US20020032133A1 - Foaming body-cleansing agents

Info

Abstract

Description

Claims

US20020032133A1

Publication number: US20020032133A1
Application number: US09/319,192
Authority: US
Inventors: Heike Schelges; Wolfhard Scholz; Gryta Schosser
Original assignee: Henkel AG and Co KGaA
Current assignee: Henkel AG and Co KGaA
Priority date: 1996-12-02
Filing date: 1997-11-24
Publication date: 2002-03-14
Anticipated expiration: 2017-11-24
Also published as: SK73099A3; HUP0000361A2; NO992630D0; DE59709526D1; NO992630L; ES2195191T3; CA2273340A1; HUP0000361A3; EP0942713A1; SK282097B6; WO1998024409A1; CN1239424A; DE19649895A1; US6391834B1; ATE234072T1; EP0942713B1; CZ195099A3; CZ289737B6

This invention concerns foaming aqueous compositions of body-cleansing agents containing anionic surfactants (A) with a strong foaming action and alkyl-(oligo)-glucosides (B) which are easily tolerated by the skin, and a combination of a zwitterionic surfactant (C). e.g., a betaine surfactant, and an ampholytic surfactant (D). e.g. a cocoamphoglycinate, to improve foaming properties and viscosity. Combining betaine and ampholytic surfactants yields a particularly creamy foam structure, consisting of particularly tiny bubbles when using said compositions.

This invention relates to foaming body-cleansing compositions in the form of a liquid surfactant composition based on a combination of high-foaming anionic surfactants and foam-boosting alkyl (poly)glycosides which contain a combination of a zwitterionic surfactant and an ampholytic surfactant for further improving the properties of the foam, more particularly its fine-bubble character and its stability (creaminess).

Liquid body-cleansing compositions which are marketed, for example, as liquid soaps, shampoos, shower bath preparations and foam bath additives are not only expected to have a good cleansing effect, they are also expected to show high skin and mucous membrane compatibility and not to overly degrease or dry the skin, even in the event of frequent use. In addition to this, however, consumers also evaluate performance properties according to the quality and quantity of the foam formed in use. In particular, consumers look for rapid initial foaming with formation of a fine-bubble and stable foam, these properties of the foam also being generally described as creaminess.

The body-cleansing formulations themselves are also expected to be distinguished by a certain viscosity so that, for example, they can be applied to the hand and do not trickle through the fingers before they can be spread over the body or the head.

There are many known surfactants which are kind to the skin and compatible with the mucous membrane. However, there are only a few surfactants which meet the additional need for a certain viscosity of the aqueous solution and for a fine-bubble character of the foam. For this reason, combinations of various surfactants have always been used hitherto in order to satisfy these various requirements. Thus, a combination of alkyl ether sulfate surfactants and alkyl (poly)glucosides has proved to be particularly high-foaming and dermatologically compatible. In addition, zwitterionic surfactants or betaine surfactants and ampholytic surfactants are known for their ability, in combination with anionic surfactants, to improve the dermatological compatibility of those surfactants and to impart a relatively high viscosity to aqueous preparations or to improve their thickenability by electrolyte salts.

DE-A42 34 487, for example,describes an aqueous detergent composition containing alkyl sulfate surfactants, alkyl ether sulfate surfactants, alkyl (oligo)glucosides and amphoteric or zwitterionic surfactants.

However, it has now been found that the properties of the foam, more especially its fine-bubble character and stability, can be further improved by using a combination of a zwitterionic surfactant and an ampholytic surfactant instead of a betaine surfactant or ampholytic surfactant.

Accordingly, the present invention relates to aqueous body-cleansing compositions containing high-foaming, dermatologically compatible anionic surfactants (A) and alkyl (oligo)glycosides (B), characterized in that they contain a combination of a zwitterionic surfactant (C) corresponding to formula I:

and an ampholytic surfactant (D) corresponding to formula II:

in which R ¹is an alkyl or alkenyl group containing 12 to 18 carbon atoms or a group R⁵—CONH—(CH₂)_n, where R⁵is an alkyl or alkenyl group containing 12 to 18 carbon atoms and n is a number of 2 to 4, and R², R³and R⁴are alkyl groups containing 1 to 4 carbon atoms or hydroxyalkyl groups containing 2 or 3 carbon atoms,

in a ratio by weight of (A) to (B) to (C+D) of 10:(0.5-5):(1-5)

in order further to improve their foam properties and their viscosity.

High-foaming, dermatologically compatible anionic surfactants (A) are known to the expert in large numbers from relevant handbooks and are commercially available. More particularly, they are alkyl sulfates in the form of their ammonium or alkanolammonium salts, alkyl ether sulfates, alkyl ether carboxylates, acyl isethionates, acyl sarcosinates, acyl taurines with linear alkyl or acyl groups containing 12 to 18 carbon atoms and in the form of their alkali metal or ammonium salts. The anionic surfactants (A) may be present in the compositions according to the invention in a quantity of 3 to 30% by weight. Particularly preferred anionic surfactants are alkyl ether sulfates. Accordingly, at least one alkyl ether sulfate surfactant corresponding to the formula III:

R⁶O(C₂H₄O)_m—SO ₃ ⁽⁻⁾M⁽⁺⁾ (III)

in which R ⁶is an alkyl or alkenyl group containing 12 to 18 carbon atoms, m=1-4 and M(+) is an alkali metal, magnesium, ammonium or alkanol-ammonium ion, is preferably present as the anionic surfactant in a quantity of at least 5% by weight, based on the composition as a whole.

Alkyl (oligo)glycosides (B) are well-known surface-active substances which can be produced from sugars and aliphatic primary alcohols containing 8 to 22 carbon atoms by acetalization. Sugar components (glycoses) include—preferably—glucose and also fructose, mannose, galactose, talose, gulose, allose, idose, arabinose, xylose, lyxose, ribose and mixtures thereof. The acetalization products of glucose with fatty alcohols obtainable, for example, from natural oils and fats by known methods are preferably used by virtue of their ready accessibility and their favorable applicational properties.

So far as the glycoside unit is concerned, both monoglycosides and oligoglycosides where a sugar unit is attached to the fatty alcohol by a glycosidic bond are suitable. Mixtures of mono- and oligoglucosides are usually present in the commercially available products.

Preferred alkyl (oligo)glycosides (B) are those with the formula R ⁷(G)_x, where R⁷is a linear alkyl group containing 8 to 16 carbon atoms and (G)_xis an (oligo)glucoside unit with an average degree of oligomerization x of 1 to 2.

Such products are commercially available, for example, under the trade mark Plantaren® or Plantacare®).

Zwitterionic surfactants (C) corresponding to formula I are also well-known and are commercially available in large numbers. The most well known and most widely used group of these surfactants are the betaine surfactants in which R ²and R³are methyl groups. Among the betaine surfactants, there are the alkyl betaines where R¹is an alkyl or alkenyl group and the amidobetaines where R¹is a group R⁵CONH—(CH₂)_n—. A cocoamidopropyl betaine of formula I, where R¹is a group R⁵CONH-—(CH₂)₃ 13 , in which R⁵CO is derived from a C_12-18cocofatty acid or palm kernel oil fatty acid, and R²and R³are methyl groups, is preferably used for the purposes of the invention. Such products are commercially available, for example, under the trade mark Dehyton®K.

Ampholytic surfactants (D) corresponding to formula II are also known and commercially available surfactants. They have the ability to react like cationic surfactants in acidic solution by protonation at the tertiary nitrogen atom and like anionic surfactants in the alkaline range by salt formation at the carboxyl group. A preferred ampholytic surfactant (D) is a cocoamphoglycinate corresponding to formula II where R ¹is a group R⁵CONH—(CH₂)₂—, in which R⁵CO is derived from a C_12-18cocofatty acid or palm kernel oil fatty acid, and R⁴is a hydroxyethyl group. One such surfactant is commercially available, for example, under the trade mark Dehyton®G.

Particularly favorable foam properties, more especially fine bubbles and creaminess, are obtained when the zwitterionic surfactant (C) and the ampholytic surfactant (D) are present in a ratio by weight of (C) to (D) of 1:(0.1-0.5).

Besides the compulsory components (A), (B), (C) and (D), the foaming aqueous preparations according to the invention may also contain other surfactants and additives. In quantitative terms, these other ingredients together should not make up any more than component (A).

Suitable other additives are, for example, nonionic surfactants, water-soluble polymers, for example cationic polymeric conditioners, pearlescers, dyes, fragrances and emulsifiers suitable therefor, water-soluble polyols such as, for example, glycerol, sorbitol, propylene glycol or polyethylene glycol, electrolyte salts, pH regulators and cosmetic or dermatological agents.

If the total content of components (A) and (B) is less than 10% by weight, the viscosity of body-cleansing compositions according to the invention may still be unsatisfactory. One particular advantage of the compositions according to the invention is that, in cases such as these, viscosity can readily be increased by the addition of water-soluble inorganic electrolyte salts.

Suitable inorganic electrolyte salts are any water-soluble alkali metal, ammonium and alkaline earth metal salts, for example the fluorides, chlorides, bromides, sulfates, phosphates, nitrates and hydrogen carbonates, providing they are soluble in water at 20° C. in a quantity of at least 1% by weight. Sodium chloride and magnesium chloride are preferably used.

The body-cleansing compositions according to the invention may be formulated as highly concentrated pastes with a water content of less than 30% by weight H ₂O or as dilute aqueous solutions containing less than 5% by weight of the anionic surfactant (A). However, the content of anionic surfactants (A) is preferably in the range from 5 to 20% by weight. In this range, body-cleansing compositions according to the invention suitable for use as shampoos or shower gels can be formulated with viscosities in the range from about 1 to 200 Pa-s (20° C.).

The following Examples are intended to illustrate the invention:

EXAMPLES

I. Surfactants Used



Texapon ®	C_12/14cocofatty alcohol-2 EO-adduct sulfate, Na
N70:	salt (70% paste)
Dehyton ®	Cocoamidopropyl Betaine (30% solution)
K:	(+) (−)
	R—CONH—(CH₂)₃—N(CH₃)₂—CH₂COO
	R¹CO = acyl group of C_8-18cocofatty acid
Dehyton ®	Cocoamphocarboxyglycinate (30% solution)
G:	R²—CONH—(CH₂)₂—NH(CH₂CH₂OH)CH₂—COOH
	R²CO = acyl group of C_8-18cocofatty acid
Plantacare ®	C_8-14alkyl polyglucoside (50% solution)
818:	R³—(G)_x, R³= C_8-14-n-alkyl group
	x = 1.4 G = glucoside unit
Cetiol ®	PEG7 Glyceryl Cocoate
HE:
Euperlan ®	Pearlescing concentrate containing glycol di-
PK810:	stearate and Texapon N70.

Evaluation of Foam Volume and Quality

Foaming behavior and foam properties were tested in a standardized arm washing test. 2 g of the composition were applied to the wet hand and spread over the hands and forearms. After 1 minute, the composition was washed off with water (15° C.). Foaming behavior, foam volume and creaminess were evaluated by ten examiners. Their scores were averaged (1=poor, 2=adequate, 3=good, 4=very good). [0028]

Formulations

Texapon N 70	15	15	15	17	18	16
Plantaren 818	2	2	2	4	—	—
Dehyton K	6	8	—	—	—	6
Dehyton G	2	—	8	—	2	2
Eurperlan PK 810	2	2	2	2	2	2
Cetiol HE	0.5	0.5	0.5	0.5	0.5	0.5
Merguat 550	0.5	0.5	0.5	0.5	0.5	0.5
Sorbitol	1.5	1.5	1.5	1.5	1.5	1.5
Glycerol	1.0	1.0	1.0	1.0	1.0	1.0
Sodium benzoate	0.4	0.4	0.4	0.4	0.4	0.4
Lactic acid	0.1	0.1	0.1	0.1	0.1	0.1
Citric acid	0.4	0.4	0.4	0.4	0.4	0.4
Perfumeoil	1.3	1.3	1.3	1.3	1.3	1.3
Water	67.3	67.3	67.3	71.3	72.3	68.3
NaCI	0.2	0.2	0.2	0.2	0.2	0.2
Foaming behavior	2.9	2.1	1.8	2.0	2.0	1.9
Foam volume	3.0	2.3	2.0	2.0	2.0	1.9
Creaminess, fine-bubble	3.5	2.2	2.5	2.1	2.1	2.1
character
Viscosity Pa · s (20° C.)	9.5	4.0	15.4	<1.0	<1.0	6.1
Haake Rotovisko, Spindle 2

% by weight

1. A foaming aqueous body-cleansing composition containing high-foaming, dermatologically compatible anionic surfactants (A) and alkyl (oligo)glycosides (B), characterized in that it contains a combination of a zwitterionic surfactant (C) corresponding to formula I:

and an ampholytic surfactant (d) corresponding to formula II:

in which R¹is an alkyl or alkenyl group containing 12 to 18 carbon atoms or a group R⁵—CONH—(CH₂)_m, where R⁵is an alkyl or alkenyl group containing 12 to 18 carbon atoms and n is a number of 2 to 4, and R², R³and R⁴are alkyl groups containing 1 to 4 carbon atoms or hydroxyalkyl groups containing 2 or 3 carbon atoms,

in a ratio by weight of (A) to (B) to (C+D) of 10:(0.5-5):(1-5)

in order further to improve its foam properties and its viscosity.

2. A foaming body-cleansing composition as claimed in claim 1, characterized in that at least one alkyl ether sulfate surfactant corresponding to formula III:

R⁶O(C₂H₄O)_m—SO₃ ^{(−) M} ⁽⁺⁾ (III)

in which R⁶is an alkyl or alkenyl group containing 12 to 18 carbon atoms, m=1-4 and M(+) is an alkali metal, magnesium, ammonium or alkanol-ammonium ion,

is present as the anionic surfactant in a quantity of at least 5% by weight.

3. A foaming body-cleansing composition as claimed in claim 1, characterized in that an alkyl glucoside with the formula R⁷(G)_x, where R⁷is a linear alkyl group containing 8 to 16 carbon atoms and (G)_xis an (oligo)glucoside unit with a degree of oligomerization x of 1 to 2, is present as the alkyl (oligo)glycoside.

4. A foaming body-cleansing composition as claimed in any of claims 1 to 3, characterized in that a cocoamidopropyl betaine corresponding to formula I, in which R¹is a group R⁵CONH—(CH₂)₃—, in which R⁵CO is derived from a C_12-18cocofatty acid or palm kernel oil fatty acid, and R²and R³are methyl groups is present as the zwitterionic surfactant (C).

5. A foaming body-cleansing composition as claimed in any of claims 1 to 4, characterized in that a cocoamphoglycinate corresponding to formula II where R¹is a group R⁵CONH—(CH₂)₂—, in which R⁵CO is derived from a C_12-18cocofatty acid or palm kernel oil fatty acid, and R⁴is a hydroxy ethyl group is present as the ampholytic surfactant (D).

6. A foaming body-cleansing composition as claimed in any of claims 1 to 5, characterized in that the zwitterionic surfactant (C) and the ampholytic surfactant (D) are present in a ratio by weight of (C) to (D) of 1:(0.1-0.5).