US20030029550A1 - Process for producing holographic material - Google Patents

Process for producing holographic material Download PDF

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Publication number
US20030029550A1
US20030029550A1 US09/971,262 US97126201A US2003029550A1 US 20030029550 A1 US20030029550 A1 US 20030029550A1 US 97126201 A US97126201 A US 97126201A US 2003029550 A1 US2003029550 A1 US 2003029550A1
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United States
Prior art keywords
printing element
holographic
substrate
holographic image
providing
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Abandoned
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US09/971,262
Inventor
Donald Weder
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Individual
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Individual
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Priority to US09/971,262 priority Critical patent/US20030029550A1/en
Publication of US20030029550A1 publication Critical patent/US20030029550A1/en
Priority to US10/617,283 priority patent/US20040062997A1/en
Abandoned legal-status Critical Current

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B38/00Ancillary operations in connection with laminating processes
    • B32B38/06Embossing
    • AHUMAN NECESSITIES
    • A47FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
    • A47GHOUSEHOLD OR TABLE EQUIPMENT
    • A47G7/00Flower holders or the like
    • A47G7/02Devices for supporting flower-pots or cut flowers
    • A47G7/08Covers for flower-pots, e.g. ornamental pots
    • A47G7/085Covers for flower-pots, e.g. ornamental pots made of flexible sheets of non-resilient material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C37/00Component parts, details, accessories or auxiliary operations, not covered by group B29C33/00 or B29C35/00
    • B29C37/0053Moulding articles characterised by the shape of the surface, e.g. ribs, high polish
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D85/00Containers, packaging elements or packages, specially adapted for particular articles or materials
    • B65D85/50Containers, packaging elements or packages, specially adapted for particular articles or materials for living organisms, articles or materials sensitive to changes of environment or atmospheric conditions, e.g. land animals, birds, fish, water plants, non-aquatic plants, flower bulbs, cut flowers or foliage
    • B65D85/505Containers, packaging elements or packages, specially adapted for particular articles or materials for living organisms, articles or materials sensitive to changes of environment or atmospheric conditions, e.g. land animals, birds, fish, water plants, non-aquatic plants, flower bulbs, cut flowers or foliage for cut flowers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D85/00Containers, packaging elements or packages, specially adapted for particular articles or materials
    • B65D85/50Containers, packaging elements or packages, specially adapted for particular articles or materials for living organisms, articles or materials sensitive to changes of environment or atmospheric conditions, e.g. land animals, birds, fish, water plants, non-aquatic plants, flower bulbs, cut flowers or foliage
    • B65D85/52Containers, packaging elements or packages, specially adapted for particular articles or materials for living organisms, articles or materials sensitive to changes of environment or atmospheric conditions, e.g. land animals, birds, fish, water plants, non-aquatic plants, flower bulbs, cut flowers or foliage for living plants; for growing bulbs
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03HHOLOGRAPHIC PROCESSES OR APPARATUS
    • G03H1/00Holographic processes or apparatus using light, infrared or ultraviolet waves for obtaining holograms or for obtaining an image from them; Details peculiar thereto
    • G03H1/02Details of features involved during the holographic process; Replication of holograms without interference recording
    • G03H1/0276Replicating a master hologram without interference recording
    • G03H1/028Replicating a master hologram without interference recording by embossing
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29LINDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
    • B29L2031/00Other particular articles
    • B29L2031/722Decorative or ornamental articles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2425/00Cards, e.g. identity cards, credit cards
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2429/00Carriers for sound or information
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2451/00Decorative or ornamental articles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/12Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by using adhesives
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03HHOLOGRAPHIC PROCESSES OR APPARATUS
    • G03H1/00Holographic processes or apparatus using light, infrared or ultraviolet waves for obtaining holograms or for obtaining an image from them; Details peculiar thereto
    • G03H1/0005Adaptation of holography to specific applications
    • G03H2001/0055Adaptation of holography to specific applications in advertising or decorative art
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03HHOLOGRAPHIC PROCESSES OR APPARATUS
    • G03H2227/00Mechanical components or mechanical aspects not otherwise provided for
    • G03H2227/04Production line for mass production
    • GPHYSICS
    • G03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03HHOLOGRAPHIC PROCESSES OR APPARATUS
    • G03H2250/00Laminate comprising a hologram layer
    • G03H2250/10Laminate comprising a hologram layer arranged to be transferred onto a carrier body
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T156/00Adhesive bonding and miscellaneous chemical manufacture
    • Y10T156/10Methods of surface bonding and/or assembly therefor
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T156/00Adhesive bonding and miscellaneous chemical manufacture
    • Y10T156/10Methods of surface bonding and/or assembly therefor
    • Y10T156/1002Methods of surface bonding and/or assembly therefor with permanent bending or reshaping or surface deformation of self sustaining lamina
    • Y10T156/1007Running or continuous length work
    • Y10T156/1023Surface deformation only [e.g., embossing]
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T156/00Adhesive bonding and miscellaneous chemical manufacture
    • Y10T156/10Methods of surface bonding and/or assembly therefor
    • Y10T156/1002Methods of surface bonding and/or assembly therefor with permanent bending or reshaping or surface deformation of self sustaining lamina
    • Y10T156/1039Surface deformation only of sandwich or lamina [e.g., embossed panels]
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T156/00Adhesive bonding and miscellaneous chemical manufacture
    • Y10T156/10Methods of surface bonding and/or assembly therefor
    • Y10T156/1002Methods of surface bonding and/or assembly therefor with permanent bending or reshaping or surface deformation of self sustaining lamina
    • Y10T156/1051Methods of surface bonding and/or assembly therefor with permanent bending or reshaping or surface deformation of self sustaining lamina by folding

Definitions

  • the present invention relates generally to processes for producing decorative material, and more particularly, but not by way of limitation, to processes for producing holographic material.
  • Processes for producing holographic materials are well known in the art.
  • One process involves passing a layer of plastic, for example, through a machine which imparts an image within the covering or upper strata of the plastic layer.
  • a powdered metallic constituent or component e.g. aluminum
  • metalizing After metalizing, a holographic or 3-dimensional image is imparted on the metalized layer of plastic.
  • This image is extremely pleasing and is widely used within the credit card and security industries since the resulting image is difficult to duplicate and thus assists in the prevention of fraud by counterfeiting, for example.
  • images produced by this process can be quite expensive since the machines required for production of the images are complicated and costly in and of themselves.
  • holographic images produced by this process are usually small in size, and larger holographic images cannot be imprinted by this process. Thus, this process of producing holographic images has not been widely used outside of the credit card and novelty industry.
  • a process for producing large sheets of holographic material at a lower cost than the process described above involves producing the holographic image laminated to a polymeric support, contacting the holographic image on the polymeric support to a substrate such as tissue paper or foil via an adhesive, and delaminating the polymeric support, thereby transferring the holographic image from the polymeric support to the tissue paper or foil substrate.
  • the image cannot be directly applied to a substrate having a rough surface because the rough surface of the substrate will refract light and will not have a highly reflective finish, thereby disrupting the holographic image.
  • processes for producing holographic material are provided which avoid the disadvantages and defects of the prior art, making the processes more economically feasible.
  • processes are provided for transferring holographic images to a substrate to produce a holographic material. These processes involve producing the holographic image on a polished, substantially smooth surface and then transferring the holographic image to a substrate, thereby bypassing the need for the polymeric support used in the prior art.
  • a printing element having a polished, substantially smooth surface is provided, and a metallic coating is applied to the smooth surface of the printing element to provide a coated surface.
  • the coated surface is embossed to provide the holographic image on the coating, and the holographic image is then transferred to a substrate, thereby producing a holographic material.
  • a non-metallic coating may be applied to the smooth surface of the printing element to provide a coated surface, which is then embossed to provide an image.
  • the embossed coated surface is then metalized to provide a holographic image on the coating, and the holographic image is transferred to a substrate to produce the holographic material.
  • holographic materials in accordance with the present invention may be performed as a continuous process or as a batch process.
  • Applications of the holographic materials produced in accordance with the present invention include wrapping a floral grouping and providing a decorative cover for an object such as a flower pot or a potted plant, as well as decorative wrappings for various food and gift items.
  • An object of the present invention is to provide improved processes for producing holographic materials.
  • Another object of the present invention while achieving the before-stated object, is to provide processes for producing holographic materials which do not suffer from the disadvantages of the prior art processes.
  • FIG. 1 is a perspective view illustrating a holographic material produced by a continuous process in accordance with the present invention.
  • FIG. 2 is a partial schematic representation of a continuous process for producing holographic material utilizing a cylindrical drum.
  • FIG. 3 is a partial schematic representation of another continuous process for producing holographic material utilizing a cylindrical drum.
  • FIG. 4 is a side plan view illustrating a holographic material produced by a batch process in accordance with the present invention.
  • FIG. 5 is a diagrammatic representation of a flat plate used to produce holographic materials in accordance with the present invention, the flat plate having a coating disposed on a surface thereof.
  • FIG. 6 is a diagrammatic representation of the flat plate with a coated surface of FIG. 5 and an embossing plate for embossing the coated surface of the flat plate to provide an embossed coated surface with a holographic image thereon.
  • FIG. 7 is a diagrammatic representation of the flat plate of FIG. 6 having an embossed coated surface and a holographic image thereon, the embossed coated surface of the flat plate having an adhesive applied thereto.
  • FIG. 8 is a diagrammatic representation of the flat plate of FIG. 7 having an embossed coated surface with a holographic image thereon and an adhesive applied thereto, the adhesive bondingly connecting the embossed coated surface to a substrate to produce a holographic material constructed from the coating containing a holographic image and the substrate.
  • FIG. 9 is a perspective view illustrating a floral grouping wrapped with a sheet of holographic material constructed in accordance with the present invention.
  • FIG. 10 is a perspective view illustrating a decorative pot cover formed from a holographic material constructed in accordance with the present invention.
  • FIG. 11 is a perspective view illustrating the decorative pot cover of FIG. 10 wherein the pre-formed pot cover has a potted plant disposed therein.
  • FIG. 1 shown in FIG. 1 and designated therein by the reference numeral 10 is a holographic material constructed in accordance with the present invention by a continuous process.
  • the holographic material 10 comprises a substrate 12 having a holographic design or image 14 formed thereon.
  • the holographic image 14 provides the holographic material 10 with a holographic or 3 -dimensional appearance.
  • holographic image as used herein is to be understood to mean a three-dimensional image most visible from an oblique angle.
  • the unique properties of holographic images are that they appear to float in space, are true-to-life and can change perspective, that is, permit one to look around corners and watch hidden features of the image come to light.
  • the “holographic image” can be in any geometric form, or any combination of geometric forms, for example, squares, round spots, triangles, rectangles, octagonals, or the like, or any non-geometric, asymmetrical or fanciful forms, or any combination thereof, for example, but not by way of limitation, hearts, balloons, flowers, lace, slogans, logos, print (any combination of letters and/or numbers), signs, human forms (real and fictional), animal forms (real and fictional), cartoon characters, and/or plant forms.
  • Such holographic images may include a color, or a portion of a color, or a combination of colors and designs.
  • at least a portion of the holographic image may be colorless, translucent, transparent, opaque, pearlescent, iridescent, or the like.
  • the term “substrate” when used herein means a sheet of material which provides stability to the holographic image 14 .
  • the substrate 12 of the holographic material 10 may be flexible or non-flexible.
  • the substrate 12 can be constructed of any suitable material capable of receiving a holographic image, such as polymeric film, non-polymeric film, foil, paper, tissue and combinations thereof.
  • the substrate 12 includes a surface 16 which may be substantially rough and textured or substantially smooth. For example, tissue paper, kraft paper and high density polyethylene film often have rough surfaces, while foil and chromecoat paper typically have smooth surfaces.
  • the thickness of the substrate 12 can vary widely. Generally, however, the substrate 12 has a thickness in a range from about 0.0002 mil to about 30 mils, and more desirably from about 0.1 mil to about 20 mils.
  • the holographic material 10 is produced using a printing element 18 .
  • the printing element 18 may be provided with a smooth surface or a rough surface.
  • the need to produce the holographic image on a substrate having a smooth surface, such as required by the prior art methods, is substantially eliminated.
  • the term “printing element” as used herein means any element having a surface capable of having a holographic image produced thereon whereby the holographic image can be transferred to a substrate without substantially distorting the holographic image.
  • the printing element 18 for producing the holographic material 10 by a continuous process 17 may be, for example, but not limited to, a cylindrical drum, a roller and the like.
  • the printing element 18 may be constructed of any suitable material capable of having a polished, substantially smooth surface and which is capable of having the holographic image formed thereon for transfer to a desired substrate.
  • the printing element 18 may be constructed of chrome, stainless steel, tool steel and the like.
  • the printing element 18 may also be constructed in part of a resilient or non-resilient material such that the printing element 18 is provided with a resilient or non-resilient surface.
  • the printing element 18 illustrated in FIGS. 2 and 3 is a cylindrical drum 20 having a smooth surface 22 .
  • the cylindrical drum 20 permits the holographic material 10 to be continuously produced.
  • a coating 30 capable of receiving a holographic image is applied to the smooth surface 22 of the cylindrical drum 20 by a coating assembly 32 , thereby providing a coated surface 34 of the cylindrical drum 20 .
  • the coating assembly 32 is illustrated as comprising a coating pan 36 and a reverse gravure doctor blade 38 .
  • the thickness of the coating 30 on the coated surface 34 of the cylindrical drum 20 can be controlled and maintained within preselected limits by the reverse gravure doctor blade 38 of the coating assembly 32 .
  • the term “coating” as used herein is to be understood to mean a maleable film which is able to be embossed to receive a holographic image on at least a portion thereof.
  • the coating 30 may be a metallic material such as metallic polymeric film, metallic non-polymeric film, foil, metalized lacquer and combinations thereof.
  • the coating 30 may also be a nonmetallic material such as polymeric film, non-polymeric film, foil, lacquer and combinations thereof. Wherein the coating 30 is a nonmetallic material, the process for producing the holographic material 10 in accordance with the present invention includes an additional step of metalizing the coated surface 34 of the cylindrical drum 20 , which will be described in detail below.
  • lacquer as used herein means a coating substance consisting of resinous materials, such as cellulose esters, cellulose ethers, shellac, gum, alkyd resins and the like, which are dissolved in a solvent that evaporates rapidly on application such as ethyl alcohol, thereby leaving a tough, adherent film.
  • Lacquers which are useful in the present invention are mixtures, such as, but not limited to, lacquers produced by mixing styrene-acrylic emulsions, such as Lucidene 603 and Lucidene 395 (Morton International, Inc., 100 North Riverside Plaza, Chicago, Ill.
  • the lacquer produced as described above may also contain a wax emulsion in water, such as Liquitron 440 (Carrol Scientific, Inc., 5401 S. Dansher Road, Countryside, Ill. 60525).
  • embossing element 40 such as an embossing drum 42 .
  • embossing elements are used to produce materials to decorate or cover articles by depressing, carving, raising, or printing designs, patterns, etc. so that at least a portion of the design, pattern, etc. is raised above the surface of the material. Embossing elements are well known in the art; thus, no further discussion of embossing methods need be required.
  • Embossing of the coated surface 34 of the cylindrical drum 20 produces a holographic image 14 on the coated surface 34 of the cylindrical drum 20 .
  • the holographic image 14 is provided with a first surface 44 and a second surface 46 which is substantially adjacent the smooth surface 22 of the cylindrical drum 20 .
  • a metallic constituent or component 48 is applied to the embossed coated surface 34 of the cylindrical drum 20 to provide the holographic image 14 .
  • the metallic constituent or component 48 can be applied to the embossed coated surface 34 of the cylindrical drum 20 by any suitable means, such as by discharging the metallic constituent or component 48 from a reservoir 50 .
  • Metallic constituents or components which may be employed to metallize the embossed coated surface 34 of the cylindrical drum 20 are known in the art and include powdered metals such as powdered aluminum.
  • a bonding material 54 is applied to the holographic image 14 by a bonding material applicator 56 .
  • the bonding material applicator 56 comprises a pan 58 and a reverse gravure doctor blade 60 for removing excess bonding material 54 and controlling the thickness of the bonding material 54 so as to insure a substantially uniform coating of bonding material 54 on the holographic image 14 present on the cylindrical drum 20 .
  • the bonding material 54 applied to the holographic image 14 is contacted with the substrate 12 , thereby bondingly contacting the holographic image 14 to the substrate 12 and producing the holographic material 10 .
  • bonding material when used herein may be an adhesive, such as a pressure sensitive adhesive, or a cohesive. Where the bonding material is a cohesive, a similar cohesive material must be placed on the adjacent surface for bondingly contacting and bondingly engaging with the cohesive material.
  • the term “bonding material” may also be materials which are heat sealable and, in this instance, the adjacent portions of the materials must be brought into contact and then heat must be applied to effect the seal.
  • the term “bonding material” when used herein also means a lacquer, which may be the coating 30 described above. In this instance, heat, sound waves, or vibrations may be applied to effect the sealing of the lacquer. In this way, the coating 30 may both receive the holographic image 14 and effect sealing of the holographic image 14 to the substrate 12 , thereby producing the holographic material 10 .
  • a nip formed by opposing rollers of the cylindrical drum 20 and a sealing drum 62 may sandwich the holographic image 14 and the substrate 12 to effect a seal between the substrate 12 and the holographic image 14 .
  • the sealing drum 62 may be a heated roller to aid in effecting the seal between the holographic image 14 and the substrate 12 .
  • the holographic material 10 is then removed from the smooth surface 22 of the cylindrical drum 20 .
  • Methods of removing the holographic material 10 from the cylindrical drum 20 are known in the art.
  • the holographic material 10 produced by the continuous process 17 may be present in different forms such as a roll or sheets of holographic material 10 .
  • FIG. 4 Shown in FIG. 4 is a holographic material 10 a constructed in accordance with the present invention by a batch process 68 .
  • the holographic material 10 a is similar to the holographic material 10 described hereinbefore, and comprises a substrate 12 a having a holographic image 14 a formed thereon.
  • the batch process 68 for producing the holographic material 10 a is illustrated in FIGS. 5, 6, 7 and 8 and described in detail hereinafter.
  • the holographic material 10 a is produced using a printing element 70 .
  • the printing element 70 may be provided with a smooth surface or a rough surface. When the printing element 70 is provided with a smooth surface, the need to produce the holographic image on a substrate having a smooth surface, such as required by the prior art methods, is substantially eliminated.
  • the printing element 70 for producing the holographic material 10 a by the batch process 68 may be a plate, a platen press and the like.
  • the printing element 70 may be constructed of any suitable material capable of having a polished, substantially smooth surface and which is capable of having the holographic image formed thereon for transfer to a desired substrate.
  • the printing element 70 may be constructed of chrome, stainless steel, tool steel and the like.
  • the printing element 70 may also be constructed in part of a resilient or non-resilient material such that the printing element 70 is provided with a resilient or non-resilient surface.
  • the printing element 70 illustrated in FIG. 5 is a flat plate 72 having a smooth surface 74 , the flat plate 72 permitting the holographic material 10 a to be produced in the batch process 68 .
  • a coating 30 a which is substantially identical to the coating 30 as described hereinbefore, is applied to the smooth surface 74 of the flat plate 72 by a coating assembly 76 , thereby providing a coated surface 78 of the flat plate 72 .
  • the coating assembly 76 is illustrated as a coating brush 80 .
  • other methods of applying the coating 30 a to the smooth surface 74 of the flat plate 72 may be employed, such as spraying, dipping, and the like.
  • the coated surface 78 of the flat plate 72 is then embossed by an embossing element 82 , such as an embossing plate 84 shown in FIG. 6. Embossing of the coated surface 78 of the flat plate 72 provides a holographic image 14 a on the coated surface 78 of the flat plate 72 .
  • the holographic image 14 a is provided with a first surface 44 a and a second surface 46 a which is substantially adjacent the smooth surface 74 of the flat plate 72 .
  • the coating 30 a used to provide the coated surface 78 of the flat plate 72 is formed of a non-metallic material, a metallic constituent or component is applied to the embossed coated surface 78 of the flat plate 72 to provide the holographic image 14 a .
  • This process is substantially identical to the metalizing of the embossed coated surface 34 of the cylindrical drum 20 by a metalizing constituent or component 50 to provide the holographic image 10 as described in detail above.
  • a bonding material 54 a which is substantially identical to the bonding material 54 as described hereinbefore, is applied to the holographic image 14 a by a bonding material applicator 86 , as shown in FIG. 7. It will be understood that other methods of applying the bonding material 54 a to the holographic image 14 a on the flat plate 72 may be employed, such as spraying, brushing, etc.
  • the bonding material 54 a applied to the holographic image 14 a is contacted with the substrate 12 a , thereby bondingly connecting the holographic image 14 a to the substrate 12 a and producing the holographic material 10 a (FIG. 8).
  • holographic image 14 a to the substrate 12 a and to transfer the holographic image 14 a from the smooth surface 74 of the flat plate 72 to the substrate 12 a
  • various methods may be employed. For example, heat and/or pressure may be applied to effect the seal between the substrate 12 a and the holographic image 14 a .
  • the holographic image 14 a and the substrate 12 a may be sandwiched between the flat plate 72 and a sealing plate 88 to effect a seal between the substrate 12 a and the holographic image 14 a .
  • the sealing plate 88 may be heated to aid in effecting the seal between the holographic image 14 a and the substrate 12 a.
  • the holographic material 10 a is then removed from the smooth surface 74 of the flat plate 72 .
  • Methods of removing the holographic material 10 a from the flat plate 72 are known in the art.
  • the holographic material 10 a produced by the batch process 68 may be present in different forms such as a roll or sheets of holographic material 10 a.
  • holographic material 10 for providing decorative covers for floral groupings such as cut flowers and potted plants will be described hereinafter. However, it will be understood that the holographic material 10 a may be used in the same manner.
  • the term “floral grouping” as used herein means cut fresh flowers, artificial flowers, a single flower as well as fresh and/or artificial plants or other floral materials, and such term includes other secondary plants and/or ornamentation or artificial or natural materials which add to the aesthetics of the overall floral arrangement.
  • the floral grouping may comprise a bloom (or foliage) portion and a stem portion. However, it will be appreciated that the floral grouping may consist of only a single bloom or only foliage.
  • the term “floral grouping” may be used interchangeably herein with the terms “plant”, “flower” and/or “floral arrangement”.
  • the term “floral grouping” may also be used interchangeably herein with the terms “botanical item” and/or “propagule”.
  • bottle item when used herein means a natural herbaceous or woody plant, taken singly or in combination.
  • the term “botanical item” also means any portion or portions of natural herbaceous or woody plants, taken singly or in combination.
  • the term “botanical item” also means any portion or portions of natural herbaceous or woody plants including stems, leaves, flowers, blossoms, buds, blooms, cones, or roots, taken singly or in combination, or in groupings of such portions such as a bouquet or floral grouping.
  • progenitor when used herein means any structure capable of being propagated or acting as an agent of reproduction including seeds, shoots, stems, runners, tubers, plants, leaves, roots or spores.
  • flower pot refers to any type of container used for holding a floral grouping or a potted plant.
  • Examples of flower pots are clay pots, plastic pots, wooden pots, pots made from natural and/or synthetic fiber, and the like.
  • FIG. 9 Shown in FIG. 9 is the holographic material 10 wrapped about a floral grouping 90 wherein the floral grouping is cut flowers 90 a to provide a decorative cover 92 .
  • the holographic image 14 of the holographic material 10 is readily visible and provides a desired optical effect to the decorative cover 92 .
  • the holographic image 14 constitutes at least a portion of the decor of the decorative cover 92 .
  • the holographic material 10 may also be used to provide a decorative cover 92 a for an object or item, such as the floral grouping 90 wherein the floral grouping is a flower pot or a potted plant 90 b .
  • the decorative cover 92 a illustrated in FIG. 10 is constructed from the holographic material 10 , and the decorative covering 92 a illustrated in FIG. 11 has the potted plant 90 b disposed therein.
  • a flower pot 96 having an outer peripheral surface 98 and a floral grouping retaining space 100 is provided, and the holographic material 10 is formed about the outer peripheral surface 98 of the flower pot 96 to provide the decorative cover 92 a .
  • the potted plant 90 b is then disposed in the floral grouping retaining space 100 of the flower pot 94 provided in the decorative cover 92 a.
  • the holographic material 10 is provided and formed into the decorative cover 92 a prior to disposing the flower pot 96 into the decorative cover 92 a .
  • the decorative cover 92 a formed in this manner has a plurality of overlapping folds which extend at various angles and at various instances.
  • the decorative cover 92 a is also provided with an object opening 102 which is formed through an upper end 104 of the decorative cover 92 a .
  • the object opening 102 is sized to receive the flower pot 96 .
  • the flower pot 96 is disposed in the object opening 102 of the decorative covering 92 so that the decorative covering 92 encompasses a substantial portion of the outer peripheral surface 98 of the flower pot 96 to provide the decorative covering 92 .
  • holographic materials 10 and 10 a will become apparent to one of ordinary skill in the art and include, but not by way of limitation, decorative wrappings for various food and gift items. Thus, uses of the holographic materials 10 and 10 a are not limited to those described herein.

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Abstract

Processes for producing a holographic material involve producing the holographic image on a polished, substantially smooth surface and then transferring the holographic image to a substrate. A metallic coating is applied to a smooth surface of a printing element to provide a coated surface, the coated surface is embossed to provide the holographic image, and the holographic image is transferred to a substrate via a bonding material, thereby producing the holographic material. The holographic material may be used to provide a decorative cover for an object or item, such as a floral grouping or a potted plant.

Description

    CROSS REFERENCE TO RELATED APPLICATIONS
  • Not applicable. [0001]
  • STATEMENT REGARDING FEDERALLY SPONSORED RESEARCH OR DEVELOPMENT
  • Not applicable. [0002]
  • BACKGROUND OF THE INVENTION
  • 1. Field of the Invention [0003]
  • The present invention relates generally to processes for producing decorative material, and more particularly, but not by way of limitation, to processes for producing holographic material. [0004]
  • 2. Brief Description of the Prior Art [0005]
  • Processes for producing holographic materials are well known in the art. One process involves passing a layer of plastic, for example, through a machine which imparts an image within the covering or upper strata of the plastic layer. A powdered metallic constituent or component (e.g. aluminum) is then applied thereon by a metalizing process. After metalizing, a holographic or 3-dimensional image is imparted on the metalized layer of plastic. This image is extremely pleasing and is widely used within the credit card and security industries since the resulting image is difficult to duplicate and thus assists in the prevention of fraud by counterfeiting, for example. However, images produced by this process can be quite expensive since the machines required for production of the images are complicated and costly in and of themselves. Additionally, holographic images produced by this process are usually small in size, and larger holographic images cannot be imprinted by this process. Thus, this process of producing holographic images has not been widely used outside of the credit card and novelty industry. [0006]
  • A process for producing large sheets of holographic material at a lower cost than the process described above involves producing the holographic image laminated to a polymeric support, contacting the holographic image on the polymeric support to a substrate such as tissue paper or foil via an adhesive, and delaminating the polymeric support, thereby transferring the holographic image from the polymeric support to the tissue paper or foil substrate. The image cannot be directly applied to a substrate having a rough surface because the rough surface of the substrate will refract light and will not have a highly reflective finish, thereby disrupting the holographic image. [0007]
  • Therefore, new and improved methods for producing holographic material requiring less time and expense are being sought. It is to such a process for producing holographic material that the present invention is directed. [0008]
  • SUMMARY OF THE INVENTION
  • According to the present invention, processes for producing holographic material are provided which avoid the disadvantages and defects of the prior art, making the processes more economically feasible. Broadly, processes are provided for transferring holographic images to a substrate to produce a holographic material. These processes involve producing the holographic image on a polished, substantially smooth surface and then transferring the holographic image to a substrate, thereby bypassing the need for the polymeric support used in the prior art. [0009]
  • In one aspect of the present invention, a printing element having a polished, substantially smooth surface is provided, and a metallic coating is applied to the smooth surface of the printing element to provide a coated surface. The coated surface is embossed to provide the holographic image on the coating, and the holographic image is then transferred to a substrate, thereby producing a holographic material. [0010]
  • In another aspect of the present invention, a non-metallic coating may be applied to the smooth surface of the printing element to provide a coated surface, which is then embossed to provide an image. The embossed coated surface is then metalized to provide a holographic image on the coating, and the holographic image is transferred to a substrate to produce the holographic material. [0011]
  • The production of holographic materials in accordance with the present invention may be performed as a continuous process or as a batch process. Applications of the holographic materials produced in accordance with the present invention include wrapping a floral grouping and providing a decorative cover for an object such as a flower pot or a potted plant, as well as decorative wrappings for various food and gift items. [0012]
  • An object of the present invention is to provide improved processes for producing holographic materials. [0013]
  • Another object of the present invention, while achieving the before-stated object, is to provide processes for producing holographic materials which do not suffer from the disadvantages of the prior art processes. [0014]
  • Other objects, features and advantages of the present invention will become apparent from the following detailed description when read in conjunction with the accompanying drawings and appended claims.[0015]
  • BRIEF DESCRIPTION OF THE DRAWINGS
  • FIG. 1 is a perspective view illustrating a holographic material produced by a continuous process in accordance with the present invention. [0016]
  • FIG. 2 is a partial schematic representation of a continuous process for producing holographic material utilizing a cylindrical drum. [0017]
  • FIG. 3 is a partial schematic representation of another continuous process for producing holographic material utilizing a cylindrical drum. [0018]
  • FIG. 4 is a side plan view illustrating a holographic material produced by a batch process in accordance with the present invention. [0019]
  • FIG. 5 is a diagrammatic representation of a flat plate used to produce holographic materials in accordance with the present invention, the flat plate having a coating disposed on a surface thereof. [0020]
  • FIG. 6 is a diagrammatic representation of the flat plate with a coated surface of FIG. 5 and an embossing plate for embossing the coated surface of the flat plate to provide an embossed coated surface with a holographic image thereon. [0021]
  • FIG. 7 is a diagrammatic representation of the flat plate of FIG. 6 having an embossed coated surface and a holographic image thereon, the embossed coated surface of the flat plate having an adhesive applied thereto. [0022]
  • FIG. 8 is a diagrammatic representation of the flat plate of FIG. 7 having an embossed coated surface with a holographic image thereon and an adhesive applied thereto, the adhesive bondingly connecting the embossed coated surface to a substrate to produce a holographic material constructed from the coating containing a holographic image and the substrate. [0023]
  • FIG. 9 is a perspective view illustrating a floral grouping wrapped with a sheet of holographic material constructed in accordance with the present invention. [0024]
  • FIG. 10 is a perspective view illustrating a decorative pot cover formed from a holographic material constructed in accordance with the present invention. [0025]
  • FIG. 11 is a perspective view illustrating the decorative pot cover of FIG. 10 wherein the pre-formed pot cover has a potted plant disposed therein.[0026]
  • DETAILED DESCRIPTION OF THE INVENTION
  • Referring now to the drawings, shown in FIG. 1 and designated therein by the [0027] reference numeral 10 is a holographic material constructed in accordance with the present invention by a continuous process. The holographic material 10 comprises a substrate 12 having a holographic design or image 14 formed thereon. The holographic image 14 provides the holographic material 10 with a holographic or 3-dimensional appearance.
  • The term “holographic image” as used herein is to be understood to mean a three-dimensional image most visible from an oblique angle. The unique properties of holographic images are that they appear to float in space, are true-to-life and can change perspective, that is, permit one to look around corners and watch hidden features of the image come to light. [0028]
  • Further, the “holographic image” can be in any geometric form, or any combination of geometric forms, for example, squares, round spots, triangles, rectangles, octagonals, or the like, or any non-geometric, asymmetrical or fanciful forms, or any combination thereof, for example, but not by way of limitation, hearts, balloons, flowers, lace, slogans, logos, print (any combination of letters and/or numbers), signs, human forms (real and fictional), animal forms (real and fictional), cartoon characters, and/or plant forms. Such holographic images may include a color, or a portion of a color, or a combination of colors and designs. Alternatively, at least a portion of the holographic image may be colorless, translucent, transparent, opaque, pearlescent, iridescent, or the like. [0029]
  • The term “substrate” when used herein means a sheet of material which provides stability to the [0030] holographic image 14. The substrate 12 of the holographic material 10 may be flexible or non-flexible. The substrate 12 can be constructed of any suitable material capable of receiving a holographic image, such as polymeric film, non-polymeric film, foil, paper, tissue and combinations thereof. The substrate 12 includes a surface 16 which may be substantially rough and textured or substantially smooth. For example, tissue paper, kraft paper and high density polyethylene film often have rough surfaces, while foil and chromecoat paper typically have smooth surfaces.
  • The thickness of the [0031] substrate 12 can vary widely. Generally, however, the substrate 12 has a thickness in a range from about 0.0002 mil to about 30 mils, and more desirably from about 0.1 mil to about 20 mils.
  • Referring now to FIGS. 2 and 3, a [0032] continuous process 17 for producing the holographic material 10 is schematically illustrated. As will be more fully described hereinafter, the holographic material 10 is produced using a printing element 18. The printing element 18 may be provided with a smooth surface or a rough surface. When the printing element 18 is provided with a smooth surface, the need to produce the holographic image on a substrate having a smooth surface, such as required by the prior art methods, is substantially eliminated.
  • The term “printing element” as used herein means any element having a surface capable of having a holographic image produced thereon whereby the holographic image can be transferred to a substrate without substantially distorting the holographic image. Thus, the [0033] printing element 18 for producing the holographic material 10 by a continuous process 17 may be, for example, but not limited to, a cylindrical drum, a roller and the like. The printing element 18 may be constructed of any suitable material capable of having a polished, substantially smooth surface and which is capable of having the holographic image formed thereon for transfer to a desired substrate. The printing element 18 may be constructed of chrome, stainless steel, tool steel and the like. The printing element 18 may also be constructed in part of a resilient or non-resilient material such that the printing element 18 is provided with a resilient or non-resilient surface.
  • The [0034] printing element 18 illustrated in FIGS. 2 and 3 is a cylindrical drum 20 having a smooth surface 22. The cylindrical drum 20 permits the holographic material 10 to be continuously produced. A coating 30 capable of receiving a holographic image is applied to the smooth surface 22 of the cylindrical drum 20 by a coating assembly 32, thereby providing a coated surface 34 of the cylindrical drum 20. The coating assembly 32 is illustrated as comprising a coating pan 36 and a reverse gravure doctor blade 38. The thickness of the coating 30 on the coated surface 34 of the cylindrical drum 20 can be controlled and maintained within preselected limits by the reverse gravure doctor blade 38 of the coating assembly 32.
  • It will be understood that other methods of applying the [0035] coating 30 to the smooth surface 22 of the cylindrical drum 20 may be employed, such as spraying, brushing, etc.
  • The term “coating” as used herein is to be understood to mean a maleable film which is able to be embossed to receive a holographic image on at least a portion thereof. For example, the [0036] coating 30 may be a metallic material such as metallic polymeric film, metallic non-polymeric film, foil, metalized lacquer and combinations thereof. The coating 30 may also be a nonmetallic material such as polymeric film, non-polymeric film, foil, lacquer and combinations thereof. Wherein the coating 30 is a nonmetallic material, the process for producing the holographic material 10 in accordance with the present invention includes an additional step of metalizing the coated surface 34 of the cylindrical drum 20, which will be described in detail below.
  • The term “lacquer” as used herein means a coating substance consisting of resinous materials, such as cellulose esters, cellulose ethers, shellac, gum, alkyd resins and the like, which are dissolved in a solvent that evaporates rapidly on application such as ethyl alcohol, thereby leaving a tough, adherent film. Lacquers which are useful in the present invention are mixtures, such as, but not limited to, lacquers produced by mixing styrene-acrylic emulsions, such as Lucidene 603 and Lucidene 395 (Morton International, Inc., 100 North Riverside Plaza, Chicago, Ill. 60606) with a non-ionic surfactant, such as Surfynol 465 (Air Products and Chemicals, Inc., 7201 Hamilton Boulevard, Allentown, Pa. 18195-1501) and ammonia (G. S. Robbins and Company, 126 Chouteau Avenue, St. Louis, Mo. 63102). The lacquer produced as described above may also contain a wax emulsion in water, such as Liquitron 440 (Carrol Scientific, Inc., 5401 S. Dansher Road, Countryside, Ill. 60525). [0037]
  • The coated [0038] surface 34 of the cylindrical drum 20 is then embossed by an embossing element 40, such as an embossing drum 42. Embossing elements are used to produce materials to decorate or cover articles by depressing, carving, raising, or printing designs, patterns, etc. so that at least a portion of the design, pattern, etc. is raised above the surface of the material. Embossing elements are well known in the art; thus, no further discussion of embossing methods need be required.
  • Embossing of the [0039] coated surface 34 of the cylindrical drum 20 produces a holographic image 14 on the coated surface 34 of the cylindrical drum 20. The holographic image 14 is provided with a first surface 44 and a second surface 46 which is substantially adjacent the smooth surface 22 of the cylindrical drum 20.
  • As shown in FIG. 3, if the [0040] coating 30 used to provide the coated surface 34 of the cylindrical drum 20 is formed of a non-metallic material, a metallic constituent or component 48 is applied to the embossed coated surface 34 of the cylindrical drum 20 to provide the holographic image 14. The metallic constituent or component 48 can be applied to the embossed coated surface 34 of the cylindrical drum 20 by any suitable means, such as by discharging the metallic constituent or component 48 from a reservoir 50. Metallic constituents or components which may be employed to metallize the embossed coated surface 34 of the cylindrical drum 20 are known in the art and include powdered metals such as powdered aluminum.
  • Once the holographic image has been produced, a [0041] bonding material 54 is applied to the holographic image 14 by a bonding material applicator 56. The bonding material applicator 56 comprises a pan 58 and a reverse gravure doctor blade 60 for removing excess bonding material 54 and controlling the thickness of the bonding material 54 so as to insure a substantially uniform coating of bonding material 54 on the holographic image 14 present on the cylindrical drum 20. The bonding material 54 applied to the holographic image 14 is contacted with the substrate 12, thereby bondingly contacting the holographic image 14 to the substrate 12 and producing the holographic material 10.
  • The term “bonding material” when used herein may be an adhesive, such as a pressure sensitive adhesive, or a cohesive. Where the bonding material is a cohesive, a similar cohesive material must be placed on the adjacent surface for bondingly contacting and bondingly engaging with the cohesive material. The term “bonding material” may also be materials which are heat sealable and, in this instance, the adjacent portions of the materials must be brought into contact and then heat must be applied to effect the seal. The term “bonding material” when used herein also means a lacquer, which may be the [0042] coating 30 described above. In this instance, heat, sound waves, or vibrations may be applied to effect the sealing of the lacquer. In this way, the coating 30 may both receive the holographic image 14 and effect sealing of the holographic image 14 to the substrate 12, thereby producing the holographic material 10.
  • To bondingly secure the [0043] holographic image 14 to the substrate 12 and to transfer the holographic image 14 from the smooth surface 22 of the cylindrical drum 20 to the substrate 12, various methods may be employed. For example, heat and/or pressure may be applied to effect the seal between the holographic image 14 and the substrate 12. As shown in FIGS. 2 and 3, a nip formed by opposing rollers of the cylindrical drum 20 and a sealing drum 62 may sandwich the holographic image 14 and the substrate 12 to effect a seal between the substrate 12 and the holographic image 14. In addition, the sealing drum 62 may be a heated roller to aid in effecting the seal between the holographic image 14 and the substrate 12.
  • It will be understood that other methods of bondingly securing and sealing the [0044] holographic image 14 and the substrate 12 in the continuous process 17 of producing the holographic material 10 as described herein may be employed in this process, and is not limited to the method described herein.
  • The [0045] holographic material 10 is then removed from the smooth surface 22 of the cylindrical drum 20. Methods of removing the holographic material 10 from the cylindrical drum 20 are known in the art. The holographic material 10 produced by the continuous process 17 may be present in different forms such as a roll or sheets of holographic material 10.
  • Shown in FIG. 4 is a [0046] holographic material 10 a constructed in accordance with the present invention by a batch process 68. The holographic material 10 a is similar to the holographic material 10 described hereinbefore, and comprises a substrate 12 a having a holographic image 14 a formed thereon. The batch process 68 for producing the holographic material 10 a is illustrated in FIGS. 5, 6, 7 and 8 and described in detail hereinafter.
  • The [0047] holographic material 10 a is produced using a printing element 70. The printing element 70 may be provided with a smooth surface or a rough surface. When the printing element 70 is provided with a smooth surface, the need to produce the holographic image on a substrate having a smooth surface, such as required by the prior art methods, is substantially eliminated. The printing element 70 for producing the holographic material 10 a by the batch process 68 may be a plate, a platen press and the like. The printing element 70 may be constructed of any suitable material capable of having a polished, substantially smooth surface and which is capable of having the holographic image formed thereon for transfer to a desired substrate. The printing element 70 may be constructed of chrome, stainless steel, tool steel and the like. The printing element 70 may also be constructed in part of a resilient or non-resilient material such that the printing element 70 is provided with a resilient or non-resilient surface. The printing element 70 illustrated in FIG. 5 is a flat plate 72 having a smooth surface 74, the flat plate 72 permitting the holographic material 10 a to be produced in the batch process 68. A coating 30 a, which is substantially identical to the coating 30 as described hereinbefore, is applied to the smooth surface 74 of the flat plate 72 by a coating assembly 76, thereby providing a coated surface 78 of the flat plate 72. The coating assembly 76 is illustrated as a coating brush 80. However, it should be understood that other methods of applying the coating 30 a to the smooth surface 74 of the flat plate 72 may be employed, such as spraying, dipping, and the like.
  • The coated [0048] surface 78 of the flat plate 72 is then embossed by an embossing element 82, such as an embossing plate 84 shown in FIG. 6. Embossing of the coated surface 78 of the flat plate 72 provides a holographic image 14 a on the coated surface 78 of the flat plate 72. The holographic image 14 a is provided with a first surface 44 a and a second surface 46 a which is substantially adjacent the smooth surface 74 of the flat plate 72.
  • If the [0049] coating 30 a used to provide the coated surface 78 of the flat plate 72 is formed of a non-metallic material, a metallic constituent or component is applied to the embossed coated surface 78 of the flat plate 72 to provide the holographic image 14 a. This process is substantially identical to the metalizing of the embossed coated surface 34 of the cylindrical drum 20 by a metalizing constituent or component 50 to provide the holographic image 10 as described in detail above.
  • Once the [0050] holographic image 14 a has been produced, a bonding material 54 a, which is substantially identical to the bonding material 54 as described hereinbefore, is applied to the holographic image 14 a by a bonding material applicator 86, as shown in FIG. 7. It will be understood that other methods of applying the bonding material 54 a to the holographic image 14 a on the flat plate 72 may be employed, such as spraying, brushing, etc.
  • The [0051] bonding material 54 a applied to the holographic image 14 a is contacted with the substrate 12 a, thereby bondingly connecting the holographic image 14 a to the substrate 12 a and producing the holographic material 10 a (FIG. 8).
  • To bondingly connect the [0052] holographic image 14 a to the substrate 12 a and to transfer the holographic image 14 a from the smooth surface 74 of the flat plate 72 to the substrate 12 a, various methods may be employed. For example, heat and/or pressure may be applied to effect the seal between the substrate 12 a and the holographic image 14 a. As shown in FIG. 8, the holographic image 14 a and the substrate 12 a may be sandwiched between the flat plate 72 and a sealing plate 88 to effect a seal between the substrate 12 a and the holographic image 14 a. In addition, the sealing plate 88 may be heated to aid in effecting the seal between the holographic image 14 a and the substrate 12 a.
  • It will be understood that other methods of bondingly connecting and sealing the [0053] holographic image 14 a and the substrate 12 a in the batch process 68 for producing the holographic material 10 a as described herein may be employed.
  • The [0054] holographic material 10 a is then removed from the smooth surface 74 of the flat plate 72. Methods of removing the holographic material 10 a from the flat plate 72 are known in the art. The holographic material 10 a produced by the batch process 68 may be present in different forms such as a roll or sheets of holographic material 10 a.
  • For the sake of brevity, only the use of the [0055] holographic material 10 for providing decorative covers for floral groupings such as cut flowers and potted plants will be described hereinafter. However, it will be understood that the holographic material 10 a may be used in the same manner.
  • The term “floral grouping” as used herein means cut fresh flowers, artificial flowers, a single flower as well as fresh and/or artificial plants or other floral materials, and such term includes other secondary plants and/or ornamentation or artificial or natural materials which add to the aesthetics of the overall floral arrangement. The floral grouping may comprise a bloom (or foliage) portion and a stem portion. However, it will be appreciated that the floral grouping may consist of only a single bloom or only foliage. The term “floral grouping” may be used interchangeably herein with the terms “plant”, “flower” and/or “floral arrangement”. The term “floral grouping” may also be used interchangeably herein with the terms “botanical item” and/or “propagule”. [0056]
  • The term “botanical item” when used herein means a natural herbaceous or woody plant, taken singly or in combination. The term “botanical item” also means any portion or portions of natural herbaceous or woody plants, taken singly or in combination. The term “botanical item” also means any portion or portions of natural herbaceous or woody plants including stems, leaves, flowers, blossoms, buds, blooms, cones, or roots, taken singly or in combination, or in groupings of such portions such as a bouquet or floral grouping. [0057]
  • The term “propagule” when used herein means any structure capable of being propagated or acting as an agent of reproduction including seeds, shoots, stems, runners, tubers, plants, leaves, roots or spores. [0058]
  • The term “flower pot” refers to any type of container used for holding a floral grouping or a potted plant. Examples of flower pots are clay pots, plastic pots, wooden pots, pots made from natural and/or synthetic fiber, and the like. [0059]
  • Shown in FIG. 9 is the [0060] holographic material 10 wrapped about a floral grouping 90 wherein the floral grouping is cut flowers 90 a to provide a decorative cover 92. In this way, the holographic image 14 of the holographic material 10 is readily visible and provides a desired optical effect to the decorative cover 92. Thus, the holographic image 14 constitutes at least a portion of the decor of the decorative cover 92.
  • The [0061] holographic material 10 may also be used to provide a decorative cover 92 a for an object or item, such as the floral grouping 90 wherein the floral grouping is a flower pot or a potted plant 90 b. The decorative cover 92 a illustrated in FIG. 10 is constructed from the holographic material 10, and the decorative covering 92 a illustrated in FIG. 11 has the potted plant 90 b disposed therein.
  • A [0062] flower pot 96 having an outer peripheral surface 98 and a floral grouping retaining space 100 is provided, and the holographic material 10 is formed about the outer peripheral surface 98 of the flower pot 96 to provide the decorative cover 92 a. The potted plant 90 b is then disposed in the floral grouping retaining space 100 of the flower pot 94 provided in the decorative cover 92 a.
  • In another method of providing the [0063] decorative cover 92 a for the flower pot 96, the holographic material 10 is provided and formed into the decorative cover 92 a prior to disposing the flower pot 96 into the decorative cover 92 a. The decorative cover 92 a formed in this manner has a plurality of overlapping folds which extend at various angles and at various instances. The decorative cover 92 a is also provided with an object opening 102 which is formed through an upper end 104 of the decorative cover 92 a. The object opening 102 is sized to receive the flower pot 96.
  • The system for forming the [0064] decorative cover 92 a by this method is described in detail in U.S. Pat. No. 4,772,182, entitled, “Article Forming System”, issued Sep. 27, 1988, which is hereby expressly incorporated herein by reference.
  • Once the [0065] decorative covering 92 is constructed, the flower pot 96 is disposed in the object opening 102 of the decorative covering 92 so that the decorative covering 92 encompasses a substantial portion of the outer peripheral surface 98 of the flower pot 96 to provide the decorative covering 92.
  • Now it will be understood that other applications of the [0066] holographic materials 10 and 10 a will become apparent to one of ordinary skill in the art and include, but not by way of limitation, decorative wrappings for various food and gift items. Thus, uses of the holographic materials 10 and 10 a are not limited to those described herein.
  • From the above description, it is clear that the present invention is well adapted to carry out the objects and to attain the advantages mentioned herein as well as those inherent in the invention. While presently preferred embodiments of the invention have been described for purposes of this disclosure, it will be understood that numerous changes may be made which will readily suggest themselves to those skilled in the art and which are accomplished within the spirit of the invention disclosed and as defined in the appended claims. [0067]

Claims (84)

What is claimed is:
1. A process for applying a holographic image to a substrate to produce a holographic material, the process comprising:
providing a printing element having a polished, substantially smooth surface;
applying a metalized coating capable of receiving a holographic image to the smooth surface of the printing element to provide a metalized coated surface;
embossing the metalized coated surface to provide a holographic image thereon, the holographic image having a first surface and a second surface wherein the second surface of the holographic image is disposed substantially adjacent the smooth surface of the printing element;
applying a bonding material to the first surface of the holographic image;
disposing a substrate adjacent the first surface of the holographic image containing the bonding material so as to transfer the holographic image to the substrate and produce a holographic material; and
removing the holographic material from the smooth surface of the printing element.
2. The process of claim 1 wherein the process is preformed as a continuous process.
3. The process of claim 2 wherein the printing element is selected from the group consisting of a cylindrical drum and a roller.
4. The process of claim 2 wherein the printing element is constructed of a material selected from the group consisting of chrome, stainless steel and tool steel.
5. The process of claim 2 wherein the surface of the printing element is resilient.
6. The process of claim 2 wherein the surface of the printing element is non-resilient.
7. The process of claim 1 wherein the process is performed as a batch process.
8. The process of claim 7 wherein the printing element is selected from the group consisting of a flat plate and a platen press.
9. The process of claim 7 wherein the printing element is constructed of a material selected from the group consisting of chrome, stainless steel and tool steel.
10. The process of claim 7 wherein the surface of the printing element is resilient.
11. The process of claim 7 wherein the surface of the printing element is non-resilient.
12. The process of claim 1 wherein the coating applied to the smooth surface of the printing element is selected from the group consisting of metallic polymeric film, metallic non-polymeric film, foil, metalized lacquer and combinations thereof.
13. The process of claim 1 wherein the substrate is constructed of a material selected from the group consisting of polymeric film, non-polymeric film, foil, paper, tissue and combinations thereof.
14. The process of claim 13 wherein the substrate has a substantially rough, textured surface.
15. The process of claim 13 wherein the substrate has a substantially smooth surface.
16. A process for applying a holographic image to a substrate to produce a holographic material, the process comprising:
providing a printing element having a polished, substantially smooth surface;
applying a coating capable of receiving a holographic image to the smooth surface of the printing element to provide a coated surface;
embossing the coated surface to provide an image on the coating;
applying a metallic constituent or component to the image to provide a holographic image having a first surface and a second surface wherein the second surface of the holographic image is disposed substantially adjacent the smooth surface of the printing element;
applying a bonding material to the first surface of the holographic image;
disposing a substrate adjacent the first surface of the holographic image containing the bonding material so as to transfer the holographic image to the substrate and produce a holographic material; and
removing the holographic material from the smooth surface of the printing element.
17. The process of claim 16 wherein the process is a continuous process.
18. The process of claim 17 wherein the printing element is selected from the group consisting of a cylindrical drum and a roller.
19. The process of claim 17 wherein the printing element is constructed of a material selected from the group consisting of chrome, stainless steel and tool steel.
20. The process of claim 17 wherein the surface of the printing element is resilient.
21. The process of claim 17 wherein the surface of the printing element is non-resilient.
22. The process of claim 16 wherein the process is a batch process.
23. The process of claim 22 wherein the printing element is selected from the group consisting of a flat plate and a platen press.
24. The process of claim 22 wherein the printing element is constructed of a material selected from the group consisting of chrome, stainless steel and tool steel.
25. The process of claim 22 wherein the surface of the printing element is resilient.
26. The process of claim 22 wherein the surface of the printing element is non-resilient.
27. The process of claim 16 wherein the coating is selected from the group consisting of polymeric film, non-polymeric film, foil, lacquer and combinations thereof.
28. The process of claim 16 wherein the substrate is selected from the group consisting of polymeric film, non-polymeric film, foil, paper, tissue and combinations thereof.
29. The process of claim 28 wherein the substrate has a substantially rough, textured surface.
30. The process of claim 28 wherein the substrate has a substantially smooth surface.
31. A method for providing a decorative cover for a floral grouping comprising:
providing a holographic material produced by applying a holographic image to a substrate, the process comprising:
providing a printing element having a polished, substantially smooth surface,
applying a metalized coating capable of receiving a holographic image to the smooth surface of the printing element to provide a metalized coated surface,
embossing the metalized coated surface to provide a holographic image thereon, the holographic image having a first surface and a second surface wherein the second surface of the holographic image is disposed substantially adjacent the smooth surface of the printing element,
applying a bonding material to the first surface of the holographic image,
disposing a substrate adjacent the first surface of the holographic image containing the bonding material so as to transfer the holographic image to the substrate and produce a holographic material, and
removing the holographic material from the smooth surface of the printing element; and
wrapping the holographic material about a floral grouping to provide the decorative cover.
32. The method of claim 31 wherein in the step of providing a holographic material, the printing element is selected from the group consisting of a cylindrical drum, a roller, a flat plate and a platen press.
33. The method of claim 32 wherein the printing element is constructed of a material selected from the group consisting of chrome, stainless steel and tool steel.
34. The method of claim 32 wherein the surface of the printing element is resilient.
35. The method of claim 32 wherein the surface of the printing element is non-resilient.
36. The method of claim 31 wherein in the step of providing a holographic material, the coating applied to the smooth surface of the printing element is selected from the group consisting of metallic polymeric film, metallic non-polymeric film, foil, metalized lacquer and combinations thereof.
37. The method of claim 31 wherein in the step of providing a holographic material, the substrate is constructed of a material selected from the group consisting of polymeric film, non-polymeric film, foil, paper, tissue and combinations thereof.
38. The method of claim 37 wherein the substrate has a substantially rough, textured surface.
39. The method of claim 37 wherein the substrate has a substantially smooth surface.
40. A method for providing a decorative cover for a floral grouping comprising:
providing a holographic material produced by applying a holographic image to a substrate, the process comprising:
providing a printing element having a polished, substantially smooth surface,
applying a coating capable of receiving a holographic image to the smooth surface of the printing element to provide a coated surface,
embossing the coated surface to provide an image on the coating,
applying a metallic constituent or component to the image to provide a holographic image having a first surface and a second surface wherein the second surface of the holographic image is disposed substantially adjacent the smooth surface of the printing element,
applying a bonding material to the first surface of the holographic image,
disposing a substrate adjacent the first surface of the holographic image containing the bonding material so as to transfer the holographic image to the substrate and produce a holographic material, and
removing the holographic material from the smooth surface of the printing element; and
wrapping the holographic material about a floral grouping to provide the decorative cover.
41. The method of claim 40 wherein in the step of providing a holographic material, the printing element is selected from the group consisting of a cylindrical drum, a roller, a flat plate and a platen press.
42. The method of claim 41 wherein the printing element is constructed of a material selected from the group consisting of chrome, stainless steel and tool steel.
43. The method of claim 41 wherein the surface of the printing element is resilient.
44. The method of claim 41 wherein the surface of the printing element is non-resilient.
45. The method of claim 40 wherein in the step of providing a holographic material, the coating is selected from the group consisting of polymeric film, non-polymeric film, foil, lacquer and combinations thereof.
46. The method of claim 40 wherein in the step of providing a holographic material, the substrate is selected from the group consisting of polymeric film, non-polymeric film, foil, paper, tissue and combinations thereof.
47. The method of claim 46 wherein the substrate has a substantially rough, textured surface.
48. The method of claim 46 wherein the substrate has a substantially smooth surface.
49. A method for providing a decorative cover for a flower pot comprising:
providing a holographic material produced by applying a holographic image to a substrate, the process comprising:
providing a printing element having a polished, substantially smooth surface,
applying a metalized coating capable of receiving a holographic image to the smooth surface of the printing element to provide a metalized coated surface,
embossing the metalized coated surface to provide a holographic image thereon, the holographic image having a first surface and a second surface wherein the second surface of the holographic image is disposed substantially adjacent the smooth surface of the printing element,
applying a bonding material to the first surface of the holographic image,
disposing a substrate adjacent the first surface of the holographic image containing the bonding material so as to transfer the holographic image to the substrate and produce a holographic material, and
removing the holographic material from the smooth surface of the printing element;
providing a flower pot having an outer peripheral surface; and
forming the holographic material about the outer peripheral surface of the flower pot to provide the decorative cover.
50. The method of claim 49 wherein in the step of providing a holographic material, the printing element is selected from the group consisting of a cylindrical drum, a roller, a flat plate and a platen press.
51. The method of claim 50 wherein the printing element is constructed of a material selected from the group consisting of chrome, stainless steel and tool steel.
52. The method of claim 50 wherein the surface of the printing element is resilient.
53. The method of claim 50 wherein the surface of the printing element is non-resilient.
54. The method of claim 49 wherein in the step of providing a holographic material, the coating applied to the smooth surface of the printing element is selected from the group consisting of metallic polymeric film, metallic non-polymeric film, foil, metalized lacquer and combinations thereof.
55. The method of claim 49 wherein in the step of providing a holographic material, the substrate is constructed of a material selected from the group consisting of polymeric film, non-polymeric film, foil, paper, tissue and combinations thereof.
56. The method of claim 55 wherein the substrate has a substantially rough, textured surface.
57. The method of claim 55 wherein the substrate has a substantially smooth surface.
58. A method for providing a decorative cover for a flower pot comprising:
providing a holographic material produced by applying a holographic image to a substrate, the process comprising:
providing a printing element having a polished, substantially smooth surface,
applying a coating capable of receiving a holographic image to the smooth surface of the printing element to provide a coated surface,
embossing the coated surface to provide an image on the coating,
applying a metallic constituent or component to the image to provide a holographic image having a first surface and a second surface wherein the second surface of the holographic image is disposed substantially adjacent the smooth surface of the printing element,
applying a bonding material to the first surface of the holographic image,
disposing a substrate adjacent the first surface of the holographic image containing the bonding material so as to transfer the holographic image to the substrate and produce a holographic material, and
removing the holographic material from the smooth surface of the printing element;
providing a flower pot having an outer peripheral surface; and
forming the holographic material about the outer peripheral surface of the flower pot to provide the decorative cover.
59. The method of claim 58 wherein in the step of providing a holographic material, the printing element is selected from the group consisting of a cylindrical drum, a roller, a flat plate and a platen press.
60. The method of claim 59 wherein the printing element is constructed of a material selected from the group consisting of chrome, stainless steel and tool steel.
61. The method of claim 59 wherein the surface of the printing element is resilient.
62. The method of claim 59 wherein the surface of the printing element is non-resilient.
63. The method of claim 58 wherein in the step of providing a holographic material, the coating is selected from the group consisting of polymeric film, non-polymeric film, foil, lacquer and combinations thereof.
64. The method of claim 58 wherein in the step of providing a holographic material, the substrate is selected from the group consisting of polymeric film, non-polymeric film, foil, paper, tissue and combinations thereof.
65. The method of claim 64 wherein the substrate has a substantially rough, textured surface.
66. The method of claim 64 wherein the substrate has a substantially smooth surface.
67. A method for providing a decorative cover for a flower pot comprising:
providing a holographic material produced by applying a holographic image to a substrate, the process comprising:
providing a printing element having a polished, substantially smooth surface,
applying a metalized coating capable of receiving a holographic image to the smooth surface of the printing element to provide a metalized coated surface,
embossing the metalized coated surface to provide a holographic image thereon, the holographic image having a first surface and a second surface wherein the second surface of the holographic image is disposed substantially adjacent the smooth surface of the printing element,
applying a bonding material to the first surface of the holographic image,
disposing a substrate adjacent the first surface of the holographic image containing the bonding material so as to transfer the holographic image to the substrate and produce a holographic material, and
removing the holographic material from the smooth surface of the printing element;
forming the holographic material into a decorative cover having a plurality of overlapping folds therein wherein the overlapping folds extend at various angles and at
various instances, the decorative cover having an object opening formed through an upper end thereof sized to receive a flower pot;
providing a flower pot having an outer peripheral surface; and
disposing the flower pot in the object opening of the decorative cover with the decorative cover encompassing a substantial portion of the outer peripheral surface of the flower pot.
68. The method of claim 67 wherein in the step of providing a holographic material, the printing element is selected from the group consisting of a cylindrical drum, a roller, a flat plate and a platen press.
69. The method of claim 68 wherein the printing element is constructed of a material selected from the group consisting of chrome, stainless steel and tool steel.
70. The method of claim 68 wherein the surface of the printing element is resilient.
71. The method of claim 68 wherein the surface of the printing element is non-resilient.
72. The method of claim 67 wherein in the step of providing a holographic material, the coating applied to the smooth surface of the printing element is selected from the group consisting of metallic polymeric film, metallic non-polymeric film, foil, metalized lacquer and combinations thereof.
73. The method of claim 67 wherein in the step of providing a holographic material, the substrate is constructed of a material selected from the group consisting of polymeric film, non-polymeric film, foil, paper, tissue and combinations thereof.
74. The method of claim 73 wherein the substrate has a substantially rough, textured surface.
75. The method of claim 73 wherein the substrate has a substantially smooth surface.
76. A method for providing a decorative cover for a flower pot comprising:
providing a holographic material produced by applying a holographic image to a substrate, the process comprising:
providing a printing element having a polished, substantially smooth surface,
applying a coating capable of receiving a holographic image to the smooth surface of the printing element to provide a coated surface,
embossing the coated surface to provide an image on the coating,
applying a metallic constituent or component to the image to provide a holographic image having a first surface and a second surface wherein the second surface of the holographic image is disposed substantially adjacent the smooth surface of the printing element,
applying a bonding material to the first surface of the holographic image,
disposing a substrate adjacent the first surface of the holographic image containing the bonding material so as to transfer the holographic image to the substrate and produce a holographic material, and
removing the holographic material from the smooth surface of the printing element;
forming the holographic material into a decorative cover having a plurality of overlapping folds therein wherein the overlapping folds extend at various angles and at various instances, the decorative cover having an object opening formed through an upper end thereof sized to receive a flower pot;
providing a flower pot having an outer peripheral surface; and
disposing the flower pot in the object opening of the decorative cover with the decorative cover encompassing a substantial portion of the outer peripheral surface of the flower pot.
77. The method of claim 76 wherein in the step of providing a holographic material, the printing element is selected from the group consisting of a cylindrical drum, a roller, a flat plate and a platen press.
78. The method of claim 77 wherein the printing element is constructed of a material selected from the group consisting of chrome, stainless steel and tool steel.
79. The method of claim 77 wherein the surface of the printing element is resilient.
80. The method of claim 77 wherein the surface of the printing element is non-resilient.
81. The method of claim 76 wherein in the step of providing a holographic material, the coating is selected from the group consisting of polymeric film, non-polymeric film, foil, lacquer and combinations thereof.
82. The method of claim 76 wherein in the step of providing a holographic material, the substrate is selected from the group consisting of polymeric film, non-polymeric film, foil, paper, tissue and combinations thereof.
83. The method of claim 82 wherein the substrate has a substantially rough, textured surface.
84. The method of claim 82 wherein the substrate has a substantially smooth surface.
US09/971,262 1995-06-07 2001-10-04 Process for producing holographic material Abandoned US20030029550A1 (en)

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US09/971,262 US20030029550A1 (en) 1999-08-11 2001-10-04 Process for producing holographic material
US10/617,283 US20040062997A1 (en) 1995-06-07 2003-07-10 Method for providing a decorative cover formed of holographic material

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US09/372,526 US6372073B1 (en) 1999-08-11 1999-08-11 Process for producing holographic material
US09/971,262 US20030029550A1 (en) 1999-08-11 2001-10-04 Process for producing holographic material

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US09/372,526 Expired - Fee Related US6372073B1 (en) 1995-06-07 1999-08-11 Process for producing holographic material
US09/584,553 Expired - Fee Related US6896755B1 (en) 1999-08-11 2000-05-31 Process for producing holographic material
US09/632,616 Expired - Fee Related US6461463B1 (en) 1999-08-11 2000-08-08 Process for producing holographic material
US09/971,262 Abandoned US20030029550A1 (en) 1995-06-07 2001-10-04 Process for producing holographic material
US09/970,745 Abandoned US20030029549A1 (en) 1999-08-11 2001-10-04 Process for producing holographic material
US09/970,731 Abandoned US20030024631A1 (en) 1995-06-07 2001-10-04 Process for producing holographic material
US09/971,324 Abandoned US20030029551A1 (en) 1995-06-07 2001-10-04 Process for producing holographic material
US09/970,744 Abandoned US20030029554A1 (en) 1995-06-07 2001-10-04 Process for producing holographic material
US10/209,631 Abandoned US20020192568A1 (en) 1999-08-11 2002-07-30 Process for producing holographic material
US10/209,557 Abandoned US20020179231A1 (en) 1999-08-11 2002-07-30 Process for producing holographic material
US10/615,699 Abandoned US20040011455A1 (en) 1995-06-07 2003-07-09 Method for providing a decorative cover formed of holographic material
US10/616,877 Abandoned US20040007316A1 (en) 1995-06-07 2003-07-10 Process for producing holographic material
US10/616,886 Abandoned US20040065405A1 (en) 1995-06-07 2003-07-10 Method for providing a decorative cover formed of holographic material
US10/617,283 Abandoned US20040062997A1 (en) 1995-06-07 2003-07-10 Method for providing a decorative cover formed of holographic material

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US09/584,553 Expired - Fee Related US6896755B1 (en) 1999-08-11 2000-05-31 Process for producing holographic material
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US09/970,745 Abandoned US20030029549A1 (en) 1999-08-11 2001-10-04 Process for producing holographic material
US09/970,731 Abandoned US20030024631A1 (en) 1995-06-07 2001-10-04 Process for producing holographic material
US09/971,324 Abandoned US20030029551A1 (en) 1995-06-07 2001-10-04 Process for producing holographic material
US09/970,744 Abandoned US20030029554A1 (en) 1995-06-07 2001-10-04 Process for producing holographic material
US10/209,631 Abandoned US20020192568A1 (en) 1999-08-11 2002-07-30 Process for producing holographic material
US10/209,557 Abandoned US20020179231A1 (en) 1999-08-11 2002-07-30 Process for producing holographic material
US10/615,699 Abandoned US20040011455A1 (en) 1995-06-07 2003-07-09 Method for providing a decorative cover formed of holographic material
US10/616,877 Abandoned US20040007316A1 (en) 1995-06-07 2003-07-10 Process for producing holographic material
US10/616,886 Abandoned US20040065405A1 (en) 1995-06-07 2003-07-10 Method for providing a decorative cover formed of holographic material
US10/617,283 Abandoned US20040062997A1 (en) 1995-06-07 2003-07-10 Method for providing a decorative cover formed of holographic material

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US20030024631A1 (en) 2003-02-06
US20030029551A1 (en) 2003-02-13
US20030029549A1 (en) 2003-02-13
US20040011455A1 (en) 2004-01-22
US20020192568A1 (en) 2002-12-19
US20040065405A1 (en) 2004-04-08
US20040062997A1 (en) 2004-04-01
US6372073B1 (en) 2002-04-16
US6896755B1 (en) 2005-05-24
US20040007316A1 (en) 2004-01-15
US20030029554A1 (en) 2003-02-13
US6461463B1 (en) 2002-10-08
US20020179231A1 (en) 2002-12-05

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