US20020166656A1 - Heat exchanger column - Google Patents

Heat exchanger column Download PDF

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Publication number
US20020166656A1
US20020166656A1 US09/852,361 US85236101A US2002166656A1 US 20020166656 A1 US20020166656 A1 US 20020166656A1 US 85236101 A US85236101 A US 85236101A US 2002166656 A1 US2002166656 A1 US 2002166656A1
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US
United States
Prior art keywords
pressure vessel
flow
group
interior
flow passageways
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
US09/852,361
Inventor
Lee Howard
Howard Rowles
Randy Nickel
Gene Lucadamo
Bruce Hill
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Air Products and Chemicals Inc
Original Assignee
Air Products and Chemicals Inc
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Publication date
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Priority to US09/852,361 priority Critical patent/US20020166656A1/en
Assigned to AIR PRODUCTS AND CHEMICALS, INC. reassignment AIR PRODUCTS AND CHEMICALS, INC. ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: HILL, BRUCE MOODIE, HOWARD, LEE JARVIS, NICKEL, RANDY JAMES, ROWLES, HOWARD CHARLES, LUCADAMO, GENE ANTHONY
Publication of US20020166656A1 publication Critical patent/US20020166656A1/en
Abandoned legal-status Critical Current

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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28DHEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
    • F28D9/00Heat-exchange apparatus having stationary plate-like or laminated conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall
    • F28D9/0062Heat-exchange apparatus having stationary plate-like or laminated conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall the conduits for one heat-exchange medium being formed by spaced plates with inserted elements
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/0204Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream characterised by the feed stream
    • F25J3/0209Natural gas or substitute natural gas
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/0204Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream characterised by the feed stream
    • F25J3/0219Refinery gas, cracking gas, coke oven gas, gaseous mixtures containing aliphatic unsaturated CnHm or gaseous mixtures of undefined nature
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/0204Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream characterised by the feed stream
    • F25J3/0223H2/CO mixtures, i.e. synthesis gas; Water gas or shifted synthesis gas
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/0228Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream characterised by the separated product stream
    • F25J3/0233Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream characterised by the separated product stream separation of CnHm with 1 carbon atom or more
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/0228Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream characterised by the separated product stream
    • F25J3/0238Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream characterised by the separated product stream separation of CnHm with 2 carbon atoms or more
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/0228Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream characterised by the separated product stream
    • F25J3/0242Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream characterised by the separated product stream separation of CnHm with 3 carbon atoms or more
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/0228Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream characterised by the separated product stream
    • F25J3/0252Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream characterised by the separated product stream separation of hydrogen
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/0228Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream characterised by the separated product stream
    • F25J3/0257Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream characterised by the separated product stream separation of nitrogen
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/0228Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream characterised by the separated product stream
    • F25J3/0261Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream characterised by the separated product stream separation of carbon monoxide
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J3/00Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
    • F25J3/02Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
    • F25J3/0295Start-up or control of the process; Details of the apparatus used, e.g. sieve plates, packings
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J5/00Arrangements of cold exchangers or cold accumulators in separation or liquefaction plants
    • F25J5/002Arrangements of cold exchangers or cold accumulators in separation or liquefaction plants for continuously recuperating cold, i.e. in a so-called recuperative heat exchanger
    • F25J5/007Arrangements of cold exchangers or cold accumulators in separation or liquefaction plants for continuously recuperating cold, i.e. in a so-called recuperative heat exchanger combined with mass exchange, i.e. in a so-called dephlegmator
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28DHEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
    • F28D9/00Heat-exchange apparatus having stationary plate-like or laminated conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall
    • F28D9/0006Heat-exchange apparatus having stationary plate-like or laminated conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall the plate-like or laminated conduits being enclosed within a pressure vessel
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2200/00Processes or apparatus using separation by rectification
    • F25J2200/80Processes or apparatus using separation by rectification using integrated mass and heat exchange, i.e. non-adiabatic rectification in a reflux exchanger or dephlegmator
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2210/00Processes characterised by the type or other details of the feed stream
    • F25J2210/12Refinery or petrochemical off-gas
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2250/00Details related to the use of reboiler-condensers
    • F25J2250/10Boiler-condenser with superposed stages
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2250/00Details related to the use of reboiler-condensers
    • F25J2250/20Boiler-condenser with multiple exchanger cores in parallel or with multiple re-boiling or condensing streams
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2270/00Refrigeration techniques used
    • F25J2270/12External refrigeration with liquid vaporising loop
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2270/00Refrigeration techniques used
    • F25J2270/60Closed external refrigeration cycle with single component refrigerant [SCR], e.g. C1-, C2- or C3-hydrocarbons
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2270/00Refrigeration techniques used
    • F25J2270/66Closed external refrigeration cycle with multi component refrigerant [MCR], e.g. mixture of hydrocarbons
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2290/00Other details not covered by groups F25J2200/00 - F25J2280/00
    • F25J2290/30Details about heat insulation or cold insulation
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F25REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
    • F25JLIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
    • F25J2290/00Other details not covered by groups F25J2200/00 - F25J2280/00
    • F25J2290/50Arrangement of multiple equipments fulfilling the same process step in parallel
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28DHEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
    • F28D21/00Heat-exchange apparatus not covered by any of the groups F28D1/00 - F28D20/00
    • F28D2021/0019Other heat exchangers for particular applications; Heat exchange systems not otherwise provided for
    • F28D2021/0061Other heat exchangers for particular applications; Heat exchange systems not otherwise provided for for phase-change applications
    • F28D2021/0063Condensers

Definitions

  • Plate-and-fin or core-type heat exchangers are widely used in the process industries for the exchange of heat between fluid mixtures, particularly those which contain components with sub-ambient boiling points. These well-known heat exchangers are typically constructed with parallel plates separated by fins wherein the plates and fins are brazed together to form an integrated assembly of alternating flow channels. The most widely-used material for fabrication of these exchangers is aluminum.
  • the characteristic operating feature of core-type heat exchangers is the cooling of a first fluid stream, which flows through a first group of flow channels or passageways, by indirect heat transfer with a second fluid stream, which is warmed in another group of flow channels.
  • the first and second fluid streams generally flow through alternating channels in order to maximize the effective heat transfer area of the exchanger. Additional fluid streams can be warmed and/or cooled in adjacent channels in the same heat exchanger, and thus core-type exchangers can transfer heat among multiple fluid streams.
  • a gas is cooled and condensed by indirect heat transfer with a warming fluid such as a vaporizing liquid process stream or refrigerant.
  • a feed gas mixture is cooled and partially condensed within a group of flow channels by indirect heat transfer with one or more refrigerants or colder fluids flowing in adjacent alternating flow channels.
  • a first embodiment of the invention is a system for cooling a fluid feed stream which comprises:
  • thermoelectric heat exchanger installed in the interior of the pressure vessel, wherein the heat exchanger comprises a group of flow passageways which has a first end and a second end, wherein at least one of the first end and the second end is open and in flow communication with the interior of the pressure vessel;
  • inlet piping means for introducing the fluid feed stream into the interior of the pressure vessel
  • outlet piping means for withdrawing from the interior of the pressure vessel at least a portion of the cooled fluid stream
  • cooling means for indirectly cooling the group of flow passageways to cool the fluid feed stream therein to form a cooled fluid stream
  • fluid transfer means for transferring the fluid feed stream from the inlet piping means into the group of flow passageways at one end thereof or for transferring a cooled fluid stream from one end of the group of flow passageways to the outlet piping means.
  • the heat exchanger can be constructed in a plate-and-fin configuration.
  • the system described above can further comprise
  • thermoelectric heat exchanger installed in the interior of the additional pressure vessel, wherein the heat exchanger comprises a group of flow passageways which has a first end and a second end, wherein at least one of the first end and the second end is open and in flow communication with the interior of the additional pressure vessel;
  • inlet piping means for introducing an intermediate fluid stream into the interior of the additional pressure vessel
  • cooling means for indirectly cooling the group of flow passageways to cool the intermediate fluid stream therein to form an additional cooled fluid stream
  • outlet piping means for withdrawing from the interior of the additional pressure vessel at least a portion of the additional cooled fluid stream
  • (l) fluid transfer means for transferring the fluid feed stream from the inlet piping means into the group of flow passageways at one end thereof or for transferring a cooled fluid stream from one end of the group of flow passageways to the outlet piping means.
  • the system described above can further comprise piping means connecting the outlet piping means of (d) with the inlet piping means of (i) such that at least a portion of the cooled fluid stream withdrawn from the pressure vessel can provide the intermediate fluid stream to the additional pressure vessel.
  • the cooling means of (e) described above can comprise
  • each additional group of flow passageways has a first end and a second end, and wherein each additional group of flow passageways is in indirect heat transfer communication with the group of flow passageways of (b);
  • inlet piping means for introducing refrigerant into the interior of the pressure vessel
  • outlet piping means for withdrawing warmed refrigerant from the interior of the pressure vessel
  • inlet distributor means for distributing the refrigerant from the inlet piping into the first end of the additional group of flow passageways
  • outlet collector means for collecting the warmed refrigerant from the second end of the additional group of flow passageways and directing warmed refrigerant into the outlet piping means.
  • the first end of the flow passageways can be an upper end and the second end of the flow passageways can be a lower end, and the lower end can be open and in flow communication with a lower region in the interior of the pressure vessel.
  • the heat exchanger can be constructed in a plate-and-fin configuration.
  • the fluid transfer means described in (l) above can comprise outlet manifold means and outlet header means for transferring a cooled fluid stream from the upper end of the group of flow passageways to the outlet piping.
  • the inlet piping means can be connected to a lower end of the pressure vessel and the outlet piping means can be connected to an upper end of the pressure vessel such that fluid can flow through the group of flow passageways in a generally upward direction.
  • the fluid transfer means comprises inlet manifold means and inlet header means for transferring the fluid feed stream from the inlet piping into the upper end of the group of flow passageways.
  • the inlet piping means can be connected to an upper end of the pressure vessel and the outlet piping means can be connected to a lower end of the pressure vessel such that fluid can flow through the group of flow passageways in a generally downward direction.
  • the fluid flowing generally downward through the group of flow passageways can be a gas which can condense therein to form a vapor and a liquid which flow into the lower end of the pressure vessel, wherein the outlet piping means of (d) is used for withdrawing vapor from the lower end of the pressure vessel, and wherein the system includes additional outlet piping means used for withdrawing liquid from the lower end of the pressure vessel.
  • system can further comprise
  • thermoelectric heat exchanger installed in the interior of the additional pressure vessel, wherein the heat exchanger comprises a group of flow passageways which has a first end and a second end, wherein at least one of the first end and the second end is open and in flow communication with the interior of the additional pressure vessel;
  • inlet piping means for introducing an intermediate fluid stream into the interior of the additional pressure vessel
  • inlet fluid transfer means for transferring the intermediate fluid stream from the inlet piping means into the group of flow passageways at one end thereof;
  • cooling means for indirectly cooling the group of flow passageways to cool the intermediate fluid stream therein to form an additional cooled fluid stream
  • outlet piping means for withdrawing from the interior of the pressure vessel at least a portion of the additional cooled fluid stream.
  • the system can further comprise piping means connecting the outlet piping means of (d) with the inlet piping means of (i) such that at least a portion of the vapor withdrawn from the pressure vessel can provide the intermediate fluid stream to the additional pressure vessel.
  • This heat exchanger in the additional pressure vessel can be constructed in a plate-and-fin configuration.
  • the inlet piping means can be connected to an upper end of the additional pressure vessel and the outlet piping means can be connected to a lower end of the additional pressure vessel such that vapor can flow through the group of flow passageways in a generally downward direction.
  • the vapor flowing generally downward through the group of flow passageways can condense therein to form an uncondensed vapor and a liquid which flow into the lower end of the additional pressure vessel, wherein the outlet piping means of (I) is used for withdrawing the uncondensed vapor from the lower end of the additional pressure vessel, and wherein the system includes additional outlet piping means used for withdrawing liquid from the lower end of the additional pressure vessel.
  • the first end of the flow passageways can be an upper end and the second end of the flow passageways can be a lower end, and wherein the upper end can be open and in flow communication with an upper region in the interior of the pressure vessel.
  • the heat exchanger in the pressure vessel can be constructed in a plate-and-fin configuration.
  • the fluid transfer means can comprise inlet manifold means and inlet header means for transferring the fluid feed stream from the inlet piping into the lower end of the group of flow passageways.
  • the inlet piping means can be connected to a lower end of the pressure vessel and the outlet piping means can be connected to an upper end of the pressure vessel such that fluid can flow through the group of flow passageways in a generally upward direction.
  • the fluid transfer means comprises outlet manifold means and outlet header means for transferring the cooled fluid stream from the lower end of the group of flow passageways to the outlet piping means.
  • the inlet piping means can be connected to an upper end of the pressure vessel and the outlet piping means can be connected to a lower end of the pressure vessel such that fluid can flow through the group of flow passageways in a generally downward direction.
  • a second embodiment of the invention is a system for cooling a fluid feed stream which comprises:
  • thermoelectric heat exchanger installed in the interior of the pressure vessel, wherein the heat exchanger comprises a group of flow passageways having a first end and a second end, wherein the first end is open and in flow communication with a first end of the interior of the pressure vessel and the second end is open and in flow communication with a second end of the interior of the pressure vessel;
  • cooling means for indirectly cooling the group of flow passageways to cool the fluid feed stream therein to form a cooled fluid stream
  • inlet piping means for introducing the fluid feed stream into the first end of the interior of the pressure vessel
  • outlet piping means for withdrawing at least a portion of the cooled fluid stream from the second end of the interior of the pressure vessel
  • seal means disposed in the pressure vessel at an axial location between the first and second ends of the group of flow passageways, which seal means isolates the first end of the interior of the pressure vessel from the second end of the interior of the pressure vessel such that the first and second ends of the interior of the pressure vessel are not in flow communication.
  • the heat exchanger in this second embodiment can be constructed in a plate-and-fin configuration.
  • the inlet piping means can be connected to a lower end of the pressure vessel and the outlet piping means can be connected to an upper end of the pressure vessel such that fluid can flow through the group of flow passageways in a generally upward direction.
  • the inlet piping means can be connected to an upper end of the pressure vessel and the outlet piping means can be connected to a lower end of the pressure vessel such that fluid can flow through the group of flow passageways in a generally downward direction.
  • the fluid flowing generally downward through the group of flow passageways can be a gas which can condense therein to form a vapor and a liquid which flow into the lower end of the pressure vessel, wherein the outlet piping means of (e) is used for withdrawing vapor from the lower end of the pressure vessel, and wherein the system includes additional outlet piping means used for withdrawing liquid from the lower end of the pressure vessel.
  • FIG. 1 is a schematic drawing of a heat exchanger assembly according to the present invention.
  • FIG. 2 is a schematic drawing of an alternative embodiment of the heat exchanger assembly according to the present invention.
  • FIG. 3 is a schematic drawing of another alternative embodiment of the heat exchanger assembly according to the present invention.
  • FIG. 4 is a schematic drawing of an embodiment of the present invention which utilizes two heat exchanger assemblies in series.
  • the invention as described herein eliminates selected distributor fins, collector fins, headers, nozzles, and manifolds from plate-and-fin core-type heat exchangers typically used for low temperature gas processing.
  • these distributor fins, collector fins, headers, nozzles, and manifolds are eliminated at the feed stream inlet, the processed stream outlet, or both the feed stream inlet and the processed stream outlet of the heat exchanger.
  • the invention can be utilized for cooling a fluid stream (i.e., a gas or a liquid stream) without phase change, or alternatively for partially or totally condensing a gas stream.
  • Heat exchanger 1 is a typical plate-and-fin core-type heat exchanger as earlier described, and usually is installed in a generally vertical orientation inside pressure vessel 3 .
  • a portion of the flow passageways in the heat exchanger can be utilized for condensing service, and these passageways form a feed circuit through which the uncondensed feed gas and condensate flow cocurrently.
  • the flow passageways are oriented such that the uncondensed feed gas and condensate flow cocurrently in a generally downward direction, i.e., in a vertical downward direction or in a downward direction which deviates from vertical wherein the flow passageways operate such that the condensate flows downward by the force of gravity.
  • the generally downward direction is preferably vertical but can deviate from the vertical as long as the deviation does not adversely affect the downward cocurrent flow of uncondensed feed gas and condensate through the exchanger and the transfer of heat from the uncondensed feed gas and condensate.
  • the bulk flow of vapor and liquid is generally parallel to the axes of the flow passageways.
  • the feed circuit heat transfer fin section extends to bottom 5 of heat exchanger 1 , and the feed circuit is open at bottom 5 and is in full flow communication with the interior of pressure vessel 3 .
  • the term “open” means that the end of the exchanger has no collector fins or headers associated with it, and therefore fluid can flow unimpeded without restriction from the end of each flow channel.
  • both vapor 7 and condensed liquid 9 flow unimpeded from the exchanger core without restriction, and the full fluid-handling capacity of the core therefore can be utilized.
  • a stream of mixed feed gas 11 enters inlet 13 of pressure vessel 3 , flows through manifolds 17 and 19 , and flows through header 21 through distributor fins (not shown) into the feed circuit of heat exchanger 1 .
  • the distributor fins are located at the entrance to the core and function to direct fluid from the header into the main flow passageways in the body of the core.
  • the distributor fins can be considered as part of the plate-and-fin heat exchanger core.
  • Manifold 17 , manifold 19 , and header 21 are generically described as fluid transfer means to transfer fluid from inlet 13 to the end of heat exchanger 1 .
  • the feed gas flows downward in this embodiment and is partially condensed therein by refrigeration provided in adjacent flow channels as described below.
  • Condensate 9 drains freely from the feed circuit at the bottom of the core and collects in the bottom of vessel 3 , from which liquid product stream 23 is withdrawn through vessel outlet 25 .
  • Uncondensed vapor 7 exits exchanger 1 via vessel outlet 27 to provide vapor product stream 29 .
  • This arrangement eliminates the need for a separator drum to separate the condensed liquid from the uncondensed vapor portion of the cooled feed.
  • Vapor product stream 29 is enriched in the lower boiling, more volatile components in the feed gas mixture and liquid product 23 is enriched in the higher boiling, less volatile components in the feed gas mixture.
  • the feed gas mixture contains more volatile components and less volatile components, and the mixture typically contains two or more components selected from the group consisting of hydrogen, helium, carbon monoxide, carbon dioxide, nitrogen, argon, oxygen, and C, to C 6 hydrocarbons.
  • Feed gas mixtures can include cracked gas, refinery and petrochemical plant offgases, synthesis gas, natural gas, and air.
  • Typical refrigerant stream 31 is introduced via vessel inlet 33 , manifolds 35 and 37 , header 39 , and distributor fins (not shown) into a refrigerant circuit which comprises a group of flow channels in the core of heat exchanger 1 .
  • Refrigerant flows upward through the refrigerant circuit in heat exchanger 1 while warming and/or vaporizing to provide indirect cooling to the condensing vapor in the feed circuit described earlier.
  • Warmed refrigerant is withdrawn from the heat exchanger through collector fins (not shown), header 41 , manifolds 43 and 45 , and outlet 47 to provide warmed refrigerant stream 49 .
  • Refrigerant 31 can be a cold process fluid which is warmed to provide sensible and/or latent heat for cooling and condensing the feed gas.
  • a liquid refrigerant can be used which vaporizes while flowing through the refrigerant circuit.
  • the liquid refrigerant can flow downward if desired.
  • Typical refrigerants can be selected from C 1 to C 3 hydrocarbons, ammonia, fluorocarbons, chlorofluorocarbons, and mixed refrigerants which are recirculated through a closed-loop refrigeration circuit. More than one refrigerant circuit can be used if desired, which would require additional header and distributor/collector systems at the top and bottom of heat exchanger 1 .
  • Additional heat exchangers can be installed in parallel with heat exchanger 1 in pressure vessel 3 if desired.
  • An additional heat exchanger 51 for example, is shown in FIG. 1 and operates in parallel with heat exchanger 1 .
  • Feed gas 11 is introduced into the feed circuit of heat exchanger 51 via inlet 13 , manifold 17 , manifold 53 , distributor header 55 , and distributor fins (not shown).
  • Uncondensed vapor 59 and condensate 61 flow from the bottom of exchanger 51 in a similar manner to the flows from heat exchanger 1 .
  • Refrigerant 31 for heat exchanger 51 enters via inlet 33 , manifolds 35 and 55 , and distributor header 57 and fins. Warmed refrigerant is withdrawn from heat exchanger 51 via collector fins and header 63 , manifolds 65 and 45 , and outlet 47 .
  • Typical operating temperatures and pressures range from +100° F. to 400° F. for feed and refrigerants, 100 to 1500 psia for the feed, and 2 to 1500 psia for refrigerants.
  • inlet and outlet lines can be manifolded inside pressure vessel 3 as shown to reduce the number of pipes passing through the vessel shell, although this is not necessary.
  • Refrigerant drums which may be used for ethylene, propylene, or similar thermosiphon-type refrigerant circuits, or for distributing two-phase refrigerant streams into the heat exchanger cores, can be located inside or outside the pressure vessel as desired.
  • the pressure vessel can be externally insulated, similar to a distillation column, so that no cold box is required, particularly where operating temperatures are above about ⁇ 250° F.
  • the feed gas 11 may be desirable to have the feed gas 11 enter and/or leave the sides, rather than the ends, of heat exchangers 1 and 51 (not shown).
  • distributor and/or collector fins would be required at one or both ends of the core to distribute flow into and/or collect flow from the cores.
  • the corresponding distributors or collectors would be open to the interior of pressure vessel 3 on the side of the core to permit feed gas to enter and/or leave the core. Headers, nozzles and manifolds would not be required for the open sides of the cores.
  • the heat exchanger as described above is utilized for condensing flow, the heat exchanger alternatively can be utilized to cool a fluid (either gas or liquid) without phase change.
  • a superheated gas stream can be cooled to a temperature above its dew point, while a liquid at or below its bubble point can be subcooled to a temperature further below its bubble point.
  • the axis of the heat exchanger and the flow direction of the fluid being cooled (which is generally parallel to the axis of the exchanger) can be vertical, horizontal, or between vertical and horizontal.
  • the fluid being cooled can flow in any desired direction.
  • FIG. 2 An alternative embodiment is shown in FIG. 2 which can be used when the feed gas is to be cooled or partially condensed in an upward flow direction, or when it is desirable to remove the vapor and liquid portions of the cooled and partially condensed gas as a mixed stream rather than as separate vapor and liquid streams.
  • feed gas 11 is introduced via inlet 201 of pressure vessel 203 , and feed gas 205 flows into the open ends of heat exchangers 207 and 209 .
  • the gas condenses as it flows upward with the resulting condensate, and the two-phase vapor/liquid stream is withdrawn via collector fins and headers 211 and 213 , manifolds 215 , 217 , and 219 , and outlet 221 to provide final vapor/liquid product 223 .
  • Headers 211 and 213 and manifolds 215 , 217 , and 219 are generically described as fluid transfer means to transfer fluid from the ends of heat exchangers 207 and 209 to outlet 221 .
  • the refrigerant in this alternative embodiment can be provided as described earlier for the embodiment of FIG. 1.
  • the flow passageways are oriented such that the cocurrent flow of uncondensed feed gas and condensate is in a generally upward direction, i.e., in a vertical upward direction or in an upward direction which is between vertical and horizontal.
  • the flow passageways deviate sufficiently from the horizontal such that the condensate flows upward by entrainment in the upward-flowing gas.
  • the flow is in a generally upward direction, which means that the flow is preferably vertically upward but can deviate from the vertical as long as the deviation does not adversely affect the upward cocurrent flow of uncondensed feed gas and entrained condensate through the exchanger and/or the transfer of heat from the uncondensed feed gas and condensate to the refrigerant.
  • the refrigerant can flow upward as shown using a vaporizing fluid, or downward using a gaseous refrigerant, to maintain an adequate temperature difference between the feed and the refrigerant.
  • heat exchangers 1 and 209 are open at the bottom and have a header and manifolds at the top of the exchanger.
  • the heat exchanger is open at the top and has a header and manifolds at the bottom.
  • Fluid flow in this alternative embodiment can be either upward or downward, and can be either single-phase or condensing flow as described above.
  • FIG. 3 Another alternative embodiment of the invention is shown in FIG. 3 which illustrates the use of two heat exchangers in parallel, although single or more than two heat exchangers can be used if desired.
  • heat exchangers 301 and 303 are installed in pressure vessel 305
  • seal means 307 (shown schematically) is installed between the heat exchanger and pressure vessel walls to segregate the vessel interior into upper section 309 and lower section 311 which are not in flow communication.
  • Seal means 307 can be installed at any appropriate axial location between the upper and lower ends of heat exchangers 301 and 303 .
  • Seal means 307 can be any type of seal known in the art for segregating the upper and lower sections of the vessel against a low gas pressure differential, for example, 1 to 10 psi. Seal means 307 could be integrated with a core or piping support member.
  • seal means 307 eliminates the need for feed distributor fins, headers, and manifolds at the top of the heat exchangers and processed gas collector fins, headers, and manifolds at the bottom of the heat exchangers.
  • the flow passageways or channels are open at both ends.
  • the term “open” means that the end of the exchanger has no distributor fins, collector fins, or headers associated with it, and therefore fluid can flow unimpeded without restriction into and out of the ends of the flow channels.
  • the heat transfer fins in the flow passageways can be continuous from the top to the bottom of the core, with no distributor or collector fins at either end.
  • the bottom end of each feed channel is in flow communication with lower section 311 of pressure vessel 305
  • the upper end of each feed channel is in flow communication with upper section 309 of the pressure vessel.
  • the refrigerant circuits can be similar to those described in FIG. 1.
  • a portion of the flow passageways in the heat exchanger can be utilized for condensing service, and these passageways form a feed circuit through which the uncondensed feed gas and condensate flow cocurrently.
  • the flow passageways are oriented such that the uncondensed feed gas and condensate flow cocurrently in a generally downward direction, i.e., in a vertical downward direction or in a downward direction which deviates from vertical wherein the flow passageways operate such that the condensate flows downward by the force of gravity.
  • the generally downward direction is preferably vertical but can deviate from the vertical as long as the deviation does not adversely affect the downward cocurrent flow of uncondensed feed gas and condensate through the exchanger and/or the transfer of heat from the uncondensed feed gas and condensate to the refrigerant.
  • feed gas stream 313 flows through vessel inlet 315 , and interior feed gas 317 flows into upper section 309 of vessel 305 and then downward through the feed channels of heat exchangers 301 and 303 . Condensation occurs as the gas and condensate flow downward through the feed channels, liquid 319 flows from the open ends of heat exchangers 301 and 303 , and liquid 321 collects in the bottom of the vessel. Liquid product 323 is withdrawn via outlet 325 and uncondensed vapor 327 flows directly from the open feed channels at the lower ends of the heat exchangers and is withdrawn via vessel outlet 329 to provide vapor product 331 .
  • the heat exchanger of FIG. 3 as described above is utilized for condensing flow
  • the heat exchanger alternatively can be utilized to cool a fluid (either gas or liquid) without phase change.
  • a superheated gas stream can be cooled to a temperature above its dew point, while a liquid at or below its bubble point can be subcooled to a temperature further below its bubble point.
  • the axis of the heat exchanger and the flow direction of the fluid being cooled (which is generally parallel to the axis of the exchanger) can be vertical, horizontal, or between vertical and horizontal.
  • the fluid being cooled can flow in any desired direction.
  • the advantage of the embodiment of FIG. 3 is that no manifolds, headers, distributor fins, or collector fins are needed at either end of heat exchangers 301 and 303 for feed introduction and product withdrawal. This greatly simplifies the entire heat exchanger assembly and results in reduced capital cost.
  • Two or more heat exchanger cores operating in different temperature or pressure ranges can be utilized in series or in parallel by stacking the pressure vessels in a vertical arrangement or by locating the vessels side-by-side. When used in series, the exit gas from a first heat exchanger is fed to a second heat exchanger for further cooling as described below.
  • An internal head can be used inside a single pressure vessel to separate the warmer and colder heat exchangers as shown in the alternative embodiment of FIG. 4.
  • lower pressure vessel section 401 and upper pressure vessel section 403 are formed by head 405 installed in overall pressure vessel 407 .
  • Lower pressure vessel 401 and heat exchangers 409 and 411 installed therein are similar to the system described above for FIG. 3.
  • Upper pressure vessel 403 and heat exchangers 413 and 415 are similar to the system described earlier for FIG. 1.
  • Feed gas 417 is processed in heat exchangers 413 and 415 in the same manner as that described earlier for exchangers 1 and 51 for the embodiment of FIG. 1.
  • Intermediate vapor product 419 flows through vessel inlet 421 into upper portion 423 of pressure vessel 401 , and is processed in the same manner as that described earlier for the embodiment of FIG. 3.
  • First liquid product 425 is withdrawn via outlet 427 .
  • Vapor 429 condenses further in exchangers 409 and 411 , which operate with a colder refrigerant than exchangers 413 and 415 .
  • Additional liquid is condensed and condensate 431 flows out of the bottoms of heat exchangers 409 and 411 , and collects in the bottom of vessel 401 as liquid 433 .
  • This liquid is withdrawn via outlet 435 to provide second liquid product stream 437 , which contains additional higher boiling components.
  • Vapor 439 flows from the bottoms of heat exchangers 409 and 411 , and vapor product 441 is withdrawn via outlet 443 .
  • This vapor product is enriched in the more volatile components in feed gas 417 .
  • Refrigerant 445 provides refrigeration to heat exchangers 413 and 415 as described earlier for the operation of heat exchangers 1 and 51 of FIG. 1.
  • Refrigerant 449 which is at a lower temperature than refrigerant 445 , provides refrigeration to heat exchangers 409 and 411 as described earlier for the operation of heat exchangers 301 and 303 of FIG. 3.
  • the two sections of vessel 407 can utilize different numbers or sizes of heat exchangers, and the sections may be of different diameters.
  • the two vessel sections of FIG. 4 can be operated at different pressures if desired.
  • vessel section 403 is operated at a higher pressure than vessel section 401 , and uncondensed gas stream 419 is reduced in pressure before being introduced into inlet 421 .
  • upper section 403 can be similar to bottom section 401 , wherein both sections utilize heat exchangers open on both ends with seals to segregate the upper and lower portions of the exchangers.
  • bottom section 401 would contain heat exchangers identical to those in upper section 403 of FIG. 4.
  • heat exchangers 409 and 411 with seal 447 , can be located in upper section 403 while heat exchangers 413 and 415 , with gas inlet headers and distributor fins, can be located in lower section 401 .
  • an internal head or other arrangement such as a chimney tray (not shown), can be used inside a single pressure vessel to separate the heat exchangers in sections 401 and 403 .
  • the vapor from the upper section can flow by means of the chimney tray directly into the lower section without flowing through external piping required for stream 419 of FIG. 4.
  • the two sections of the pressure vessel can contain the same size or different sizes of heat exchangers, can contain the same or different numbers of heat exchangers, and can be of different diameters if necessary.
  • the feed gas can flow either upward or downward in each of the heat exchangers as described earlier.
  • the feed inlet, the processed gas/liquid outlet, or both the feed inlet and processed gas/liquid outlet of each of the heat exchangers can be open to the interior of the pressure vessel.
  • a common feature of all embodiments of the invention described above operating in condensing flow is that condensed liquid and uncondensed vapor flow through the channels of the core-type heat exchangers cocurrently, i.e., in the same direction.
  • flow is in a generally downward direction, but upward flow is used in at least one alternative embodiment as described above.
  • the heat exchangers must be designed so that the upward gas flow velocity is sufficient to entrain the condensate such that essentially none of the condensate flows in a downward direction.
  • the pressure vessel for the present invention can be designed to operate at any pressure level, preferably in the range of 100 to 1500 psia.
  • the heat exchanger cores can be any size, both in cross-section and in length. Welded-blocks, i.e. two or more cores welded together side-by-side, can be utilized to increase the available cross-section of the heat exchanger cores to a very large size, such as 4 feet by 8 feet or more. Any length of core can be used, and is typically in the range of 5 to 20 feet.
  • the pressure vessel can be externally insulated, similar to a distillation column, so that no cold box is required for the heat exchangers.
  • the pressure vessel shell can be minimized by manifolding refrigerant stream nozzles inside the pressure vessel.
  • Refrigerant drums can also be located either inside or outside the pressure vessel, as desired.
  • three or more heat exchangers each operating at progressively colder temperatures, can be installed in series within a single pressure vessel, or in separate vessels, or a combination of stacked and separate pressure vessels. Any combination of feed flow direction and open core ends/sides can be used in each of the heat exchangers. All refrigerant streams entering or leaving the heat exchangers typically would utilize conventional distributors, collectors, headers, and nozzles, which are piped through the vessel shell.
  • one or more of the heat exchangers can be replaced by a dephlegmator.
  • feed gas enters the pressure vessel, flows into the open bottom end of the core and upward through the core. Condensed liquid drains downward, and rectification occurs as the liquid and vapor flow countercurrently in the core. Condensate exits freely from the bottom of the core into the bottom of the vessel for removal.
  • the feed vapor outlet at the top end of the dephlegmator may be either open or closed. All refrigerant streams entering or leaving the dephlegmator typically would utilize conventional distributors, collectors, headers, and nozzles.
  • the present invention simplifies the design of plate-and-fin heat exchanger cores which operate in the condensing mode and allows efficient use of the core cross section because no manifolds, distributor fins, and headers are required at the inlet of each feed circuit.
  • vapor collector fins, manifolds, and headers are not required at the outlet of each feed circuit, further simplifying heat exchanger design and operation.
  • the present invention allows operation of plate-and-fin core-type heat exchangers at higher pressures than many prior art systems which require dome headers or similar integrated vessels attached to the heat exchanger feed circuits.
  • higher throughput is possible because the available fluid handling capacity of each heat exchanger is not reduced by distributors, collectors, headers, nozzles, or manifolds.

Abstract

Plate-and-fin core-type heat exchangers are installed within pressure vessels in a manner which eliminates the need for distributors, collectors, headers, nozzles, and manifolds at the feed inlet, the processed gas outlet, or both the feed inlet and the processed gas outlet of each exchanger core. The heat exchangers can be installed in parallel or in series within a single pressure vessel. Alternatively, the heat exchangers can be installed in pressure vessels which are arranged in series such that multiple liquid product streams can be obtained. The heat exchangers preferably are operated in the condensing mode in which feed gas is cooled and partially condensed. The operation of the heat exchangers is characterized by the cocurrent flow of the condensate and uncondensed feed gas, preferably in the vertical or near-vertical direction. In an alternative embodiment, the heat exchangers are operated such that a feed fluid is cooled without phase change.

Description

    BACKGROUND OF THE INVENTION
  • Plate-and-fin or core-type heat exchangers are widely used in the process industries for the exchange of heat between fluid mixtures, particularly those which contain components with sub-ambient boiling points. These well-known heat exchangers are typically constructed with parallel plates separated by fins wherein the plates and fins are brazed together to form an integrated assembly of alternating flow channels. The most widely-used material for fabrication of these exchangers is aluminum. [0001]
  • The characteristic operating feature of core-type heat exchangers is the cooling of a first fluid stream, which flows through a first group of flow channels or passageways, by indirect heat transfer with a second fluid stream, which is warmed in another group of flow channels. The first and second fluid streams generally flow through alternating channels in order to maximize the effective heat transfer area of the exchanger. Additional fluid streams can be warmed and/or cooled in adjacent channels in the same heat exchanger, and thus core-type exchangers can transfer heat among multiple fluid streams. [0002]
  • In a typical application, a gas is cooled and condensed by indirect heat transfer with a warming fluid such as a vaporizing liquid process stream or refrigerant. In the condensation mode of operation, a feed gas mixture is cooled and partially condensed within a group of flow channels by indirect heat transfer with one or more refrigerants or colder fluids flowing in adjacent alternating flow channels. [0003]
  • An important requirement for the efficient operation of plate-and-fin core-type heat exchangers is the proper distribution of each process stream into the heat exchanger so that the stream flows uniformly through each of the desired flow channels. This is accomplished by the use of feed distributor fins, headers, and nozzles which are joined to the inlet of the heat exchanger assembly. In addition, similar collector fins, headers, and nozzles are required to withdraw the process streams evenly from the outlet end of the heat exchanger. These distributor and collector devices are complex and expensive. When multiple, parallel heat exchangers are required, complex and expensive manifolding also is required to distribute flow to and collect flow from the parallel heat exchangers. Dome headers eliminate the distributor fins or collector fins. However, these distributor and collector devices typically cannot be used on cores larger than about 3 feet by 4 feet in cross section at pressures above about 150 psig. [0004]
  • Because these heat exchangers often are used in the processing of low-boiling gas mixtures, the resulting low-temperature operation typically requires the use of cold boxes to contain the heat exchangers, phase separators, and associated piping. [0005]
  • Low-temperature gas processing plants, which utilize the complex heat exchange equipment described above, are highly capital-intensive. There is an ongoing need to reduce the capital cost and equipment complexity of these plants, while retaining high operating efficiency. The invention described below and defined by the claims which follow meets this need by reducing or eliminating the use of complex feed gas distributors and collectors, and optionally by eliminating the need for cold boxes to contain the heat exchangers and associated piping. [0006]
  • BRIEF SUMMARY OF THE INVENTION
  • A first embodiment of the invention is a system for cooling a fluid feed stream which comprises: [0007]
  • (a) a pressure vessel having an interior and an exterior; [0008]
  • (b) a heat exchanger installed in the interior of the pressure vessel, wherein the heat exchanger comprises a group of flow passageways which has a first end and a second end, wherein at least one of the first end and the second end is open and in flow communication with the interior of the pressure vessel; [0009]
  • (c) inlet piping means for introducing the fluid feed stream into the interior of the pressure vessel; [0010]
  • (d) outlet piping means for withdrawing from the interior of the pressure vessel at least a portion of the cooled fluid stream; [0011]
  • (e) cooling means for indirectly cooling the group of flow passageways to cool the fluid feed stream therein to form a cooled fluid stream; and [0012]
  • (f) fluid transfer means for transferring the fluid feed stream from the inlet piping means into the group of flow passageways at one end thereof or for transferring a cooled fluid stream from one end of the group of flow passageways to the outlet piping means. [0013]
  • In this first embodiment, the heat exchanger can be constructed in a plate-and-fin configuration. [0014]
  • The system described above can further comprise [0015]
  • (g) an additional pressure vessel having an interior and an exterior; [0016]
  • (h) a heat exchanger installed in the interior of the additional pressure vessel, wherein the heat exchanger comprises a group of flow passageways which has a first end and a second end, wherein at least one of the first end and the second end is open and in flow communication with the interior of the additional pressure vessel; [0017]
  • (i) inlet piping means for introducing an intermediate fluid stream into the interior of the additional pressure vessel; [0018]
  • (j) cooling means for indirectly cooling the group of flow passageways to cool the intermediate fluid stream therein to form an additional cooled fluid stream; [0019]
  • (k) outlet piping means for withdrawing from the interior of the additional pressure vessel at least a portion of the additional cooled fluid stream; and [0020]
  • (l) fluid transfer means for transferring the fluid feed stream from the inlet piping means into the group of flow passageways at one end thereof or for transferring a cooled fluid stream from one end of the group of flow passageways to the outlet piping means. [0021]
  • The system described above can further comprise piping means connecting the outlet piping means of (d) with the inlet piping means of (i) such that at least a portion of the cooled fluid stream withdrawn from the pressure vessel can provide the intermediate fluid stream to the additional pressure vessel. [0022]
  • The cooling means of (e) described above can comprise [0023]
  • (1) one or more additional groups of flow passageways in the heat exchanger wherein each additional group of flow passageways has a first end and a second end, and wherein each additional group of flow passageways is in indirect heat transfer communication with the group of flow passageways of (b); [0024]
  • (2) inlet piping means for introducing refrigerant into the interior of the pressure vessel; [0025]
  • (3) outlet piping means for withdrawing warmed refrigerant from the interior of the pressure vessel; [0026]
  • (4) inlet distributor means for distributing the refrigerant from the inlet piping into the first end of the additional group of flow passageways; and [0027]
  • (5) outlet collector means for collecting the warmed refrigerant from the second end of the additional group of flow passageways and directing warmed refrigerant into the outlet piping means. [0028]
  • In a first alternative of the system described in the first embodiment above, the first end of the flow passageways can be an upper end and the second end of the flow passageways can be a lower end, and the lower end can be open and in flow communication with a lower region in the interior of the pressure vessel. In this first alternative, the heat exchanger can be constructed in a plate-and-fin configuration. [0029]
  • The fluid transfer means described in (l) above can comprise outlet manifold means and outlet header means for transferring a cooled fluid stream from the upper end of the group of flow passageways to the outlet piping. The inlet piping means can be connected to a lower end of the pressure vessel and the outlet piping means can be connected to an upper end of the pressure vessel such that fluid can flow through the group of flow passageways in a generally upward direction. In this case, the fluid transfer means comprises inlet manifold means and inlet header means for transferring the fluid feed stream from the inlet piping into the upper end of the group of flow passageways. [0030]
  • Alternatively, the inlet piping means can be connected to an upper end of the pressure vessel and the outlet piping means can be connected to a lower end of the pressure vessel such that fluid can flow through the group of flow passageways in a generally downward direction. In this case, the fluid flowing generally downward through the group of flow passageways can be a gas which can condense therein to form a vapor and a liquid which flow into the lower end of the pressure vessel, wherein the outlet piping means of (d) is used for withdrawing vapor from the lower end of the pressure vessel, and wherein the system includes additional outlet piping means used for withdrawing liquid from the lower end of the pressure vessel. [0031]
  • In this first alternative of the first embodiment, the system can further comprise [0032]
  • (g) an additional pressure vessel having an interior and an exterior; [0033]
  • (h) a heat exchanger installed in the interior of the additional pressure vessel, wherein the heat exchanger comprises a group of flow passageways which has a first end and a second end, wherein at least one of the first end and the second end is open and in flow communication with the interior of the additional pressure vessel; [0034]
  • (i) inlet piping means for introducing an intermediate fluid stream into the interior of the additional pressure vessel; [0035]
  • (j) inlet fluid transfer means for transferring the intermediate fluid stream from the inlet piping means into the group of flow passageways at one end thereof; [0036]
  • (k) cooling means for indirectly cooling the group of flow passageways to cool the intermediate fluid stream therein to form an additional cooled fluid stream; and [0037]
  • (l) outlet piping means for withdrawing from the interior of the pressure vessel at least a portion of the additional cooled fluid stream. [0038]
  • The system can further comprise piping means connecting the outlet piping means of (d) with the inlet piping means of (i) such that at least a portion of the vapor withdrawn from the pressure vessel can provide the intermediate fluid stream to the additional pressure vessel. This heat exchanger in the additional pressure vessel can be constructed in a plate-and-fin configuration. [0039]
  • The inlet piping means can be connected to an upper end of the additional pressure vessel and the outlet piping means can be connected to a lower end of the additional pressure vessel such that vapor can flow through the group of flow passageways in a generally downward direction. In this case, the vapor flowing generally downward through the group of flow passageways can condense therein to form an uncondensed vapor and a liquid which flow into the lower end of the additional pressure vessel, wherein the outlet piping means of (I) is used for withdrawing the uncondensed vapor from the lower end of the additional pressure vessel, and wherein the system includes additional outlet piping means used for withdrawing liquid from the lower end of the additional pressure vessel. [0040]
  • In a second alternative of the first embodiment described above, the first end of the flow passageways can be an upper end and the second end of the flow passageways can be a lower end, and wherein the upper end can be open and in flow communication with an upper region in the interior of the pressure vessel. The heat exchanger in the pressure vessel can be constructed in a plate-and-fin configuration. The fluid transfer means can comprise inlet manifold means and inlet header means for transferring the fluid feed stream from the inlet piping into the lower end of the group of flow passageways. In one mode of this second alternative, the inlet piping means can be connected to a lower end of the pressure vessel and the outlet piping means can be connected to an upper end of the pressure vessel such that fluid can flow through the group of flow passageways in a generally upward direction. In this case, the fluid transfer means comprises outlet manifold means and outlet header means for transferring the cooled fluid stream from the lower end of the group of flow passageways to the outlet piping means. In another mode of this second alternative, the inlet piping means can be connected to an upper end of the pressure vessel and the outlet piping means can be connected to a lower end of the pressure vessel such that fluid can flow through the group of flow passageways in a generally downward direction. [0041]
  • A second embodiment of the invention is a system for cooling a fluid feed stream which comprises: [0042]
  • (a) a pressure vessel having an interior and an exterior; [0043]
  • (b) a heat exchanger installed in the interior of the pressure vessel, wherein the heat exchanger comprises a group of flow passageways having a first end and a second end, wherein the first end is open and in flow communication with a first end of the interior of the pressure vessel and the second end is open and in flow communication with a second end of the interior of the pressure vessel; [0044]
  • (c) cooling means for indirectly cooling the group of flow passageways to cool the fluid feed stream therein to form a cooled fluid stream; [0045]
  • (d) inlet piping means for introducing the fluid feed stream into the first end of the interior of the pressure vessel; [0046]
  • (e) outlet piping means for withdrawing at least a portion of the cooled fluid stream from the second end of the interior of the pressure vessel; and [0047]
  • (f) seal means disposed in the pressure vessel at an axial location between the first and second ends of the group of flow passageways, which seal means isolates the first end of the interior of the pressure vessel from the second end of the interior of the pressure vessel such that the first and second ends of the interior of the pressure vessel are not in flow communication. [0048]
  • The heat exchanger in this second embodiment can be constructed in a plate-and-fin configuration. [0049]
  • In one alternative of this second embodiment, the inlet piping means can be connected to a lower end of the pressure vessel and the outlet piping means can be connected to an upper end of the pressure vessel such that fluid can flow through the group of flow passageways in a generally upward direction. In another alternative, the inlet piping means can be connected to an upper end of the pressure vessel and the outlet piping means can be connected to a lower end of the pressure vessel such that fluid can flow through the group of flow passageways in a generally downward direction. In this second alternative, the fluid flowing generally downward through the group of flow passageways can be a gas which can condense therein to form a vapor and a liquid which flow into the lower end of the pressure vessel, wherein the outlet piping means of (e) is used for withdrawing vapor from the lower end of the pressure vessel, and wherein the system includes additional outlet piping means used for withdrawing liquid from the lower end of the pressure vessel.[0050]
  • BRIEF DESCRIPTION OF SEVERAL VIEWS OF THE DRAWINGS
  • FIG. 1 is a schematic drawing of a heat exchanger assembly according to the present invention. [0051]
  • FIG. 2 is a schematic drawing of an alternative embodiment of the heat exchanger assembly according to the present invention. [0052]
  • FIG. 3 is a schematic drawing of another alternative embodiment of the heat exchanger assembly according to the present invention. [0053]
  • FIG. 4 is a schematic drawing of an embodiment of the present invention which utilizes two heat exchanger assemblies in series.[0054]
  • DETAILED DESCRIPTION OF THE INVENTION
  • The invention as described herein eliminates selected distributor fins, collector fins, headers, nozzles, and manifolds from plate-and-fin core-type heat exchangers typically used for low temperature gas processing. In the various embodiments of the invention, these distributor fins, collector fins, headers, nozzles, and manifolds are eliminated at the feed stream inlet, the processed stream outlet, or both the feed stream inlet and the processed stream outlet of the heat exchanger. The invention can be utilized for cooling a fluid stream (i.e., a gas or a liquid stream) without phase change, or alternatively for partially or totally condensing a gas stream. [0055]
  • A first embodiment of the invention is illustrated in FIG. 1. Heat exchanger [0056] 1 is a typical plate-and-fin core-type heat exchanger as earlier described, and usually is installed in a generally vertical orientation inside pressure vessel 3. A portion of the flow passageways in the heat exchanger can be utilized for condensing service, and these passageways form a feed circuit through which the uncondensed feed gas and condensate flow cocurrently. The flow passageways are oriented such that the uncondensed feed gas and condensate flow cocurrently in a generally downward direction, i.e., in a vertical downward direction or in a downward direction which deviates from vertical wherein the flow passageways operate such that the condensate flows downward by the force of gravity. The generally downward direction is preferably vertical but can deviate from the vertical as long as the deviation does not adversely affect the downward cocurrent flow of uncondensed feed gas and condensate through the exchanger and the transfer of heat from the uncondensed feed gas and condensate.
  • The bulk flow of vapor and liquid is generally parallel to the axes of the flow passageways. The feed circuit heat transfer fin section extends to [0057] bottom 5 of heat exchanger 1, and the feed circuit is open at bottom 5 and is in full flow communication with the interior of pressure vessel 3. The term “open” means that the end of the exchanger has no collector fins or headers associated with it, and therefore fluid can flow unimpeded without restriction from the end of each flow channel. Thus in FIG. 1 both vapor 7 and condensed liquid 9 flow unimpeded from the exchanger core without restriction, and the full fluid-handling capacity of the core therefore can be utilized.
  • A stream of mixed feed gas [0058] 11 enters inlet 13 of pressure vessel 3, flows through manifolds 17 and 19, and flows through header 21 through distributor fins (not shown) into the feed circuit of heat exchanger 1. The distributor fins are located at the entrance to the core and function to direct fluid from the header into the main flow passageways in the body of the core. The distributor fins can be considered as part of the plate-and-fin heat exchanger core. Manifold 17, manifold 19, and header 21 are generically described as fluid transfer means to transfer fluid from inlet 13 to the end of heat exchanger 1.
  • The feed gas flows downward in this embodiment and is partially condensed therein by refrigeration provided in adjacent flow channels as described below. Condensate [0059] 9 drains freely from the feed circuit at the bottom of the core and collects in the bottom of vessel 3, from which liquid product stream 23 is withdrawn through vessel outlet 25. Uncondensed vapor 7 exits exchanger 1 via vessel outlet 27 to provide vapor product stream 29. This arrangement eliminates the need for a separator drum to separate the condensed liquid from the uncondensed vapor portion of the cooled feed.
  • [0060] Vapor product stream 29 is enriched in the lower boiling, more volatile components in the feed gas mixture and liquid product 23 is enriched in the higher boiling, less volatile components in the feed gas mixture. The feed gas mixture contains more volatile components and less volatile components, and the mixture typically contains two or more components selected from the group consisting of hydrogen, helium, carbon monoxide, carbon dioxide, nitrogen, argon, oxygen, and C, to C6 hydrocarbons. Feed gas mixtures can include cracked gas, refinery and petrochemical plant offgases, synthesis gas, natural gas, and air.
  • Typical [0061] refrigerant stream 31 is introduced via vessel inlet 33, manifolds 35 and 37, header 39, and distributor fins (not shown) into a refrigerant circuit which comprises a group of flow channels in the core of heat exchanger 1. Refrigerant flows upward through the refrigerant circuit in heat exchanger 1 while warming and/or vaporizing to provide indirect cooling to the condensing vapor in the feed circuit described earlier. Warmed refrigerant is withdrawn from the heat exchanger through collector fins (not shown), header 41, manifolds 43 and 45, and outlet 47 to provide warmed refrigerant stream 49.
  • [0062] Refrigerant 31 can be a cold process fluid which is warmed to provide sensible and/or latent heat for cooling and condensing the feed gas. Alternatively, a liquid refrigerant can be used which vaporizes while flowing through the refrigerant circuit. The liquid refrigerant can flow downward if desired. Typical refrigerants can be selected from C1 to C3 hydrocarbons, ammonia, fluorocarbons, chlorofluorocarbons, and mixed refrigerants which are recirculated through a closed-loop refrigeration circuit. More than one refrigerant circuit can be used if desired, which would require additional header and distributor/collector systems at the top and bottom of heat exchanger 1.
  • Additional heat exchangers can be installed in parallel with heat exchanger [0063] 1 in pressure vessel 3 if desired. An additional heat exchanger 51, for example, is shown in FIG. 1 and operates in parallel with heat exchanger 1. Feed gas 11 is introduced into the feed circuit of heat exchanger 51 via inlet 13, manifold 17, manifold 53, distributor header 55, and distributor fins (not shown). Uncondensed vapor 59 and condensate 61 flow from the bottom of exchanger 51 in a similar manner to the flows from heat exchanger 1. Refrigerant 31 for heat exchanger 51 enters via inlet 33, manifolds 35 and 55, and distributor header 57 and fins. Warmed refrigerant is withdrawn from heat exchanger 51 via collector fins and header 63, manifolds 65 and 45, and outlet 47.
  • Typical operating temperatures and pressures range from +100° F. to 400° F. for feed and refrigerants, 100 to 1500 psia for the feed, and 2 to 1500 psia for refrigerants. [0064]
  • When parallel heat exchanger cores are used, inlet and outlet lines can be manifolded inside [0065] pressure vessel 3 as shown to reduce the number of pipes passing through the vessel shell, although this is not necessary. Refrigerant drums, which may be used for ethylene, propylene, or similar thermosiphon-type refrigerant circuits, or for distributing two-phase refrigerant streams into the heat exchanger cores, can be located inside or outside the pressure vessel as desired. The pressure vessel can be externally insulated, similar to a distillation column, so that no cold box is required, particularly where operating temperatures are above about −250° F.
  • Alternatively, it may be desirable to have the feed gas [0066] 11 enter and/or leave the sides, rather than the ends, of heat exchangers 1 and 51 (not shown). In this case, distributor and/or collector fins would be required at one or both ends of the core to distribute flow into and/or collect flow from the cores. The corresponding distributors or collectors would be open to the interior of pressure vessel 3 on the side of the core to permit feed gas to enter and/or leave the core. Headers, nozzles and manifolds would not be required for the open sides of the cores.
  • While the heat exchanger as described above is utilized for condensing flow, the heat exchanger alternatively can be utilized to cool a fluid (either gas or liquid) without phase change. For example, a superheated gas stream can be cooled to a temperature above its dew point, while a liquid at or below its bubble point can be subcooled to a temperature further below its bubble point. In this alternative, the axis of the heat exchanger and the flow direction of the fluid being cooled (which is generally parallel to the axis of the exchanger) can be vertical, horizontal, or between vertical and horizontal. Thus the fluid being cooled can flow in any desired direction. [0067]
  • An alternative embodiment is shown in FIG. 2 which can be used when the feed gas is to be cooled or partially condensed in an upward flow direction, or when it is desirable to remove the vapor and liquid portions of the cooled and partially condensed gas as a mixed stream rather than as separate vapor and liquid streams. In this arrangement, feed gas [0068] 11 is introduced via inlet 201 of pressure vessel 203, and feed gas 205 flows into the open ends of heat exchangers 207 and 209. The gas condenses as it flows upward with the resulting condensate, and the two-phase vapor/liquid stream is withdrawn via collector fins and headers 211 and 213, manifolds 215, 217, and 219, and outlet 221 to provide final vapor/liquid product 223. Headers 211 and 213 and manifolds 215, 217, and 219 are generically described as fluid transfer means to transfer fluid from the ends of heat exchangers 207 and 209 to outlet 221. The refrigerant in this alternative embodiment can be provided as described earlier for the embodiment of FIG. 1.
  • The flow passageways are oriented such that the cocurrent flow of uncondensed feed gas and condensate is in a generally upward direction, i.e., in a vertical upward direction or in an upward direction which is between vertical and horizontal. The flow passageways deviate sufficiently from the horizontal such that the condensate flows upward by entrainment in the upward-flowing gas. Preferably, the flow is in a generally upward direction, which means that the flow is preferably vertically upward but can deviate from the vertical as long as the deviation does not adversely affect the upward cocurrent flow of uncondensed feed gas and entrained condensate through the exchanger and/or the transfer of heat from the uncondensed feed gas and condensate to the refrigerant. The refrigerant can flow upward as shown using a vaporizing fluid, or downward using a gaseous refrigerant, to maintain an adequate temperature difference between the feed and the refrigerant. [0069]
  • In the embodiments of FIGS. 1 and 2, [0070] heat exchangers 1 and 209 are open at the bottom and have a header and manifolds at the top of the exchanger. In an alternative embodiment (not shown), the heat exchanger is open at the top and has a header and manifolds at the bottom. Fluid flow in this alternative embodiment can be either upward or downward, and can be either single-phase or condensing flow as described above.
  • Another alternative embodiment of the invention is shown in FIG. 3 which illustrates the use of two heat exchangers in parallel, although single or more than two heat exchangers can be used if desired. In this embodiment, [0071] heat exchangers 301 and 303 are installed in pressure vessel 305, and seal means 307 (shown schematically) is installed between the heat exchanger and pressure vessel walls to segregate the vessel interior into upper section 309 and lower section 311 which are not in flow communication. Seal means 307 can be installed at any appropriate axial location between the upper and lower ends of heat exchangers 301 and 303. Seal means 307 can be any type of seal known in the art for segregating the upper and lower sections of the vessel against a low gas pressure differential, for example, 1 to 10 psi. Seal means 307 could be integrated with a core or piping support member.
  • The use of seal means [0072] 307 eliminates the need for feed distributor fins, headers, and manifolds at the top of the heat exchangers and processed gas collector fins, headers, and manifolds at the bottom of the heat exchangers. Thus the flow passageways or channels are open at both ends. The term “open” means that the end of the exchanger has no distributor fins, collector fins, or headers associated with it, and therefore fluid can flow unimpeded without restriction into and out of the ends of the flow channels. The heat transfer fins in the flow passageways can be continuous from the top to the bottom of the core, with no distributor or collector fins at either end. The bottom end of each feed channel is in flow communication with lower section 311 of pressure vessel 305, and the upper end of each feed channel is in flow communication with upper section 309 of the pressure vessel. The refrigerant circuits can be similar to those described in FIG. 1.
  • A portion of the flow passageways in the heat exchanger can be utilized for condensing service, and these passageways form a feed circuit through which the uncondensed feed gas and condensate flow cocurrently. The flow passageways are oriented such that the uncondensed feed gas and condensate flow cocurrently in a generally downward direction, i.e., in a vertical downward direction or in a downward direction which deviates from vertical wherein the flow passageways operate such that the condensate flows downward by the force of gravity. The generally downward direction is preferably vertical but can deviate from the vertical as long as the deviation does not adversely affect the downward cocurrent flow of uncondensed feed gas and condensate through the exchanger and/or the transfer of heat from the uncondensed feed gas and condensate to the refrigerant. [0073]
  • In this embodiment, feed [0074] gas stream 313 flows through vessel inlet 315, and interior feed gas 317 flows into upper section 309 of vessel 305 and then downward through the feed channels of heat exchangers 301 and 303. Condensation occurs as the gas and condensate flow downward through the feed channels, liquid 319 flows from the open ends of heat exchangers 301 and 303, and liquid 321 collects in the bottom of the vessel. Liquid product 323 is withdrawn via outlet 325 and uncondensed vapor 327 flows directly from the open feed channels at the lower ends of the heat exchangers and is withdrawn via vessel outlet 329 to provide vapor product 331.
  • While the heat exchanger of FIG. 3 as described above is utilized for condensing flow, the heat exchanger alternatively can be utilized to cool a fluid (either gas or liquid) without phase change. For example, a superheated gas stream can be cooled to a temperature above its dew point, while a liquid at or below its bubble point can be subcooled to a temperature further below its bubble point. In this alternative, the axis of the heat exchanger and the flow direction of the fluid being cooled (which is generally parallel to the axis of the exchanger) can be vertical, horizontal, or between vertical and horizontal. Thus the fluid being cooled can flow in any desired direction. [0075]
  • The advantage of the embodiment of FIG. 3 is that no manifolds, headers, distributor fins, or collector fins are needed at either end of [0076] heat exchangers 301 and 303 for feed introduction and product withdrawal. This greatly simplifies the entire heat exchanger assembly and results in reduced capital cost.
  • Two or more heat exchanger cores operating in different temperature or pressure ranges can be utilized in series or in parallel by stacking the pressure vessels in a vertical arrangement or by locating the vessels side-by-side. When used in series, the exit gas from a first heat exchanger is fed to a second heat exchanger for further cooling as described below. An internal head can be used inside a single pressure vessel to separate the warmer and colder heat exchangers as shown in the alternative embodiment of FIG. 4. In this embodiment, lower [0077] pressure vessel section 401 and upper pressure vessel section 403 are formed by head 405 installed in overall pressure vessel 407. Lower pressure vessel 401 and heat exchangers 409 and 411 installed therein are similar to the system described above for FIG. 3. Upper pressure vessel 403 and heat exchangers 413 and 415 are similar to the system described earlier for FIG. 1.
  • [0078] Feed gas 417 is processed in heat exchangers 413 and 415 in the same manner as that described earlier for exchangers 1 and 51 for the embodiment of FIG. 1. Intermediate vapor product 419 flows through vessel inlet 421 into upper portion 423 of pressure vessel 401, and is processed in the same manner as that described earlier for the embodiment of FIG. 3. First liquid product 425 is withdrawn via outlet 427. Vapor 429 condenses further in exchangers 409 and 411, which operate with a colder refrigerant than exchangers 413 and 415.
  • Additional liquid is condensed and [0079] condensate 431 flows out of the bottoms of heat exchangers 409 and 411, and collects in the bottom of vessel 401 as liquid 433. This liquid is withdrawn via outlet 435 to provide second liquid product stream 437, which contains additional higher boiling components. Vapor 439 flows from the bottoms of heat exchangers 409 and 411, and vapor product 441 is withdrawn via outlet 443. This vapor product is enriched in the more volatile components in feed gas 417.
  • [0080] Refrigerant 445 provides refrigeration to heat exchangers 413 and 415 as described earlier for the operation of heat exchangers 1 and 51 of FIG. 1. Refrigerant 449, which is at a lower temperature than refrigerant 445, provides refrigeration to heat exchangers 409 and 411 as described earlier for the operation of heat exchangers 301 and 303 of FIG. 3. The two sections of vessel 407 can utilize different numbers or sizes of heat exchangers, and the sections may be of different diameters.
  • The two vessel sections of FIG. 4 can be operated at different pressures if desired. In this mode of operation, [0081] vessel section 403 is operated at a higher pressure than vessel section 401, and uncondensed gas stream 419 is reduced in pressure before being introduced into inlet 421.
  • Several alternatives to the embodiment of FIG. 4 are possible. In one alternative, [0082] upper section 403 can be similar to bottom section 401, wherein both sections utilize heat exchangers open on both ends with seals to segregate the upper and lower portions of the exchangers. In another alternative, the bottom section 401 would contain heat exchangers identical to those in upper section 403 of FIG. 4. In yet another alternative, heat exchangers 409 and 411, with seal 447, can be located in upper section 403 while heat exchangers 413 and 415, with gas inlet headers and distributor fins, can be located in lower section 401.
  • In another alternative, an internal head or other arrangement, such as a chimney tray (not shown), can be used inside a single pressure vessel to separate the heat exchangers in [0083] sections 401 and 403. In this alternative, the vapor from the upper section can flow by means of the chimney tray directly into the lower section without flowing through external piping required for stream 419 of FIG. 4. The two sections of the pressure vessel can contain the same size or different sizes of heat exchangers, can contain the same or different numbers of heat exchangers, and can be of different diameters if necessary. The feed gas can flow either upward or downward in each of the heat exchangers as described earlier. The feed inlet, the processed gas/liquid outlet, or both the feed inlet and processed gas/liquid outlet of each of the heat exchangers can be open to the interior of the pressure vessel.
  • A common feature of all embodiments of the invention described above operating in condensing flow is that condensed liquid and uncondensed vapor flow through the channels of the core-type heat exchangers cocurrently, i.e., in the same direction. Preferably, flow is in a generally downward direction, but upward flow is used in at least one alternative embodiment as described above. When upward flow is used, the heat exchangers must be designed so that the upward gas flow velocity is sufficient to entrain the condensate such that essentially none of the condensate flows in a downward direction. [0084]
  • As discussed earlier, conventional full dome header distributor and collector devices typically cannot be used on cores larger than about 3 feet by 4 feet in cross section at pressures above about 150 psig. The pressure vessel for the present invention, however, can be designed to operate at any pressure level, preferably in the range of 100 to 1500 psia. The heat exchanger cores can be any size, both in cross-section and in length. Welded-blocks, i.e. two or more cores welded together side-by-side, can be utilized to increase the available cross-section of the heat exchanger cores to a very large size, such as 4 feet by 8 feet or more. Any length of core can be used, and is typically in the range of 5 to 20 feet. [0085]
  • The pressure vessel can be externally insulated, similar to a distillation column, so that no cold box is required for the heat exchangers. When parallel heat exchanger cores are used, the number of pipes which must pass through the pressure vessel shell can be minimized by manifolding refrigerant stream nozzles inside the pressure vessel. Refrigerant drums can also be located either inside or outside the pressure vessel, as desired. [0086]
  • In other alternative embodiments, three or more heat exchangers, each operating at progressively colder temperatures, can be installed in series within a single pressure vessel, or in separate vessels, or a combination of stacked and separate pressure vessels. Any combination of feed flow direction and open core ends/sides can be used in each of the heat exchangers. All refrigerant streams entering or leaving the heat exchangers typically would utilize conventional distributors, collectors, headers, and nozzles, which are piped through the vessel shell. [0087]
  • When two or more heat exchangers are utilized in series in either stacked or separate pressure vessels, one or more of the heat exchangers can be replaced by a dephlegmator. In the dephlegmator, feed gas enters the pressure vessel, flows into the open bottom end of the core and upward through the core. Condensed liquid drains downward, and rectification occurs as the liquid and vapor flow countercurrently in the core. Condensate exits freely from the bottom of the core into the bottom of the vessel for removal. The feed vapor outlet at the top end of the dephlegmator may be either open or closed. All refrigerant streams entering or leaving the dephlegmator typically would utilize conventional distributors, collectors, headers, and nozzles. [0088]
  • Thus the present invention simplifies the design of plate-and-fin heat exchanger cores which operate in the condensing mode and allows efficient use of the core cross section because no manifolds, distributor fins, and headers are required at the inlet of each feed circuit. In an optional embodiment, vapor collector fins, manifolds, and headers are not required at the outlet of each feed circuit, further simplifying heat exchanger design and operation. The present invention allows operation of plate-and-fin core-type heat exchangers at higher pressures than many prior art systems which require dome headers or similar integrated vessels attached to the heat exchanger feed circuits. In addition, higher throughput is possible because the available fluid handling capacity of each heat exchanger is not reduced by distributors, collectors, headers, nozzles, or manifolds. [0089]
  • The essential characteristics of the present invention are described completely in the foregoing disclosure. One skilled in the art can understand the invention and make various modifications without departing from the basic spirit of the invention, and without deviating from the scope and equivalents of the claims which follow. [0090]

Claims (28)

1. A system for cooling a fluid feed stream which comprises:
(a) a pressure vessel having an interior and an exterior;
(b) a heat exchanger installed in the interior of the pressure vessel, wherein the heat exchanger comprises a group of flow passageways which has a first end and a second end, wherein at least one of the first end and the second end is open and in flow communication with the interior of the pressure vessel;
(c) inlet piping means for introducing the fluid feed stream into the interior of the pressure vessel;
(d) outlet piping means for withdrawing from the interior of the pressure vessel at least a portion of the cooled fluid stream;
(e) cooling means for indirectly cooling the group of flow passageways to cool the fluid feed stream therein to form a cooled fluid stream; and
(f) fluid transfer means for transferring the fluid feed stream from the inlet piping means into the group of flow passageways at one end thereof or for transferring a cooled fluid stream from one end of the group of flow passageways to the outlet piping means.
2. The system of claim 1 wherein the heat exchanger is constructed in a plate-and-fin configuration.
3. The system of claim 1 wherein the cooling means of (e) comprises
(1) one or more additional groups of flow passageways in the heat exchanger wherein each additional group of flow passageways has a first end and a second end, and wherein each additional group of flow passageways is in indirect heat transfer communication with the group of flow passageways of (b);
(2) inlet piping means for introducing refrigerant into the interior of the pressure vessel;
(3) outlet piping means for withdrawing warmed refrigerant from the interior of the pressure vessel;
(4) inlet distributor means for distributing the refrigerant from the inlet piping into the first end of the additional group of flow passageways; and
(5) outlet collector means for collecting the warmed refrigerant from the second end of the additional group of flow passageways and directing warmed refrigerant into the outlet piping means.
4. The system of claim 1 which further comprises
(g) an additional pressure vessel having an interior and an exterior;
(h) a heat exchanger installed in the interior of the additional pressure vessel, wherein the heat exchanger comprises a group of flow passageways which has a first end and a second end, wherein at least one of the first end and the second end is open and in flow communication with the interior of the additional pressure vessel;
(i) inlet piping means for introducing an intermediate fluid stream into the interior of the additional pressure vessel;
(j) cooling means for indirectly cooling the group of flow passageways to cool the intermediate fluid stream therein to form an additional cooled fluid stream;
(k) outlet piping means for withdrawing from the interior of the additional pressure vessel at least a portion of the additional cooled fluid stream; and
(l) fluid transfer means for transferring the fluid feed stream from the inlet piping means into the group of flow passageways at one end thereof or for transferring a cooled fluid stream from one end of the group of flow passageways to the outlet piping means.
5. The system of claim 4 which further comprises piping means connecting the outlet piping means of (d) with the inlet piping means of (i) such that at least a portion of the cooled fluid stream withdrawn from the pressure vessel can provide the intermediate fluid stream to the additional pressure vessel.
6. The system of claim 1 wherein the first end of the flow passageways is an upper end and the second end of the flow passageways is a lower end, and wherein the lower end is open and in flow communication with a lower region in the interior of the pressure vessel.
7. The system of claim 6 wherein the heat exchanger is constructed in a plate-and-fin configuration.
8. The system of claim 6 wherein the fluid transfer means comprises outlet manifold means and outlet header means for transferring a cooled fluid stream from the upper end of the group of flow passageways to the outlet piping.
9. The system of claim 8 wherein the inlet piping means is connected to a lower end of the pressure vessel and the outlet piping means is connected to an upper end of the pressure vessel such that fluid can flow through the group of flow passageways in a generally upward direction.
10. The system of claim 6 wherein the fluid transfer means comprises inlet manifold means and inlet header means for transferring the fluid feed stream from the inlet piping into the upper end of the group of flow passageways.
11. The system of claim 10 wherein the inlet piping means is connected to an upper end of the pressure vessel and the outlet piping means is connected to a lower end of the pressure vessel such that fluid can flow through the group of flow passageways in a generally downward direction.
12. The system of claim 11 wherein the fluid flowing generally downward through the group of flow passageways is a gas which can condense therein to form a vapor and a liquid which flow into the lower end of the pressure vessel, wherein the outlet piping means of (d) is used for withdrawing vapor from the lower end of the pressure vessel, and wherein the system includes additional outlet piping means used for withdrawing liquid from the lower end of the pressure vessel.
13. The system of claim 6 which further comprises
(g) an additional pressure vessel having an interior and an exterior;
(h) a heat exchanger installed in the interior of the additional pressure vessel, wherein the heat exchanger comprises a group of flow passageways which has a first end and a second end, wherein at least one of the first end and the second end is open and in flow communication with the interior of the additional pressure vessel;
(i) inlet piping means for introducing an intermediate fluid stream into the interior of the additional pressure vessel;
(j) inlet fluid transfer means for transferring the intermediate fluid stream from the inlet piping means into the group of flow passageways at one end thereof;
(k) cooling means for indirectly cooling the group of flow passageways to cool the intermediate fluid stream therein to form an additional cooled fluid stream; and
(l) outlet piping means for withdrawing from the interior of the pressure vessel at least a portion of the additional cooled fluid stream.
14. The system of claim 13 which further comprises piping means connecting the outlet piping means of (d) with the inlet piping means of (i) such that at least a portion of the vapor withdrawn from the pressure vessel can provide the intermediate fluid stream to the additional pressure vessel.
15. The system of claim 14 wherein the heat exchanger in the additional pressure vessel is constructed in a plate-and-fin configuration.
16. The system of claim 14 wherein the inlet piping means is connected to an upper end of the additional pressure vessel and the outlet piping means is connected to a lower end of the additional pressure vessel such that vapor can flow through the group of flow passageways in a generally downward direction.
17. The system of claim 16 wherein the vapor flowing generally downward through the group of flow passageways can condense therein to form an uncondensed vapor and a liquid which flow into the lower end of the additional pressure vessel, wherein the outlet piping means of (I) is used for withdrawing the uncondensed vapor from the lower end of the additional pressure vessel, and wherein the system includes additional outlet piping means used for withdrawing liquid from the lower end of the additional pressure vessel.
18. The system of claim 1 wherein the first end of the flow passageways is an upper end and the second end of the flow passageways is a lower end, and wherein the upper end is open and in flow communication with an upper region in the interior of the pressure vessel.
19. The system of claim 18 wherein the heat exchanger is constructed in a plate-and-fin configuration.
20. The system of claim 18 wherein the fluid transfer means comprises inlet manifold means and inlet header means for transferring the fluid feed stream from the inlet piping into the lower end of the group of flow passageways.
21. The system of claim 20 wherein the inlet piping means is connected to a lower end of the pressure vessel and the outlet piping means is connected to an upper end of the pressure vessel such that fluid can flow through the group of flow passageways in a generally upward direction.
22. The system of claim 18 wherein the fluid transfer means comprises outlet manifold means and outlet header means for transferring the cooled fluid stream from the lower end of the group of flow passageways to the outlet piping means.
23. The system of claim 21 wherein the inlet piping means is connected to an upper end of the pressure vessel and the outlet piping means is connected to a lower end of the pressure vessel such that fluid can flow through the group of flow passageways in a generally downward direction.
24. A system for cooling a fluid feed stream which comprises:
(a) a pressure vessel having an interior and an exterior;
(b) a heat exchanger installed in the interior of the pressure vessel, wherein the heat exchanger comprises a group of flow passageways having a first end and a second end, wherein the first end is open and in flow communication with a first end of the interior of the pressure vessel and the second end is open and in flow communication with a second end of the interior of the pressure vessel;
(c) cooling means for indirectly cooling the group of flow passageways to cool the fluid feed stream therein to form a cooled fluid stream;
(d) inlet piping means for introducing the fluid feed stream into the first end of the interior of the pressure vessel;
(e) outlet piping means for withdrawing at least a portion of the cooled fluid stream from the second end of the interior of the pressure vessel; and
(f) seal means disposed in the pressure vessel at an axial location between the first and second ends of the group of flow passageways, which seal means isolates the first end of the interior of the pressure vessel from the second end of the interior of the pressure vessel such that the first and second ends of the interior of the pressure vessel are not in flow communication.
25. The system of claim 24 wherein the heat exchanger is constructed in a plate-and-fin configuration.
26. The system of claim 24 wherein the inlet piping means is connected to a lower end of the pressure vessel and the outlet piping means is connected to an upper end of the pressure vessel such that fluid can flow through the group of flow passageways in a generally upward direction.
27. The system of claim 24 wherein the inlet piping means is connected to an upper end of the pressure vessel and the outlet piping means is connected to a lower end of the pressure vessel such that fluid can flow through the group of flow passageways in a generally downward direction.
28. The system of claim 27 wherein the fluid flowing generally downward through the group of flow passageways is a gas which can condense therein to form a vapor and a liquid which flow into the lower end of the pressure vessel, wherein the outlet piping means of (e) is used for withdrawing vapor from the lower end of the pressure vessel, and wherein the system includes additional outlet piping means used for withdrawing liquid from the lower end of the pressure vessel.
US09/852,361 2001-05-09 2001-05-09 Heat exchanger column Abandoned US20020166656A1 (en)

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Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102007054772A1 (en) * 2007-05-18 2008-11-20 Messer Group Gmbh Device for cooling material flows
US20130068422A1 (en) * 2011-09-15 2013-03-21 Alan Mark Horowitz System and method for recycling energy from ice remnants
US20140196499A1 (en) * 2013-01-14 2014-07-17 Alstom Technology Ltd. Stripper overhead heat integration system for reduction of energy consumption
GB2571945A (en) * 2018-03-13 2019-09-18 Linde Ag Method for operating a natural gas processing plant
FR3100609A1 (en) * 2019-09-09 2021-03-12 L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude Device, installation and method of heat exchange.
EP3808437A1 (en) * 2010-02-22 2021-04-21 Life Technologies Corporation Condenser assembly, and related method for condensing a humid gas
US11229855B2 (en) 2014-03-21 2022-01-25 Life Technologies Corporation Condenser systems for processing a fluid
US11554335B2 (en) 2014-03-21 2023-01-17 Life Technologies Corporation Methods for gas filteration in fluid processing systems

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102007054772A1 (en) * 2007-05-18 2008-11-20 Messer Group Gmbh Device for cooling material flows
DE102007054772B4 (en) * 2007-05-18 2009-11-26 Messer Group Gmbh Device for cooling material flows
EP3808437A1 (en) * 2010-02-22 2021-04-21 Life Technologies Corporation Condenser assembly, and related method for condensing a humid gas
US11492582B2 (en) 2010-02-22 2022-11-08 Life Technologies Corporation Heat exchanger system with flexible bag
US20130068422A1 (en) * 2011-09-15 2013-03-21 Alan Mark Horowitz System and method for recycling energy from ice remnants
US20140196499A1 (en) * 2013-01-14 2014-07-17 Alstom Technology Ltd. Stripper overhead heat integration system for reduction of energy consumption
US11229855B2 (en) 2014-03-21 2022-01-25 Life Technologies Corporation Condenser systems for processing a fluid
US11554335B2 (en) 2014-03-21 2023-01-17 Life Technologies Corporation Methods for gas filteration in fluid processing systems
US11717768B2 (en) 2014-03-21 2023-08-08 Life Technologies Corporation Condenser bag for processing a fluid
GB2571945A (en) * 2018-03-13 2019-09-18 Linde Ag Method for operating a natural gas processing plant
FR3100609A1 (en) * 2019-09-09 2021-03-12 L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude Device, installation and method of heat exchange.

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