US20030082978A1 - Dry wipe - Google Patents

Dry wipe Download PDF

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Publication number
US20030082978A1
US20030082978A1 US10/142,533 US14253302A US2003082978A1 US 20030082978 A1 US20030082978 A1 US 20030082978A1 US 14253302 A US14253302 A US 14253302A US 2003082978 A1 US2003082978 A1 US 2003082978A1
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US
United States
Prior art keywords
batt
fabric
bulky
thickness
fibrous fabric
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
US10/142,533
Inventor
Hyun Lim
Robert Marin
Jeffrey Petroff
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
EIDP Inc
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to US10/142,533 priority Critical patent/US20030082978A1/en
Priority to PCT/US2002/015235 priority patent/WO2002095110A1/en
Priority to JP2002591568A priority patent/JP2004532366A/en
Priority to CNA028101820A priority patent/CN1509356A/en
Priority to EP02771837A priority patent/EP1397543A1/en
Assigned to E. I. DU PONT DE NEMOURS AND COMPANY reassignment E. I. DU PONT DE NEMOURS AND COMPANY ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: LIM, HYUN SUNG, MARIN, ROBERT ANTHONY, PETROFF, JEFFREY J.
Assigned to E. I. DU PONT DE NEMOURS AND COMPANY reassignment E. I. DU PONT DE NEMOURS AND COMPANY ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: LIM, HYUN SUNG, MARIN, ROBERT ANTHONY, PETROFF, JEFFREY J.
Publication of US20030082978A1 publication Critical patent/US20030082978A1/en
Abandoned legal-status Critical Current

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Classifications

    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01DMECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00Formation of filaments, threads, or the like
    • D01D5/11Flash-spinning
    • AHUMAN NECESSITIES
    • A47FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
    • A47LDOMESTIC WASHING OR CLEANING; SUCTION CLEANERS IN GENERAL
    • A47L13/00Implements for cleaning floors, carpets, furniture, walls, or wall coverings
    • A47L13/10Scrubbing; Scouring; Cleaning; Polishing
    • A47L13/16Cloths; Pads; Sponges
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/44Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling
    • D04H1/46Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling by needling or like operations to cause entanglement of fibres
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/40Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
    • D04H1/44Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling
    • D04H1/46Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling by needling or like operations to cause entanglement of fibres
    • D04H1/492Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling by needling or like operations to cause entanglement of fibres by fluid jet
    • D04H1/495Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties the fleeces or layers being consolidated by mechanical means, e.g. by rolling by needling or like operations to cause entanglement of fibres by fluid jet for formation of patterns, e.g. drilling or rearrangement
    • DTEXTILES; PAPER
    • D04BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
    • D04HMAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
    • D04H1/00Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
    • D04H1/70Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres characterised by the method of forming fleeces or layers, e.g. reorientation of fibres
    • D04H1/72Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres characterised by the method of forming fleeces or layers, e.g. reorientation of fibres the fibres being randomly arranged
    • D04H1/724Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres characterised by the method of forming fleeces or layers, e.g. reorientation of fibres the fibres being randomly arranged forming webs during fibre formation, e.g. flash-spinning
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/60Nonwoven fabric [i.e., nonwoven strand or fiber material]
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/60Nonwoven fabric [i.e., nonwoven strand or fiber material]
    • Y10T442/608Including strand or fiber material which is of specific structural definition
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/60Nonwoven fabric [i.e., nonwoven strand or fiber material]
    • Y10T442/608Including strand or fiber material which is of specific structural definition
    • Y10T442/609Cross-sectional configuration of strand or fiber material is specified
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/60Nonwoven fabric [i.e., nonwoven strand or fiber material]
    • Y10T442/608Including strand or fiber material which is of specific structural definition
    • Y10T442/609Cross-sectional configuration of strand or fiber material is specified
    • Y10T442/611Cross-sectional configuration of strand or fiber material is other than circular
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/60Nonwoven fabric [i.e., nonwoven strand or fiber material]
    • Y10T442/682Needled nonwoven fabric
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/60Nonwoven fabric [i.e., nonwoven strand or fiber material]
    • Y10T442/689Hydroentangled nonwoven fabric

Definitions

  • the invention relates to a needled fibrous batt made from fibers having a ribbon-shaped cross-section.
  • Nonwoven dry wipes containing spunlaced layers of polyester web and scrim are commercially available.
  • dry wipes are Swiffer®, available from The Procter & Gamble Company, Cincinnati, Ohio, and Grab-It®), available from S. C. Johnson & Son, Inc., Racine, Wis., which are generally made by needling round polyester staple fibers into a scrim.
  • These wipes are electrostatically charged to attract dirt and dust, and the three-dimensional structure of the webs used is open so that dirt particles are trapped by the wipes.
  • Another example of a dry dust wipe is Scotch-Brite®, available from Minnesota Mining and Manufacturing Company, St. Paul, Minn., made from spunlaced webs of polyester staple fibers having longitudinal grooves therein.
  • U.S. Pat. No. 5,290,628 discloses a process for hydraulically needling a web of staple fibers into an unbonded flash spun web made of continuous plexifilaments to form a spunlaced nonwoven fabric.
  • the flash spun web may optionally be bonded to increase the level of permeability of the nonwoven fabric.
  • Disclosed as end uses for the nonwoven fabric are filtration applications, and bulky, downproof and featherproof barrier liners for garments, sleeping bags, pillows, comforters and the like.
  • U.S. Pat. No. 4,704,321 discloses a nonwoven fabric, useful as a wipe-cloth, comprising a layer of nonbonded, polyethylene plexifilamentary film-fibril strands, the layer being stitched through with thread that forms spaced apart rows of stitches extending along the length of the fabric.
  • Zafiroglu found that standard thermally bonded plexifilamentary sheets were not functional for wiping cloths because after thermal bonding to generate structural integrity the dust retention was inadequate, and the non thermally bonded, cold consolidated sheet lacked sufficient surface stability for a wiping cloth.
  • Japanese patent application Hei 4-196066 assigned to Japan Vilene Co. Ltd., discloses a nonwoven fabric cleaning wipe having superior dust attracting ability, and a process for making such a wipe.
  • the invention provides a bulky fibrous fabric comprising a batt of fibers each fiber having a ribbon-shaped cross-section, the batt having a surface area of at least 2 m 2 /g and a thickness/basis weight ratio of at least 0.005 mm/g/m 2 .
  • a bulky fibrous fabric is provided by a process comprising:
  • a batt of fibers each individual fiber having a ribbon-shaped cross-section
  • ribbon-shaped is meant that the average aspect ratio of the individual fiber cross-section is between 1.4 and 6.8.
  • the batt of fibers may be obtained by a variety of known methods. One known method is for different cross-sectional shaped melt-spun fibers, such as star-shaped fibers, to be spunlaced and subsequently broken into smaller ribbon-shaped fibers.
  • the batt consists of overlapping continuous plexifilamentary film-fibril strands, formed by flash-spinning techniques generally described in U.S. Pat. No. 3,851,023 (Brethauer et al.), herein incorporated by reference.
  • the film-fibrils are very thin ribbon-like fibrous elements, which are generally less than 20 microns thick.
  • the cross-section of each fiber in a plexifilamentary strand is generally ribbon-shaped.
  • the flash-spun batt is formed from polyolefin polymer, and more preferably, high density polyethylene polymer.
  • the spin agent with which the polymer is mixed is preferably a blend of pentane and cyclopentane.
  • the spin agent may also be a refrigerant such as Freon@, available from E. I. du Pont de Nemours and Company, Inc., Wilmington, Del.
  • the percentage of polymer in the polymer-spin agent mixture is preferably between 15 and 25%, most preferably 17%.
  • the temperature of the polymer and spin agent mixture just prior to being emitted through the spin orifice should be maintained at between 185 and 200 degrees C., most preferably 190 degrees C.
  • the plexifilamentary film-fibril strands are electrostatically charged in order to pin them to the moving belt on which they are collected as they are spun.
  • the electrostatic charge imparted is high enough to overcome the vapor blast or high turbulence that may exist in the web forming chamber.
  • consolidated is meant that the as-formed batt has been lightly compressed by a nip roll so that it may be handled as a sheet.
  • unbonded is meant that the batt has not been further bonded by chemical or thermal means, such as by compaction by heated rolls or plates, so that the batt has not become a coherent sheet.
  • the individual plexifilamentary webs which overlap one another to make up the unbonded, consolidated batt are held together in such a way that the batt may be handled as a sheet but the individual webs may be easily pulled away from the surface of the batt.
  • the batt is needled in order to form the bulky fibrous fabric of the invention.
  • the needling may take the form of hydroentangling, such as described in U.S. Pat. No. 3,485,706.
  • the hydroentangling is carried out by subjecting the batt to high pressure liquid streams of at least 200 psig while supported by an apertured member, such as perforated plate or woven wire screen.
  • the number of jets, jet type, jet pressure and apertured member can be varied to achieve various fabric strength, surface stability and thickness.
  • the needling is carried out by needlepunching in a needle machine to obtain the fabric of the invention having a thickness of at least 0.20 millimeters, a basis weight of between 37 and 78 g/m 2 , and a thickness/basis weight ratio of at least 0.005 mm/g/m 2 (7 mil/oz/yd 2 ).
  • the needle density, or “punch density,” is between 60 and 500/cm 2 , preferably between 200 and 300/cm 2 , on each side of the batt.
  • the needle penetration is between 5 and 10 mm on each surface of the batt, preferably about 5 mm.
  • the needle pattern is random such that the needle punches are approximately evenly spaced across both surfaces of the batt.
  • the bulky fibrous fabric of the invention is obtained by simply needling an unbonded, consolidated batt of fibers, the bulky fibrous fabric may be manufactured more economically than existing dry dust wipes made by needling staple fibers into a scrim.
  • Basis Weight was determined by ASTM D-3776, which is hereby incorporated by reference, and is reported in g/m 2 .
  • Tensile Strength was determined by ASTM D 5035-95, which is hereby incorporated by reference, with the following modifications. In the test a 2.54 cm by 20.32 cm (1 inch by 8 inch) sample was clamped at opposite ends of the sample. The clamps were attached 12.7 cm (5 inches) from each other on the sample. The sample was pulled steadily at a speed of 5.08 cm/min (2 inches/min) until the sample broke. The force at break was recorded in pounds/inch and converted to Newtons/cm as the breaking tensile strength.
  • Thickness was determined by ASTM D177-64, which is hereby incorporated by reference, and is reported in millimeters.
  • Elongation to Break of a sheet is a measure of the amount a sheet stretches prior to breaking in a strip tensile test.
  • a 2.54 cm (1 inch) wide sample is mounted in the clamps, set 12.7 cm (5 inches) apart, of a constant rate of extension tensile testing machine such as an Instron table model tester.
  • a continuously increasing load is applied to the sample at a crosshead speed of 5.08 cm/min (2 inches/min) until failure. The measurement is given in percentage of stretch prior to failure.
  • the test generally follows ASTM D 5035-95.
  • Density was calculated from measured basis weight divided by measured thickness and is reported in gram/cm 3 .
  • Void Fraction was calculated as (1-calculated density/0.95) ⁇ 100 and is reported in %.
  • Wiping Performance Test is a measure of a material's cleaning performance as a dust mop.
  • three test environments were used, referred to as Home, Light Industrial and Heavy Industrial.
  • the Home environment was the floor of an office area which was cleaned daily.
  • the Light Industrial environment was a busy hallway in a manufacturing area which had more traffic than the Home environment and was not cleaned daily.
  • the Heavy Industrial environment had forklift truck traffic and was never cleaned.
  • the materials to be tested were cut into samples measuring approximately 5 inches by 11 inches. Each sample was weighed and the weight recorded. Two samples to be compared were secured to the bottom surface of a dry mop with a flat, smooth rubber bottom surface. The mopping surface of the mop was approximately 10 inches by 3 inches.
  • the mop was pushed over a fifty foot section of the floor.
  • the samples were then removed from the mop and folded in such a way that the dust collected by each sample was held within that sample.
  • Each sample was reweighed to determine the amount of dust collected by that sample.
  • the percent performance was determined by dividing the dust collected by the dust collected by the incumbent, or comparison sample, and multiplying by 100%. This means that the incumbent will always have 100% performance, while the invention example will have a percent relative to the incumbent. Values less than 100% indicate inferior performance, while values greater than 100% indicate superior performance. Seven to ten sample pairs were run for each environment and the result is the average.
  • Fiber Surface Stability Test is a measure of how cohesive a surface is when exposed to a destructive external force.
  • the samples were exposed to standard Scotch transparent tape, available from 3M, St. Paul, Minn. Four measurements were taken on one surface of the sample and four on the other. Eight (8) seven-inch pieces of tape were cut and weighed, and the initial weight recorded. Each piece of tape was applied to the surface to be tested and rubbed evenly to insure contact between the tape and the sample surface. The tape is then pulled away from the sample, then reapplied and pulled away for a total of five times for each piece of tape. Each piece of tape is weighed a second time and the final weight recorded.
  • the final and initial weights for each piece of tape were used to calculate the weight of the fibers removed from the sample surface. An average was calculated for each side of the sample. The more fiber lost by the surface of the sample, the more unstable the surface of the sample is. The results are reported in grams.
  • Flash spun unbonded batts were obtained by flash spinning high density polyethylene at various concentrations in a blend of pentane and cyclopentane spin agent at various temperatures by a process as described in Brethauer. The batts were lightly consolidated using a nip roll. The spinning conditions (percent polymer in spin agent and spinning temperature) and properties measured for each of these batts are listed as Comparative Examples 1-6 in Table 1.
  • the batts were then needlepunched in a needle machine using a 4500 needles per meter board on each of the top and bottom surfaces. Each batt was needled at a punch density of 60/cm 2 on each side and a needle penetration of 10 mm on the top surface and 5 mm on the bottom. A random needle pattern was used. The output speed was 6-7 meters per minute.
  • the properties of these needlepunched batts, or nonwoven fabrics, are listed as Examples 1-9 in Table 1. Examples 1-9 are the nonwoven fabrics resulting from needlepunching the batts of Comparative Examples 1-6. Comparative Examples 1, 2, 4 and 6 provided the starting material for Examples 1, 2, 5 and 9, respectively. Comparative Example 3 provided the starting material for both Examples 3 and 4. Comparative Example 5 provided the starting material for Examples 6, 7 and 8.
  • the thickness/basis weight (BW) ratio is a measure of the bulkiness of the fabric. The higher the thickness/BW, the bulkier the fabric.
  • the thickness/BW of the unbonded, unneedled batt (Comparative Examples 1-6) ranges from 4.5 to 5.2 depending on the basis weight and spinning conditions.
  • the thickness/BW of needlepunched fabric (Examples 1-9) ranges from 7.2 to 7.9.
  • the increase in thickness/BW of the needlepunched fabric is attributed to fiber entanglement caused by the action of the needles. This phenomenon is contrary to typical needlepunching of webs where the needles cause the web to consolidate and lower the thickness.
  • This increased thickness/BW ratio, or bulkiness is important for the wiping performance of the fabric of the invention, since it provides greater capacity for the fabric to capture and store dust and dirt particles.
  • Table 2 illustrates the effects on surface stability and wiping performance when the spinning conditions are held constant and the needling density and penetration are varied.
  • Examples 8 and 10-13 are based on the starting batt material of Comparative Example 5, and each is needlepunched at a different needle density and penetration (on the upper and lower sides), listed in Table 2. Surface area measurements are also included in Table 2.
  • Flash spun unbonded batts were obtained by flash spinning high density polyethylene at various concentrations in a blend of pentane and cyclopentane spin agent at various temperatures by a process as described in Brethauer.
  • the batts were lightly consolidated using a nip roll.
  • the spinning conditions percent polymer in spin agent and spinning temperature
  • properties measured for each of these batts are listed as Comparative Examples 1-6 in Table 1.
  • the batts were then hydroentangled using high pressure water on each of the top and bottom surfaces.
  • the number of jets, jet type, jet pressure and apertured member were varied to achieve various fabric strength, fiber surface stability and thickness.
  • the properties of these hydroentangled batts, or nonwoven fabrics, are listed as Examples 14-17 in Table 3.
  • the batt was supported on a first apertured member and hydroentangled by making several passes under high pressure water jets with the line running at 50 yards per minute.
  • the batt was then turned over, placed on a second apertured member and again hydroentangled by making several passes under high pressure water jets with the line running at 50 yards per minute.

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Nonwoven Fabrics (AREA)
  • Cleaning Implements For Floors, Carpets, Furniture, Walls, And The Like (AREA)

Abstract

A bulky fibrous fabric is provided, made by a process comprising obtaining an unbonded, consolidated batt of fibers wherein each fiber has a ribbon-shaped cross-section, and needling said batt to obtain the bulky fibrous fabric. The fabric has a surface area of at least 2 m2/g and a thickness/basis weight ratio of at least 0.005 mm/g/m2 (7 mil/oz/yd2) The fabric has utility particularly as a dry wipe for cleaning and dusting.

Description

    FIELD OF THE INVENTION
  • The invention relates to a needled fibrous batt made from fibers having a ribbon-shaped cross-section. [0001]
  • BACKGROUND OF THE INVENTION
  • There exists a need for a material in the form of a dry wipe for dusting and cleaning which attracts and entraps dust and dirt particles during use more effectively than existing dry wipes and which may be manufactured more economically than existing dry wipes. [0002]
  • Nonwoven dry wipes containing spunlaced layers of polyester web and scrim are commercially available. Examples of such dry wipes are Swiffer®, available from The Procter & Gamble Company, Cincinnati, Ohio, and Grab-It®), available from S. C. Johnson & Son, Inc., Racine, Wis., which are generally made by needling round polyester staple fibers into a scrim. These wipes are electrostatically charged to attract dirt and dust, and the three-dimensional structure of the webs used is open so that dirt particles are trapped by the wipes. Another example of a dry dust wipe is Scotch-Brite®, available from Minnesota Mining and Manufacturing Company, St. Paul, Minn., made from spunlaced webs of polyester staple fibers having longitudinal grooves therein. [0003]
  • U.S. Pat. No. 5,290,628 (Lim et al.) discloses a process for hydraulically needling a web of staple fibers into an unbonded flash spun web made of continuous plexifilaments to form a spunlaced nonwoven fabric. The flash spun web may optionally be bonded to increase the level of permeability of the nonwoven fabric. Disclosed as end uses for the nonwoven fabric are filtration applications, and bulky, downproof and featherproof barrier liners for garments, sleeping bags, pillows, comforters and the like. [0004]
  • U.S. Pat. No. 4,704,321 (Zafiroglu) discloses a nonwoven fabric, useful as a wipe-cloth, comprising a layer of nonbonded, polyethylene plexifilamentary film-fibril strands, the layer being stitched through with thread that forms spaced apart rows of stitches extending along the length of the fabric. Zafiroglu found that standard thermally bonded plexifilamentary sheets were not functional for wiping cloths because after thermal bonding to generate structural integrity the dust retention was inadequate, and the non thermally bonded, cold consolidated sheet lacked sufficient surface stability for a wiping cloth. [0005]
  • Japanese patent application Hei 4-196066, assigned to Japan Vilene Co. Ltd., discloses a nonwoven fabric cleaning wipe having superior dust attracting ability, and a process for making such a wipe. [0006]
  • SUMMARY OF THE INVENTION
  • The invention provides a bulky fibrous fabric comprising a batt of fibers each fiber having a ribbon-shaped cross-section, the batt having a surface area of at least 2 m[0007] 2/g and a thickness/basis weight ratio of at least 0.005 mm/g/m2.
  • In another embodiment of the invention, a bulky fibrous fabric is provided by a process comprising: [0008]
  • a) obtaining an unbonded, consolidated batt of fibers wherein each fiber has a ribbon-shaped cross-section; and [0009]
  • b) needling said batt to obtain the bulky fibrous fabric having a surface area of at least 2 m[0010] 2/g and a thickness/basis weight ratio of at least 0.005 mm/g/m2.
  • DETAILED DESCRIPTION OF THE INVENTION
  • 30 The process by which the bulky fibrous fabric of the invention is made will now be described in detail. A batt of fibers, each individual fiber having a ribbon-shaped cross-section, is obtained. By “ribbon-shaped” is meant that the average aspect ratio of the individual fiber cross-section is between 1.4 and 6.8. The batt of fibers may be obtained by a variety of known methods. One known method is for different cross-sectional shaped melt-spun fibers, such as star-shaped fibers, to be spunlaced and subsequently broken into smaller ribbon-shaped fibers. [0011]
  • Preferably, the batt consists of overlapping continuous plexifilamentary film-fibril strands, formed by flash-spinning techniques generally described in U.S. Pat. No. 3,851,023 (Brethauer et al.), herein incorporated by reference. The film-fibrils are very thin ribbon-like fibrous elements, which are generally less than 20 microns thick. The cross-section of each fiber in a plexifilamentary strand is generally ribbon-shaped. [0012]
  • Preferably, the flash-spun batt is formed from polyolefin polymer, and more preferably, high density polyethylene polymer. The spin agent with which the polymer is mixed is preferably a blend of pentane and cyclopentane. The spin agent may also be a refrigerant such as Freon@, available from E. I. du Pont de Nemours and Company, Inc., Wilmington, Del. [0013]
  • In order to achieve the desired bulkiness in the final product, the percentage of polymer in the polymer-spin agent mixture is preferably between 15 and 25%, most preferably 17%. The temperature of the polymer and spin agent mixture just prior to being emitted through the spin orifice should be maintained at between 185 and 200 degrees C., most preferably 190 degrees C. [0014]
  • As described in U.S. Pat. No. 3,851,023, the plexifilamentary film-fibril strands are electrostatically charged in order to pin them to the moving belt on which they are collected as they are spun. The electrostatic charge imparted is high enough to overcome the vapor blast or high turbulence that may exist in the web forming chamber. [0015]
  • By “consolidated” is meant that the as-formed batt has been lightly compressed by a nip roll so that it may be handled as a sheet. By “unbonded” is meant that the batt has not been further bonded by chemical or thermal means, such as by compaction by heated rolls or plates, so that the batt has not become a coherent sheet. In the preferred embodiment in which the batt is obtained by flash spinning, the individual plexifilamentary webs which overlap one another to make up the unbonded, consolidated batt are held together in such a way that the batt may be handled as a sheet but the individual webs may be easily pulled away from the surface of the batt. [0016]
  • The batt is needled in order to form the bulky fibrous fabric of the invention. The needling may take the form of hydroentangling, such as described in U.S. Pat. No. 3,485,706. As stated in U.S. Pat. No. 3,485,706, the hydroentangling is carried out by subjecting the batt to high pressure liquid streams of at least 200 psig while supported by an apertured member, such as perforated plate or woven wire screen. The number of jets, jet type, jet pressure and apertured member can be varied to achieve various fabric strength, surface stability and thickness. [0017]
  • Preferably, the needling is carried out by needlepunching in a needle machine to obtain the fabric of the invention having a thickness of at least 0.20 millimeters, a basis weight of between 37 and 78 g/m[0018] 2, and a thickness/basis weight ratio of at least 0.005 mm/g/m2 (7 mil/oz/yd2). The needle density, or “punch density,” is between 60 and 500/cm2, preferably between 200 and 300/cm2, on each side of the batt. The needle penetration is between 5 and 10 mm on each surface of the batt, preferably about 5 mm. The needle pattern is random such that the needle punches are approximately evenly spaced across both surfaces of the batt.
  • Since the bulky fibrous fabric of the invention is obtained by simply needling an unbonded, consolidated batt of fibers, the bulky fibrous fabric may be manufactured more economically than existing dry dust wipes made by needling staple fibers into a scrim. [0019]
  • Test Methods
  • Basis Weight was determined by ASTM D-3776, which is hereby incorporated by reference, and is reported in g/m[0020] 2.
  • Tensile Strength was determined by ASTM D 5035-95, which is hereby incorporated by reference, with the following modifications. In the test a 2.54 cm by 20.32 cm (1 inch by 8 inch) sample was clamped at opposite ends of the sample. The clamps were attached 12.7 cm (5 inches) from each other on the sample. The sample was pulled steadily at a speed of 5.08 cm/min (2 inches/min) until the sample broke. The force at break was recorded in pounds/inch and converted to Newtons/cm as the breaking tensile strength. [0021]
  • Thickness was determined by ASTM D177-64, which is hereby incorporated by reference, and is reported in millimeters. [0022]
  • Grab Tensile Strength was determined by ASTM D 5034-95, which is hereby incorporated by reference, recorded in pounds/inch and converted to Newtons/cm. [0023]
  • Elongation to Break of a sheet is a measure of the amount a sheet stretches prior to breaking in a strip tensile test. A 2.54 cm (1 inch) wide sample is mounted in the clamps, set 12.7 cm (5 inches) apart, of a constant rate of extension tensile testing machine such as an Instron table model tester. A continuously increasing load is applied to the sample at a crosshead speed of 5.08 cm/min (2 inches/min) until failure. The measurement is given in percentage of stretch prior to failure. The test generally follows ASTM D 5035-95. [0024]
  • Grab Elongation to Break was determined by ASTM D5034-95, which is hereby incorporated by reference, and recorded in %. [0025]
  • Density was calculated from measured basis weight divided by measured thickness and is reported in gram/cm[0026] 3.
  • Void Fraction was calculated as (1-calculated density/0.95)×100 and is reported in %. [0027]
  • Wiping Performance Test is a measure of a material's cleaning performance as a dust mop. For the test results reported herein, three test environments were used, referred to as Home, Light Industrial and Heavy Industrial. The Home environment was the floor of an office area which was cleaned daily. The Light Industrial environment was a busy hallway in a manufacturing area which had more traffic than the Home environment and was not cleaned daily. The Heavy Industrial environment had forklift truck traffic and was never cleaned. The materials to be tested were cut into samples measuring approximately 5 inches by 11 inches. Each sample was weighed and the weight recorded. Two samples to be compared were secured to the bottom surface of a dry mop with a flat, smooth rubber bottom surface. The mopping surface of the mop was approximately 10 inches by 3 inches. The mop was pushed over a fifty foot section of the floor. The samples were then removed from the mop and folded in such a way that the dust collected by each sample was held within that sample. Each sample was reweighed to determine the amount of dust collected by that sample. The percent performance was determined by dividing the dust collected by the dust collected by the incumbent, or comparison sample, and multiplying by 100%. This means that the incumbent will always have 100% performance, while the invention example will have a percent relative to the incumbent. Values less than 100% indicate inferior performance, while values greater than 100% indicate superior performance. Seven to ten sample pairs were run for each environment and the result is the average. [0028]
  • Fiber Surface Stability Test is a measure of how cohesive a surface is when exposed to a destructive external force. For this test, the samples were exposed to standard Scotch transparent tape, available from 3M, St. Paul, Minn. Four measurements were taken on one surface of the sample and four on the other. Eight (8) seven-inch pieces of tape were cut and weighed, and the initial weight recorded. Each piece of tape was applied to the surface to be tested and rubbed evenly to insure contact between the tape and the sample surface. The tape is then pulled away from the sample, then reapplied and pulled away for a total of five times for each piece of tape. Each piece of tape is weighed a second time and the final weight recorded. The final and initial weights for each piece of tape were used to calculate the weight of the fibers removed from the sample surface. An average was calculated for each side of the sample. The more fiber lost by the surface of the sample, the more unstable the surface of the sample is. The results are reported in grams. [0029]
  • Surface Area is calculated from the amount of nitrogen absorbed by a sample at liquid nitrogen temperatures by means of the Brunauer-Emmet-Teller equation and is given in m[0030] 2/g. The nitrogen absorption is determined using a Stohlein Surface Area Meter manufactured by Standard Instrumentation, Inc., Charleston, W. Va. The test method applied is found in the J. Am. Chem. Soc., V. 60 p. 309-319 (1938).
  • EXAMPLES 1-13
  • Flash spun unbonded batts were obtained by flash spinning high density polyethylene at various concentrations in a blend of pentane and cyclopentane spin agent at various temperatures by a process as described in Brethauer. The batts were lightly consolidated using a nip roll. The spinning conditions (percent polymer in spin agent and spinning temperature) and properties measured for each of these batts are listed as Comparative Examples 1-6 in Table 1. [0031]
  • The batts were then needlepunched in a needle machine using a 4500 needles per meter board on each of the top and bottom surfaces. Each batt was needled at a punch density of 60/cm[0032] 2 on each side and a needle penetration of 10 mm on the top surface and 5 mm on the bottom. A random needle pattern was used. The output speed was 6-7 meters per minute. The properties of these needlepunched batts, or nonwoven fabrics, are listed as Examples 1-9 in Table 1. Examples 1-9 are the nonwoven fabrics resulting from needlepunching the batts of Comparative Examples 1-6. Comparative Examples 1, 2, 4 and 6 provided the starting material for Examples 1, 2, 5 and 9, respectively. Comparative Example 3 provided the starting material for both Examples 3 and 4. Comparative Example 5 provided the starting material for Examples 6, 7 and 8.
  • The properties of nonwoven fabrics Swiffer® (commercially available from The Procter and Gamble Company, Cincinnati, Ohio) and Grab It® (commercially available from S. C. Johnson & Son, Inc., Racine, Wis.) were measured and listed in Table 1 as Comparative Examples 7 and 8. [0033]
  • The thickness/basis weight (BW) ratio is a measure of the bulkiness of the fabric. The higher the thickness/BW, the bulkier the fabric. The thickness/BW of the unbonded, unneedled batt (Comparative Examples 1-6) ranges from 4.5 to 5.2 depending on the basis weight and spinning conditions. The thickness/BW of needlepunched fabric (Examples 1-9) ranges from 7.2 to 7.9. The increase in thickness/BW of the needlepunched fabric is attributed to fiber entanglement caused by the action of the needles. This phenomenon is contrary to typical needlepunching of webs where the needles cause the web to consolidate and lower the thickness. This increased thickness/BW ratio, or bulkiness, is important for the wiping performance of the fabric of the invention, since it provides greater capacity for the fabric to capture and store dust and dirt particles. [0034]
  • Slight increases in the mechanical properties of Examples 1-9 as compared with Comparative Examples 1-6, specifically grab tensile strength, grab elongation to break, tensile strength and elongation to break, are attributed to the fiber entanglements caused by the needlepunching process. The mechanical properties are increased with increasing basis weight. A 54 g/m[0035] 2 needlepunched fabric has a similar range of mechanical properties as the current incumbent wipe products.
  • Table 2 illustrates the effects on surface stability and wiping performance when the spinning conditions are held constant and the needling density and penetration are varied. Examples 8 and 10-13 are based on the starting batt material of Comparative Example 5, and each is needlepunched at a different needle density and penetration (on the upper and lower sides), listed in Table 2. Surface area measurements are also included in Table 2. [0036]
  • Surface area measurements were made on the existing dust wipe materials, Swiffer® and Grab-It® (Comparative Examples 7 and 8), and the result was 0.0 m[0037] 2/g, meaning less than 0.1 m2/g.
    TABLE 1
    Comparison Comparison Comparison Comparison Comparison Comparison
    Example 1 2 3 4 5 6 1 2
    Spun condition (% polymer, 17/190 17/197 17/200 20/200 17/190 17/190 17/190 17/197
    degrees C)
    Basis Weight (g/m2) 41 41 54 51 54 78 37 41
    Thickness (mm) 0.159 0.155 0.203 0.198 0.203 0.264 0.221 0.236
    Thickness/Basis 3.90E − 06 3.80E − 06 3.80E − 06 3.90E − 06 3.80E − 06 3.40E − 06 6.00E − 06 5.80E − 06
    Weight (m3/g)
    Density (g/cm3) 0.257 0.263 0.267 0.257 0.267 0.295 0.169 0.172
    Void Fraction (%) 73 72.3 71.9 72.9 71.9 68.9 82.2 81.9
    Grab Tenacity MD/CD (N/cm) 5./10 5./9 12./46 9./47 19/28 24/46 10./12 10./16
    Grab Elongation MD/CD (%) 44/64 43/57 50/34 40/51 41/53 45/39 43/45
    Tensile MD/CD (N/cm) 1.9/2.3 1.7/1.7 2.6/8.9 2.6/8.8 3.5/4.5 6.6/6.6 1.9/3.1 2.6/3.3
    Elongation MD/CD (%) 4./15 6./13 15/23 15/23 9./13 9.4/11.4 26/27 29/28
    Fiber Surface Stability:
    Belt side (g) 0.0975 0.0614 0.0461 0.295 0.554 0.149 0.0496 0.0505
    Top side (g) 0.302 0.143 0.0667 0.0646 0.156 0.276 0.0657 0.0708
    Wiping Performance (%):
    Home environment 81 110 76 90 105 170
    Light Industrial 81 100 87 82 90 100 130
    Heavy Industrial 76 100 85 100 85 75 80
    Comparison Comparison
    Example 3 4 5 6 7 8 9 7 8
    Spun condition (% 17/200 17/200 20/200 17/190 17/190 17/190 17/190
    polymer, degrees C)
    Basis Weight (g/m2) 49 51 51 56 48 51 78 64 58
    Thickness (mm) 0.287 0.274 0.292 0.307 0.251 0.3 0.414 0.297 0.305
    Thickness/Basis 5.90E − 06 5.40E − 06 5.70E − 06 5.50E − 06 5.20E − 06 5.90E − 06 5.30E − 06 4.60E − 06 5.30E − 06
    Weight (m3/g)
    Density (g/cm3) 0.171 0.186 0.174 0.183 0.192 0.17 0.189
    Void Fraction (%) 82 80.4 81.7 80.7 79.8 82.1 80.1
    Grab Tenacity 18/24 18/21 30/44 30/35 44/53 16/9 28/9
    MD/CD (N/cm)
    Grab Elongation 82/55 53/30 53/34 47/43 49/36 112/78 56/71
    MD/CD (%)
    Tensile MD/CD 4.7/7.9 3.8/8.4 7./12 7./8.8 9./16 7./2.8 17/3
    (N/cm)
    Elongation 41/36 37/33 39/41 34/35 34/29 56/29 50/44
    MD/CD (%)
    Fiber Surface
    Stability:
    Belt side (g) 0.0061 0.0143 0.0148 0.0385 0.0405 0.0048 0.0122 0.0244 0.00754
    Top side (g) 0.0344 0.0724 0.0236 0.0208 0.0513 0.0129 0.0045 0.0667 0.0043
    Wiping Performance
    (%):
    Home environment 110 130 117/150 108 100/130 100
    Light Industrial 122 117 110/120 83 107/86 100
    Heavy Industrial 107 107 100/90 100 107/80 100
  • [0038]
    TABLE 2
    Example Comparison 5 8 10 11 12 13
    Spun conditions (% polymer/degrees C) 17/190 17/190 17/190 17/190 17/190 17/190
    Needle (density/penetration upper/lower):
    Density (needles/cm2) 60 100 100 150 225
    Penetration (upper/lower) (mm) 10./5 10.0/5 5.0/5 5.0/5 5.0/5
    Basis Weight (g/m2) 54 51 51 51 51 51
    Thickness (mm) 0.203 0.3 0.31 0.297 0.312 0.368
    Thickness/BW (m3/g) 3.80E − 06 5.90E − 06 6.10E − 06 5.80E − 06 6.10E − 06 7.20E − 06
    Density (g/cm3) 0.267 0.17 0.164 0.172 0.163 0.138
    Void Fraction (%) 71.9 82.1 82.7 81.9 82.8 85.5
    Grab Tenacity MD/CD (N/cm) 19/28 30/35 23/28 30/31 23/22 30/31
    Grab Elongation MD/CD (%) 40/51 47/43 50/44 52/47 47/41.6 52/43.6
    Tensile MD/CD (N/cm) 3.5/4.5 7/8.8 7/7.9 7.7/8.8 7.5/6.6 6.6/8.9
    Elongation MD/CD (%) 9./13 34/35 32/35 29/32 27/33 30.2/34
    Fiber Surface Stability:
    Belt side (g) 0.554 0.0048 0.0194 0.011 0.079 0.016
    Top side (g) 0.156 0.0129 0.0108 0.017 0.023 0.016
    Wiping vs. Swiffer:
    Home environment 76 109/130 93 138 110 150
    Light Industrial 82 122/86 126 114 114 118
    Heavy Industrial 100 98/80 93 100 106 107
    Surface Area (m2/g) 15.3 11.8 9.5 10.8 8.4 9.7
  • EXAMPLES 14-17
  • Flash spun unbonded batts were obtained by flash spinning high density polyethylene at various concentrations in a blend of pentane and cyclopentane spin agent at various temperatures by a process as described in Brethauer. The batts were lightly consolidated using a nip roll. The spinning conditions (percent polymer in spin agent and spinning temperature) and properties measured for each of these batts are listed as Comparative Examples 1-6 in Table 1. [0039]
  • The batts were then hydroentangled using high pressure water on each of the top and bottom surfaces. The number of jets, jet type, jet pressure and apertured member were varied to achieve various fabric strength, fiber surface stability and thickness. The properties of these hydroentangled batts, or nonwoven fabrics, are listed as Examples 14-17 in Table 3. In each case, the batt was supported on a first apertured member and hydroentangled by making several passes under high pressure water jets with the line running at 50 yards per minute. The batt was then turned over, placed on a second apertured member and again hydroentangled by making several passes under high pressure water jets with the line running at 50 yards per minute. [0040]
    TABLE 3
    Example 14 15 16 17
    Spun condition (% polymer/degrees C) 17/200 17/200 17/200 17/200
    Water jet pressure Low Pressure High Pressure Low Pressure
    Basis Weight (g/m2) 47 58 58 58
    Thickness (mm) 0.292 0.318 0.356 0.356
    Thickness/BW (m3/g) 6.20E − 06 5.50E − 06 6.10E − 06 6.10E − 06
    Density (g/cm3)
    Void Fraction (%)
    Grab Tenacity MD/CD (N/cm) 42 58 47 42
    Grab Elongation MD/CD (%) 46 34 36 44
    Tensile MD/CD (N/cm) 25.4 12.2 19.2 14
    Elongation MD/CD (%) 24 40 37 37
    Fiber Surface Stability:
    Belt side (g) 0.018 0.006 0.003
    Top side (g) 0.013 0.01 0.003
    Wiping vs. Swiffer:
    Home environment 80 130 110
    Light Industrial
    Heavy Industrial 95 96 91
    Surface Area (m2/g) 8.6 8 6.3 7.1
  • EXAMPLE 14
  • During the first pass of hydroentangling, the batt was supported on a first apertured member of a 75 mesh woven wire. Four jets were used. During the second pass of hydroentangling, the batt was supported on a second apertured member of a perforated plate having a clover pattern with a 20 mesh sub screen. Three jets were used. The jet hole diameters, number of holes per inch per jet, and the jet operating pressures are listed below in Table 4. [0041]
    TABLE 4
    Hole diameter Pressure
    Jet (mils) Holes per inch (psi)
    First Pass
    1 4 80 500
    2 5 40 1000
    3 5 40 1500
    4 5 40 1500
    Second Pass
    1 4 80 300
    2 5 40 500
    3 5 40 1000
  • EXAMPLE 15
  • During the first pass of hydroentangling, the batt was supported on a first apertured member of a 75 mesh woven wire. Four jets were used. During the second pass of hydroentangling, the batt was supported on a second apertured member of an 8 mesh woven wire. Four jets were used. The jet parameters are listed in Table 5. [0042]
    TABLE 5
    Hole diameter Pressure
    Jet (mils) Holes per inch (psi)
    First Pass
    1 4 80 500
    2 5 40 1000
    3 5 40 1500
    4 5 40 1500
    Second Pass
    1 4 80 500
    2 5 40 800
    3 5 40 1000
    4 5 40 1000
  • EXAMPLE 16
  • During the first pass of hydroentangling, the batt was supported on a first apertured member of a 75 mesh woven wire. Four jets were used. During the second pass of hydroentangling, the batt was supported on a second apertured member of an 13 mesh woven wire. Eight jets were used. The jet parameters are listed in Table 6. [0043]
    TABLE 6
    Hole diameter Pressure
    Jet (mils) Holes per inch (psi)
    First Pass
    1 4 80 500
    2 5 40 1000
    3 5 40 1500
    4 5 40 1500
    Second Pass
    1 4 80 300
    2 4 80 500
    3 5 40 800
    4 5 40 1000
    5 5 40 1200
    6 5 40 1500
    7 5 40 1700
    8 5 40 1800
  • EXAMPLE 17
  • During the first pass of hydroentangling, the batt was supported on a first apertured member of a 75 mesh woven wire. Eight jets were used. During the second pass of hydroentangling, the batt was supported on a second apertured member of an 8 mesh woven wire. Eight jets were used. The jet parameters are listed in Table 7. [0044]
    TABLE 7
    Hole diameter Pressure
    Jet (mils) Holes per inch (psi)
    First Pass
    1 4 80 300
    2 5 40 500
    3 5 40 800
    4 5 40 1000
    5 5 40 1200
    6 5 40 1500
    7 5 40 1800
    8 5 40 1800
    Second Pass
    1 4 80 300
    2 4 80 500
    3 5 40 800
    4 5 40 1000
    5 5 40 1200
    6 5 40 1500
    7 5 40 1700
    8 5 40 1800

Claims (10)

What is claimed is:
1. A bulky fibrous fabric comprising a batt of fibers each fiber having a ribbon-shaped cross-section, the batt having a surface area of at least 2 m2/g and a thickness/basis weight ratio of at least 0.005 mm/g/m2 (7 mil/oz/yd2).
2. A bulky fibrous fabric made by a process comprising:
a) obtaining an unbonded, consolidated batt of fibers wherein each fiber has a ribbon-shaped cross-section; and
b) needling said batt to obtain the bulky fibrous fabric having a surface area of at least 2 m2/g and a thickness/basis weight ratio of at least 0.005 mm/g/m2 (7 mil/oz/yd2).
3. The bulky fibrous fabric of claim 2 wherein the batt is made from flash-spun plexifilamentary film-fibril web.
4. The bulky fibrous fabric of claim 2 or claim 3 wherein the needling is performed by hydroentangling.
5. The bulky fibrous fabric of claim 2 or claim 3 wherein the needling is performed by needlepunching.
6. The bulky fibrous fabric of claim 1 wherein the bulky fibrous fabric is a nonwoven fabric and the fibers are polyolefin.
7. The bulky fibrous fabric of claim 1 wherein the bulky fibrous fabric is a nonwoven fabric and the fibers are polyethylene.
8. The bulky fibrous fabric of claim 6 wherein the surface area is between 2 and 30 m2/g and the thickness/basis weight ratio is between 0.005 and 0.0075 mm/g/m2.
9. A bulky nonwoven fabric made by a process comprising: a) obtaining an unbonded, consolidated flash-spun batt; b) needlepunching said flash-spun batt to obtain the bulky nonwoven fabric having a surface area of at least 2 m2/g, a thickness/basis weight ratio of at least 0.005 mm/g/m2, a thickness of at least 0.20 mm and a basis weight of between 37 and 78 g/m2.
10. A dry wipe useful for cleaning and dusting made from the bulky nonwoven fabric according to any of the preceding claims.
US10/142,533 2001-05-18 2002-05-09 Dry wipe Abandoned US20030082978A1 (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20070270071A1 (en) * 2006-05-18 2007-11-22 Greer J Travis Nonwoven fabric towel
US10993855B2 (en) 2013-03-15 2021-05-04 The Procter & Gamble Company Absorbent articles with nonwoven substrates having fibrils

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20140272359A1 (en) 2013-03-15 2014-09-18 The Procter & Gamble Company Nonwoven substrates
CN116103836A (en) * 2021-04-16 2023-05-12 江苏青昀新材料科技有限公司 Composite sheet and processing method thereof
CN116024734A (en) * 2021-04-16 2023-04-28 江苏青昀新材料科技有限公司 Sheet material prepared by flash spinning method

Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3169899A (en) * 1960-11-08 1965-02-16 Du Pont Nonwoven fiberous sheet of continuous strand material and the method of making same
US3485706A (en) * 1968-01-18 1969-12-23 Du Pont Textile-like patterned nonwoven fabrics and their production
US3619339A (en) * 1969-07-08 1971-11-09 Du Pont Porous nonwoven film-fibril sheet and process for producing said sheet
US3851023A (en) * 1972-11-02 1974-11-26 Du Pont Process for forming a web
US3920874A (en) * 1970-12-16 1975-11-18 Du Pont Softened fibrillated sheet
US4704321A (en) * 1986-11-05 1987-11-03 E. I. Du Pont De Nemours And Company Stitched polyethylene plexifilamentary sheet
US4910075A (en) * 1988-10-18 1990-03-20 E. I. Du Pont De Nemours And Company Point-bonded jet-softened polyethylene film-fibril sheet
US5023130A (en) * 1990-08-14 1991-06-11 E. I. Du Pont De Nemours And Company Hydroentangled polyolefin web
US5290628A (en) * 1992-11-10 1994-03-01 E. I. Du Pont De Nemours And Company Hydroentangled flash spun webs having controllable bulk and permeability
US6037282A (en) * 1994-08-22 2000-03-14 Sca Hygiene Paper Ab Nonwoven material comprising a certain proportion of recycled fibres originating from nonwoven and/or textile waste

Patent Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3169899A (en) * 1960-11-08 1965-02-16 Du Pont Nonwoven fiberous sheet of continuous strand material and the method of making same
US3485706A (en) * 1968-01-18 1969-12-23 Du Pont Textile-like patterned nonwoven fabrics and their production
US3619339A (en) * 1969-07-08 1971-11-09 Du Pont Porous nonwoven film-fibril sheet and process for producing said sheet
US3920874A (en) * 1970-12-16 1975-11-18 Du Pont Softened fibrillated sheet
US3851023A (en) * 1972-11-02 1974-11-26 Du Pont Process for forming a web
US4704321A (en) * 1986-11-05 1987-11-03 E. I. Du Pont De Nemours And Company Stitched polyethylene plexifilamentary sheet
US4910075A (en) * 1988-10-18 1990-03-20 E. I. Du Pont De Nemours And Company Point-bonded jet-softened polyethylene film-fibril sheet
US5023130A (en) * 1990-08-14 1991-06-11 E. I. Du Pont De Nemours And Company Hydroentangled polyolefin web
US5290628A (en) * 1992-11-10 1994-03-01 E. I. Du Pont De Nemours And Company Hydroentangled flash spun webs having controllable bulk and permeability
US6037282A (en) * 1994-08-22 2000-03-14 Sca Hygiene Paper Ab Nonwoven material comprising a certain proportion of recycled fibres originating from nonwoven and/or textile waste

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20070270071A1 (en) * 2006-05-18 2007-11-22 Greer J Travis Nonwoven fabric towel
US10993855B2 (en) 2013-03-15 2021-05-04 The Procter & Gamble Company Absorbent articles with nonwoven substrates having fibrils

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