US1936155A - Gaseous fuel - Google Patents

Gaseous fuel Download PDF

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Publication number
US1936155A
US1936155A US319448A US31944828A US1936155A US 1936155 A US1936155 A US 1936155A US 319448 A US319448 A US 319448A US 31944828 A US31944828 A US 31944828A US 1936155 A US1936155 A US 1936155A
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United States
Prior art keywords
fuel
gaseous fuel
air
gas
hydrogen
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Expired - Lifetime
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US319448A
Inventor
Florez Luis De
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Texaco Inc
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Texaco Inc
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Publication date
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Priority to US319448A priority Critical patent/US1936155A/en
Priority to US690948A priority patent/US1936156A/en
Application granted granted Critical
Publication of US1936155A publication Critical patent/US1936155A/en
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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L3/00Gaseous fuels; Natural gas; Synthetic natural gas obtained by processes not covered by subclass C10G, C10K; Liquefied petroleum gas

Definitions

  • This invention pertains to a gaseous fuel which is suitable for use in internal combustion engines, and has particular reference to a gaseous fuel for air craft lighter than air, such as dirigibles.
  • Fuel storage Space may be'provided in the form of partitioned gas storage spaces within the body of the dirigible so that as gaseous fuel is consumed air may be admitted to such spaces and the same relative buoyancy of the ship may be maintained.
  • Such fuel must have a relatively high B. t. u. value per cubic foot to warrant its use, and it is essential also that the fuel shall have a relatively low dew point or point of condensation, such as for example below 20? F. As pointed out above, the density should be approximately equivalent 0 air.
  • mixtures may be made up from individual gaseous hydrocarbons and hydrogen in the proportion to give the desired density equivalent to air, low dew point and high thermal value.
  • a mixture of 27.5% of hydrogen and 72.5% of propane will have a density about equal to air and will have a high fuel value of about 2,035 B. t. u. per cubic foot; also a mixture of 52.0% of hydrogen and 48.0% of butane gives a fuel equal to air in density and a high fuel value of about 1,845 B. t. u. per cubic foot.
  • the hydrocarbon fraction selected should be of) fairly close boiling range and contain only limited amounts of hydrocarbons which are difiicult to liquefy and which may therefore be shipped on a commercial scale in metal cylinders or pressure tank cars.
  • the composition of these gases will vary, depending upon the character of the natural gas from which the gasoline was derived and upon the character of rectification to which the raw gasoline was subjected.
  • this residual gas consisted almost entirely of butane and propane with 30 very small amounts of pentane, ethane and methane.
  • a gaseous fuel for internal, combustion engines of lighter-than-air craft consisting of about 52% hydrogen and about 48% butane.

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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Output Control And Ontrol Of Special Type Engine (AREA)

Description

Patented Nov. 21, 1933 res 1,936,155 GASEOUS FUEL Luis de Florez, Pomfret,
Texas Company, New York,
tion of Delaware Conm, assignor to The N. Y., a corpora- No Drawing. Application November 14, 1928 1 Serial No. 319,448
1 Claim. (01. 48-199) This invention pertains to a gaseous fuel which is suitable for use in internal combustion engines, and has particular reference to a gaseous fuel for air craft lighter than air, such as dirigibles.
In the practical operation of lighter-than-air air craft, the use of liquid fuels has several disadadditional burden which must be compensated for by providing lifting capacity for the starting load;
As liquid fuel is consumed, the total weight of the craft is graduallyreduced and over a long cruising range this loss is large. It thus becomes necessary to compensate for this loss in weight by exhausting from the gas bag a portion of the lifting gas. In the case of the rarer non-inflammable gas, helium, this would constitute a serious loss, difiicult of replacement and highly expensive. Even with the use of hydrogen as a lifting gas, the loss of gas is such as to greatly add to the expense of operation. The use of condensers on the exhaust of engines has been resorted to, to retain the water formed by combustion as ballast but the provision of such equipment reduces the efficiency of the ship.
In view of these difliculties, it is proposed to use a gaseous fuel mixture which has a density approximately the same as air. Fuel storage Space may be'provided in the form of partitioned gas storage spaces within the body of the dirigible so that as gaseous fuel is consumed air may be admitted to such spaces and the same relative buoyancy of the ship may be maintained.
Such fuel must have a relatively high B. t. u. value per cubic foot to warrant its use, and it is essential also that the fuel shall have a relatively low dew point or point of condensation, such as for example below 20? F. As pointed out above, the density should be approximately equivalent 0 air.
In the preparation of a gaseous fuel in accordance with my invention, various mixtures may be employed. For example mixtures may be made up from individual gaseous hydrocarbons and hydrogen in the proportion to give the desired density equivalent to air, low dew point and high thermal value. Thus, for example, a mixture of 27.5% of hydrogen and 72.5% of propane will have a density about equal to air and will have a high fuel value of about 2,035 B. t. u. per cubic foot; also a mixture of 52.0% of hydrogen and 48.0% of butane gives a fuel equal to air in density and a high fuel value of about 1,845 B. t. u. per cubic foot.
However, since the individual hydrocarbons are not readily available in quantity it is quite desirable to use mixtures of hydrocarbons, such for example as those from natural gas or fromgas derived from the cracking of hydrocarbon oils, and other similar sources. By selecting a fairly close out of the gaseous hydrocarbons, such as may be 00 obtained by carefully controlled rectification under pressure, a mixture of hydrocarbons may be secured which when mixed with hydrogen in the proper proportions gives a fuel having the required fuel value, density and dew point to be as acceptable for dirigible use. 1
' It is highly desirable that the hydrocarbon fraction selected should be of) fairly close boiling range and contain only limited amounts of hydrocarbons which are difiicult to liquefy and which may therefore be shipped on a commercial scale in metal cylinders or pressure tank cars. Imay,for example, take the residual gases derived from the rectification of raw natural gasoline. The composition of these gases will vary, depending upon the character of the natural gas from which the gasoline was derived and upon the character of rectification to which the raw gasoline was subjected. However, in a. typical case, this residual gas consisted almost entirely of butane and propane with 30 very small amounts of pentane, ethane and methane. In some instances it may only be necessary to compress and liquefy this residual gas to obtain as a condensate a suitable hydrocarbon mixture which may be shipped under compression in cylinders, to be mixed with hydrogen in the proper quantity at the point of use to obtain the proper gravity. If the residual gas contains substan tial quantities of methane and ethane, it may be desirable to subject the condensate obtained on compression and cooling to a rectification under pressure to eliminate these difiicultly liqueflable gases from the desired condensate. The practice is similar to that'employed in the manufacture of natural gasoline from raw compression gasoline in which a portion of the butane and all of the lighter hydrocarbons are generally removed by rectification. I
What I claim is:
A gaseous fuel for internal, combustion engines of lighter-than-air craft. consisting of about 52% hydrogen and about 48% butane.
v LUIS on FIOREZ.
US319448A 1928-11-14 1928-11-14 Gaseous fuel Expired - Lifetime US1936155A (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
US319448A US1936155A (en) 1928-11-14 1928-11-14 Gaseous fuel
US690948A US1936156A (en) 1928-11-14 1933-09-25 Gaseous fuel

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US319448A US1936155A (en) 1928-11-14 1928-11-14 Gaseous fuel

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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3125085A (en) * 1964-03-17 Control of fuel introduction to engine cylinder
US5660602A (en) * 1994-05-04 1997-08-26 University Of Central Florida Hydrogen enriched natural gas as a clean motor fuel
US5666923A (en) * 1994-05-04 1997-09-16 University Of Central Florida Hydrogen enriched natural gas as a motor fuel with variable air fuel ratio and fuel mixture ratio control
US6397790B1 (en) 2000-04-03 2002-06-04 R. Kirk Collier, Jr. Octane enhanced natural gas for internal combustion engine
US6405720B1 (en) 2000-04-03 2002-06-18 R. Kirk Collier, Jr. Natural gas powered engine
US6508209B1 (en) 2000-04-03 2003-01-21 R. Kirk Collier, Jr. Reformed natural gas for powering an internal combustion engine
US6739125B1 (en) 2002-11-13 2004-05-25 Collier Technologies, Inc. Internal combustion engine with SCR and integrated ammonia production

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3125085A (en) * 1964-03-17 Control of fuel introduction to engine cylinder
US5660602A (en) * 1994-05-04 1997-08-26 University Of Central Florida Hydrogen enriched natural gas as a clean motor fuel
US5666923A (en) * 1994-05-04 1997-09-16 University Of Central Florida Hydrogen enriched natural gas as a motor fuel with variable air fuel ratio and fuel mixture ratio control
US6397790B1 (en) 2000-04-03 2002-06-04 R. Kirk Collier, Jr. Octane enhanced natural gas for internal combustion engine
US6405720B1 (en) 2000-04-03 2002-06-18 R. Kirk Collier, Jr. Natural gas powered engine
US6508209B1 (en) 2000-04-03 2003-01-21 R. Kirk Collier, Jr. Reformed natural gas for powering an internal combustion engine
US6739125B1 (en) 2002-11-13 2004-05-25 Collier Technologies, Inc. Internal combustion engine with SCR and integrated ammonia production

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