US1901389A - Process for liquefying and rectifying air - Google Patents
Process for liquefying and rectifying air Download PDFInfo
- Publication number
- US1901389A US1901389A US398459A US39845929A US1901389A US 1901389 A US1901389 A US 1901389A US 398459 A US398459 A US 398459A US 39845929 A US39845929 A US 39845929A US 1901389 A US1901389 A US 1901389A
- Authority
- US
- United States
- Prior art keywords
- air
- liquefying
- pressure
- exchanger
- refrigerator
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000000034 method Methods 0.000 title description 11
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- 238000001816 cooling Methods 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000010079 rubber tapping Methods 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Images
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
- F25J1/02—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process
- F25J1/0203—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process using a single-component refrigerant [SCR] fluid in a closed vapor compression cycle
- F25J1/0208—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures requiring the use of refrigeration, e.g. of helium or hydrogen ; Details and kind of the refrigeration system used; Integration with other units or processes; Controlling aspects of the process using a single-component refrigerant [SCR] fluid in a closed vapor compression cycle in combination with an internal quasi-closed refrigeration loop, e.g. with deep flash recycle loop
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
- F25J1/0002—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the fluid to be liquefied
- F25J1/0012—Primary atmospheric gases, e.g. air
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
- F25J1/003—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production
- F25J1/0032—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using the feed stream itself or separated fractions from it, i.e. "internal refrigeration"
- F25J1/0035—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using the feed stream itself or separated fractions from it, i.e. "internal refrigeration" by gas expansion with extraction of work
- F25J1/0037—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using the feed stream itself or separated fractions from it, i.e. "internal refrigeration" by gas expansion with extraction of work of a return stream
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J1/00—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures
- F25J1/003—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production
- F25J1/0032—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using the feed stream itself or separated fractions from it, i.e. "internal refrigeration"
- F25J1/004—Processes or apparatus for liquefying or solidifying gases or gaseous mixtures characterised by the kind of cold generation within the liquefaction unit for compensating heat leaks and liquid production using the feed stream itself or separated fractions from it, i.e. "internal refrigeration" by flash gas recovery
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
- F25J3/04—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream for air
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J2270/00—Refrigeration techniques used
- F25J2270/90—External refrigeration, e.g. conventional closed-loop mechanical refrigeration unit using Freon or NH3, unspecified external refrigeration
Definitions
- This invention relates to the liquefaction of air.
- the cooling of the air compressed at 200 atm. is carried out by means of an additional refrigerator with liquefied gas, which is located in the circuit after the exchanger, but before the division into two streams of the air under pressure. all the mass of which is thus submitted to said cooling under the pressure of 200 atm.
- the arrangement of -the refrigerator between the exchanger and the point of the circuit where the division of the air takes place has the following advantages: at the exhaust of the exchanger, the temperature of all the mass of air under pressure is reduced from 20 to approximately 10
- the temperature of the air at the admission thereof into the expander is reduced to approximately -100, which is disadvantageous; on the contrary, in the present invention, all the mass of compressed air, after its passage through the refrigerator, is cooled only to approximately the temperature of admission of the air into the expander thus being raised from 100 to -50 without the necessity, as is the case for known processes, of removing the exchanger (which re- 5 moval would cause a loss of cold at the exhaustof the counter current).
- This raise determines an increase in the output of the outer expansion and said increase, added to the almost cost free auxiliary cold supplied by the refrigerator (about 15 frigorie's per kilog. of compressed air), approximately doubles the production of liquid air per horse-power of compression.
- the cost free auxiliary cold which can be caused to be absorbed by the compressed air at the exhaust of an exchanger, is equal to the excess of its calorific power between about 20 and 50 over the amount of cold supplied by the counter current to thesame. But this amount is so much weaker that the o specific heat and the weight of the counter current are less. It results therefrom that it is necessary to send into the expander only a counter-current which is entirely expanded.
- the raise of the pressure of the com- 55 pressed air to 200 results in an increase in the specific heat and the calorific capacity of the mass of this air. Besides, the increase in the liquefaction owing to this high pressure reduces the importance of the countercurrent and, consequently, the amount of cold which is brought back into the system by the counter-current.
- Fig. 1 is adiagrammatic view of apparatus used for effecting the liquefaction
- Fig. 2 illustrates diagrammatically how the liquefaction apparatus is combined with the rectification apparatus.
- the air used for liquefaction is compressed at high'pres'sure, for example, 200 atmos- 85 pheres, by a compressor 1' and cooled in a water cooler 2.
- the air is then purified according to current practice and passed to an exchanger 3.
- the air is conveyed to a a0 refrigerator 4 utilizing liquefied gas, for example, ammonia.
- a a0 refrigerator 4 utilizing liquefied gas, for example, ammonia.
- the compressed and cooled air is divided into two parts.
- One part is led into a piston engine 9, in which it expands up to atmos- 9 pheric pressure.
- the other part under a pressure of 200 atm., passes through a liquefying exchanger 5 and upon leaving the same is expanded to atmospheric pressure in an expansion vessel 6 through a tap, or 1 0 cock, 11. That portion of the expanded air which remains in a gaseous state is returned as a counter current to the exchangers, in conjunction with the exhaust of the expander 9 which may join the same either at the bottom of the liquefier 5, as shown, or in the expanding vessel 6.
- a cock 7 permits the liquefied air to be drawn ofil
- the liquefaction in the expander 9 is a very intensive one and couldv interfere with the operation thereof if suitable counter-acting provisions were not made, such as a tapping ofi device at the end of the piston stroke or a compounding with tapping off in the receiver. It may be desirable in some cases, even with a decrease in cooling action, to avoid complications in effecting reduction in condensation in expander 9. This result may be attained for example by lowering the pressure at which air is admitted to the expander by means of a cook or tap, 8, or by raising the temperature of admission of the air to motor 9, either at point 13 or partly at point 13 and partly at point 12.
- the apparatus wh1ch has just been described is particularly well adapted to be coupled with one of the well known double column rectifiers.
- this quantity is usually about 30% greater than the exhaust of the expander of the liquefying machine associated with the column when the said machine is working at the rate of its maximum output.
- a process for liquefying air which comprises passing the air under high pressure through an exchanger and then through a refrigerator, dividing the air after it has passed through the refri erator into two streams, expanding one 0 said streams in a low pressure liquefying chamber, expanding the other of said streams in a work performing device operable by the expansion, returning the unliquefied air under low pressure from the liquefying chamber in heat exchange relationship to the air flowing to the liquefying chamber, and also returning the expanded, low pressure air from the work performing device in heat exchange relationship to the air flowing to the liquefying chamber.
- a process for liquefying air as set forth in claim 1 in which the return of the low pressure air from the liquefying chamber and the work performing device is directed in heat exchange relationship to the air flowing to the liquefying chamber both before and after the air flowing to the liquefying chamber passes through the refrigerator.
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- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Mechanical Engineering (AREA)
- Thermal Sciences (AREA)
- General Engineering & Computer Science (AREA)
- Separation By Low-Temperature Treatments (AREA)
Description
March 1933- M. HAZARD-FLAMAND PROCESS FOR LIQUEFYING AND RECTIFYING AIR Filea- Oct. 9, 1929 2 Sheets-Sheet l Fig.1
March 14, 1933. V M. HAZARD-FLAMAND 1,901,339
PROCESS FOR LIQUEFYING" AND RECTIFYING AIR Filed Oct. 9, 1929 2 Sheets-Sheet 2 Fig.2
Patented Mar. 14, 1933 PATENT OFFICE MAURICE HAZARD-FLAMAND, OF DOUAI, FRAIFCE PROCESS FOR LIQUEFYJING AND RECTIFYING AIR Application filed October 9, 1929, Serial No. 398,459, and in France October 18, 1928.
This invention relates to the liquefaction of air.
It is not new to cause air to be liquefied to be compressed at a pressure of 200 atm. and then to divide this air into two streams, one of which is expanded in the performance of work and the other by a throttle. It is also known to cool the air to be liquefied by means of a refrigerator.
19 It has been also proposed heretofore to divide the air into two streams, and to cool one of these streams by means of an additional refrigerator, the said stream being, however. compressed at a pressure lower than thatof the other stream.
According to the present invention, the cooling of the air compressed at 200 atm., which air is divided into two streams, is carried out by means of an additional refrigerator with liquefied gas, which is located in the circuit after the exchanger, but before the division into two streams of the air under pressure. all the mass of which is thus submitted to said cooling under the pressure of 200 atm.
The arrangement of -the refrigerator between the exchanger and the point of the circuit where the division of the air takes place has the following advantages: at the exhaust of the exchanger, the temperature of all the mass of air under pressure is reduced from 20 to approximately 10 In known processes using an exchanger, the temperature of the air at the admission thereof into the expander is reduced to approximately -100, which is disadvantageous; on the contrary, in the present invention, all the mass of compressed air, after its passage through the refrigerator, is cooled only to approximately the temperature of admission of the air into the expander thus being raised from 100 to -50 without the necessity, as is the case for known processes, of removing the exchanger (which re- 5 moval would cause a loss of cold at the exhaustof the counter current). This raise determines an increase in the output of the outer expansion and said increase, added to the almost cost free auxiliary cold supplied by the refrigerator (about 15 frigorie's per kilog. of compressed air), approximately doubles the production of liquid air per horse-power of compression.
The cost free auxiliary cold, which can be caused to be absorbed by the compressed air at the exhaust of an exchanger, is equal to the excess of its calorific power between about 20 and 50 over the amount of cold supplied by the counter current to thesame. But this amount is so much weaker that the o specific heat and the weight of the counter current are less. It results therefrom that it is necessary to send into the expander only a counter-current which is entirely expanded. The raise of the pressure of the com- 55 pressed air to 200 results in an increase in the specific heat and the calorific capacity of the mass of this air. Besides, the increase in the liquefaction owing to this high pressure reduces the importance of the countercurrent and, consequently, the amount of cold which is brought back into the system by the counter-current.
The process in accordance with the present invention'is carried out in the manner Y5 particularly described hereinafter, reference being had to the accompanying drawings, of which:
Fig. 1 is adiagrammatic view of apparatus used for effecting the liquefaction;
Fig. 2 illustrates diagrammatically how the liquefaction apparatus is combined with the rectification apparatus.
The air used for liquefaction is compressed at high'pres'sure, for example, 200 atmos- 85 pheres, by a compressor 1' and cooled in a water cooler 2. The air is then purified according to current practice and passed to an exchanger 3.
From exchanger 3 the air is conveyed to a a0 refrigerator 4 utilizing liquefied gas, for example, ammonia. After leaving refrigerator 4. the compressed and cooled air is divided into two parts. One part is led into a piston engine 9, in which it expands up to atmos- 9 pheric pressure. The other part, under a pressure of 200 atm., passes through a liquefying exchanger 5 and upon leaving the same is expanded to atmospheric pressure in an expansion vessel 6 through a tap, or 1 0 cock, 11. That portion of the expanded air which remains in a gaseous state is returned as a counter current to the exchangers, in conjunction with the exhaust of the expander 9 which may join the same either at the bottom of the liquefier 5, as shown, or in the expanding vessel 6. A cock 7 permits the liquefied air to be drawn ofil The liquefaction in the expander 9 is a very intensive one and couldv interfere with the operation thereof if suitable counter-acting provisions were not made, such as a tapping ofi device at the end of the piston stroke or a compounding with tapping off in the receiver. It may be desirable in some cases, even with a decrease in cooling action, to avoid complications in effecting reduction in condensation in expander 9. This result may be attained for example by lowering the pressure at which air is admitted to the expander by means of a cook or tap, 8, or by raising the temperature of admission of the air to motor 9, either at point 13 or partly at point 13 and partly at point 12.
In virtue of its arrangements and of its powerful output, the apparatus wh1ch has just been described is particularly well adapted to be coupled with one of the well known double column rectifiers.
It is well known that a prominent feature of this known rectifying apparatus consists in supplying to the lower column an excess of liquid nitrogen capable of rectifying in the upper column, at atmospheric pressure,
- a supplement ofair exceeding about 30% of the quantity supplied to the lower column. Now this quantity is usually about 30% greater than the exhaust of the expander of the liquefying machine associated with the column when the said machine is working at the rate of its maximum output.
It will therefore be possible, just as in other processes, to direct the exhaust of the condenser 5 into the lower column 17, either 7 directly or through a concentrating coil 18,
while, after complete expansion, the whole of the exhaust of the expander 9 will be directed upon the plate in the upper column 19. The excess of air to be rectified will be supplied to the rectifier by two compressors or a combined compressor 21 which will supply this partly compressed air into the lower column 17, and eventually partly at atmospheric pressure into the upper column 19. The counter-current of the liquefying apparatus will be secured by part of the nitrogen leaving the upper column 19.
What I claim is:
1'. A process for liquefying air which comprises passing the air under high pressure through an exchanger and then through a refrigerator, dividing the air after it has passed through the refri erator into two streams, expanding one 0 said streams in a low pressure liquefying chamber, expanding the other of said streams in a work performing device operable by the expansion, returning the unliquefied air under low pressure from the liquefying chamber in heat exchange relationship to the air flowing to the liquefying chamber, and also returning the expanded, low pressure air from the work performing device in heat exchange relationship to the air flowing to the liquefying chamber.
2. A process for liquefying air as set forth in claim 1 in which the return of the low pressure air from the liquefying chamber and the work performing device is directed in heat exchange relationship to the air flowing to the liquefying chamber both before and after the air flowing to the liquefying chamber passes through the refrigerator.
3. A process as set forth in claim 1 in which the low pressure air after being returned in heat exchange relationship to the air flowing to the liquefying chamber is directed into apparatus for separating the air into its constituents oxygen and nitrogen.
In testimony whereof I hereunto aflix my signature.
MAURICE HAZARD-FLAMAND.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR336798X | 1928-10-18 |
Publications (1)
Publication Number | Publication Date |
---|---|
US1901389A true US1901389A (en) | 1933-03-14 |
Family
ID=8891399
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US398459A Expired - Lifetime US1901389A (en) | 1928-10-18 | 1929-10-09 | Process for liquefying and rectifying air |
Country Status (2)
Country | Link |
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US (1) | US1901389A (en) |
GB (1) | GB336798A (en) |
Cited By (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2509034A (en) * | 1948-10-04 | 1950-05-23 | Elliott Co | Method and apparatus for liquefying gaseous fluids |
US2522787A (en) * | 1948-06-11 | 1950-09-19 | Phillips Petroleum Co | Method of and apparatus for liquefying gases |
US2626510A (en) * | 1947-06-18 | 1953-01-27 | Air Prod Inc | Air fractionating cycle and apparatus |
US2695219A (en) * | 1949-01-04 | 1954-11-23 | Phillips Petroleum Co | Detection of corrosion and damage to apparatus |
US2760356A (en) * | 1952-04-22 | 1956-08-28 | Nat Res Dev | Method of liquefying gases |
US2764877A (en) * | 1950-04-26 | 1956-10-02 | Hartford Nat Bank & Trust Co | Apparatus for liquefying air |
US3094402A (en) * | 1960-10-17 | 1963-06-18 | British Oxygen Co Ltd | Process for the separation of air |
US3100696A (en) * | 1957-07-04 | 1963-08-13 | Linde Eismasch Ag | Method and apparatus for separating gases |
US3152457A (en) * | 1961-10-26 | 1964-10-13 | Martin Marietta Corp | Refrigerating apparatus for continuously producing very low temperatures |
US3180709A (en) * | 1961-06-29 | 1965-04-27 | Union Carbide Corp | Process for liquefaction of lowboiling gases |
US3182461A (en) * | 1961-09-19 | 1965-05-11 | Hydrocarbon Research Inc | Natural gas liquefaction and separation |
US3233418A (en) * | 1962-07-23 | 1966-02-08 | Philips Corp | Apparatus for liquefying helium |
US5168728A (en) * | 1988-12-22 | 1992-12-08 | Sorelec | Process of cooling and dehumidifying hot, damp air and the installation enabling this process to be performed |
US11536511B2 (en) | 2019-08-08 | 2022-12-27 | Herbert L. Williams | Method and system for liquifying a gas |
-
1929
- 1929-10-09 US US398459A patent/US1901389A/en not_active Expired - Lifetime
- 1929-10-17 GB GB31594/29A patent/GB336798A/en not_active Expired
Cited By (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2626510A (en) * | 1947-06-18 | 1953-01-27 | Air Prod Inc | Air fractionating cycle and apparatus |
US2522787A (en) * | 1948-06-11 | 1950-09-19 | Phillips Petroleum Co | Method of and apparatus for liquefying gases |
US2509034A (en) * | 1948-10-04 | 1950-05-23 | Elliott Co | Method and apparatus for liquefying gaseous fluids |
US2695219A (en) * | 1949-01-04 | 1954-11-23 | Phillips Petroleum Co | Detection of corrosion and damage to apparatus |
US2764877A (en) * | 1950-04-26 | 1956-10-02 | Hartford Nat Bank & Trust Co | Apparatus for liquefying air |
US2760356A (en) * | 1952-04-22 | 1956-08-28 | Nat Res Dev | Method of liquefying gases |
US3100696A (en) * | 1957-07-04 | 1963-08-13 | Linde Eismasch Ag | Method and apparatus for separating gases |
US3094402A (en) * | 1960-10-17 | 1963-06-18 | British Oxygen Co Ltd | Process for the separation of air |
US3180709A (en) * | 1961-06-29 | 1965-04-27 | Union Carbide Corp | Process for liquefaction of lowboiling gases |
US3182461A (en) * | 1961-09-19 | 1965-05-11 | Hydrocarbon Research Inc | Natural gas liquefaction and separation |
US3152457A (en) * | 1961-10-26 | 1964-10-13 | Martin Marietta Corp | Refrigerating apparatus for continuously producing very low temperatures |
US3233418A (en) * | 1962-07-23 | 1966-02-08 | Philips Corp | Apparatus for liquefying helium |
US5168728A (en) * | 1988-12-22 | 1992-12-08 | Sorelec | Process of cooling and dehumidifying hot, damp air and the installation enabling this process to be performed |
US11536511B2 (en) | 2019-08-08 | 2022-12-27 | Herbert L. Williams | Method and system for liquifying a gas |
Also Published As
Publication number | Publication date |
---|---|
GB336798A (en) | 1930-10-23 |
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