US191257A - Improvement in processes of preserving wood and other vegetable matter - Google Patents
Improvement in processes of preserving wood and other vegetable matter Download PDFInfo
- Publication number
- US191257A US191257A US191257DA US191257A US 191257 A US191257 A US 191257A US 191257D A US191257D A US 191257DA US 191257 A US191257 A US 191257A
- Authority
- US
- United States
- Prior art keywords
- wood
- processes
- improvement
- lead
- vegetable matter
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000002023 wood Substances 0.000 title description 13
- 238000000034 method Methods 0.000 title description 8
- 235000013311 vegetables Nutrition 0.000 title description 4
- 239000000047 product Substances 0.000 description 8
- 150000003839 salts Chemical class 0.000 description 8
- 239000000243 solution Substances 0.000 description 7
- 239000003795 chemical substances by application Substances 0.000 description 4
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 3
- 239000011148 porous material Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 229910021653 sulphate ion Inorganic materials 0.000 description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- 241001162694 Hippolyte Species 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000002244 precipitate Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 1
- 229910002651 NO3 Inorganic materials 0.000 description 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 1
- 235000011941 Tilia x europaea Nutrition 0.000 description 1
- 150000001242 acetic acid derivatives Chemical class 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 230000002421 anti-septic effect Effects 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 210000003850 cellular structure Anatomy 0.000 description 1
- 239000013043 chemical agent Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000004571 lime Substances 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- 229940072033 potash Drugs 0.000 description 1
- 235000015320 potassium carbonate Nutrition 0.000 description 1
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Substances [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- 238000009877 rendering Methods 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 238000009738 saturating Methods 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
- B27K3/52—Impregnating agents containing mixtures of inorganic and organic compounds
Definitions
- the plumbic .liquids we employ are, first, plumbates of lime, potash, or soda second, double hyposulphites of lead and soda; third, ammonio-plumbic salts-that is'to say, insoluble salts of lead retained in solution by the presence of ammoniacal products; fourth, basic acetates and pyrolignites of lead.
- Our invention is also applicable to the application of salts of lead for preserving cloth or canvas used for awnings, tents, sails, wrappers, or coverings, and generally all kinds of fabrics exposed to the action of air or moisture, and liable to deterioration from these or other causes of a like nature; also, in their application for the preservation of cables,
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Forests & Forestry (AREA)
- Chemical And Physical Treatments For Wood And The Like (AREA)
Description
UNITED STATES PATENT QFFIC'E.
HENRI N. ROGE, EDOUARD PORET, PIERRE H. BAFFOY, AND PIERRE S. E.
DUPRE, OF PARIS, FRANCE.
IMPROVEMENT l N PROCESSES 0F PRESERVING WOOD AND OTHER VEGETABLE MATTER.
Specification forming part of Letters Patent No. 19] ,267, dated May 29, 1877; application filed December 21, 1876.
To all whom it may concern Be it known that we, HENRI NICOLAS ROGE, EDOUARD PORET, PIERRE HIPPO- LYTE BAFFOY, and PIERRE STANISLAS ELEO-' wood or other vegetable matter.
Experience has shown that all plumbic preparations are not suitable for this purpose, and those which have been tried, some even on a large scale, have failed, owing either to an unwise choice of the product employed or to the defective method of application adopted.
We shall, therefore, in the present specification, endeavor more especially to specify clearly the methods or processes upon which the value of our invention depends, it being understood that we make no claim to any other method, whether based or not on the employment of plumbic compounds differing from those hereinafter specified. We have found that when wood is first impregnated with a soluble salt of lead, (such as acetate or nitrate of lead,) and then with a re-agent, (sulphate, carbonate, alkali, &c.,) capable of precipitating-that is to say, of rendering insoluble the salt of lead-this second solution is only with great difficulty made to penetrate the cellular structure of the wood except by driving out and taking the place of the firstmentioned solution, with which the pores of the wood are already filled, so that the result desired is not attained. Moreover, the precipitates formed at the free ends of the ligneous fibers at once obstruct the channels to the stance of the wood itself, and more especially with its nitrogenous products, instead of being merely a foreign substance deposited in ble.
the pores of the wood in an insoluble form, as would be the case could a lead precipitate be really produced in the wood by means of a chemical re-agent.
The action of these solutions is still more illusory when they are simply externally applied upon the wood, as it has been heretofore proposed.
In order that metallic solutions should have a real preservative action, it is further necessary that the combination which they form directly with the wood or other vegetable products should be effected as rapidly as possi- In using sulphate of copper, the slowness of the transformation (when it really takes place) is one of the many causes of the inferiority of the product.
Having in view these various considerations, we have based the method of our invention on the employment of a soluble salt of lead, which combines easily and rapidly with the extractive matter of wood in order to form therewith, and without the aid of any other chemical agent, an insoluble, imputrescible combination with the wood, and not a simple deposit in its pores.
The plumbic .liquids we employ are, first, plumbates of lime, potash, or soda second, double hyposulphites of lead and soda; third, ammonio-plumbic salts-that is'to say, insoluble salts of lead retained in solution by the presence of ammoniacal products; fourth, basic acetates and pyrolignites of lead.
We proceed by injection, employing the same means as in using sulphate of copper. One liquid only being used, but one injection is required.
Among the products above recited we prefer to employ the basic pyrolignite of lead, by reason of the facility with which it is decomposed in presence of organic matters, and because it contains fuliginous or tarry matters, which add still more to the antiseptic properties of its base. This salt is obtained by completely saturating pyroligneous acid with protoxide of lead, and when the saturation is quite complete and the solution has become freely alkaline, the product is dried, or it may' be diluted with water, in order to bring the solution to the degree of concentration proper for injecting, viz., from one to three degrees Baum. For diluting, water is used which has been deprived of its earthy salts by the ordinary re-agents, or the re-agents may be added to the salt of lead itself.
We do not, however, necessarily employ any special method of manufacture, but can adopt that in ordinary use in the manufacture of chemical products.
Our invention isalso applicable to the application of salts of lead for preserving cloth or canvas used for awnings, tents, sails, wrappers, or coverings, and generally all kinds of fabrics exposed to the action of air or moisture, and liable to deterioration from these or other causes of a like nature; also, in their application for the preservation of cables,
ropes, cordage, string, twine, and all kinds of PIERRE HIPPOLYTE BA FFOY. PIERRE STANISLAS ELEONORE DUPRE.
Witnesses:
RoBT. M. HOOPER, JEAN BAPTIST-E ROLLAND.
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US191257A true US191257A (en) | 1877-05-29 |
Family
ID=2260664
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US191257D Expired - Lifetime US191257A (en) | Improvement in processes of preserving wood and other vegetable matter |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US191257A (en) |
-
0
- US US191257D patent/US191257A/en not_active Expired - Lifetime
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