure, DMTD is chlorinated to form the desired bissulfenyl chloride which is then reacted with at least one mercaptan (RSH and/or R′ SH). U.S. Pat. No. 3,087,932 describes a one-step process for preparing 2,5-bis(hydrocarbyldithio)-1,3,4-thiadiazole. Compositions prepared in this manner are described in U.S. Pat. No. 2,749,311. It will be understood by those skilled in the art that the reactions referenced and described above may produce some amounts of the monohydrocarbyldithio-thiadiazole as well as the bis-hydrocarbyl compounds. The ratio of the two can be adjusted by varying the amounts of the reactants. - The preparation of 2-hydrocarbyldithio-5-mercapto-1,3,4-thiadiazoles having the formula:
where R′ is a hydrocarbyl substituent, is described in U.S. Pat. No. 3,663,561. The compositions are prepared by the oxidative coupling of equimolecular portions of a hydrocarbyl mercaptan and DMTD or its alkali metal mercaptide. The compositions are reported to be excellent sulfur scavengers and are useful in preventing copper corrosion by active sulfur. The mono-mercaptans used in the preparation of the compounds are represented by the formula R′ SH wherein R′ is a hydrocarbyl group containing from about 1 to about 28 carbon atoms. A peroxy compound, hypohalide, or air, or mixtures thereof, can be utilized to promote the oxidative coupling. Specific examples of the mono-mercaptan include methyl mercaptan, isopropyl mercaptan, hexyl mercaptan, decyl mercaptan, and long chain alkyl mercaptans, for example, mercaptans derived from propene polymers and isobutylene polymers especially polyisobutylenes, having about 3 to about 70 propene or isobutylene units per molecule. - The thiadiazole or derivative thereof may be present in an amount of about 0.05 wt % or more. As a further example, the thiadiazole may be present in an amount of about 0.095 wt % to about 5 wt %, or in an amount of about 0.095 wt % to about 1 wt %, or in an amount of about 0.3 wt % to about 0.5 wt %. Further, the thiadiazole or derivative thereof may be present in an amount sufficient to provide a coefficient of friction of about 0.085 or greater in a steel-on-steel application. As a further example, the thiadiazole or derivative thereof may be present in an amount sufficient to provide a coefficient of friction of about 0.09 or greater in a steel-on-steel application.
- The embodiments of the present disclosure may provide a fluid or additive composition that has improved steel-on-steel properties. Such properties may be compared to a fluid comprising less than the disclosed amount of thiadiazole or derivative thereof.
- In an embodiment of the present invention, the thiadiazole may be directly added to a power transmission fluid to improve steel-on-steel friction. A process for preparing the transmission fluid additives of the present invention may comprise combining in any sequence a thiadiazole with a transmission fluid at room temperature.
- Base Oils
- Embodiments of the present invention may comprise a major amount of a base oil. Base or lubricating oils contemplated in preparing the power transmission fluids of the present invention may be derived from natural lubricating oils, synthetic lubricating oils, and mixtures thereof. Further, the base oil may comprise any suitable base oil or mixture of base oils for a particular application. In some embodiments, additives may be provided in an additive package concentrate. Further, some embodiments may comprise a diluent, e.g., a diluent oil. A diluent may be included to ease blending, solubilizing, and transporting the additive package. The diluent may be compatible with a base oil and/or the additive package. The diluent may be present in any suitable amount in the concentrate. A suitable diluent may comprise a process oil of lubricating viscosity.
- The base oil may comprise a mineral oil, mixture of mineral oils, a synthetic oil, mixture of synthetic oils, or mixtures thereof. Suitable base oils may comprise a Group I, Group II, Group III, Group IV, or Group V base stock. Suitable base oils may be manufactured from the gas-to-liquid process.
- Other Components
- In addition to formulations and methods employing a thiadiazole to improve steel-on-steel friction, the lubricating fluids of the present invention may include other optional components. These may include, for example, one or more of an extreme pressure agent; an antiwear agent; an antioxidant or an antioxidant system, such as an amine antioxidant or phenolic antioxidant; a corrosion inhibitor or a corrosion inhibitor system; a metal deactivator; an anti-rust agent; a friction modifier; a dispersant; a detergent; a dye; a seal swell agent; an anti-foam agent; a surfactant; a viscosity index improver; a perfume or odor mask; and any suitable combinations thereof. For example, while friction modifiers may be routinely added to lubricating fluids, the particular type and amount of friction modifier is unique and specific to the needs of each particular application. The embodiments of the present invention have been found to be effective when used in conjunction with a variety of these additives.
- For example, nitrogen-containing ashless dispersants are well known as supplemental lubricating oil additives. Suitable ashless dispersants that may be used in the present invention include hydrocarbyl succinimides, hydrocarbyl succinamides, mixed ester/amides of hydrocarbyl-substituted succinic acid, hydroxyesters of hydrocarbyl-substituted succinic acid, and Mannich condensation products of hydrocarbyl-substituted phenols, formaldehyde and amines. Also used in the present invention are condensation products of polyamines and hydrocarbyl-substituted phenyl acids. Mixtures of any of these dispersants may also be used.
- Two transmission fluid formulations were tested and evaluated for effectiveness in modifying steel-on-steel friction. Each fluid had identical concentrations and differed only in the amount of the thiadiazole component. In this example, a mono alkyl thiadiazole was used.
- The data shown in Table 1 was acquired using a push-belt CVT dynamometer test developed by Van Doome Transmissie. Table 1 shows steel-on-steel friction results measured at low pulley ratios for two different concentrations of thiadiazole. The standard deviation of measurement at the low ratio was 0.0016, which was established through reference runs taken over an extended period of time with a reference fluid, as recommended by Van Doorne.
TABLE 1 Effectiveness of Mono Alkyl Thiadiazole in Improving Steel-on-Steel Friction Top Pulley Overdrive Pulley Low Pulley Coefficient Coefficient Coefficient of Friction of Friction of Friction Formula (1) 0.0792 0.0830 0.0758 0.095 wt % thiadiazole Formula (2) 0.0792 0.0835 0.0855 0.30 wt % thiadiazole - The results show that at the low ratio, steel-on-steel friction increases significantly when the weight percent of thiadiazole is increased. For the top ratio and overdrive ratios, the steel-on-steel friction results were equivalent. In evaluating the data shown in Table 1, the objective or goal in these measures of friction is to approach 0.090, preferably to be as high or close to 0.090 as possible. Thus, the results from Formula (2) are superior to those from Formula (1).
- The present disclosure thus provides a composition for increasing steel-on-steel friction using thiadiazole or a derivative thereof. The compositions and methods described herein will allow the formulation of transmission fluids with applications in continuously variable transmissions as well as conventional automatic transmissions and with different kinds of start-up clutches.
- As used throughout the specification and claims, “a” and/or “an” may refer to one or more than one. Unless otherwise indicated, all numbers expressing quantities of ingredients, properties such as molecular weight, percent, ratio, reaction conditions, and so forth used in the specification and claims are to be understood as being modified in all instances by the term “about.” Accordingly, unless indicated to the contrary, the numerical parameters set forth in the specification and claims are approximations that may vary depending upon the desired properties sought to be obtained by the present invention. At the very least, and not as an attempt to limit the application of the doctrine of equivalents to the scope of the claims, each numerical parameter should at least be construed in light of the number of reported significant digits and by applying ordinary rounding techniques. Notwithstanding that the numerical ranges and parameters setting forth the broad scope of the invention are approximations, the numerical values set forth in the specific examples are reported as precisely as possible. Any numerical value, however, inherently contains certain errors necessarily resulting from the standard deviation found in their respective testing measurements.
- While the present disclosure has been described in some detail by way of illustration and example, it should be understood that the embodiments are susceptible to various modifications and alternative forms, and are not restricted to the specific embodiments set forth. It should be understood that these specific embodiments are not intended to limit the invention but, on the contrary, the intention is to cover all modifications, equivalents, and alternatives falling within the spirit and scope of the invention.
Claims (21)
Priority Applications (8)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US10/727,950 US20050124508A1 (en) | 2003-12-04 | 2003-12-04 | Compositions for improved friction durability in power transmission fluids |
CA002487091A CA2487091A1 (en) | 2003-12-04 | 2004-11-05 | Compositions for improved friction durability in power transmission fluids |
EP04026423A EP1544278A1 (en) | 2003-12-04 | 2004-11-08 | Thiadiazoles as additives improving the friction durability of power transmission fluids |
JP2004336066A JP2005163037A (en) | 2003-12-04 | 2004-11-19 | Composition for improved friction durability in power transmission fluid |
AU2004231256A AU2004231256A1 (en) | 2003-12-04 | 2004-11-23 | Compositions for improved friction durability in power transmission fluids |
CNA2004101038341A CN1637124A (en) | 2003-12-04 | 2004-12-03 | Compositions for improved friction durability in power transmission fluids |
KR1020040101165A KR100731560B1 (en) | 2003-12-04 | 2004-12-03 | Compositions and methods for improving steel-on-steel friction |
SG200407082A SG112945A1 (en) | 2003-12-04 | 2004-12-03 | Compositions for improved friction durability in power transmission fluids |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US10/727,950 US20050124508A1 (en) | 2003-12-04 | 2003-12-04 | Compositions for improved friction durability in power transmission fluids |
Publications (1)
Publication Number | Publication Date |
---|---|
US20050124508A1 true US20050124508A1 (en) | 2005-06-09 |
Family
ID=34523003
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US10/727,950 Abandoned US20050124508A1 (en) | 2003-12-04 | 2003-12-04 | Compositions for improved friction durability in power transmission fluids |
Country Status (8)
Country | Link |
---|---|
US (1) | US20050124508A1 (en) |
EP (1) | EP1544278A1 (en) |
JP (1) | JP2005163037A (en) |
KR (1) | KR100731560B1 (en) |
CN (1) | CN1637124A (en) |
AU (1) | AU2004231256A1 (en) |
CA (1) | CA2487091A1 (en) |
SG (1) | SG112945A1 (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8410032B1 (en) * | 2012-07-09 | 2013-04-02 | Afton Chemical Corporation | Multi-vehicle automatic transmission fluid |
Citations (24)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2191125A (en) * | 1937-10-20 | 1940-02-20 | Collins Douglas | Auxiliary steering mechanism |
US2719125A (en) * | 1952-12-30 | 1955-09-27 | Standard Oil Co | Oleaginous compositions non-corrosive to silver |
US2719126A (en) * | 1952-12-30 | 1955-09-27 | Standard Oil Co | Corrosion inhibitors and compositions containing same |
US2749311A (en) * | 1952-12-04 | 1956-06-05 | Standard Oil Co | Corrosion inhibitors and compositions containing the same |
US3087937A (en) * | 1961-03-22 | 1963-04-30 | Tesi Giorgio | Bis (perfluoromethyl) phosphinic nitride |
US3087932A (en) * | 1959-07-09 | 1963-04-30 | Standard Oil Co | Process for preparing 2, 5-bis(hydrocarbondithio)-1, 3, 4-thiadiazole |
US3663561A (en) * | 1969-12-29 | 1972-05-16 | Standard Oil Co | 2-hydrocarbyldithio - 5 - mercapto-1,3,4-thiadiazoles and their preparation |
US4556503A (en) * | 1983-09-09 | 1985-12-03 | Idemitsu Kosan Company Limited | Traction drive fluids |
US4684754A (en) * | 1985-11-29 | 1987-08-04 | Idemitsu Kosan Company Limited | Working fluid for traction drive |
US4755317A (en) * | 1986-04-11 | 1988-07-05 | Idemitsu Kosan Company Limited | Working fluid for traction drive |
US5032308A (en) * | 1989-11-07 | 1991-07-16 | The Dow Chemical Company | Layered mixed metal hydroxides in electrorheological fluids |
US5283384A (en) * | 1991-04-08 | 1994-02-01 | Idemitsu Kosan Co., Ltd. | Traction drive fluid, process for producing the same and bicyclo octane compound |
US5792731A (en) * | 1995-10-05 | 1998-08-11 | Idemitsu Kosan Co., Ltd. | Lubricant composition for continuous variable transmissions and method for lubricating them with said lubricant composition |
US5853435A (en) * | 1994-12-30 | 1998-12-29 | Mobil Oil Corporation | Polymeric amine-heterocyclic reaction products as fuel and lubricant antiwear, detergency and cleanliness additives |
US6184185B1 (en) * | 1998-05-08 | 2001-02-06 | Tonen Corporation | Lubricant oil composition comprising borated cyclic carboxylic acid imide |
US6225266B1 (en) * | 1999-05-28 | 2001-05-01 | Infineum Usa L.P. | Zinc-free continuously variable transmission fluid |
US6251840B1 (en) * | 1995-09-12 | 2001-06-26 | The Lubrizol Corporation | Lubrication fluids for reduced air entrainment and improved gear protection |
US6426323B1 (en) * | 2000-06-05 | 2002-07-30 | Tonengeneral Sekiyu K.K. | Lubricating oil composition for continuously variable transmission |
US6451745B1 (en) * | 1999-05-19 | 2002-09-17 | The Lubrizol Corporation | High boron formulations for fluids continuously variable transmissions |
US20020151441A1 (en) * | 2001-02-14 | 2002-10-17 | Sanjay Srinivasan | Automatic transmission fluids with improved anti-shudder properties |
US6528458B1 (en) * | 2002-04-19 | 2003-03-04 | The Lubrizol Corporation | Lubricant for dual clutch transmission |
US20030092585A1 (en) * | 2001-11-13 | 2003-05-15 | The Lubrizol Corporation | Lubricating compositions and concentrates containing an antiwear amount of a thiadiazole |
US6634977B2 (en) * | 2000-12-14 | 2003-10-21 | Honda Giken Kogyo Kabushiki Kaisha | Clutch control system in continuously variable transmission system for vehicle |
US20050054542A1 (en) * | 2002-02-14 | 2005-03-10 | Muchmore Robert A. | Antifoam agent and method for use in automatic transmission fluid applications involving high pressure pumps |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5055584A (en) * | 1987-05-04 | 1991-10-08 | Karol Thomas J | Maleic derivatives of 2,5-dimercapto-1,3,4-thiadiazoles and lubricating compositions containing same |
JP2840526B2 (en) * | 1993-06-24 | 1998-12-24 | 出光興産株式会社 | Lubricating oil composition |
JP3775986B2 (en) * | 2000-12-20 | 2006-05-17 | 株式会社ジャパンエナジー | Traction drive fluid |
JP4919555B2 (en) * | 2001-08-30 | 2012-04-18 | Jx日鉱日石エネルギー株式会社 | Lubricating oil composition for automatic transmission |
JP4138311B2 (en) * | 2001-12-27 | 2008-08-27 | 新日本石油株式会社 | Transmission oil composition for automobiles |
-
2003
- 2003-12-04 US US10/727,950 patent/US20050124508A1/en not_active Abandoned
-
2004
- 2004-11-05 CA CA002487091A patent/CA2487091A1/en not_active Abandoned
- 2004-11-08 EP EP04026423A patent/EP1544278A1/en not_active Withdrawn
- 2004-11-19 JP JP2004336066A patent/JP2005163037A/en active Pending
- 2004-11-23 AU AU2004231256A patent/AU2004231256A1/en not_active Abandoned
- 2004-12-03 CN CNA2004101038341A patent/CN1637124A/en active Pending
- 2004-12-03 SG SG200407082A patent/SG112945A1/en unknown
- 2004-12-03 KR KR1020040101165A patent/KR100731560B1/en not_active IP Right Cessation
Patent Citations (25)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2191125A (en) * | 1937-10-20 | 1940-02-20 | Collins Douglas | Auxiliary steering mechanism |
US2749311A (en) * | 1952-12-04 | 1956-06-05 | Standard Oil Co | Corrosion inhibitors and compositions containing the same |
US2719125A (en) * | 1952-12-30 | 1955-09-27 | Standard Oil Co | Oleaginous compositions non-corrosive to silver |
US2719126A (en) * | 1952-12-30 | 1955-09-27 | Standard Oil Co | Corrosion inhibitors and compositions containing same |
US3087932A (en) * | 1959-07-09 | 1963-04-30 | Standard Oil Co | Process for preparing 2, 5-bis(hydrocarbondithio)-1, 3, 4-thiadiazole |
US3087937A (en) * | 1961-03-22 | 1963-04-30 | Tesi Giorgio | Bis (perfluoromethyl) phosphinic nitride |
US3663561A (en) * | 1969-12-29 | 1972-05-16 | Standard Oil Co | 2-hydrocarbyldithio - 5 - mercapto-1,3,4-thiadiazoles and their preparation |
US4556503A (en) * | 1983-09-09 | 1985-12-03 | Idemitsu Kosan Company Limited | Traction drive fluids |
US4684754A (en) * | 1985-11-29 | 1987-08-04 | Idemitsu Kosan Company Limited | Working fluid for traction drive |
US4755317A (en) * | 1986-04-11 | 1988-07-05 | Idemitsu Kosan Company Limited | Working fluid for traction drive |
US5032308A (en) * | 1989-11-07 | 1991-07-16 | The Dow Chemical Company | Layered mixed metal hydroxides in electrorheological fluids |
US5283384A (en) * | 1991-04-08 | 1994-02-01 | Idemitsu Kosan Co., Ltd. | Traction drive fluid, process for producing the same and bicyclo octane compound |
US5853435A (en) * | 1994-12-30 | 1998-12-29 | Mobil Oil Corporation | Polymeric amine-heterocyclic reaction products as fuel and lubricant antiwear, detergency and cleanliness additives |
US6251840B1 (en) * | 1995-09-12 | 2001-06-26 | The Lubrizol Corporation | Lubrication fluids for reduced air entrainment and improved gear protection |
US5792731A (en) * | 1995-10-05 | 1998-08-11 | Idemitsu Kosan Co., Ltd. | Lubricant composition for continuous variable transmissions and method for lubricating them with said lubricant composition |
US6184185B1 (en) * | 1998-05-08 | 2001-02-06 | Tonen Corporation | Lubricant oil composition comprising borated cyclic carboxylic acid imide |
US6451745B1 (en) * | 1999-05-19 | 2002-09-17 | The Lubrizol Corporation | High boron formulations for fluids continuously variable transmissions |
US6225266B1 (en) * | 1999-05-28 | 2001-05-01 | Infineum Usa L.P. | Zinc-free continuously variable transmission fluid |
US6337309B1 (en) * | 1999-05-28 | 2002-01-08 | Infineum International Ltd | Zinc-free continuously variable transmission fluid |
US6426323B1 (en) * | 2000-06-05 | 2002-07-30 | Tonengeneral Sekiyu K.K. | Lubricating oil composition for continuously variable transmission |
US6634977B2 (en) * | 2000-12-14 | 2003-10-21 | Honda Giken Kogyo Kabushiki Kaisha | Clutch control system in continuously variable transmission system for vehicle |
US20020151441A1 (en) * | 2001-02-14 | 2002-10-17 | Sanjay Srinivasan | Automatic transmission fluids with improved anti-shudder properties |
US20030092585A1 (en) * | 2001-11-13 | 2003-05-15 | The Lubrizol Corporation | Lubricating compositions and concentrates containing an antiwear amount of a thiadiazole |
US20050054542A1 (en) * | 2002-02-14 | 2005-03-10 | Muchmore Robert A. | Antifoam agent and method for use in automatic transmission fluid applications involving high pressure pumps |
US6528458B1 (en) * | 2002-04-19 | 2003-03-04 | The Lubrizol Corporation | Lubricant for dual clutch transmission |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8410032B1 (en) * | 2012-07-09 | 2013-04-02 | Afton Chemical Corporation | Multi-vehicle automatic transmission fluid |
Also Published As
Publication number | Publication date |
---|---|
KR20050054473A (en) | 2005-06-10 |
AU2004231256A1 (en) | 2005-06-23 |
SG112945A1 (en) | 2005-07-28 |
CA2487091A1 (en) | 2005-06-04 |
KR100731560B1 (en) | 2007-06-22 |
JP2005163037A (en) | 2005-06-23 |
CN1637124A (en) | 2005-07-13 |
EP1544278A1 (en) | 2005-06-22 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US6337309B1 (en) | Zinc-free continuously variable transmission fluid | |
US20070082826A1 (en) | Power transmission fluids having extended durability | |
US11214750B2 (en) | Combinations of phosphorous-containing compounds for use as anti-wear additives in lubricant compositions | |
US20070293406A1 (en) | Power transmission fluid with enhanced friction characteristics | |
NL8201722A (en) | ANTIOXIDIZER COMBINATIONS OF MOLYBDENE COMPLEXES AND AROMATIC AMINE COMPOUNDS. | |
US20060240998A1 (en) | Corrosion protection for lubricants | |
US4776969A (en) | Cyclic phosphate additives and their use in oleaginous compositions | |
JP2007131856A (en) | Transmission fluid having comparatively low viscosity | |
JP2020059861A (en) | Friction control method | |
US4123369A (en) | Lubricating oil composition | |
KR100744983B1 (en) | Power transmission fluids with enhanced antishudder durability and handling characteristics | |
US6852680B2 (en) | Dithiocarbamates containing alkylthio and hydroxy substituents | |
EP0555344A1 (en) | Antiwear/antioxidant additives based on dimercapto derivatives of acrylates and methacrylates polymers and amine reaction products thereof | |
US4228022A (en) | Sulfurized alkylphenol-olefin reaction product lubricating oil additive | |
US20050124508A1 (en) | Compositions for improved friction durability in power transmission fluids | |
EP0333705B1 (en) | Heterocyclic compounds useful as additives for lubricant and fuel compositions | |
JP6209294B2 (en) | Color-stable transmission fluid composition | |
US9340746B1 (en) | Low viscosity transmission fluids with enhanced gear fatigue and frictional performance | |
US5512189A (en) | Antiwear and antioxidant additives | |
US5120456A (en) | Triazole/arylamine-modified sulfonates as multifunctional additives for lubricants | |
JP4044224B2 (en) | Additive for lubricant | |
US8664171B2 (en) | Nitrated extreme pressure additives and blends | |
EP0116460B1 (en) | Friction modifier additive for power transmission shift fluids | |
US3499838A (en) | Reaction product of diorganophosphorodithioates and diorganocarbodiimides | |
JPH04182494A (en) | Organomolybdenum compound and use thereof |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
AS | Assignment |
Owner name: ETHYL PETROLEUM ADDITIVES, INC., VIRGINIA Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:LYER, RAMNATH N.;TERSIGNI, SAMUEL H.;REEL/FRAME:014774/0202 Effective date: 20031202 |
|
AS | Assignment |
Owner name: SUNTRUST BANK, AS ADMINISTRATIVE AGENT, GEORGIA Free format text: SECURITY AGREEMENT;ASSIGNOR:ETHYL PETROLEUM ADDITIVES, INC.;REEL/FRAME:014782/0317 Effective date: 20040618 |
|
AS | Assignment |
Owner name: AFTON CHEMICAL CORPORATION, VIRGINIA Free format text: CHANGE OF NAME;ASSIGNOR:ETHYL PETROLEUM ADDITIVES, INC.;REEL/FRAME:015918/0557 Effective date: 20040701 |
|
AS | Assignment |
Owner name: SUNTRUST BANK,VIRGINIA Free format text: SECURITY AGREEMENT;ASSIGNOR:AFTON CHEMICAL CORPORATION;REEL/FRAME:018883/0865 Effective date: 20061221 Owner name: SUNTRUST BANK, VIRGINIA Free format text: SECURITY AGREEMENT;ASSIGNOR:AFTON CHEMICAL CORPORATION;REEL/FRAME:018883/0865 Effective date: 20061221 |
|
STCB | Information on status: application discontinuation |
Free format text: ABANDONED -- FAILURE TO RESPOND TO AN OFFICE ACTION |
|
AS | Assignment |
Owner name: AFTON CHEMICAL CORPORATION, VIRGINIA Free format text: RELEASE BY SECURED PARTY;ASSIGNOR:SUNTRUST BANK;REEL/FRAME:026707/0563 Effective date: 20110513 |