US1937405A - Separator for storage batteries - Google Patents

Separator for storage batteries Download PDF

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Publication number
US1937405A
US1937405A US133663A US13366326A US1937405A US 1937405 A US1937405 A US 1937405A US 133663 A US133663 A US 133663A US 13366326 A US13366326 A US 13366326A US 1937405 A US1937405 A US 1937405A
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United States
Prior art keywords
mat
plate
separator
strips
sheet
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Expired - Lifetime
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US133663A
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Theodore B Entz
Almond H Snyder
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GOULD STORAGE BATTERY Corp
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GOULD STORAGE BATTERY CORP
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Priority to US133663A priority Critical patent/US1937405A/en
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/40Separators; Membranes; Diaphragms; Spacing elements inside cells
    • H01M50/409Separators, membranes or diaphragms characterised by the material
    • H01M50/411Organic material
    • H01M50/429Natural polymers
    • H01M50/4295Natural cotton, cellulose or wood
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

Definitions

  • This invention relates to separators for storage batteries, and more especially to separators comprising two or more elements.
  • the principal object of our invention is to provide a separator composed of two or more elements in which the position and compression of one o1 said elements is controlled.
  • Another object of our invention is to provide in a compound separator a spacing member which shall have marginal portions adapted to conne a fibrous member.
  • Another object is to provide a compound separator with a member having projections from a face adapted to limit the compression to which a fibrous member of said separator may be subjected.
  • Still another object is to provide a separator comprising a supporting member, preferably of rubber, which may have marginal strips adapted to position a iibrous mat of glass wool, and further to limit the extent to which the glass wool may be compressed.
  • a further object is to provide a separator comprising a supporting member having on one side portions adapted to position a brous mat and on the other side spacing strips adapted to ensure adequate circulation of the electrolyte.
  • a still further object is to provide under certain circumstances a separator of glass wool,
  • Figure 1 is a vertical longitudinal view with portions of the several elements removed to show those parts in their interrelation.
  • Figure 2 is a horizontal sectional view on the line 2-2 of Fig. 1.
  • The-beneficial effect of the use of wood or Wood elements in storage batteries is now generally recognized, especially with respect to the effect on the negative plate.
  • This benecial effect may be accomplished by associating wood or wood elements with the-active materials of the plates or, as is the more common practice, by using a wood diaphragm.
  • we may secure the beneficial effect of wood elements by making the supporting member of wood, one form of which is shown in the drawing, or we may use a wood diaphragm interposed between the supporting member 2 and the mat 4.
  • Another manner in which wood or wood elements may be introduced is to insert a layer of vegetable fiber in the fibrous mat or to associate with the glass'wool vegetable iiber or Wood elements.
  • a valuable feature of our invention is the fact that while the active material of the positive plate is held in place by the compressible mat of glass wool, which allows for the required expansion, the marginal columns of the plate and the separators may be adapted to be rigidly and mutually supporting. Further, should the plate 95 warp, the strips 3 will prevent the mat from being crushed or cut through With-the accompanying danger of short circuiting.
  • Figs. l and 2 embody a preferred form of our invention, the number and position of the spacing strips 3 and 5 may be varied to suit the requirements of the particular battery.
  • a separator comprising a sheet of 'material' provided with perforations throughout the major portion of its area with its side edges imperforate, relatively rigid strips secured to said sheet at the marginal portions thereof and adapted to bear against the edges of the positive plate, said strips spacing the sheet away from the plate to define a recess of slightly less dimensions than the plate, and a mat of felted brousmaterial located within and filling said recess and contacting with the positive plate.
  • a separator comprising a sheet of material provided with perforations throughout the major portion of its area with its side edges imperforate, relatively rigid strips secured to said sheet at the marginal portions thereof and adapted to bear against the edges of the positive plate, said strips spacing the sheet away from the plate to dene a recess of slightly less dimensions than the plate, and a mat of felted fibrous material located within and filling said recess and contacting with the positive plate, the mat comprising glass wool.
  • a separator comprising a sheet of material provided with perforations throughout the major portion of its area with its side edges imperforate, relatively rigid strips secured to said sheet at the marginal portions thereof and adapted to bear against the edges of the positive plate, said strips spacing the sheet away from the plate to dene a recess of slightly less dimensions than the plate, and a mat of felted fibrous material located within and lling said recess and contacting with the positive plate, the mat comprising glass wool having wood fiber incorporated there- 1n.
  • a separator comprising a sheet of material provided with perforations throughout the major portion of its area with its side edges imperforate, relatively rigid strips secured to said sheet at the marginal portions thereof and adapted to bear against the edges of the positive plate, said strips spacing the sheet away from the plate to dene a recess of slightly less dimensions than the plate, a mat of felted fibrous material located within and filling said recess and contacting with the positive plate, and spaced vertical strips on the outer side of said sheet adapted to contact with the adjacent negative plate to define vertical openings for the passage of the electrolyte.
  • a separator comprising a sheet of material provided with perforations throughout the major portion of its area with its side edges lmperforate, relatively rigid strips secured to said sheet at the marginal portions thereof and adapted to bear against the edges of the positive plate, said strips spacing the sheet away from the plate to dene a recess of slightly less dimensions than the plate, and a mat of felted brous material located within and filling said recess and contacting with the positive plate, the sheet being of greater dimensions than the plates whereby to project beyond the edges thereof.
  • a separator located between the plates and comprising a mat of yielding material and a supporting member, said member having on one side a plurality of marginal portions coextensive with the mat and located beyond the edges thereof to restrain the mat against lateral displacement with respect to said member and to coact with marginal portions of said positive plate to limit the compression of the mat by said plates, said supporting member having on the other side vertical spacing portions adapted to coact with marginal and intermediate portions of said negative plate to provide vertical passages for the circulation of said electrolyte.
  • a positive plate, a negativeA plate, electrolyte, and a separator located between the plates and comprising a mat of felted inert yielding material and a supporting member, said member having on one side a plurality of portions extending the full length thereof adapted to position said mat and to coact with portions of said positive plate to limit the compression of the mat by the plates, said supporting member having on the other side projecting portions engaging against portions of said negative plate to provide spaces for the circulation of said electrolyte, the edges of the positive plate being exposed.
  • a separator for the plates of a storage battery comprising a sheet of rigid material having relatively rigid strips carried by certain of the edges thereof adapted to bear against and project beyond the side of a storage battery plate, said strips spacing the major portion of the sheet away from the plate to define a recess, and a felted brous mat located within the recess and contacting throughout flatly with the sheet and plate.

Description

NOV. 28, 1933. T. B ENTZ E( AL 1,937,405
I SEPARATOR FOR STORAGE BATTERIES Original Filed Sept. 4l 1926 ngc one
gogo ooogog oooooo O OO O0 O OO 0000 O 00000000000000000000 0000 302002 oooo UUU oooo OgOgOgOgO OOOO Oogoooooo Patented Nov. 28, 1933 SEPABATOR FOR STORAGE BATTERIES Theodore B. Entz, Brooklyn, and Almond H. Snyder, Lancaster, N. Y., assignors, by mesne assignments, to Gould Storage Battery Corporation, Depew, N. Y., a corporation of Delaware Application September 4, 1926, Serial No. 133,663 Renewed June 29, 1931 -iso 8 Claims.
This invention relates to separators for storage batteries, and more especially to separators comprising two or more elements.
The principal object of our invention is to provide a separator composed of two or more elements in which the position and compression of one o1 said elements is controlled.
Another object of our invention is to provide in a compound separator a spacing member which shall have marginal portions adapted to conne a fibrous member.
Another object, also, is to provide a compound separator with a member having projections from a face adapted to limit the compression to which a fibrous member of said separator may be subjected. Y.
Still another object is to provide a separator comprising a supporting member, preferably of rubber, which may have marginal strips adapted to position a iibrous mat of glass wool, and further to limit the extent to which the glass wool may be compressed.
A further object is to provide a separator comprising a supporting member having on one side portions adapted to position a brous mat and on the other side spacing strips adapted to ensure adequate circulation of the electrolyte.
A still further object is to provide under certain circumstances a separator of glass wool,
3 Wood and a supporting member of relatively inert material.
Other objects of our invention will become readily apparent on consideration of the drawing which shows a preferred form of our invention, inwhich,-
Figure 1 is a vertical longitudinal view with portions of the several elements removed to show those parts in their interrelation.
Figure 2 is a horizontal sectional view on the line 2-2 of Fig. 1.
. In the development of compound separators it has been found very advantageous to use a mat of glass Wool or similar inert fibrous material in contact with the positive plate 1. The difllculty has hitherto been to protect this mass of brittle bers and to insure that the mat is of a uniform density which will freely.. permit the 'passage of electrolyte but prevent; the passage of nely divided particles from the positive plate which might cause a short circuit. The density of this iibrous mass is largely controlled by the degree to\which it is compressed. To control this degree of compression we may provide a supporting member 2, preferably of rubbed or other insulating mterial, having marginal strips (Cl. 13G-145) 3 spaced to enclose a mat of felted glass wool 4. Disregarding for a moment the other characteristics of the mat 4 which eiects its permeability, such as the size of the individual strands, it will be readily seen that by varying the thickness of these strips 3 in conjunction with the thickness of the mat 4, a desired degree of compression and, hence, a desreddegree of density and permeability, may be obtained.
Under certain conditions it is desirable to have free circulation of the electrolyte between the plates. We may insure this condition by providing the member 2 with a number of spacing strips 5 on the opposite side from the marginal strips 3 which would form vertical open spaces against the negative plate 6.
The-beneficial effect of the use of wood or Wood elements in storage batteries is now generally recognized, especially with respect to the effect on the negative plate. This benecial effect may be accomplished by associating wood or wood elements with the-active materials of the plates or, as is the more common practice, by using a wood diaphragm. In our invention we may secure the beneficial effect of wood elements by making the supporting member of wood, one form of which is shown in the drawing, or we may use a wood diaphragm interposed between the supporting member 2 and the mat 4. Another manner in which wood or wood elements may be introduced is to insert a layer of vegetable fiber in the fibrous mat or to associate with the glass'wool vegetable iiber or Wood elements.
A valuable feature of our invention is the fact that while the active material of the positive plate is held in place by the compressible mat of glass wool, which allows for the required expansion, the marginal columns of the plate and the separators may be adapted to be rigidly and mutually supporting. Further, should the plate 95 warp, the strips 3 will prevent the mat from being crushed or cut through With-the accompanying danger of short circuiting.
While Figs. l and 2 embody a preferred form of our invention, the number and position of the spacing strips 3 and 5 may be varied to suit the requirements of the particular battery.
Having described our invention, we claim:-
1. In a storage battery embodying positive and negative plates, a separator comprising a sheet of 'material' provided with perforations throughout the major portion of its area with its side edges imperforate, relatively rigid strips secured to said sheet at the marginal portions thereof and adapted to bear against the edges of the positive plate, said strips spacing the sheet away from the plate to define a recess of slightly less dimensions than the plate, and a mat of felted brousmaterial located within and filling said recess and contacting with the positive plate.
2. In a storage battery embodying positive and negative plates, a separator comprising a sheet of material provided with perforations throughout the major portion of its area with its side edges imperforate, relatively rigid strips secured to said sheet at the marginal portions thereof and adapted to bear against the edges of the positive plate, said strips spacing the sheet away from the plate to dene a recess of slightly less dimensions than the plate, and a mat of felted fibrous material located within and filling said recess and contacting with the positive plate, the mat comprising glass wool.
3. In a storage battery embodying positive and negative plates, a separator comprising a sheet of material provided with perforations throughout the major portion of its area with its side edges imperforate, relatively rigid strips secured to said sheet at the marginal portions thereof and adapted to bear against the edges of the positive plate, said strips spacing the sheet away from the plate to dene a recess of slightly less dimensions than the plate, and a mat of felted fibrous material located within and lling said recess and contacting with the positive plate, the mat comprising glass wool having wood fiber incorporated there- 1n.
4. In a storage battery embodying positive and negative plates, a separator comprising a sheet of material provided with perforations throughout the major portion of its area with its side edges imperforate, relatively rigid strips secured to said sheet at the marginal portions thereof and adapted to bear against the edges of the positive plate, said strips spacing the sheet away from the plate to dene a recess of slightly less dimensions than the plate, a mat of felted fibrous material located within and filling said recess and contacting with the positive plate, and spaced vertical strips on the outer side of said sheet adapted to contact with the adjacent negative plate to define vertical openings for the passage of the electrolyte.
5. In a storage battery embodying positive and negative plates, a separator comprising a sheet of material provided with perforations throughout the major portion of its area with its side edges lmperforate, relatively rigid strips secured to said sheet at the marginal portions thereof and adapted to bear against the edges of the positive plate, said strips spacing the sheet away from the plate to dene a recess of slightly less dimensions than the plate, and a mat of felted brous material located within and filling said recess and contacting with the positive plate, the sheet being of greater dimensions than the plates whereby to project beyond the edges thereof.
6. In a storage battery embodying a positive plate, a negative plate and electrolyte, a separator located between the plates and comprising a mat of yielding material and a supporting member, said member having on one side a plurality of marginal portions coextensive with the mat and located beyond the edges thereof to restrain the mat against lateral displacement with respect to said member and to coact with marginal portions of said positive plate to limit the compression of the mat by said plates, said supporting member having on the other side vertical spacing portions adapted to coact with marginal and intermediate portions of said negative plate to provide vertical passages for the circulation of said electrolyte.
7. In a storage battery, a positive plate, a negativeA plate, electrolyte, and a separator located between the plates and comprising a mat of felted inert yielding material and a supporting member, said member having on one side a plurality of portions extending the full length thereof adapted to position said mat and to coact with portions of said positive plate to limit the compression of the mat by the plates, said supporting member having on the other side projecting portions engaging against portions of said negative plate to provide spaces for the circulation of said electrolyte, the edges of the positive plate being exposed.
8. A separator for the plates of a storage battery comprising a sheet of rigid material having relatively rigid strips carried by certain of the edges thereof adapted to bear against and project beyond the side of a storage battery plate, said strips spacing the major portion of the sheet away from the plate to define a recess, and a felted brous mat located within the recess and contacting throughout flatly with the sheet and plate.
THEODORE B. ENTZ. ALMOND H. SNYDER.
US133663A 1926-09-04 1926-09-04 Separator for storage batteries Expired - Lifetime US1937405A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2490630A (en) * 1944-10-03 1949-12-06 Electric Storage Battery Co Storage battery plate and retainer construction

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2490630A (en) * 1944-10-03 1949-12-06 Electric Storage Battery Co Storage battery plate and retainer construction

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