US20030188634A1 - Pressure swing adsorption process with controlled internal depressurization flow - Google Patents
Pressure swing adsorption process with controlled internal depressurization flow Download PDFInfo
- Publication number
- US20030188634A1 US20030188634A1 US10/119,165 US11916502A US2003188634A1 US 20030188634 A1 US20030188634 A1 US 20030188634A1 US 11916502 A US11916502 A US 11916502A US 2003188634 A1 US2003188634 A1 US 2003188634A1
- Authority
- US
- United States
- Prior art keywords
- gas
- adsorber
- bed
- product
- feed
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
- B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
- B01D53/047—Pressure swing adsorption
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
- B01D2253/10—Inorganic adsorbents
- B01D2253/106—Silica or silicates
- B01D2253/108—Zeolites
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
- B01D2253/10—Inorganic adsorbents
- B01D2253/116—Molecular sieves other than zeolites
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
- B01D2253/25—Coated, impregnated or composite adsorbents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2256/00—Main component in the product gas stream after treatment
- B01D2256/10—Nitrogen
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/10—Single element gases other than halogens
- B01D2257/104—Oxygen
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2259/00—Type of treatment
- B01D2259/40—Further details for adsorption processes and devices
- B01D2259/40003—Methods relating to valve switching
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2259/00—Type of treatment
- B01D2259/40—Further details for adsorption processes and devices
- B01D2259/40011—Methods relating to the process cycle in pressure or temperature swing adsorption
- B01D2259/40013—Pressurization
- B01D2259/40016—Pressurization with three sub-steps
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2259/00—Type of treatment
- B01D2259/40—Further details for adsorption processes and devices
- B01D2259/40011—Methods relating to the process cycle in pressure or temperature swing adsorption
- B01D2259/40013—Pressurization
- B01D2259/40018—Pressurization with more than three sub-steps
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2259/00—Type of treatment
- B01D2259/40—Further details for adsorption processes and devices
- B01D2259/40011—Methods relating to the process cycle in pressure or temperature swing adsorption
- B01D2259/40028—Depressurization
- B01D2259/40032—Depressurization with three sub-steps
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2259/00—Type of treatment
- B01D2259/40—Further details for adsorption processes and devices
- B01D2259/40011—Methods relating to the process cycle in pressure or temperature swing adsorption
- B01D2259/40028—Depressurization
- B01D2259/40033—Depressurization with more than three sub-steps
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2259/00—Type of treatment
- B01D2259/40—Further details for adsorption processes and devices
- B01D2259/40011—Methods relating to the process cycle in pressure or temperature swing adsorption
- B01D2259/40043—Purging
- B01D2259/4005—Nature of purge gas
- B01D2259/40052—Recycled product or process gas
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2259/00—Type of treatment
- B01D2259/40—Further details for adsorption processes and devices
- B01D2259/40011—Methods relating to the process cycle in pressure or temperature swing adsorption
- B01D2259/40058—Number of sequence steps, including sub-steps, per cycle
- B01D2259/40069—Eight
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2259/00—Type of treatment
- B01D2259/40—Further details for adsorption processes and devices
- B01D2259/40011—Methods relating to the process cycle in pressure or temperature swing adsorption
- B01D2259/40058—Number of sequence steps, including sub-steps, per cycle
- B01D2259/40073—Ten
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2259/00—Type of treatment
- B01D2259/40—Further details for adsorption processes and devices
- B01D2259/40011—Methods relating to the process cycle in pressure or temperature swing adsorption
- B01D2259/40058—Number of sequence steps, including sub-steps, per cycle
- B01D2259/40075—More than ten
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2259/00—Type of treatment
- B01D2259/40—Further details for adsorption processes and devices
- B01D2259/40011—Methods relating to the process cycle in pressure or temperature swing adsorption
- B01D2259/40077—Direction of flow
- B01D2259/40081—Counter-current
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2259/00—Type of treatment
- B01D2259/40—Further details for adsorption processes and devices
- B01D2259/402—Further details for adsorption processes and devices using two beds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
- B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
- B01D53/047—Pressure swing adsorption
- B01D53/053—Pressure swing adsorption with storage or buffer vessel
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Separation Of Gases By Adsorption (AREA)
Abstract
A gas transfer segment of a pressure swing adsorption process cycle utilizing multiple parallel adsorbent beds, each bed having a feed end and a product end, wherein the gas transfer segment comprises transferring gas from a bed at a higher pressure to another bed at a lower pressure followed by withdrawing a waste depressurization gas from the feed end of the bed while transferring gas from the bed at a higher pressure to another bed a lower pressure.
Description
- Pressure swing adsorption is an important gas separation process which is widely used in the process and manufacturing industries. Pressure swing adsorption (PSA) is used for recovering high-purity gas products from crude process gas streams, for example in hydrogen production, or as an alternative to hauled-in atmospheric gas products or onsite cryogenic air separation processes. The PSA process has been highly developed for the separation of a wide variety of gas mixtures including, for example, the separation of air to provide oxygen and nitrogen products. For smaller product volumes in air separation applications, PSA processes may use a single adsorbent bed and one or more gas storage tanks to provide a constant product flow as well as gas for repressurization and purge. At higher product volumes, multiple adsorbent beds operating in parallel with overlapping cycles are used to generate a constant product gas flow as well as provide gas for repressurization and purge.
- Each adsorbent bed in a pressure swing adsorption (PSA) cycle proceeds through a sequence of steps beginning with a feed or adsorption step in which a pressurized feed gas mixture is passed through a bed of adsorbent which selectively adsorbs one or more of the components in the mixed feed gas. A product gas containing the desired component at acceptable purity is withdrawn from the bed until the adsorption step is terminated at a predetermined time.
- After termination of the adsorption step, the pressure in the bed is reduced in one or more steps in which gas is transferred at decreasing pressure to one or more other beds to provide pressurization gas to those beds. Final depressurization typically is completed by withdrawing a waste gas in a final waste depressurization or blowdown step. The depressurized bed then is purged with product gas or transfer gas provided from other beds, thereby removing additional adsorbed components and void space gas from the bed.
- Upon completion of the purge step, the bed is repressurized to an intermediate pressure by one or more pressurization steps in which gas is transferred from other beds, and the bed then is pressurized further to the feed pressure with feed and/or product gas. The steps are repeated in a cyclic manner.
- The transfer of gas from a bed at decreasing pressure to another bed at increasing pressure is an important and highly-developed feature of many PSA cycles. In this bed-to-bed gas transfer process, gas which is below product quality, but which still contains a significant concentration of the final product component, is transferred from the product end of a bed to the product end of another bed. This important step significantly increases product recovery, but must be carefully controlled to meet the required product purity. Optionally, gas of lower quality can be transferred from the feed end of the bed to the feed end of another bed.
- Further refinement in the bed-to-bed gas transfer process holds promise for needed improvements in product recovery and product purity, and also for increased productivity, in the PSA process. In particular, there is a need for improved control of gas flow within a bed undergoing gas withdrawal during the gas transfer process. This need is addressed by the present invention as described below and defined by the claims which follow.
- The invention relates to a gas transfer segment of a pressure swing adsorption process cycle utilizing multiple parallel adsorbent beds, each bed having a feed end and a product end, wherein the gas transfer segment comprises transferring gas from a bed at a higher pressure to another bed at a lower pressure followed by withdrawing a waste depressurization gas from the feed end of the bed while transferring gas from the bed at a higher pressure to another bed a lower pressure.
- The invention includes a pressure swing adsorption process for recovering a less readily adsorbable component from a feed gas mixture comprising at least one less readily adsorbable component and at least one more readily adsorbable component. The process comprises performing cyclic process steps in a plurality of adsorbent beds, each bed having a feed end and a product end and containing adsorbent material which selectively adsorbs the more readily adsorbable component, each bed proceeding in turn through cyclic process segments which include an adsorption-make product segment, a first gas transfer segment in which gas flows from a bed initially at a higher pressure into one or more other beds initially at a lower pressure or lower pressures, a regeneration segment, a second gas transfer segment in which gas flows into a bed initially at a lower pressure from one or more other beds initially at a higher pressure or higher pressures, and a final repressurization segment. The gas transfer segments include (1) transferring gas from the product end of the bed to the product end of another bed followed by (2) withdrawing waste depressurization gas from the feed end of the bed while continuing to transfer gas from the product end of the bed to the product end of another bed.
- The ratio of the volume of gas transferred from the product end of the bed during (1) to the volume of gas transferred from the product end of the bed during (2) may be between about 3 and about 20. During (2), the ratio of the volume of waste depressurization gas withdrawn from the feed end of the bed to the volume of gas transferred from the product end of the bed may be between about 0.1 and about 0.6.
- The feed gas mixture may be air wherein the more readily adsorbable component is oxygen and the less readily adsorbable component is nitrogen. The adsorbent material may comprise carbon molecular sieve which is kinetically more selective for the adsorption of oxygen than nitrogen.
- During either or both of (1) and (2), the pressure swing adsorption process may also include transferring gas from the feed end of the bed to the feed end or ends of the one or more other beds. The process also may further comprise, prior to (1), an additional step of transferring gas from the product end of the bed at a higher pressure to the product end of another bed at a lower pressure. The ratio of the volume of gas transferred from the product end of the bed during (1) to the volume of gas transferred from the product end of the bed during (2) may be between about 3 and about 20. During (2), the ratio of the volume of waste depressurization gas withdrawn from the feed end of the bed to the volume of gas transferred from the product end of the bed may be between about 0.1 and about 0.6.
- In another embodiment, the process may further comprise, during either or both of (1) and (2), transferring gas from a point intermediate the feed end and the product end of the bed to the feed end or ends of the one or more other beds. The process may include, prior to (1), an additional step of transferring gas from the product end of the bed at a higher pressure to the product end of another bed at a lower pressure. In this embodiment, the ratio of the volume of gas transferred from the product end of the bed during (1) to the volume of gas transferred from the product end of the bed during (2) may be between about 3 and about 20. During (2), the ratio of the volume of waste depressurization gas withdrawn from the feed end of the bed to the volume of gas transferred from the product end of the bed may be between about 0.1 and about 0.6.
- The invention also relates to a pressure swing adsorption process for recovering a less readily adsorbable component from a pressurized feed gas comprising at least one less readily adsorbable component and at least one more readily adsorbable component, which process comprises performing cyclic process steps in two parallel adsorbers, each adsorber having a feed end and a product end and containing adsorbent material which selectively adsorbs the more readily adsorbable component. The cyclic process steps include:
- (a) providing a pressurized feed gas at superatmospheric pressure and introducing the pressurized feed gas into the feed end of a first adsorber, selectively adsorbing a portion of the more readily adsorbable component on the adsorptive material, and withdrawing from the product end of the first adsorber a product gas enriched in the less readily adsorbable component;
- (b) depressurizing the first adsorber by (1) transferring gas from an outlet at the product end of the first adsorber into the product end of the second adsorber and (2) withdrawing gas through an additional outlet disposed at a distance from the product end of the first adsorber and transferring this gas into the feed end of the second adsorber;
- (c) continuing to transfer gas from the outlet at the product end of the first adsorber into the product end of the second adsorber and from the additional outlet of the first adsorber into the feed end of the second adsorber while simultaneously withdrawing waste depressurization gas from the feed end of the first adsorber;
- (d) terminating all transfer of gas from the first adsorber to the second adsorber while continuing to withdraw waste depressurization gas from the feed end of the first adsorber;
- (e) introducing product gas into the product end of the first adsorber while continuing to withdraw waste depressurization gas from the feed end of the first adsorber;
- (f) pressurizing the first adsorber by (1) transferring gas from an outlet at the product end of the second adsorber to the product end of the first adsorber and (2) withdrawing gas through an additional outlet disposed at a distance from the product end of the second adsorber and transferring this gas into the feed end of the first adsorber, wherein the second adsorber is initially at a higher pressure than the first adsorber;
- (g) further pressurizing the first adsorber by transferring gas from the product end of the second adsorber to the product end of the first adsorber and from the additional outlet of the second adsorber to the feed end of the first adsorber, and withdrawing waste depressurization gas from the feed end of the second adsorber;
- (h) terminating all transfer of gas from the second adsorber to the first adsorber and further pressurizing the first adsorber by one or more steps selected from the group consisting of introducing product gas into the product end thereof, introducing pressurized feed gas mixture into the feed end thereof, and introducing product gas into the product end thereof while also introducing pressurized feed gas into the feed end thereof; and
- (i) repeating steps (a) through (h) in a cyclic manner.
- The additional outlet of the first adsorber in steps (b) and (c) may be at the feed end of the first adsorber and the additional outlet of the second adsorber in steps (f) and (g) may be at the feed end of the second adsorber. Alternatively, the additional outlet of the first adsorber in steps (b) and (c) may be intermediate the feed and product ends of the first adsorber and the additional outlet of the second adsorber in steps (f) and (g) may be intermediate the feed and product ends of the second adsorber.
- The process may further comprise, following step (a) and prior to step (b), transferring gas from the product end of the first adsorber into the product end of the second adsorber, wherein the second adsorber is at a lower pressure than the first adsorber; and following step (e) and prior to step (f), further pressurizing the first adsorber by transferring gas from the product end of the second adsorber to the product end of the first adsorber, wherein the second adsorber is at a higher pressure than the first adsorber.
- The process may further comprise, following step (e) and prior to step (f), terminating the withdrawal of waste depressurization gas from the feed end of the first adsorber and continuing to introduce product gas into the product end of the first adsorber. Alternatively, the process may further comprise, following step (a), terminating the introducing of the pressurized feed gas into the feed end of the first adsorber while continuing withdrawing from the product end of the first adsorber a product gas enriched in the less readily adsorbable component.
- FIG. 1 is a schematic flow diagram of a PSA system which can be used with the process cycles of the present invention.
- FIG. 2 is a bed step diagram illustrating the process steps for an adsorbent bed according to one embodiment of the present invention.
- FIG. 3 is a bed step diagram illustrating the process steps for an adsorbent bed according to a second embodiment of the present invention.
- FIG. 4 is a bed step diagram illustrating the process steps for an adsorbent bed according to a third embodiment of the present invention.
- The present invention relates to improved pressure swing adsorption process cycles with particular emphasis on improved aspects of the gas transfer steps in which gas is transferred from a bed at a higher pressure to another bed at a lower pressure. In the following discussion, the PSA cycle is defined as a series of process segments, each of which may include one or more individual process steps. Each PSA cycle of the present invention is divided into five process segments, each of which comprises one or more individual process steps, some of which are optional. The process segments as defined below for each individual adsorbent bed are (1) an adsorption/make product segment, (2) a first gas transfer segment, (3) a bed regeneration segment, (4) a second gas transfer segment, and (5) a bed repressurization segment.
- The adsorption/make product segment is defined as the withdrawal of product gas from an adsorbent bed during which feed gas is introduced into the bed for at least a portion of the segment. The more readily adsorbed component or components are selectively adsorbed by the adsorbent material during this segment. The first gas transfer segment is defined as one or more steps in which gas is transferred from the bed at a higher pressure to one or more other beds at a lower pressure or lower pressures. The regeneration segment is defined as the desorption and removal of adsorbed components and void space gas from the bed, one step of which is defined as waste depressurization in which void space and desorbed gas are discharged from the feed end of the bed as the pressure in the bed decreases. The resulting waste depressurization gas is discharged directly from the PSA process, typically as a waste stream. The second gas transfer segment is defined as one or more steps in which gas is transferred to the bed at a lower pressure from one or more other beds at a higher pressure or higher pressures. The bed repressurization segment is defined as pressurizing the first bed by one or more steps selected from the group consisting of introducing product gas into the product end thereof, introducing pressurized feed gas mixture into the feed end thereof, and introducing product gas into the product end thereof while also introducing pressurized feed gas into the feed end thereof.
- The generic term “gas transfer segment” is defined to include both the first and second gas transfer segments defined above, and therefore includes by definition the transfer of gas between any bed and one or more other beds.
- In all embodiments of the invention as described below, the gas transfer segment partially overlaps the regeneration segment such that (1) gas is transferred from a bed at a higher pressure to another bed at a lower pressure and then (2) a waste depressurization gas is withdrawn from the feed end of the bed and simultaneously gas is transferred from the bed at a higher pressure to another bed a lower pressure. When air is the feed gas being separated, waste depressurization may be driven by the differential pressure between the bed pressure and atmospheric pressure, and the waste depressurization gas may be discharged directly to the atmosphere. Alternatively, the waste depressurization gas may be discharged into a vessel or reservoir which is initially at a lower pressure than the bed pressure and the discharged gas may be utilized as a secondary gas product enriched in the more readily adsorbed component.
- The invention can be utilized in process cycles with multiple parallel adsorbent beds and is particularly adapted for use with two parallel beds. In one embodiment which uses two parallel beds, gas is transferred from the product end of the first bed to the product end of the second bed during an initial portion of the first gas transfer segment. Then, during a later step in the first gas transfer segment, while gas transfer continues from the product end of the first bed to the product end of the second bed, waste depressurization gas is withdrawn from the feed end of the first bed. Waste depressurization gas flows from the feed end of a bed as a result of a pressure differential between the bed and a lower pressure region.
- In a second embodiment, additional gas is transferred from the feed end of the first bed to the feed end of the second bed during both steps of the first gas transfer segment. In a third embodiment, additional gas is transferred from a point intermediate the feed and product ends of the first bed to the feed end of the second bed during both steps of the gas transfer segment. In an alternative version of either the second or third embodiment, an additional gas transfer step may be used at the beginning of the gas transfer segment such that the first gas transfer segment includes three gas transfer steps. This additional gas transfer step entails transferring gas from the product end of the first bed into the product end of the second bed. This alternative version of the invention thus comprises a gas transfer segment which includes a first step wherein gas is transferred from the product end of the first bed to the product end of the second bed, a second step in which gas continues to be transferred between the product ends of the first and second beds while additional gas is transferred between the feed ends of the beds or between an intermediate point in the first bed to the feed end of the second bed, and a third step in which waste depressurization gas is withdrawn from the feed end of the first bed while gas transfer continues at the feed and product ends.
- The features of the present invention can be applied in process cycles which utilize two or more adsorbent beds and can be used generically to separate any gas mixture which contains components which are more readily adsorbed and other components which are less readily adsorbed by the adsorbent material in the beds. The invention is particularly useful for the recovery of high purity nitrogen from air, and can be operated economically with two adsorbent beds.
- FIG. 1 is a schematic flow diagram for a two-bed PSA system typical of those known in the art which can be utilized for operation of the PSA process of the present invention. The invention is illustrated below for the recovery of nitrogen from air and is not limited to operation using this particular system. Any appropriate type of PSA system known in the art may be utilized for the invention. The system of FIG. 1 includes air compressor1, feed
flow control valve 3 andmanifolds feed valves Manifold 13 is connected tomanifolds valves Valve 19 andcontrol valve 21connect manifold 13 withwaste discharge line 23.Manifolds adsorber beds - In one embodiment of the invention later described, midpoint
gas transfer manifolds valves control valve 39, andcheck valves Gas withdrawal assemblies -
Product gas manifolds adsorber beds valves product line 59.Flow control valve 61 connectsproduct line 59 withproduct tank 63 andproduct line 65 transfers final product gas to a downstream user. -
Purge line 67 withflow control valve 69 connectsproduct manifolds Gas transfer manifold 71 withvalve 73 andcontrol valve 75 also connectproduct manifolds - A first embodiment of the invention is illustrated below for the recovery of nitrogen from air with reference to the schematic flow diagram of FIG. 1 and the bed step diagram of FIG. 2, which shows schematically the step sequence for a given bed through one process cycle. In this embodiment, midpoint
gas transfer manifolds valves control valve 39,check valves gas withdrawal assemblies - 1. Adsorption/Make Product Segment
- Step (1a): Feed air is compressed to a typical pressure of 110-130 psig in compressor1, passes through
flow control valve 3,control valve 9, andmanifold 5 intoadsorber bed 25. Oxygen is preferentially adsorbed therein and high purity nitrogen product which may contain 95 to 99.9995 vol % nitrogen flows viamanifold 49,valve 53,line 59,control valve 61, and intoproduct tank 63. Final product nitrogen is withdrawn vialine 65 to the user. The duration of this step is typically 60 to 180 seconds and the end-of-step pressure may be in the range of 100 to 120 psig. In this step and the following steps, a control valve typically is used for on-off control of a gas stream while a flow control valve is set to control gas flow at a predetermined value. In some applications, an orifice plate may be used instead of a flow control valve. - Step (1b) (optional): In this optional make product step, feed flow to
adsorber bed 25 is terminated by closingvalve 9 while product gas continues to flow throughproduct manifold 49. This optional step may continue for 0.5 to 2.0 seconds and is terminated by closingvalve 53. A typical end-of-step pressure is 98 to 118 psig. - 2. First Gas Transfer Segment
- Step (2a):
Valves valves bed 25 throughmanifolds bed 27. This step may continue for 1 to 10 seconds and may end when the differential pressure betweenbeds - Step (2b): While the product-end-to-product-end gas transfer of step (2a) continues,
valves bed 25 throughmanifold 5,manifold 13, andwaste discharge line 23. This step may continue for 0.5 to 3 seconds and typically ends when the differential pressure betweenbeds bed 25 at the end of step (2b) may be in the range of 40 to 60 psig. The ratio of the volume of gas transferred from the product end ofbed 25 during step (2a) to the volume of gas transferred from the product end ofbed 25 during step (2b) may be between about 3 and about 20. The ratio of the volume of waste depressurization gas withdrawn from the feed end ofbed 25 during step (2b) to the volume of gas transferred from the product end ofbed 25 during step (2b) may be between about 0.1 and about 0.6. - 3. Regeneration Segment
- Step (3a):
Valves valve 19 opens to increase the discharge rate of waste depressurization gas frombed 25. Step (3a) typically lasts for 4 to 5 seconds and may end when the pressure inbed 25 is in the range of 0 to 10 psig. - Step (3b):
Valve 69 opens and product purge gas flows viamanifolds bed 25 while waste gas continues to flow viamanifold 5,manifold 13,valves waste discharge line 23. Alternatively, product gas for purge may be obtained fromproduct tank 63 vialine 59 andvalve 53. Step (3b) typically lasts for 60 to 180 seconds and may be carried out at pressures approaching 0 psig. - Step (3c):
Valves valve 69 andmanifold 67 into the product end ofbed 25. This pushes the front of desorbing oxygen back into the bed in preparation for the following repressurization steps. Alternatively, product gas for this purpose may be obtained fromproduct tank 63 vialine 59 andvalve 53. Step (3c) typically lasts for 2 to 20 seconds and the end-of-step pressure inbed 25 may be in the range of 2 to 8 psig. This is an optional step. - 4. Second Gas Transfer Segment
- Step (4a):
Valve 69 closes andvalves bed 25 frombed 27, which has just completed adsorption/make product step (1a) or optionally has just completed make product step (1b).Valves beds - Step (4b): While the product-end-to-product-end gas transfer of step (4a) continues,
valves bed 27 throughmanifold 7,manifold 13, andwaste discharge line 23. This step may continue for 0.5 to 3 seconds and typically ends when the differential pressure betweenbeds bed 25 at the end of step (4b) is in the range of 35 to 60 psig. The ratio of the volume of gas transferred from the product end ofbed 27 during step (4a) to the volume of gas transferred from the product end ofbed 27 during step (4b) is preferably between about 3 and about 20. The ratio of the volume of waste depressurization gas withdrawn from the feed end ofbed 27 during step (4b) to the volume of gas transferred from the product end ofbed 27 during step (4b) preferably is between about 0.1 and about 0.6. - 5. Repressurization Segment
- Repressurization of
bed 25 commences whilebed 27 proceeds into step (3a).Bed 25 can be repressurized by any desired combination of product gas viavalve 53 andmanifold 49 and/or feed gas viavalves manifold 5. This step may continue for 3 to 5 seconds and may end when the pressure inbed 25 at the end of step (5) is in the range of 90 to 110 psig. - The process described above may be operated with several options and/or additional steps as described below.
- Option A: Additional Feed-end-to-feed-end Gas Transfer
- In this option, additional gas is transferred during steps (2a) and 2(b) from the feed end of
bed 25 throughmanifolds valves manifold 7 into the feed end ofbed 27.Valves bed 27 throughmanifolds valves manifold 5 into the feed end ofbed 25. This option is illustrated in the bed step diagram of FIG. 3. - Option B: Mid-bed-to-feed-end Gas Transfer
- This option utilizes midpoint
gas transfer manifolds valves control valve 39,check valves gas withdrawal assemblies gas withdrawal assembly 45,manifold 29,valve 35,manifold 31,control valve 39,manifold 33, andcheck valve 43 viamanifold 7 into the feed end ofbed 27. Additional gas is transferred during steps (4a) and (4b) fromgas withdrawal assembly 47,manifold 29,valve 37,manifold 31,control valve 39,manifold 33, andcheck valve 41 viamanifold 5 into the feed end ofbed 25. This option is illustrated in the bed step diagram of FIG. 4. - Option C: Intermediate-point-to-intermediate-point Gas Transfer
- In this option, additional gas is transferred during steps (2a) and 2(b) from
gas withdrawal assembly 45, which may be located at any desired point between the feed and product ends of bed 25 (not shown). The gas is transferred via a modified manifold (not shown) to a gas introduction point between the feed and product ends ofbed 27. The distance betweengas withdrawal assembly 45 and the feed end ofbed 25 is greater than the distance between the gas introduction point and feed and ofbed 27. Also, additional gas is transferred during steps (4a) and (4b) fromgas withdrawal assembly 47, which may be located at any convenient point between the feed and product ends of bed 27 (not shown). The gas is transferred via a modified manifold (not shown) to a gas introduction point between the feed and product ends ofbed 25. The distance betweengas withdrawal assembly 47 and the feed end ofbed 27 is greater than the distance between the gas introduction point and feed end ofbed 25. - Option D: Additional product-end-to-product-end Gas Transfer
- This option may be used in any of Options A, B, and C described above. Additional gas transfer steps between the product ends of
beds bed 25 to the feed end ofbed 27 by the valves and manifolds described above. A corresponding step (4) is added prior to step (4a) in which gas is transferred from the feed end ofbed 27 to the feed end ofbed 25 by the valves and manifolds described above. - Option E: Alternative Steps for Regeneration Segment
- Alternative steps may be used for the regeneration segment in any of the options described above. In one regeneration option, waste repressurization step (3a) is not used while steps (3b) and (3c) are used as described. In another regeneration option, purge step (3a) is used as described, purge step (3b) is not used, and product gas is not introduced into the product end of the bed during step (3c). These regeneration options are illustrated by the bed step diagrams of FIGS.1-4.
- The above description emphasizes the cycle of steps for
bed 25 with some reference to certain steps occurring inbed 27.Bed 27 proceeds through the same cycle steps described above forbed 25, but the two cycles are 180° out of phase. The main requirement is that gas transfer steps (2a) and (2b) inbed 25 must coincide with gas transfer steps (4a) and (4b) respectively inbed 27. In addition, gas transfer steps (2a) and (2b) inbed 27 must coincide with gas transfer steps (4a) and (4b) respectively inbed 25. - A two-bed PSA process utilizing cycle segments1 through 5 described above including Options B and D is operated according to the process flowsheet of FIG. 1 and the cycle step diagram of FIG. 4. Step (3a) is not used. The process separates feed air supplied at 700 SCFM and a pressure of 125 psig to yield 170 SCFM of high purity nitrogen product containing 99.99 vol % nitrogen.
Adsorbent beds TABLE 1 Cycle Times and Pressures for Each Bed Example 1 Duration, End-of-step Cycle Segment Step seconds pressure, psig Adsorption/ Make 1a 107 112 Product 1b 2 110 First Gas 2 1 105.5 Transfer 2a 5.5 65 2b 0.5 58.5 Regeneration 3b 95 0 3c 18 8 Second Gas 4 1 12.5 Transfer 4a 5.5 53 4b 0.5 56 Repressurization 5 4 100 -
TABLE 2 Cycle Steps and Times for Beds Example 1 Duration (sec) 4 91 16 2 1 5.5 0.5 4 91 16 2 1 5.5 0.5 End-of- Step 4 95 111 113 114 119.5 120 124 215 231 233 234 239.5 240 Time (sec) Cycle Step 5 1a 1b 2 2a 2b 3b 3c 4 4a 4b (bed 25) Cycle Step 3b 3c 4 4a 4b 5 1a 1b 2 2a 2b (bed 27) - The present invention thus offers a PSA cycle with improved control of gas flow within a bed undergoing gas withdrawal during the gas transfer process. Careful control and timing of gas transfer at the product ends of the beds and from an intermediate location and/or the feed ends of the beds yields several benefits. At the end of the adsorption/make product segment, the void spaces within the bed contain gas at high pressure which ranges in purity from product quality at the product end of the bed to lower quality at the feed end of the bed. In the first gas transfer segment, the pressure energy within this void gas is partially recovered and transferred to another bed. As described above, the transferred gas may be withdrawn from the product end, the feed end, or from a point intermediate either end.
- Gas transferred from the product end of the high pressure bed is of higher purity than gas from the middle or the feed end of the bed, and is therefore preferred for transfer to the product end of another bed which is at lower pressure. There is a possible deleterious effect of gas transfer from the product end which may limit the benefit of this gas transfer. As gas transfer proceeds, the gas within the bed will flow towards the product end of the bed, and the unwanted component of the feedstock may be drawn far enough towards the product end to reduce the effectiveness of the subsequent regeneration step in cleaning the bed. In addition, transfer of the unwanted component may result in contamination of the receiving bed.
- These deleterious effects may be reduced by conducting a portion of the gas transfer from a secondary outlet closer to the feed end of the high pressure bed, such as the middle of the bed, or from the feed end itself. The gas transfer from this secondary outlet causes internal gas flow away from the product end of the bed, which reduces the migration of the unwanted component towards that end of the bed. However, in order to provide a sufficient amount of internal flow towards the feed end of the bed and compensate for the internal flow due to gas transfer from the product end of the bed, the amount of gas transferred from the secondary outlet should be carefully controlled to prevent the excessive transfer of low purity gas to the receiving bed.
- The invention provides a means to optimize the internal gas flow in the higher pressure bed during gas transfer to the lower pressure bed. By utilizing carefully controlled waste depressurization from the feed end of the bed during a lafter portion of the gas transfer segment, additional internal gas flow is created towards the feed end to oppose the flow due to the gas transfer from the product end, and this minimizes the potential deleterious effects of the pressure transfer from the product end of the bed while maximizing the amount of gas which can be transferred. In addition, by initiating the waste depressurization step during the latter part of the first gas transfer segment, the regeneration segment is effectively lengthened, and the regeneration of the bed can be made more complete.
Claims (21)
1. A gas transfer segment of a pressure swing adsorption process cycle utilizing multiple parallel adsorbent beds, each bed having a feed end and a product end, wherein the gas transfer segment comprises transferring gas from a bed at a higher pressure to another bed at a lower pressure followed by withdrawing a waste depressurization gas from the feed end of the bed while transferring gas from the bed at a higher pressure to another bed a lower pressure.
2. A pressure swing adsorption process for recovering a less readily adsorbable component from a feed gas mixture comprising at least one less readily adsorbable component and at least one more readily adsorbable component, which process comprises performing cyclic process steps in a plurality of adsorbent beds, each bed having a feed end and a product end and containing adsorbent material which selectively adsorbs the more readily adsorbable component, each bed proceeding in turn through cyclic process segments which include an adsorption-make product segment, a first gas transfer segment in which gas flows from a bed initially at a higher pressure into one or more other beds initially at a lower pressure or lower pressures, a regeneration segment, a second gas transfer segment in which gas flows into a bed initially at a lower pressure from one or more other beds initially at a higher pressure or higher pressures, and a final repressurization segment, wherein the gas transfer segments include (1) transferring gas from the product end of the bed to the product end of another bed followed by (2) withdrawing waste depressurization gas from the feed end of the bed while continuing to transfer gas from the product end of the bed to the product end of another bed.
3. The process of claim 2 wherein the ratio of the volume of gas transferred from the product end of the bed during (1) to the volume of gas transferred from the product end of the bed during (2) is between about 3 and about 20.
4. The process of claim 2 wherein during (2) the ratio of the volume of waste depressurization gas withdrawn from the feed end of the bed to the volume of gas transferred from the product end of the bed is between about 0.1 and about 0.6.
5. The process of claim 2 wherein the feed gas mixture is air.
6. The process of claim 5 wherein the more readily adsorbable component is oxygen and the less readily adsorbable component is nitrogen.
7. The process of claim 6 wherein the adsorbent material comprises carbon molecular sieve which is kinetically more selective for the adsorption of oxygen than nitrogen.
8. The process of claim 2 which further comprises, during either or both of (1) and (2), transferring gas from the feed end of the bed to the feed end or ends of the one or more other beds.
9. The process of claim 8 which further comprises, prior to (1), an additional step of transferring gas from the product end of the bed at a higher pressure to the product end of another bed at a lower pressure.
10. The process of claim 8 wherein the ratio of the volume of gas transferred from the product end of the bed during (1) to the volume of gas transferred from the product end of the bed during (2) is between about 3 and about 20.
11. The process of claim 8 wherein during (2) the ratio of the volume of waste depressurization gas withdrawn from the feed end of the bed to the volume of gas transferred from the product end of the bed is between about 0.1 and about 0.6.
12. The process of claim 2 which further comprises, during either or both of (1) and (2), transferring gas from a point intermediate the feed end and the product end of the bed to the feed end or ends of the one or more other beds.
13. The process of claim 12 which further comprises, prior to (1), an additional step of transferring gas from the product end of the bed at a higher pressure to the product end of another bed at a lower pressure.
14. The process of claim 12 wherein the ratio of the volume of gas transferred from the product end of the bed during (1) to the volume of gas transferred from the product end of the bed during (2) is between about 3 and about 20.
15. The process of claim 12 wherein during (2) the ratio of the volume of waste depressurization gas withdrawn from the feed end of the bed to the volume of gas transferred from the product end of the bed is between about 0.1 and about 0.6.
16. A pressure swing adsorption process for recovering a less readily adsorbable component from a pressurized feed gas comprising at least one less readily adsorbable component and at least one more readily adsorbable component, which process comprises performing cyclic process steps in two parallel adsorbers, each adsorber having a feed end and a product end and containing adsorbent material which selectively adsorbs the more readily adsorbable component, which cyclic process steps include:
(a) providing a pressurized feed gas at superatmospheric pressure and introducing the pressurized feed gas into the feed end of a first adsorber, selectively adsorbing a portion of the more readily adsorbable component on the adsorptive material, and withdrawing from the product end of the first adsorber a product gas enriched in the less readily adsorbable component;
(b) depressurizing the first adsorber by (1) transferring gas from an outlet at the product end of the first adsorber into the product end of the second adsorber and (2) withdrawing gas through an additional outlet disposed at a distance from the product end of the first adsorber and transferring this gas into the feed end of the second adsorber;
(c) continuing to transfer gas from the outlet at the product end of the first adsorber into the product end of the second adsorber and from the additional outlet of the first adsorber into the feed end of the second adsorber while simultaneously withdrawing waste depressurization gas from the feed end of the first adsorber;
(d) terminating all transfer of gas from the first adsorber to the second adsorber while continuing to withdraw waste depressurization gas from the feed end of the first adsorber;
(e) introducing product gas into the product end of the first adsorber while continuing to withdraw waste depressurization gas from the feed end of the first adsorber;
(f) pressurizing the first adsorber by (1) transferring gas from an outlet at the product end of the second adsorber to the product end of the first adsorber and (2) withdrawing gas through an additional outlet disposed at a distance from the product end of the second adsorber and transferring this gas into the feed end of the first adsorber, wherein the second adsorber is initially at a higher pressure than the first adsorber;
(g) further pressurizing the first adsorber by transferring gas from the product end of the second adsorber to the product end of the first adsorber and from the additional outlet of the second adsorber to the feed end of the first adsorber, and withdrawing waste depressurization gas from the feed end of the second adsorber;
(h) terminating all transfer of gas from the second adsorber to the first adsorber and further pressurizing the first adsorber by one or more steps selected from the group consisting of introducing product gas into the product end thereof, introducing pressurized feed gas mixture into the feed end thereof, and introducing product gas into the product end thereof while also introducing pressurized feed gas into the feed end thereof; and
(i) repeating steps (a) through (h) in a cyclic manner.
17. The process of claim 16 wherein the additional outlet of the first adsorber in steps (b) and (c) is at the feed end of the first adsorber and the additional outlet of the second adsorber in steps (f) and (g) is at the feed end of the second adsorber.
18. The process of claim 16 wherein the additional outlet of the first adsorber in steps (b) and (c) is intermediate the feed and product ends of the first adsorber and the additional outlet of the second adsorber in steps (f) and (g) is intermediate the feed and product ends of the second adsorber.
19. The process of claim 16 which further comprises:
following step (a) and prior to step (b), transferring gas from the product end of the first adsorber into the product end of the second adsorber, wherein the second adsorber is at a lower pressure than the first adsorber; and
following step (e) and prior to step (f), further pressurizing the first adsorber by transferring gas from the product end of the second adsorber to the product end of the first adsorber, wherein the second adsorber is at a higher pressure than the first adsorber.
20. The process of claim 16 which further comprises, following step (e) and prior to step (f), terminating the withdrawal of waste depressurization gas from the feed end of the first adsorber and continuing to introduce product gas into the product end of the first adsorber.
21. The process of claim 16 which further comprises, following step (a), terminating the introducing of the pressurized feed gas into the feed end of the first adsorber while continuing withdrawing from the product end of the first adsorber a product gas enriched in the less readily adsorbable component.
Priority Applications (6)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US10/119,165 US6709486B2 (en) | 2002-04-08 | 2002-04-08 | Pressure swing adsorption process with controlled internal depressurization flow |
EP03007368A EP1352680A3 (en) | 2002-04-08 | 2003-04-01 | Pressure swing adsorption process with controlled internal depressurization flow |
CA002424559A CA2424559C (en) | 2002-04-08 | 2003-04-01 | Pressure swing adsorption process with controlled internal depressurization flow |
KR10-2003-0020679A KR100515703B1 (en) | 2002-04-08 | 2003-04-02 | Pressure swing adsorption process with controlled internal depressurization flow |
CNB03110245XA CN1306987C (en) | 2002-04-08 | 2003-04-08 | Pressure swing adsorption process with controlled internal depressurization flow |
TW092108042A TW587955B (en) | 2002-04-08 | 2003-04-08 | Pressure swing adsorption process with controlled internal depressurization flow |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US10/119,165 US6709486B2 (en) | 2002-04-08 | 2002-04-08 | Pressure swing adsorption process with controlled internal depressurization flow |
Publications (2)
Publication Number | Publication Date |
---|---|
US20030188634A1 true US20030188634A1 (en) | 2003-10-09 |
US6709486B2 US6709486B2 (en) | 2004-03-23 |
Family
ID=28453980
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US10/119,165 Expired - Lifetime US6709486B2 (en) | 2002-04-08 | 2002-04-08 | Pressure swing adsorption process with controlled internal depressurization flow |
Country Status (6)
Country | Link |
---|---|
US (1) | US6709486B2 (en) |
EP (1) | EP1352680A3 (en) |
KR (1) | KR100515703B1 (en) |
CN (1) | CN1306987C (en) |
CA (1) | CA2424559C (en) |
TW (1) | TW587955B (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2015062908A (en) * | 2014-12-26 | 2015-04-09 | クラレケミカル株式会社 | Nitrogen gas separation method and nitrogen gas separation device |
JP2016007582A (en) * | 2014-06-25 | 2016-01-18 | クラレケミカル株式会社 | Nitrogen gas separation method and nitrogen gas separation device |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2896861B1 (en) * | 2006-01-31 | 2008-07-18 | Air Liquide | METHOD FOR CONTROLLING A SET OF CRYOGENIC DISTILLATION AIR SEPARATION APPARATUS AND AIR SEPARATION APPARATUS ASSEMBLY USING THE SAME |
CN102009963B (en) * | 2010-09-30 | 2013-03-20 | 中国舰船研究设计中心 | High-purity nitrogen preparing method and device |
Family Cites Families (39)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3430418A (en) * | 1967-08-09 | 1969-03-04 | Union Carbide Corp | Selective adsorption process |
US3564816A (en) * | 1968-12-30 | 1971-02-23 | Union Carbide Corp | Selective adsorption process |
US3636679A (en) * | 1971-01-04 | 1972-01-25 | Union Carbide Corp | Selective adsorption gas separation process |
US4077780A (en) * | 1976-10-20 | 1978-03-07 | Union Carbide Corporation | Recovery of hydrogen and nitrogen from ammonia plant purge gas |
DE2652486A1 (en) * | 1976-11-18 | 1978-05-24 | Bergwerksverband Gmbh | METHOD FOR THE EXTRACTION OF NITROGEN-GASES FROM GASES CONTAINING N LOW 2 LESS THAN AT LEAST O LOW 2, E.g. AIR |
US4256469A (en) * | 1978-11-06 | 1981-03-17 | Linde Aktiengesellschaft | Repressurization technique for pressure swing adsorption |
ZA811931B (en) * | 1980-03-31 | 1982-05-26 | African Oxygen Ltd | Process and apparatus for the separation of gaseous mixture |
GB2086258A (en) * | 1980-10-30 | 1982-05-12 | Boc Ltd | Process and apparatus for separation of a gaseous mixture |
DE3132758A1 (en) * | 1981-08-19 | 1983-03-03 | Linde Ag, 6200 Wiesbaden | ABSORPTION PROCEDURE |
DE3528909A1 (en) * | 1985-08-12 | 1987-02-19 | Linde Ag | PRESSURE EXCHANGE ADDING METHOD |
US5234472A (en) * | 1987-11-16 | 1993-08-10 | The Boc Group Plc | Separation of gas mixtures including hydrogen |
EP0449448B1 (en) * | 1990-03-29 | 1997-01-22 | The Boc Group, Inc. | Process for producing oxygen enriched product stream |
US5258056A (en) * | 1991-09-27 | 1993-11-02 | The Boc Group, Inc. | PSA system with product turndown and purity control |
JP3215713B2 (en) | 1992-03-17 | 2001-10-09 | クラレケミカル株式会社 | Nitrogen gas separation method |
US5328503A (en) * | 1992-11-16 | 1994-07-12 | Air Products And Chemicals, Inc. | Adsorption process with mixed repressurization and purge/equalization |
EP0609620B1 (en) * | 1993-01-30 | 1999-02-10 | The BOC Group plc | Gas separation |
US5294247A (en) * | 1993-02-26 | 1994-03-15 | Air Products And Chemicals, Inc. | Adsorption process to recover hydrogen from low pressure feeds |
US5429666A (en) * | 1994-02-03 | 1995-07-04 | Air Products And Chemicals, Inc. | VSA adsorption process with continuous operation |
US5441558A (en) | 1994-08-09 | 1995-08-15 | Air Products And Chemicals, Inc. | High purity nitrogen PSA utilizing controlled internal flows |
US5518526A (en) * | 1994-10-07 | 1996-05-21 | Praxair Technology, Inc. | Pressure swing adsorption process |
US5520720A (en) | 1994-11-30 | 1996-05-28 | The Boc Group, Inc. | Pressure swing adsorption process |
JP3309197B2 (en) * | 1995-03-02 | 2002-07-29 | 住友精化株式会社 | Recovery method of concentrated oxygen |
US5529607A (en) * | 1995-03-15 | 1996-06-25 | The Boc Group, Inc. | PSA process with dynamic purge control |
US5565018A (en) * | 1995-07-12 | 1996-10-15 | Praxair Technology, Inc. | Optimal pressure swing adsorption refluxing |
US5656068A (en) * | 1996-02-29 | 1997-08-12 | Praxair Technology, Inc. | Large capacity vacuum pressure swing adsorption process and system |
US5733359A (en) * | 1996-06-19 | 1998-03-31 | The Boc Group, Inc. | Pressure swing adsorption process turndown control |
FR2751641B1 (en) * | 1996-07-26 | 1998-09-11 | Inst Francais Du Petrole | ISOALKANE/N-ALKANE SEPARATION PROCESS BY GAS PHASE ADSORPTION USING PRESSURE MODULATION AND FOUR ADSORBERS |
US5738709A (en) | 1996-12-20 | 1998-04-14 | Air Products And Chemicals, Inc. | Nitrogen PSA with intermediate pressure transfer |
US5735938A (en) * | 1997-01-15 | 1998-04-07 | Praxair Technology, Inc. | Method for production of nitrogen using oxygen selective adsorbents |
US5846294A (en) * | 1997-04-23 | 1998-12-08 | The Boc Group, Inc. | Pressure swing adsorption process and apparatus |
US6007606A (en) * | 1997-12-09 | 1999-12-28 | Praxair Technology, Inc. | PSA process and system |
US6048384A (en) * | 1997-12-09 | 2000-04-11 | Smolarek; James | PSA process and system using simultaneous top and bottom evacuation of absorbent bed |
US6045603A (en) * | 1998-08-21 | 2000-04-04 | The Boc Group, Inc. | Two phase pressure swing adsorption process |
US6102985A (en) * | 1998-11-25 | 2000-08-15 | Air Products And Chemicals, Inc. | Pressure swing adsorption process and system with dual product storage tanks |
US6113672A (en) * | 1999-01-21 | 2000-09-05 | The Boc Group, Inc. | Multiple equalization pressure swing adsorption process |
US6083299A (en) * | 1999-01-21 | 2000-07-04 | The Boc Group, Inc. | High pressure purge pressure swing adsorption process |
US6210466B1 (en) * | 1999-08-10 | 2001-04-03 | Uop Llc | Very large-scale pressure swing adsorption processes |
US6277174B1 (en) * | 2000-01-07 | 2001-08-21 | Praxair Technology, Inc. | Low pressure ratio VPSA plant tuning and balancing system |
US6428607B1 (en) * | 2000-06-26 | 2002-08-06 | Air Products And Chemicals, Inc. | Pressure swing adsorption process which provides product gas at decreasing bed pressure |
-
2002
- 2002-04-08 US US10/119,165 patent/US6709486B2/en not_active Expired - Lifetime
-
2003
- 2003-04-01 EP EP03007368A patent/EP1352680A3/en not_active Withdrawn
- 2003-04-01 CA CA002424559A patent/CA2424559C/en not_active Expired - Fee Related
- 2003-04-02 KR KR10-2003-0020679A patent/KR100515703B1/en not_active IP Right Cessation
- 2003-04-08 TW TW092108042A patent/TW587955B/en not_active IP Right Cessation
- 2003-04-08 CN CNB03110245XA patent/CN1306987C/en not_active Expired - Fee Related
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2016007582A (en) * | 2014-06-25 | 2016-01-18 | クラレケミカル株式会社 | Nitrogen gas separation method and nitrogen gas separation device |
JP2015062908A (en) * | 2014-12-26 | 2015-04-09 | クラレケミカル株式会社 | Nitrogen gas separation method and nitrogen gas separation device |
Also Published As
Publication number | Publication date |
---|---|
EP1352680A2 (en) | 2003-10-15 |
KR20030081043A (en) | 2003-10-17 |
TW200304849A (en) | 2003-10-16 |
CA2424559C (en) | 2006-07-04 |
CN1449859A (en) | 2003-10-22 |
CN1306987C (en) | 2007-03-28 |
US6709486B2 (en) | 2004-03-23 |
EP1352680A3 (en) | 2005-03-30 |
KR100515703B1 (en) | 2005-09-15 |
CA2424559A1 (en) | 2003-10-08 |
TW587955B (en) | 2004-05-21 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US6641645B1 (en) | Vacuum swing adsorption process with controlled waste gas withdrawal | |
KR100254295B1 (en) | Pressure swing adsorption process with a single adsorbent bed | |
EP0383312B1 (en) | Adsorption process for recovering two high purity gas products from multicomponent gas mixtures | |
EP0008512B1 (en) | Separation of multicomponent gas mixtures | |
EP0008882B1 (en) | Separation of multicomponent gas mixtures by pressure swing adsorption | |
US5122164A (en) | Process for producing oxygen enriched product stream | |
US5520720A (en) | Pressure swing adsorption process | |
US4914218A (en) | Adsorptive process for separating multicomponent gas mixtures | |
US4468238A (en) | Process for removing a nitrogen gas from mixture comprising N2 and CO or N2 ' CO2 and CO | |
US4790858A (en) | Fractionation of multicomponent gas mixtures by pressure swing adsorption | |
US3564816A (en) | Selective adsorption process | |
CA2189232C (en) | Method of recovering oxygen-rich gas | |
US4715867A (en) | Auxiliary bed pressure swing adsorption molecular sieve | |
EP1101522B1 (en) | Pressure swing adsorption process | |
EP1018359A2 (en) | Pressure swing adsorption process and system with product storage tank(s) | |
KR102481433B1 (en) | Method of Separating and Purifying Hydrogen from Gas Mixture of Ammonia Decompositions | |
EP0873776B1 (en) | Pressure swing adsorption process | |
EP1004342A2 (en) | Pressure swing adsorption gas separation process and system using single adsorber and product recycle | |
US5738709A (en) | Nitrogen PSA with intermediate pressure transfer | |
US6709486B2 (en) | Pressure swing adsorption process with controlled internal depressurization flow | |
CA2072905C (en) | Process for producing oxygen enriched product stream | |
JPH0478324B2 (en) |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
AS | Assignment |
Owner name: AIR PRODUCTS AND CHEMICALS, INC., PENNSYLVANIA Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:LEE, SANG KOOK;BUKOWSKI, JUSTIN DAVID;REEL/FRAME:012796/0088 Effective date: 20020405 |
|
STCF | Information on status: patent grant |
Free format text: PATENTED CASE |
|
FPAY | Fee payment |
Year of fee payment: 4 |
|
FPAY | Fee payment |
Year of fee payment: 8 |
|
FPAY | Fee payment |
Year of fee payment: 12 |