US20040079628A1 - Clean production of coke - Google Patents
Clean production of coke Download PDFInfo
- Publication number
- US20040079628A1 US20040079628A1 US10/691,339 US69133903A US2004079628A1 US 20040079628 A1 US20040079628 A1 US 20040079628A1 US 69133903 A US69133903 A US 69133903A US 2004079628 A1 US2004079628 A1 US 2004079628A1
- Authority
- US
- United States
- Prior art keywords
- coke
- tar
- fines
- mixture
- pyrolyzer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
- C10B57/00—Other carbonising or coking processes; Features of destructive distillation processes in general
- C10B57/04—Other carbonising or coking processes; Features of destructive distillation processes in general using charges of special composition
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
- C10B53/00—Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form
- C10B53/08—Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form in the form of briquettes, lumps and the like
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L5/00—Solid fuels
- C10L5/02—Solid fuels such as briquettes consisting mainly of carbonaceous materials of mineral or non-mineral origin
- C10L5/06—Methods of shaping, e.g. pelletizing or briquetting
- C10L5/10—Methods of shaping, e.g. pelletizing or briquetting with the aid of binders, e.g. pretreated binders
- C10L5/14—Methods of shaping, e.g. pelletizing or briquetting with the aid of binders, e.g. pretreated binders with organic binders
- C10L5/16—Methods of shaping, e.g. pelletizing or briquetting with the aid of binders, e.g. pretreated binders with organic binders with bituminous binders, e.g. tar, pitch
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L5/00—Solid fuels
- C10L5/02—Solid fuels such as briquettes consisting mainly of carbonaceous materials of mineral or non-mineral origin
- C10L5/26—After-treatment of the shaped fuels, e.g. briquettes
- C10L5/28—Heating the shaped fuels, e.g. briquettes; Coking the binders
Definitions
- the present invention relates generally to clean production of coke and more particularly to the use of two types of carbon, one of which comprises low quality coal fines, such as waste coal fines, and/or waste coke or char fines which, after mixing, may be fired without formation into objects or formed into objects and fired to produce solid pyrolyzed objects or pieces, with by-products from pyrolyzation being recycled for use within the coke-producing closed system.
- low quality coal fines such as waste coal fines, and/or waste coke or char fines which, after mixing, may be fired without formation into objects or formed into objects and fired to produce solid pyrolyzed objects or pieces, with by-products from pyrolyzation being recycled for use within the coke-producing closed system.
- Coke heretofore has conventionally been produced from high quality sources of carbon, such as high quality coking coals.
- Prior processes and apparatus for conventionally producing coke typically are open or partly open systems, which generate by-products released to pollute the atmosphere.
- the present invention overcomes or substantially alleviates problems associated with prior ways of conventionally producing coke.
- the present invention may be summarized as comprising closed system apparatus and processes by which carbon feedstock, comprised of a mixture of non-coking coal and/or another carbonaceous material, such as waste coke fines, are mixed together and pyrolyzed into coke either as solid pieces or not.
- carbon feedstock comprised of a mixture of non-coking coal and/or another carbonaceous material, such as waste coke fines
- solid pieces or objects of the mixture are formed, they are fired through pyrolyzation into solid pieces of coke, with solid and/or liquid and gaseous by-products of pyrolyzation being recycled for use within the closed coke-producing system, thereby eliminating release of undesirable substances to the atmosphere.
- Feedback tars with or without a char-forming binder, is added to the carbon mixture prior to pyrolyzation.
- Another paramount object of the present invention is to produce a novel form of coke and to do so using novel apparatus and unique processes.
- a further dominant object is to produce coke from a mixture comprising low quality or non-coking coal fines, which mixture is pyrolyzed into high quality coke.
- Another important object is to produce coke from a mixture comprising waste coke fines, which mixture is pyrolyzed into high quality coke.
- An additional object of importance is to produce coke so as to avoid contaminating the environment by recycling or recirculating solid and/or liquid and gaseous by-products within the closed coke-producing system.
- FIG. 1 is a flow diagram of one process by which low quality coal and another carbonaceous material, such as waste coke fines, are transformed into metallurgical and other grades of coke; and
- FIG. 2 is a flow diagram of another similar process by which low quality coal and other carbonaceous material is transformed into metallurgical and other grades of coke.
- the present invention addresses these problems and provides processes by which waste coke fines (including coke breeze generated from conventional coking processes or petroleum coke) with coal fines are blended to produce a high quality coke product.
- Non-coking coal fines and coke fines may be blended together in such proportions that production of pyrolysis by-products is limited to the amount required for binding and for process heat.
- Feedback tar may be combined with additional synthetic or natural binder to produce prime quality solid coke pieces or objects, such as briquettes or blocks.
- the process 1) uses feedstock material more efficiently than other form coke processes by eliminating discharge of secondary, low value by-products, and 2) uses undesirable materials and industrial wastes not heretofore used to produce coke (i.e., low quality coal and/or coke or char fines) as a feedstock which represent a current serious environmental problem.
- Energy savings for a steel plant can be exemplified by assuming a typical coke fines waste rate of 10% of the total coke production. Energy savings are noted in the increased utilization of raw materials, including extraction, transportation, and differences in processing requirements. Based on a steel mill capacity of about 6,000 tons of hot metal (THM)/day this represents an energy savings of about 4.5 ⁇ 10 11 kJ/year over current technology.
- TBM hot metal
- coke is a universal fuel used in the iron and steel industry.
- Metallurgical coke is commonly required for operation of iron ore reduction facilities, such as blast furnaces.
- Foundry coke is required for scrap melting in cupolas and in casting operations.
- Coke is also an important fuel for other applications, such as the phosphate industry.
- Coke ovens have for some time been of serious environmental concern due to the release of particulate and sulfur gases, as well as emissions of carcinogenic and mutagenic polycyclic aromatic hydrocarbons (PAHs) and benzene-toluene-xylenes (BTX). Consequently, the coke-manufacturing industry is being subjected to increasingly stringent environmental regulations. Advances in coke oven design, such as non-recovery ovens and jumbo coking reactors, show some environmental advantages but still require expensive coking coals to operate and represent a very large capital investment. As environmental regulations become more stringent, existing coking facilities will continue to be closed and capacity reduced.
- Form coke is a term which generally describes carbonized, briquetted or otherwise formed fuel, made from pyrolyzed coal chars.
- FMC pyrolyzed coal chars.
- the coal is crushed and then charred at temperatures between 600 and 800° C., then mixed with a binder, briquetted, and finally carbonized at 900-1000° C.
- the initial partial devolatilization is designed to prevent swelling or sticking of the briquettes during the high temperature treatment.
- the binders needed for this briquetting are usually obtained from the combined by-products and tars generated during the low and high temperature charring and carbonizing steps.
- Most form coke processes can utilize non-coking coals for a portion of the feedstock, combined with expensive coking coals.
- the FMC process requires multiple, staged, fluid-bed heaters to char and carbonize the coal.
- the tars are captured and used as a binder to form the char into briquettes which are calcined in a shaft furnace.
- the process incurs high capital costs.
- the now discontinued CTC process used gasification to char the feed coal.
- the char was then crushed, hot-briquetted and finally calcined.
- By-products had to be refined into salable liquid fuels in order for the CTC process to be economically feasible.
- the CTC process utilized high grade coking coals for a portion of its feedstock.
- a supplemental binder system may include combining a natural or synthetic binder with a carbonaceous binder such as tar, including but not limited to feedback tar from within the system.
- a carbonaceous binder such as tar
- Extensive development and testing of the waste coke fines briquettes has been performed. Indications are that waste coke fines briquettes formed using the present invention, compare favorably with other successful form cokes, such as those obtained from the FMC and CTC processes. See TABLE 1, below: TABLE 1 Comparison of briquettes from proposed process with other successful form cokes.
- Form Coke Apparent Specific Abrasion Type gravity Resistance CSR CRI FMC 1 0.8 69 47 75 CTC 2 1.2 54 30 15 New Process 3 1.4 80 50-70 15-30
- the economics of the present coke fines process is improved by: (1) use of feedback tar, resulting in the elimination of the need to import the tar portion of the binder and/or (2) elimination of the requirement to process and sell excess low-value tars.
- the present invention contemplates blending coke fines (e.g. coke breeze generated from conventional coking processes or petroleum coke) with waste non-coking coal fines.
- coke breeze and/or petroleum coke fines and low grade coal fines are blended with a binder.
- the blend may be fed directly into the pyrolyzer or pressed into briquettes or other solid forms and subsequently cured.
- the relative mixture of coke fines with coal fines can be varied depending on the devolatilization products of the coal to obtain a process with closed material-loops where all of the products of devolatilization are used within the process.
- the temperature of the formed feedstock is elevated at a rate approximately within the range of 1500-2000° C./hr to a maximum temperature within the range of 800- 1100° C.
- the devolatilization behavior of the feedstock varies during heat-up, depending on the feedstock mixture, but gases and tar evolve, leaving a carbon matrix behind.
- Devolatilization behavior depends on many factors such as peak temperature, heating rate, particle size and coal type. General trends are that occluded carbon dioxide and methane are driven off at about 200° C. Above this temperature, internal condensation occurs among the macromolecular structures with the evolution of carbon dioxide and water.
- the evolution of hydrogen begins at 400-500° C. with a critical point at about 700° C. characterized by a rapid evolution of hydrogen and carbon monoxide.
- Tar formation begins at around 300-400° C., with a maximum yield occurring at approximately 500-550° C., depending on heating rate and particle size.
- the character and composition of the tars will vary with temperature.
- Low-temperature tar usually consists mainly of olefin, paraffin hydrocarbons, and cyclic hydroaromatic structures.
- the aromatic nature of tar increases with increasing temperature until high-temperature tars are composed mostly of aromatic hydrocarbons.
- the present processes take advantage of the fact that coke is very low in volatile matter (1-2%) and therefore produces nearly no pyrolytic products.
- This process comprises blending coke fines with coal fines in the proper amount to create just enough pyrolytic products required to perpetuate the process.
- the mixture of coal/coke fines are cleaned and blended with tar or other fixed-carbon producing binders.
- the mix may then be formed into appropriate solid shapes. These shapes are then fed to a pyrolyzer, where the temperature is raised to 800-1100° C. to devolatilize the solid objects driving off tars and gases and leaving a strong, high carbon-content coke.
- the gases and tars are cooled to approximately 300° C., condensing the tars, allowing them to be separated from the fuel-rich gas and collected.
- the tars are then recycled to be used within the process as a binder while the gases are oxidized to provide heat to the pyrolyzer.
- the resulting products are 77% fixed carbon (coke product), 15% tars (used as a binder on a recycle basis), and 8% gas (used to fuel the pyrolyzer).
- This gas consists of about 25% water and carbon dioxide, leaving about 6% of the total feed as a combustible gas.
- the heating value of this gas is typical of coke oven gas (about 21,600 kJ/kg).
- About 1300 kJ of energy in the form of fuel rich gas is produced per kilogram of uncoked briquettes. The amount of energy required to raise the temperature of the briquettes from ambient to 900° C.
- the attending amount of evolved combustible gas is sufficient to operate a pyrolysis unit at 84% thermal efficiency.
- the feedstock mix can be adjusted according to pyrolysis product requirements.
- the original briquettes typically will lose only about 20-25% of their weight as opposed to 35-50% in prior form coke processes.
- briquettes or other solid objects obtained from the present invention have a higher product yield.
- the proposed process 1) utilizes low-value carbon fines to produce a high-value coke product; and 2) operates with closed material loops so that the sale of low-value, secondary products is not required to enhance its economic viability, a characteristic of prior form coke processes.
- a typical form coking practice requires that the process be divided into three steps; 1) coal pyrolysis to form a dense char, 2) briquetting of the char with a binder, and 3) curing the resulting briquettes. Simply binding coal fines together and curing the resulting briquettes is not acceptable. The resulting briquettes exhibit considerable mass loss (35-50%), are small, laden with stress cracks, structurally weak, and likely too reactive. Excess by-products, such as coal tars, must be collected and sold to make the process economically feasible. Due to the high cost of processing these by-products and their aromatic nature they must often be sold as low quality feedstock materials to refiners at a low price.
- the processes of the present invention allow the coal pyrolysis and briquette curing processes to be combined. It does not require coking coals nor does it necessarily produce a surplus of pyrolytic products. Coal fines and coke fines are blended together in such proportions that just the amount of pyrolysis products are produced needed for perpetuating the binding and heating phases.
- the tar portion of the binder may be supplemented with a synthetic or natural binder, as appropriately determined by those skilled in the art, which produces a prime quality coke briquette or block. Since dense, low reactivity discarded or waste coke fines from conventional coke ovens or petroleum refining operations are used as a portion of the feedstock, product mass loss is significantly reduced, resulting in a strong product, where reactivity is lowered.
- Tremendous energy resources are normally associated with coal and coke-intensive industries such as mining, iron and steel production, metal castings, and other manufacturing processes. During normal materials handling, significant amounts of fines are generated which, in the best case, can be sold as a low quality product, but typically are landfilled. This loss of raw material is about 5-15% of the total coal or coke production and represents a significant energy loss.
- the present processes allow the steel and mining industries to minimize disposal by utilizing heretofore unused, potentially valuable wastes, thus reducing material costs, land-fill charges and other expenses. Energy savings occur as the consumption of raw materials and the generation of land-filled waste is reduced.
- This innovative technology significantly reduces wastes generated from coking and mining operations and represents a high end use for petroleum coke fines. Like all effective process-specific recycles, the amount of raw materials input for a given output is reduced.
- Energy savings are noted in the increased utilization of raw materials, including extraction, transportation, and differences in processing requirements. Energy savings for a steel plant producing 6,000 THM per day can be exemplified by reasonably assuming a typical coke fines generation rate of 10% of the total coke production. Use of the briquettes represents a more than 1 to 1 savings in raw materials, since the briquette replaces both the raw material of appropriate size and the feedstocks that would have been discarded since they were too fine. To produce the additional coke required to compensate for the generation of fines that are too small to use, for the plant size described, requires approximately 1.1 ⁇ 10 12 kJ/year.
- the cost associated with form coke plants can vary according to the process requirements.
- Capital costs for the 1 million ton/year FMC plant was estimated at $350 million in 1992.
- Operating costs were very sensitive to raw material costs and were most favorable for western coals priced at $10/ton, where 60% of the coal weight is lost in the process, as by-products.
- Total costs associated with coke production were stated to be about $63/ton using western coals, $90/ton with Midwestern coals, and $107/ton with eastern coking coals.
- the costs for western and Midwestern coals assume a credit for sale of by-products.
- An FMC formed coke plan uses multiple fluidized beds for char production and a curing oven and calciner for coke production.
- the processing and capital costs associated with commercial use of the present technology are expected to be much lower than for prior form coke processes, since the char production step is eliminated.
- Total costs for coke production from the present process are likely to be in the range of $50-60/ton, without requiring the sale of by-products.
- Current metallurgical coke prices are in the range of $100-120/ton and foundry coke is $140-160/ton.
- Metallurgical coke used in blast furnaces must be (1) a fuel to provide heat to meet the endothermic requirements of chemical reactions and melting of the slag and metal, (2) a producer and regenerator of reducing gases for the reduction of iron oxides, and (3) an agent to provide permeability for gas flow and support for furnace burden. Because of the many requirements placed on metallurgical coke, it must meet stringent standards of strength, size and composition. As a fuel and producer of reducing gases, the carbon content should be maximized. As a regenerator of reducing gas, it should have an adequate reactivity to carbon dioxide and water vapor. To provide permeability and burden support, it should be charged in a narrow size range and experience minimal breakdown as it progresses through the blast furnace.
- the ‘solution loss’ reaction produces carbon monoxide from carbon dioxide reacting with coke above 900° C. It is highly endothermic or energy consuming.
- iron and carbon monoxide are produced by carbon reacting endothermically with iron oxide by the direct reduction reaction.
- the joint CSR/CRI test heats a bed of coke in a nitrogen atmosphere to 1100° C. in 30 minutes, reacts the coke sample in a flow of CO 2 for 120 minutes with the bed temperature constant at 1100° C., cools the sample to 100° C., transfers the sample to a tumbler, and tumbles the sample for 600 revolutions in 30 minutes.
- the sample is then sieved in a 3 ⁇ 8 inch sieve.
- the CSR is calculated as the remaining portion in the sieve compared to the amount removed from the furnace.
- the purpose of the CRI test is to give insight into the ability of CO 2 to react with the carbon in the coke, a necessary reaction in the blast furnace but which must be controlled to prevent carbon from being consumed prematurely.
- the CSR test provides information about two different issues; 1) the strength of the briquettes after reacting with CO 2 , and 2) the amount of dust produced by CO 2 attack and bed agitation. Fine dust can be detrimental in the blast furnace since it can decrease the permeability of the bed requiring increased blast pressure to force the air up through the bed.
- FMC and CTC Processes described above have demonstrated that they are able to produce form coke capable of blast furnace use.
- the FMC process utilizes subbituminous coals and lignites, and yields small (11 ⁇ 4 ⁇ 11 ⁇ 8 ⁇ 3 ⁇ 4 in, or 7 ⁇ 8 ⁇ 3 ⁇ 4 ⁇ 1 ⁇ 2 in) coke briquettes, that have performed well in experimental blast furnace trials.
- a comparison of FMC formed coke and a standard metallurgical coke is shown in TABLE 3 (Berkowitz, 1979) and some data from tests of FMC coke in a US Steel Corporation experimental blast furnace are summarized in TABLE 4 (Berkowitz, 1979).
- the ability to utilize the present new coke product can be determined by comparing its properties with cokes that have been proven to be effective blast furnace fuels.
- TABLE 5 compares some of the advantages of coke fines briquettes produced according to the present invention with other cokes previously or currently used as blast furnace fuels and also lists what is accepted as a standard metallurgical coke (Berkowitz, 1979). While the coke fines/coal fines briquettes may vary somewhat from those produced with coke fines only, the properties will be similar. Testing of briquettes made with coal/coke blends show crush strength values of around 1400 psi.
- Coals charged to standard coke ovens comprise a blend of coals with differing properties. Typically 3-5 coals are blended together in such proportions that the properties of the blend will produce a high quality coke product. If a weakly coking coal of low fusibility is used in the blend then the strongly coking coal component must be more fusible and higher in volatile matter to compensate. Therefore, even though mildly and weakly coking coals may be used in a particular blend, the blend would be formulated such that its properties would reflect the parameters outlined below in TABLE 6. TABLE 6 lists referenced characteristics for high quality coking coals or blends (Van Krevelen, 1993.) Coal blends not meeting these characteristics would produce inferior coke.
- low quality coking coals are any coals, individually and collectively, that fall appreciably outside one or more of the parameters listed in TABLE 6. Although such coals may be included in a blend for standard coke oven use, they do not meet the requirements by themselves. Such coal or coals could be used as the sole source of coal within the new process.
- FIGS. 1 and 2 are flow diagrams of processes by which fine or particulate carbonaceous material, normally considered waste, is transformed into metallurgical and other grades of coke.
- FIGS. 1 and 2 are identical flow diagrams, except that char-forming binder is not added to the mix in the mixer 16 . Accordingly, with this exception, the following description of FIG. 1 applies also to FIG. 2.
- Two sources of feedstock are provided, i.e. low grade coal 10 and discarded or waste coke 12 .
- Any suitable carbonaceous material such as petroleum coke fines, coke breeze char, or carbon black, may comprise material 12
- coal, or waste coal fines may comprise material 10 . If unsatisfactorily large in size, the materials 10 and 12 can be crushed to a fine particle size. Material 10 and material 12 , if not sufficiently particulate, are, therefore, crushed by a commercially available crusher 14 , to obtain suitably sized fine particles.
- Any suitable crusher may be used provided, however, in most applications, the crusher must be able to reduce oversized material to about 1 ⁇ 4′′ or 1 ⁇ 8′′ and below.
- the percentages of the various materials being fed to the crusher 14 depend largely on the type of materials being fed. Typically, coal, petroleum coke, and in some cases, metallurgical coke breeze may be fed to the crusher. Coal may account for 20-40% of the mix, petroleum coke may be 40-70%, and metallurgical coke breeze 5-10% of the total mix.
- the mixer 16 must be able to adequately combine the carbon fines and the fedback tars and pitches as well as integrate liquid synthetic and/or natural binders, if used.
- the fines comprising materials 10 and 12 crushed or not crushed as the case may be, are blended in mixer 16 with feedback tars including pitches, obtained during the process (FIG. 2) or feedback tars obtained during the process are mixed with a suitable natural and/or synthetic binder (FIG. 1).
- Suitable char-forming binders comprises tars, pitches, CAT bottoms and thermosetting resins.
- the effluent from the mixer 16 may be displaced into a solid object former 18 , which may be a briquette machine when solid coke objects or pieces are desired.
- the former 18 compresses the mixture into a desired shape e.g. briquettes, blocks, etc. Formation of solid objects or pieces, such as briquettes, is optional, since coke is usable in a variety of forms.
- the mixture can be discharged from the mixer 16 straight into the pyrolyzer 20 , without formation into solid objects. Any suitable type of former may be used depending on the size and shape desired for the final product, as specified by the end user.
- the solid objects, such as briquettes, from the former 18 are or material from the mixer 16 is introduced into a pyrolyzer 20 , where the same is coked and prepared for final use.
- the pyrolyzer furnace 20 must be able to heat the feed stock to around 800-1100° C. at a rate of 1500-2000° C./hr an be able to capture the resulting off-gases and tars.
- the Pyrolyzer 20 normally lowers the coke volatility below 2%. This typically requires temperatures of greater than 800° C., usually within the range of 800-1100° C. Heat-up rate is important to prevent cracking of final product and should be no greater than about 1500° C. per hour.
- Coke, as solid objects or otherwise, is discharged from the pyrolyzer 20 at site 22 .
- gases and tars evolve as by-products in the pyrolyzer 20 . As they evolve they exit the pyrolyzer at site 24 and become the influent to a separator 28 at site 26 .
- the separator 28 separates the by-product tars from the gases.
- the tars are discharged at site 30 and fed back as a binder into the mixer 16 at site 34 , either with or without the addition of an additional char-forming synthetic and/or natural binder.
- the gases are discharged at site 32 and fed back as fuel for the pyrolyzer 20 .
- the separator 28 must be able to collect the off-gases and cool, condense and collect the condensed tars.
- the present technology's primary objective is to produce fuel for the steel industry's iron production blast furnaces.
- the finished product can also be used in cupolas in the foundry industry as smokeless fuel, or a general carbon fuel source.
- the technology provides a less expensive, high-performance product with few if any by-product contamination or environmental problems.
Abstract
Closed apparatus and processes by which carbon feedstock, is composed of a mixture of non-coking coal fines and another carbonaceous material, such as waste coke fines are disclosed. The coal and coke fines are mixed together and may be formed into solid pieces. The mixture alone or as solid pieces is fired through pyrolyzation into solid pieces of coke, with solid and gaseous by-products of pyrolyzation being recycled for use within the coke-producing closed system, thereby reducing or eliminating release of undesirable substances to the environment. A char-forming binder may or may not be added to the carbon mixture prior to pyrolyzation.
Description
- The present invention relates generally to clean production of coke and more particularly to the use of two types of carbon, one of which comprises low quality coal fines, such as waste coal fines, and/or waste coke or char fines which, after mixing, may be fired without formation into objects or formed into objects and fired to produce solid pyrolyzed objects or pieces, with by-products from pyrolyzation being recycled for use within the coke-producing closed system.
- Coke heretofore has conventionally been produced from high quality sources of carbon, such as high quality coking coals. Prior processes and apparatus for conventionally producing coke typically are open or partly open systems, which generate by-products released to pollute the atmosphere.
- In brief summary, the present invention overcomes or substantially alleviates problems associated with prior ways of conventionally producing coke. The present invention may be summarized as comprising closed system apparatus and processes by which carbon feedstock, comprised of a mixture of non-coking coal and/or another carbonaceous material, such as waste coke fines, are mixed together and pyrolyzed into coke either as solid pieces or not. When solid pieces or objects of the mixture are formed, they are fired through pyrolyzation into solid pieces of coke, with solid and/or liquid and gaseous by-products of pyrolyzation being recycled for use within the closed coke-producing system, thereby eliminating release of undesirable substances to the atmosphere. Feedback tars, with or without a char-forming binder, is added to the carbon mixture prior to pyrolyzation.
- With the foregoing in mind, it is a primary object of the present invention to overcome or substantially alleviate problems of the past associated with production of coke.
- Another paramount object of the present invention is to produce a novel form of coke and to do so using novel apparatus and unique processes.
- A further dominant object is to produce coke from a mixture comprising low quality or non-coking coal fines, which mixture is pyrolyzed into high quality coke.
- Another important object is to produce coke from a mixture comprising waste coke fines, which mixture is pyrolyzed into high quality coke.
- An additional object of importance is to produce coke so as to avoid contaminating the environment by recycling or recirculating solid and/or liquid and gaseous by-products within the closed coke-producing system.
- These and other objects and features of the present invention will be apparent from the detailed description taken with reference to the accompanying drawings.
- FIG. 1 is a flow diagram of one process by which low quality coal and another carbonaceous material, such as waste coke fines, are transformed into metallurgical and other grades of coke; and
- FIG. 2 is a flow diagram of another similar process by which low quality coal and other carbonaceous material is transformed into metallurgical and other grades of coke.
- Waste carbonaceous fines have not heretofore been used in the commercial production of coke. Coke is a fuel universally used in the iron and steel industry. Currently, nearly all metallurgical and foundry coke is produced in conventional coke oven facilities requiring the use of good quality coking coals. These coals are becoming scarce, difficult to mine, and, therefore, expensive. Because of the high costs, decreasing supply of these feedstock materials, and environmental contamination problems associated with current coke-making practices, there is a need for alternative coke-making and coke supplementing technologies. Prior attempts to use various form coke processes have primarily resulted in commercial failure and, furthermore, excess by-products of pyrolysis are generated in such processes, which must be refined into salable liquid fuels. Elimination of the need to process and market excess aromatic tars from form coke processes has been a problem. The present invention addresses these problems and provides processes by which waste coke fines (including coke breeze generated from conventional coking processes or petroleum coke) with coal fines are blended to produce a high quality coke product.
- These coke processes do not require high quality coking coals nor are a surplus of pyrolytic products produced. Non-coking coal fines and coke fines may be blended together in such proportions that production of pyrolysis by-products is limited to the amount required for binding and for process heat. Feedback tar may be combined with additional synthetic or natural binder to produce prime quality solid coke pieces or objects, such as briquettes or blocks. The process 1) uses feedstock material more efficiently than other form coke processes by eliminating discharge of secondary, low value by-products, and 2) uses undesirable materials and industrial wastes not heretofore used to produce coke (i.e., low quality coal and/or coke or char fines) as a feedstock which represent a current serious environmental problem.
- Energy savings for a steel plant can be exemplified by assuming a typical coke fines waste rate of 10% of the total coke production. Energy savings are noted in the increased utilization of raw materials, including extraction, transportation, and differences in processing requirements. Based on a steel mill capacity of about 6,000 tons of hot metal (THM)/day this represents an energy savings of about 4.5×1011 kJ/year over current technology.
- Capital costs for the briquetting or solid objects portion of the process have been estimated based on other similar briquetting operations at between $20-30 million for a one-half million ton/year plant. Raw material costs are estimated to be in the range of $10/ton for waste coal fines and $20/ton for coke fines. The processing costs for briquetting or formation of solid objects, which include the price of the additional natural or synthetic binder, if used, are estimated to be around $18/ton, depending on the type of binder. Total costs for coke production from the process are expected to be in the range of $50-60/ton. Current metallurgical coke prices are in the range of $100-120/ton and foundry coke is $140-160/ton. For a steel plant producing 6,000 THM/day, at an approximate rate of 500 lbs coke/THM, by incorporating the proposed process, a net savings of $3.3 to $2.8 million/year is expected.
- The ability to utilize this new coke product, as a partial coke replacement in the blast furnace, will ultimately be proven by such an application. The properties of coke produced using the present invention compare well with other cokes previously or currently used as blast furnace fuels.
- One concern regarding the use of form coke, made from a previous process, in a blast furnace is that its reactivity tended to be higher than standard metallurgical coke produced in slot ovens. The new coke produced according to the present invention is expected to be able to replace oven-coke and have reactivities and strengths as good as or better than standard metallurgical coke.
- As stated above, coke is a universal fuel used in the iron and steel industry. Metallurgical coke is commonly required for operation of iron ore reduction facilities, such as blast furnaces. Foundry coke is required for scrap melting in cupolas and in casting operations. Coke is also an important fuel for other applications, such as the phosphate industry.
- The American steel industry underwent a major restructuring during the 1980's, resulting in the closing of many steel and coke-making plants. From 1980 to 1990, approximately 40% of the United States coke-making capacity was shut down. During this same time, very few new coke-making facilities were built. Today, approximately 26 million tons of metallurgical coke and 2 million tons of foundry coke are produced annually in the United States. Many of the remaining coking facilities are approaching the end of, or have been extended beyond, their life expectancies. Nearly 50% of the current capacity is over 20 years old and 40% is over 30 years old. These older facilities are not only expensive to maintain and operate but they are difficult to keep in compliance with environmental regulations.
- Nearly all metallurgical and foundry coke is produced in conventional coke oven facilities requiring the use of high quality coking coals. Prime coking coals tend to have a volatile content between 19-33%. These coals are becoming scarce, difficult to mine, and, therefore, expensive. In 1995, the average delivered price for metallurgical coking coals in the U.S. was over $47/ton while steam coals were about $27/ton.
- Coke ovens have for some time been of serious environmental concern due to the release of particulate and sulfur gases, as well as emissions of carcinogenic and mutagenic polycyclic aromatic hydrocarbons (PAHs) and benzene-toluene-xylenes (BTX). Consequently, the coke-manufacturing industry is being subjected to increasingly stringent environmental regulations. Advances in coke oven design, such as non-recovery ovens and jumbo coking reactors, show some environmental advantages but still require expensive coking coals to operate and represent a very large capital investment. As environmental regulations become more stringent, existing coking facilities will continue to be closed and capacity reduced. Furthermore, the high capital cost of building new cokemaking plants based on current technology and dwindling supplies of domestic prime coking coals has caused U.S. companies to look outside the country for coke supplies. The United States already imports a sizable quantity of coke, some produced from its own exported metallurgical coals. Because of the high costs, decreasing supply of feedstock materials, and environmental problems associated with current coke-making and coke supplementing technologies.
- An alternative to producing coke from metallurgical coals in conventional slot ovens, is to use various form coke processes. Form coke is a term which generally describes carbonized, briquetted or otherwise formed fuel, made from pyrolyzed coal chars. In a process known as the FMC process, the coal is crushed and then charred at temperatures between 600 and 800° C., then mixed with a binder, briquetted, and finally carbonized at 900-1000° C. The initial partial devolatilization is designed to prevent swelling or sticking of the briquettes during the high temperature treatment. The binders needed for this briquetting are usually obtained from the combined by-products and tars generated during the low and high temperature charring and carbonizing steps. Most form coke processes can utilize non-coking coals for a portion of the feedstock, combined with expensive coking coals.
- Numerous form coke processes have been unsatisfactorily experimentally tested. Only a few have reached commercial production. Exceptions are the above-mentioned FMC Process, which converts sub-bituminous coal into pillow-shaped coke briquettes for phosphate production and, also, a process known as the CTC Process, which was commercially discontinued recently.
- The FMC process requires multiple, staged, fluid-bed heaters to char and carbonize the coal. The tars are captured and used as a binder to form the char into briquettes which are calcined in a shaft furnace. The process incurs high capital costs.
- The now discontinued CTC process used gasification to char the feed coal. The char was then crushed, hot-briquetted and finally calcined. By-products had to be refined into salable liquid fuels in order for the CTC process to be economically feasible. The CTC process utilized high grade coking coals for a portion of its feedstock.
- By contrast, the present processes pertain to making briquettes from waste coke fines rather than coal char. A supplemental binder system, if used, may include combining a natural or synthetic binder with a carbonaceous binder such as tar, including but not limited to feedback tar from within the system. Extensive development and testing of the waste coke fines briquettes has been performed. Indications are that waste coke fines briquettes formed using the present invention, compare favorably with other successful form cokes, such as those obtained from the FMC and CTC processes. See TABLE 1, below:
TABLE 1 Comparison of briquettes from proposed process with other successful form cokes. Form Coke Apparent Specific Abrasion Type gravity Resistance CSR CRI FMC1 0.8 69 47 75 CTC2 1.2 54 30 15 New Process3 1.4 80 50-70 15-30 - The economics of the present coke fines process is improved by: (1) use of feedback tar, resulting in the elimination of the need to import the tar portion of the binder and/or (2) elimination of the requirement to process and sell excess low-value tars. In order to do this, the present invention contemplates blending coke fines (e.g. coke breeze generated from conventional coking processes or petroleum coke) with waste non-coking coal fines. The coke breeze and/or petroleum coke fines and low grade coal fines are blended with a binder. The blend may be fed directly into the pyrolyzer or pressed into briquettes or other solid forms and subsequently cured. The relative mixture of coke fines with coal fines can be varied depending on the devolatilization products of the coal to obtain a process with closed material-loops where all of the products of devolatilization are used within the process.
- During the pyrolysis operation, the temperature of the formed feedstock is elevated at a rate approximately within the range of 1500-2000° C./hr to a maximum temperature within the range of 800- 1100° C. The devolatilization behavior of the feedstock varies during heat-up, depending on the feedstock mixture, but gases and tar evolve, leaving a carbon matrix behind.
- Devolatilization behavior depends on many factors such as peak temperature, heating rate, particle size and coal type. General trends are that occluded carbon dioxide and methane are driven off at about 200° C. Above this temperature, internal condensation occurs among the macromolecular structures with the evolution of carbon dioxide and water.
- In the range of 200-500° C., methane begins to evolve with its higher homologues and olefin. Most of the oxygen in coal structures is eliminated as water and oxides of carbon. The decomposition of both nitrogen structures and organic sulfur species begins in this temperature range.
- The evolution of hydrogen begins at 400-500° C. with a critical point at about 700° C. characterized by a rapid evolution of hydrogen and carbon monoxide.
- In the temperature range of 500-700° C., the volume of gases such as hydrogen, carbon monoxide, methane, and nitrogen increase with increasing temperature, while most hydrocarbons decrease.
- Tar formation begins at around 300-400° C., with a maximum yield occurring at approximately 500-550° C., depending on heating rate and particle size. The character and composition of the tars will vary with temperature. Low-temperature tar usually consists mainly of olefin, paraffin hydrocarbons, and cyclic hydroaromatic structures. The aromatic nature of tar increases with increasing temperature until high-temperature tars are composed mostly of aromatic hydrocarbons.
- The tars which evolve from the coal fines are captured and returned to be used as a binder. Fuel rich gases are used to operate the pyrolysis furnace. The idea of recycling tar to be used as the binder is not unique, standing alone. Many form coke processes utilize this step, among many others. However, since prior form coke processes typically use only raw coal in their feedstock they lose a significant portion of their initial weight (30-50%) as tars and gases. While a portion of these products can be utilized as a binder and for process heat, the quantity produced using prior processes is generally larger than can be consumed within the facility and, therefore, must be appropriately disposed of or sold to enhance the economic attractiveness of the process. Due to the high cost of processing these by-products and their aromatic nature, they must often be sold as low quality feedstock materials to refiners at low prices.
- The present processes take advantage of the fact that coke is very low in volatile matter (1-2%) and therefore produces nearly no pyrolytic products. This process comprises blending coke fines with coal fines in the proper amount to create just enough pyrolytic products required to perpetuate the process.
- The mixture of coal/coke fines are cleaned and blended with tar or other fixed-carbon producing binders. The mix may then be formed into appropriate solid shapes. These shapes are then fed to a pyrolyzer, where the temperature is raised to 800-1100° C. to devolatilize the solid objects driving off tars and gases and leaving a strong, high carbon-content coke. The gases and tars are cooled to approximately 300° C., condensing the tars, allowing them to be separated from the fuel-rich gas and collected. The tars are then recycled to be used within the process as a binder while the gases are oxidized to provide heat to the pyrolyzer. Calculations indicate that, with, for example only, a mix of 55% coke fines, 30% bituminous coal fines and 15% binder, the amounts of tars and gases generated are appropriate to operate the process in a closed-loop fashion. Of course these proportions will vary under control of one skilled in the art, depending on feedstock properties. At a briquette pyrolysis temperature of 900° C., typical product yields for the various constituents are shown in TABLE 2, below:
TABLE 2 Approximate product yields at 900° C. of constituents in mix (ash free basis) Constituent Fixed Carbon Tars Gases Coke 100 0 0 Bituminous Coal 52 30 18 Tar Binder 40 40 20 - If these components are blended in the mixture fractions given above, then the resulting products are 77% fixed carbon (coke product), 15% tars (used as a binder on a recycle basis), and 8% gas (used to fuel the pyrolyzer). This gas consists of about 25% water and carbon dioxide, leaving about 6% of the total feed as a combustible gas. The heating value of this gas is typical of coke oven gas (about 21,600 kJ/kg). About 1300 kJ of energy in the form of fuel rich gas is produced per kilogram of uncoked briquettes. The amount of energy required to raise the temperature of the briquettes from ambient to 900° C. is 1100 kJ/kg, assuming a specific heat of coal of 1.26 kJ/kg° K. Therefore, to produce the proper amount of tars required within the process, the attending amount of evolved combustible gas is sufficient to operate a pyrolysis unit at 84% thermal efficiency. The feedstock mix can be adjusted according to pyrolysis product requirements. During the pyrolysis step, the original briquettes typically will lose only about 20-25% of their weight as opposed to 35-50% in prior form coke processes. Thus, briquettes or other solid objects obtained from the present invention have a higher product yield.
- In summary, among other advantages, the proposed process: 1) utilizes low-value carbon fines to produce a high-value coke product; and 2) operates with closed material loops so that the sale of low-value, secondary products is not required to enhance its economic viability, a characteristic of prior form coke processes.
- Nearly all metallurgical and foundry coke is produced in conventional, by-product recovery, horizontal slot ovens, requiring high quality coking coals as a raw material. The evolutionary development of conventional coke ovens is approaching its technological and economic limits. Because of this, several alternative coking processes have been attempted. Some of these are variations of the slot-oven type of systems including the Jewell-Thompson non-recovery coke oven and the Jumbo coking reactor. The goal of these types of slot oven technologies is to improve the efficiency and environmental friendliness in the production of coke. However, the economics of producing coke using these new technologies is not an improvement over conventional coke ovens. Another disadvantage of the new slot oven technologies is that they still require prime coking coals as a feedstock, which coking coals are becoming scarce, difficult to mine, and, therefore, expensive.
- One type of emerging coking technology, different from the slot oven approach are form coke processes, discussed briefly above. A wide range of coals have been tested and some of the processes have produced form coke, the strength and reactivity of which are in an acceptable range for blast furnace use. However, strength tends to be at the low end and reactivity at the high end of that which is generally acceptable. These processes are performed in closed systems, making them very environmentally attractive. Their commercialization has been impeded due to economic considerations and product quality.
- A typical form coking practice requires that the process be divided into three steps; 1) coal pyrolysis to form a dense char, 2) briquetting of the char with a binder, and 3) curing the resulting briquettes. Simply binding coal fines together and curing the resulting briquettes is not acceptable. The resulting briquettes exhibit considerable mass loss (35-50%), are small, laden with stress cracks, structurally weak, and likely too reactive. Excess by-products, such as coal tars, must be collected and sold to make the process economically feasible. Due to the high cost of processing these by-products and their aromatic nature they must often be sold as low quality feedstock materials to refiners at a low price.
- The processes of the present invention allow the coal pyrolysis and briquette curing processes to be combined. It does not require coking coals nor does it necessarily produce a surplus of pyrolytic products. Coal fines and coke fines are blended together in such proportions that just the amount of pyrolysis products are produced needed for perpetuating the binding and heating phases. The tar portion of the binder may be supplemented with a synthetic or natural binder, as appropriately determined by those skilled in the art, which produces a prime quality coke briquette or block. Since dense, low reactivity discarded or waste coke fines from conventional coke ovens or petroleum refining operations are used as a portion of the feedstock, product mass loss is significantly reduced, resulting in a strong product, where reactivity is lowered.
- While the present processes more efficiently use feedstock material than is true of the prior form coke processes, there is another very significant feature of the present processes. The feedstock used within this process (i.e. coke fines and coal fines) are normally discarded and classified as either wastes or undesirable materials, representing a current environmental problem. Coke breeze produced at existing coking plants cannot per se be utilized within the blast furnace and must either be disposed of, or sold at a relatively low cost. Delayed petroleum coke fines and fluid-coke are often landfilled. Coal fines are currently either disposed of in slurry ponds or are landfilled. The transformation of these waste materials into a high value coke is a surprising and valuable step forward.
- Tremendous energy resources are normally associated with coal and coke-intensive industries such as mining, iron and steel production, metal castings, and other manufacturing processes. During normal materials handling, significant amounts of fines are generated which, in the best case, can be sold as a low quality product, but typically are landfilled. This loss of raw material is about 5-15% of the total coal or coke production and represents a significant energy loss. The present processes allow the steel and mining industries to minimize disposal by utilizing heretofore unused, potentially valuable wastes, thus reducing material costs, land-fill charges and other expenses. Energy savings occur as the consumption of raw materials and the generation of land-filled waste is reduced. This innovative technology significantly reduces wastes generated from coking and mining operations and represents a high end use for petroleum coke fines. Like all effective process-specific recycles, the amount of raw materials input for a given output is reduced.
- Energy savings are noted in the increased utilization of raw materials, including extraction, transportation, and differences in processing requirements. Energy savings for a steel plant producing 6,000 THM per day can be exemplified by reasonably assuming a typical coke fines generation rate of 10% of the total coke production. Use of the briquettes represents a more than 1 to 1 savings in raw materials, since the briquette replaces both the raw material of appropriate size and the feedstocks that would have been discarded since they were too fine. To produce the additional coke required to compensate for the generation of fines that are too small to use, for the plant size described, requires approximately 1.1×1012 kJ/year. To convert those fines into a useable coke product using the proposed process requires only about 6.5×1011 kJ/year. The resulting energy savings is about 4.5×1011 kJ/year. Other similar values could be obtained for the chemical processing, castings, and other coke consuming industries.
- The capital cost of installing a coke works at an iron production facility represents a significant portion (about 40%) of the overall required capital cost. In 1987 the annual investment costs per ton of coke production was $46-$65. The 1987 maintenance and repair costs were estimated at about $2.50-$3.25/ton. The growing emphasis on safeguarding the environment, both the working environment for the operators and the general environment outside the works boundary, is escalating the cost of coke ovens. The cost of the new 2 million ton/year Kaiserstuhl III coke works was about $800 million, including the cost for coke quenching and the by-products plant. The rebuilding of a 900,000 ton/year plant at the Great Lakes Division of National Steel cost in excess of $450 million. It has been argued that the Kaiserstuhl III works represents the highest development potential of slot-type coke ovens and that a radical departure from the classical design is needed to achieve any major reduction in the cost of coke production.
- The cost associated with form coke plants can vary according to the process requirements. Capital costs for the 1 million ton/year FMC plant was estimated at $350 million in 1992. Operating costs were very sensitive to raw material costs and were most favorable for western coals priced at $10/ton, where 60% of the coal weight is lost in the process, as by-products. Total costs associated with coke production were stated to be about $63/ton using western coals, $90/ton with Midwestern coals, and $107/ton with eastern coking coals. The costs for western and Midwestern coals assume a credit for sale of by-products.
- Detailed capital and operating costs associated with the present processes remains to be precisely determined. However, some comparisons with other processes can be made. Capital costs for the present briquetting operations have been estimated, based on other similar briquetting operations, at between $20-30 million for a one-half million ton/year plant. Estimates of operating costs for a briquetting plant of this size include raw materials costs and processing costs. Raw materials costs are estimated to be in the range of $10/ton for waste coal fines and $20/ton for coke fines. The processing costs for briquetting, which include the price of an additional natural or synthetic binder, are estimated to be around $18/ton, depending on the type of binder.
- An FMC formed coke plan, as stated above, uses multiple fluidized beds for char production and a curing oven and calciner for coke production. The processing and capital costs associated with commercial use of the present technology are expected to be much lower than for prior form coke processes, since the char production step is eliminated. Total costs for coke production from the present process are likely to be in the range of $50-60/ton, without requiring the sale of by-products. Current metallurgical coke prices are in the range of $100-120/ton and foundry coke is $140-160/ton.
- For a steel plant producing 6,000 THM/day, at an approximate rate of 500 lbs coke/THM and at an approximate cost of $100/ton for coke, the replacement value of the coke normally lost would be about $5.5 million a year. Reduction in the amount purchased, since all the coke is initially used or reclaimed and used, represents another 1% or $0.55 million. With briquette costs expected to be around $50-60/ton, a net savings of $3.3 to $2.8 million/year is expected.
- The characteristics of supplemental coke products and cokes made from alternative coking technologies must fall within the strict standards necessary for its intended use. The most stringent requirements for coke are associated with blast furnace use. Metallurgical coke used in blast furnaces must be (1) a fuel to provide heat to meet the endothermic requirements of chemical reactions and melting of the slag and metal, (2) a producer and regenerator of reducing gases for the reduction of iron oxides, and (3) an agent to provide permeability for gas flow and support for furnace burden. Because of the many requirements placed on metallurgical coke, it must meet stringent standards of strength, size and composition. As a fuel and producer of reducing gases, the carbon content should be maximized. As a regenerator of reducing gas, it should have an adequate reactivity to carbon dioxide and water vapor. To provide permeability and burden support, it should be charged in a narrow size range and experience minimal breakdown as it progresses through the blast furnace.
- Different iron ore reduction reactions occur within the blast furnace, depending on furnace operation and temperature region. Indirect reduction occurs at relatively low temperatures (850-900° C.) in the stack. This exothermic reaction can occur with carbon monoxide as follows:
- 3Fe2O3(s)+CO→2Fe3O4+CO2 (1)
- Fe3O4(s)+CO→3(FeO)+CO2 (2)
- and
- FeO(s)+CO→Fe+CO2 (3)
- The ‘solution loss’ reaction produces carbon monoxide from carbon dioxide reacting with coke above 900° C. It is highly endothermic or energy consuming.
- C(s)+CO2→2CO (4)
- At high temperatures in the lower part of the furnace, iron and carbon monoxide are produced by carbon reacting endothermically with iron oxide by the direct reduction reaction.
- FeO(s)+C(s)→Fe+CO (5)
- Decreasing direct reduction in favor of indirect reduction is advantageous because the latter is exothermic and lowers the overall heat requirements for the blast furnace. Increasing the CO or H2 content of the blast furnace gas increases the rate of indirect reduction.
- Standard testing procedures for cokes to qualify them for use in blast furnaces have been developed over the years, as the science and art of blast furnace operation and the requirements of coke have become better understood. Prior to 1993, standard coke tests included proximate analysis to determine chemical make-up, drop shatter and tumbler tests to determine strength, and specific gravity and porosity tests to measure structural characteristics. None of these tests were performed under conditions that the coke might encounter in the blast furnace, such as a harsh chemical environment, high pressure, and high temperature. In recent years, the Japanese steel industry developed a procedure that tests coke strength and breakdown to CO2 attack under blast furnace conditions. In 1993, this test was adopted as an ASTM standard test for coke as ASTM D 5341-93 entitled Standard Test Method for Measuring Coke Reactivity Index (CRI) and Coke Strength After Reaction (CSR).
- The joint CSR/CRI test heats a bed of coke in a nitrogen atmosphere to 1100° C. in 30 minutes, reacts the coke sample in a flow of CO2 for 120 minutes with the bed temperature constant at 1100° C., cools the sample to 100° C., transfers the sample to a tumbler, and tumbles the sample for 600 revolutions in 30 minutes. The sample is then sieved in a ⅜ inch sieve. The CSR is calculated as the remaining portion in the sieve compared to the amount removed from the furnace.
- The purpose of the CRI test is to give insight into the ability of CO2 to react with the carbon in the coke, a necessary reaction in the blast furnace but which must be controlled to prevent carbon from being consumed prematurely. The CSR test provides information about two different issues; 1) the strength of the briquettes after reacting with CO2, and 2) the amount of dust produced by CO2 attack and bed agitation. Fine dust can be detrimental in the blast furnace since it can decrease the permeability of the bed requiring increased blast pressure to force the air up through the bed.
- Both the FMC and CTC Processes described above have demonstrated that they are able to produce form coke capable of blast furnace use. The FMC process utilizes subbituminous coals and lignites, and yields small (1¼×1⅛×¾ in, or ⅞×¾×½ in) coke briquettes, that have performed well in experimental blast furnace trials. A comparison of FMC formed coke and a standard metallurgical coke is shown in TABLE 3 (Berkowitz, 1979) and some data from tests of FMC coke in a US Steel Corporation experimental blast furnace are summarized in TABLE 4 (Berkowitz, 1979).
TABLE 3 FMC Formed Coke Properties “Standard” FMC Coke Metallurgical Coke Relative crushing strength, lb/in2 3000 400-2000 (ASTM) Apparent density, gm/cm3 0.8-1.2 0.85-1.3 Bulk density, lb/ft3 30-45 20-30 Hardness, moh scale 6+ 6+ Surface area, m2/gm 50-200 1-25 Chemical reactivity, %/hr 15-50 1-5 Volatile matter, % <3 1-2 -
TABLE 4 Experimental Blast-furnace Test Data “Standard” 2 × ¾-in FMC Coke Metallurgical Coke Sinter/coke, lb/lb 2.96 2.82 Coke rate, lb/ton hot metal 1062 1096 Production rate, lb/hr 3601 3384 Slag volume, lb/ton hot metal 604 600 Stack dust, lb/hr 20.2 12.7 - The ability to utilize the present new coke product can be determined by comparing its properties with cokes that have been proven to be effective blast furnace fuels. TABLE 5 compares some of the advantages of coke fines briquettes produced according to the present invention with other cokes previously or currently used as blast furnace fuels and also lists what is accepted as a standard metallurgical coke (Berkowitz, 1979). While the coke fines/coal fines briquettes may vary somewhat from those produced with coke fines only, the properties will be similar. Testing of briquettes made with coal/coke blends show crush strength values of around 1400 psi.
TABLE 5 Coke Properties FMC Coke fines “Standard” Coke Briquettes Metallurgical Coke Relative crushing 600 1400-4000 400-2000 strength, lb/in2 Apparent density, 0.8-1.2 1.2-1.5 0.85-1.3 gm/cm3 Bulk density, lb/ft3 30-45 na 20-30 Surface area, m2/gm 50-200 na 1-25 Relative CO2 reactivity 60-75 15-30 20-30 (CRI) Coke Strength (CSR) 40-50 50-75 50-65 - Coals charged to standard coke ovens comprise a blend of coals with differing properties. Typically 3-5 coals are blended together in such proportions that the properties of the blend will produce a high quality coke product. If a weakly coking coal of low fusibility is used in the blend then the strongly coking coal component must be more fusible and higher in volatile matter to compensate. Therefore, even though mildly and weakly coking coals may be used in a particular blend, the blend would be formulated such that its properties would reflect the parameters outlined below in TABLE 6. TABLE 6 lists referenced characteristics for high quality coking coals or blends (Van Krevelen, 1993.) Coal blends not meeting these characteristics would produce inferior coke.
- As used in this specification, low quality coking coals are any coals, individually and collectively, that fall appreciably outside one or more of the parameters listed in TABLE 6. Although such coals may be included in a blend for standard coke oven use, they do not meet the requirements by themselves. Such coal or coals could be used as the sole source of coal within the new process.
TABLE 6 Main parameters to Characterize coals for carbonization (coking) Parameter group Parameters Indicative values Rank parameters C-content, daf (%) 86-90 H-content, daf (%) 5.0 to 5.5 Rm (V-reflectance) 1.0 to 1.35 VM-content, daf (%) 24-28 CV (MJ/kg), mmmf 34-36 Rheological parameters FSI 6.5-8 (on heating) Dilation behavior eu-plastic (ortho-pl. type) dil. 100 to 125% Maximum fluidity 900-1100 Parameters for Ash Less than 7 Contaminants S Less than 0.6 - With reference to the drawings, in light of the foregoing presentation, numerals are used throughout to identify common parts. FIGS. 1 and 2 are flow diagrams of processes by which fine or particulate carbonaceous material, normally considered waste, is transformed into metallurgical and other grades of coke. FIGS. 1 and 2 are identical flow diagrams, except that char-forming binder is not added to the mix in the
mixer 16. Accordingly, with this exception, the following description of FIG. 1 applies also to FIG. 2. - Two sources of feedstock are provided, i.e.
low grade coal 10 and discarded orwaste coke 12. Any suitable carbonaceous material, such as petroleum coke fines, coke breeze char, or carbon black, may comprisematerial 12, while, coal, or waste coal fines may comprisematerial 10. If unsatisfactorily large in size, thematerials Material 10 andmaterial 12, if not sufficiently particulate, are, therefore, crushed by a commerciallyavailable crusher 14, to obtain suitably sized fine particles. Any suitable crusher may be used provided, however, in most applications, the crusher must be able to reduce oversized material to about ¼″ or ⅛″ and below. The percentages of the various materials being fed to thecrusher 14 depend largely on the type of materials being fed. Typically, coal, petroleum coke, and in some cases, metallurgical coke breeze may be fed to the crusher. Coal may account for 20-40% of the mix, petroleum coke may be 40-70%, and metallurgical coke breeze 5-10% of the total mix. - The
mixer 16 must be able to adequately combine the carbon fines and the fedback tars and pitches as well as integrate liquid synthetic and/or natural binders, if used. Thefines comprising materials mixer 16 with feedback tars including pitches, obtained during the process (FIG. 2) or feedback tars obtained during the process are mixed with a suitable natural and/or synthetic binder (FIG. 1). Suitable char-forming binders comprises tars, pitches, CAT bottoms and thermosetting resins. - Mixing continues until a desired homogeneous blend of the influent materials is obtained.
- The effluent from the
mixer 16 may be displaced into a solid object former 18, which may be a briquette machine when solid coke objects or pieces are desired. The former 18 compresses the mixture into a desired shape e.g. briquettes, blocks, etc. Formation of solid objects or pieces, such as briquettes, is optional, since coke is usable in a variety of forms. The mixture can be discharged from themixer 16 straight into thepyrolyzer 20, without formation into solid objects. Any suitable type of former may be used depending on the size and shape desired for the final product, as specified by the end user. - The solid objects, such as briquettes, from the former18 are or material from the
mixer 16 is introduced into apyrolyzer 20, where the same is coked and prepared for final use. Thepyrolyzer furnace 20 must be able to heat the feed stock to around 800-1100° C. at a rate of 1500-2000° C./hr an be able to capture the resulting off-gases and tars. ThePyrolyzer 20 normally lowers the coke volatility below 2%. This typically requires temperatures of greater than 800° C., usually within the range of 800-1100° C. Heat-up rate is important to prevent cracking of final product and should be no greater than about 1500° C. per hour. Coke, as solid objects or otherwise, is discharged from thepyrolyzer 20 atsite 22. - During the pyrolyzing process, gases and tars evolve as by-products in the
pyrolyzer 20. As they evolve they exit the pyrolyzer atsite 24 and become the influent to aseparator 28 atsite 26. Theseparator 28 separates the by-product tars from the gases. The tars are discharged atsite 30 and fed back as a binder into themixer 16 atsite 34, either with or without the addition of an additional char-forming synthetic and/or natural binder. The gases are discharged atsite 32 and fed back as fuel for thepyrolyzer 20. Theseparator 28 must be able to collect the off-gases and cool, condense and collect the condensed tars. - The exact make-up of
feedstock - The present technology's primary objective is to produce fuel for the steel industry's iron production blast furnaces. The finished product can also be used in cupolas in the foundry industry as smokeless fuel, or a general carbon fuel source. The technology provides a less expensive, high-performance product with few if any by-product contamination or environmental problems.
- The invention may be embodied in other specific forms without departing from the spirit of the central characteristics thereof. The present embodiments therefore to be considered in all respects as illustrative and not restrictive, the core of the invention being indicated by the appended claims rather than by the foregoing description, and all changes which come within the meaning and range of equivalency of the claims are therefore intended to be embraced therein.
Claims (31)
1. A method of producing coke from at least one lower grade material on a low pollution or no pollution basis, comprising the acts of:
introducing a mixture of low grade coal fines and another type of carbonaceous fines as an influent into a pyrolyzer;
pyrolyzing the mixture in the pyrolyzer;
discharging coke and pyrolytic by-products as effluents from the pyrolyzer;
separating the pyrolytic by-products into tar and combustible off gas;
using the separated tar as a binder in the mixture, without discharging the tar to the environment;
using the combustible off gas as a source of fuel in the pyrolyzer without discharging the off gas to the environment.
2. A method according to claim 1 wherein the introducing act comprises obtaining a mixture comprising coal fines and coke fines.
3. A method according to claim 1 further comprising the act of crushing low grade coal and/or another type of carbonaceous material, prior to the introducing act, to obtain the fines.
4. A method according to claim 1 further comprising the act of forming the mixture into solid objects prior to the introducing act.
5. A method according to claim 4 wherein the discharging act comprises discharging the coke as solid objects.
6. A method according to claim 1 wherein the using act comprises combining the separated tar, a synthetic binder and the mixture of fines prior to the introducing act.
7. A method according to claim 1 wherein the separated tar is fed back to the mixture prior to the introducing act.
8. A method according to claim 1 wherein the separating act comprises cooling the by-products and condensing the tar to separate the tar from the off gas.
9. A method of producing coke from at least one low grade material on a low pollution or no pollution basis, comprising the acts of:
introducing a mixture of low grade coal fines and another type of carbonaceous fines as an influent into a pyrolyzer;
pyrolyzing the mixture in the pyrolyzer;
discharging coke and pyrolytic by-products as effluents from the pyrolyzer;
separating the pyrolytic by-products into tar and combustible off gas;
using the separated tar as a binder in the mixture without discharging the tar to the environment;
using the combustible off gas as a source of fuel in the pyrolyzer without discharging the off gas to the environment.
10. A method according to claim 9 wherein the introducing act comprises obtaining a mixture comprising coke fines and coal fines.
11. A method according to claim 9 further comprising the act of crushing coke and/or another type of carbonaceous material, prior to the introducing act, to obtain the fines.
12. A method according to claim 9 further comprising the act of forming the mixture into solid objects prior to the introducing act.
13. A method according to claim 12 wherein the discharging act comprises discharging the coke from the pyrolyzer as solid objects.
14. A method according to claim 9 wherein the using act comprises combining the separated tar, a synthetic binder and the mixture of fines prior to the introducing act.
15. A method according to claim 9 wherein the separated tar is fed back to the mixture prior to the introducing act.
16. A method according to claim 9 wherein the separating act comprises cooling the by-products and condensing the tar to separate the tar from the off gas.
17. A method of producing coke from low grade coal and waste coke fines on a low pollution or no pollution basis, comprising the acts of:
introducing a mixture of lower grade coal fines and waste coke fines as an influent into a pyrolyzer;
pyrolyzing the mixture in the pyrolyzer;
discharging segregated coke, on the one hand, and pyrolytic by-products comprising combustible off gas and tar on the other hand, as effluents from the pyrolyzer;
separating the pyrolytic by-products into segregated tar and combustible off-gas;
using the segregated tar as a binder in the mixture without discharging the tar to the environment;
using the segregated combustible off gas as a source of fuel in the pyrolyzer without discharging the off gas to the environment.
18. A method according to claim 17 further comprising the act of crushing oversized waste coke and/or oversized low grade coal, to obtain the fines.
19. A method according to claim 17 further comprising the act of forming the mixture into solid objects prior to the introducing act.
20. A method according to claim 19 wherein the discharging act comprises discharging the coke from the pyrolyzer as solid objects.
21. A method according to claim 17 wherein the using act comprises combining the separated tar, a synthetic binder and the mixture of fines in a mixer.
22. A method according to claim 17 wherein the separated tar is fed back to the mixture of fines.
23. A method according to claim 17 wherein low grade coal comprises 20-40% by weight of the mixture.
24. A method according to claim 17 wherein petroleum coke comprises 40-70% by weight of the mixture.
25. A method according to claim 17 wherein coke breeze comprises 5-10% by weight of the mixture.
26. A method according to claim 17 wherein the pyrolyzing act comprises heating the introduced mixture to a temperature within the range of 800-1100° C. at a rate within the range of 1500-2000° C./hour to lower coke volatility below 2%.
27. A method according to claim 17 wherein the separating act comprises cooling the by-products to about 300° C. and condensing the tar to separate the tar from the off gas.
28. A method of producing coke on a low pollution or no pollution basis comprising the acts of:
introducing at least one source of carbon comprising low grade coal fines as an influent into a pyrolyzer;
pyrolyzing the fines in the pyrolyzer;
discharging coke, and pyrolytic by-product comprising combustible off gas, and tar as effluents from the pyrolyzer;
condensing the tar;
using the tar as a binder for coal fines without discharging the tar to the environment;
using the combustible off gas as a source of fuel in the pyrolyzer without discharging the off gas to the environment.
29. A method of producing coke on a low pollution or no pollution basis comprising the acts of:
introducing at least one source of carbon comprising waste coke fines and/or coal fines as an influent into a pyrolyzer;
pyrolyzing the fines in the pyrolyzer;
discharging coke, and pyrolytic by-products comprising combustible off gas, and tar as effluents from the pyrolyzer;
condensing the tar to separate the tar and off gas;
using the tar as a binder for the fines without discharging the tar to the environment;
using the combustible off gas as a source of fuel in the pyrolyzer without discharging the off gas to the environment.
30. A method according to claim 29 wherein all condensed tar is utilized as binder and all combustible off gas is used to fuel the pyrolyzer.
31. A method according to claim 29 wherein the condensed tar is the sole binder source and the combustible off-gas is the sole source of fuel for the pyrolyzer.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US10/691,339 US20040079628A1 (en) | 2001-09-17 | 2003-10-22 | Clean production of coke |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US09/954,603 US20030057083A1 (en) | 2001-09-17 | 2001-09-17 | Clean production of coke |
US10/691,339 US20040079628A1 (en) | 2001-09-17 | 2003-10-22 | Clean production of coke |
Related Parent Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US09/954,603 Continuation US20030057083A1 (en) | 2001-09-17 | 2001-09-17 | Clean production of coke |
Publications (1)
Publication Number | Publication Date |
---|---|
US20040079628A1 true US20040079628A1 (en) | 2004-04-29 |
Family
ID=25495675
Family Applications (4)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US09/954,603 Abandoned US20030057083A1 (en) | 2001-09-17 | 2001-09-17 | Clean production of coke |
US10/666,419 Abandoned US20040055864A1 (en) | 2001-09-17 | 2003-09-19 | Clean production of coke |
US10/691,339 Abandoned US20040079628A1 (en) | 2001-09-17 | 2003-10-22 | Clean production of coke |
US11/999,160 Expired - Lifetime US7785447B2 (en) | 2001-09-17 | 2007-12-03 | Clean production of coke |
Family Applications Before (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US09/954,603 Abandoned US20030057083A1 (en) | 2001-09-17 | 2001-09-17 | Clean production of coke |
US10/666,419 Abandoned US20040055864A1 (en) | 2001-09-17 | 2003-09-19 | Clean production of coke |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US11/999,160 Expired - Lifetime US7785447B2 (en) | 2001-09-17 | 2007-12-03 | Clean production of coke |
Country Status (2)
Country | Link |
---|---|
US (4) | US20030057083A1 (en) |
WO (1) | WO2003025093A1 (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20050223632A1 (en) * | 1999-12-02 | 2005-10-13 | Matviya Thomas M | Cellular coal products |
US20060222854A1 (en) * | 2005-03-31 | 2006-10-05 | Matviya Thomas M | High density carbon foam |
US7611609B1 (en) * | 2001-05-01 | 2009-11-03 | ArcelorMittal Investigacion y Desarrollo, S. L. | Method for producing blast furnace coke through coal compaction in a non-recovery or heat recovery type oven |
Families Citing this family (63)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20100038288A1 (en) * | 2008-08-12 | 2010-02-18 | MR&E, Ltd. | Refining coal-derived liquid from coal gasification, coking, and other coal processing operations |
US8287696B2 (en) * | 2008-09-05 | 2012-10-16 | Purdue Research Foundation | Multipurpose coke plant for synthetic fuel production |
US8394240B2 (en) * | 2009-07-14 | 2013-03-12 | C2O Technologies, Llc | Process for treating bituminous coal by removing volatile components |
US8470134B2 (en) * | 2009-07-14 | 2013-06-25 | C2O Technologies, Llc | Process for treating coal by removing volatile components |
GB0912214D0 (en) * | 2009-07-14 | 2009-08-26 | Eden Robert D | Pyrolyser |
EP2616524A2 (en) * | 2010-09-16 | 2013-07-24 | Franklin G. Rinker | Coal processing with added biomass and volatile control |
WO2012048205A2 (en) * | 2010-10-08 | 2012-04-12 | Munchkin, Inc. | Toilet training devices for small children |
CA2832887A1 (en) | 2011-04-11 | 2012-10-18 | ADA-ES, Inc. | Fluidized bed method and system for gas component capture |
US8968520B2 (en) | 2011-06-03 | 2015-03-03 | National Institute Of Clean And Low-Carbon Energy (Nice) | Coal processing to upgrade low rank coal having low oil content |
RU2458974C1 (en) * | 2011-06-08 | 2012-08-20 | Государственное образовательное учреждение высшего профессионального образования "Национальный исследовательский Томский политехнический университет" | Method of producing fuel briquettes from low-grade fuel |
CN103687934A (en) * | 2011-06-10 | 2014-03-26 | 丹麦科技大学 | Torrefaction and partial pyrolysis to produce fuel pellets with counter current flow of tar |
US9005322B2 (en) | 2011-07-12 | 2015-04-14 | National Institute Of Clean And Low-Carbon Energy (Nice) | Upgrading coal and other carbonaceous fuels using a lean fuel gas stream from a pyrolysis step |
US9074138B2 (en) | 2011-09-13 | 2015-07-07 | C2O Technologies, Llc | Process for treating coal using multiple dual zone steps |
KR101325432B1 (en) * | 2011-11-28 | 2013-11-04 | 주식회사 포스코 | Method for removing byproduct of tar mixer and Apparatus for removing the same |
US9261274B2 (en) * | 2011-12-21 | 2016-02-16 | Res Usa, Llc | Supplemental fuel to combustor of dual fluidized bed gasifier |
RU2484125C1 (en) * | 2012-04-16 | 2013-06-10 | Федеральное государственное бюджетное образовательное учреждение высшего профессионального образования "Национальный исследовательский Томский политехнический университет" | Method of making fuel briquettes from biomass |
US9243186B2 (en) | 2012-08-17 | 2016-01-26 | Suncoke Technology And Development Llc. | Coke plant including exhaust gas sharing |
US9359554B2 (en) | 2012-08-17 | 2016-06-07 | Suncoke Technology And Development Llc | Automatic draft control system for coke plants |
WO2014047354A1 (en) | 2012-09-20 | 2014-03-27 | ADA-ES, Inc. | Method and system to reclaim functional sites on a sorbent contaminated by heat stable salts |
US10047295B2 (en) | 2012-12-28 | 2018-08-14 | Suncoke Technology And Development Llc | Non-perpendicular connections between coke oven uptakes and a hot common tunnel, and associated systems and methods |
CA2896475C (en) | 2012-12-28 | 2020-03-31 | Suncoke Technology And Development Llc. | Systems and methods for removing mercury from emissions |
US10883051B2 (en) | 2012-12-28 | 2021-01-05 | Suncoke Technology And Development Llc | Methods and systems for improved coke quenching |
US9238778B2 (en) | 2012-12-28 | 2016-01-19 | Suncoke Technology And Development Llc. | Systems and methods for improving quenched coke recovery |
CA2896478C (en) | 2012-12-28 | 2016-06-07 | Suncoke Technology And Development Llc. | Vent stack lids and associated systems and methods |
US10760002B2 (en) | 2012-12-28 | 2020-09-01 | Suncoke Technology And Development Llc | Systems and methods for maintaining a hot car in a coke plant |
US9476547B2 (en) | 2012-12-28 | 2016-10-25 | Suncoke Technology And Development Llc | Exhaust flow modifier, duct intersection incorporating the same, and methods therefor |
CN104955921B (en) | 2013-01-09 | 2017-09-15 | C2O技术发展公司 | Handle method of the coal to improve the recovery of condensable coal derived liquid |
US9273250B2 (en) | 2013-03-15 | 2016-03-01 | Suncoke Technology And Development Llc. | Methods and systems for improved quench tower design |
PL3090034T3 (en) | 2013-12-31 | 2020-10-05 | Suncoke Technology And Development Llc | Methods for decarbonizing coking ovens, and associated systems and devices |
UA123141C2 (en) | 2014-06-30 | 2021-02-24 | Санкоук Текнолоджі Енд Дівелепмент Ллк | Horizontal heat recovery coke ovens having monolith crowns |
CN104101554B (en) * | 2014-07-16 | 2017-05-03 | 首钢总公司 | Determining device and detecting method for reactivity and hot strength of coke |
WO2016016716A1 (en) | 2014-07-31 | 2016-02-04 | Sabic Global Technologies B.V. | Methods for utilizing olefin coke in a steel making process and products made therefrom |
RU2644461C1 (en) | 2014-08-28 | 2018-02-12 | САНКОУК ТЕКНОЛОДЖИ ЭНД ДИВЕЛОПМЕНТ ЭлЭлСи | System for coke furnace loading |
EP3194531A4 (en) | 2014-09-15 | 2018-06-20 | Suncoke Technology and Development LLC | Coke ovens having monolith component construction |
BR112017014233A2 (en) * | 2014-12-31 | 2018-03-27 | Suncoke Tech & Development Llc | coke material multimodal beds |
KR102531894B1 (en) | 2015-01-02 | 2023-05-11 | 선코크 테크놀러지 앤드 디벨로프먼트 엘엘씨 | Integrated coke plant automation and optimization using advanced control and optimization technology |
US11060032B2 (en) | 2015-01-02 | 2021-07-13 | Suncoke Technology And Development Llc | Integrated coke plant automation and optimization using advanced control and optimization techniques |
US9327320B1 (en) | 2015-01-29 | 2016-05-03 | Green Search, LLC | Apparatus and method for coal dedusting |
CN104698147B (en) * | 2015-02-12 | 2016-06-29 | 首钢总公司 | A kind of coking coal cost performance method for quantitatively evaluating |
WO2017011912A1 (en) * | 2015-07-21 | 2017-01-26 | British Columbia Biocarbon Ltd. | Biocoal fuel product and processes and systems for the production thereof |
KR102253567B1 (en) | 2015-12-28 | 2021-05-17 | 선코크 테크놀러지 앤드 디벨로프먼트 엘엘씨 | Method and system for dynamically filling a coke oven |
EP3465369A4 (en) | 2016-06-03 | 2020-01-15 | Suncoke Technology and Development LLC | Methods and systems for automatically generating a remedial action in an industrial facility |
WO2018154499A1 (en) * | 2017-02-24 | 2018-08-30 | Afri Eco Trade (Pty) Ltd. | Production of form coke |
BR112019024618B1 (en) | 2017-05-23 | 2022-05-03 | Suncoke Technology And Development Llc | System and method for repairing a coke oven |
CA3040059C (en) * | 2017-07-18 | 2020-10-27 | Ekomatter Ip Holdings 2 Llc | Coke processing energy production |
US20210355386A1 (en) * | 2017-07-18 | 2021-11-18 | Ekomatter Ip Holdings 1 Llc | Custom Coke Production |
US10530428B2 (en) * | 2017-12-08 | 2020-01-07 | JRL Coal, Inc. | Coal tracker |
WO2020122888A1 (en) * | 2018-12-12 | 2020-06-18 | Ekomatter Ip Holdings 3 Llc | Carbonaceous material processing |
WO2020140086A1 (en) | 2018-12-28 | 2020-07-02 | Suncoke Technology And Development Llc | Particulate detection for industrial facilities, and associated systems and methods |
WO2020140092A1 (en) | 2018-12-28 | 2020-07-02 | Suncoke Technology And Development Llc | Heat recovery oven foundation |
BR112021012511B1 (en) | 2018-12-28 | 2023-05-02 | Suncoke Technology And Development Llc | SPRING LOADED HEAT RECOVERY FURNACE SYSTEM AND METHOD |
WO2020140079A1 (en) | 2018-12-28 | 2020-07-02 | Suncoke Technology And Development Llc | Decarbonizatign of coke ovens, and associated systems and methods |
BR112021012598B1 (en) | 2018-12-28 | 2024-01-23 | Suncoke Technology And Development Llc | METHOD FOR DETECTING A LEAK IN A SYSTEM FOR COKING COAL, METHOD FOR DETECTING AN AIR LEAK IN A SYSTEM FOR COKING COAL, METHOD FOR DETECTING AN AIR LEAK IN A SYSTEM FOR COKING COAL UNDER NEGATIVE PRESSURE, AND METHOD FOR DETECTING A LEAK IN AIR BETWEEN A HIGH PRESSURE SYSTEM AND A LOW PRESSURE SYSTEM |
WO2020140074A1 (en) | 2018-12-28 | 2020-07-02 | Suncoke Technology And Development Llc | Improved oven uptakes |
US11486572B2 (en) | 2018-12-31 | 2022-11-01 | Suncoke Technology And Development Llc | Systems and methods for Utilizing flue gas |
WO2020142391A1 (en) | 2018-12-31 | 2020-07-09 | Suncoke Technology And Development Llc | Methods and systems for providing corrosion resistant surfaces in contaminant treatment systems |
JP7335513B2 (en) | 2020-04-01 | 2023-08-30 | 日本製鉄株式会社 | coke production method |
WO2021225988A1 (en) | 2020-05-03 | 2021-11-11 | Suncoke Technology And Development Llc | High-quality coke products |
EP4225873A1 (en) * | 2020-10-12 | 2023-08-16 | Tata Steel Limited | A method for producing metallurgical coke and the metallurigical coke thereof |
WO2022235839A1 (en) * | 2021-05-04 | 2022-11-10 | Suncoke Technology And Development Llc | Foundry coke products, and associated systems and methods |
US11946108B2 (en) | 2021-11-04 | 2024-04-02 | Suncoke Technology And Development Llc | Foundry coke products and associated processing methods via cupolas |
KR20230164076A (en) | 2021-11-04 | 2023-12-01 | 선코크 테크놀러지 앤드 디벨로프먼트 엘엘씨 | Foundry coke products and related systems, devices and methods |
WO2023119146A1 (en) * | 2021-12-23 | 2023-06-29 | Tata Steel Limited | A method for producing metallurgical coke and the metallurigical coke thereof |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1912002A (en) * | 1929-09-12 | 1933-05-30 | Combustion Utilities Corp | Process of making carbonized fuel briquettes |
US4352720A (en) * | 1979-04-05 | 1982-10-05 | Firma Carl Still Gmbh & Co., Kg | Process and apparatus for the production of molded metallurgical coke from coal briquettes |
US4530752A (en) * | 1984-06-20 | 1985-07-23 | Union Oil Company Of California | Oil shale retorting process |
US6043289A (en) * | 1997-04-22 | 2000-03-28 | Institut Francais Du Petrole | Catalyzed degradation of thermoplastic polyolefins and incorporation of the degradation products into heavy hydrocarbons |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5251402A (en) * | 1975-10-23 | 1977-04-25 | Nippon Kokan Kk <Nkk> | Manufacturing of metallurgical coke |
US4052168A (en) * | 1976-01-12 | 1977-10-04 | Edward Koppelman | Process for upgrading lignitic-type coal as a fuel |
FR2385786A1 (en) * | 1977-03-28 | 1978-10-27 | Nord Pas Calais Houilleres | PROCESS FOR OBTAINING MOLD COKE FROM NON-COKEFIABLE COALS |
US4164467A (en) * | 1977-12-14 | 1979-08-14 | Liller Delbert I | Coal washing plant employing a feed equalizer and a critically dimensioned deflector surface in the inlet pipes of a plurality of cyclones |
US4314887A (en) * | 1978-06-19 | 1982-02-09 | Peabody Coal Company, Inc. | Apparatus for producing coke from fine and coarse coal |
DE3163120D1 (en) * | 1980-01-15 | 1984-05-24 | Centre Rech Metallurgique | Process for manufacturing metallurgical coke from a coal mixture |
US5752993A (en) * | 1994-01-21 | 1998-05-19 | Covol Technologies, Inc. | Blast furnace fuel from reclaimed carbonaceous materials and related methods |
-
2001
- 2001-09-17 US US09/954,603 patent/US20030057083A1/en not_active Abandoned
-
2002
- 2002-02-01 WO PCT/US2002/002839 patent/WO2003025093A1/en not_active Application Discontinuation
-
2003
- 2003-09-19 US US10/666,419 patent/US20040055864A1/en not_active Abandoned
- 2003-10-22 US US10/691,339 patent/US20040079628A1/en not_active Abandoned
-
2007
- 2007-12-03 US US11/999,160 patent/US7785447B2/en not_active Expired - Lifetime
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1912002A (en) * | 1929-09-12 | 1933-05-30 | Combustion Utilities Corp | Process of making carbonized fuel briquettes |
US4352720A (en) * | 1979-04-05 | 1982-10-05 | Firma Carl Still Gmbh & Co., Kg | Process and apparatus for the production of molded metallurgical coke from coal briquettes |
US4530752A (en) * | 1984-06-20 | 1985-07-23 | Union Oil Company Of California | Oil shale retorting process |
US6043289A (en) * | 1997-04-22 | 2000-03-28 | Institut Francais Du Petrole | Catalyzed degradation of thermoplastic polyolefins and incorporation of the degradation products into heavy hydrocarbons |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20050223632A1 (en) * | 1999-12-02 | 2005-10-13 | Matviya Thomas M | Cellular coal products |
US8048528B2 (en) | 1999-12-02 | 2011-11-01 | Touchstone Research Laboratory, Ltd. | Cellular coal products |
US7611609B1 (en) * | 2001-05-01 | 2009-11-03 | ArcelorMittal Investigacion y Desarrollo, S. L. | Method for producing blast furnace coke through coal compaction in a non-recovery or heat recovery type oven |
US20060222854A1 (en) * | 2005-03-31 | 2006-10-05 | Matviya Thomas M | High density carbon foam |
WO2006105493A1 (en) * | 2005-03-31 | 2006-10-05 | Touchstone Research Laboratory, Ltd. | High density carbon foam |
Also Published As
Publication number | Publication date |
---|---|
US20040055864A1 (en) | 2004-03-25 |
US7785447B2 (en) | 2010-08-31 |
WO2003025093A1 (en) | 2003-03-27 |
US20080116052A1 (en) | 2008-05-22 |
US20030057083A1 (en) | 2003-03-27 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US7785447B2 (en) | Clean production of coke | |
US5807420A (en) | Process for reduction of iron with solid fuel objects as amended by exam | |
US8790420B2 (en) | Method for producing reduced metal and slag containing oxidized nonferrous metal using an upgraded coal | |
RU2346058C2 (en) | Plant for manufacturing of melted iron by means of injection of fine-dispersed carbon-bearing material into gas-producing melting furnace and manufacturing method of melted iron by using of this plant | |
JP4278521B2 (en) | Metallurgical coke production | |
CA2294272C (en) | Method for using coal fines in a melt-down gasifier | |
CN113817521A (en) | Preparation method of biomass charcoal composite fuel for blast furnace injection | |
Lu et al. | Evaluation of coal for metallurgical applications | |
US4362532A (en) | Production of blast furnace coke via novel briquetting system | |
CN103370396B (en) | The preparation method of partially carbonized coal briquette, the preparation facilities of partially carbonized coal briquette and molten iron preparation facilities | |
US4135983A (en) | Method for improving coking property of coal for use in production of cokes | |
ÖZDEN et al. | A PILOT PLANT SCALE INVESTIGATION OF POSSIBILITY OF USING NON-COKING ARMUTÇUK AND AMASRA COALS IN METALLURGICAL COKE PRODUCTION | |
KR101353896B1 (en) | Manufacture method of coke dust briquetting | |
US4243488A (en) | Coke compositions and process for manufacturing same | |
KR101969110B1 (en) | Method for manufacturing coal briquettes and apparatus for manufacturing the same | |
Gray | Coal to coke conversion | |
Lu | Utilization parameters of coal for metallurgical applications | |
Kuyumcu | Preparation of coal blends for coke-making | |
JP5532574B2 (en) | Method for producing a coagulation material for sinter production | |
US4248669A (en) | Process for making metallurgical coke using fluidizer char | |
CN116287522A (en) | Metallized pellet for electric furnace and preparation process thereof | |
US2184317A (en) | Wood coke and process of making same | |
KR101626814B1 (en) | Coal briquettes and Method for manufacturing the same | |
Teleshev | 98lO1021 Effect of coal moisture control on coke qualities | |
CN115354150A (en) | Biomass carbon-containing pellet for blast furnace ironmaking and preparation method thereof |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
STCB | Information on status: application discontinuation |
Free format text: ABANDONED -- FAILURE TO RESPOND TO AN OFFICE ACTION |