US1856934A - Refining lubricating oil - Google Patents

Refining lubricating oil Download PDF

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Publication number
US1856934A
US1856934A US286073A US28607328A US1856934A US 1856934 A US1856934 A US 1856934A US 286073 A US286073 A US 286073A US 28607328 A US28607328 A US 28607328A US 1856934 A US1856934 A US 1856934A
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United States
Prior art keywords
lubricating oil
oil
refining
refining lubricating
bath
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
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US286073A
Inventor
James G Stafford
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sinclair Refining Co
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Sinclair Refining Co
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Publication date
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Priority to US286073A priority Critical patent/US1856934A/en
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Publication of US1856934A publication Critical patent/US1856934A/en
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Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G25/00Refining of hydrocarbon oils in the absence of hydrogen, with solid sorbents
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G71/00Treatment by methods not otherwise provided for of hydrocarbon oils or fatty oils for lubricating purposes

Definitions

  • the fullers earth, or other solid absorbent is maintained in suspension in a bath of the oil heated to a temperature of 500600 F. while a II1OXldizing, or better a reducing, gaseous medium is bubbled therethrough.
  • the gaseous media useful in carrying out my invention include hydrogen, carbon dioxide, nitrogen and pressure still tail gases.
  • Pressure still tail gases that is the gas mixture remaining uncondensed in operations carried out for the production of gasoline by cracking gas oil, for example, are particularly advantageous.
  • the fullers earth may be maintained in suspension in the bath by appropriately introducing the gas or gas mixture or by mechanical agitation or by both of these means.
  • the operation can be controlled by regulating the proportion of solid absorbent employed.
  • the operation can also be controlled by regulating the time of treatment; which is usually an average of 25 minutes.
  • gaseous treating medium should be supplied Application filed June 16, 1928.
  • the treated lubri cating oil may be steamed to strip out any components absorbed from the gaseous treating medium; this step is particularly useful where pressure still tail gases are used as the gaseous treating medium.
  • the improvement which comprises contacting the lubricating oil with a comminuted solid consisting solely of a non-metallic adsorbent at a temperature of about 500600 F. for about 2-5 minutes in the presence of a maintained atmosphere of pressure still tail gases.
  • the improvement which comprises contacting the lubricating oil with a comminuted solid consisting solely of a non-metallic adsorbent at a temperature of about 500600 F. for about 25 minutes in the presence of a maintained atmosphere of a reducing gas.

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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Description

Patented May 3, 1932 UNITED STATES PATENT OFFICE JAMES G. STAFFORD, OF WHITING, INDIANA, ASSIGNOR TO SINCLAIR REFINING COIM- PANY, OF NEW YORK, N. Y., A CORPORATION OF MAINE REFININ G LUBRICATING- OIL No Drawing.
" or and cast, by digestion at a temperature of about 500-600 F. while in contact with a comminuted solid absorbent such as fullers earth in the presence of a maintained atmosphere of a non-oxidizing, or better a reducing, gaseous medium.
According to my invention, the fullers earth, or other solid absorbent, is maintained in suspension in a bath of the oil heated to a temperature of 500600 F. while a II1OXldizing, or better a reducing, gaseous medium is bubbled therethrough.
The gaseous media useful in carrying out my invention include hydrogen, carbon dioxide, nitrogen and pressure still tail gases.
Pressure still tail gases, that is the gas mixture remaining uncondensed in operations carried out for the production of gasoline by cracking gas oil, for example, are particularly advantageous. The fullers earth may be maintained in suspension in the bath by appropriately introducing the gas or gas mixture or by mechanical agitation or by both of these means.
Although I have referred to the operation as digestion, it can be carried out in a continuousmanner by supplying untreated oil and fresh absorbent to the bath and by discharging treated oil and spent absorbent from V the bath as the operation proceeds.
The operation can be controlled by regulating the proportion of solid absorbent employed. About 8% by weight on the oil of fullers earth of 100-200 mesh, for example,
is is usually satisfactory, although the proportion used may be more than 1% or less than The operation can also be controlled by regulating the time of treatment; which is usually an average of 25 minutes. The
gaseous treating medium should be supplied Application filed June 16, 1928.
Serial No. 286,073.
at a rate suflicient to maintain the oil bath saturated therewith.
Following this treatment, the treated lubri cating oil may be steamed to strip out any components absorbed from the gaseous treating medium; this step is particularly useful where pressure still tail gases are used as the gaseous treating medium.
I have observed in particular that my in Vention, applied to lubricating oils which would otherwise have a blue cast, tends to change the cast to a green. This improvement in the cast is effected at the same time that the color of the lubricating oil is improved.
I claim:
1. In the refining of lubricatingoils, the improvement which comprises contacting the lubricating oil with a comminuted solid consisting solely of a non-metallic adsorbent at a temperature of about 500600 F. for about 2-5 minutes in the presence of a maintained atmosphere of pressure still tail gases.
2. In the refining of lubricating oils, the improvement which comprises contacting the lubricating oil with a comminuted solid consisting solely of a non-metallic adsorbent at a temperature of about 500600 F. for about 25 minutes in the presence of a maintained atmosphere of a reducing gas.
In testimony whereof, I have subscribed my name.
JAMES, G. STAFF ORD,
US286073A 1928-06-16 1928-06-16 Refining lubricating oil Expired - Lifetime US1856934A (en)

Priority Applications (1)

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US286073A US1856934A (en) 1928-06-16 1928-06-16 Refining lubricating oil

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Application Number Priority Date Filing Date Title
US286073A US1856934A (en) 1928-06-16 1928-06-16 Refining lubricating oil

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US1856934A true US1856934A (en) 1932-05-03

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2461454A (en) * 1945-05-04 1949-02-08 Texas Co Manufacture of lubricating oil
US2461453A (en) * 1945-05-04 1949-02-08 Texas Co Manufacture of lubricating oil
US2461455A (en) * 1945-05-04 1949-02-08 Texas Co Manufacture of lubricating oil
US2703783A (en) * 1950-04-28 1955-03-08 Exxon Research Engineering Co Process for the clarification of lubricating oil additive concentrates
US2756196A (en) * 1952-12-08 1956-07-24 Shell Dev Refining lubricating oils

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2461454A (en) * 1945-05-04 1949-02-08 Texas Co Manufacture of lubricating oil
US2461453A (en) * 1945-05-04 1949-02-08 Texas Co Manufacture of lubricating oil
US2461455A (en) * 1945-05-04 1949-02-08 Texas Co Manufacture of lubricating oil
US2703783A (en) * 1950-04-28 1955-03-08 Exxon Research Engineering Co Process for the clarification of lubricating oil additive concentrates
US2756196A (en) * 1952-12-08 1956-07-24 Shell Dev Refining lubricating oils

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