US191698A - Improvement in processes of producing wrought-lron and steel from cold-short pig - Google Patents
Improvement in processes of producing wrought-lron and steel from cold-short pig Download PDFInfo
- Publication number
- US191698A US191698A US191698DA US191698A US 191698 A US191698 A US 191698A US 191698D A US191698D A US 191698DA US 191698 A US191698 A US 191698A
- Authority
- US
- United States
- Prior art keywords
- steel
- iron
- cold
- lron
- improvement
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229910000831 Steel Inorganic materials 0.000 title description 8
- 239000010959 steel Substances 0.000 title description 8
- 238000000034 method Methods 0.000 title description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 28
- 229910052742 iron Inorganic materials 0.000 description 14
- 229910052751 metal Inorganic materials 0.000 description 9
- 239000002184 metal Substances 0.000 description 9
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 6
- 229910052698 phosphorus Inorganic materials 0.000 description 6
- 239000011574 phosphorus Substances 0.000 description 6
- 239000000126 substance Substances 0.000 description 5
- 238000010438 heat treatment Methods 0.000 description 4
- 239000002893 slag Substances 0.000 description 4
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 3
- 229910000754 Wrought iron Inorganic materials 0.000 description 3
- 229910001208 Crucible steel Inorganic materials 0.000 description 2
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- UCNNJGDEJXIUCC-UHFFFAOYSA-L hydroxy(oxo)iron;iron Chemical compound [Fe].O[Fe]=O.O[Fe]=O UCNNJGDEJXIUCC-UHFFFAOYSA-L 0.000 description 2
- NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Inorganic materials O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- 229910001018 Cast iron Inorganic materials 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000003610 charcoal Substances 0.000 description 1
- 238000005262 decarbonization Methods 0.000 description 1
- 238000009950 felting Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 235000000396 iron Nutrition 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 235000017550 sodium carbonate Nutrition 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21C—PROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
- C21C3/00—Manufacture of wrought-iron or wrought-steel
Definitions
- the work may be conducted in the ordinary puddling or boiling furnace with a fix or felting of pulverized magnetic oxide of iron.
- Thedamper is kept well open, so as to run up to near a white heat, which will cause the impurities of the iron to separate and unite with the chemicals, and be washed off with the slag.
- the iron has come to nature, and the ball formed by the usual manipulation, it is to be taken out and put through the squeezer or other compacting device, and next drawn into muck-bar.
- the operation of forming the puddle-ball may be completed in, say, an hour to an hour and fifteen minutes in the ordinary puddlingfurnace, the best results being obtained by taking out the ball as soon as it has sufficient consistency to be handled, further heating having a tendency to cause the phosphorus to return to the iron.
- the muck-bar is next cut into fagots, piled, reheated in a heatingfurnace, and drawn or rolled into any form required, and will be a good article of merchantable iron, free from shortness, either hot or cold.
- the treatment is to be varied as follows, using the same metal and chemicals as before:
- the heating is kept up till the charge begins to show signs of coming to nature-that is, when it begins to grain or curdle.
- the chemicals are then added, and the damper closed, so as to prevent the further decarbonization of the pig-metal.
- the puddler should then work the chargejwith the bar, taking care to keep the mass well covered with the slag, so as to prevent as much as possible the contact of the oxygen with the iron.
- the muck-ball is formed, taken out, and hammered, so as to form a bloom, which may be reheated and drawn either by hammering or rolling.
- the steel or steely iron thus produced is a good article for many purposes; but in order to make it into good cast-steel, the hammerbloom should be drawn into bars about two inches wide and half-inch thick, and then out into mold pieces or chips, as ordinarily practiced in making crucible-steel. The pieces are then melted in a crucible with the addition of half pound of black oxide of manganese and a fourth pound of pulverized charcoal to each charge of seventy-five pounds of the pieces of steel.
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Manufacture Of Iron (AREA)
Description
iron or steel.
lUNiTE STATES PATENT QEEIGE oHAELES o. MGGARTEY, OF KNOXVILLE, TENNESSEE.
IMPROVEMENT lN PROCESSES 0F PRODUCING WROUGHT-IRON AND STEEL FROM COLD-SHORT EIG.
Specification forming part of Letters Patent No. 19 1,698, dated J une 5, 1877; application filed May 28, 1877.
To all whom it may concern:
Be it known that I,'GH ARLES G. MCCAR- TEY, of Knoxville, in the county of Knox and State of Tennessee, .have invented certain ing proportioned to the amount of phosphorus contained in the'iron, and theheat and time of treatment being regulated so as to produce either iron or steel, as desired, and
also so as to produce different qualities of steel as wanted.
The following description will enable others to carry out the invention.
As a good example to illustrate in a practical way the invention,-I give the complete method of producing from what is known as Mayville or Iron Ridge pig-metal, good bar The analysis of this metal shows it to contain about. 2.63 per cent. of phosphorus, and it is quite coldshort, and would require much skill if treated in the ordinary manner of puddling or boiling to produce any bar-iron, and good iron cannot be produced at-all.
The work may be conducted in the ordinary puddling or boiling furnace with a fix or felting of pulverized magnetic oxide of iron.
4 This magnetic oxide is very free from phosphorus, and, therefore, the amount of phosphorus in the pig-metal will not be increased. Upon the hearth is placed the usual bed of slag, roll or hammer scale, and wrought-iron scrap, as commonly usedin puddling. Upon this is placed the charge of pig-metal to be treated,rwhich is melted in the usual way upon the hearth of the furnace. As soon as it is melted, for every three hundred pounds of melted cast-iron I add three pounds of black oxide of manganese, three-fourths of a pound of carbonate of soda, and one-fourth pound of soda-ash. these chemicals being pulverized and well mixed together. Thedamper is kept well open, so as to run up to near a white heat, which will cause the impurities of the iron to separate and unite with the chemicals, and be washed off with the slag. When the iron has come to nature, and the ball formed by the usual manipulation, it is to be taken out and put through the squeezer or other compacting device, and next drawn into muck-bar.
The operation of forming the puddle-ball may be completed in, say, an hour to an hour and fifteen minutes in the ordinary puddlingfurnace, the best results being obtained by taking out the ball as soon as it has sufficient consistency to be handled, further heating having a tendency to cause the phosphorus to return to the iron. The muck-bar is next cut into fagots, piled, reheated in a heatingfurnace, and drawn or rolled into any form required, and will be a good article of merchantable iron, free from shortness, either hot or cold.
When the final result is to be steel, steely iron, or homogeneous metal, the treatment is to be varied as follows, using the same metal and chemicals as before: The heating is kept up till the charge begins to show signs of coming to nature-that is, when it begins to grain or curdle. The chemicals are then added, and the damper closed, so as to prevent the further decarbonization of the pig-metal. The puddler should then work the chargejwith the bar, taking care to keep the mass well covered with the slag, so as to prevent as much as possible the contact of the oxygen with the iron. When the whole mass has come to nature, and the metal is uniform beneath the slag, and separated therefrom, the muck-ball is formed, taken out, and hammered, so as to form a bloom, which may be reheated and drawn either by hammering or rolling.
The steel or steely iron thus produced is a good article for many purposes; but in order to make it into good cast-steel, the hammerbloom should be drawn into bars about two inches wide and half-inch thick, and then out into mold pieces or chips, as ordinarily practiced in making crucible-steel. The pieces are then melted in a crucible with the addition of half pound of black oxide of manganese and a fourth pound of pulverized charcoal to each charge of seventy-five pounds of the pieces of steel.
1 have described the operation as it is conducted with the ordinary puddling-furnace, and the ordinary mode of heating such furnace; but other forms of furnaces and other modes of heating may be substituted without departing from the nature of the invention, as hereinabove stated.
I have given the proportions of chemicals to be used when treating an iron of the character of the Mayville pig-metal. Other irons have some more and some less of phosphorus, for which the proportions should be varied accordingly.
I have described the use of soda-salts, which I prefer, but potash-salts may be substituted.
Having thus described my invention, what I claim, and desire to secure "by Letters Pat-
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US191698A true US191698A (en) | 1877-06-05 |
Family
ID=2261105
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US191698D Expired - Lifetime US191698A (en) | Improvement in processes of producing wrought-lron and steel from cold-short pig |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US191698A (en) |
-
0
- US US191698D patent/US191698A/en not_active Expired - Lifetime
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