US20020009516A1 - Injection molding nozzle tip insulator, method for insulating same, and injection molding device - Google Patents

Injection molding nozzle tip insulator, method for insulating same, and injection molding device Download PDF

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US20020009516A1
US20020009516A1 US09/170,054 US17005498A US2002009516A1 US 20020009516 A1 US20020009516 A1 US 20020009516A1 US 17005498 A US17005498 A US 17005498A US 2002009516 A1 US2002009516 A1 US 2002009516A1
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Prior art keywords
nozzle tip
insulator
nozzle
injection molding
tip insulator
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US6428305B2 (en
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Edward J. Jenko
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Husky Injection Molding Systems Ltd
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C45/00Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
    • B29C45/17Component parts, details or accessories; Auxiliary operations
    • B29C45/26Moulds
    • B29C45/27Sprue channels ; Runner channels or runner nozzles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C45/00Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
    • B29C45/17Component parts, details or accessories; Auxiliary operations
    • B29C45/26Moulds
    • B29C45/27Sprue channels ; Runner channels or runner nozzles
    • B29C2045/2766Heat insulation between nozzle and mould
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C45/00Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
    • B29C45/17Component parts, details or accessories; Auxiliary operations
    • B29C45/26Moulds
    • B29C45/27Sprue channels ; Runner channels or runner nozzles
    • B29C45/278Nozzle tips
    • B29C2045/2787Nozzle tips made of at least 2 different materials

Definitions

  • the present invention relates to the field of injection molding. More particularly, the invention relates to insulating nozzle tips used, for example, in thermoplastic molding.
  • Injection molding takes plastic pellets and converts them to a broad array of useful items such as bottles, other types containers, and toys.
  • One example of a device for performing this process has a hopper for holding a quantity of the pellets.
  • a passage links the hopper with a manifold. In the passage, the pellets melt through the action of a screw pushing the pellets along the passage, and heaters warming the passage.
  • the molten plastic reaches the manifold, and is injected through one or more nozzle assemblies into a mold.
  • Each nozzle assembly has an opening for receiving the molten material from the manifold.
  • An elongated portion of the nozzle assembly guides the molten material to its tip.
  • Each nozzle tip has one or more orifices for ejecting the molten material into the mold.
  • a heating assembly in each nozzle assembly maintains the plastic material in a molten state until it is injected into the mold.
  • the entry orifice in the mold for receiving the molten material is sized to accommodate at least a part of the nozzle assembly. Once the molten material reaches the mold, it is rapidly cooled to form the desired shape. To facilitate cooling of the molten material, some molds incorporate channels through which cooling water flows.
  • a number of molds may be arranged in a turret, with the nozzle assembly positioned so that it can be inserted at the gate to the mold.
  • the molten material is then injected into the mold through one or more orifices in the distal end of the nozzle assembly, the nozzle assembly is removed from the mold, and the turret turns a predetermined distance to align the gate of another mold with the nozzle assembly. This process then repeats.
  • the cooler mold may reduce the temperature of the nozzle tip, and hence the temperature of molten material. This causes two problems:
  • U.S. Pat. No. 5,569,475 to Adas et al. describes a thermal insulator between the nozzle assembly and the surrounding molding plates.
  • This patent describes using, preferably, a ceramic insulator such as zirconia oxide.
  • a thin layer of the zirconia oxide is sprayed onto either the opening in the mold plate, or onto the nozzle body. If a spray-on coating is used, the nozzle body can first be roughened, and an undercoat, such as nickel-aluminum, applied to the nozzle body to assist with bonding.
  • a protective coating may be sprayed onto the insulator layer.
  • the protective coating should be a wear-resistant and machinable material, preferably a metal such as titanium, nickel, or molybdenum. This metallic protective layer then contacts the mold.
  • U.S. Pat. No. 5,474,439 to McGrevy discloses a cap (a titanium insulator) tightly disposed on the nozzle body by heating.
  • the cap has a gate well, an opening that aligns with the orifice of the nozzle.
  • the cap has projections with indentations therebetween on an outer surface of the cap.
  • the projections abut the mold.
  • the indentations are filled with air, and these air gaps help to maintain the projections abutting the mold at an ambient temperature even when heated fluid flows through the gate wells. This, the patent asserts, maintains the desired relationship between the projections and the mold.
  • U.S. Pat. No. 5,324,191 to Schmidt discloses a sealed edge gate for an injection molding system.
  • the Schmidt patent describes placing a seal ring around the tip end of the nozzle housed within a recess in a mold plate.
  • the seal ring is made of a material with a lower thermal coefficient of expansion than that of the nozzle material.
  • the seal ring could be made of titanium, where the nozzle is made of steel or copper alloy. With this arrangement, the expansion of the nozzle will press the seal ring outward against the wall of the mold plate, and will more tightly grip the seal ring.
  • Bubble grooves may be included in the seal ring, the grooves communicating with the nozzle orifices. In this way, plastic material fills the groove and acts as a thermal insulator to minimize the heat transferred via the seal ring to the mold cavity plate.
  • the sleeve has two components.
  • the first component is elastically yieldable.
  • the second component located upstream of the first component, is rigid. That is, the two components of the sleeve are arranged serially along a longitudinal direction of the nozzle.
  • the first component may be made of an elastomeric, fluoroplastic, or silicone material which does not degrade at the operating temperature of the nozzle.
  • the second component may be made of liquid crystal aromatic polyester copolymers, polyimides, polyethersulfones.
  • the second component may be termed a back-up ring and provides alignment between the nozzle and the die cavity, while being sufficiently rigid to keep the first component from being displaced.
  • VespelTM is useful as an insulator since it is rated to a continuous use temperature of approximately 260° C. [500°].
  • many resins are now processed at higher temperatures which cause polymer degradation and cracking of the known VespelTM nozzle tip insulator.
  • Titanium is not an optimum insulator since it conducts too much heat and because it does not always seal properly (e.g., titanium can withstand only a small preload, such as 0.1 mm). If the hot tip positions and/or the gate detail ball dimensions are out of specification, the preload that a titanium insulator can withstand becomes even smaller, and a gap may be created.
  • a “gate bubble” may form in which molten material leaks from the orifice(s) of the nozzle. This leaked material then cools and becomes less fluid. Consequently, the material may clog the nozzle orifice(s) and/or seal the gate opening in the mold, interfering with the molding process.
  • one aspect of the invention comprises a nozzle tip insulator having inner and outer annular portions.
  • the inner annular portion contacts the injection molding nozzle tip, and the outer annular portion contacts the inner annular portion.
  • the outer annular portion is less thermally conductive than the inner annular portion. That is, the insulator has a stepped heat gradient profile from an inside to an outside thereof.
  • the invention is directed to an injection molding nozzle tip insulator including an inner conductive portion and an outer insulative portion.
  • the outer insulative portion surrounds the inner portion, and an inner surface of the outer portion contacts an outer surface of the inner portion along at least a portion of the surfaces.
  • the inner conductive portion may be, or include, titanium.
  • the outer insulative portion may be, or include, VespelTM.
  • the present invention is directed to a nozzle tip insulator for use with an injection molding nozzle tip.
  • the insulator according to this embodiment includes an inner conductive ring and an outer insulative ring.
  • the outer insulative ring is concentric with the inner ring, with an inner surface of the outer ring contacting an outer surface of the inner ring.
  • the outer insulative ring is less heat-conductive than the inner conductive ring.
  • Yet another aspect of the invention is an injection molding device including a mold with an opening, and a nozzle assembly for contacting the opening.
  • the nozzle assembly includes a nozzle tip having at least one opening through which molten material passes, and a nozzle tip insulator surrounding the nozzle tip.
  • the nozzle tip insulator in turn, includes an inner conductive portion, and an outer insulative portion surrounding the inner portion. An inner surface of the outer portion contacting an outer surface of the inner portion along at least a portion of the surfaces.
  • a further aspect of the present invention encompasses an injection molding nozzle tip insulator including inner means, in contact with a nozzle tip, for conducting heat, and outer means for insulating the heat conducted by the inner means.
  • the outer means surrounding the inner means, an inner surface of the outer means contacting an outer surface of the inner means along at least a portion of the surfaces.
  • Another aspect of the present invention is directed to a method for insulating an injection molding nozzle tip.
  • the method includes steps of (1) providing an inner annular portion in contact with an injection molding nozzle tip, and (2) providing an outer annular portion in contact with the inner annular portion, the outer annular portion being less thermally conductive than the inner annular portion so that the insulator has a stepped heat gradient profile from an inside to an outside thereof.
  • An additional aspect of the present invention encompasses a method for insulating an injection molding nozzle tip, including the steps of (1) providing an inner conductive portion of a nozzle tip insulator, and (2) providing an outer insulative portion of a nozzle tip insulator surrounding the inner portion, an inner surface of the outer portion contacting an outer surface of the inner portion along at least a portion of the surfaces.
  • FIG. 1 is a cross-sectional view of a mold and a molding machine including a nozzle tip insulated by a nozzle tip insulator according to the present invention.
  • FIG. 2 is a cross-sectional view of a nozzle tip insulator according to a first embodiment of the invention.
  • FIG. 3 is a cross-sectional view of a nozzle tip insulator according to a second embodiment of the invention.
  • FIG. 4 is a cross-sectional view of a nozzle tip insulator according to a third embodiment of the invention.
  • FIG. 5 is a cross-sectional view of a nozzle tip insulator illustrating interfaces at which temperatures were experimentally measured.
  • FIG. 1 illustrates the overall arrangement of molding device 1 .
  • the device includes manifold 10 through which molten material reaches nozzle 20 .
  • the nozzle has an opening at its proximal end, also called its head portion identified by reference numeral 20 a , for receiving the molten material from the manifold.
  • the nozzle feeds the material to nozzle tip 21 at its distal end, having one or more orifices 22 .
  • the nozzle injects the molten material through the orifices into mold 30 using known methods.
  • the mold has an upper mold plate 29 and a mold cavity 32 . Cooling channels 33 carry cooling water to cool the mold.
  • Nozzle tip insulator 23 surrounds a portion of nozzle tip 21 , and provides thermal insulation for the nozzle tip. Between the nozzle tip insulator and manifold 10 , nozzle housing 24 surrounds nozzle 20 .
  • the insulator has a composite design including inner and outer portions.
  • Inner portion 25 surrounds and is in contact with at least a portion of nozzle 20
  • outer portion 26 surrounds and is in contact with at least a portion of the inner portion 25 in an axial direction of the nozzle.
  • the inner and outer portions are preferably annular, and both portions taper near their distal ends to conform to the shape of the nozzle.
  • the portion of the nozzle tip having the orifice or orifices preferably extends below the distal end of the nozzle tip insulator.
  • the inner portion 25 preferably has flange portion 27 at a proximal end of the nozzle tip insulator.
  • This flange portion may improve the sealing characteristics of the nozzle tip insulator and provides additional heat transfer characteristics to be described below.
  • Mold cavity 32 has an opening 31 , or “gate,” into which the nozzle tip and the insulator may be removably inserted.
  • the molten material passes through the gate into the mold where the material is molded as it cools into the desired form.
  • FIG. 2 illustrates the first embodiment of the nozzle tip insulator in greater detail.
  • the materials used for the inner and outer portions in the present invention are selected to have different thermal insulation coefficients.
  • inner portion 25 includes a conductive material, preferably titanium.
  • Outer portion 26 includes an insulative material, preferably VespelTM polyamide available from DuPont. More information regarding the properties of VespelTM is available at
  • the outer portion may be recessed at ambient temperature, relative to the inner portion, where titanium and VespelTM are used for the inner and outer portions, respectively.
  • the recess is identified by reference numeral 28 in FIG. 3. This arrangement is advantageous because if the two portions are aligned at ambient conditions, when heated, the outer VespelTM portion may protrude beyond the titanium face, causing a stagnant zone and exposing an unprotected region of the nozzle tip to pressure from the molten material.
  • the amount of recess will depend on the materials used for the inner and outer portions, and upon the temperature and pressure conditions to which the nozzle tip insulator will be exposed during the intended molding application.
  • One of ordinary skill in the art would be able to determine the appropriate recess for a particular application.
  • FIG. 4 illustrates a third embodiment of the invention having air gaps 50 provided between the tip 21 , the inner portion 25 and/or the outer portion 26 .
  • the air gaps may be disposed as desired for manufacturing or other reasons.
  • This composite nozzle tip insulator described in the embodiments above resists deformation, cracking, or other undesirable characteristics, even at high temperatures.
  • This heat resistance results in the nozzle tip insulator being positive sealing, reducing the gate bubble and improving the quality and yield of the molding process.
  • This two-piece construction results in the nozzle tip insulator having a stepped heat gradient profile from an inside to an outside thereof.
  • This stepped heat gradient extends the useful life of the nozzle tip insulator because the VespelTM material, when used as an outer portion of the composite tip insulator, experiences a much lower temperature differential compared to a standard design using only VespelTM. Since many resins are now molded at temperatures above VespelTM's rated continuous use temperature, problems with polymer degradation and cracking in VespelTM insulators are avoided by the two-part insulators described above.
  • Table 1 displays the average results of three tests. TABLE 1 Average Results of the Three Tests Ti/Tip Vespel TM/Ti Test Tip Temp. 42 Interface 40 Interface 41 (C.) (C.) (C.) (C.) 280 253 219 117 300 271 244 125 320 288 266 134 340 305 281 144
  • the temperature differential experienced by the VespelTM in the composite design nozzle tip insulator was about half that experienced by VespelTM in a standard VespelTM tip insulator. This enormous decrease in temperature differential may be explained by thermal contact resistances at each interface.
  • the nozzle tip insulator according to the present invention shows an enormous improvement in longevity.
  • One experiment showed an improvement from 6,000 injection cycles before replacement using standard (non-composite) tip insulators to 400,000 injection cycles and counting before replacement using the composite tip insulators of the present invention.
  • Composite design Titanium on the inner (hot) face and VespelTM on the outer (cold) face.
  • All five tip insulators were cycled once from room temperature to 260° C. [500° F. ] and back down to room temperature and inspected.
  • One of the materials listed above (other than VespelTM) was placed in one test rig and a standard VespelTM in a parallel test rig.
  • the manifold temperature was set to 405° C. [760° F. ] and the tips to 350° C. [665° F. ] and maintained for a period of 6 hours.
  • the cooling water temperature in the mold was maintained at 20°.
  • the Hyd-Imide HT sample failed on the initial heat up and cool down cycle from room temperature to 260° C. [500° F. ] and back down to room temperature.
  • the Celazole sample failed on the first 6 hour inspection. Cracking was prevalent on the inside edge (as with the Hyd-Imide HT sample) but also on the conical (seal off) face.
  • the Duratron insulator failed at the first 6 hour inspection. The inner edge which makes contact with the nozzle tip warped (curved) due to the high temperature.
  • the test was made with the tip bearing a preload of 0.30 mm.
  • the manifold temperature was set to 410° C. [770° F. ] and the tip to 465° C. [8700F. ].
  • Table 2 summarizes the test results. TABLE 2 Longevity of Nozzle Tip Insulator Materials SAMPLE LONGEVITY AT TEMPERATURE Standard Vespel TM 44h @ 350° C. [665° F.] Celazole 6h @ 350° C. [665° F.] Hyd-Imide HT failed immediately on heat up cycle Duratron 6h @ 350° C. [665° F.] Composite design 240 h @ 465° C. [870° F.] (Ti/Vespel TM)
  • the composite tip insulator made with an inner titanium portion and an outer VespelTM portion lasted for 240 hours (10 days) at 465° C. [870° F. ].
  • the composite design lasted 5.5 times longer than the tip insulator made of VespelTM alone at a higher temperature.
  • the composite design will last 7 times longer than the standard VespelTM.
  • the temperature-time (longevity) relationship is not linear, and longevity improves faster for a given decrease in temperature. That is, the increase in longevity will be larger than the decrease in temperature.
  • the composite design should have a service life of more than 7 times that of the VespelTM insulator.
  • the composite design tip insulator outperformed the standard VespelTM insulator for molding polycarbonate at 180 MPa injection pressure and 315° C. tip temperature.
  • the composite design gate bubble was clear with no signs of burning.
  • the standard VespelTM design did not seal on the inside (tip) face, allowing resin to degrade and wash out into the flow path.
  • the standard VespelTM design gate bubble displayed burned resin. This burned resin would be expected to exit the gate bubble in a few more cycles, leading to streaks and burned parts.
  • Table 4 displays average results of two sets of tests and the relative heat loss factor: TABLE 4 Average Tip Temperatures and Heat Loss Factor Heat Loss Factor* Tip Temperatures Composite (° C.) design to Set Standard Standard Temperature Composite Vespel TM Vespel TM (° C.) design design design 240 189 195 1.03 260 202 209 1.03 280 218 225 1.03 300 232 238 1.03

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  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Mechanical Engineering (AREA)
  • Moulds For Moulding Plastics Or The Like (AREA)
  • Injection Moulding Of Plastics Or The Like (AREA)

Abstract

An injection molding nozzle tip insulator includes an inner annular portion in contact with the injection molding nozzle tip, and an outer annular portion in contact with the inner annular portion, the outer annular portion being less thermally conductive than the inner annular portion so that the insulator has a stepped heat gradient profile from an inside to an outside thereof.

Description

    BACKGROUND OF THE INVENTION
  • 1. Field of the Invention [0001]
  • The present invention relates to the field of injection molding. More particularly, the invention relates to insulating nozzle tips used, for example, in thermoplastic molding. [0002]
  • 2. Description of the Related Art [0003]
  • Injection molding takes plastic pellets and converts them to a broad array of useful items such as bottles, other types containers, and toys. One example of a device for performing this process has a hopper for holding a quantity of the pellets. A passage links the hopper with a manifold. In the passage, the pellets melt through the action of a screw pushing the pellets along the passage, and heaters warming the passage. The molten plastic reaches the manifold, and is injected through one or more nozzle assemblies into a mold. Each nozzle assembly has an opening for receiving the molten material from the manifold. An elongated portion of the nozzle assembly guides the molten material to its tip. Each nozzle tip has one or more orifices for ejecting the molten material into the mold. A heating assembly in each nozzle assembly maintains the plastic material in a molten state until it is injected into the mold. [0004]
  • The entry orifice in the mold for receiving the molten material, known as a “gate,” is sized to accommodate at least a part of the nozzle assembly. Once the molten material reaches the mold, it is rapidly cooled to form the desired shape. To facilitate cooling of the molten material, some molds incorporate channels through which cooling water flows. [0005]
  • In practical application, a number of molds may be arranged in a turret, with the nozzle assembly positioned so that it can be inserted at the gate to the mold. The molten material is then injected into the mold through one or more orifices in the distal end of the nozzle assembly, the nozzle assembly is removed from the mold, and the turret turns a predetermined distance to align the gate of another mold with the nozzle assembly. This process then repeats. [0006]
  • Where the distal end (the tip) of the nozzle assembly nears the mold, the cooler mold may reduce the temperature of the nozzle tip, and hence the temperature of molten material. This causes two problems: [0007]
  • (1) the molten material cools and hardens somewhat, clogging the nozzle orifice(s); [0008]
  • (2) a “gate bubble” develops, formed on molten material leaked because the seal between the nozzle tip and the mold fails. [0009]
  • To avoid these problems, the nozzle tip is frequently insulated. For example, U.S. Pat. No. 5,569,475 to Adas et al. describes a thermal insulator between the nozzle assembly and the surrounding molding plates. This patent describes using, preferably, a ceramic insulator such as zirconia oxide. A thin layer of the zirconia oxide is sprayed onto either the opening in the mold plate, or onto the nozzle body. If a spray-on coating is used, the nozzle body can first be roughened, and an undercoat, such as nickel-aluminum, applied to the nozzle body to assist with bonding. In addition, a protective coating may be sprayed onto the insulator layer. The protective coating, according to the patent, should be a wear-resistant and machinable material, preferably a metal such as titanium, nickel, or molybdenum. This metallic protective layer then contacts the mold. [0010]
  • Other sources also teach insulating a nozzle. For example, U.S. Pat. No. 5,474,439 to McGrevy discloses a cap (a titanium insulator) tightly disposed on the nozzle body by heating. The cap has a gate well, an opening that aligns with the orifice of the nozzle. The cap has projections with indentations therebetween on an outer surface of the cap. The projections abut the mold. The indentations are filled with air, and these air gaps help to maintain the projections abutting the mold at an ambient temperature even when heated fluid flows through the gate wells. This, the patent asserts, maintains the desired relationship between the projections and the mold. [0011]
  • U.S. Pat. No. 5,324,191 to Schmidt discloses a sealed edge gate for an injection molding system. In response to the gate bubble problem above, the Schmidt patent describes placing a seal ring around the tip end of the nozzle housed within a recess in a mold plate. The seal ring, according to a preferred embodiment, is made of a material with a lower thermal coefficient of expansion than that of the nozzle material. For example, the seal ring could be made of titanium, where the nozzle is made of steel or copper alloy. With this arrangement, the expansion of the nozzle will press the seal ring outward against the wall of the mold plate, and will more tightly grip the seal ring. Bubble grooves may be included in the seal ring, the grooves communicating with the nozzle orifices. In this way, plastic material fills the groove and acts as a thermal insulator to minimize the heat transferred via the seal ring to the mold cavity plate. [0012]
  • Another approach, described in U.S. Pat. No. 4,662,837 to Anderson, provides a thermally insulative sleeve for an injection molding apparatus. The sleeve has two components. The first component is elastically yieldable. The second component, located upstream of the first component, is rigid. That is, the two components of the sleeve are arranged serially along a longitudinal direction of the nozzle. The first component may be made of an elastomeric, fluoroplastic, or silicone material which does not degrade at the operating temperature of the nozzle. The second component may be made of liquid crystal aromatic polyester copolymers, polyimides, polyethersulfones. The second component may be termed a back-up ring and provides alignment between the nozzle and the die cavity, while being sufficiently rigid to keep the first component from being displaced. [0013]
  • However, challenges remain in sealing and insulating the interface between the nozzle and the mold. For instance, Vespel™ is useful as an insulator since it is rated to a continuous use temperature of approximately 260° C. [500°]. However, many resins are now processed at higher temperatures which cause polymer degradation and cracking of the known Vespel™ nozzle tip insulator. [0014]
  • Titanium is not an optimum insulator since it conducts too much heat and because it does not always seal properly (e.g., titanium can withstand only a small preload, such as 0.1 mm). If the hot tip positions and/or the gate detail ball dimensions are out of specification, the preload that a titanium insulator can withstand becomes even smaller, and a gap may be created. [0015]
  • With such an imperfect seal, a “gate bubble” may form in which molten material leaks from the orifice(s) of the nozzle. This leaked material then cools and becomes less fluid. Consequently, the material may clog the nozzle orifice(s) and/or seal the gate opening in the mold, interfering with the molding process. [0016]
  • SUMMARY OF THE INVENTION
  • It is an object of the invention to create a nozzle tip insulator that overcomes the drawbacks of conventional nozzle tip insulators. [0017]
  • To this end, one aspect of the invention comprises a nozzle tip insulator having inner and outer annular portions. The inner annular portion contacts the injection molding nozzle tip, and the outer annular portion contacts the inner annular portion. The outer annular portion is less thermally conductive than the inner annular portion. That is, the insulator has a stepped heat gradient profile from an inside to an outside thereof. [0018]
  • In another aspect, the invention is directed to an injection molding nozzle tip insulator including an inner conductive portion and an outer insulative portion. The outer insulative portion surrounds the inner portion, and an inner surface of the outer portion contacts an outer surface of the inner portion along at least a portion of the surfaces. The inner conductive portion may be, or include, titanium. The outer insulative portion may be, or include, Vespel™. [0019]
  • According to still another aspect, the present invention is directed to a nozzle tip insulator for use with an injection molding nozzle tip. The insulator according to this embodiment includes an inner conductive ring and an outer insulative ring. The outer insulative ring is concentric with the inner ring, with an inner surface of the outer ring contacting an outer surface of the inner ring. The outer insulative ring is less heat-conductive than the inner conductive ring. [0020]
  • Yet another aspect of the invention is an injection molding device including a mold with an opening, and a nozzle assembly for contacting the opening. The nozzle assembly includes a nozzle tip having at least one opening through which molten material passes, and a nozzle tip insulator surrounding the nozzle tip. The nozzle tip insulator, in turn, includes an inner conductive portion, and an outer insulative portion surrounding the inner portion. An inner surface of the outer portion contacting an outer surface of the inner portion along at least a portion of the surfaces. [0021]
  • A further aspect of the present invention encompasses an injection molding nozzle tip insulator including inner means, in contact with a nozzle tip, for conducting heat, and outer means for insulating the heat conducted by the inner means. The outer means surrounding the inner means, an inner surface of the outer means contacting an outer surface of the inner means along at least a portion of the surfaces. [0022]
  • Another aspect of the present invention is directed to a method for insulating an injection molding nozzle tip. The method includes steps of (1) providing an inner annular portion in contact with an injection molding nozzle tip, and (2) providing an outer annular portion in contact with the inner annular portion, the outer annular portion being less thermally conductive than the inner annular portion so that the insulator has a stepped heat gradient profile from an inside to an outside thereof. [0023]
  • An additional aspect of the present invention encompasses a method for insulating an injection molding nozzle tip, including the steps of (1) providing an inner conductive portion of a nozzle tip insulator, and (2) providing an outer insulative portion of a nozzle tip insulator surrounding the inner portion, an inner surface of the outer portion contacting an outer surface of the inner portion along at least a portion of the surfaces. [0024]
  • The invention is described in more detail below with reference to the accompanying drawings.[0025]
  • BRIEF DESCRIPTION OF THE DRAWINGS
  • FIG. 1 is a cross-sectional view of a mold and a molding machine including a nozzle tip insulated by a nozzle tip insulator according to the present invention. [0026]
  • FIG. 2 is a cross-sectional view of a nozzle tip insulator according to a first embodiment of the invention. [0027]
  • FIG. 3 is a cross-sectional view of a nozzle tip insulator according to a second embodiment of the invention. [0028]
  • FIG. 4 is a cross-sectional view of a nozzle tip insulator according to a third embodiment of the invention. [0029]
  • FIG. 5 is a cross-sectional view of a nozzle tip insulator illustrating interfaces at which temperatures were experimentally measured.[0030]
  • DESCRIPTION OF THE PREFERRED EMBODIMENTS
  • The first embodiment of the invention will be described with reference to FIGS. 1 and 2. FIG. 1 illustrates the overall arrangement of [0031] molding device 1. The device includes manifold 10 through which molten material reaches nozzle 20. The nozzle has an opening at its proximal end, also called its head portion identified by reference numeral 20 a, for receiving the molten material from the manifold. The nozzle feeds the material to nozzle tip 21 at its distal end, having one or more orifices 22. The nozzle injects the molten material through the orifices into mold 30 using known methods. The mold has an upper mold plate 29 and a mold cavity 32. Cooling channels 33 carry cooling water to cool the mold.
  • [0032] Nozzle tip insulator 23 surrounds a portion of nozzle tip 21, and provides thermal insulation for the nozzle tip. Between the nozzle tip insulator and manifold 10, nozzle housing 24 surrounds nozzle 20.
  • The insulator has a composite design including inner and outer portions. [0033] Inner portion 25 surrounds and is in contact with at least a portion of nozzle 20, and outer portion 26 surrounds and is in contact with at least a portion of the inner portion 25 in an axial direction of the nozzle. As shown in FIG. 1, the inner and outer portions are preferably annular, and both portions taper near their distal ends to conform to the shape of the nozzle. The portion of the nozzle tip having the orifice or orifices preferably extends below the distal end of the nozzle tip insulator.
  • In addition, as can be seen in the cross-section shown in FIG. 2, the [0034] inner portion 25 preferably has flange portion 27 at a proximal end of the nozzle tip insulator. This flange portion may improve the sealing characteristics of the nozzle tip insulator and provides additional heat transfer characteristics to be described below.
  • [0035] Mold cavity 32 has an opening 31, or “gate,” into which the nozzle tip and the insulator may be removably inserted. The molten material passes through the gate into the mold where the material is molded as it cools into the desired form.
  • FIG. 2 illustrates the first embodiment of the nozzle tip insulator in greater detail. The materials used for the inner and outer portions in the present invention are selected to have different thermal insulation coefficients. In this embodiment, [0036] inner portion 25 includes a conductive material, preferably titanium. Outer portion 26 includes an insulative material, preferably Vespel™ polyamide available from DuPont. More information regarding the properties of Vespel™ is available at
  • www.dupont.com/enggpolymers/americas/vespel. [0037]
  • As shown in a second embodiment illustrated in FIG. 3, at the distal end of the nozzle tip insulator (the end closest to the nozzle tip) the outer portion may be recessed at ambient temperature, relative to the inner portion, where titanium and Vespel™ are used for the inner and outer portions, respectively. The recess is identified by [0038] reference numeral 28 in FIG. 3. This arrangement is advantageous because if the two portions are aligned at ambient conditions, when heated, the outer Vespel™ portion may protrude beyond the titanium face, causing a stagnant zone and exposing an unprotected region of the nozzle tip to pressure from the molten material.
  • The amount of recess will depend on the materials used for the inner and outer portions, and upon the temperature and pressure conditions to which the nozzle tip insulator will be exposed during the intended molding application. One of ordinary skill in the art would be able to determine the appropriate recess for a particular application. [0039]
  • FIG. 4 illustrates a third embodiment of the invention having [0040] air gaps 50 provided between the tip 21, the inner portion 25 and/or the outer portion 26. The air gaps may be disposed as desired for manufacturing or other reasons.
  • This composite nozzle tip insulator described in the embodiments above resists deformation, cracking, or other undesirable characteristics, even at high temperatures. This heat resistance results in the nozzle tip insulator being positive sealing, reducing the gate bubble and improving the quality and yield of the molding process. This two-piece construction results in the nozzle tip insulator having a stepped heat gradient profile from an inside to an outside thereof. [0041]
  • This stepped heat gradient extends the useful life of the nozzle tip insulator because the Vespel™ material, when used as an outer portion of the composite tip insulator, experiences a much lower temperature differential compared to a standard design using only Vespel™. Since many resins are now molded at temperatures above Vespel™'s rated continuous use temperature, problems with polymer degradation and cracking in Vespel™ insulators are avoided by the two-part insulators described above. [0042]
  • Experimental results confirm that the Vespel™ temperature differential is much lower with the composite design tip insulator than it would be with a standard Vespel™ tip insulator. This was confirmed by measuring the temperature of the Ti/[0043] tip interface 40 and the temperature of the Ti/Vespel™ interface 41, as well as tip temperature 42, shown in FIG. 5, in nozzle tip insulators of the composite design described herein.
  • Table 1 displays the average results of three tests. [0044]
    TABLE 1
    Average Results of the Three Tests
    Ti/Tip Vespel ™/Ti
    Test Tip Temp. 42 Interface 40 Interface 41
    (C.) (C.) (C.) (C.)
    280 253 219 117
    300 271 244 125
    320 288 266 134
    340 305 281 144
  • Assuming that the Ti/tip interface temperature would be the temperature experienced by a Vespel™ in a standard Vespel™ tip insulator, the temperature differential experienced by the Vespel™ in the composite design nozzle tip insulator was about half that experienced by Vespel™ in a standard Vespel™ tip insulator. This enormous decrease in temperature differential may be explained by thermal contact resistances at each interface. [0045]
  • In practice, the nozzle tip insulator according to the present invention shows an enormous improvement in longevity. One experiment showed an improvement from 6,000 injection cycles before replacement using standard (non-composite) tip insulators to 400,000 injection cycles and counting before replacement using the composite tip insulators of the present invention. [0046]
  • Below are experiments which demonstrate some of the advantages of the present invention. [0047]
  • EXPERIMENT 1
  • Comparison With Known Nozzle Tip Insulators [0048]
  • The comparison was performed among five insulators each made from one of the following materials: [0049]
  • Celazole [0050]
  • Hyd-Imide HT [0051]
  • Duratron [0052]
  • Vespel™[0053]
  • Composite design: Titanium on the inner (hot) face and Vespel™ on the outer (cold) face. [0054]
  • All five tip insulators were cycled once from room temperature to 260° C. [500° F. ] and back down to room temperature and inspected. One of the materials listed above (other than Vespel™) was placed in one test rig and a standard Vespel™ in a parallel test rig. The manifold temperature was set to 405° C. [760° F. ] and the tips to 350° C. [665° F. ] and maintained for a period of 6 hours. The cooling water temperature in the mold was maintained at 20°. [0055]
  • The Hyd-Imide HT sample failed on the initial heat up and cool down cycle from room temperature to 260° C. [500° F. ] and back down to room temperature. The Celazole sample failed on the first 6 hour inspection. Cracking was prevalent on the inside edge (as with the Hyd-Imide HT sample) but also on the conical (seal off) face. The Duratron insulator failed at the first 6 hour inspection. The inner edge which makes contact with the nozzle tip warped (curved) due to the high temperature. [0056]
  • Both the composite design and standard vespel™ lasted 24 hours (4 tests at 6 hours). These two insulators were then placed back in the rig and left for 20 h before inspection. The inside face of the standard Vespel™ insulator had started to burn, but the composite design was unaffected by the additional testing time. Furthermore, the gate was removed at 100° C. and the tip insulators felt. The standard Vespel™ insulator felt extremely hot on the sealing face, while the composite design was very cool on the sealing face. [0057]
  • EXPERIMENT 2
  • Longevity of Composite Nozzle Tip Insulator [0058]
  • The test was made with the tip bearing a preload of 0.30 mm. The manifold temperature was set to 410° C. [770° F. ] and the tip to 465° C. [8700F. ]. [0059]
  • The composite design tip insulator withstood the 465° C. [870° F. ] temperature for a total of 240 hours (10 days), at which point it appeared that burning and cracking began. [0060]
  • Table 2 summarizes the test results. [0061]
    TABLE 2
    Longevity of Nozzle Tip Insulator Materials
    SAMPLE LONGEVITY AT TEMPERATURE
    Standard Vespel ™ 44h @ 350° C. [665° F.]
    Celazole 6h @ 350° C. [665° F.]
    Hyd-Imide HT failed immediately on heat up cycle
    Duratron 6h @ 350° C. [665° F.]
    Composite design 240 h @ 465° C. [870° F.]
    (Ti/Vespel ™)
  • The composite tip insulator made with an inner titanium portion and an outer Vespel™ portion lasted for 240 hours (10 days) at 465° C. [870° F. ]. In actual machine operation, it is unlikely that such an elevated temperature would ever be reached and, hence, the true life of the design will be much longer. Nevertheless, the composite design lasted 5.5 times longer than the tip insulator made of Vespel™ alone at a higher temperature. Assuming that the temperature-time relationship is linear, then the composite design will last 7 times longer than the standard Vespel™. In reality, the temperature-time (longevity) relationship is not linear, and longevity improves faster for a given decrease in temperature. That is, the increase in longevity will be larger than the decrease in temperature. In actual use, the composite design should have a service life of more than 7 times that of the Vespel™ insulator. [0062]
  • EXPERIMENT 3
  • Actual Molding Process The composite design of the nozzle tip insulator has also been shown to outperform the Vespel™ design in an injection molding machine when actually making parts. [0063]
  • A test was made with a preload on all four drops of roughly 0:23 mm, that is, the tip insulators were randomly placed in the drop locations. The injection pressure was increased to 180 MPa [26000 psi] and the tip temperature to 315° C. [600F. ] and good polycarbonate (PC) parts were still produced. These test conditions permitted a quicker comparison between the standard and composite designs, since burning and structural failure would be sped up. [0064]
  • At the 80,000 cycle mark, a comparison of the two designs on six criteria showed the superiority of the composite design. The results are summarized in Table 3 below. [0065]
    TABLE 3
    Comparison of Nozzle Tip Insulators in
    Actual Molding Operation
    Area of Concern Standard Vespel ™ Composite Design
    Leakage on the very insignificant insignificant
    outside taper amount had start amount had crept
    face to proceed between the Ti and
    backwards along Vespel ™ and leaked
    the taper face and out the Ti
    the molten resin shoulder but was
    was starting to not burnt and was
    burn there in a location that
    could not affect
    the plastic part
    as it could not
    retreat (similar
    to a weepage
    channel)
    Leakage on the significant no leakage.
    inside taper leakage and Titanium was
    face burning of the sealing as
    molten resin all designed onto the
    along the Id of tip.
    the insulator.
    The edge that
    makes contact with
    the tip was not
    sealing
    Burning on the Vespel ™ was not no burning present
    outside taper burnt, but plastic
    face was starting to
    burn
    Burning on the burning of the some discoloring
    inside taper Vespel ™ had of the titanium
    face started on the but no burning
    nozzle
    tip/insulator
    sealing taper face
    Presence of cracking had no cracking
    cracking started on the present
    inside edge that
    seals with the
    nozzle tip
    Bubble burning was bubble was clear
    characteristics prevalent in the (PC and no burning
    gate bubble. was visible
    Streaks in the anywhere.
    plastic part would
    be present
    shortly. The
    reason appears to
    be that the
    plastic leaked
    between the
    insulator and
    nozzle tip,
    degrades and then
    was washing out
    into the flow path
  • In actual use,then, the composite design tip insulator outperformed the standard Vespel™ insulator for molding polycarbonate at 180 MPa injection pressure and 315° C. tip temperature. The composite design gate bubble was clear with no signs of burning. In contrast, the standard Vespel™ design did not seal on the inside (tip) face, allowing resin to degrade and wash out into the flow path. The standard Vespel™ design gate bubble displayed burned resin. This burned resin would be expected to exit the gate bubble in a few more cycles, leading to streaks and burned parts. [0066]
  • EXPERIMENT 4
  • Heat Loss Comparison [0067]
  • A comparison of relative thermal heat loss between the standard and composite designs showed a small additional heat loss for the composite design. The size of the additional heat loss, however, was small enough to be unimportant in actual use. [0068]
  • Table 4 displays average results of two sets of tests and the relative heat loss factor: [0069]
    TABLE 4
    Average Tip Temperatures and Heat Loss Factor
    Heat Loss
    Factor*
    Tip Temperatures Composite
    (° C.) design to
    Set Standard Standard
    Temperature Composite Vespel ™ Vespel ™
    (° C.) design design design
    240 189 195 1.03
    260 202 209 1.03
    280 218 225 1.03
    300 232 238 1.03
  • The individual components shown in outline in this application are all well known in the image recording arts and their specific construction and operation are not critical to the operation or best mode for carrying out the invention. [0070]
  • While the present invention has been described for what are presently considered the preferred embodiments, the invention is not so limited. To the contrary, the invention is intended to cover various modifications and equivalent arrangements included within the spirit and scope of the appended claims. The scope of the following claims is to be accorded the broadest interpretation so as to encompass all such modifications and equivalent structures and functions. [0071]

Claims (26)

I claim:
1. An injection molding nozzle tip insulator comprising:
an inner annular portion in contact with the injection molding nozzle tip; and
an outer annular portion in contact with said inner annular portion, said outer annular portion being less thermally conductive than said inner annular portion so that said insulator has a stepped heat gradient profile from an inside to an outside thereof.
2. An injection molding nozzle tip insulator comprising:
an inner conductive portion;
an outer insulative portion surrounding said inner portion, an inner surface of said outer portion contacting an outer surface of said inner portion along at least a portion of the surfaces.
3. A nozzle tip insulator according to claim 2, said inner conductive portion comprising titanium.
4. A nozzle tip insulator according to claim 2, said outer insulative portion comprising vespel™.
5. A nozzle tip insulator according to claim 2, said inner conductive portion further comprising a flared portion having an angled surface parallel to an angled surface of said outer insulative portion at a distal end of said nozzle tip insulator, the distal end being an end of said nozzle tip insulator closest to an end of a nozzle tip.
6. A nozzle tip insulator according to claim 2, said inner conductive portion further comprising a flange portion at a proximal end of said nozzle tip insulator, the proximal end being an end of the nozzle tip insulator disposed away from an end of a nozzle tip.
7. A nozzle tip insulator according to claim 2, said inner conductive portion being annular, an opening in said inner conductive portion being sized to accommodate a nozzle tip.
8. A nozzle tip insulator for use with an injection molding nozzle tip comprising:
an inner conductive ring;
an outer insulative ring concentric with said inner ring, an inner surface of said outer ring contacting an outer surface of said inner ring, said outer insulative ring being less heat-conductive than said inner conductive ring.
9. An injection molding device comprising:
a mold with an opening;
a nozzle assembly for contacting the opening and comprising:
a nozzle tip having at least one opening through which molten material passes; and
a nozzle tip insulator surrounding said nozzle tip, said nozzle tip insulator including: an inner conductive portion, and an outer insulative portion surrounding said inner portion, an inner surface of said outer portion contacting an outer surface of said inner portion along at least a portion of the surfaces.
10. A molding device according to claim 9, the opening is said mold being sized to accommodate said nozzle assembly to allow molten material to pass from said nozzle assembly into said mold.
11. A molding device according to claim 9, said nozzle assembly further comprising at least one heating element to achieve a temperature within said nozzle assembly so that molten material passes through the opening in said nozzle tip.
12. A molding device according to claim 9, said nozzle tip insulator located on said nozzle tip so that, when said nozzle tip is placed in the opening of said mold, said nozzle tip insulator prevents said nozzle tip from contacting said mold.
13. A molding device according to claim 9, said mold further comprising a cooling element.
14. An injection molding nozzle tip insulator, comprising:
inner means, in contact with a nozzle tip, for conducting heat;
outer means for insulating the heat conducted by said inner means, said outer means surrounding said inner means, an inner surface of said outer means contacting an outer surface of said inner means along at least a portion of the surfaces.
15. A nozzle tip insulator according to claim 14, said inner means comprising titanium.
16. A nozzle tip insulator according to claim 14, said outer means comprising Vespel™.
17. A nozzle tip insulator according to claim 14, said inner means further comprising a flared portion having a surface extending beyond an inner surface of said outer means at a distal end of said nozzle tip insulator, the distal end being an end of the nozzle tip insulator closest to an end of a nozzle tip.
18. A nozzle tip insulator according to claim 14, said inner means further comprising a flange portion extending over an end face of said outer means at a proximal end of said nozzle tip insulator, the proximal end being an end of the nozzle tip insulator disposed away from an end of a nozzle tip.
19. A method for insulating an injection molding nozzle tip, comprising the steps of:
providing an inner annular portion in contact with an injection molding nozzle tip; and
providing an outer annular portion in contact with the inner annular portion, the outer annular portion being less thermally conductive than the inner annular portion so that the insulator has a stepped heat gradient profile from an inside to an outside thereof.
20. A method for insulating an injection molding nozzle tip, comprising the steps of:
providing an inner conductive portion of a nozzle tip insulator; and
providing an outer insulative portion of a nozzle tip insulator surrounding the inner portion, an inner surface of the outer portion contacting an outer surface of the inner portion along at least a portion of the surfaces.
21. A method for insulating a nozzle tip according to claim 20, wherein the inner conductive portion provided in said step of providing the inner conductive portion comprising titanium.
22. A method for insulating a nozzle tip according to claim 20, wherein the outer conductive portion provided in said step of providing the outer insulative portion comprises Vespel™.
23. A method for insulating a nozzle tip according to claim 20, wherein the inner conductive portion provided in said step of providing the inner conductive portion includes a flared portion having an angled surface parallel to an angled surface of the outer insulative portion at a distal end of the nozzle tip insulator, the distal end being an end of the nozzle tip insulator closest to an end of a nozzle tip.
24. A method for insulating a nozzle tip according to claim 20, wherein the inner conductive portion provided in said step of providing the inner conductive portion includes a flange portion at a proximal end of the nozzle tip insulator, the proximal end being an end of the nozzle tip insulator disposed away from an end of a nozzle tip.
25. An injection molding nozzle comprising:
a nozzle housing having a head portion and a tip portion;
a nozzle tip thermal insulator disposed adjacent said nozzle tip portion having an inner portion and an outer portion, the inner portion and the outer portion having different thermal insulation coefficients.
26. An injection molding nozzle according to claim 25, further comprising an air gap disposed between said inner portion and said outer portion.
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US20070243285A1 (en) * 2006-04-10 2007-10-18 Stackteck Systems Limited Composite nozzle cap
US7927094B2 (en) * 2006-04-10 2011-04-19 Stackteck Systems Limited Composite nozzle cap
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