US20020192104A1 - High density soft magnetic products and method for the preparation thereof - Google Patents
High density soft magnetic products and method for the preparation thereof Download PDFInfo
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- US20020192104A1 US20020192104A1 US09/963,633 US96363301A US2002192104A1 US 20020192104 A1 US20020192104 A1 US 20020192104A1 US 96363301 A US96363301 A US 96363301A US 2002192104 A1 US2002192104 A1 US 2002192104A1
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- compaction
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- soft magnetic
- iron
- density
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01F—MAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
- H01F1/00—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties
- H01F1/01—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials
- H01F1/03—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity
- H01F1/12—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of soft-magnetic materials
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C33/00—Making ferrous alloys
- C22C33/02—Making ferrous alloys by powder metallurgy
- C22C33/0257—Making ferrous alloys by powder metallurgy characterised by the range of the alloying elements
- C22C33/0264—Making ferrous alloys by powder metallurgy characterised by the range of the alloying elements the maximum content of each alloying element not exceeding 5%
- C22C33/0271—Making ferrous alloys by powder metallurgy characterised by the range of the alloying elements the maximum content of each alloying element not exceeding 5% with only C, Mn, Si, P, S, As as alloying elements, e.g. carbon steel
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F3/00—Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces
- B22F3/02—Compacting only
- B22F3/087—Compacting only using high energy impulses, e.g. magnetic field impulses
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C33/00—Making ferrous alloys
- C22C33/02—Making ferrous alloys by powder metallurgy
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01F—MAGNETS; INDUCTANCES; TRANSFORMERS; SELECTION OF MATERIALS FOR THEIR MAGNETIC PROPERTIES
- H01F1/00—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties
- H01F1/01—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials
- H01F1/03—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity
- H01F1/12—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of soft-magnetic materials
- H01F1/14—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of soft-magnetic materials metals or alloys
- H01F1/20—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of soft-magnetic materials metals or alloys in the form of particles, e.g. powder
- H01F1/22—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of soft-magnetic materials metals or alloys in the form of particles, e.g. powder pressed, sintered, or bound together
Definitions
- This invention relates to the general field of powder metallurgy. Particularly the invention is concerned with a method of preparation of high density soft magnetic products.
- an insulated powder is prepared by treating an iron powder with a coating solution including phosphoric acid and chromic acid.
- Insulating coatings are also described in e.g. U.S. Pat. No. 5,798,177 and DE 34 39 397. According to these publications the coatings are obtained by treating iron based powders with coating solutions including phosphoric acid. The compacted product prepared from the insulated powders is subsequently heat treated.
- Another type of coating is disclosed in U.S. Pat. No. 4,602,957.
- a magnetic powder core is prepared by treating an iron powder with an aqueous solution of potassium dichromate, drying the powder, compressing the powder to form a compact and heat treating the compact at substantially 600° C.
- soft iron particles are coated with thermoplastic materials before pressing.
- the U.S. Pat. Nos. 4,947,065 and 5,198,137 teach such methods whereby iron powders are coated with a thermoplastic material.
- a more recent method of coating iron-based powders for soft magnetic applications is described in PCT SE97/00283.
- the magnetic properties such as the initial permeability as a function of the frequency (frequency stability)
- a high velocity compaction (HVC) technique which is described more in detail below.
- HVC high velocity compaction
- An object of the invention is to provide a method for the preparation of high density soft magnetic products, particularly products having a density above 7.25, preferably above 7.30 and most preferably above 7.35 g/cm 3 .
- a second object is to provide a compaction method adapted to industrial use for mass production of such high density products.
- a third object is to provide compacted bodies having high density and high green strength.
- a fourth object is to provide a soft magnetic compacts bodies having high initial permeability.
- the method of preparing such high density compacts comprises the steps of subjecting an iron or iron-based soft magnetic powder to HVC compaction with an uniaxial pressure movement with a ram speed of at least 2 m/s.
- the particles of powder may, but must not, be electrically insulated.
- the base powder i.e. the non-insulated powder
- the base powder may be a substantially pure water atomised iron powder or a sponge iron powder having irregularly shaped particles.
- substantially pure means that the powder should be substantially free from inclusions and that the amounts of the impurities O, C an N should be kept at a minimum.
- the average particle sizes are generally below 300 ⁇ m and above 10 ⁇ m. Examples of such powders are ABC 100.30, ASC 100.29, AT 40.29, ASC 200, ASC 300, NC 100.24, SC 100.26, MH 300, MH 40.28, MH 40.24 available from Höganäs AB, Sweden.
- An insulating coating may be applied in order to improve the properties in alternating magnetic fields. Such a coating also permits heat treatment which further enhances the magnetic properties.
- the coating and the coating method is believed not to be critical and the coating could e.g. be any of those disclosed above. Especially preferred are thin coatings based on phosphorus and silicone, aluminium and titanium.
- the compacting method is important. Normally used compaction equipment does not work quite satisfactorily, as the strain on the equipment will be too great. It has now been found that the high densities required may be obtained by the use of the computer controlled percussion machine disclosed in the U.S. Pat. No. 6,202,757 which is which is hereby incorporated by reference. Particularly, the impact ram of such a percussion machine may be used for impacting the upper punch of a die including the powder in a cavity having a shape corresponding to the desired shape of the final compacted component. When supplemented with a system for holding a die, e.g.
- this percussion machine permits an industrially useful method for production of high-density compacts.
- An especially important advantage is that, in contrast to previously proposed methods, this arrangement driven by hydraulics permits mass production (continuous production) of such high density components.
- the ram speed should be above 2 m/s.
- the ram speed is a manner of providing energy to the powder through the punch of the die. No straight equivalence exists between compaction pressure in a conventional press and the ram speed.
- the compaction which is obtained with this computer controlled HVC depends, in addition to the impact ram speed, i.a. on the amount of powder to be compacted, the weight of the impact body, the number of impacts or strokes, the impact length and the final geometry of the component. Furthermore, large amounts of powder require more impacts than small amounts of powder.
- the optimal conditions for the HVC compaction i.e. the amount of kinetic energy which should be transferred to the powder, may be decided by experiments performed by the man skilled in the art.
- the compaction may be performed with a lubricated die. It is also possible to include a suitable particular lubricant in the powder to be compacted. Alternatively, a combination thereof may be used.
- the lubricant can be selected among conventionally used lubricants such as metal soaps, waxes and thermoplastic materials, such as polyamides, polyimides, polyolefins, polyesters, polyalkoxides, polyalcohols. Specific examples of lubricants are zinc stearate, H-wax® and Kenolube®.
- the amount of lubricant may vary up to 1% by weight of the powder composition.
- This example illustrates the possibility of obtaining high initial permeability with a soft magnetic powder (Somaloy 500 available from Höganäs, Sweden), the particles of which are electrically insulated.
- Somaloy 500 available from Höganäs, Sweden
- the compaction machine was Model HYP 35-4 from Hudropulsor Sweden.
- the green density was determined by principle of Archimedes (1).
- the height, inner and outer diameter was measured on each sample. After compaction the toroids were wound with 25 turns of insulated copper wire. The inductance of the coil was measured at 1000 and 2000 Hz with a HP 4284 A LCR-meter. The inductance was measured at low currents (10 mA) and the initial permeability was calculated from (2).
- ⁇ in L*l* 10 ⁇ 3 /( N 2 *A* ⁇ 0 )
- N number of turns
- ⁇ 0 permeability of free space
- This example illustrates the possibility of obtaining high initial permeability and high frequency stability with a powder (ABC 100.30 available from Höganäs, Sweden), the particles of which are not electrically insulated before the compaction.
- the samples have the same geometry and testing was made exactly the same way. At a given density an unexpected difference could be observed between HVC and conventional compacted samples as can be seen from FIGS. 2 and 3. 0.2 and 0.5% by weight, respectively, of a particular lubricant (Kenolube®) was added to the iron powder before the compaction.
- the stroke lengths used for the HVC compaction in FIG. 2 were 85 and 100 mm corresponding to ram speeds of 8 and 9 m/s, respectively.
- the stroke lengths used for the HVC compaction in FIG. 3 were 70 and 90 mm corresponding to ram speeds of 7.5 and 8.5 m/s, respectively.
Abstract
Description
- This invention relates to the general field of powder metallurgy. Particularly the invention is concerned with a method of preparation of high density soft magnetic products.
- In recent years the use of powdered metals for the manufacture of soft magnetic core components has expanded and the research has been directed to the development of iron powder compositions that enhance certain physical and magnetic properties without detrimentally affecting other properties. To this end many efforts have been made in order to provide electrical coatings which insulate the individual iron powder particles and many examples of different coatings are disclosed in the art.
- Thus according to the U.S. Pat. No. 3,245,841 an insulated powder is prepared by treating an iron powder with a coating solution including phosphoric acid and chromic acid. Insulating coatings are also described in e.g. U.S. Pat. No. 5,798,177 and DE 34 39 397. According to these publications the coatings are obtained by treating iron based powders with coating solutions including phosphoric acid. The compacted product prepared from the insulated powders is subsequently heat treated. Another type of coating is disclosed in U.S. Pat. No. 4,602,957. According to this patent a magnetic powder core is prepared by treating an iron powder with an aqueous solution of potassium dichromate, drying the powder, compressing the powder to form a compact and heat treating the compact at substantially 600° C. In other known processes soft iron particles are coated with thermoplastic materials before pressing. The U.S. Pat. Nos. 4,947,065 and 5,198,137 teach such methods whereby iron powders are coated with a thermoplastic material. A more recent method of coating iron-based powders for soft magnetic applications is described in PCT SE97/00283. Thus by using different types of coatings and coating techniques desired properties such as high permeability through an extended frequency range, high pressed strength, low core losses and suitability for compression moulding techniques have been considerably improved lately.
- It has now been found that the magnetic properties, such as the initial permeability as a function of the frequency (frequency stability), may be improved by using a high velocity compaction (HVC) technique, which is described more in detail below. Especially unexpected is the finding that, for a given density, the initial permeability at different frequencies are significantly higher with this HVC technique and that these properties have been observed for both insulated and not insulated powder particles.
- An object of the invention is to provide a method for the preparation of high density soft magnetic products, particularly products having a density above 7.25, preferably above 7.30 and most preferably above 7.35 g/cm3.
- A second object is to provide a compaction method adapted to industrial use for mass production of such high density products.
- A third object is to provide compacted bodies having high density and high green strength.
- A fourth object is to provide a soft magnetic compacts bodies having high initial permeability.
- In brief the method of preparing such high density compacts comprises the steps of subjecting an iron or iron-based soft magnetic powder to HVC compaction with an uniaxial pressure movement with a ram speed of at least 2 m/s. The particles of powder may, but must not, be electrically insulated.
- The base powder, i.e. the non-insulated powder, may be a substantially pure water atomised iron powder or a sponge iron powder having irregularly shaped particles. In this context the term “substantially pure” means that the powder should be substantially free from inclusions and that the amounts of the impurities O, C an N should be kept at a minimum. The average particle sizes are generally below 300 μm and above 10 μm. Examples of such powders are ABC 100.30, ASC 100.29, AT 40.29, ASC 200, ASC 300, NC 100.24, SC 100.26, MH 300, MH 40.28, MH 40.24 available from Höganäs AB, Sweden.
- An insulating coating may be applied in order to improve the properties in alternating magnetic fields. Such a coating also permits heat treatment which further enhances the magnetic properties. The coating and the coating method is believed not to be critical and the coating could e.g. be any of those disclosed above. Especially preferred are thin coatings based on phosphorus and silicone, aluminium and titanium.
- In order to obtain the products having the desired high density according to the present invention the compacting method is important. Normally used compaction equipment does not work quite satisfactorily, as the strain on the equipment will be too great. It has now been found that the high densities required may be obtained by the use of the computer controlled percussion machine disclosed in the U.S. Pat. No. 6,202,757 which is which is hereby incorporated by reference. Particularly, the impact ram of such a percussion machine may be used for impacting the upper punch of a die including the powder in a cavity having a shape corresponding to the desired shape of the final compacted component. When supplemented with a system for holding a die, e.g. a conventionally used die, and a unit for powder filling (which may also be of conventional type) this percussion machine permits an industrially useful method for production of high-density compacts. An especially important advantage is that, in contrast to previously proposed methods, this arrangement driven by hydraulics permits mass production (continuous production) of such high density components.
- In the U.S. Pat. No. 6,202,757 it is stated that the use of the percussion machine involves “adiabatic” moulding. As it is not fully clarified if the compaction is adiabatic in a strictly scientific meaning and we have used the term high velocity compaction (HVC) for this type of compaction wherein the density of the compacted product is controlled by the impact energy transferred to the powder.
- According to the present invention the ram speed should be above 2 m/s. The ram speed is a manner of providing energy to the powder through the punch of the die. No straight equivalence exists between compaction pressure in a conventional press and the ram speed. The compaction which is obtained with this computer controlled HVC depends, in addition to the impact ram speed, i.a. on the amount of powder to be compacted, the weight of the impact body, the number of impacts or strokes, the impact length and the final geometry of the component. Furthermore, large amounts of powder require more impacts than small amounts of powder. Thus the optimal conditions for the HVC compaction i.e. the amount of kinetic energy which should be transferred to the powder, may be decided by experiments performed by the man skilled in the art. Contrary to the teaching in the U.S. Pat. No. 6,202,757 there is, however, no need to use a specific impact sequence involving a light stroke, a high energy stroke and a medium-high energy stroke for the compaction of the powder. According to the present invention the strokes (if more than one stroke is needed) may be essential identical and provide the same energy to the powder.
- Experiments with existing equipment has permitted ram speeds up to 30 m/s and, as is illustrated by the examples, high green densities are obtained with ram speeds about 10 m/s. The method according to the invention is however not restricted to these ram speeds but it is believed that ram speeds up to 100 or even up to 200 or 250 m/s may be used. Ram speeds below about 2 m/s does, however, not give the pronounced effect of densification. It is preferred that the ram speed above 3 m/s. Most preferably the ram speed is above 5 m/s.
- The compaction may be performed with a lubricated die. It is also possible to include a suitable particular lubricant in the powder to be compacted. Alternatively, a combination thereof may be used. The lubricant can be selected among conventionally used lubricants such as metal soaps, waxes and thermoplastic materials, such as polyamides, polyimides, polyolefins, polyesters, polyalkoxides, polyalcohols. Specific examples of lubricants are zinc stearate, H-wax® and Kenolube®. The amount of lubricant may vary up to 1% by weight of the powder composition.
- The invention is further illustrated by the following examples:
- This example illustrates the possibility of obtaining high initial permeability with a soft magnetic powder (
Somaloy 500 available from Höganäs, Sweden), the particles of which are electrically insulated. - 100 g powder of the powder were used in a ring tool with the dimensions Ø72/56. Both conventional compaction and HVC compaction were used. The following two mixes were tested:
-
Somaloy 500+0.2% Kenolube* -
Somaloy 500+0% Kenolube* - The compaction machine was Model HYP 35-4 from Hudropulsor Sweden.
- The same type of Die Wall Lubrication was used for both mixes and for both compacting methods.
- The green density was determined by principle of Archimedes (1).
- ρ=m air/(mair −m w) (1)
- mair=mass in air
- mw=mass in water
- The height, inner and outer diameter was measured on each sample. After compaction the toroids were wound with 25 turns of insulated copper wire. The inductance of the coil was measured at 1000 and 2000 Hz with a HP 4284 A LCR-meter. The inductance was measured at low currents (10 mA) and the initial permeability was calculated from (2).
- μin =L*l*10−3/(N 2 *A*μ 0)
- L=measured inductance in μHenry
- l=magnetic length in cm
- N=number of turns
- A=cross section area in cm2
- μ0=permeability of free space
- The samples have the same geometry and testing was made exactly the same way. At a given density an unexpected difference as regards the initial permeability could be observed between HVC and conventional compacted samples as can be seen from FIG. 1. The ram speeds for the HVC compaction were about 7-8 m/s.
- This example illustrates the possibility of obtaining high initial permeability and high frequency stability with a powder (ABC 100.30 available from Höganäs, Sweden), the particles of which are not electrically insulated before the compaction.
- The samples have the same geometry and testing was made exactly the same way. At a given density an unexpected difference could be observed between HVC and conventional compacted samples as can be seen from FIGS. 2 and 3. 0.2 and 0.5% by weight, respectively, of a particular lubricant (Kenolube®) was added to the iron powder before the compaction. The stroke lengths used for the HVC compaction in FIG. 2 were 85 and 100 mm corresponding to ram speeds of 8 and 9 m/s, respectively. The stroke lengths used for the HVC compaction in FIG. 3 were 70 and 90 mm corresponding to ram speeds of 7.5 and 8.5 m/s, respectively.
Claims (9)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
SE0102103A SE0102103D0 (en) | 2001-06-13 | 2001-06-13 | High density soft magnetic products and method for the preparation thereof |
SE0102103-9 | 2001-06-13 | ||
SE0102103 | 2001-06-19 |
Publications (2)
Publication Number | Publication Date |
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US20020192104A1 true US20020192104A1 (en) | 2002-12-19 |
US6503444B1 US6503444B1 (en) | 2003-01-07 |
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US09/963,633 Expired - Fee Related US6503444B1 (en) | 2001-06-13 | 2001-09-27 | High density soft magnetic products and method for the preparation thereof |
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US (1) | US6503444B1 (en) |
EP (1) | EP1404473B1 (en) |
JP (1) | JP2004528481A (en) |
KR (1) | KR100945365B1 (en) |
CN (1) | CN1326648C (en) |
BR (1) | BR0210388B1 (en) |
CA (1) | CA2450427C (en) |
DE (1) | DE60213413T2 (en) |
ES (1) | ES2268047T3 (en) |
MX (1) | MXPA03011537A (en) |
RU (1) | RU2292987C2 (en) |
SE (1) | SE0102103D0 (en) |
TW (1) | TW557454B (en) |
WO (1) | WO2002100580A1 (en) |
Cited By (1)
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---|---|---|---|---|
WO2019122307A1 (en) * | 2017-12-22 | 2019-06-27 | Querdenkfabrik Ag | Process for producing a soft-magnetic moulding and soft-magnetic moulding |
Families Citing this family (14)
Publication number | Priority date | Publication date | Assignee | Title |
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US7153594B2 (en) | 2002-12-23 | 2006-12-26 | Höganäs Ab | Iron-based powder |
US20050189844A1 (en) * | 2003-09-05 | 2005-09-01 | Du Hung T. | Field assemblies having pole pieces with dovetail features for attaching to a back iron piece(s) and methods of making same |
US7205696B2 (en) * | 2003-09-05 | 2007-04-17 | Black & Decker Inc. | Field assemblies having pole pieces with ends that decrease in width, and methods of making same |
TW200514334A (en) * | 2003-09-05 | 2005-04-16 | Black & Decker Inc | Field assemblies and methods of making same |
US20060226729A1 (en) * | 2003-09-05 | 2006-10-12 | Du Hung T | Field assemblies and methods of making same with field coils having multiple coils |
US7146706B2 (en) * | 2003-09-05 | 2006-12-12 | Black & Decker Inc. | Method of making an electric motor |
US7211920B2 (en) * | 2003-09-05 | 2007-05-01 | Black & Decker Inc. | Field assemblies having pole pieces with axial lengths less than an axial length of a back iron portion and methods of making same |
SE0302427D0 (en) * | 2003-09-09 | 2003-09-09 | Hoeganaes Ab | Iron based soft magnetic powder |
EP2562912A1 (en) | 2005-03-07 | 2013-02-27 | Black & Decker Inc. | Power Tools with Motor Having a Multi-Piece Stator |
JP2007013072A (en) * | 2005-05-30 | 2007-01-18 | Mitsubishi Materials Pmg Corp | Dust core and method for manufacturing same, and reactor using same |
KR101269688B1 (en) | 2006-05-22 | 2013-05-30 | 한국생산기술연구원 | Method for manufacturing a soft magnetic core |
US20110234347A1 (en) * | 2010-03-24 | 2011-09-29 | Aspect Magnet Technologies Ltd. | Pole piece for permanent magnet mri systems |
CN104134529B (en) * | 2014-07-21 | 2016-08-17 | 华南理工大学 | A kind of anisotropy nano-crystalline neodymium-iron-boronmagnet magnet and preparation method and application |
CN105458249A (en) * | 2015-11-26 | 2016-04-06 | 扬州海昌粉末冶金有限公司 | Method for manufacturing high-magnetic-conductivity sintered iron-based soft magnetism product |
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GB1046241A (en) | 1961-08-31 | 1966-10-19 | Secr Defence | Improvements in the production of iron powder having high electrical resistivity |
GB8425860D0 (en) | 1984-10-12 | 1984-11-21 | Emi Ltd | Magnetic powder compacts |
DE3439397A1 (en) | 1984-10-27 | 1986-04-30 | Vacuumschmelze Gmbh, 6450 Hanau | Process for the production of a soft-magnetic body by powder metallurgy |
US4925501A (en) | 1988-03-03 | 1990-05-15 | General Motors Corporation | Expolosive compaction of rare earth-transition metal alloys in a fluid medium |
EP0331286A3 (en) | 1988-03-03 | 1989-11-02 | General Motors Corporation | Rapid compaction of rare earth-transition metal alloys in a fluid-filled die |
CN1014688B (en) * | 1988-12-31 | 1991-11-13 | 吴成义 | Process for preparing nd-fe-b spherical non-crystalline microcrystalline powder |
US5198137A (en) | 1989-06-12 | 1993-03-30 | Hoeganaes Corporation | Thermoplastic coated magnetic powder compositions and methods of making same |
US4947065A (en) | 1989-09-22 | 1990-08-07 | General Motors Corporation | Stator assembly for an alternating current generator |
SE9401392D0 (en) | 1994-04-25 | 1994-04-25 | Hoeganaes Ab | Heat-treating or iron powders |
US5541868A (en) * | 1995-02-21 | 1996-07-30 | The United States Of America As Represented By The Secretary Of The Navy | Annular GMR-based memory element |
SE9501129D0 (en) | 1995-03-28 | 1995-03-28 | Hoeganaes Ab | Soft magnetic anisotropic composite materials |
DK0833714T3 (en) | 1995-06-21 | 2001-03-05 | Hydropulsor Ab | Stroke Engine |
EP0881959B1 (en) | 1996-02-23 | 2003-09-03 | Höganäs Ab | Phosphate coated iron powder and method for the manufacturing thereof |
CN1069616C (en) * | 1997-12-19 | 2001-08-15 | 化学工业部天津化工研究院 | Method for preparing zirconium oxide-aluminum oxide composite and its use |
SE511834C2 (en) * | 1998-01-13 | 1999-12-06 | Valtubes Sa | Fully dense products made by uniaxial high speed metal powder pressing |
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2001
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- 2001-07-20 TW TW090117814A patent/TW557454B/en not_active IP Right Cessation
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- 2002-06-12 DE DE60213413T patent/DE60213413T2/en not_active Expired - Lifetime
- 2002-06-12 CA CA002450427A patent/CA2450427C/en not_active Expired - Fee Related
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
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WO2019122307A1 (en) * | 2017-12-22 | 2019-06-27 | Querdenkfabrik Ag | Process for producing a soft-magnetic moulding and soft-magnetic moulding |
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ES2268047T3 (en) | 2007-03-16 |
CN1326648C (en) | 2007-07-18 |
EP1404473B1 (en) | 2006-07-26 |
EP1404473A1 (en) | 2004-04-07 |
CA2450427C (en) | 2008-05-06 |
BR0210388A (en) | 2004-06-29 |
CA2450427A1 (en) | 2002-12-19 |
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CN1516629A (en) | 2004-07-28 |
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RU2292987C2 (en) | 2007-02-10 |
DE60213413T2 (en) | 2006-12-21 |
WO2002100580A1 (en) | 2002-12-19 |
DE60213413D1 (en) | 2006-09-07 |
JP2004528481A (en) | 2004-09-16 |
BR0210388B1 (en) | 2012-02-07 |
KR20040014555A (en) | 2004-02-14 |
RU2004100544A (en) | 2005-06-10 |
US6503444B1 (en) | 2003-01-07 |
SE0102103D0 (en) | 2001-06-13 |
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