US1865629A - Sealing composition - Google Patents
Sealing composition Download PDFInfo
- Publication number
- US1865629A US1865629A US340325A US34032529A US1865629A US 1865629 A US1865629 A US 1865629A US 340325 A US340325 A US 340325A US 34032529 A US34032529 A US 34032529A US 1865629 A US1865629 A US 1865629A
- Authority
- US
- United States
- Prior art keywords
- naphthalene
- sealing composition
- wax
- sealing
- gilsonite
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000203 mixture Substances 0.000 title description 16
- 238000007789 sealing Methods 0.000 title description 13
- 150000002790 naphthalenes Chemical class 0.000 description 12
- 238000007598 dipping method Methods 0.000 description 5
- 238000000576 coating method Methods 0.000 description 4
- 239000003921 oil Substances 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 239000004615 ingredient Substances 0.000 description 3
- 239000001993 wax Substances 0.000 description 3
- QEPTXDCPBXMWJC-UHFFFAOYSA-N 1,2,3-trichloronaphthalene Chemical compound C1=CC=C2C(Cl)=C(Cl)C(Cl)=CC2=C1 QEPTXDCPBXMWJC-UHFFFAOYSA-N 0.000 description 2
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 2
- 239000004204 candelilla wax Substances 0.000 description 2
- 235000013868 candelilla wax Nutrition 0.000 description 2
- 229940073532 candelilla wax Drugs 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 239000011888 foil Substances 0.000 description 2
- IUJAMGNYPWYUPM-UHFFFAOYSA-N hentriacontane Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCC IUJAMGNYPWYUPM-UHFFFAOYSA-N 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- DSEKYWAQQVUQTP-XEWMWGOFSA-N (2r,4r,4as,6as,6as,6br,8ar,12ar,14as,14bs)-2-hydroxy-4,4a,6a,6b,8a,11,11,14a-octamethyl-2,4,5,6,6a,7,8,9,10,12,12a,13,14,14b-tetradecahydro-1h-picen-3-one Chemical compound C([C@H]1[C@]2(C)CC[C@@]34C)C(C)(C)CC[C@]1(C)CC[C@]2(C)[C@H]4CC[C@@]1(C)[C@H]3C[C@@H](O)C(=O)[C@@H]1C DSEKYWAQQVUQTP-XEWMWGOFSA-N 0.000 description 1
- NAQWICRLNQSPPW-UHFFFAOYSA-N 1,2,3,4-tetrachloronaphthalene Chemical compound C1=CC=CC2=C(Cl)C(Cl)=C(Cl)C(Cl)=C21 NAQWICRLNQSPPW-UHFFFAOYSA-N 0.000 description 1
- CGYGETOMCSJHJU-UHFFFAOYSA-N 2-chloronaphthalene Chemical compound C1=CC=CC2=CC(Cl)=CC=C21 CGYGETOMCSJHJU-UHFFFAOYSA-N 0.000 description 1
- ZRYCRPNCXLQHPN-UHFFFAOYSA-N 3-hydroxy-2-methylbenzaldehyde Chemical compound CC1=C(O)C=CC=C1C=O ZRYCRPNCXLQHPN-UHFFFAOYSA-N 0.000 description 1
- 235000010919 Copernicia prunifera Nutrition 0.000 description 1
- 244000180278 Copernicia prunifera Species 0.000 description 1
- 241001553290 Euphorbia antisyphilitica Species 0.000 description 1
- 239000010022 Myron Substances 0.000 description 1
- 241001439614 Myron Species 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000004203 carnauba wax Substances 0.000 description 1
- 235000013869 carnauba wax Nutrition 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- SLGWESQGEUXWJQ-UHFFFAOYSA-N formaldehyde;phenol Chemical compound O=C.OC1=CC=CC=C1 SLGWESQGEUXWJQ-UHFFFAOYSA-N 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 235000015250 liver sausages Nutrition 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- 239000012262 resinous product Substances 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- XYSQXZCMOLNHOI-UHFFFAOYSA-N s-[2-[[4-(acetylsulfamoyl)phenyl]carbamoyl]phenyl] 5-pyridin-1-ium-1-ylpentanethioate;bromide Chemical compound [Br-].C1=CC(S(=O)(=O)NC(=O)C)=CC=C1NC(=O)C1=CC=CC=C1SC(=O)CCCC[N+]1=CC=CC=C1 XYSQXZCMOLNHOI-UHFFFAOYSA-N 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J195/00—Adhesives based on bituminous materials, e.g. asphalt, tar, pitch
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
- C08L2666/28—Non-macromolecular organic substances
- C08L2666/32—Halogen-containing compounds
Definitions
- This invention relates to sealing compositions adapted for use in the manufacture of fixed electrical condensers and equivalent articles.
- Such condensers are commonly prepared by rolling two continuous sheets of metal foil in contact with two or more separating sheets of insulating paper until the surface area of foil included is that necessary for the required electrical capacity, impregnating with insulating wax and then dipping the rolls in a sealing composition to prevent the entrance of moisture.
- a composition is demanded that requires but one dipping to produce and effective seal and which chills to a solid condition as soon as the condensers are withdrawn from the molten composition.
- the applied composition be flexible so that a coating will not chip oil m; from a dipped condenser if accidentally dropped or otherwise subjected to impacts.
- sealing compositions for condensers can be obtained from mixtures of wax-like halogenated naphthalenes, which in themselves are somewhat crystalline and too brittle for use as sealing compositions, and bitumens, such as gilsonite, or mineral or other waxes, for example, candelilla, carnauba, etc., which bitumens or waxes,
- coated condensers are subsequently immersed in oil to avoid drawing in ofany air during a cooling operation. All these mixtures have the further advantage of being freefrom any acid ingredients to affect the paper insulation and being substantially noncombustible.
- Ewample 1 A chlorinated naphthalene wax-like product consisting principally of a tetrachloro-naphthalene is melted and gilsonite is dissolved therein in the proportions by weight of about 1 part of gilsonite to 3-9 parts of chlorinated naphthalene. This solution is maintained in a molten condition for dipping and upon withdrawal of acondenser from the solution forms a sub-' stantially uniform flexible coating thereon of sufficient thickness with a single dipping.
- the proportions given are not critical and may be varied, but those stated are found preferable in actual practice.
- Example 2 A chlorinated naphthalene comprising mainly a trichloro-naphthalene in the molten condition has substantially an equal amount of candelilla wax added to it. These ingredients are miscible in substantially all proportions and considerable variation from that stated is possible without appreciably modifying the properties of rapid cooling, resistance to moisture and flexibility.
- Emample 3 In the above example ozokerite and/or carnauba wax are substituted in part for the candelilla wax.
- Example r A chlorinated naphthalene, containing as its principal constituent a trichloronaphthalene, is mixed with a cresolformaldehyde resinoid in substantially equal parts.
- a characteristic of a product obtained by adding gilsonite to halogenated naphthalene is the increase in its flow point with continued heating. This renders the product particularly desirable for the sealing of condensers enclosed in cabinets or the like and /or closely associated with heat-generating electrical units, as danger of the sealing compound flowing on account of becoming heated and exposing the condenser elements is substantially eliminated.
- a sealing composition characterized by resistance to moisture penetration and including a wax-like halogenated naphthalene in solution with gilsonite.
- a sealing composition characterized by resistance to moisture and including about 3 to 9 parts of a wax-like chlorinated naphthalene in solution with about 1 part of gilsonite.
- a process of preparing a sealing composition which comprises melting a wax-like halogented naphthalene and dissolving gilsonite in said molten halogenated naphthalene.
- Sealing composition comprising a waxlike halogenated naphthalene and about an equal amount of a phenolic resinoid.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Organic Insulating Materials (AREA)
- Paints Or Removers (AREA)
- Structures Or Materials For Encapsulating Or Coating Semiconductor Devices Or Solid State Devices (AREA)
Description
Patented July 5, 1932 UNrrEn STATES PATE F ERNEST R. HANSON, OF BLOOMFIELID, AND MYRON DELANEY, OF EAST ORANGE, NEW
JERSEY, ASSIGNORS T HALOWAX CORPORATION, NEW YORK, N. Y., A GORPORA- 1 TION OF DELAWARE SEALING COMPOSITION i No Drawing.
This invention relates to sealing compositions adapted for use in the manufacture of fixed electrical condensers and equivalent articles. Such condensers are commonly prepared by rolling two continuous sheets of metal foil in contact with two or more separating sheets of insulating paper until the surface area of foil included is that necessary for the required electrical capacity, impregnating with insulating wax and then dipping the rolls in a sealing composition to prevent the entrance of moisture. For commercial operations a composition is demanded that requires but one dipping to produce and effective seal and which chills to a solid condition as soon as the condensers are withdrawn from the molten composition. Furthermore it is desirable that the applied composition be flexible so that a coating will not chip oil m; from a dipped condenser if accidentally dropped or otherwise subjected to impacts.
e have discovered that sealing compositions for condensers can be obtained from mixtures of wax-like halogenated naphthalenes, which in themselves are somewhat crystalline and too brittle for use as sealing compositions, and bitumens, such as gilsonite, or mineral or other waxes, for example, candelilla, carnauba, etc., which bitumens or waxes,
2': though likewise brittle and/or otherwise unsuited for sealing purposes, so modify the halogenated naphthalenes as to yield compositions depositing in one dipping operation moisture resistant coatings with sufficient flexibility to withstand cracking or chipping due to such impacts as may be likely to occur in the manufacture of the condensers. Admixtures of synthetic amorphous or resinous products, such as the phenol-formaldehyde resinoids which harden when heated, with the halogenated naphthalene wax-like products can be made to yield moisture-resistant coatings having in addition the property of resistance to the action of oils; this property of resistance to oils is desirable where the hot Application filed February 15, 1929. Serial No. 340,325.
coated condensers are subsequently immersed in oil to avoid drawing in ofany air during a cooling operation. All these mixtures have the further advantage of being freefrom any acid ingredients to affect the paper insulation and being substantially noncombustible.
Some specific examples are hereinafter given to illustrate the invention, but it is to be understood that the invention is not restricted to the ingredients or proportions stated.
Ewample 1: A chlorinated naphthalene wax-like product consisting principally of a tetrachloro-naphthalene is melted and gilsonite is dissolved therein in the proportions by weight of about 1 part of gilsonite to 3-9 parts of chlorinated naphthalene. This solution is maintained in a molten condition for dipping and upon withdrawal of acondenser from the solution forms a sub-' stantially uniform flexible coating thereon of sufficient thickness with a single dipping. The proportions given are not critical and may be varied, but those stated are found preferable in actual practice.
Example 2: A chlorinated naphthalene comprising mainly a trichloro-naphthalene in the molten condition has substantially an equal amount of candelilla wax added to it. These ingredients are miscible in substantially all proportions and considerable variation from that stated is possible without appreciably modifying the properties of rapid cooling, resistance to moisture and flexibility.
Emample 3: In the above example ozokerite and/or carnauba wax are substituted in part for the candelilla wax.
Example r. A chlorinated naphthalene, containing as its principal constituent a trichloronaphthalene, is mixed with a cresolformaldehyde resinoid in substantially equal parts.
A characteristic of a product obtained by adding gilsonite to halogenated naphthalene is the increase in its flow point with continued heating. This renders the product particularly desirable for the sealing of condensers enclosed in cabinets or the like and /or closely associated with heat-generating electrical units, as danger of the sealing compound flowing on account of becoming heated and exposing the condenser elements is substantially eliminated.
We claim:
1. A sealing composition characterized by resistance to moisture penetration and including a wax-like halogenated naphthalene in solution with gilsonite.
2. A sealing composition characterized by resistance to moisture and including about 3 to 9 parts of a wax-like chlorinated naphthalene in solution with about 1 part of gilsonite.
3. A process of preparing a sealing composition which comprises melting a wax-like halogented naphthalene and dissolving gilsonite in said molten halogenated naphthalene.
4. Sealing composition comprising a waxlike halogenated naphthalene and about an equal amount of a phenolic resinoid.
In testimony whereof we afiix our signatures.
ERNEST R. HANSON. MYRON E. DELANEY.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US340325A US1865629A (en) | 1929-02-15 | 1929-02-15 | Sealing composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US340325A US1865629A (en) | 1929-02-15 | 1929-02-15 | Sealing composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US1865629A true US1865629A (en) | 1932-07-05 |
Family
ID=23332869
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US340325A Expired - Lifetime US1865629A (en) | 1929-02-15 | 1929-02-15 | Sealing composition |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US1865629A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20200062952A1 (en) * | 2017-03-13 | 2020-02-27 | Tiger Coatings Gmbh & Co. Kg | Use of a thermosetting polymeric powder composition |
-
1929
- 1929-02-15 US US340325A patent/US1865629A/en not_active Expired - Lifetime
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20200062952A1 (en) * | 2017-03-13 | 2020-02-27 | Tiger Coatings Gmbh & Co. Kg | Use of a thermosetting polymeric powder composition |
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