US2004271A - Production of artificial filaments, threads, ribbons, films, and the like - Google Patents
Production of artificial filaments, threads, ribbons, films, and the like Download PDFInfo
- Publication number
- US2004271A US2004271A US491816A US49181630A US2004271A US 2004271 A US2004271 A US 2004271A US 491816 A US491816 A US 491816A US 49181630 A US49181630 A US 49181630A US 2004271 A US2004271 A US 2004271A
- Authority
- US
- United States
- Prior art keywords
- ribbons
- threads
- films
- filaments
- viscose
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000004519 manufacturing process Methods 0.000 title description 13
- 229920000297 Rayon Polymers 0.000 description 14
- 238000000034 method Methods 0.000 description 11
- 230000001112 coagulating effect Effects 0.000 description 9
- 238000009987 spinning Methods 0.000 description 8
- ZMZDMBWJUHKJPS-UHFFFAOYSA-M Thiocyanate anion Chemical compound [S-]C#N ZMZDMBWJUHKJPS-UHFFFAOYSA-M 0.000 description 7
- ZMZDMBWJUHKJPS-UHFFFAOYSA-N hydrogen thiocyanate Natural products SC#N ZMZDMBWJUHKJPS-UHFFFAOYSA-N 0.000 description 7
- 229920002678 cellulose Polymers 0.000 description 4
- 239000001913 cellulose Substances 0.000 description 4
- 239000000463 material Substances 0.000 description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- 230000015271 coagulation Effects 0.000 description 2
- 238000005345 coagulation Methods 0.000 description 2
- 230000008929 regeneration Effects 0.000 description 2
- 238000011069 regeneration method Methods 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000000080 wetting agent Substances 0.000 description 2
- ALWXETURCOIGIZ-UHFFFAOYSA-N 1-nitropropylbenzene Chemical compound CCC([N+]([O-])=O)C1=CC=CC=C1 ALWXETURCOIGIZ-UHFFFAOYSA-N 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
- 238000007792 addition Methods 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000000701 coagulant Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000002093 peripheral effect Effects 0.000 description 1
- 239000004627 regenerated cellulose Substances 0.000 description 1
- VGTPCRGMBIAPIM-UHFFFAOYSA-M sodium thiocyanate Chemical compound [Na+].[S-]C#N VGTPCRGMBIAPIM-UHFFFAOYSA-M 0.000 description 1
- 235000000346 sugar Nutrition 0.000 description 1
- 150000008163 sugars Chemical class 0.000 description 1
- 235000011149 sulphuric acid Nutrition 0.000 description 1
- 239000001117 sulphuric acid Substances 0.000 description 1
- 150000003567 thiocyanates Chemical class 0.000 description 1
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 description 1
- 235000009529 zinc sulphate Nutrition 0.000 description 1
- 239000011686 zinc sulphate Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F2/00—Monocomponent artificial filaments or the like of cellulose or cellulose derivatives; Manufacture thereof
- D01F2/06—Monocomponent artificial filaments or the like of cellulose or cellulose derivatives; Manufacture thereof from viscose
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F2/00—Monocomponent artificial filaments or the like of cellulose or cellulose derivatives; Manufacture thereof
- D01F2/06—Monocomponent artificial filaments or the like of cellulose or cellulose derivatives; Manufacture thereof from viscose
- D01F2/08—Composition of the spinning solution or the bath
Definitions
- any desired additions may be made to the coagulating liquids for the purpose of assisting or increasing the regeneration of the cellulose.
- a stretch may be applied to the materials during coagulation so as to draw them out to the required denier or cross-section.
- a stretch may be applied thereto after coagulation and during or after regeneration of the cellulose (where a subsequent treatment is applied for this purpose); for instance filaments may be carried in succession round two or more feed rollers having successively increasing peripheral speeds.
- Example relatively short time for example 18 30 hours, and in which the viscose has been allowed to stand for about 70-80 hours at 17 (3., is spun through a nozzle having spinning apertures of 0.08 millimetre diameter into an aqueous coagulating bath containing 6-8% of concentrated sulphuric acid, 20-30% of sodium thiocyanate, 1% of zinc sulphate, and 10% of glucose, the bath being maintained at a temperature of about 10 C., and the length of immersion of the filaments being 16-20 inches.
- the yarn is carried out of the coagulating bath and wound on a bobbin the rate of extrusion of the spinning solution from the nozzle.
- the yarn may be further Washed and dried as desired.
- thiocyanate used is that of sodium.
- Process for the manufacture of filaments, threads, ribbons, films or other products from viscose comprising spinning viscose into an aqueous coagulating bath containing a thiocyanate and a compound selected. from the group consisting of glycerine and sugars.
- Process for the manufacture of filaments, threads, ribbons, films or other products from viscose which comprises spinning viscose into an aqueous coagulating bath containing a thiocyanate and then treating the formed materials to regenerate the cellulose.
- Process for the manufacture of filaments, threads, ribbons, films or other products from viscose which comprises spinning viscose intoan aqueous coagulating bath containing a 'thiocyanate, subjecting the product to a stretching operation and then treating the formed materials to regenerate the cellulose.
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Artificial Filaments (AREA)
- Spinning Methods And Devices For Manufacturing Artificial Fibers (AREA)
Description
Patented June 11, 1935 2,004,271 PRODUCTION OF ARTIFICIAL FILAMENTS, THREADS, RIBBONS, FILMS, AND THE LIKE Henry Dreyfus, London, England N 0 Drawing. Application October 28, 1930, Serial No. 491,816. In Great Britain November .5, 1929 10 Claims. This invention relates to the manufacture f filaments, threads, ribbons, films, sheets or other products from viscose.
In prior U. S. Patent are described for the manufacture of filaments for example ammonium, sodium or calcium thiocyanate.
I have now found that such coagulating agents are advantageousin the case of the formation of filaments or other products of regenerated cellulose.
As in U. S. Patent No. 1,465,994 the process permits of the production of filaments or other cross-section of the products being produced. ning With relatively large jet orifices higher concentrations of thiocyanate may be employed than with smaller jet orifices. At the same time the use of relatively. concentrated solutions of thiocyanates enables the products to be drawn out to fine deniers or low cross-sections.
Any desired additions may be made to the coagulating liquids for the purpose of assisting or increasing the regeneration of the cellulose.
wetting agents.
As indicated above a stretch may be applied to the materials during coagulation so as to draw them out to the required denier or cross-section.
Alternatively or in addition a stretch may be applied thereto after coagulation and during or after regeneration of the cellulose (where a subsequent treatment is applied for this purpose); for instance filaments may be carried in succession round two or more feed rollers having successively increasing peripheral speeds.
The following example shows the best method For example, in spinknown to me for carrying the invention into effect, but it is not to be regarded as limiting it in any Way:-
Example relatively short time, for example 18 30 hours, and in which the viscose has been allowed to stand for about 70-80 hours at 17 (3., is spun through a nozzle having spinning apertures of 0.08 millimetre diameter into an aqueous coagulating bath containing 6-8% of concentrated sulphuric acid, 20-30% of sodium thiocyanate, 1% of zinc sulphate, and 10% of glucose, the bath being maintained at a temperature of about 10 C., and the length of immersion of the filaments being 16-20 inches. The yarn is carried out of the coagulating bath and wound on a bobbin the rate of extrusion of the spinning solution from the nozzle. The yarn may be further Washed and dried as desired.
What I claim and desire to secure by Letters I Patent is:
1. Process for the manufacture of filaments, threads, ribbons, films or other products from viscose, comprising spinning viscose into an aqueous, coagulating bath containing a thiccyanate.
2. Process according to claim 1, thiocyanate used is that of sodium.
3. Process for the manufacture of filaments,
wherein the thiocyanate in a concentration of 20 to 30%.
5. Process for the manufacture of filaments,
which either a. or b may be zero.
6. Process for the manufacture of filaments, threads, ribbons, films or other products from viscose, comprising spinning viscose into an aqueous coagulating bath containing a thiocyanate and a compound selected. from the group consisting of glycerine and sugars.
'7. Process for the manufacture of filaments threads, ribbons, films or other products from viscose, comprising spinning viscose into an aqueous coagulating bath containing a thiccyanate and a wetting agent.
8. Process for the manufacture of filaments, threads, ribbons, films or other products from. viscose, comprising spinning Viscose into an aqueous coagulating bath containing a thiocyanate, and subjecting the product to a stretching operation. 7
9. Process for the manufacture of filaments, threads, ribbons, films or other products from viscose, which comprises spinning viscose into an aqueous coagulating bath containing a thiocyanate and then treating the formed materials to regenerate the cellulose.
10. Process for the manufacture of filaments, threads, ribbons, films or other products from viscose, which comprises spinning viscose intoan aqueous coagulating bath containing a 'thiocyanate, subjecting the product to a stretching operation and then treating the formed materials to regenerate the cellulose.
HENRY DREYFUS.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB2004271X | 1929-11-05 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US2004271A true US2004271A (en) | 1935-06-11 |
Family
ID=10895797
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US491816A Expired - Lifetime US2004271A (en) | 1929-11-05 | 1930-10-28 | Production of artificial filaments, threads, ribbons, films, and the like |
Country Status (2)
| Country | Link |
|---|---|
| US (1) | US2004271A (en) |
| FR (1) | FR704279A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2433733A (en) * | 1945-01-04 | 1947-12-30 | Skenandoa Rayon Corp | Process of manufacturing viscose rayon yarn |
| US2462927A (en) * | 1943-11-06 | 1949-03-01 | Du Pont | Artificial filaments and yarn |
| US2777751A (en) * | 1951-03-08 | 1957-01-15 | American Cyanamid Co | Process for spinning aqueous-saline solutions of acrylonitrile polymers |
| DE1291050B (en) * | 1962-11-06 | 1969-03-20 | Chimiotex S A | Process for the production of regenerated cellulose threads |
| EP0587830A1 (en) * | 1992-01-10 | 1994-03-23 | Accurate Polymers, Ltd. | Cellulose chromatographic supports and method |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL219893A (en) * | 1956-08-29 |
-
1930
- 1930-10-23 FR FR704279D patent/FR704279A/en not_active Expired
- 1930-10-28 US US491816A patent/US2004271A/en not_active Expired - Lifetime
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2462927A (en) * | 1943-11-06 | 1949-03-01 | Du Pont | Artificial filaments and yarn |
| US2433733A (en) * | 1945-01-04 | 1947-12-30 | Skenandoa Rayon Corp | Process of manufacturing viscose rayon yarn |
| US2777751A (en) * | 1951-03-08 | 1957-01-15 | American Cyanamid Co | Process for spinning aqueous-saline solutions of acrylonitrile polymers |
| DE1291050B (en) * | 1962-11-06 | 1969-03-20 | Chimiotex S A | Process for the production of regenerated cellulose threads |
| EP0587830A1 (en) * | 1992-01-10 | 1994-03-23 | Accurate Polymers, Ltd. | Cellulose chromatographic supports and method |
| EP0587830A4 (en) * | 1992-01-10 | 1995-06-21 | Accurate Polymers Ltd | Cellulose chromatographic supports and method. |
Also Published As
| Publication number | Publication date |
|---|---|
| FR704279A (en) | 1931-05-16 |
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