US1944167A - Alloy for use in the manufacture of tetraethyl lead - Google Patents
Alloy for use in the manufacture of tetraethyl lead Download PDFInfo
- Publication number
- US1944167A US1944167A US401621A US40162129A US1944167A US 1944167 A US1944167 A US 1944167A US 401621 A US401621 A US 401621A US 40162129 A US40162129 A US 40162129A US 1944167 A US1944167 A US 1944167A
- Authority
- US
- United States
- Prior art keywords
- lead
- alloy
- manufacture
- tetraethyl lead
- matter
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- MRMOZBOQVYRSEM-UHFFFAOYSA-N tetraethyllead Chemical compound CC[Pb](CC)(CC)CC MRMOZBOQVYRSEM-UHFFFAOYSA-N 0.000 title description 16
- 238000004519 manufacturing process Methods 0.000 title description 9
- 229910045601 alloy Inorganic materials 0.000 title description 3
- 239000000956 alloy Substances 0.000 title description 3
- 239000000203 mixture Substances 0.000 description 8
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 5
- HRYZWHHZPQKTII-UHFFFAOYSA-N chloroethane Chemical compound CCCl HRYZWHHZPQKTII-UHFFFAOYSA-N 0.000 description 5
- 229960003750 ethyl chloride Drugs 0.000 description 5
- 229910052708 sodium Inorganic materials 0.000 description 5
- 239000011734 sodium Substances 0.000 description 5
- 229910000528 Na alloy Inorganic materials 0.000 description 4
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 4
- -1 alkyl lead compounds Chemical class 0.000 description 3
- 238000002844 melting Methods 0.000 description 3
- 230000008018 melting Effects 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 229910021578 Iron(III) chloride Inorganic materials 0.000 description 2
- KEAYESYHFKHZAL-UHFFFAOYSA-N Sodium Chemical compound [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 229910001510 metal chloride Inorganic materials 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 230000003213 activating effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic Table
- C07F7/24—Lead compounds
Definitions
- This invention relates to compositions of matter for use in the manufacture of tetraethyl lead and more particularly to a new composition of matter of lead and sodium containing an activating metal chloride.
- composition of matter is then treated with ethyl chloride under pressure at temperatures varying between 35 and 90 C.
- a new composition of matter for use in the production of alkyl lead compounds which comprises the product obtained by melting together substantially 10 parts sodium, 90 parts lead and 001 part of one of the members of the group consisting of aluminum chlorideand ferric chloride.
- a new composition of matter for use in the production of alkyl lead compound which comprises the product obtained by melting together substantially 10 parts sodium, 90 parts lead, and
- a composition of matter for use in the production of alkyl lead compounds which comprises the product obtained by melting together substantially 10 parts sodium, 90 parts lead, and 0.01 part ferric chloride.
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
Description
Patented .Ian. 23, 1934 I OFFICE, I
ALLOY FOR USE IN THE MANUFACTURE OF LEAD TETRAETHYL William S. Calcott, Penns Grove,
Point,
Parmelee, Carneys Meschter, Penns Grove, du Pont de Nemours &
and Alfred E.
and Homer F.
N. .L, assignors to E. 1.
Company, Wilmington,
Del., a corporation of Delaware No Drawing. Original application August 17,
1928, Serial No. 300,370. Divided andthis application October 3 Claims.
This invention relates to compositions of matter for use in the manufacture of tetraethyl lead and more particularly to a new composition of matter of lead and sodium containing an activating metal chloride.
This application is a division of our copending application Serial No. 300,370, filed August 17, 1928.
Thesuccessful production of tetraethyl lead 10 by the'interaction of lead mono-sodium alloy with ethyl-chloride depends upon the speed with which the reaction can be started and maintained at relatively low temperatures. It has been the practice to treat lead mono-sodium alloy with ethyl chloride under pressure, at temperatures varying between and 100 C. By this procedure it has been possible to obtain yields of 80% of the theoretical. V
Wehave now discovered that if very small amounts of certain inorganic salts, such as chlorides of aluminum or iron, are added to the lead sodium alloy, either during its formation or by remelting the already formed alloy and incorporating therewith the desired compound, the al- 5 loy is activated and higher yields of tetraethyl lead may be obtained when this new composition of matter issubjected to the reaction conditions ordinarily employed in the manufacture of tetraethyl lead from lead sodium alloy and ethyl chloride.
- The following example indicates by way of illustration one embodiment of our invention:
10 grams of sodium, 90 grams of lead and 0.01 gram of aluminum chloride are placed together in a suitable vessel and heated until the whole mass becomes liquid. The liquid mass is then agitated in any manner desired to secure thorough mixing and is subsequently cooled. The cold composition of matter is then reduced to a powder and is placed in areaction vessel capable of withstanding pressure. of fineness oi the powder is not an essentialiea- (Althoughthe degree 22, 1929. Serial No. 401,621
ture, we prefer to employ a coarse'powder for this purpose.) The composition of matter is then treated with ethyl chloride under pressure at temperatures varying between 35 and 90 C.
It will be understood that the conditions of pressure and temperature may vary as is usual in the known processes of manufacturing tetraethyl lead and for this reason the details of the usual reaction conditions, and of the recovery of tetraethyl lead from the reaction mass, are not given because they are unessential' here. Our'improvement lies in the presence of a metal chloride in the alloy, irrespective of the particular conditions employed for the production or tetraethyl lead using ethyl chloride. 'It will be apparent that other embodiments of this invention exist and may be practiced with out departing from the-spirit thereof, and it is understoodthat we do not limit ourselves to the foregoing example or description except as indicated in the following patent claims.
We claim:
1. A new composition of matter for use in the production of alkyl lead compounds which comprises the product obtained by melting together substantially 10 parts sodium, 90 parts lead and 001 part of one of the members of the group consisting of aluminum chlorideand ferric chloride.
2. A new composition of matter for use in the production of alkyl lead compound which comprises the product obtained by melting together substantially 10 parts sodium, 90 parts lead, and
.01 part aluminum chloride.
3. A composition of matter for use in the production of alkyl lead compounds which comprises the product obtained by melting together substantially 10 parts sodium, 90 parts lead, and 0.01 part ferric chloride.
WILLIAM S. CALCOTI. .ALFRED E. PARMEIEE- HOMERE. MESCHTER.
CERTIFICATE OF CGRRECTION.
Patent No. 1,944,167. Jenodry 23, 1934;
WILLIAM s. GALGOTT, ET AL.
lt is hereby certified that error appears in the printed specification of the above numbered patent requiring correction as follows: Line 93, claim 3, for
"0.01" read 0,1; and that the said Letters Patent shonld be read with this correclion therein that the same may conform to the record oithe case in the Patent Office.
Signed and sealed this law day of March, A. p. 1934;
} F. M. Hopkins (Seal) Acting Commissioner of Patents.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US401621A US1944167A (en) | 1928-08-17 | 1929-10-22 | Alloy for use in the manufacture of tetraethyl lead |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US300370A US1962173A (en) | 1928-08-17 | 1928-08-17 | Manufacture of tetraethyl lead |
| US401621A US1944167A (en) | 1928-08-17 | 1929-10-22 | Alloy for use in the manufacture of tetraethyl lead |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US1944167A true US1944167A (en) | 1934-01-23 |
Family
ID=26971750
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US401621A Expired - Lifetime US1944167A (en) | 1928-08-17 | 1929-10-22 | Alloy for use in the manufacture of tetraethyl lead |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US1944167A (en) |
-
1929
- 1929-10-22 US US401621A patent/US1944167A/en not_active Expired - Lifetime
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