US20050029718A1 - Filtration system for magnesium recycling and purification - Google Patents

Filtration system for magnesium recycling and purification Download PDF

Info

Publication number
US20050029718A1
US20050029718A1 US10/493,006 US49300604A US2005029718A1 US 20050029718 A1 US20050029718 A1 US 20050029718A1 US 49300604 A US49300604 A US 49300604A US 2005029718 A1 US2005029718 A1 US 2005029718A1
Authority
US
United States
Prior art keywords
chamber
magnesium
magnesium melt
filter
melt
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
US10/493,006
Inventor
BangHong Hu
Kin Tong
Chee Choy
Su Zhang
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Agency for Science Technology and Research Singapore
Original Assignee
Agency for Science Technology and Research Singapore
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Agency for Science Technology and Research Singapore filed Critical Agency for Science Technology and Research Singapore
Assigned to AGENCY FOR SCIENCE, TECHNOLOGY AND RESEARCH reassignment AGENCY FOR SCIENCE, TECHNOLOGY AND RESEARCH ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: CHOY, CHEE MUN, TONG, KIN KONG, ZHANG, SU XIA, HU, BANGHONG
Publication of US20050029718A1 publication Critical patent/US20050029718A1/en
Abandoned legal-status Critical Current

Links

Images

Classifications

    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B26/00—Obtaining alkali, alkaline earth metals or magnesium
    • C22B26/20—Obtaining alkaline earth metals or magnesium
    • C22B26/22—Obtaining magnesium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B22—CASTING; POWDER METALLURGY
    • B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D17/00—Pressure die casting or injection die casting, i.e. casting in which the metal is forced into a mould under high pressure
    • B22D17/20—Accessories: Details
    • B22D17/30—Accessories for supplying molten metal, e.g. in rations
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B22—CASTING; POWDER METALLURGY
    • B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D43/00—Mechanical cleaning, e.g. skimming of molten metals
    • B22D43/001—Retaining slag during pouring molten metal
    • B22D43/004—Retaining slag during pouring molten metal by using filtering means
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B9/00—General processes of refining or remelting of metals; Apparatus for electroslag or arc remelting of metals
    • C22B9/006—General processes of refining or remelting of metals; Apparatus for electroslag or arc remelting of metals with use of an inert protective material including the use of an inert gas
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B9/00—General processes of refining or remelting of metals; Apparatus for electroslag or arc remelting of metals
    • C22B9/02—Refining by liquating, filtering, centrifuging, distilling, or supersonic wave action including acoustic waves
    • C22B9/023—By filtering
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00—Technologies related to metal processing
    • Y02P10/20—Recycling

Definitions

  • the present invention relates generally to a filtration system for purifying magnesium. Specifically, the present invention relates to a filtration system for recycling and purification of scrap magnesium and magnesium ingots with impurities.
  • Magnesium alloys are heated to a molten state in preparation for hot-working thereof. Molten magnesium alloys easily oxidise and react with impurities, especially when scrap magnesium alloys are reused. As a result, magnesium alloys are contaminated by non-metallic and metallic inclusions, for example oxides or intermetallic compounds, when melted.
  • the magnesium alloys are typically melted for producing castings.
  • the presence of inclusions within the magnesium alloys results in metallurgical defects therein and will adversely affect the quality of the castings produced from the magnesium alloys.
  • a known method for removing the impurities is to send the magnesium alloys to a smelter for smelting.
  • smelting is a costly process.
  • Another known process uses impediment plates disposed within a furnace for removing top and bottom sludge from magnesium melts.
  • the impediment plates do not remove inclusions suspended in the magnesium melts.
  • a filtration system for magnesium recycling and purification comprising:
  • a filtration method for magnesium recycling and purification comprising the steps of:
  • a filtration method for magnesium recycling and purification comprising the steps of:
  • FIG. 1 shows a partial front sectional view of a filtration system according to an embodiment of the invention
  • FIG. 2 shows a partial side sectional view of the filtration system of FIG. 1 ;
  • FIG. 3 is an illustration of a filter of the filtration system of FIG. 1 ;
  • FIG. 4 is an illustration of a first chamber and the filter of FIG. 3 ;
  • FIG. 5 a shows a low magnification light optical microscope (LOM) micrograph of a tensile specimen made from magnesium melt obtained from the filtration system of FIG. 1 ;
  • LOM low magnification light optical microscope
  • FIG. 5 b shows the LOM micrograph of FIG. 5 a under high magnification
  • FIG. 6 a shows a low magnification light optical microscope (LOM) micrograph of a mobile phone case specimen made from magnesium melt obtained from the filtration system of FIG. 1 ;
  • LOM low magnification light optical microscope
  • FIG. 6 b shows the LOM micrograph of FIG. 6 b under high magnification
  • FIG. 7 a shows a graph plotting the tensile strength (ultimate tensile strength and yield strength) of test samples as a function of cross-head speed with the test samples being cast from a magnesium melt purified using the filtration system of FIG. 1 ;
  • FIG. 7 b shows a graph plotting the percentage elongation of the test samples of FIG. 7 b , as a function of cross-head speed.
  • FIG. 1 shows a partial front sectional view of the filtration system 20
  • FIG. 2 shows a partial side sectional view of the filtration system 20 .
  • the filtration system 20 is for use in substantially purifying magnesium.
  • the filtration system 20 includes a crucible 22 being divided into two parts by a filter adapter 24 disposed therein, the two parts of the crucible being namely a first chamber 26 and a second chamber 28 .
  • the first chamber 26 is in fluid communication with the second chamber 28 through an opening 30 , as shown in FIG. 2 , in the filter adapter 24 that forms a passageway therebetween.
  • the filter adapter 24 is for receiving a filter 32 therewithin and for removably engaging thereto.
  • FIG. 3 is an illustration of the filter 32
  • FIG. 4 is an illustration of the first chamber 26 and the filter 32 .
  • the filter adapter 24 is preferably a steel structure that shaped and dimensioned for holding the filter 32 at the periphery thereof.
  • the filtration system 20 further includes a heating apparatus coupled to the crucible 22 .
  • the heating apparatus is preferably integrated with the crucible 22 for providing heat to the crucible 22 and its contents.
  • the heating apparatus is electrically connected to a controller (all not shown).
  • the filtration system 20 is for providing substantially purified magnesium melts to downstream systems or machineries, for example, a die-casting machine.
  • magnesium ingots or scraps are provided to the first chamber 26 of the filtration system 20 .
  • the controller activates the heating apparatus to provide heat to the crucible 22 and the magnesium therein, thereby melting the magnesium.
  • magnesium melt can be provided to the first chamber 26 of the crucible 22 .
  • the heating apparatus provides heat to the crucible 22 to maintain the magnesium melt in its molten state and to melt the magnesium scraps and ingots added to the magnesium melt thereafter.
  • the filter 32 of the filtration system 20 is preferably made of a silicon-free material.
  • Conventional filters for example a filter for aluminium alloys, are made of silicon-based materials. The silicon-based materials readily react with magnesium to cause contamination therein and are therefore undesirable.
  • the filter 32 is made of one of steels or ceramic material which comprises of one or more material selected from a group consisting of Al 2 O 3 , MgO, AlPO 4 and Mg 3 (PO 4 ) 2 .
  • the filter 32 comprises of an array of apertures (not shown). Each of the apertures is shaped and dimensioned for preventing the passage of a particle having a size greater than 5 microns therethrough. Preferably, each pair of adjacent apertures are spaced apart a distance of 5 to 250 microns.
  • the magnesium melt 38 in the first chamber 26 passes through the filter 32 and into the second chamber 28 of the crucible 22 . Therefore, the impurities suspended in the magnesium melt 38 contained in the first chamber 26 is substantially removed by the filter 32 before entering the second chamber 28 as purified magnesium melt 40 .
  • the magnesium melt 38 contained in the first chamber 26 contains bottom sludge that has settled at the bottom of the first chamber 26 .
  • top sludge can also be found floating at the surface of the magnesium melt 38 contained in the first chamber 26 .
  • the filter adapter 24 functions to substantially impede the top sludge and bottom sludge in the first chamber 26 from entering the second chamber 28 (all not shown).
  • the magnesium melt 38 in the first chamber 26 is drawn into the second chamber 28 by hydrostatic forces acting on the magnesium melt 38 .
  • the magnesium melt 38 in the first chamber 26 continues to be drawn into the second chamber until the hydrostatic pressures of magnesium melt 38 in the first chamber 26 and the purified magnesium melt 40 in the second chamber 28 are in equilibrium.
  • each of the first chamber 26 and the second chamber 28 has a thermocouple 42 disposed therewithin. Both the thermocouples 42 are electrically connected to the controller for transducing temperature of the magnesium melt 38 in the first chamber 26 into first temperature signals (not shown) and the temperature of the purified magnesium melt 40 in the second chamber 40 into second temperature signals (not shown).
  • the first and second temperature signals are transmitted to the controller.
  • the controller uses a control function (not shown) to determine and control the heat output of the heating apparatus, thereby maintaining the magnesium melt 38 and the purified magnesium melt 40 in a molten state and to prevent overheating thereof. In the molten state, the viscosities of both the magnesium melt 38 and the purified magnesium melt 40 are greatly reduced, thereby facilitating flow thereof through the filter 32 .
  • the crucible 22 is preferably enclosed for receiving and retaining protective gas therein.
  • a gas feed system (not shown) is connected to the crucible for supplying the protective gas thereinto.
  • the protective gas prevents both the magnesium melt 38 and the purified magnesium melt 40 from reacting with the atmosphere by forming a screen therebetween.
  • An extractor 44 extends from within the second chamber 28 to a die-casting assembly 46 .
  • the extractor 44 is for extracting the purified magnesium melt 40 from the second chamber 28 and providing the purified magnesium melt 40 to the die-casting assembly 46 .
  • the extractor 44 shown in FIG. 1 uses a piston and a goose-neck chamber assembly for extracting the purified magnesium melt 40 .
  • Extracting the purified magnesium melt 40 from the second chamber 28 reduces the level of the purified magnesium melt 40 contained therein.
  • the reduction of the level of the purified magnesium melt 40 in the second chamber 28 further draws the magnesium melt 38 from the first chamber 26 and into the second chamber 28 .
  • Magnesium melt and magnesium ingots or scraps can be further provided to the first chamber 26 for replenishing the second chamber 28 and thereby the filtration system 20 with purified magnesium melt 40 .
  • the purified magnesium melt 40 supplied from the filtration system 20 to the die-casting assembly 46 provides the die-casting assembly with a substantially inclusion-free purified magnesium melt 40 supply for use in a die-casting process.
  • the alloy used in the tests was AZ91 HP having a composition of Al 8-9.5%, Zn 0.3-1.0%, Mn ⁇ 0.17%, Si ⁇ 0.05%, Fe ⁇ 0.004%, Cu ⁇ 0.015%, Ni ⁇ 0.01%, others ⁇ 0.01%, others ⁇ 0.01%, Mg (remaining).
  • AZ91 HP having a composition of Al 8-9.5%, Zn 0.3-1.0%, Mn ⁇ 0.17%, Si ⁇ 0.05%, Fe ⁇ 0.004%, Cu ⁇ 0.015%, Ni ⁇ 0.01%, others ⁇ 0.01%, others ⁇ 0.01%, Mg (remaining).
  • the tests were conducted using 100% fresh ingot and ingot including 10% scraps material.
  • microstructure analysis was conducted with light optical microscopy (LOM) while mechanical properties were determined using an Instron tensile testing machine.
  • LOM light optical microscopy
  • the cross-head speed was varied from 0.1 to 20 mm/min during tensile tests.
  • Typical microstructures for the tensile test specimen having a diameter of 10 mm-thick walled part and a mobile phone case, having a wall thickness of 0.6 mm-thin wall part.
  • the microstructures consist mainly of ⁇ -Mg, intermetallic-Al 2 Mg 17 , eutectic composition and some fine precipitate.
  • the thin walled parts showed much finer structure, as shown in FIGS. 7 a and 7 b , when compared to the thick walled parts shown in FIGS. 6 a and 6 b .
  • the reduced ⁇ -Mg grain size is due to rapid solidification rate occurred in the thin walled part.
  • FIGS. 8 a and 8 b show the tensile strength, comprising the ultimate tensile strength (ITS) and yield strength (YS) and elongation as a function of the cross-head speed.
  • ITS ultimate tensile strength
  • YS yield strength
  • elongation as a function of the cross-head speed.
  • the UTS and YS are about 142 and 119 MPa respectively with an elongation of about 1%.

Abstract

Magnesium alloys are heated to a molten state in preparation for hot-working thereof, for example, die-casting. The presence of inclusions within the magnesium alloys results in metallurgical defects therein and will adversely affect the quality of the castings produced from the magnesium alloys. An embodiment of the invention processes the magnesium melt containing impurities through a non-reactive filter under an environment filled with protective gas for substantially purifying the magnesium melt and to reduce the presence of inclusions in castings formed therefrom.

Description

    FIELD OF INVENTION
  • The present invention relates generally to a filtration system for purifying magnesium. Specifically, the present invention relates to a filtration system for recycling and purification of scrap magnesium and magnesium ingots with impurities.
    • BACKGROUND
  • Magnesium alloys are heated to a molten state in preparation for hot-working thereof. Molten magnesium alloys easily oxidise and react with impurities, especially when scrap magnesium alloys are reused. As a result, magnesium alloys are contaminated by non-metallic and metallic inclusions, for example oxides or intermetallic compounds, when melted.
  • The magnesium alloys are typically melted for producing castings. The presence of inclusions within the magnesium alloys results in metallurgical defects therein and will adversely affect the quality of the castings produced from the magnesium alloys.
  • A known method for removing the impurities is to send the magnesium alloys to a smelter for smelting. However, smelting is a costly process. Another known process uses impediment plates disposed within a furnace for removing top and bottom sludge from magnesium melts. However, the impediment plates do not remove inclusions suspended in the magnesium melts.
  • Hence, this clearly affirms a need for a filtration system for purifying magnesium melts.
    • SUMMARY
  • In accordance with a first aspect of the invention, there is disclosed a filtration system for magnesium recycling and purification, the filtration system comprising:
      • a first chamber for containing magnesium melt, the magnesium melt containing impurities; and
      • a second chamber for receiving purified magnesium melt,
      • wherein said first and second chambers have disposed therebetween a filter, the filter being a silicon-free medium.
  • In accordance with a second aspect of the invention, there is disclosed a filtration method for magnesium recycling and purification, comprising the steps of:
      • receiving magnesium melt into a first chamber, the magnesium melt containing impurities within the first chamber containing impurities;
      • providing a second chamber, the second chamber being in fluid communication with the first chamber; and
      • substantially removing the impurities from the magnesium melt flowing from the first chamber into the second chamber using a filter, the filter being disposed between the first chamber and the second chamber and the filter including a silicon-free medium.
  • In accordance to a third aspect of the invention, there is disclosed a filtration method for magnesium recycling and purification, comprising the steps of:
      • receiving magnesium into a first chamber, the magnesium within the first chamber containing impurities and the magnesium being one of a magnesium melt or solid magnesium ingot;
      • providing a second chamber, the second chamber being in fluid communication with the first chamber;
      • heating the magnesium contained in the first chamber by a heating apparatus for melting the magnesium and for maintaining the magnesium melt in a molten state, and the magnesium melt in the first chamber thereby flowing into the second chamber; and
      • substantially removing the impurities from the magnesium melt flowing from the first chamber into the second chamber using a filter, the filter being disposed between the first chamber and the second chamber and the filter including a silicon-free medium.
    BRIEF DESCRIPTION OF THE DRAWINGS
  • Embodiments of the invention are described hereinafter with reference to the following drawings, in which:
  • FIG. 1 shows a partial front sectional view of a filtration system according to an embodiment of the invention;
  • FIG. 2 shows a partial side sectional view of the filtration system of FIG. 1;
  • FIG. 3 is an illustration of a filter of the filtration system of FIG. 1;
  • FIG. 4 is an illustration of a first chamber and the filter of FIG. 3;
  • FIG. 5 a shows a low magnification light optical microscope (LOM) micrograph of a tensile specimen made from magnesium melt obtained from the filtration system of FIG. 1;
  • FIG. 5 b shows the LOM micrograph of FIG. 5 a under high magnification;
  • FIG. 6 a shows a low magnification light optical microscope (LOM) micrograph of a mobile phone case specimen made from magnesium melt obtained from the filtration system of FIG. 1;
  • FIG. 6 b shows the LOM micrograph of FIG. 6 b under high magnification;
  • FIG. 7 a shows a graph plotting the tensile strength (ultimate tensile strength and yield strength) of test samples as a function of cross-head speed with the test samples being cast from a magnesium melt purified using the filtration system of FIG. 1; and
  • FIG. 7 b shows a graph plotting the percentage elongation of the test samples of FIG. 7 b, as a function of cross-head speed.
    • DETAILED DESCRIPTION
  • An embodiment of the invention, a filtration system 20 is described with reference to FIG. 1, which shows a partial front sectional view of the filtration system 20 and FIG. 2 which shows a partial side sectional view of the filtration system 20. The filtration system 20 is for use in substantially purifying magnesium.
  • As shown in FIG. 1, the filtration system 20 includes a crucible 22 being divided into two parts by a filter adapter 24 disposed therein, the two parts of the crucible being namely a first chamber 26 and a second chamber 28. The first chamber 26 is in fluid communication with the second chamber 28 through an opening 30, as shown in FIG. 2, in the filter adapter 24 that forms a passageway therebetween.
  • As shown in FIG. 2, the filter adapter 24 is for receiving a filter 32 therewithin and for removably engaging thereto. FIG. 3 is an illustration of the filter 32 and FIG. 4 is an illustration of the first chamber 26 and the filter 32. When the filter 32 is engaged to the filter adapter 24, the filter 32 blocks the opening 30 of the filter adapter 24, thereby intersecting the passageway between the first chamber 26 and the second chamber 28, as shown in FIGS. 1, 2 and 5. The filter adapter 24 is preferably a steel structure that shaped and dimensioned for holding the filter 32 at the periphery thereof.
  • The filtration system 20 further includes a heating apparatus coupled to the crucible 22. The heating apparatus is preferably integrated with the crucible 22 for providing heat to the crucible 22 and its contents. The heating apparatus is electrically connected to a controller (all not shown).
  • The filtration system 20 is for providing substantially purified magnesium melts to downstream systems or machineries, for example, a die-casting machine. For obtaining purified magnesium melts from the filtration system 20, magnesium ingots or scraps are provided to the first chamber 26 of the filtration system 20. The controller activates the heating apparatus to provide heat to the crucible 22 and the magnesium therein, thereby melting the magnesium.
  • Alternatively, magnesium melt can be provided to the first chamber 26 of the crucible 22. The heating apparatus provides heat to the crucible 22 to maintain the magnesium melt in its molten state and to melt the magnesium scraps and ingots added to the magnesium melt thereafter.
  • The filter 32 of the filtration system 20 is preferably made of a silicon-free material. Conventional filters, for example a filter for aluminium alloys, are made of silicon-based materials. The silicon-based materials readily react with magnesium to cause contamination therein and are therefore undesirable. The filter 32 is made of one of steels or ceramic material which comprises of one or more material selected from a group consisting of Al2O3, MgO, AlPO4 and Mg3(PO4)2.
  • The filter 32 comprises of an array of apertures (not shown). Each of the apertures is shaped and dimensioned for preventing the passage of a particle having a size greater than 5 microns therethrough. Preferably, each pair of adjacent apertures are spaced apart a distance of 5 to 250 microns. The magnesium melt 38 in the first chamber 26 passes through the filter 32 and into the second chamber 28 of the crucible 22. Therefore, the impurities suspended in the magnesium melt 38 contained in the first chamber 26 is substantially removed by the filter 32 before entering the second chamber 28 as purified magnesium melt 40. The magnesium melt 38 contained in the first chamber 26 contains bottom sludge that has settled at the bottom of the first chamber 26. In most situations, top sludge can also be found floating at the surface of the magnesium melt 38 contained in the first chamber 26. The filter adapter 24 functions to substantially impede the top sludge and bottom sludge in the first chamber 26 from entering the second chamber 28 (all not shown).
  • With reference to FIG. 1, the magnesium melt 38 in the first chamber 26 is drawn into the second chamber 28 by hydrostatic forces acting on the magnesium melt 38. The magnesium melt 38 in the first chamber 26 continues to be drawn into the second chamber until the hydrostatic pressures of magnesium melt 38 in the first chamber 26 and the purified magnesium melt 40 in the second chamber 28 are in equilibrium.
  • Preferably, each of the first chamber 26 and the second chamber 28 has a thermocouple 42 disposed therewithin. Both the thermocouples 42 are electrically connected to the controller for transducing temperature of the magnesium melt 38 in the first chamber 26 into first temperature signals (not shown) and the temperature of the purified magnesium melt 40 in the second chamber 40 into second temperature signals (not shown). The first and second temperature signals are transmitted to the controller. From the first and second temperature signals, the controller uses a control function (not shown) to determine and control the heat output of the heating apparatus, thereby maintaining the magnesium melt 38 and the purified magnesium melt 40 in a molten state and to prevent overheating thereof. In the molten state, the viscosities of both the magnesium melt 38 and the purified magnesium melt 40 are greatly reduced, thereby facilitating flow thereof through the filter 32.
  • The crucible 22 is preferably enclosed for receiving and retaining protective gas therein. A gas feed system (not shown) is connected to the crucible for supplying the protective gas thereinto. The protective gas prevents both the magnesium melt 38 and the purified magnesium melt 40 from reacting with the atmosphere by forming a screen therebetween.
  • An extractor 44, as shown in FIG. 1, extends from within the second chamber 28 to a die-casting assembly 46. The extractor 44 is for extracting the purified magnesium melt 40 from the second chamber 28 and providing the purified magnesium melt 40 to the die-casting assembly 46. The extractor 44 shown in FIG. 1 uses a piston and a goose-neck chamber assembly for extracting the purified magnesium melt 40.
  • Extracting the purified magnesium melt 40 from the second chamber 28 reduces the level of the purified magnesium melt 40 contained therein. The reduction of the level of the purified magnesium melt 40 in the second chamber 28 further draws the magnesium melt 38 from the first chamber 26 and into the second chamber 28. Magnesium melt and magnesium ingots or scraps can be further provided to the first chamber 26 for replenishing the second chamber 28 and thereby the filtration system 20 with purified magnesium melt 40.
  • The purified magnesium melt 40 supplied from the filtration system 20 to the die-casting assembly 46 provides the die-casting assembly with a substantially inclusion-free purified magnesium melt 40 supply for use in a die-casting process.
  • Two types of parts, hand-phone case and tensile test specimens, were cast during tests. The alloy used in the tests was AZ91 HP having a composition of Al 8-9.5%, Zn 0.3-1.0%, Mn≧0.17%, Si≦0.05%, Fe≦0.004%, Cu≦0.015%, Ni≦0.01%, others ≦0.01%, others ≦0.01%, Mg (remaining). For comparison the tests were conducted using 100% fresh ingot and ingot including 10% scraps material.
  • After casting, the microstructure and chemical properties of the specimens were analyzed. The microstructure analysis was conducted with light optical microscopy (LOM) while mechanical properties were determined using an Instron tensile testing machine. The cross-head speed was varied from 0.1 to 20 mm/min during tensile tests.
  • Typical microstructures for the tensile test specimen, having a diameter of 10 mm-thick walled part and a mobile phone case, having a wall thickness of 0.6 mm-thin wall part. In both thick and thin walled parts, the microstructures consist mainly of α-Mg, intermetallic-Al2Mg17, eutectic composition and some fine precipitate. However, the thin walled parts showed much finer structure, as shown in FIGS. 7 a and 7 b, when compared to the thick walled parts shown in FIGS. 6 a and 6 b. The reduced α-Mg grain size is due to rapid solidification rate occurred in the thin walled part.
  • Mechanical properties of cast samples were determined after casting. FIGS. 8 a and 8 b show the tensile strength, comprising the ultimate tensile strength (ITS) and yield strength (YS) and elongation as a function of the cross-head speed. As the cross-head speed is directly related to the strain rate of the testing, the results obtained indicated that the strain rate has a very slight influence on the flow stress and strain of magnesium castings when tested at room temperature. The UTS and YS are about 142 and 119 MPa respectively with an elongation of about 1%.
  • A comparison was made between the mechanical properties of castings made with filtered magnesium (with about 10% scraps) and castings made with fresh magnesium (100% new ingot). The strength of the castings is increased when filtered magnesium is used as compared to when 100% new magnesium ingot is used. However, the ductility of the magnesium alloys is reduced. The decreased ductility is typically due to the presence of more intermetallic compounds and less magnesium in the alloy having scrap parts therein although the alloy has already been filtered. Therefore, the composition of the alloy should be adjusted when using scrap parts.
  • In the foregoing manner, a filtration system is described according to an embodiment of the invention for addressing the foregoing disadvantages of conventional filtration devices. Although only one embodiment of the invention is disclosed, it will be apparent to one skilled in the art in view of this disclosure that numerous changes and/or modification can be made without departing from the scope and spirit of the invention.

Claims (20)

1. A filtration system for magnesium recycling and purification, the filtration system comprising:
a fast chamber for containing magnesium melt the magnesium melt containing impurities ad the first chamber enclosing the magnesium melt containing impurities therein; and
a second chamber for receiving purified magnesia melt, the second chamber enclosing the purified magnesium melt therein and the first and second chambers respectively separating the magnesium melt containing impurities and the purified magnesium melt from the atmosphere,
wherein sad first and second chambers have disposed therebetween a filter, the filter being a silicon-free medium, and each of the first chamber and the second chamber for further containing and enclosing protective gases therein.
2. The filtration system as in claim 1, the second chamber being in fluid communication with the first chamber and the filter for substantially removing the impurities from the magnesium melt flowing from the first chamber into the second chamber.
3. The filtration system as in claim 1, further comprising;
a heating apparatus integrated with the first and second chambers for maintaining the magnesium melt contained in the first and second chambers in a molten state.
4. The filtration system as in claim 1, further comprising.
a filter adapter disposed between the first chamber and the second chamber, the filter being removably coupled to the filter adapter and the filter adapter for positioning the filter to interface the first chamber and the second chamber.
5. The filtration system as in claim 1, the filter comprising one of steel or ceramic material.
6. The filtration system as in claim 5, the filter further comprises at least one material selected from a group consisting of Al2O3, MgO, AlPO4 and Mg3(PO4)2.
7. The filtration system as m claim 1, the filter comprising an array of at least one aperture.
8. The filtration system as in claim 7, each of the at least one aperture being shaped and dimension for preventing passage of a panicle having a size greater than 5 microns therethrough.
9. The filtration system as in claim 7, each pair adjacent apertures being spaced apart a distance of 5 to 250 microns.
10. The filtration system as in claim 1, further comprising a temperature control system for regulating temperature of the magnesium melt within the first chamber and the second chamber.
11. The filtration system as in claim 10, the temperature control system, comprising:
a controller, the heating apparatus being electrically connected to the controller;
a first thermocouple being electrically connected to the controller and being disposed within the first chamber for transducing temperature of the magnesium melt therein into first temperature signals; and
a second thermocouple being electrically connected to the controller and being disposed within the second chamber for transducing temperature of the filtered magnesium melt therein into second temperature signals,
wherein the first temperature signals and the second temperature signals are transmitted to the controller, the controller having a control function for controlling the heating apparatus and thereby maintaining the magnesium melt in a molten state and preventing overheating of the magnesium melt.
12. The filtration system as in claim 1, further comprising a gas feed system for introducing a protective gas in to the first and second chambers.
13. The filtration system as in claim 1, further comprising a step of:
an extractor for extracting the magnesium melt from the second chamber, the extractor being extending from within the second chamber to a die-casting assembly, the extractor for providing the extracted magnesium melt to the die-casting assembly.
14. A filtration method for magnesium recycling and purification, comprising the steps of:
receiving magnesium melt into a first chamber, the magnesium melt containing impurities within the first chamber containing impurities and the first chamber enclosing the magnesium melt containing impurities therein;
providing a second chamber, the second chamber being in fluid communication with the first chamber, the second chamber enclosing the purified magnesium melt herein and the first and second chambers respectively separating the magnesium melt containing impurities and the purified magnesium melt from the atmosphere; and
substantially removing the impurities from the magnesium melt flowing from the first chamber into the second chamber using a filter, the filter being disposed between the first chamber and the second chamber, each of the first chamber and the second chamber for further containing and enclosing protective gases therein, and the filter including a silicon-free medium.
15. The filtration method as in claim 14, ether comprising a step of:
providing a heating apparatus integrated with the first and second chambers for maintaining the magnesium melt contained in the first and second chambers in a molten state.
16. The filtration method as in claim 14, the filter comprising one of steel or ceramic material.
17. The filtration method as in claim 15, further comprising a step of providing a temperature control system for regulation temperature of the magnesium melt within the first chamber and the second chamber.
18. The filtration method as in claim 17, the temperature control system comprising:
a controller, the heating apparatus being electrically connected to the controller;
a first thermocouple being electrically connected to the controller and being disposed within the first chamber for transducing temperature of the magnesium melt therein into first temperature signals; and
a second thermocouple being electrically connected to the controller and being disposed within the second chamber for transducing temperature of the filtered magnesium melt therein into second temperature signals,
wherein the first temperature signals and the second temperature signals are transmitted to the controller, the controller having a control fraction for controlling the heating apparatus and thereby maintaining the magnesium melt in a molten state and preventing overheating of the magnesium melt.
19. The filtration method as in claim 14, further comprising a step of:
extracting the magnesium melt from the second chamber by an extractor, the extractor extending from within the second chamber to a die-casting assembly, the extractor for providing the extracted magnesium melt to the die-casting assembly.
20. A filtration method for magnesium recycling and purification, comprising the steps of:
receiving magnesium into a first chamber, the magnesium within the first chamber containing impurities, the first chamber enclosing the magnesium melt containing impurities therein and the magnesium being one of a magnesium melt or solid magnesium ingot;
providing a second chamber, the second chamber being in fluid communication with the first chamber, the second chamber enclosing the purified magnesium melt therein and the fist and second chambers respectively separating the magnesium melt containing impurities and the purified magnesium melt from the atmosphere;
heating the magnesium contained in the fist chamber by a heating apparatus for melting the magnesium and for maintaining the magnesium melt in a molten state, and the magnesium melt in the first chamber thereby flowing into the second chamber; and
substantially removing the impurities from the magnesium melt flowing from the first chamber into the second chamber using a filter, the filter being disposed between the first chamber and the second chamber, each of the first chamber and the second chamber for further containing and enclosing protective gases therein, and the filter including a silicon-free medium.
US10/493,006 2001-10-19 2002-10-18 Filtration system for magnesium recycling and purification Abandoned US20050029718A1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
SG200106275A SG121696A1 (en) 2001-10-19 2001-10-19 Filtration system for recycling and purification of a magnesium melt
SGSG200106275-1 2001-10-19
PCT/SG2002/000238 WO2003033748A1 (en) 2001-10-19 2002-10-18 A filtration system for magnesium recycling and purification

Publications (1)

Publication Number Publication Date
US20050029718A1 true US20050029718A1 (en) 2005-02-10

Family

ID=20430845

Family Applications (1)

Application Number Title Priority Date Filing Date
US10/493,006 Abandoned US20050029718A1 (en) 2001-10-19 2002-10-18 Filtration system for magnesium recycling and purification

Country Status (3)

Country Link
US (1) US20050029718A1 (en)
SG (1) SG121696A1 (en)
WO (1) WO2003033748A1 (en)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101039725B1 (en) 2009-03-23 2011-06-09 (주)이노캐스트 Apparatus and method for regenerating scrap of magnesium alloy
WO2016131174A1 (en) * 2015-02-16 2016-08-25 谭何易 Production line for producing national-standard magnesium alloy ingots on the basis of magnesium alloy waste material
CN108193061A (en) * 2017-12-21 2018-06-22 李本根 A kind of purifying plant for rare earth feed liquid
CN108237206A (en) * 2018-02-28 2018-07-03 厦门格欧博新材料科技有限公司 A kind of salt core former
CN110724833A (en) * 2019-11-27 2020-01-24 国科镁业科技(河南)有限公司 Application of simple substance silicon filter material in gas-phase magnesium purification and production system comprising same
CN113444888A (en) * 2021-06-29 2021-09-28 重庆大学 Method for purifying magnesium melt by adopting directional solidification

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AU2005215071B2 (en) * 2004-02-24 2010-02-11 Alcan International Limited Method of priming filter for molten metal
CN108311652B (en) * 2018-02-06 2019-12-17 洛阳晟雅镁合金科技有限公司 Preparation process of ME20M magnesium alloy slab ingot

Citations (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3281238A (en) * 1963-11-13 1966-10-25 Aluminum Co Of America Treatment of molten aluminous metal
US4010186A (en) * 1971-04-05 1977-03-01 Ppg Industries, Inc. Removal of lead from aqueous solution using metallic magnesium
US4154802A (en) * 1976-06-09 1979-05-15 Brandt Peter J Upgrading of magnesium containing materials
US4194884A (en) * 1978-11-24 1980-03-25 Thermo Electron Corporation Method and apparatus for air sampling and filtration
US4303610A (en) * 1980-05-19 1981-12-01 Pennzoil Company Test kit for field analysis of plant tissue magnesium and calcium
US4334990A (en) * 1979-08-24 1982-06-15 Servimetal Cartridge for active filtration and treatment of liquid metals and alloys
US4337157A (en) * 1978-03-17 1982-06-29 Manville Service Corporation Biopolymer filtration process
US4409194A (en) * 1978-12-14 1983-10-11 Stauffer Chemical Company Method of separating magnesium from wet process superphosphoric acid
US4418028A (en) * 1980-01-14 1983-11-29 Servimetal Filtration block for liquid metals and alloys, with a mechanical and physical-chemical effect
US4457496A (en) * 1980-01-14 1984-07-03 Servimetal Filtration block for liquid metals and alloys, with a mechanical and physical-chemical effect
US4604271A (en) * 1985-09-30 1986-08-05 The United States Of America As Represented By The Secretary Of The Army Magnesium borohydride diammoniate and triammoniate
US4692323A (en) * 1984-09-14 1987-09-08 Centre National De La Recherche Scientifique (C.N.R.S.) Process for separation of magnesium-based, and possibly fluorine-and aluminum-based impurities from a wet-produced phosphoric acid
US4699730A (en) * 1985-05-24 1987-10-13 Chemfil Corporation Magnesium sulfate and complex silicate mineral paint denaturant
US4746444A (en) * 1987-02-06 1988-05-24 Henry Filters, Inc. Prevention of chip build-up in filtration equipment
US5091161A (en) * 1986-11-21 1992-02-25 Noranda, Inc. Production of pure magnesium chloride solution from siliceous magnesium minerals
US5286285A (en) * 1989-05-05 1994-02-15 Veitscher Magnesitwerke-Actien-Gesellschaft Finely powdery magnesium hydroxide and a process for preparing thereof
US5476249A (en) * 1994-10-27 1995-12-19 Aluminum Pechiney Ladle for the filtration of liquid metal over a filter medium with improved heating
US5534168A (en) * 1991-05-24 1996-07-09 Exxon Chemical Patents Inc. Preparation of overbased magnesium sulphonates
US5914440A (en) * 1997-03-18 1999-06-22 Noranda Inc. Method and apparatus removal of solid particles from magnesium chloride electrolyte and molten magnesium by filtration

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3843355A (en) * 1972-04-04 1974-10-22 Dow Chemical Co Method for melting and purifying magnesium
US4024056A (en) * 1975-07-21 1977-05-17 Swiss Aluminium Ltd. Filtering of molten metal
US4092153A (en) * 1977-07-29 1978-05-30 Swiss Aluminium Limited Filtering and inline degassing of molten metal
US4124506A (en) * 1977-09-22 1978-11-07 Swiss Aluminium Ltd. Method for the filtration of molten metal in a crucible type furnace
US4640497A (en) * 1985-10-25 1987-02-03 Swiss Aluminium Ltd. Filtration apparatus
JPH033572Y2 (en) * 1986-10-17 1991-01-30
JPH0426725A (en) * 1990-05-18 1992-01-29 Ngk Insulators Ltd Filter medium for molten metal
FR2711560B1 (en) * 1993-10-27 1995-11-24 Pechiney Aluminium Liquid metal filtration bag on filter medium with improved heating.
NO311437B1 (en) * 1999-03-31 2001-11-26 Norsk Hydro As Process and apparatus for refining magnesium and magnesium alloys

Patent Citations (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3281238A (en) * 1963-11-13 1966-10-25 Aluminum Co Of America Treatment of molten aluminous metal
US4010186A (en) * 1971-04-05 1977-03-01 Ppg Industries, Inc. Removal of lead from aqueous solution using metallic magnesium
US4154802A (en) * 1976-06-09 1979-05-15 Brandt Peter J Upgrading of magnesium containing materials
US4337157A (en) * 1978-03-17 1982-06-29 Manville Service Corporation Biopolymer filtration process
US4194884A (en) * 1978-11-24 1980-03-25 Thermo Electron Corporation Method and apparatus for air sampling and filtration
US4409194A (en) * 1978-12-14 1983-10-11 Stauffer Chemical Company Method of separating magnesium from wet process superphosphoric acid
US4334990A (en) * 1979-08-24 1982-06-15 Servimetal Cartridge for active filtration and treatment of liquid metals and alloys
US4457496A (en) * 1980-01-14 1984-07-03 Servimetal Filtration block for liquid metals and alloys, with a mechanical and physical-chemical effect
US4418028A (en) * 1980-01-14 1983-11-29 Servimetal Filtration block for liquid metals and alloys, with a mechanical and physical-chemical effect
US4303610A (en) * 1980-05-19 1981-12-01 Pennzoil Company Test kit for field analysis of plant tissue magnesium and calcium
US4692323A (en) * 1984-09-14 1987-09-08 Centre National De La Recherche Scientifique (C.N.R.S.) Process for separation of magnesium-based, and possibly fluorine-and aluminum-based impurities from a wet-produced phosphoric acid
US4699730A (en) * 1985-05-24 1987-10-13 Chemfil Corporation Magnesium sulfate and complex silicate mineral paint denaturant
US4604271A (en) * 1985-09-30 1986-08-05 The United States Of America As Represented By The Secretary Of The Army Magnesium borohydride diammoniate and triammoniate
US5091161A (en) * 1986-11-21 1992-02-25 Noranda, Inc. Production of pure magnesium chloride solution from siliceous magnesium minerals
US4746444A (en) * 1987-02-06 1988-05-24 Henry Filters, Inc. Prevention of chip build-up in filtration equipment
US5286285A (en) * 1989-05-05 1994-02-15 Veitscher Magnesitwerke-Actien-Gesellschaft Finely powdery magnesium hydroxide and a process for preparing thereof
US5534168A (en) * 1991-05-24 1996-07-09 Exxon Chemical Patents Inc. Preparation of overbased magnesium sulphonates
US5476249A (en) * 1994-10-27 1995-12-19 Aluminum Pechiney Ladle for the filtration of liquid metal over a filter medium with improved heating
US5914440A (en) * 1997-03-18 1999-06-22 Noranda Inc. Method and apparatus removal of solid particles from magnesium chloride electrolyte and molten magnesium by filtration

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101039725B1 (en) 2009-03-23 2011-06-09 (주)이노캐스트 Apparatus and method for regenerating scrap of magnesium alloy
WO2016131174A1 (en) * 2015-02-16 2016-08-25 谭何易 Production line for producing national-standard magnesium alloy ingots on the basis of magnesium alloy waste material
CN108193061A (en) * 2017-12-21 2018-06-22 李本根 A kind of purifying plant for rare earth feed liquid
CN108237206A (en) * 2018-02-28 2018-07-03 厦门格欧博新材料科技有限公司 A kind of salt core former
CN110724833A (en) * 2019-11-27 2020-01-24 国科镁业科技(河南)有限公司 Application of simple substance silicon filter material in gas-phase magnesium purification and production system comprising same
CN113444888A (en) * 2021-06-29 2021-09-28 重庆大学 Method for purifying magnesium melt by adopting directional solidification

Also Published As

Publication number Publication date
SG121696A1 (en) 2006-05-26
WO2003033748A1 (en) 2003-04-24

Similar Documents

Publication Publication Date Title
EP0095645B1 (en) Method and apparatus for melting and casting metal
Wang et al. Formation of CaS on Al 2 O 3-CaO inclusions during solidification of steels
Apelian et al. Removal of inclusions from steel melts by filtration
US5913353A (en) Process for casting light metals
JP3003914B2 (en) Method for producing copper alloy containing active metal
US5143564A (en) Low porosity, fine grain sized strontium-treated magnesium alloy castings
US20050029718A1 (en) Filtration system for magnesium recycling and purification
EP1225236A1 (en) Process and apparatus for continuous vacuum purification of molten metal
WO2007092203A2 (en) Method to prepare metal structure suitable for semi-solid metal processing
Abdollahi et al. An evaluation of calcium as a eutectic modifier in A357 alloy
Baligidad et al. Processing of high carbon Fe3Al based intermetallic alloy
US6210478B1 (en) Refining and analysis of material using horizontal cold-crucible induction levitation melting
Brant et al. Fumeless in-line degassing and cleaning of liquid aluminum
Jarrett et al. Direct chill billet casting of aluminium alloys
Fan et al. Microstructure and mechanical properties of AZ91D magnesium alloy by expendable pattern shell casting with different mechanical vibration amplitudes and pouring temperatures
JP5369909B2 (en) Method for suppressing nozzle clogging of Zr-added steel and method for producing fine oxide-dispersed steel
Wang et al. Oxide film and porosity defects in magnesium alloy AZ91
Ashrafizadeh et al. Solidification structures and mechanical properties of Zn–27Al alloy cast in metal moulds
Wang Best practices for making high integrity lightweight metal castings-molten metal composition and cleanliness control
Yim et al. Effect of gas bubbling on tensile elongation of gravity mold castings of magnesium alloy
CN214665983U (en) Smelting device for preparing high-cleanliness magnesium or magnesium alloy melt
Haruna Removal of inclusions from cast superalloy revert
Luo et al. Development of inclusions in 3104 alloy melt during heating and holding treatments
Hohmann et al. Modern systems for production of high quality metal alloy powder
Da Silva et al. Analysis of Inclusions and Impurities Present in Typical Hpdc, Stamping and Extrusion Alloys Produced with Different Scrap Levels

Legal Events

Date Code Title Description
AS Assignment

Owner name: AGENCY FOR SCIENCE, TECHNOLOGY AND RESEARCH, SINGA

Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:HU, BANGHONG;TONG, KIN KONG;CHOY, CHEE MUN;AND OTHERS;REEL/FRAME:015166/0195;SIGNING DATES FROM 20040518 TO 20040630

STCB Information on status: application discontinuation

Free format text: ABANDONED -- FAILURE TO RESPOND TO AN OFFICE ACTION