US1926620A - Process of producing monochrome or multicolor gelatin relief photographs - Google Patents
Process of producing monochrome or multicolor gelatin relief photographs Download PDFInfo
- Publication number
- US1926620A US1926620A US452817A US45281730A US1926620A US 1926620 A US1926620 A US 1926620A US 452817 A US452817 A US 452817A US 45281730 A US45281730 A US 45281730A US 1926620 A US1926620 A US 1926620A
- Authority
- US
- United States
- Prior art keywords
- color
- photographs
- support
- positives
- gelatin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 108010010803 Gelatin Proteins 0.000 title description 13
- 229920000159 gelatin Polymers 0.000 title description 13
- 239000008273 gelatin Substances 0.000 title description 13
- 235000019322 gelatine Nutrition 0.000 title description 13
- 235000011852 gelatine desserts Nutrition 0.000 title description 13
- 238000000034 method Methods 0.000 title description 11
- 239000000839 emulsion Substances 0.000 description 48
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 28
- 239000000975 dye Substances 0.000 description 24
- YCIMNLLNPGFGHC-UHFFFAOYSA-N catechol Chemical compound OC1=CC=CC=C1O YCIMNLLNPGFGHC-UHFFFAOYSA-N 0.000 description 15
- 235000010265 sodium sulphite Nutrition 0.000 description 14
- 229920000742 Cotton Polymers 0.000 description 10
- 238000004043 dyeing Methods 0.000 description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical compound [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 5
- 238000004040 coloring Methods 0.000 description 3
- 229920002160 Celluloid Polymers 0.000 description 2
- COHYTHOBJLSHDF-UHFFFAOYSA-N Indigo Chemical compound N1C2=CC=CC=C2C(=O)C1=C1C(=O)C2=CC=CC=C2N1 COHYTHOBJLSHDF-UHFFFAOYSA-N 0.000 description 2
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 2
- 239000000969 carrier Substances 0.000 description 2
- STLZCUYBVPNYED-UHFFFAOYSA-N chlorbetamide Chemical compound OCCN(C(=O)C(Cl)Cl)CC1=CC=C(Cl)C=C1Cl STLZCUYBVPNYED-UHFFFAOYSA-N 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 239000004332 silver Substances 0.000 description 2
- 229910052709 silver Inorganic materials 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- 230000003313 weakening effect Effects 0.000 description 2
- -1 Benzopurpurin Chemical compound 0.000 description 1
- CRDNMYFJWFXOCH-BUHFOSPRSA-N Couroupitine B Natural products N\1C2=CC=CC=C2C(=O)C/1=C1/C2=CC=CC=C2NC1=O CRDNMYFJWFXOCH-BUHFOSPRSA-N 0.000 description 1
- 241000735495 Erica <angiosperm> Species 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- AOADSHDCARXSGL-ZMIIQOOPSA-M alkali blue 4B Chemical compound CC1=CC(/C(\C(C=C2)=CC=C2NC2=CC=CC=C2S([O-])(=O)=O)=C(\C=C2)/C=C/C\2=N\C2=CC=CC=C2)=CC=C1N.[Na+] AOADSHDCARXSGL-ZMIIQOOPSA-M 0.000 description 1
- 239000000987 azo dye Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 230000000295 complement effect Effects 0.000 description 1
- IQFVPQOLBLOTPF-HKXUKFGYSA-L congo red Chemical compound [Na+].[Na+].C1=CC=CC2=C(N)C(/N=N/C3=CC=C(C=C3)C3=CC=C(C=C3)/N=N/C3=C(C4=CC=CC=C4C(=C3)S([O-])(=O)=O)N)=CC(S([O-])(=O)=O)=C21 IQFVPQOLBLOTPF-HKXUKFGYSA-L 0.000 description 1
- 125000000664 diazo group Chemical group [N-]=[N+]=[*] 0.000 description 1
- SOCTUWSJJQCPFX-UHFFFAOYSA-N dichromate(2-) Chemical compound [O-][Cr](=O)(=O)O[Cr]([O-])(=O)=O SOCTUWSJJQCPFX-UHFFFAOYSA-N 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 239000000982 direct dye Substances 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- CRDNMYFJWFXOCH-UHFFFAOYSA-N indirubin Chemical compound N1C2=CC=CC=C2C(=O)C1=C1C2=CC=CC=C2NC1=O CRDNMYFJWFXOCH-UHFFFAOYSA-N 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- NYGZLYXAPMMJTE-UHFFFAOYSA-M metanil yellow Chemical group [Na+].[O-]S(=O)(=O)C1=CC=CC(N=NC=2C=CC(NC=3C=CC=CC=3)=CC=2)=C1 NYGZLYXAPMMJTE-UHFFFAOYSA-M 0.000 description 1
- 239000000983 mordant dye Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 239000010979 ruby Substances 0.000 description 1
- 229910001750 ruby Inorganic materials 0.000 description 1
- 239000001648 tannin Substances 0.000 description 1
- 235000018553 tannin Nutrition 0.000 description 1
- 229920001864 tannin Polymers 0.000 description 1
- 239000000984 vat dye Substances 0.000 description 1
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C5/00—Photographic processes or agents therefor; Regeneration of such processing agents
- G03C5/26—Processes using silver-salt-containing photosensitive materials or agents therefor
- G03C5/29—Development processes or agents therefor
- G03C5/315—Tanning development
Definitions
- the invention consists in applying to photographic emulsions (for instance halogen-silver-emulsions) soluble, non-diffusing colloidal and highly transparent dyes (substantive cotton dyes), in which the emulsions are colored, such emulsions serving then for the production of-monochrome or multi-color gelatin, relief ,photographs' in the multi-color-specially three color photography.
- photographic emulsions for instance halogen-silver-emulsions
- non-diffusing colloidal and highly transparent dyes substantially transparent dyes
- substantially cotton dyes substantially transparent dyes
- the removable emulsions containing thenon-diffusing colloidal dyes being squeezed on paper after their tanning developmentproducing relief pictures, dried and pulled ofi.
- the colloidal color photographs are quite clear, as the photograph, when being transferred onto paper do not diffuse. This is especially advantageous for the production of three color photographs, as these, when the individual photographs are made on emulsions capable to be transferred; require the prevention of diffusions of the colors at the transferring upon color emulsions which have already been properly mounted.
- the invention consists further in that the in- ,dividual relief photographs, produced by tanning developing and colored with nondiffusing' 'colloidal dyes", are mounted successively on a support such as paper, celluloid or the like so that-the contours register and then pulled off their emulsion carriers, each emulsion being pressed on the support and dried, before the next following emulsion is pressed on, so that the finished multi-color photograph consists only of superposed transfer-- special manner of applyingthe developer and in a support.
- a support such as paper, celluloid or the like
- a solution containing the tannin, pyrocatechin, and sodium sulphite in which the ratio of sodium sulphite to pyrocatechin by weight is greater than one-half.
- the use of a pyrocatechindeveloper without sodium sulphite enables to produce washable relief photographs but, because of the accompanying oxidizing reaction the gelatin, adjacent to the silver, is hardened and made insoluble.
- the use of a substantial quantity of sodium sulphite prevents oxidation and consequent hardening of the gelatin, and thus provides for its removal with hot water.
- colloidal dyes are added to the photographic emulsion, it will be found, that the tanning developer without the sulphite is incapable of dissolving the gelatin-dye-complex even, in very hot water. Only developing solutions containing higher quantities of sulphite are capable of dissolving an excess of the gelatin dye.
- a halogen silver gelatin layer to which colloidal dyes'are added, is developed with a pyrocatechin developer containing a quantity by weight of sodium sulphite,
- the coloring can be made weaker as desired, by subjecting the support bearing the gelatin-dye-complexes to a warm water bath for a sufilcient time to accomplish approximate or complete dissolution of the excess complexes.
- a f: vorable ,mutual blending of the part photographs can be obtained.
- this blending is important.
- At the copying and developing of multicolor photographs it happens frequently, that an excess of certain colors occurs.
- Excess of color can be easily eliminated, according to the invention, by weakening. Longer washing for weakening, as is for instance usual for mordant dyes photographs, absorption photographsor the like, is impossible for colloidal dyes relief photographs.
- Every individual relief photograph can be produced, according .to the invention, with the aid of a half tone screen, mutually displaced half tone screens being for instance used for the differently colored relief photographs.
- this layers can be produced on transparent supports.
- That process of color photography which consists in preparing .a set of films having transparent supports coated with a light sensitive emulsion layer on one side, dyeing each respective emulsion layer with a respective primary color with a substantive cotton dye corresponding to such color, printing each film through its support from the corresponding color selection negative, developing the printed films to form positives in a solution of pyrocatechin and sodium sulphite, fixing the developed positives, and arranging the fixed emulsion layers in superposed registering relation and stripped from their supports.
- That process of color photography which consists in preparing a set of films having transparent supports coated with a light sensitive emulsion layer on one side, dyeing each respective emulsion layer with a respective primary color with a non-diifusing-colloidal transparent substantive cotton dye corresponding to "such color, printing each film through its support from the. corresponding color selection negative, developing the printed films to form positives in a solution of pyrocatechin and sodium sulphite, fixing the developed positives, and arranging the fixed emulsion layers in superposed registering relation and stripped from their supports.
- That process of color photography which consists in preparing a set of films having translparent supports coated with a light sensitive emulsion layer on one side, dyeing each respective emulsion layer with a respective primary color with a substantive cotton dye corresponding to such color, printing each film through its support from the corresponding color selection negative, developing the printed films to form positives in a solution of pyrocatechin and sodium sulphite, fixing the developed positives, placing one of the fixed positives on a permanent support with the emulsion side in contact with the permanent support, stripping the transparent support from the placed emulsion, similarly treating the remaining fixed positives to cause them to lie in superposed relation and in registry.
- That process of color photography which consists in preparing a set of films having transparent supports coated with a light sensitive emulsion layer on one side, dyeing each respective emulsion layer with a respective primary color with a non-diffusing colloidal transparent substantive cotton dye corresponding to such color, printing eachfilm through its support from the corresponding color selection negative, de-
- That process of color photography which consists in preparing a set of films having transparent gelatinous supports coated with a light sensitive emulsion layer on one side, dyeing each respective emulsion layer with a respective primary color with a non-diffusing colloidal transparent substantive cotton dye corresponding to such color, printing each film through its support from the corresponding color selection negative, developing the printed films to form positives in a solution of pyrocatechin and sodium sulphite, fixing the developed positives, and arranging the fixed emulsion layers in superposed registering relation and stripped from their supports.
- That process of color photography which consists in preparing a set of films having transparent gelatinous supports coated with a light sensitive emulsion layer on one side, dyeing each respective emulsion layer with a respective primary color with a substantive cotton dye corresponding to such color, printing each film through its support from the corresponding color selection negative, developing the printed films to form positives in a solution of pyrocatechin and sodium sulphite, fixing the developed positives, placing one of the fixed positives on a permanent support with the emulsion side in contact with .the permanent support, stripping the transparent support from the placed emulsion, similarly treating the remaining fixed positives to cause them to lie in superposed relation and in registry.
- That process of color photography which consists in preparing a set of films having transparent gelatinous supports coated with a light sensitive emulsion layer on one side, dyeing each respective emulsion layer with a respective primary color with a non-diffusing colloidal transparent substantive cotton dye corresponding to such color, printing each'film through its support from the corresponding color selection negative, developing the printed films to form positives in a solution of pyrocatechin and sodium sulphite, fixing the developed positives, placing one of the fixed positives on a permanent support with the emulsion side in contact with the permanent support, stripping the transparent support from the placed emulsion, similarly treating the remaining fixed positives to cause them to lie in superposed relation and in registry.
- That process of color' photography which consists in preparing a set of films having transparent supports coated with a light sensitive emulsion layer on one side, dyeing each respective emulsion layer with a respective primary color with a substantive cotton dye corresponding to such color, printing each film through its support from the corresponding color selection negative, developing the printed films to form positives in a solution of pyrocatechin and sodium sulphite with the sodium sulphite exceeding by weight one-half the pyrocatechin, fixing the developed positives, and arranging the fixed emulsion layers in superposed registering relation and stripped from their supports.
Landscapes
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Silver Salt Photography Or Processing Solution Therefor (AREA)
- Color Printing (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE1926620X | 1929-05-17 | ||
GB17113/29A GB333668A (en) | 1929-05-17 | 1929-06-04 | Process of producing multi-colour photographs |
Publications (1)
Publication Number | Publication Date |
---|---|
US1926620A true US1926620A (en) | 1933-09-12 |
Family
ID=26011409
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US452817A Expired - Lifetime US1926620A (en) | 1929-05-17 | 1930-05-15 | Process of producing monochrome or multicolor gelatin relief photographs |
Country Status (3)
Country | Link |
---|---|
US (1) | US1926620A (en(2012)) |
BE (1) | BE370307A (en(2012)) |
GB (1) | GB333668A (en(2012)) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2647049A (en) * | 1947-02-25 | 1953-07-28 | Polaroid Corp | Photographic element for color photography and a process of producing multicolor pictures |
US2650878A (en) * | 1949-12-09 | 1953-09-01 | Du Pont | Method of producing etched printing plates |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
BE414508A (en(2012)) * | 1935-04-10 | |||
DE3736645A1 (de) * | 1987-10-29 | 1989-05-11 | Du Pont Deutschland | System zur herstellung punktgeaetzter lithographischer filme |
-
0
- BE BE370307D patent/BE370307A/xx unknown
-
1929
- 1929-06-04 GB GB17113/29A patent/GB333668A/en not_active Expired
-
1930
- 1930-05-15 US US452817A patent/US1926620A/en not_active Expired - Lifetime
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2647049A (en) * | 1947-02-25 | 1953-07-28 | Polaroid Corp | Photographic element for color photography and a process of producing multicolor pictures |
US2650878A (en) * | 1949-12-09 | 1953-09-01 | Du Pont | Method of producing etched printing plates |
Also Published As
Publication number | Publication date |
---|---|
GB333668A (en) | 1930-08-21 |
BE370307A (en(2012)) |
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