US1926265A - Coating metal with zinc phosphate - Google Patents

Coating metal with zinc phosphate Download PDF

Info

Publication number
US1926265A
US1926265A US500870A US50087030A US1926265A US 1926265 A US1926265 A US 1926265A US 500870 A US500870 A US 500870A US 50087030 A US50087030 A US 50087030A US 1926265 A US1926265 A US 1926265A
Authority
US
United States
Prior art keywords
zinc
cyanide
phosphate
bath
solution
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US500870A
Inventor
Van M Darsey
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
METAL FINISHING RES CORP
METAL FINISHING RESEARCH Corp
Original Assignee
METAL FINISHING RES CORP
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by METAL FINISHING RES CORP filed Critical METAL FINISHING RES CORP
Priority to US500870A priority Critical patent/US1926265A/en
Application granted granted Critical
Publication of US1926265A publication Critical patent/US1926265A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
    • C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
    • C23C22/07—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing phosphates
    • C23C22/08—Orthophosphates
    • C23C22/12—Orthophosphates containing zinc cations

Definitions

  • This invention relates to producing a phosphate coating on surfaces of iron, steel, zinc or magnesium or their alloys by means of zinc phosphate, and more particularly by means of 5 such a phosphate when its action is accelerated.
  • the object of the invention is to produce a method and solution by which a coating of the character desired may be produced in reduced time and at a reduced temperature.
  • a bath is formed by introducing therein zinc dihydrogen phosphate and zinc cyanide, preferably about 3% by weight of zinc cyanide to the zinc phosphate powder introduced in the bath.
  • the work to be coated is then introduced into the bath, the bath being kept at a suitabletemperature.
  • the zinc cyanide acts as an accelerator and under favorable conditions a complete coating on iron surfaces may be produced in as little as three minutes but under ordinary workingconditions a time from seven to fifteen minutes may be expected to give complete coating upon ordinary work.
  • the quality of the coating is not injured in any way by 0 the accelerating compound.
  • the bath may be 5 nearly as rapidly at 75 centigrade as at from 95 to 98 centigrade, the usual temperature at which the bath has been kept hitherto. This possibility of acting at a reduced temperature is a considerable convenience under many circumstances.
  • Zinc cyanide added to other phosphate baths suitable for coating also has an accelerating action but is not as effective in baths made up of manganese and iron phosphates as where zinc phosphate is used to form and replenish the bath. The presence of zinc ions in the bath seems to render the zinc cyanide much more effective.
  • Soluble cyanides such as potassium cyanide, sodium cyanide and ammonium cyanide, may be used to produce an accelerating effect upon a phosphate bath, whether of phosphates of iron and manganese phosphate or zinc phosphate, but is most effective in thebath containing zinc phosphate.
  • the soluble cyanides quickly form insoluble compounds, apparently mostly with the phosphates of iron in the bath, and thereby the cyanides lose their accelerating effect. For this reason'addition of a soluble cyanide to a bath has only a temporary accelerating effect.
  • Zinc cyanide as well as other slightly soluble cyanides such as cyanides of copper, barium and manganese, go into the solution slowly, and, therefore, have a more permanent accelerating action. Of these less soluble cyanides, the zinc cyanide appears to be most active and at the same time maintains its effect.
  • a less amount of cyanide than 3% may be added and obtain a degree of acceleration, and considerably greater amounts may be used if desired without injurious results.
  • Soluble cyanides such as sodium cyanide
  • acid phosphates of iron, manganese or zinc react therewith and give off HCN gas, which is very objectionable.
  • the soluble cyanides should beadded to the bath separately and not mixed with the powdered phosphates before being placed in the bath.
  • the reaction with zinc phosphate is less than with the other phosphates but even in that case it is inadvisable to mix a soluble cyanide with acid zinc phosphate.
  • the reaction of the less soluble cyanides is much less than that of the soluble cyanides when mixed with acid phosphates and the reaction of zinc cyanide with zinc phosphate is comparatively slight, if it occurs at all.
  • the zinc cyanide may be mixed with the zinc phosphate powder for sometime without losing its accelerating effect and without producing a perceptible amount of HCN gas.
  • Zinc carbonate also has some accelerating effect upon a zinc phosphate bath and may be added in amounts up to 4% of the phosphate in powder form.
  • the addition of zinc carbonate to the zinc phosphate powder aids somewhat also in preventing the caking of the powder and, if mixed with zinc cyanide before being mixed with the phosphate, lessens the contact of the cyanide with the phosphate and reduces the danger of objectionable reaction. For these reasons it is advisable to mix zinc carbonate and zinc cyanide and addthis mixtureto zinc phosphate, if the powders are to be mixed before being added to the bath. It will be understood that the addition of the cyanide will be. just' as effective if the bath is prepared by introducing zinc phosphate in some other way' than by first producing the zinc phosphate crystals,
  • the same amount of zinc cyanide should be used in proportion to the zinc phosphate in the bath, regardless of how this phosphate is introduced.
  • a method of coating surfaces of metal in the group consisting of iron, zinc, magnesium and their alloys which consists in forming a solution containing acid phosphates of metal in the group consisting of zinc, manganese and iron and a cyanide compound, and subjecting the surface to be coated to the action of the solution.
  • cyanide compound is a metal cyanide that is only slightly soluble in the phosphate solution.
  • a method of coating surfaces of metal in the group consisting of iron, zinc, magnesium and their alloys which consists in forming a solution containing acid phosphates, including zinc dihydrogen phosphate, zinc' carbonate and zinc cyanide, and subjecting the surface to be coated to the action of the solution.
  • a compound for replenishing coating baths comprising dry zinc dihydrogen phosphate as its major constituent, zinc'carbonate and zinc cyanide.
  • a method of coating surfaces of metal of the group consisting of iron, zinc, magnesium and their alloys which consists in forming a solution containing acid phosphates of metal in the group consisting of"zinc, manganese and iron, and'a cyanide compound, subjectingsurfaces to be coated to the action of the solution, and replenishing the solution-by the addition of zinc di-hydrogen phosphate and zinc cyanide, the amount of the cyanide being about 3% of the amount of phosphate.

Description

Patented Sept. 12, 1933 UNITED STATES COATING METAL WITH zmc PHOSPHATE Van M, Darsey, Detroit, Mich., assignor to Metal Finishing Research Corporation, Detroit, Mich., 'a corporation of Michigan No Drawing. Application December 8,
Serial No. 500,870. Renewed July 10, 1933 Claims. (Cl. 1486.5)
This invention relates to producing a phosphate coating on surfaces of iron, steel, zinc or magnesium or their alloys by means of zinc phosphate, and more particularly by means of 5 such a phosphate when its action is accelerated.
The object of the invention is to produce a method and solution by which a coating of the character desired may be produced in reduced time and at a reduced temperature.
The material and method of treatment is susceptible to various modifications, but the preferred form of the invention will be described first and then modifications will be discussed later.
In the preferred form of the invention a bath is formed by introducing therein zinc dihydrogen phosphate and zinc cyanide, preferably about 3% by weight of zinc cyanide to the zinc phosphate powder introduced in the bath. The work to be coated is then introduced into the bath, the bath being kept at a suitabletemperature. The zinc cyanide acts as an accelerator and under favorable conditions a complete coating on iron surfaces may be produced in as little as three minutes but under ordinary workingconditions a time from seven to fifteen minutes may be expected to give complete coating upon ordinary work. The quality of the coating is not injured in any way by 0 the accelerating compound. The bath may be 5 nearly as rapidly at 75 centigrade as at from 95 to 98 centigrade, the usual temperature at which the bath has been kept hitherto. This possibility of acting at a reduced temperature is a considerable convenience under many circumstances.
Zinc cyanide added to other phosphate baths suitable for coating also has an accelerating action but is not as effective in baths made up of manganese and iron phosphates as where zinc phosphate is used to form and replenish the bath. The presence of zinc ions in the bath seems to render the zinc cyanide much more effective.
Soluble cyanides, such as potassium cyanide, sodium cyanide and ammonium cyanide, may be used to produce an accelerating effect upon a phosphate bath, whether of phosphates of iron and manganese phosphate or zinc phosphate, but is most effective in thebath containing zinc phosphate. However, the soluble cyanides quickly form insoluble compounds, apparently mostly with the phosphates of iron in the bath, and thereby the cyanides lose their accelerating effect. For this reason'addition of a soluble cyanide to a bath has only a temporary accelerating effect.
Zinc cyanide, as well as other slightly soluble cyanides such as cyanides of copper, barium and manganese, go into the solution slowly, and, therefore, have a more permanent accelerating action. Of these less soluble cyanides, the zinc cyanide appears to be most active and at the same time maintains its effect. I
A less amount of cyanide than 3% may be added and obtain a degree of acceleration, and considerably greater amounts may be used if desired without injurious results.
Soluble cyanides, such as sodium cyanide, when mixed with acid phosphates of iron, manganese or zinc, react therewith and give off HCN gas, which is very objectionable. For this reason if the soluble cyanides are to be used they should beadded to the bath separately and not mixed with the powdered phosphates before being placed in the bath. The reaction with zinc phosphate is less than with the other phosphates but even in that case it is inadvisable to mix a soluble cyanide with acid zinc phosphate.
The reaction of the less soluble cyanides is much less than that of the soluble cyanides when mixed with acid phosphates and the reaction of zinc cyanide with zinc phosphate is comparatively slight, if it occurs at all. Apparently the zinc cyanide may be mixed with the zinc phosphate powder for sometime without losing its accelerating effect and without producing a perceptible amount of HCN gas.
Zinc carbonate also has some accelerating effect upon a zinc phosphate bath and may be added in amounts up to 4% of the phosphate in powder form. The addition of zinc carbonate to the zinc phosphate powder aids somewhat also in preventing the caking of the powder and, if mixed with zinc cyanide before being mixed with the phosphate, lessens the contact of the cyanide with the phosphate and reduces the danger of objectionable reaction. For these reasons it is advisable to mix zinc carbonate and zinc cyanide and addthis mixtureto zinc phosphate, if the powders are to be mixed before being added to the bath. It will be understood that the addition of the cyanide will be. just' as effective if the bath is prepared by introducing zinc phosphate in some other way' than by first producing the zinc phosphate crystals,
providing the same composition of bath is obtained. In such cases the same amount of zinc cyanide should be used in proportion to the zinc phosphate in the bath, regardless of how this phosphate is introduced.
While the specific invention relates to the addition'of zinc cyanide to a bath containing zinc phosphate it will be readily understood from the foregoing that various modifications and substitutions may be made within the scope of the appended claims.
What is claimed is:
1. A method of coating surfaces of metal in the group consisting of iron, zinc, magnesium and their alloys, which consists in forming a solution containing acid phosphates of metal in the group consisting of zinc, manganese and iron and a cyanide compound, and subjecting the surface to be coated to the action of the solution.
2. A method in accordance with claim 1, in which the acid phosphate includes zinc phosphate.
3. A method in accordance with claim 1, in which the cyanide compound is a metal cyanide that is only slightly soluble in the phosphate solution.
4. A method in accordance with claim 1, in which the acid phosphate includes zinc phosphate, and the cyanide compound is zinc cyanide.
5. A method of coating surfaces of metal in the group consisting of iron, zinc, magnesium and their alloys, which consists in forming a solution containing acid phosphates, including zinc dihydrogen phosphate, zinc' carbonate and zinc cyanide, and subjecting the surface to be coated to the action of the solution.
6. A solution for coating surfaces of metal in the group consisting of iron, zinc, magnesium and their alloys, which comprises acid phosphates of metal in the group consisting of zinc,
manganese, and iron, and a cyanide compound.
7. A solution as claimed in claim 6 in which the acid phosphates include zinc dihydrogen phosphate.
8. A solution as claimed in claim 6, in which the cyanide compound is a metal cyanide slightly soluble in the phosphate solution.
9. A solution in accordance with claim 6, in which the cyanide is zinc cyanide.
10. A solution in accordance with claim 6, in which zinc dihydrogen phosphate is included in the acid phosphates and the cyanide is zinc cyanide.
11. A solution in accordance with claim 6, and which contains zinc carbonate.
12. A solution for coating surfaces of metal in the group consisting of iron, zinc, magnesium and their alloys, which comprises acid phosphates including zinc dihydrogen phosphate, zinc carbonate, and zinc cyanide.
13. A compound for replenishing coating baths, comprising dry zinc dihydrogen phosphate as its major constituent, zinc'carbonate and zinc cyanide.
14. A compound in accordance with claim 12, and in which the zinc carbonate forms about 4% and the zinc cyanide about 3%.
15. A method of coating surfaces of metal of the group consisting of iron, zinc, magnesium and their alloys, which consists in forming a solution containing acid phosphates of metal in the group consisting of"zinc, manganese and iron, and'a cyanide compound, subjectingsurfaces to be coated to the action of the solution, and replenishing the solution-by the addition of zinc di-hydrogen phosphate and zinc cyanide, the amount of the cyanide being about 3% of the amount of phosphate.
' VAN M. DARSEY.
US500870A 1930-12-08 1930-12-08 Coating metal with zinc phosphate Expired - Lifetime US1926265A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
US500870A US1926265A (en) 1930-12-08 1930-12-08 Coating metal with zinc phosphate

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US500870A US1926265A (en) 1930-12-08 1930-12-08 Coating metal with zinc phosphate

Publications (1)

Publication Number Publication Date
US1926265A true US1926265A (en) 1933-09-12

Family

ID=23991280

Family Applications (1)

Application Number Title Priority Date Filing Date
US500870A Expired - Lifetime US1926265A (en) 1930-12-08 1930-12-08 Coating metal with zinc phosphate

Country Status (1)

Country Link
US (1) US1926265A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE750957C (en) * 1938-02-04 1945-02-03 Process for the production of phosphate coatings on metals
US2515529A (en) * 1946-07-22 1950-07-18 Nat Aluminate Corp Corrosion inhibiting compositions and method

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE750957C (en) * 1938-02-04 1945-02-03 Process for the production of phosphate coatings on metals
US2515529A (en) * 1946-07-22 1950-07-18 Nat Aluminate Corp Corrosion inhibiting compositions and method

Similar Documents

Publication Publication Date Title
US1911726A (en) Production of phosphate coatings on metals
US2477841A (en) Method of coating metal surfaces comprising aluminum
JP2700061B2 (en) Method of forming phosphate film
US2462196A (en) Protective phosphate coatings for metal surfaces
US2460896A (en) Composition for blackening copper and copper alloy surfaces
US2067007A (en) Method of coating metal
JP2845246B2 (en) Method of forming phosphate film
US1254263A (en) Rust-proofing iron and steel surfaces.
US2813812A (en) Method for coating iron or zinc with phosphate composition and aqueous solution therefor
US1926265A (en) Coating metal with zinc phosphate
US2234206A (en) Coated aluminum
US2840498A (en) Composition and method for producing combination corrosion resistant and lubricatingcoatings on metals
KR840007037A (en) Phosphoric Acid Treatment of Galvanized Metals
US2591479A (en) Method of and solution for coating surfaces chiefly of zinc
US2001754A (en) Method and material for producing phosphate coating
JPS5855229B2 (en) Surface conditioner for zinc phosphate treatment
US3181976A (en) Phosphating process and composition
US1291352A (en) Solution for rust-proofing articles of iron and steel.
US2097211A (en) Protective treatment of metals and alloys
US2322205A (en) Method of treating magnesium and its alloys
US2930723A (en) Surface treatment of metals
US3510365A (en) Process of pretreating ferrous metal surfaces before phosphatizing
GB768443A (en) Improvements relating to the production of phosphate coatings on metal surfaces
US1796248A (en) Process for the cementation of iron and steel
US2045499A (en) Method of and material for coating metal surfaces