US20030178162A1 - Process for biological deinking of office waste paper - Google Patents
Process for biological deinking of office waste paper Download PDFInfo
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- US20030178162A1 US20030178162A1 US10/103,840 US10384002A US2003178162A1 US 20030178162 A1 US20030178162 A1 US 20030178162A1 US 10384002 A US10384002 A US 10384002A US 2003178162 A1 US2003178162 A1 US 2003178162A1
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- 239000010893 paper waste Substances 0.000 title claims abstract description 17
- 238000000034 method Methods 0.000 title claims description 43
- 241000894006 Bacteria Species 0.000 claims abstract description 24
- 229920001131 Pulp (paper) Polymers 0.000 claims description 28
- 230000001580 bacterial effect Effects 0.000 claims description 22
- 239000013535 sea water Substances 0.000 claims description 18
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 18
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- 238000005119 centrifugation Methods 0.000 claims description 4
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- 238000007865 diluting Methods 0.000 claims description 2
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- 238000005516 engineering process Methods 0.000 abstract description 18
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- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
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Images
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C5/00—Other processes for obtaining cellulose, e.g. cooking cotton linters ; Processes characterised by the choice of cellulose-containing starting materials
- D21C5/02—Working-up waste paper
- D21C5/025—De-inking
- D21C5/027—Chemicals therefor
-
- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
- C12P1/00—Preparation of compounds or compositions, not provided for in groups C12P3/00 - C12P39/00, by using microorganisms or enzymes
- C12P1/04—Preparation of compounds or compositions, not provided for in groups C12P3/00 - C12P39/00, by using microorganisms or enzymes by using bacteria
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21C—PRODUCTION OF CELLULOSE BY REMOVING NON-CELLULOSE SUBSTANCES FROM CELLULOSE-CONTAINING MATERIALS; REGENERATION OF PULPING LIQUORS; APPARATUS THEREFOR
- D21C5/00—Other processes for obtaining cellulose, e.g. cooking cotton linters ; Processes characterised by the choice of cellulose-containing starting materials
- D21C5/005—Treatment of cellulose-containing material with microorganisms or enzymes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/64—Paper recycling
Abstract
Description
- The present invention relates to decolorization of office waste paper using microorganisms from marine habitats. More particularly, the present invention relates to a process for biological deinking of photocopied and inkjet-printed paper or toner photocopied paper pulp using a gram-negative coccoid bacterium deposited at National Institute of Oceanography, Dona Paula, Goa 403 043, India having accession No. NIO/DI/32 and being deposited at an international depository ______ having accession number ______ and also deposited at Microbial Technology, Chandigarh, India having accession No. ______.
- Paper manufacturing is a major industry and a continuously growing one. Increased production of paper imposes a severe demand on plant raw material and thus harms the environment. Recycling of used paper is an alternative that can alleviate the stress that is exercised on the environment. The three major sources of raw material for such recycling are newsprint, photocopied paper and inkjet—printed papers. Recycling of paper requires the removal of the printing ink from the used paper, called deinking, so that the processed material is brighter. Printing on paper is accomplished by using two types of inks, the impact and the non-impact inks. In impact inks, used for newsprints, the ink does not fuse with the paper and is, therefore, easy to remove or disperse during the deinking, or recycling process. Such recycling is now well known and has been carried out for years. On the contrary, non-impact inks used in photocopying, ink-jet printing and laser printing results in the ink fusing with the paper and makes it non-dispersible, thus rendering the deinking process much more difficult (Jeffries, 2002). The toners used for photocopying generally contain iron oxide (about 55%), olefins (about 5%) and plastic or polymer (Website:http://www.eng-tips.com).
- Various hydrolytic enzymes such as cellulase, lipase, amylase of bacterial or fungal origin, individually or in combination have been used for deinking of office waste paper.
- (i) A reference may be made to a publication wherein, a method for deinking of xerographic and printed paper, collectively called office waste, includes applying deinking solution to the paper to be deinked, the deinking solution being composed of a cleaning solution and a surfactant, abrading the paper to remove the ink from paper, and washing the paper to remove the deinking solution from the paper (U.S. Pat. No. 6,022,423 Bhatia, S. 1996 Method for deinking paper dtd 2000-02-08). However, this patent involves using a special device for deinking of whole sheets and cannot be used on pulp.
- (ii) Another reference may be made to wherein, a monocomponent cellulase is used for removal of ink and toners from printed paper (U.S. Pat. No. 5,525,193 Neal, E., Steven, B. E., Hans, H. C. 1994. Use of monocomponent cellulase for removing inks, coatings and toners from printed paper). The technique of isolating monocomponent cellulase from microorganisms by various purifications, chromatographic steps is time consuming and expensive.
- (iii) A reference may be made to a publication wherein, endogluconases and hemicellulases from several fungi are used effectively for deinking of xerox and laser-printed paper (Gubitz, G. M., Mansfield, S. D., Bohm, D. Saddler, J. N. 1998. Effect of endoglucanases and hemicellulases in magnetic and flotation deinking of xerographic and laser-printed papers. Journal of Biotechnology. 65:209-215). As mentioned above the enzyme technology is still an expensive one for using on a large scale.
- (iv) A reference may be made to a publication, wherein deinking of laser printed or xerographic paper is done using enzyme containing a resistant binder. Enzyme is added in the specified form to improve speck removal (Landley, J. G. Stockwell, J. O. 1997. Enzyme deinking of paper. Patent Number. GB 2304741 dated 26.03.97). As with the above references, the technology to produce enzymes, their purification and application is an expensive process.
- (v) A reference may be made to a publication, wherein deinking of office waste paper is carried out by contacting the pulp with a deinking agent containing enzymes cellulase, preferably active at
pH 4 to 8. The treated paper is used in the production of newsprint and high quality paper (Jobbins, J. M. Asbrand, Jr. G. R. 1996. Composition and process for deinking office waste paper. Patent number: EP 717144 dated 19.06.96). As with the above references, the technology to produce enzymes, their purification and application is an expensive process. - (vi) A reference may be made to a publication, wherein deinking of waste paper is achieved by incubating the paper pulp with cellulase at 40° C. for 1 hour under pressure. Following dissociation of ink particles, the resulting washed pulp is brighter (Mitsubishi Heavy Industries. 1994. Deinking of waste paper. Patent number: JP06346390 dated 20.12.94). As with the above references, the technology to produce enzymes, their purification and application is an expensive process.
- (vii) A reference may be made to a publication, wherein deinking is achieved by using lipase to remove ink from used paper. The procedure is carried out under neutral or alkaline conditions which produces regenerated pulp having enhanced brightness (Novo. 1990. Removing ink from used paper. Patent number: JP2160984 dated 20.06.90).
- (viii) A reference may be made to a publication, wherein deinking of waste paper is done by using the yeastHansenula polymorpha, which degrades the ink-based resin (Jeonju-Paper. 1993. Waste-paper deinking. Patent number: KR 9303705 dated 08.05.93). However, the ink floats on the surface and the pulp has to be extensively washed to remove the detached ink.
- (ix) A reference may be made to a publication, wherein decolorization of Indian ink is achieved by using thermostable alkaline cellulase from a Bacillus sp (Kao. 1998. A microbiologically produced thermostable alkaline cellulase and a process for its preparation. Patent number: JP 10313859)
- The main object of the present invention is to provide a process for decolorization of waste paper.
- Another object of the present invention is to provide a process for biological deinking of photocopied and inkjet-printed paper pulp using a gram-negative coccoid bacterium deposited at National Institute of Oceanography, Dona Paula, Goa 403 043, India having accession No. NIO/DI/32 and being deposited at an international depository ______ having accession number ______ and also deposited at Microbial Technology, Chandigarh, India having accession No. ______.
- The present invention provides a process for decolorization of paper pulp and more particularly, the present invention relates to a process for biological deinking of photocopied and inkjet-printed paper pulp using a gram negative coccoid bacteria deposited at National Institute of Oceanography, Dona Paula, Goa 403 043, India having accession No. NIO/DI/32 and being deposited at an international depository ______ having accession number ______ and also deposited at Microbial Technology, Chandigarh, India having accession No. ______.
- Accordingly, the present invention provides a process for biological deinking of office waste paper inclusive of xerographic and inkjet-printed paper printed with non-impact and non-dispersible ink, said process comprises:
- (a) growing coccoid bacterial isolate deposited at National Institute of Oceanography, Dona Paula, Goa 403 043, India having accession No. NIO/DI/32 and being deposited at an international depository ______having accession number ______ and also deposited at Microbial Technology, Chandigarh, India having accession No. ______, in a nutrient broth containing beef extract, peptic digest of animal tissue and salinity ranging between 30 to 35 parts per thousand for at least 4 days;
- (b) adding the resulting biomass of step (a) at 20% concentration to inoculate paper pulp diluted to at least 6% consistency suspended in sea water with salinity diluted to 50%;
- (c) incubating the inoculated pulp for a minimum period of 96 hours followed by diluting the pulp tenfold;
- (d) adding 1% by wt. of a surfactant and aerating for at least 10 minutes with compressed air to let the stray residual ink particles and contaminants flow out of the container, and
- (e) filtering the pulp of step (d) over a funnel under suction, to get a sheet of pulp with uniform thickness and reading the brightness by radiance measurement.
- In an embodiment of the present invention, wherein in step (a), the bacterium is grown for a minimum of 4 days in nutrient broth containing beef extract and peptic digest of animal tissue in sea water with salinity diluted to 50%.
- In another embodiment of the present invention, wherein in step (b), the resulting bacterial biomass is concentrated by centrifugation and diluted to get final optical density of 1.0 measured at 660 nm in a spectrophotometer.
- In yet another embodiment of the present invention, the diluted bacterial culture is inoculated to at least 6% pulp suspended in seawater with salinity diluted to 50% and incubated for a minimum period of 4 days within to completely beach the pulp.
- In still another embodiment of the present invention, the resulting bleached pulp is diluted tenfold, to which 1% surfactant is added, aerated using compressed air, and any free residual ink particles and contaminants are allowed to flow out of the solution.
- In a further embodiment of the present invention, wherein after step (d) the xerographic or inkjet-printed paper is soaked in hot water for 1-2 hours and macerated after adding 1% surfactant to pulp.
- In one more embodiment of the present invention, the paper is macerated using conventional mixers.
- In one another embodiment of the present invention, wherein in step (e), the washed pulp is filtered over a Buchner funnel under suction to get a pulp sheet of uniform thickness.
- In an embodiment of the present invention, the pulp sheet is pressed at 60° C. for a minimum of 4-5 hours to make it uniform and dried.
- In another embodiment of the present invention, the radiance of the resultant sheet is read from 412 to 684 nm and the radiance expressed as Lux units (LU) {wherein one LU is equivalent to μW/cm2/nm/Sr}.
- In still another embodiment of the present invention, the pulp sheet made out of recycled paper is used as a reference.
- In yet another embodiment of the present invention, wherein in steps (a) and (b), pure water containing 1.5% by wt of sodium chloride can be used in the place of sea water.
- Deinking of paper is a limiting factor in recycling of paper. Newsprint and office waste paper is generally deinked using chemicals which go into the effluent and cause pollution of the water bodies. The newsprint or offset printing is done using dispersible or non-impact ink whereas laser, xerographic and ink-jet printer ink does not disperse and is also called impact ink. There are several patents describing various methods of deinking by using hydrolytic enzymes such as cellulase, hemicellulase and lipase of microbial origin which release toner particles from fibers. However, enzyme action is affected by the paper constituents in the deinking condition. The chemically pulped fibers are more susceptible than mechanically pulped fibers. Office waste paper is high in laser and toner content and the technology for taking the toner particles out is not very good at the moment (Jefferies, 2002).
- In the present invention, the Applicants report a process for deinking of office waste paper comprising xerographic and ink-jet printed paper by a bacterium isolated from marine sediment of an estuary in Goa, India. The salinity of the water at the time of isolation was around 15 parts per thousand which is equivalent to half-strength sea water.
- The present invention provides a process for biological deinking of office waste paper comprising xerographed, ink-jet printed, and similar other non-impact ink printed papers. The process is achieved by using a coccoid bacterium deposited National Institute of Oceanography, Dona Paula, Goa 403 043, India having accession No. NIO/DI/32 and being deposited at an international depository ______ having accession number ______ and also deposited at Microbial Technology, Chandigarh, India having accession No. ______, said culture may be grown in nutrient broth containing beef extract, and peptic digest of animal tissue and prepared with sea water with its salinity diluted to 50%.
- The present invention more particularly provides a process wherein the aforesaid pre-grown bacterial culture is inoculated onto the office pulp suspended in seawater with its salinity diluted to 50% and incubated for a minimum period of 4 days to decolorize the paper pulp.
- The paper pulp becomes brighter, the black ink is totally decolorized and the supernatant water remains clear. The water needs to be simply drained to recover the deinked pulp. The pulp can be diluted tenfold Optionally to remove any free residual ink particles and other contaminants. Conventional surfactant at 1% concentration may be added to the diluted paper pulp, aerated for at least 10 minutes by which the particles float and go out of the pulp slurry. The washed pulp can be filtered over a large funnel under suction and dried at 60° C. for at least 6 hours to obtain decolorized paper pulp.
- The organism given in the present invention is a gram-negative, coccoid bacterium isolated from coastal marine sediment. The coccoid bacterium has been deposited at National Institute of Oceanography, Dona Paula, Goa 403 043, India having accession No. NIO/DI/32 and being deposited at an international depository ______ having accession number ______ and also deposited at Microbial Technology, Chandigarh, India having accession No. ______. Said bacterium can be grown in nutrient broth containing beef extract, peptic digest of animal tissue, prepared with sea water with salinity diluted to 50% and having a pH of at least 7.5. The bacterium when grown in nutrient agar medium appears as circular colonies off-white in colour, having 2 mm diameter colonies in the beginning and growing to a size of 5 mm within 3-4 days. The bacterium is capable of producing lipase and amylase in the presence of Tween 80 and starch respectively. It is fermentative and catalase-negative bacterium. The bacterium is grown at room temperature (30° C.) for about 4 days, the bacterial cells are collected by centrifugation under sterile conditions, diluted appropriately to get optical density of 1 at 660 nm. Xerographic, ink-jet printed paper and other papers having printed with impact ink are pulped by soaking in hot water for a minimum of 2 hrs, macerated in a domestic mixer with surfactant such as Tween 80. An example for the process for deinking involves suspending such a pulp at least at 6% consistency in seawater with salinity diluted to 50%, inoculating with 20% bacterial suspension prepared as described above and incubating at room temperature for a minimum of 4 days to get completely decolorized pulp and the ink is disappeared from water also. The pulp can be diluted, aerated from bottom to remove free contaminating particles, salts and bacterial cells. A surfactant such as Tween 80 can be added at 1% concentration for flotation of any residual ink particles. The pulp is filtered over a Buchner funnel under suction, pressed with flat stainless steel plates to make the pulp sheet uniform in thickness. The radiance of the resultant sheet is read from 412 to 684 nm and the radiance expressed in Lux units (Lu). One LU is equivalent to μW/cm2/nm/Sr. The ratio of radiance between recycled paper purchased from the market and biologically deinked paper is taken as a measure of brightness.
- In a typical example plain toner powder of xerox machine suspended in seawater with its salinity diluted to 50% also became completely colorless within 7 days after inoculating it with the said bacterial suspension.
- Most of the organisms used for biological deinking release ink particles from the fibers and they need to be subsequently washed off from the pulp. In the process described in the present invention, this problem does not arise as the ink and toner particles are totally decolorized. The method is very cost effective as the only step involved is raising the bacterial inoculum in any conventional nutrient broth containing assimilable carbon and nitrogen source. A comparative statement given in Table 1 explains the novelty of our invention in comparison with prior art known in this field.
TABLE 1 Comparative statement Type of Reference paper or Source of (Prior art) ink deinking agent Remarks Patent Impact Chemical & a surfactant, Not US6022423 ink and abrading the practical on office paper and washing a large waste the deinked paper scale using a special device to put whole sheet US5525193 Toner, Monocomponent cellulase Enzyme impact purified from technology is ink cellulolytic enzymes expensive from of various mixed microorganisms office or genetically waste engineered orgainsm which produces only monocomponent cellulase Gubitz et al. Xerox and Endogluconases and Enzyme 1998 laser- hemicellulases technology is printed from fungi expensive. paper GB2304741 Laser- Enzyme containing Purification printed or a resistant and xerographic binder application paper of enzyme technology is still expensive Patent Office Cellulase Expensive EP 717144 waste enzyme paper technology JP06346390 Office Contacting with Enzyme high waste cellulase at temperature paper 40° C. 1 h and pressure under pressure will make the cost of technology not very practical. JP2160984 Office Contacting Adjustment of waste pulp with pH and enzyme paper lipase technology enzyme under will not neutral or make it very alkaline practical. conditions KR9303705 Office Contacting The ink floats waste pulp with the on the surface paper culture of the and the pulp yeast Hansenula has to be polymorpha extensively which degrades washed the ink- based resin. JP10313859 For Thermostable Recommen-ded decolor- alkaline for surfactant ization on cellulase composition, as of Indian from a a fiber treat- ink bacterium ment agent and as an Indian ink decolor- ization agent. Our For Xerox Direct contact No enzyme, no invention and inkjet- of pulp temp-erature or printed slurry with pH adjustment, paper pulp the bacterium the pulp and NIO/DI/32 the water are for 72 h to clear and get complete washing is decolorization only optional. of the pulp and clear water - In the drawings accompanying the specification,
- FIG. 1 shows the radiance of Xerox paper pulp (XP) is lowest in comparison with that of recycled paper pulp (RP) and biologically deinked pulp (BP);
- FIG. 2 shows the ratio of radiance of biologically deinked paper to that of recycled paper;
- FIG. 3 compares the deinking done by the present invention on papers of three different photocopier machines;
- FIG. 4 compares the radiance of decolorized paper pulp after 4 days at different concentration of inoculum;
- FIG. 5 compares the reflectance ratio of the deinked paper pulp by at different concentrations of inoculum;
- FIG. 6 compares the radiance ratio of the deinked paper pulp with the number of days;
- FIG. 7 shows the ratio of radiance between recycled paper and deinked paper;
- FIG. 8 shows that with an inoculam concentration of 2 ml, maximum brightness is achieved after 72 hours and
- FIG. 9 shows that with an inoculum concentration of 10 ml, maximum brightness is achieved by 72 hours.
- The present invention is further described with reference to the accompanying examples, which are given by way of illustration and therefore, should not be construed to limit the scope of the present invention in any manner.
- The bacterial isolate NIO/DI/32 was isolated from the coastal esturine sediment, Dona Paula, Goa, India in nutrient agar medium containing beef extract and peptic digest of animal tissue and agar in sea water with its salinity diluted to 50%. The culture was maintained in the slants of nutrient agar medium for all further experiments.
- The said bacterium can be grown in nutrient broth containing beef extract, peptic digest of animal tissue in sea water with its salinity diluted to 50%. The bacterium is grown at room temperature (30° C.) for about 4 days, the bacterial cells are collected by centrifugation under sterile conditions, diluted appropriately to get optical density of 1 at 660 nm using a spectrophotometer. Xerographic paper printed with impact ink from HP machine are pulped by soaking in hot water for a minimum of 2 hrs, macerated in a conventional domestic mixer with surfactant such as Tween 80. An example for the process for deinking involves suspending such a pulp at least at 6% consistency (6 g wet pulp in 100 ml of water) in sea water with its salinity diluted to 50%, inoculating with 20% bacterial suspension prepared as described above and incubating at room temperature for a minimum of 4 days to get completely bleached pulp with the ink totally disappearing from the supernatant water. The pulp can be diluted, aerated from bottom to remove free contaminating particles, salts and bacterial cells. A surfactant such as Tween 80 can be added at 1% concentration for flotation of any residual ink particles. The pulp is filtered over a Buchner funnel under suction, pressed with flat stainless steel plates to make the pulp sheet uniform in thickness. The radiance of the resultant sheet is read from 412 to 684 nm and the radiance expressed in Lux units (Lu). One LU is equivalent to μW/cm2/nm/Sr. The ratio of radiance between recycled paper available in any stationery shop and biologically deinked paper is taken as a measure of brightness.
- Accordingly, FIG. 1 shows the radiance of Xerox paper pulp (XP) is lowest in comparison with that of recycled paper pulp (RP) and biologically deinked pulp (BP). This brightness was achieved 4 days after inoculation with the said bacterium. As the target was to achieve brightness of recycled paper, the Applicants have shown the same data as ratio of radiance of Xerox paper to recycled paper and similarly, the ratio of radiance of biologically deinked paper to that of recycled paper is shown in FIG. 2.
- Xerographic printed paper obtained from various Xerox machines were compared for their efficiency in being deinked by the said bacterium. Accordingly FIG. 3 shows that out of 3 different machines, Xerox paper obtained from Lanier machine were deinked effectively by the process described in the present invention.
- As seen in the previous example, the bacterium could grow in the plain paper pulp suspended in water, and bleach the pulp in 4 days, the Xerox toner (HP make) at 1% concentration was suspended in sterile sea water and inoculated with the said bacterial suspension and incubated at room temperature for 15 days. The control flask did not receive any bacterial inoculum. The contents of experimental flask and the control flask were filtered over pre-weighed filter paper, rinsed with sterile distilled water to remove salts and dried to a constant weight at 60° C. The difference in weight of residual toner powder was compared in the two sets.
- Accordingly, in the experimental flask after 15 days the dry weight was 143 mg whereas, in the control flask it was 220 mg. Thus, almost 65% toner was degraded in the inoculated flasks. Besides, the water in the experimental flask became almost colorless.
- The ability of the bacterial isolate having accession number NIO/DI/32 (also being deposited at an international depository) to deink ink-jet printed paper was tried as follows:
- The inkjet printed-paper was prepared into pulp as described in Example 1 and inoculated with the said bacterium as described in Example 1. However, the inoculum dose varied from 2 ml to 10 ml with the increment of 2 ml. The other procedures used were the same as described n the Example 1.
- Accordingly, FIG. 4 shows radiance of decolorized paper pulp after 4 days in comparison with Xerox and recycled paper. The radiance of biologically deinked paper was more than the recycled paper and there was not much difference between inoculum concentration of 6 to 10 ml in the final radiance achieved.
- FIG. 5 shows the ratio of reflectance between Xerox paper to recycled paper in comparison with paper pulp deinked using different concentrations of the said bacterial suspension. The brightness achieved by using 8 ml or 10 ml inoculum was almost similar.
- The deinking of inkjet-printed paper in relation to time of incubation (in days) was carried out as follows:
- The preparation of pulp, inoculum and experimental set up were same as in the previous example, but the inoculum concentration used here was 10 ml and radiance of the pulp was tested on
day - Accordingly, FIG. 6 shows that by
day 6 maximum brightness is achieved and here also the radiance of biologically deinked pulp was slightly greater than that of recycled paper purchased from the market. The control was the inkjet printed paper pulp. - FIG. 7 shows the ratio of radiance between recycled paper and deinked paper. The control was the ink-jet printed paper pulp which showed lowest radiance ratio.
- Ability of the said bacterium to deink the inkjet—printed paper with two concentrations of the inoculum at varying incubation period was compared to arrive at a combination where deinking is achieved in a shortest time.
- Accordingly FIG. 8 shows that with an inoculam concentration of 2 ml, maximum brightness is achieved after 72 hours.
- FIG. 9 also shows that with an inoculum concentration of 10 ml, maximum brightness is achieved by 72 hours.
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US10/103,840 US20030178162A1 (en) | 2002-03-25 | 2002-03-25 | Process for biological deinking of office waste paper |
US11/301,207 US7645358B2 (en) | 2002-03-25 | 2005-12-12 | Process for biological deinking of office waste paper |
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US10/103,840 US20030178162A1 (en) | 2002-03-25 | 2002-03-25 | Process for biological deinking of office waste paper |
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20060260772A1 (en) * | 2002-03-25 | 2006-11-23 | Chandralatha Raghukumar | Process for biological deinking of office waste paper |
WO2007017889A1 (en) * | 2005-08-05 | 2007-02-15 | Council Of Scientific & Industrial Research | A process for enzymatic deinking of printed papers |
WO2008011325A2 (en) * | 2006-07-21 | 2008-01-24 | Sonoco Development, Inc. | Infrared-absorbing ticket stock and method of making same |
WO2011030003A1 (en) * | 2009-09-11 | 2011-03-17 | Upm-Kymmene Corporation | Method of deinking inkjet ink-containing suspensions |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5525193A (en) * | 1994-10-26 | 1996-06-11 | Novo Nordisk A/S | Use of monocomponent cellulase for removing inks, coatings, and toners from printed paper |
US6022423A (en) * | 1996-05-23 | 2000-02-08 | Imagex Technologies, Inc. | Method for deinking paper |
-
2002
- 2002-03-25 US US10/103,840 patent/US20030178162A1/en not_active Abandoned
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5525193A (en) * | 1994-10-26 | 1996-06-11 | Novo Nordisk A/S | Use of monocomponent cellulase for removing inks, coatings, and toners from printed paper |
US6022423A (en) * | 1996-05-23 | 2000-02-08 | Imagex Technologies, Inc. | Method for deinking paper |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20060260772A1 (en) * | 2002-03-25 | 2006-11-23 | Chandralatha Raghukumar | Process for biological deinking of office waste paper |
US7645358B2 (en) * | 2002-03-25 | 2010-01-12 | Council Of Scientific And Industrial Research | Process for biological deinking of office waste paper |
WO2007017889A1 (en) * | 2005-08-05 | 2007-02-15 | Council Of Scientific & Industrial Research | A process for enzymatic deinking of printed papers |
WO2008011325A2 (en) * | 2006-07-21 | 2008-01-24 | Sonoco Development, Inc. | Infrared-absorbing ticket stock and method of making same |
WO2008011325A3 (en) * | 2006-07-21 | 2008-07-03 | Sonoco Dev Inc | Infrared-absorbing ticket stock and method of making same |
WO2011030003A1 (en) * | 2009-09-11 | 2011-03-17 | Upm-Kymmene Corporation | Method of deinking inkjet ink-containing suspensions |
CN102498182A (en) * | 2009-09-11 | 2012-06-13 | 芬欧汇川集团公司 | Method of deinking inkjet ink-containing suspensions |
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