US1867301A

US1867301A - Three-color photography

Info

Publication number: US1867301A
Application number: US384794A
Authority: US
Inventors: Baker Thomas Thorne
Original assignee: Agfa Ansco Corp
Current assignee: GAF Chemicals Corp
Priority date: 1928-08-28
Filing date: 1929-08-09
Publication date: 1932-07-12
Anticipated expiration: 1949-07-12
Also published as: FR666685A; BE355365A; GB321998A

Description

T. T. BAKER 1,867,301

. THREE-P011011 PHOTOGRAPHY I Filed Aug. 9. 1929 ifi l IIHIIH I A A E. C 6

July 12, 1932.

Patented -.luly 12, 1932 THOMAS THOBNE BAKER, 0F HATCH END, ENGLAND, ASSIGNOR,'BY MESNE ASSIGIT- MENTS, TO AGFA ANSCO ('1OIRIPOBA'IPION', OF BINGHAMTON, NEW YORK, A CORPORA 'I'ION OF NEW YORK cums-coma riroroemnr Application filed August 9, 1929, Serial No. 384,794, and in Great Britain August 28, 192a.

This invention relates to three-color photography of the kindin which three primary color-sensation records are made simultaneously on three sensitive layers one behind another, such compound layers being known as tri-packs.

Hitherto the three sensitive layers have usuallybeen arranged with the blue-violetrecording layer in front and the orange-redrecording layer at-the back. Owing to the turbidity of the front and intermediate layers, the image on the back layer is the least well-defined. When prints or transparencies are made from the three color-records by the I subtractive method, the positive image fromthe orange-red record is a blue-green image, which is combined with magenta'and yellow images from the other two records to form the complete picture in natural colors. Of these three ,subtractive colors, the bluegreen or minus red image is the darkest visually, and therefore it plays the mostrimpor tant part in determining the degreeof definition in the final picture. 7

With the usual arrangement, this darkest image is obtained from the least well-defined color-record, namely, the orange-red record, and therefore it has been impossible with this arrangement to obtain sharply defined pictures. The same consideration applies if the color synthesis is effected by an additive method, for example, in a three-color lantern; the definition of the orange-red record determines the quality of definition of the composite picture. v

It has long been recognized that a well defined picture can be obtained, so long as the orange-red record is well-defined, even if the green record and the blue-violet record and particularly the latter) are not well defined,

and tri-packs have been proposed in which. the orange-redsensitive layer was to be in front and the blue-violet-sensitive layer at' the back. So far as I am aware, however, such proposals have never led to successful results in practice.

It is the object of the present invention'to provide a tri-pack in which the orange-redsensitive layer is in front (thus enabling sharply-defined composite subtractive pictures to be secured) while nevertheless the color-separation and balance of the three records are sufliciently good to enable a very close approximation to naturalcolors to be I i obtained.-

According to the principal feature of the present invention, a tri-pack comprises a front layer of silver halide emulsion rendered highly sensitive to the red region of According to a further feature of the invention, the front layer (and preferably also the intermediatelayer) has a quantity of silver halide perunit of area which is only a small fraction (for example one-fifth or onequarter) ofthat of a normal emulsion-coats ing, while its characteristics are so chosen that a normal degree of contrast in the developed image can be readily obtained, for example, a de ee of contrast the same or approximately t e same as that given by the back emulslon layer with the same developer and time of development.

- According to another feature of the invention, the back emulsion layer is treated with a substance which depresses its inherent green-sensitivity, for example, a dye having that property.

' According to yet another feature of-the invention, the intermediate emulsion layer is treated with a dye which depresses its blueviolet sensitivity but nevertheless transmits sulficient violet li ht to enable a satisfactory image to be obtalned on the back layer.

A tri-pack according to this invention which has given satisfactory results will now be described with reference to the accompanying drawing. In Figure 1 the light filgreen light.

ter is located in front of the camera lens, in re' 2 it is located behind the lens and in igure 3 it is incorporated in the tripack itself. 1 The front emulsion layer A is a highlycontrasty silver-bromide emulsion (preferably containinglitt-le or no silver iodide) rendered extremely red-sensitive (but not green-sensitive) by means of a suitable sensitizer of the iso-cyanine or similar class. Its

sensitivity to daylight is about 500 H. and D. and it iscoated in such a way that the quantity of silver bromide per unit area is only about one-fifth of the normal.

If desired, substances, well known'to those skilled in the art, may be added to reduce or destroy the sensitivity of the emulsion to emulsion B is sensitized togreen, for example, by means of erythrosine, and its-sensitivit is about 300 H. and D. to daylight. A yel ow dye may be added to this emulsion to reduce its blue-sensitivity, but the amount should be such as to permit suflicient violet light to pass to enable a The intermediate record to be obtained on the third emulsion one-quarter of layer behind it. The intermediate emulsion treated in such a way as to reduce its sensitivity to green light as much as ossible, as for example, it may be made wit out silver iodide or with only a very small proportion thereof, or substances (known to those skilled inthe art) may be added which destroy or reduce its green sensitivity.

As previously stated, a filtering layer 1) is employed in front of the tri-pack' which absorbs ultra-violet radiation wholly, transmits the whole or a considerable proportion of the violet light and absorbs the whole or a considerable proportion of the blue light. This filtering layer D may be placed infront of or behind the lens E, as illustrated in Figures 1 and 2, or may be incorporated in the Y tri-pack itself (see Figure 3). Preferablyf it comprises aesculine, a small proportion o filter yellow, and mandarin orange, these dyes being incorporated in a transparent medium in the well-understoodmannerL If dyes having similar absorption characteristics are chosen whichhave no deleterious effect on the emulsion, they may be incorporated in the front emulsion layer itself, but it is preferred to provide a separate filter ing layer.

Pleasing results have been obtained by the use of a tri-pack constituted as described, in spite of the fact that some violet light is recorded on the front and intermediate layers and that the back layer records mainly the violet and very little blue.

I claim 1 1. A tri-pack comprisin a front layer of silver halide emulsion ren red highly sensitive to the red-region of the spectrum but substantiall insensitive to the green region, an interme iate layer of silver halide emulsion rendered sensitive to the reen region of the spectrum but not to the red region, and a back layer of non-color-sensitized silver halide emulsion having a substantially higher sensitivity than either of the other two emulsions, in combination with light-filtering means for the front layer adapted to absorb ultra-violet radiation, to transmit violet light and to absorb at least zrproportion of blue light.

2. A tri-pack according to claim 1 wherein the back emulsion layer is treated with a substance which depresses its inherent greensensitivity.

3. A tri-pack according to claim 1 wherein the intermediate emulsion layer is treated with a dye which depresses its blue-violet sensitivity but nevertheless transmits sulficient violet light to enable a satisfactory image to be obtained on the back layer. I

4;. A tri-pack according to claim 1 wherein the intermediate emulsion layer is treated with a dye which depresses its blue-violet sensitivity but nevertheless transmits sufficient violet light to enable a satisfactory image to be obtained on theback layer, and the back emulsion layer is treated with a sub stance which depresses its inherent greensensitivity.

5. Atri- 'ack according to claim 1 wherein the light-filtering means com rises aesculine,

a small proportion of filter ye low, and mandarin orange.

6. A tri-pack according to claim 1 wherein the sensitivities to daylight of the front, intermediate and back layers are substantially in the ratio 10:6: 17

7. A tripack according to claim 1 wherein the front layer has a quantity of silver halide per unit area which is only a small fraction of that in a normal emulsion coating, so that it gives rise to.a normal degree of contrast in the developed image which approximates to that in the back emulsion layer when the same developer and time of development are employed. 8. A tripack according to claim 1 wherein the intermediate layer has a quantity of silver halide per unit area which is only a small fraction of that in a normal emulsion coating so that it gives rise to a normal degree of contrast in the developed image which approximates to that in the back emulsion layer when the same develdper and time of development are employed.

9. A tripack according to claim 1 wherein the front layer has a quantity of silver halide per unit area which is between one fifth and one quarter of that in a normal emulsion coating, so that it gives rise to a normal degree of contrast in the developed image which approximates to that in the back emulsion layer when the same developer and time of development are employed.

10. A tripack according to claim 1 wherein the intermediate layer has .a quantity of silver halide per unit area which isbetween one fifth and one quarter of that in a normal emulsion coating, so that it gives rise to a normal degree of contrast in the developed image which approximates to that in the bank emulsion layer when the same developer and time of development are employed.

11. A tripack according to claim 1 wherein the front layer has a quantity of silver halide per unit area which 1s only a small fraction of that in a normal emulsion coating, so that it gives rise to a normal degree of contrast in the developed image which approximates to that in the back emulsion layer when the same developer and time of development are employed and the back emulsion layer is treated with a substance which depresses its I inherent green sensitivity.

' 12. A tripack according to claim 1 wherein the intermediate layer has a quantity of silver halide per unit area which is only a small fraction of that in a normal emulsion coating,

.so that it gives rise to a normal degree of contrast in the developed image which approximates to that in the back emulsion layer when the same developer and time of development are employed and the back emulsion layer is treated with a substance which depresses its inherent green sensitivity.

In testimony whereof I afiix my signature. THOMAS THORNE BAKER.