US20040086609A1 - Anaerobic fermentation method and apparatus - Google Patents

Anaerobic fermentation method and apparatus Download PDF

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Publication number
US20040086609A1
US20040086609A1 US10/702,818 US70281803A US2004086609A1 US 20040086609 A1 US20040086609 A1 US 20040086609A1 US 70281803 A US70281803 A US 70281803A US 2004086609 A1 US2004086609 A1 US 2004086609A1
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Prior art keywords
airlock
apparatus recited
recited
bubbles
amount
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US10/702,818
Inventor
Andre Pazik
Daniel Kornacki
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KOPA HOLDINGS LLC
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Pazik Andre J
Kornacki Daniel C
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Filing date
Publication date
Application filed by Pazik Andre J, Kornacki Daniel C filed Critical Pazik Andre J
Priority to US10/702,818 priority Critical patent/US20040086609A1/en
Publication of US20040086609A1 publication Critical patent/US20040086609A1/en
Priority to PCT/US2004/036778 priority patent/WO2005042690A2/en
Assigned to KOPA HOLDINGS, LLC reassignment KOPA HOLDINGS, LLC ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: KORNACKI, DANIEL C., PAZIK, ANDRE J.
Assigned to BUFFALO AND ERIE COUNTY REGIONAL DEVELOPMENT CORPORATION reassignment BUFFALO AND ERIE COUNTY REGIONAL DEVELOPMENT CORPORATION SECURITY AGREEMENT Assignors: KOPA HOLDINGS, LLC
Abandoned legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C12BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12GWINE; PREPARATION THEREOF; ALCOHOLIC BEVERAGES; PREPARATION OF ALCOHOLIC BEVERAGES NOT PROVIDED FOR IN SUBCLASSES C12C OR C12H
    • C12G1/00Preparation of wine or sparkling wine
    • C12G1/02Preparation of must from grapes; Must treatment and fermentation
    • C12G1/0206Preparation of must from grapes; Must treatment and fermentation using a home wine making vessel
    • CCHEMISTRY; METALLURGY
    • C12BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12LPITCHING OR DEPITCHING MACHINES; CELLAR TOOLS
    • C12L11/00Cellar tools
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N33/00Investigating or analysing materials by specific methods not covered by groups G01N1/00 - G01N31/00
    • G01N33/02Food
    • G01N33/14Beverages
    • G01N33/146Beverages containing alcohol
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N33/00Investigating or analysing materials by specific methods not covered by groups G01N1/00 - G01N31/00
    • G01N33/48Biological material, e.g. blood, urine; Haemocytometers
    • G01N33/483Physical analysis of biological material
    • G01N33/497Physical analysis of biological material of gaseous biological material, e.g. breath
    • G01N33/4977Metabolic gas from microbes, cell cultures or plant tissues
    • CCHEMISTRY; METALLURGY
    • C12BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12GWINE; PREPARATION THEREOF; ALCOHOLIC BEVERAGES; PREPARATION OF ALCOHOLIC BEVERAGES NOT PROVIDED FOR IN SUBCLASSES C12C OR C12H
    • C12G2200/00Special features
    • C12G2200/31Wine making devices having compact design or adapted for home use

Definitions

  • This patent includes a computer program listing appendix on compact disc. Two duplicate compact discs are provided herewith. Each compact disc contains a computer program listing as follows:
  • the present invention relates generally to a method and apparatus useful during anaerobic fermentation, and more particularly to a method and apparatus for measuring the volume and rate of gas produced during anaerobic fermentation, this invention having particular utility during the making of alcoholic beverages.
  • the airlock may be molded from a clear plastic, all airlocks being quite uniform in size. It has been observed that when using some airlocks that each bubble has substantially the same volume, i.e., 1.7 ml. It is also known that during fermentation that equal mole volumes of CO 2 and alcohol are produced.
  • the present invention broadly comprises a method and apparatus for measuring gas produced during anaerobic fermentation.
  • the method comprises the steps of counting bubbles which pass through said airlock to determine a volume of gas produced and determining the amount of alcohol produced based on the volume of gas produced.
  • FIG. 1 illustrates a prior art “S” type airlock
  • FIG. 2 illustrates an airlock of a first embodiment of the present invention, an airlock being provided with electrodes;
  • FIG. 3 shows a dust cap for the modified “S” type airlock, which dust cap is provided with suitable contacts for contacting the electrodes in the modified “S” type airlock;
  • FIG. 4 shows a first embodiment of the present invention with the airlock being mounted on a vessel suitable for anaerobic fermentation
  • FIG. 5 shows a bubble interrupting the flow of current through between the electrodes, signaling a bubble event
  • FIG. 6 shows an embodiment of the electrical circuit of the control means
  • FIG. 7 shows an alternate embodiment of the electrical circuit of the control means
  • FIG. 8 illustrates a second embodiment of an airlock of the present invention
  • FIG. 9 illustrates a third embodiment of an airlock of the present invention.
  • FIG. 10 illustrates a fourth embodiment of an airlock of the present invention
  • FIG. 11 illustrates a fifth embodiment of the present invention, comprising an optical sensor and communication means
  • FIG. 12 illustrates an embodiment of the present invention wherein multiple control means are connected to a single communication control means
  • FIG. 13 illustrates an alternate embodiment of the present invention wherein multiple control means are connected to a single communication control means
  • FIG. 14 illustrates a schematic of the electrical circuit for the fifth embodiment of the present invention, comprising an optical sensor
  • FIGS. 15 and 16 illustrate an embodiment of the present invention wherein the optical detector is arranged to mate with a portion of an airlock having two parallel sides and two arcuate sides;
  • FIGS. 17 and 18 illustrate an embodiment of the present invention wherein the optical detector is arranged to mate with a portion of an airlock having a rectangular cross section;
  • FIGS. 19 and 120 illustrate an embodiment of the present invention wherein the optical detector is arranged to mate with a portion of an airlock having a hexagonal cross section.
  • an airlock is illustrated, said airlock being indicated generally at 10 .
  • This airlock consists of a molded clear plastic member indicated generally at 12 , the plastic member including an “S” shaped passageway which will be described later. Extending downwardly from the “S” shaped passageway is a mounting stem 14 which is inserted into the rubber bung or cork 16 of a fermenting vessel 18 so as to be an airtight fit.
  • the airlock is provided with a dust cap 20 at its upper end.
  • the “S” shaped passageway includes an upwardly extending portion 22 which is in direct communication with the stem 14 , the portion 22 being essentially cylindrical in cross section.
  • a “U” shaped member 24 having a circular cross section connects the portion 22 with a downwardly extending portion 26 having upper, intermediate, and lower bulbs 26 . 1 , 26 . 2 , and 26 . 3 , respectively.
  • a further “U” shaped member 28 having a circular cross section connects the lower end of the downwardly extending portion 26 with an upwardly extending portion 30 provided with upper, intermediate and lower bulbs 30 . 1 , 30 . 2 , and 30 . 3 , respectively.
  • An upwardly extending member 32 is provided with a bulb 34 at its top end, which bulb receives the dust cap 20 .
  • a clear plastic web or flashing 36 extends between the downwardly extending portion 26 and the upwardly extending portion 30 , and also between the downwardly extending portion 26 and the upwardly extending portion 22 to keep the various parts in fixed relationship to each other.
  • the vessel which liquid may be a wine must, the vessel is sealed with an airlock at the commencement of anaerobic fermentation.
  • a sterilizing liquid is placed in the “S” shaped airlock, the sterilizing liquid filling the “U” shaped member 28 and 1 ⁇ 2 of each of the lower bulbs 26 . 3 and 30 . 3 , the sterilizing liquid being indicated generally at SL in FIG. 2.
  • the sterilizing liquid typically contains either sodium or potassium metabisulfite, although other sterilizing agents may be used.
  • the yeast is less active than during the initial aerobic fermentation, and the CO 2 produced with escape through the sterilizing liquid one bubble at a time.
  • the “S” type airlock of the present invention is provided with two electrodes 40 , 42 .
  • Electrode 40 is embedded in the flashing 36 which extends between the downwardly extending portion 26 and the upwardly extending portion 30 .
  • Additional flashing 44 is provided to one side of the upwardly extending portion 30 for the receipt of electrode 42 .
  • the electrodes have lower terminal ends that extend into the passageway 28 . Normally the ends of the electrodes are covered with the sterilizing liquid, which conducts electricity. Thus, when a voltage is applied between them, current flows between the electrodes. However, when a bubble passes through the tube 28 , the current flow between the electrodes is interrupted. Dust cap 20 , shown in FIG. 3, prevents dust from settling into the airlock when it is engaged with the top of airlock 12 .
  • Conducting members 21 connect to electrodes 40 and 42 .
  • Electrodes 40 and 42 are connected to control means 60 through conducting members 21 .
  • Control means 60 comprises control buttons 65 A, 65 B, 65 C, 65 D, and 65 E, and a display 70 .
  • Bottle 18 contains wine must W.
  • Control means 60 counts the number of times the current between electrodes 40 and 42 is interrupted.
  • Control means 60 determines the status of the fermenting liquid based on the history of bubbles detected.
  • Control means 60 displays the status of the fermenting liquid on display 70 .
  • Bubble 50 created by the production of CO 2 during fermentation, envelops the exposed conductive material of both electrodes. Thus, with a low voltage drop across the electrodes, the gas does not conduct electricity between the electrodes. A preferred voltage drop across the electrodes is approximately 5 V, although other voltage drops might be suitable.
  • the control means of the apparatus records each interruption in the current as a bubble event.
  • FIG. 6 is a schematic of an embodiment of the electrical circuit of the control means.
  • the circuit shown comprises electrodes 40 and 42 , a 5 V source, resistor 85 , operational amplifier (op amp) 87 , positive and negative power supplies V + and V ⁇ to power the op amp, and processor 90 .
  • Processor 90 is a conventional microprocessor, well known to those in the electronics art.
  • the 5 V source is connected across electrodes 40 and 42 through resistor 85 .
  • V in ⁇ When current exists between the electrodes, V in ⁇ is 0 V.
  • the 5 V source is shorted to ground.
  • V in ⁇ is no longer zero.
  • V in+ is connected to ground.
  • processor 90 can determine the presence of a bubble between electrodes 40 and 42 from the output of operational amplifier 87 .
  • FIG. 7 shows a second possible embodiment of control means 60 .
  • This embodiment comprises a plurality of control buttons 65 A, 65 B, 65 C, 65 D, 65 E, and 65 F, electrodes 40 and 42 , a 5 V source, resistor 89 , pin 88 of processor 90 , audio alarm 92 , and visual alarm 94 .
  • Pin 88 of processor 90 is connected to electrode 40 and to a 5 V source through resistor 89 .
  • Electrode 42 is connected to ground. When current exists between the electrodes, pin 88 is shorted to ground. When the current is interrupted by a bubble, pin 88 will be lifted to a non-zero voltage. (The voltage level will depend on the resistance value of resistor 89 ). In this manner, processor 90 can determine the presence of bubbles between electrodes 40 and 42 .
  • a measure volume of a liquid subject to fermentation such as a wine-must
  • a container is placed in a container.
  • the airlock of the present invention is inserted in the neck of the container.
  • the user programs the volume of liquid present in the container using the control buttons.
  • control means 60 are configured as follows. First, the batch size must be set. Button 65 A increases the batch size by 10 liters each time it is pushed. Button 65 B increases the batch size one liter each time it is pushed. Button 65 C accepts the batch size when it is pushed, if the batch size is non-zero. (Buttons 65 D and 65 E have no function in setup mode). After the batch size is set, the user can enter a user specified time alarm, to be activated when the enter amount of time passes without a bubble being detected. Button 65 A increases this alarm time by one hour each time it is pushed. Button 65 B increases this alarm time by one minute each time it is pushed. Button 65 C accepts the current alarm time.
  • Button 65 A increases the alcohol level alarm by one percent each time it is pushed.
  • Button 65 B increases the alcohol level alarm by one tenth of one percent each time it is pushed.
  • Button 65 C accepts the current alcohol level.
  • the user can activate the 24 hour alarm.
  • Button 65 A enables the 24 hour alarm.
  • Button B disables the 24 hour alarm.
  • Button 65 C accepts the current 24 hour alarm status.
  • the control means detects the bubbles of gas escaping from the airlock and displays the status of the liquid on display 70 .
  • control means 60 determines the amount of gas to escape from the airlock.
  • the amount of alcohol generated during anaerobic fermentation can be determined based on the volume of CO 2 generated (assuming substantially all of the escaping gas is CO 2 generated by fermentation) and the amount of liquid present in the container (input using the control buttons, as discussed above). Accordingly, control means 60 can calculate the volume of alcohol generated and display this amount on display 70 .
  • buttons of the control means function as follows.
  • Button 65 A scrolls the display of the bubble events towards the most current event.
  • Button 65 B scrolls the display of the bubble events towards the least recent event.
  • Button 65 C deletes the display of the displayed event if pressed alone.
  • Button 65 D caused the control means to reenter setup mode.
  • Button 65 E silences current alarms and calls up a screen to review past alarms. Display 70 is set to the most recent event when button 65 E is released. When buttons 65 C and 65 E are pressed simultaneously, past alarms are cleared.
  • control means 60 displays a countdown of the amount of alcohol still to be generated.
  • Control means 60 can include an audible alarm 94 and/or visual alarm 96 to signal a user when the desired amount of alcohol has been produced. This can be especially useful in making beverages wherein some fermentation is desired after the liquid is bottled. The alarm can be set to alert the user when a portion of the desired alcohol has been produced. The user can then transfer the beverage to individual bottles for the remaining fermentation. This is also useful for the production of a sweet beverage. The user can stop fermentation before all the sugar has been consumed by the yeast.
  • This alarm also allows a user to add further ingredients at different stages of the fermentation, such as the addition of malolactic cultures, nutrients, and other ingredients known in the art.
  • the present invention allows for greater quality control in production by determining to a greater accuracy the proper time to add additional ingredients.
  • Control means 60 also includes timing means to determine the amount of time between each bubble.
  • Counting means displays the amount of time since the last bubble on display 70 .
  • Audible and/or visible alarms can be activated to alert the user after a specified time without a bubble has been reached. In one embodiment, this time period is 24 hours. In another embodiment, this time period is set by the user using the control buttons (the user specified alarm discussed above).
  • a potential problem with fermentations that can take a long period of time is the evaporation of the sterilizing liquid. If the sterilizing liquid evaporated to the point wherein outside air may pass into vessel 18 , then the fermentation may be spoiled.
  • the present invention warns a user when the level of the sterilizing liquid is low. Electrodes 40 and 42 are placed in member 28 such that they are exposed to air before the liquid level drops to an extent that air could reenter vessel 18 , as shown in FIG. 2. Control means 60 times the length of the bubbles. If the sterilizing liquid has partially evaporated, then the electrodes will be exposed to air continuously.
  • control means 60 when control means 60 detects an interruption of the current that lasts an extended period of time (in one embodiment 1 hour), it displays a low liquid level warning on display 60 . Audible and/or visible alarms may also be activated.
  • bubble detection indicator 92 is lit when a bubble is being detected (when current is not flowing between electrodes 40 and 42 .) This can also allow a user to determine there is a problem if the bubble detection indicator remains lit for an extended period of time.
  • the low liquid level warning and bubble detection indicator allow a user to replace the lost sterilizing liquid before the fermenting liquid is spoiled.
  • FIGS. 2, 4, and 5 show the present invention being practiced with an “S” type airlock.
  • FIGS. 8 - 10 illustrate several valves known in the art.
  • FIG. 8 shows a flapper check valve 110 . Electrodes 140 and 142 contact conducting strip 145 on flapper 115 when the valve is closed. Thus, when the valve is closed, current flows from electrode 140 to electrode 142 through strip 145 . When flapper 115 is forced open by gas pressure, the current flowing between electrode 140 and electrode 142 is interrupted. Thus, the number of times gas escapes from the valve can be counted.
  • FIG. 9 shows a piston check valve 210 comprising electrodes 240 and 242 , and valve member 215 having conducting strip 245 on a surface thereon.
  • FIG. 10 shows ball check valve 310 comprising electrodes 340 and 342 and conducting ball 345 . When the valve is closed, current flows from electrode 340 to electrode 342 through conducting ball 345 .
  • airlock is intended to mean any airlock or valve known in the art or hereafter developed that can be modified as described herein to practice the present invention.
  • An embodiment of the present invention may be arranged to have the elevation of the apparatus entered using the control buttons or through the communication means described below.
  • the processing means adjusts the calculated alcohol percentage by volume based on the altitude of the apparatus. This corrected alcohol percentage by volume is used in computing the amount of alcohol present in the solution being fermented.
  • An embodiment of the present invention can also include a flow rate alarm, where the flow rate, for example computed in cubic centimeters of alcohol produced per hour per liter of liquid, can be corrected based on the elevation of the apparatus. When the flow rate of alcohol exceeds a threshold in put by a user, the alarm is sounded. This may be a visual or optical alarm, as discussed above. Software that implements the above-described functions is included in the appendix.
  • Apparatus 410 comprises control means 460 , display 470 , and communication control means 475 .
  • Control means 460 comprises control buttons 465 A, 465 B, 465 C, 465 D, and 465 E.
  • Apparatus 410 also includes optical sensor 450 arranged to mate with portion 428 of airlock 412 .
  • Wire 448 connects sensor 450 to control means 460 .
  • Airlock 412 contains sterilizing liquid SL.
  • the display and control buttons function as described above for the first embodiment.
  • Communication control means 475 communicates with information system 490 with communication means 480 .
  • Communication means 480 may comprise a hard wire or a wireless connection, both of which are known in the art.
  • Information system 490 may comprise a single personal computer, a local area network, a wide area network such as the Internet, a wireless phone system, a pager system, a personal digital assistant system, or any other information system known in the art.
  • apparatus 410 is arranged to transmit and receive messages over communication means 480 to and from information system 490 .
  • the appendix contains a software listing that, when loaded on a general purpose microprocessor, transmits messages to a digital cellular phone.
  • the apparatus may receive parameters for programming the apparatus from the information system.
  • a local personal computer, a computer connected to the Internet, a personal digital assistant, or any of the other information system known in the art may be used to program the present invention.
  • the apparatus may transmit the status of any of the above-described alarms to any of the information systems known in the art.
  • a user can be warned by cell phone, pager, or personal digital assistant that the alcohol alarm is active.
  • the status of the fermentation may be emailed to a user, or it may be posted on a website.
  • the communication means can receive all of the parameters used to program the control means, as discussed above, such as altitude, batch size, user specified time alarm setting (alarm activated when no bubbles are detected for specified time), alcohol level alarm (alarm activated when alcohol level reaches specified level), and enabling/disabling the 24 hour alarm.
  • the data received by the communication means can comprise commands to clear any specific alarm, or all alarms.
  • the data transmitted by the communication means can comprise: alcohol level, alarm status, time since the last bubble detection, bubble count, or any other parameter stored in the control means. It should be readily apparent to one skilled in the art that other parameters may be used by the control means, and these parameters may be sent over the communication means. These modifications are within the spirit and scope of the invention as claimed.
  • the communication means may transmit messages using RS-232 protocol, Transfer Control Protocol/Internet Protocol (TCP/IP), Universal Serial Bus (USB) protocol, or any other protocol known in the art.
  • TCP/IP Transfer Control Protocol/Internet Protocol
  • USB Universal Serial Bus
  • the software listing in the appendix when loaded on a conventional general purpose microprocessor, sends messages using the RS-232 protocol.
  • An embodiment of the present invention may also be configured to log the data sent to and received form the control means. This allows a user to evaluate the batch either by comparison to an ideal fermentation, or comparison to other fermentation batches, for example graphically. It should be readily apparent to one skilled in the art that data from the present invention can be logged into a database program and displayed graphically, with commercially available software packages, as described above.
  • FIG. 12 illustrates an embodiment of the present invention wherein communication control means 475 sends and receives data from multiple control means 460 A, 460 B, and 460 C.
  • Communication control means 475 communicates with information system 490 over communication means 480 .
  • Communication control means 475 comprises at least one port 477 .
  • control means 460 A, 460 B, and 460 C are each connected to communication control means 475 .
  • the connection is made by connecting wire 478 between port 477 of communication control means 475 and port 462 of control means 460 A, 460 B, and 460 C, respectively.
  • FIG. 13 shows another embodiment of the present invention wherein control means 460 A, 460 B, and 460 C are daisy chained together.
  • Control means 460 A is connected to control means 460 B with a wire 478 connected between port 462 of control means 460 A and port 462 of control means 460 B.
  • Control means 460 B is connected to control means 460 C with a wire 478 connected between port 462 of control means 460 B and port 462 of control means 460 C.
  • Control means 460 C is connected to communication control means 475 with a wire 478 connected between port 462 of control means 460 C and port 477 of communication control means 475 .
  • any combination of direct connections to a communication control means and daisy chaining multiple control means are possible, and these modifications are within the spirit and scope of the invention as claimed.
  • the present invention may also be practiced as shown in FIG.
  • control means 475 is integral with control means 460 .
  • each control means 460 communicates with the information system 490 through its respective communication control means 475 .
  • the control means 460 shown in FIGS. 12 and 13 may comprise optical sensors as shown in FIG. 11, or may comprise two electrodes, as shown in FIG. 4. Any bubble counting apparatus comprising communication means for transmitting and receiving data to and from an information system is within the spirit and scope of the invention as claimed.
  • FIG. 14 is a schematic of an exemplary embodiment of an electrical circuit for an embodiment of the present invention comprising optical sensor 450 .
  • Sensor 450 comprises optical beam emitter 452 and optical beam detector 454 .
  • emitter 452 is an LED and detector 454 is a phototransistor.
  • Beam emitter 452 emits a light beam towards detector 454 .
  • the beam passes through the wall 428 A of airlock portion 428 .
  • Wall 428 A is normal to the line connecting emitter 452 and detector 454 .
  • the beam enters the interior of airlock portion 428 normal to the surface of wall 428 A.
  • the beam passes through the sterilizing liquid, through wall 428 B of the airlock portion 428 , and is incident on detector 454 .
  • phototransistor 454 When light is incident on phototransistor 454 , current may flow through the phototransistor. This shorts connection 456 to ground.
  • bubble 50 passes through airlock portion 428 , the edges 52 will refract the incident light that is propagating in a direction normal to walls 428 A and 428 B in a direction that is not normal to walls 428 A and 428 B.
  • bubble edge 52 is located between emitter 452 and detector 454 , light will not be incident on detector 454 . This disables current from flowing through phototransistor 454 , which isolates pin 456 from ground.
  • the 5 V source pulls pin 456 up to 5 V.
  • the beam passes through the gas mixture to the detector. This allows current to flow through the phototransistor, pulling pin 456 down to 0 V.
  • Pin 456 is connected to a general purpose microprocessor programmed to monitor the voltage transitions at pin 456 between 0 V and 5 V. Thus, the processor increments the bubble count by 1 for each pair of interruptions of the light beam (each pair of 5 V pulses at pin 456 ).
  • Optical sensor 450 may comprise a sensor such as the Omron® EE-SX198, EE-SX199, EE-SX1018, EE-SX1025, EE-SX1041, EE-SX1042, E-SX1070, or EE-SX1071, available from Omron Corporation, Shiokoji Horikawa, Shimogyo-ku, Kyoto, 600-8530 Japan.
  • the processor is programmed to use the bubble count as described above for the first embodiment.
  • the appendix contains a software listing for a processor using the optical sensor of the present embodiment.
  • any airlock may be used with the embodiment comprising an optical sensor, providing it comprises a portion with two parallel sides.
  • FIGS. 15 and 16 show optical sensor 450 arranged to detect bubbles passing through airlock portion 428 having two parallel sides 428 A and 428 B, and two arcuate sides 428 C.
  • FIGS. 17 and 18 show optical sensor 450 arranged to detect bubbles passing through airlock portion 428 having a rectangular cross section, with two parallel sides 428 A and 428 B and two parallel sides 428 D that are perpendicular to sides 428 A and 428 B.
  • 19 and 20 show optical sensor 450 arranged to detect bubbles passing through airlock portion 428 having two parallel sides 428 A and 428 B, and sides 428 E that form a hexagonal cross section. It should be readily apparent to one skilled in the art that airlocks having portions with cross sections of other shapes, with two parallel sides are possible, and these modifications are within the spirit and scope of the invention as claimed.

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Abstract

A method and apparatus for monitoring a liquid undergoing anaerobic fermentation in a vessel is disclosed. The apparatus comprises an airlock containing a fluid for sealing the vessel and means to detect passage of bubbles through the airlock.

Description

    CROSS-REFERENCE TO RELATED APPLICATIONS
  • This application is a Continuation-in-Part of U.S. application Ser. No. 10/289,033, filed Nov. 6, 2002, incorporated by reference herein.[0001]
  • REFERENCE TO COMPUTER PROGRAM LISTING APPENDIX
  • This patent includes a computer program listing appendix on compact disc. Two duplicate compact discs are provided herewith. Each compact disc contains a computer program listing as follows: [0002]
  • Filename: Fermentometer_Interface3.vbp [0003]
  • Size: 2 kilobytes [0004]
  • Date Created: Aug. 20, 2003 [0005]
  • Filename: Main2.frm [0006]
  • Size: 61 kilobytes [0007]
  • Date Created: Aug. 20, 2003 [0008]
  • Filename: Module1.bas [0009]
  • Size: 1 kilobyte [0010]
  • Date Created: Aug. 20, 2003 [0011]
  • Filename: patent01.c [0012]
  • Size: 20 kilobytes [0013]
  • Date Created: Aug. 20, 2003 [0014]
  • Filename: hc11.h [0015]
  • Size: 4 kilobytes [0016]
  • Date Created: Aug. 20, 2003 [0017]
  • Filename: _const.h [0018]
  • Size: 1 kilobyte [0019]
  • Date Created: Aug. 20, 2003 [0020]
  • Filename: stdio.h [0021]
  • Size: 1 kilobyte [0022]
  • Date Created: Aug. 20, 2003 [0023]
  • The computer program listing appendix is hereby expressly incorporated by reference in the present application. [0024]
  • FIELD OF THE INVENTION
  • The present invention relates generally to a method and apparatus useful during anaerobic fermentation, and more particularly to a method and apparatus for measuring the volume and rate of gas produced during anaerobic fermentation, this invention having particular utility during the making of alcoholic beverages. [0025]
  • BACKGROUND OF THE INVENTION
  • It is common when making alcoholic beverages in the home to place the liquid subject to fermentation into a vessel for anaerobic fermentation, the vessel being closed by a fermentation airlock. The purpose of the fermentation airlock is to prevent undesirable dust and bacteria from contaminating the material being fermented. Therefore it is common to utilize an airtrap, the gas produced by fermentation bubbling though a liquid in the airtrap, the liquid typically containing water and a sterilizing agent such as sodium or potassium metabisulfite. Differing types of fermentation locks are employed, various examples being shown in U.S. Pat. Nos. 4,517,884, 4,842,869, and 5,950,524. A favorite form of airlock is the “S” type airlock, variations being shown in U.S. Pat. Nos. 2,023,153 and 4,717,031, and German patents 412,918 and 957,563. Another prior art form of “S” type airlock is shown in FIG. 1 of this application. [0026]
  • The airlock may be molded from a clear plastic, all airlocks being quite uniform in size. It has been observed that when using some airlocks that each bubble has substantially the same volume, i.e., 1.7 ml. It is also known that during fermentation that equal mole volumes of CO[0027] 2 and alcohol are produced.
  • SUMMARY OF THE INVENTION
  • The present invention broadly comprises a method and apparatus for measuring gas produced during anaerobic fermentation. The method comprises the steps of counting bubbles which pass through said airlock to determine a volume of gas produced and determining the amount of alcohol produced based on the volume of gas produced. [0028]
  • The above objects, and other objects and advantages of this invention will become more apparent to those skilled in the art after a consideration of the following detailed description taken in conjunction with the accompanying drawings in which a preferred form of this invention is illustrated. [0029]
  • BRIEF DESCRIPTION OF THE DRAWINGS
  • It should be appreciated that, in the detailed description of the invention which follows, like reference numbers on different drawing views are intended to identify identical structural elements of the invention in the respective views. [0030]
  • FIG. 1 illustrates a prior art “S” type airlock; [0031]
  • FIG. 2 illustrates an airlock of a first embodiment of the present invention, an airlock being provided with electrodes; [0032]
  • FIG. 3 shows a dust cap for the modified “S” type airlock, which dust cap is provided with suitable contacts for contacting the electrodes in the modified “S” type airlock; [0033]
  • FIG. 4 shows a first embodiment of the present invention with the airlock being mounted on a vessel suitable for anaerobic fermentation; [0034]
  • FIG. 5 shows a bubble interrupting the flow of current through between the electrodes, signaling a bubble event; [0035]
  • FIG. 6 shows an embodiment of the electrical circuit of the control means; [0036]
  • FIG. 7 shows an alternate embodiment of the electrical circuit of the control means; [0037]
  • FIG. 8 illustrates a second embodiment of an airlock of the present invention; [0038]
  • FIG. 9 illustrates a third embodiment of an airlock of the present invention; [0039]
  • FIG. 10 illustrates a fourth embodiment of an airlock of the present invention; [0040]
  • FIG. 11 illustrates a fifth embodiment of the present invention, comprising an optical sensor and communication means; [0041]
  • FIG. 12 illustrates an embodiment of the present invention wherein multiple control means are connected to a single communication control means; [0042]
  • FIG. 13 illustrates an alternate embodiment of the present invention wherein multiple control means are connected to a single communication control means; [0043]
  • FIG. 14 illustrates a schematic of the electrical circuit for the fifth embodiment of the present invention, comprising an optical sensor; [0044]
  • FIGS. 15 and 16 illustrate an embodiment of the present invention wherein the optical detector is arranged to mate with a portion of an airlock having two parallel sides and two arcuate sides; [0045]
  • FIGS. 17 and 18 illustrate an embodiment of the present invention wherein the optical detector is arranged to mate with a portion of an airlock having a rectangular cross section; and, [0046]
  • FIGS. 19 and 120 illustrate an embodiment of the present invention wherein the optical detector is arranged to mate with a portion of an airlock having a hexagonal cross section.[0047]
  • DETAILED DESCRIPTION
  • With reference initially to FIG. 1, an airlock is illustrated, said airlock being indicated generally at [0048] 10. This airlock consists of a molded clear plastic member indicated generally at 12, the plastic member including an “S” shaped passageway which will be described later. Extending downwardly from the “S” shaped passageway is a mounting stem 14 which is inserted into the rubber bung or cork 16 of a fermenting vessel 18 so as to be an airtight fit. The airlock is provided with a dust cap 20 at its upper end.
  • The “S” shaped passageway includes an upwardly extending [0049] portion 22 which is in direct communication with the stem 14, the portion 22 being essentially cylindrical in cross section. A “U” shaped member 24 having a circular cross section connects the portion 22 with a downwardly extending portion 26 having upper, intermediate, and lower bulbs 26.1, 26.2, and 26.3, respectively. A further “U” shaped member 28 having a circular cross section connects the lower end of the downwardly extending portion 26 with an upwardly extending portion 30 provided with upper, intermediate and lower bulbs 30.1, 30.2, and 30.3, respectively. An upwardly extending member 32 is provided with a bulb 34 at its top end, which bulb receives the dust cap 20. A clear plastic web or flashing 36 extends between the downwardly extending portion 26 and the upwardly extending portion 30, and also between the downwardly extending portion 26 and the upwardly extending portion 22 to keep the various parts in fixed relationship to each other.
  • After the liquid to be fermented is placed in the vessel, which liquid may be a wine must, the vessel is sealed with an airlock at the commencement of anaerobic fermentation. To this end, a sterilizing liquid is placed in the “S” shaped airlock, the sterilizing liquid filling the “U” shaped [0050] member 28 and ½ of each of the lower bulbs 26.3 and 30.3, the sterilizing liquid being indicated generally at SL in FIG. 2. The sterilizing liquid typically contains either sodium or potassium metabisulfite, although other sterilizing agents may be used. During anaerobic fermentation the yeast is less active than during the initial aerobic fermentation, and the CO2 produced with escape through the sterilizing liquid one bubble at a time.
  • With reference to FIG. 2, it can be seen that the “S” type airlock of the present invention is provided with two [0051] electrodes 40, 42. Electrode 40 is embedded in the flashing 36 which extends between the downwardly extending portion 26 and the upwardly extending portion 30. Additional flashing 44 is provided to one side of the upwardly extending portion 30 for the receipt of electrode 42. As can be seen from FIG. 2, the electrodes have lower terminal ends that extend into the passageway 28. Normally the ends of the electrodes are covered with the sterilizing liquid, which conducts electricity. Thus, when a voltage is applied between them, current flows between the electrodes. However, when a bubble passes through the tube 28, the current flow between the electrodes is interrupted. Dust cap 20, shown in FIG. 3, prevents dust from settling into the airlock when it is engaged with the top of airlock 12. Conducting members 21 connect to electrodes 40 and 42.
  • As illustrated in FIG. 4, [0052] electrodes 40 and 42 are connected to control means 60 through conducting members 21. Control means 60 comprises control buttons 65A, 65B, 65C, 65D, and 65E, and a display 70. Bottle 18 contains wine must W. Control means 60 counts the number of times the current between electrodes 40 and 42 is interrupted. Control means 60 determines the status of the fermenting liquid based on the history of bubbles detected. Control means 60 displays the status of the fermenting liquid on display 70.
  • The interruption of the current between the electrodes is illustrated in FIG. 5. [0053] Bubble 50, created by the production of CO2 during fermentation, envelops the exposed conductive material of both electrodes. Thus, with a low voltage drop across the electrodes, the gas does not conduct electricity between the electrodes. A preferred voltage drop across the electrodes is approximately 5 V, although other voltage drops might be suitable. The control means of the apparatus records each interruption in the current as a bubble event.
  • FIG. 6 is a schematic of an embodiment of the electrical circuit of the control means. The circuit shown comprises [0054] electrodes 40 and 42, a 5 V source, resistor 85, operational amplifier (op amp) 87, positive and negative power supplies V+ and V to power the op amp, and processor 90. Processor 90 is a conventional microprocessor, well known to those in the electronics art. The 5 V source is connected across electrodes 40 and 42 through resistor 85. When current exists between the electrodes, Vin− is 0 V. (The 5 V source is shorted to ground.) However, when a bubble interrupts the current through the electrodes, Vin− is no longer zero. (Ground is separated from Vin− by an open circuit.) Vin+ is connected to ground. Thus processor 90 can determine the presence of a bubble between electrodes 40 and 42 from the output of operational amplifier 87.
  • FIG. 7 shows a second possible embodiment of control means [0055] 60. This embodiment comprises a plurality of control buttons 65A, 65B, 65C, 65D, 65E, and 65F, electrodes 40 and 42, a 5 V source, resistor 89, pin 88 of processor 90, audio alarm 92, and visual alarm 94. Pin 88 of processor 90 is connected to electrode 40 and to a 5 V source through resistor 89. Electrode 42 is connected to ground. When current exists between the electrodes, pin 88 is shorted to ground. When the current is interrupted by a bubble, pin 88 will be lifted to a non-zero voltage. (The voltage level will depend on the resistance value of resistor 89). In this manner, processor 90 can determine the presence of bubbles between electrodes 40 and 42.
  • To use the above-described device, a measure volume of a liquid subject to fermentation, such as a wine-must, is placed in a container. (This is typically done after a period of aerobic fermentation and a hydrometer measurement to determine the proportion of sugar remaining.) The airlock of the present invention is inserted in the neck of the container. The user programs the volume of liquid present in the container using the control buttons. [0056]
  • In a preferred embodiment, control means [0057] 60 are configured as follows. First, the batch size must be set. Button 65A increases the batch size by 10 liters each time it is pushed. Button 65B increases the batch size one liter each time it is pushed. Button 65C accepts the batch size when it is pushed, if the batch size is non-zero. ( Buttons 65D and 65E have no function in setup mode). After the batch size is set, the user can enter a user specified time alarm, to be activated when the enter amount of time passes without a bubble being detected. Button 65A increases this alarm time by one hour each time it is pushed. Button 65B increases this alarm time by one minute each time it is pushed. Button 65C accepts the current alarm time. (Zero may be entered if no user specified time alarm is desired.) When the user specified alarm is set, the user can then enter an alcohol alarm level. Button 65A increases the alcohol level alarm by one percent each time it is pushed. Button 65B increases the alcohol level alarm by one tenth of one percent each time it is pushed. Button 65C accepts the current alcohol level. After the alcohol level alarm is set, the user can activate the 24 hour alarm. Button 65A enables the 24 hour alarm. Button B disables the 24 hour alarm. Button 65C accepts the current 24 hour alarm status. The control means then detects the bubbles of gas escaping from the airlock and displays the status of the liquid on display 70.
  • The status is determined based on the history of bubbles detected by control means [0058] 60. In one embodiment, airlock 12 is configured such that the escaping bubbles have a volume at room temperature and 1 atmosphere of pressure of 1.7 ml. (It is assumed that the fermentation is done at a constant temperature, thus an equal amount of gas is contained in each bubble). Thus, by counting the number of bubbles, control means 60 can determine the amount of gas to escape from the airlock. According to calculations known in the art, the amount of alcohol generated during anaerobic fermentation can be determined based on the volume of CO2 generated (assuming substantially all of the escaping gas is CO2 generated by fermentation) and the amount of liquid present in the container (input using the control buttons, as discussed above). Accordingly, control means 60 can calculate the volume of alcohol generated and display this amount on display 70.
  • In a preferred embodiment the buttons of the control means function as follows. [0059] Button 65A scrolls the display of the bubble events towards the most current event. Button 65B scrolls the display of the bubble events towards the least recent event. Button 65C deletes the display of the displayed event if pressed alone. Button 65D caused the control means to reenter setup mode. Button 65E silences current alarms and calls up a screen to review past alarms. Display 70 is set to the most recent event when button 65E is released. When buttons 65C and 65E are pressed simultaneously, past alarms are cleared.
  • As discussed above, a user can preprogram a percentage of alcohol desired with the control buttons. In this case, control means [0060] 60 displays a countdown of the amount of alcohol still to be generated. Control means 60 can include an audible alarm 94 and/or visual alarm 96 to signal a user when the desired amount of alcohol has been produced. This can be especially useful in making beverages wherein some fermentation is desired after the liquid is bottled. The alarm can be set to alert the user when a portion of the desired alcohol has been produced. The user can then transfer the beverage to individual bottles for the remaining fermentation. This is also useful for the production of a sweet beverage. The user can stop fermentation before all the sugar has been consumed by the yeast. This alarm also allows a user to add further ingredients at different stages of the fermentation, such as the addition of malolactic cultures, nutrients, and other ingredients known in the art. The present invention allows for greater quality control in production by determining to a greater accuracy the proper time to add additional ingredients.
  • Control means [0061] 60 also includes timing means to determine the amount of time between each bubble. Counting means displays the amount of time since the last bubble on display 70. Audible and/or visible alarms can be activated to alert the user after a specified time without a bubble has been reached. In one embodiment, this time period is 24 hours. In another embodiment, this time period is set by the user using the control buttons (the user specified alarm discussed above).
  • A potential problem with fermentations that can take a long period of time is the evaporation of the sterilizing liquid. If the sterilizing liquid evaporated to the point wherein outside air may pass into [0062] vessel 18, then the fermentation may be spoiled. The present invention warns a user when the level of the sterilizing liquid is low. Electrodes 40 and 42 are placed in member 28 such that they are exposed to air before the liquid level drops to an extent that air could reenter vessel 18, as shown in FIG. 2. Control means 60 times the length of the bubbles. If the sterilizing liquid has partially evaporated, then the electrodes will be exposed to air continuously. Thus, when control means 60 detects an interruption of the current that lasts an extended period of time (in one embodiment 1 hour), it displays a low liquid level warning on display 60. Audible and/or visible alarms may also be activated. In addition, bubble detection indicator 92 is lit when a bubble is being detected (when current is not flowing between electrodes 40 and 42.) This can also allow a user to determine there is a problem if the bubble detection indicator remains lit for an extended period of time. The low liquid level warning and bubble detection indicator allow a user to replace the lost sterilizing liquid before the fermenting liquid is spoiled.
  • FIGS. 2, 4, and [0063] 5 show the present invention being practiced with an “S” type airlock. However, it should be readily apparent to one skilled in the art that other airlocks or valves may be modified to practice the present invention. FIGS. 8-10 illustrate several valves known in the art. FIG. 8 shows a flapper check valve 110. Electrodes 140 and 142 contact conducting strip 145 on flapper 115 when the valve is closed. Thus, when the valve is closed, current flows from electrode 140 to electrode 142 through strip 145. When flapper 115 is forced open by gas pressure, the current flowing between electrode 140 and electrode 142 is interrupted. Thus, the number of times gas escapes from the valve can be counted. The amount of gas that escapes each time is measured and programmed into control means 60. In this manner, a fermentation process can be monitored as described above. In a similar manner, FIG. 9 shows a piston check valve 210 comprising electrodes 240 and 242, and valve member 215 having conducting strip 245 on a surface thereon. When the valve is closed, current flows from electrode 240 to electrode 242 through strip 245. When member 215 is forced open by gas pressure, the current flowing between electrode 240 and electrode 242 is interrupted. FIG. 10 shows ball check valve 310 comprising electrodes 340 and 342 and conducting ball 345. When the valve is closed, current flows from electrode 340 to electrode 342 through conducting ball 345. When ball 345 is forced up by gas pressure, the current flowing between electrode 340 and electrode 342 is interrupted. The amount of gas released each time the valve opens is used to determine how much gas is produced during fermentation, in the manner described above. These modifications, including the use of the practicing of the present invention with other valves not shown, is intended to be within the spirit and scope of the invention as claimed. In the present specification and claims, the word “airlock” is intended to mean any airlock or valve known in the art or hereafter developed that can be modified as described herein to practice the present invention.
  • An embodiment of the present invention may be arranged to have the elevation of the apparatus entered using the control buttons or through the communication means described below. The processing means adjusts the calculated alcohol percentage by volume based on the altitude of the apparatus. This corrected alcohol percentage by volume is used in computing the amount of alcohol present in the solution being fermented. An embodiment of the present invention can also include a flow rate alarm, where the flow rate, for example computed in cubic centimeters of alcohol produced per hour per liter of liquid, can be corrected based on the elevation of the apparatus. When the flow rate of alcohol exceeds a threshold in put by a user, the alarm is sounded. This may be a visual or optical alarm, as discussed above. Software that implements the above-described functions is included in the appendix. [0064]
  • An embodiment of the present invention including communication means [0065] 480 is shown in FIG. 11. Apparatus 410 comprises control means 460, display 470, and communication control means 475. Control means 460 comprises control buttons 465A, 465B, 465C, 465D, and 465E. Apparatus 410 also includes optical sensor 450 arranged to mate with portion 428 of airlock 412. Wire 448 connects sensor 450 to control means 460. Airlock 412 contains sterilizing liquid SL. The display and control buttons function as described above for the first embodiment. Communication control means 475 communicates with information system 490 with communication means 480. Communication means 480 may comprise a hard wire or a wireless connection, both of which are known in the art. Information system 490 may comprise a single personal computer, a local area network, a wide area network such as the Internet, a wireless phone system, a pager system, a personal digital assistant system, or any other information system known in the art. Thus, apparatus 410 is arranged to transmit and receive messages over communication means 480 to and from information system 490. (For example, the appendix contains a software listing that, when loaded on a general purpose microprocessor, transmits messages to a digital cellular phone.)
  • The apparatus may receive parameters for programming the apparatus from the information system. Thus, a local personal computer, a computer connected to the Internet, a personal digital assistant, or any of the other information system known in the art may be used to program the present invention. The apparatus may transmit the status of any of the above-described alarms to any of the information systems known in the art. Thus, for example, a user can be warned by cell phone, pager, or personal digital assistant that the alcohol alarm is active. The status of the fermentation may be emailed to a user, or it may be posted on a website. The communication means can receive all of the parameters used to program the control means, as discussed above, such as altitude, batch size, user specified time alarm setting (alarm activated when no bubbles are detected for specified time), alcohol level alarm (alarm activated when alcohol level reaches specified level), and enabling/disabling the 24 hour alarm. The data received by the communication means can comprise commands to clear any specific alarm, or all alarms. The data transmitted by the communication means can comprise: alcohol level, alarm status, time since the last bubble detection, bubble count, or any other parameter stored in the control means. It should be readily apparent to one skilled in the art that other parameters may be used by the control means, and these parameters may be sent over the communication means. These modifications are within the spirit and scope of the invention as claimed. The communication means may transmit messages using RS-232 protocol, Transfer Control Protocol/Internet Protocol (TCP/IP), Universal Serial Bus (USB) protocol, or any other protocol known in the art. (For example, the software listing in the appendix, when loaded on a conventional general purpose microprocessor, sends messages using the RS-232 protocol.) It should be readily apparent to one skilled in the art that other communication means and information systems are possible, and these modifications are within the spirit and scope of the invention as claimed. [0066]
  • An embodiment of the present invention may also be configured to log the data sent to and received form the control means. This allows a user to evaluate the batch either by comparison to an ideal fermentation, or comparison to other fermentation batches, for example graphically. It should be readily apparent to one skilled in the art that data from the present invention can be logged into a database program and displayed graphically, with commercially available software packages, as described above. [0067]
  • FIG. 12 illustrates an embodiment of the present invention wherein communication control means [0068] 475 sends and receives data from multiple control means 460A, 460B, and 460C. Communication control means 475 communicates with information system 490 over communication means 480. Communication control means 475 comprises at least one port 477. As shown in FIG. 12, control means 460A, 460B, and 460C are each connected to communication control means 475. The connection is made by connecting wire 478 between port 477 of communication control means 475 and port 462 of control means 460A, 460B, and 460C, respectively. FIG. 13 shows another embodiment of the present invention wherein control means 460A, 460B, and 460C are daisy chained together. Control means 460A is connected to control means 460B with a wire 478 connected between port 462 of control means 460A and port 462 of control means 460B. Control means 460B is connected to control means 460C with a wire 478 connected between port 462 of control means 460B and port 462 of control means 460C. Control means 460C is connected to communication control means 475 with a wire 478 connected between port 462 of control means 460C and port 477 of communication control means 475. As should be readily apparent to one skilled in the art, any combination of direct connections to a communication control means and daisy chaining multiple control means are possible, and these modifications are within the spirit and scope of the invention as claimed. The present invention may also be practiced as shown in FIG. 11, wherein communication control means 475 is integral with control means 460. In this case, each control means 460 communicates with the information system 490 through its respective communication control means 475. It should be readily apparent to one skilled in the art that the control means 460 shown in FIGS. 12 and 13 may comprise optical sensors as shown in FIG. 11, or may comprise two electrodes, as shown in FIG. 4. Any bubble counting apparatus comprising communication means for transmitting and receiving data to and from an information system is within the spirit and scope of the invention as claimed.
  • FIG. 14 is a schematic of an exemplary embodiment of an electrical circuit for an embodiment of the present invention comprising [0069] optical sensor 450. Sensor 450 comprises optical beam emitter 452 and optical beam detector 454. In the embodiment shown, emitter 452 is an LED and detector 454 is a phototransistor. Beam emitter 452 emits a light beam towards detector 454. The beam passes through the wall 428A of airlock portion 428. Wall 428A is normal to the line connecting emitter 452 and detector 454. Thus, the beam enters the interior of airlock portion 428 normal to the surface of wall 428A. If no bubble is present in the sterilizing liquid, the beam passes through the sterilizing liquid, through wall 428B of the airlock portion 428, and is incident on detector 454. When light is incident on phototransistor 454, current may flow through the phototransistor. This shorts connection 456 to ground. When bubble 50 passes through airlock portion 428, the edges 52 will refract the incident light that is propagating in a direction normal to walls 428A and 428B in a direction that is not normal to walls 428A and 428B. Thus, when bubble edge 52 is located between emitter 452 and detector 454, light will not be incident on detector 454. This disables current from flowing through phototransistor 454, which isolates pin 456 from ground. The 5 V source pulls pin 456 up to 5 V. When the bubble is between the emitter and detector, the beam passes through the gas mixture to the detector. This allows current to flow through the phototransistor, pulling pin 456 down to 0 V. Thus, for each bubble that passes through airlock portion 428, the light beam will be interrupted briefly twice by each bubble edge 52, leading to two voltage pulses of 5V, compared to the normal value of 0V. Pin 456 is connected to a general purpose microprocessor programmed to monitor the voltage transitions at pin 456 between 0 V and 5 V. Thus, the processor increments the bubble count by 1 for each pair of interruptions of the light beam (each pair of 5 V pulses at pin 456). Optical sensor 450 may comprise a sensor such as the Omron® EE-SX198, EE-SX199, EE-SX1018, EE-SX1025, EE-SX1041, EE-SX1042, E-SX1070, or EE-SX1071, available from Omron Corporation, Shiokoji Horikawa, Shimogyo-ku, Kyoto, 600-8530 Japan. The processor is programmed to use the bubble count as described above for the first embodiment. The appendix contains a software listing for a processor using the optical sensor of the present embodiment.
  • It should be readily apparent to one skilled in the art that any airlock may be used with the embodiment comprising an optical sensor, providing it comprises a portion with two parallel sides. For example, FIGS. 15 and 16 show [0070] optical sensor 450 arranged to detect bubbles passing through airlock portion 428 having two parallel sides 428A and 428B, and two arcuate sides 428C. FIGS. 17 and 18 show optical sensor 450 arranged to detect bubbles passing through airlock portion 428 having a rectangular cross section, with two parallel sides 428A and 428B and two parallel sides 428D that are perpendicular to sides 428A and 428B. FIGS. 19 and 20 show optical sensor 450 arranged to detect bubbles passing through airlock portion 428 having two parallel sides 428A and 428B, and sides 428E that form a hexagonal cross section. It should be readily apparent to one skilled in the art that airlocks having portions with cross sections of other shapes, with two parallel sides are possible, and these modifications are within the spirit and scope of the invention as claimed.
  • While a preferred form of this invention has been described above and shown in the accompanying drawings, it should be understood that applicant does not intend to be limited to the particular details described above and illustrated in the accompanying drawings, but intends to be limited only to the scope of the invention as defined by the following claims. In this regard, the term “means for” as used in the claims is intended to include not only the designs illustrated in the drawings of this application and the equivalent designs discussed in the text, but it is also intended to cover other equivalents now known to those skilled in the art, or those equivalents which may become known to those skilled in the art in the future. [0071]

Claims (45)

What is claimed is:
1. A method for determining an amount of alcohol produced during anaerobic fermentation in a sealed anaerobic fermentation vessel containing a liquid being fermented, said vessel sealed with an airlock, the method comprising the steps of:
counting bubbles which pass through said airlock to determine a volume of gas produced, said bubbles detected by an optical detector; and,
determining said amount of alcohol produced based on said volume of gas produced.
2. The method recited in claim 1 further including the step of determining the interval between bubbles so that the rate of fermentation may be determined.
3. The method recited in claim 1 further including the step of activating an alarm when a desired amount of alcohol is produced.
4. The method recited in claim 1 wherein said airlock is an “S” type airlock.
5. The method recited in claim 1 further including the step of correcting said amount of alcohol produced based on an elevation of said vessel.
6. A method for measuring gas produced during anaerobic fermentation comprising the steps of:
providing a vessel suitable for anaerobic fermentation;
placing liquid materials subject to anaerobic fermentation within the vessel;
sealing the vessel with an “S” type airlock; and,
counting the bubbles which pass through the airlock to determine the volume of gas produced, said bubbles detected by an optical detector.
7. The method recited in claim 6 further comprising the step of determining the interval between bubbles so that the rate of fermentation may be determined.
8. An apparatus for monitoring a liquid undergoing anaerobic fermentation in a vessel, comprising:
an airlock containing a fluid for sealing the vessel; and,
an optical detector operatively arranged to detect passage of bubbles through said airlock.
9. The apparatus recited in claim 8 wherein said airlock is an “S” type airlock.
10. The apparatus recited in claim 9 wherein said airlock comprises a portion with two parallel sides.
11. The apparatus recited in claim 10 wherein said optical detector engages said portion of said airlock having two parallel sides.
12. The apparatus recited in claim 8 further comprising means for determining the volume of gas produced based on said detected passage of bubbles.
13. The apparatus recited in claim 12 further comprising:
means to determine an amount of alcohol produced based on said amount of gas produced, said amount corrected based on an altitude of said apparatus; and,
a display operatively arranged to display said amount of alcohol produced.
14. The apparatus recited in claim 13 further comprising:
an alarm operatively arranged to warn a user when a preprogrammed amount of alcohol has been produced.
15. The apparatus recited in claim 8 further comprising:
means for determining the time between bubble detections; and,
means for determining the rate of gas production based on said time between bubble detections.
16. The apparatus recited in claim 15 further comprising:
an alarm operatively arranged to warn a user when no bubbles are detected for a predetermined amount of time.
17. The apparatus recited in claim 16 wherein said predetermined amount of time is 24 hours.
18. The apparatus recited in claim 8 further comprising:
means for determining the length of time a bubble is proximate said optical detector; and,
an alarm operatively arranged to warn a user when the liquid in said airlock is low, based on said length of time said bubble is proximate said optical detector.
19. The apparatus recited in claim 13 further comprising means for computing a flow rate of alcohol produced, said flow rate corrected based on an elevation of said apparatus.
20. The apparatus recited in claim 19 further comprising alarm means for signaling when said computed flow rate exceeds a flow rate threshold set by a user.
21. An airlock comprising:
a portion having a cross section with two parallel sides.
22. The airlock recited in claim 21 wherein said portion has a polygonal cross section.
23. The airlock recited in claim 21 wherein said portion has a rectangular cross section.
24. The airlock recited in claim 21 wherein said cross section of said portion further comprises two opposing, arcuate sides.
25. An apparatus for monitoring anaerobic fermentation comprising:
an airlock;
a bubble detector;
processing means connected to said detector, said processing means operatively arranged to count a number of bubbles passing through said airlock; and, communication means connected to said processing means, said communication means operatively arranged to communicate data between said processing means and an information system.
26. The apparatus recited in claim 25 wherein said airlock comprises a portion having two parallel sides.
27. The apparatus recited in claim 25 wherein said processing means comprises a general purpose microprocessor programmed to count said number of bubbles passing through said airlock.
28. The apparatus recited in claim 25 wherein said processing means is operatively arranged to determine a quantity of alcohol produced by said anaerobic fermentation.
29. The apparatus recited in claim 25 wherein said processing means is operatively arranged to measure a period of time between said bubbles passing through said airlock.
30. The apparatus recited in claim 25 wherein said processing means is operatively arranged to determine when said anaerobic fermentation has ended.
31. The apparatus recited in claim 25 wherein said processing means is operatively arranged to determine if said airlock contains an inadequate amount of liquid.
32. The apparatus recited in claim 25 wherein said data is said amount of alcohol produced.
33. The apparatus recited in claim 25 wherein said data is an alarm status.
34. The apparatus recited in claim 25 wherein said data is a warning that an inadequate amount of liquid is in said airlock.
35. The apparatus recited in claim 25 wherein said data is a warning that said anaerobic fermentation has ended.
36. The apparatus recited in claim 25 wherein said communication means is an RS-232 connection.
37. The apparatus recited in claim 25 wherein said communication means is a TCP/IP connection.
38. The apparatus recited in claim 25 wherein said communication means is a USB connection.
39. The apparatus recited in claim 25 wherein said information system is the Internet.
40. The apparatus recited in claim 25 wherein said information system is a personal computer.
41. The apparatus recited in claim 25 wherein said information system is a wireless phone system.
42. The apparatus recited in claim 25 wherein said information system is a pager system.
43. The apparatus recited in claim 25 wherein said information system is a personal digital assistant system.
44. The apparatus recited in claim 25 wherein said information system is a wireless local area network.
45. The apparatus recited in claim 25 further comprising database means to store said data.
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US9867385B2 (en) * 2003-09-25 2018-01-16 Suntory Beverage & Food Limited Method of processing green coffee beans
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US20100116937A1 (en) * 2008-11-13 2010-05-13 Sanderson Terry M Collapsible wing beams and method
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CA2503785A1 (en) 2004-05-27
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US20040086608A1 (en) 2004-05-06
EP1585803A1 (en) 2005-10-19
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EP1585803A4 (en) 2010-05-12
WO2004044116A1 (en) 2004-05-27

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