US1871329A - A cobpobation of - Google Patents
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- US1871329A US1871329A US1871329DA US1871329A US 1871329 A US1871329 A US 1871329A US 1871329D A US1871329D A US 1871329DA US 1871329 A US1871329 A US 1871329A
- Authority
- US
- United States
- Prior art keywords
- parts
- water
- glue
- soya bean
- caustic soda
- Prior art date
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- Expired - Lifetime
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- HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 84
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 58
- 239000003292 glue Substances 0.000 description 54
- 235000013312 flour Nutrition 0.000 description 38
- 235000010469 Glycine max Nutrition 0.000 description 36
- 240000007842 Glycine max Species 0.000 description 36
- 235000011121 sodium hydroxide Nutrition 0.000 description 28
- 239000000203 mixture Substances 0.000 description 26
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 20
- 235000013311 vegetables Nutrition 0.000 description 16
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 14
- NTHWMYGWWRZVTN-UHFFFAOYSA-N Sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 14
- 235000015450 Tilia cordata Nutrition 0.000 description 14
- 235000011941 Tilia x europaea Nutrition 0.000 description 14
- 239000004615 ingredient Substances 0.000 description 14
- 239000004571 lime Substances 0.000 description 14
- 239000000463 material Substances 0.000 description 14
- 238000000034 method Methods 0.000 description 12
- 235000018102 proteins Nutrition 0.000 description 12
- 108090000623 proteins and genes Proteins 0.000 description 12
- 102000004169 proteins and genes Human genes 0.000 description 12
- 239000000126 substance Substances 0.000 description 12
- 150000001875 compounds Chemical class 0.000 description 10
- 235000019353 potassium silicate Nutrition 0.000 description 10
- AXCZMVOFGPJBDE-UHFFFAOYSA-L Calcium hydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 8
- 239000002253 acid Substances 0.000 description 8
- 239000000853 adhesive Substances 0.000 description 8
- 230000001070 adhesive Effects 0.000 description 8
- 239000000920 calcium hydroxide Substances 0.000 description 8
- 235000011116 calcium hydroxide Nutrition 0.000 description 8
- QGJOPFRUJISHPQ-UHFFFAOYSA-N carbon bisulphide Chemical compound S=C=S QGJOPFRUJISHPQ-UHFFFAOYSA-N 0.000 description 8
- KWYUFKZDYYNOTN-UHFFFAOYSA-M potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 8
- 150000003839 salts Chemical class 0.000 description 8
- 239000011780 sodium chloride Substances 0.000 description 8
- BVKZGUZCCUSVTD-UHFFFAOYSA-N Carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 6
- ARUVKPQLZAKDPS-UHFFFAOYSA-L Copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 description 6
- 235000010627 Phaseolus vulgaris Nutrition 0.000 description 6
- 240000005158 Phaseolus vulgaris Species 0.000 description 6
- KIEOKOFEPABQKJ-UHFFFAOYSA-N Sodium dichromate Chemical compound [Na+].[Na+].[O-][Cr](=O)(=O)O[Cr]([O-])(=O)=O KIEOKOFEPABQKJ-UHFFFAOYSA-N 0.000 description 6
- NWONKYPBYAMBJT-UHFFFAOYSA-L Zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 description 6
- 239000005018 casein Substances 0.000 description 6
- 239000004832 casein glue Substances 0.000 description 6
- 235000021240 caseins Nutrition 0.000 description 6
- 239000003795 chemical substances by application Substances 0.000 description 6
- 229910000365 copper sulfate Inorganic materials 0.000 description 6
- 238000007580 dry-mixing Methods 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 6
- KEAYESYHFKHZAL-UHFFFAOYSA-N sodium Chemical compound [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 description 6
- 239000011734 sodium Substances 0.000 description 6
- 229910052708 sodium Inorganic materials 0.000 description 6
- 238000003756 stirring Methods 0.000 description 6
- 102100001249 ALB Human genes 0.000 description 4
- 101710027066 ALB Proteins 0.000 description 4
- 210000004369 Blood Anatomy 0.000 description 4
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L Calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 4
- TUSDEZXZIZRFGC-XIGLUPEJSA-N Corilagin Chemical compound O([C@H]1[C@H](O)[C@H]2OC(=O)C3=CC(O)=C(O)C(O)=C3C3=C(O)C(O)=C(O)C=C3C(=O)OC[C@@H](O1)[C@H]2O)C(=O)C1=CC(O)=C(O)C(O)=C1 TUSDEZXZIZRFGC-XIGLUPEJSA-N 0.000 description 4
- KMUONIBRACKNSN-UHFFFAOYSA-N Potassium dichromate Chemical compound [K+].[K+].[O-][Cr](=O)(=O)O[Cr]([O-])(=O)=O KMUONIBRACKNSN-UHFFFAOYSA-N 0.000 description 4
- 235000017343 Quebracho blanco Nutrition 0.000 description 4
- 241000065615 Schinopsis balansae Species 0.000 description 4
- 239000004115 Sodium Silicate Substances 0.000 description 4
- 229940050528 albumin Drugs 0.000 description 4
- LSNNMFCWUKXFEE-UHFFFAOYSA-M bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 4
- 239000008280 blood Substances 0.000 description 4
- 235000012970 cakes Nutrition 0.000 description 4
- OYPRJOBELJOOCE-UHFFFAOYSA-N calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 4
- 239000011575 calcium Substances 0.000 description 4
- 229910052791 calcium Inorganic materials 0.000 description 4
- SOCTUWSJJQCPFX-UHFFFAOYSA-N dichromate(2-) Chemical compound [O-][Cr](=O)(=O)O[Cr]([O-])(=O)=O SOCTUWSJJQCPFX-UHFFFAOYSA-N 0.000 description 4
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 239000002994 raw material Substances 0.000 description 4
- 239000011347 resin Substances 0.000 description 4
- 229920005989 resin Polymers 0.000 description 4
- 239000001488 sodium phosphate Substances 0.000 description 4
- 229960003339 sodium phosphate Drugs 0.000 description 4
- 229910000162 sodium phosphate Inorganic materials 0.000 description 4
- 235000011008 sodium phosphates Nutrition 0.000 description 4
- 229910052911 sodium silicate Inorganic materials 0.000 description 4
- 238000003892 spreading Methods 0.000 description 4
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 4
- -1 viz. Substances 0.000 description 4
- 229960001763 zinc sulfate Drugs 0.000 description 4
- 229910000368 zinc sulfate Inorganic materials 0.000 description 4
- DIZPMCHEQGEION-UHFFFAOYSA-H Aluminium sulfate Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 description 2
- LCQXXBOSCBRNNT-UHFFFAOYSA-K Ammonium aluminium sulfate Chemical compound [NH4+].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O LCQXXBOSCBRNNT-UHFFFAOYSA-K 0.000 description 2
- QVQLCTNNEUAWMS-UHFFFAOYSA-N Barium oxide Chemical compound [Ba]=O QVQLCTNNEUAWMS-UHFFFAOYSA-N 0.000 description 2
- ZKQDCIXGCQPQNV-UHFFFAOYSA-N Calcium hypochlorite Chemical compound [Ca+2].Cl[O-].Cl[O-] ZKQDCIXGCQPQNV-UHFFFAOYSA-N 0.000 description 2
- OIDPCXKPHYRNKH-UHFFFAOYSA-J Chrome alum Chemical compound [K]OS(=O)(=O)O[Cr]1OS(=O)(=O)O1 OIDPCXKPHYRNKH-UHFFFAOYSA-J 0.000 description 2
- 241000196324 Embryophyta Species 0.000 description 2
- QWVGKYWNOKOFNN-UHFFFAOYSA-N O-Cresol Chemical compound CC1=CC=CC=C1O QWVGKYWNOKOFNN-UHFFFAOYSA-N 0.000 description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Natural products OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- 241000218657 Picea Species 0.000 description 2
- 239000011398 Portland cement Substances 0.000 description 2
- 229940069002 Potassium Dichromate Drugs 0.000 description 2
- 240000004029 Rhus coriaria Species 0.000 description 2
- 101700058464 SILIC Proteins 0.000 description 2
- 241000687904 Soa Species 0.000 description 2
- JBUKJLNBQDQXLI-UHFFFAOYSA-N Sodium perborate Chemical compound [Na+].[Na+].O[B-]1(O)OO[B-](O)(O)OO1 JBUKJLNBQDQXLI-UHFFFAOYSA-N 0.000 description 2
- 229920002472 Starch Polymers 0.000 description 2
- 229940091251 Zinc Supplements Drugs 0.000 description 2
- JIAARYAFYJHUJI-UHFFFAOYSA-L Zinc chloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 229910052783 alkali metal Inorganic materials 0.000 description 2
- 150000001340 alkali metals Chemical class 0.000 description 2
- 229940037003 alum Drugs 0.000 description 2
- 150000004645 aluminates Chemical class 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminum Chemical class [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- 229940077747 antacids containing calcium compounds Drugs 0.000 description 2
- 229910001864 baryta Inorganic materials 0.000 description 2
- 239000002585 base Substances 0.000 description 2
- 239000007844 bleaching agent Substances 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 150000001674 calcium compounds Chemical class 0.000 description 2
- 229940043430 calcium compounds Drugs 0.000 description 2
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 2
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium monoxide Chemical compound [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 2
- 159000000007 calcium salts Chemical class 0.000 description 2
- QSLZFPQJJGGNFN-UHFFFAOYSA-N calcium;sulfane Chemical compound S.[Ca+2] QSLZFPQJJGGNFN-UHFFFAOYSA-N 0.000 description 2
- 235000014633 carbohydrates Nutrition 0.000 description 2
- 150000001720 carbohydrates Chemical class 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 239000003518 caustics Substances 0.000 description 2
- 239000001913 cellulose Substances 0.000 description 2
- 229920002678 cellulose Polymers 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 238000000227 grinding Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxyl anion Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 2
- 239000000395 magnesium oxide Substances 0.000 description 2
- 235000012054 meals Nutrition 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 150000002989 phenols Chemical class 0.000 description 2
- 229940072033 potash Drugs 0.000 description 2
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Substances [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 2
- 235000015320 potassium carbonate Nutrition 0.000 description 2
- 235000011118 potassium hydroxide Nutrition 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 238000003825 pressing Methods 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 150000004760 silicates Chemical class 0.000 description 2
- 229960001922 sodium perborate Drugs 0.000 description 2
- 235000010339 sodium tetraborate Nutrition 0.000 description 2
- 235000019698 starch Nutrition 0.000 description 2
- 239000008107 starch Substances 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
- BSVBQGMMJUBVOD-UHFFFAOYSA-N trisodium borate Chemical compound [Na+].[Na+].[Na+].[O-]B([O-])[O-] BSVBQGMMJUBVOD-UHFFFAOYSA-N 0.000 description 2
- 230000003245 working Effects 0.000 description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
- 239000011701 zinc Substances 0.000 description 2
- 229910052725 zinc Inorganic materials 0.000 description 2
- 239000011592 zinc chloride Substances 0.000 description 2
- 235000005074 zinc chloride Nutrition 0.000 description 2
- 150000003752 zinc compounds Chemical class 0.000 description 2
- 229940100888 zinc compounds Drugs 0.000 description 2
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J189/00—Adhesives based on proteins; Adhesives based on derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L89/00—Compositions of proteins; Compositions of derivatives thereof
Definitions
- water-proof in this connection, it is not meant that resist the action of water indefinitely, but it is meant that they are water-pro'of in the 2o sense in which the term is usedin the veneer industry, viz., that a panel can be soakedin cold water for from seventy-two to one hun-' dred hours, or in boiling water for eight hours, without separation.
- Vegetable compounds have not, so far as we are' aware, been heretofore satisfactorily employed as a basis for water-proof glues of the type in question. It is true that some on account of the high price.
- the invention consists of the combination of ingredients or composition of matter and the steps involved in the not available except in certain situations.
- soya bean flour constitutes an admirable raw material for our purpose.
- Such flour is preferably made by grinding soya bean-cake so that per cent. will passa mesh screen and when treated with certain chemicals, or other substances, we make therefrom a very satisfactory glue that meets the requirements of the veneer trade fully and is in many respects better than the usual glues now on the market.
- Such bean cake as analyzed by us, is found to contain on the average 45 per cent. protein, 12'per cent.'water, 5 per cent. cellulose or crude fibre, 7 per cent. oil, 6 per cent. ash, and 25. per cent. carbohydrates.
- soya bean flour or to vegetable protein derived from this source.
- Soya bean flour made from soya bean cake 75 from which the oil has been expressed is preferably used in practice because it is cheaper and makes a better glue, but flour made from whole soya beans, without ex pressing the contained oil, may also be used, although obviously this would not be2'economical in view of the value which attaches to such oil.
- the fineness of theflour it is not necessary that the meal be ground as fine as indicated above, but fineness is desirable from a practical standpoint.
- casein glue When the usual chemicals employed in making casein glue, viz., lime and sodium silicate, are added to a vegetable protein containing material, for example, soya bean flour, a glue results, but itisnot asgood as casein glue. It is not as highly water resistant nor as workable. We find, however by the use of caustic soda "with such vegetable 05 protein-containing matter,a muchbetter glue is obtained, such causticsoda apparently playing the part of dispersing the colloidal material. The resultant glue is then some what similar in its working properties. to'
- caustic soda caustic potash and ammonia may be used, although more exnsive Other'equivalents of caustic soda re salts of soda (or potash) with weak acids, e. g. sodium phosphate,sodium borate and the like, whenjlime is present.
- weak acids e. g. sodium phosphate,sodium borate and the like, whenjlime is present.
- magnesia, baryta and stront1a may be used as equivalents.
- Carbon bisulfi e calcium polysulfide.
- Cogper sulfate, cuprammonium coms copper-caustic soda compounds Cogper sulfate, cuprammonium coms copper-caustic soda compounds.
- Zinc sulfate, ,zinc chloride, ammonium zincate is other zinc compounds.
- Rosin, sodium or calcium soa 'ofrosin Equivalents would be other" resins or resin combinations with metals.
- Carbon bisulfide impartsvery great water resistingdproperties, as does also calcium copper salts and t polysul e, although to a. lesser degree;
- the alums, the tanning agents, zinc comtmds, calcium compounds and cresylic acid increase the water resistance of the glue;
- silicates and related compounds act as thinners while at the same. time. increasing the water resistance and the strength of the glue; and the rosin and derivatives thereof act as thinners and make the workable. Substances su which act as a thinner, or render the glue more readily workable, may be appropriately to. add to glue more readily c referred to as Spreaders.
- caustic soda-solution stlr well; then add 2 parts calcium hywhereupon the dratein 30 parts of water, giging finishedfl (3) Mix 30 parts soya bearr flour, 5 parts rosin, 1 parts copper sulfate, 1 part quebracho together dry; add 90 parts water and 26 parts 18 per cent. caustic soda solution;
- the. glue that we are at present making commercially. is made as follows, viz :-soya bean flour, lime, rosin and potassium dichromate are mixed dry, and in this form is shipped to the veneer plants. Inthe latter such dry product is then mixed with water, caustic soda solution and sodium silicatein the form of water glass, thereby making the finished glue.
- the proportions in which the foregoing ingredients are employed in the case of the particular method of manufacture just described will be substantially as given in the preceding formulae numbered (1) to (7) inclusive.
- a process of making an adhesive which comprises dry-mixing soya bean flour with a compound of an alkali-forming metal, and
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Adhesives Or Adhesive Processes (AREA)
Description
Patented Aug. 9, 1932 UNITED STATES PATENT OFFICE.
IRVING F. LAUCKS AND GLENN DAVIDSON, OF. SEATTLE, WASHINGTON, ASSIGNORS TO I. F. LAUCKS, INCORPORATED, OI SEATTLE, WASHINGTON, A CORPORATION or WASHINGTON GLUE AND METHOD OF MAKING No Drawing. Original application filed October 29, i923 Serial No. 671,881. I Divided and this application filed October 4, 1928. Serial No. 310,431
preparation of such composition hereinafter. fully described and particularly pointed out in the claims, it being understood that such disclosed ingredients and steps constitute but. several of the various ways in which the principle of-the invention may be used.
The art of making a water-proof glue from certain protein materials has been knownfor some time;thus casein and blood albumin are in common use. These last mentioned compounds, however, have a number of disadvantages from a practical standpoint.
Casein is costly and .lack of uniformity-in the material as derived from various sources is a seriousdetriment; while blood albumin There is accordingly a great demand, particu-, larly in the veneer industry where large quantities of glue are consumed, for a new glue that will be cheap and at'the sufliciently water-proof.
By water-proof, in this connection, it is not meant that resist the action of water indefinitely, but it is meant that they are water-pro'of in the 2o sense in which the term is usedin the veneer industry, viz., that a panel can be soakedin cold water for from seventy-two to one hun-' dred hours, or in boiling water for eight hours, without separation.
Vegetable compounds have not, so far as we are' aware, been heretofore satisfactorily employed as a basis for water-proof glues of the type in question. It is true that some on account of the high price.
veneer makers, of casein, have come to use starch glues but these, at least as heretofore made, are not at all water-proof, and vegetable proteins-have not heretofore been used at all, so far as we are aware. g
We have now discovered, however, that by subjecting; the same to proper treatment, vegetable matter containing proteins in proper amount, can be converted into a water. proof glue'that will satisfy the rigid require- -ments of veneer making. The requisite raw material may be derived from a number of sources and thetreatment of such material is relatively simple and inexpensive so that as a result we, are able to produce a satisfactory glue at a much lowercost than has heretofore been possible.
To the accomplishment of the foregoing and related ends, the invention, then, consists of the combination of ingredients or composition of matter and the steps involved in the not available except in certain situations.
same time glues thus characterized will \Ve have found that soya bean flour constitutes an admirable raw material for our purpose. Such flour is preferably made by grinding soya bean-cake so that per cent. will passa mesh screen and when treated with certain chemicals, or other substances, we make therefrom a very satisfactory glue that meets the requirements of the veneer trade fully and is in many respects better than the usual glues now on the market. Such bean cake, as analyzed by us, is found to contain on the average 45 per cent. protein, 12'per cent.'water, 5 per cent. cellulose or crude fibre, 7 per cent. oil, 6 per cent. ash, and 25. per cent. carbohydrates.
We do not, however, wish to limit ourselves to soya bean flour or to vegetable protein derived from this source.
Soya bean flour made from soya bean cake 75 from which the oil has been expressed, is preferably used in practice because it is cheaper and makes a better glue, but flour made from whole soya beans, without ex pressing the contained oil, may also be used, although obviously this would not be2'economical in view of the value which attaches to such oil. As to the fineness of theflour, it is not necessary that the meal be ground as fine as indicated above, but fineness is desirable from a practical standpoint.
When the usual chemicals employed in making casein glue, viz., lime and sodium silicate, are added to a vegetable protein containing material, for example, soya bean flour, a glue results, but itisnot asgood as casein glue. It is not as highly water resistant nor as workable. We find, however by the use of caustic soda "with such vegetable 05 protein-containing matter,a muchbetter glue is obtained, such causticsoda apparently playing the part of dispersing the colloidal material. The resultant glue is then some what similar in its working properties. to'
uivalents would be other-alkaline com "pounds of copper. I
Sodium dichromate. .Equivalents would be other metallic dichromates or chromates.
casein glue, althougli its water resistance is still slightly less.
Preferab y we react on our vegetable protein-contaimng material with both caustic soda and lime. As equivalents of such caustic soda, caustic potash and ammonia may be used, although more exnsive Other'equivalents of caustic soda re salts of soda (or potash) with weak acids, e. g. sodium phosphate,sodium borate and the like, whenjlime is present. Similarly in place of lime, magnesia, baryta and stront1a may be used as equivalents.
In order to improve the workin properties, e. g. the spreadin and flow, o the'glue produced as aforesai as well as the water resisting properties,
ble to add other substances of which the gollowing are exam lesz.
Carbon bisulfi e, calcium polysulfide.
Equivalents would be othersulfur compounds of like properties or constitution.-
Cogper sulfate, cuprammonium coms copper-caustic soda compounds.
' Chrome alum, ammonia alum, aluminum sulfate. Equivalents would be other alums and aluminum salts, including aluminates.
Quebracho, sumach, spruce extract (cons centrated sulfite liquor) These are all commonly used tanning agents. Equivalents would be other vegetable tanning agents.
Zinc sulfate, ,zinc chloride, ammonium zincate. Equivalents would be other zinc compounds.
Calcium sulfate, calcium oxychloride (bleaching powder). Equivalents would be other calcium salts, or alkaline earth salts.
Gresylic acid.. Equivalents would be other phenols.
Rosin, sodium or calcium soa 'ofrosin. Equivalents would be other" resins or resin combinations with metals.
Carbon bisulfide impartsvery great water resistingdproperties, as does also calcium copper salts and t polysul e, although to a. lesser degree; the
glue more readily workable while at the same time imparting increased water resistance; the alums, the tanning agents, zinc comtmds, calcium compounds and cresylic acid increase the water resistance of the glue;'the
silicates and related compounds act as thinners while at the same. time. increasing the water resistance and the strength of the glue; and the rosin and derivatives thereof act as thinners and make the workable. Substances su which act as a thinner, or render the glue more readily workable, may be appropriately to. add to glue more readily c referred to as Spreaders.
It has 8186 been found desirable we have found it desir e dichroma'tesmake the as the foregoing,
I We have also found that certain substances,
inconjunction with lime, will act in the same way as the caustic soda and also as thinners, e. sodiumphosphate, sodium perborate and so sulfite.
lue after mixing 'These salts are all related in formulae that we have used and that they are combinations of the strong base sodium with a weak acid 'and there are a number of other salts that fall in the same cate ory and which have a similar efiect, 'so,
-nee notbelistedindetaih a I I As examples we may cite the following typical formulaez- (1) Mix parts soya bean flour with 120 parts water; add .13 parts of 18 per'cent.
caustic soda solution and mix; 5 parts carbon bisulfide are then added and stirred well; to
this?) partscalcium hydrate are added and. stirred in; then 15 parts water glass (sodium silicate) are stirred in; finally, add 1 part copper sulfate to 5 arts of water and stir in. This makes the fimshed glue, which is then spread on panels, for example, put under pressure for several hours, pressure may be released. (2) Mix 15 parts soya bean flour with 1 part sodium dichromate; add parts water and 13 parts 18 per cent. caustic soda-solution; stlr well; then add 2 parts calcium hywhereupon the dratein 30 parts of water, giging finishedfl (3) Mix 30 parts soya bearr flour, 5 parts rosin, 1 parts copper sulfate, 1 part quebracho together dry; add 90 parts water and 26 parts 18 per cent. caustic soda solution;
stir well; add 6 parts calcium hydrate in 15 parts water; then add 15 parts water glass, givingfinished glue.
(4) Mix dry, 40 parts soya-bean flour, 6 parts rosin, 8 parts Portland cement, 3' parts dichromate of soda arid 5 parts caustic soda;
add 140 parts water and 14 parts water glass; stir well; add 50 parts water.
(5) Mix 30 parts'soya bean flour, 1 part alum, 7.0 parts water; add 13 parts 18. per cent. caust ie soda. solution and 4 parts calcium hydrate in 20 parts water.
(6) -Mix 30 parts soya bean flour, 1 part sodium dichromate, 0.1 part zinc sulfate, 80 parts water; add 13 parts 18 per cent. caustic soda solution and 4 parts calcium hydrate in 20 parts water.
(7) Mix 30 parts soya bean flour, 5 parts 20 parts of lime, and subsequently incorporosin, 1 parts copper sulfate, part sorating a caustic soda solution to spreading dium dichromate, 90 parts water, 1 part creconsistency.
sylic acid, 26 parts 18 per cent. caustic soda solution, 6 parts calcium hydrate in 15 parts water, 15 parts water glass. i
The particular order in which the several ingredients are admixed togetherin the formulae just given may be varied, and it is not necessary that the manufacture of the product be completed in a single continuous operation, but as a matter of practice we have found it desirable in.certain cases to mix only certain of the ingredients initially and then add the others just before the glue is required for use. Thus, the. glue that we are at present making commercially. is made as follows, viz :-soya bean flour, lime, rosin and potassium dichromate are mixed dry, and in this form is shipped to the veneer plants. Inthe latter such dry product is then mixed with water, caustic soda solution and sodium silicatein the form of water glass, thereby making the finished glue. The proportions in which the foregoing ingredients are employed in the case of the particular method of manufacture just described will be substantially as given in the preceding formulae numbered (1) to (7) inclusive.
, It will also be understood, of course, that the foregoing formulae are typical and tha many variations are actually made therein 1n the compounding of our improved glue.
This application is a division of our application Serial No. 671,381, filed October 29, 1923 (now Patent No. 1,689,? 32).
Other modes of applying the principle of our invention may be employed instead-of the one explained, change being made as regards the process herein disclosed or the materials employed in carrying out such process provided the stated ingredients and steps or the e uivalent of such stated ingredients or steps e employed.
We therefore particularly point out and distinctly claim as our invention 1. The process of making an adhesive, which comprises dry mixing soya bean flour with an alkaline-earth hydroxide, and subsequently incorporating an alkali metal hydrox'ide and water.
2. A process of making an adhesive, which comprises dry-mixing soya bean flour with a compound of an alkali-forming metal, and
subsequently incorporating an alkaline medium and water to spreading consistency.
3. The process of making an adhesive, which comprises dry mixing soya bean flour with lime, and subsequently incorporating a caustic soda solution.
4:. The process of making an adhesive, which comprises dry mixingsoya bean flour with lime, in the proportion of about 100 parts of the soya bean flour and about 10 to GLENN DAVIDSON.
Publications (1)
Publication Number | Publication Date |
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US1871329A true US1871329A (en) | 1932-08-09 |
Family
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US1871329D Expired - Lifetime US1871329A (en) | A cobpobation of |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2595257A (en) * | 1948-07-13 | 1952-05-06 | Weyerhaeuser Timber Co | Protein adhesive composition |
WO2012040037A1 (en) * | 2010-09-20 | 2012-03-29 | State Of Oregon Acting By & Through The State Board Of Higher Edu. On Behalf Of Oregon State Univ. | Soy adhesives and composites made from the adhesives |
-
0
- US US1871329D patent/US1871329A/en not_active Expired - Lifetime
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2595257A (en) * | 1948-07-13 | 1952-05-06 | Weyerhaeuser Timber Co | Protein adhesive composition |
WO2012040037A1 (en) * | 2010-09-20 | 2012-03-29 | State Of Oregon Acting By & Through The State Board Of Higher Edu. On Behalf Of Oregon State Univ. | Soy adhesives and composites made from the adhesives |
CN103108933A (en) * | 2010-09-20 | 2013-05-15 | 由俄勒冈州高等教育管理委员会代表的俄勒冈州立大学 | Soy adhesives and composites made from the adhesives |
AU2011305750B2 (en) * | 2010-09-20 | 2015-05-21 | State Of Oregon Acting By And Through The State Board Of Higher Education On Behalf Of Oregon State University | Soy adhesives and composites made from the adhesives |
US9493693B2 (en) | 2010-09-20 | 2016-11-15 | Oregon State University | Soy adhesives and composites made from the adhesives |
JP2017020024A (en) * | 2010-09-20 | 2017-01-26 | オレゴン ステイト ユニバーシティー | Soy adhesives, and composites made from the adhesives |
EA025892B1 (en) * | 2010-09-20 | 2017-02-28 | Орегон Стейт Юниверсити | Soy adhesives and composites made from the adhesives |
CN103108933B (en) * | 2010-09-20 | 2017-04-19 | 由俄勒冈州高等教育管理委员会代表的俄勒冈州立大学 | Soy adhesives and composites made from the adhesives |
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