US1848650A - of basel - Google Patents
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- US1848650A US1848650A US1848650DA US1848650A US 1848650 A US1848650 A US 1848650A US 1848650D A US1848650D A US 1848650DA US 1848650 A US1848650 A US 1848650A
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- azo
- brown
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- amino
- acid
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- 150000008049 diazo compounds Chemical class 0.000 description 38
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 38
- 125000000751 azo group Chemical group [*]N=N[*] 0.000 description 32
- HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 28
- -1 amino-azo Chemical group 0.000 description 26
- 239000000975 dye Substances 0.000 description 22
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 22
- YGSDEFSMJLZEOE-UHFFFAOYSA-N Salicylic acid Chemical compound OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 description 20
- 125000003277 amino group Chemical group 0.000 description 18
- 239000003795 chemical substances by application Substances 0.000 description 18
- 229910052757 nitrogen Inorganic materials 0.000 description 18
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 18
- 239000002253 acid Substances 0.000 description 16
- 230000001808 coupling Effects 0.000 description 14
- 238000010168 coupling process Methods 0.000 description 14
- 238000005859 coupling reaction Methods 0.000 description 14
- VEXZGXHMUGYJMC-UHFFFAOYSA-N HCl Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 12
- VYZAMTAEIAYCRO-UHFFFAOYSA-N chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 12
- 238000004519 manufacturing process Methods 0.000 description 12
- 239000011780 sodium chloride Substances 0.000 description 12
- 235000011121 sodium hydroxide Nutrition 0.000 description 12
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 10
- UHOVQNZJYSORNB-UHFFFAOYSA-N benzene Substances C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 10
- 238000006193 diazotization reaction Methods 0.000 description 10
- 150000002790 naphthalenes Chemical group 0.000 description 10
- 229960004889 salicylic acid Drugs 0.000 description 10
- 125000002777 acetyl group Chemical group [H]C([H])([H])C(*)=O 0.000 description 8
- 125000000664 diazo group Chemical group [N-]=[N+]=[*] 0.000 description 8
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 8
- 239000000203 mixture Substances 0.000 description 8
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 6
- 239000003513 alkali Substances 0.000 description 6
- 229910052783 alkali metal Inorganic materials 0.000 description 6
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 6
- 229910052804 chromium Inorganic materials 0.000 description 6
- 239000011651 chromium Substances 0.000 description 6
- 230000000875 corresponding Effects 0.000 description 6
- 238000004043 dyeing Methods 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 description 6
- 239000000843 powder Substances 0.000 description 6
- 150000003839 salts Chemical class 0.000 description 6
- 239000001117 sulphuric acid Substances 0.000 description 6
- 235000011149 sulphuric acid Nutrition 0.000 description 6
- 229920000742 Cotton Polymers 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 239000000835 fiber Substances 0.000 description 4
- TUJKJAMUKRIRHC-UHFFFAOYSA-N hydroxyl radical Chemical group [OH] TUJKJAMUKRIRHC-UHFFFAOYSA-N 0.000 description 4
- 230000003993 interaction Effects 0.000 description 4
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 4
- CDBYLPFSWZWCQE-UHFFFAOYSA-L sodium carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 4
- ZAJAQTYSTDTMCU-UHFFFAOYSA-N 3-aminobenzenesulfonic acid Chemical compound NC1=CC=CC(S(O)(=O)=O)=C1 ZAJAQTYSTDTMCU-UHFFFAOYSA-N 0.000 description 2
- WUBBRNOQWQTFEX-UHFFFAOYSA-N 4-Aminosalicylic acid Chemical compound NC1=CC=C(C(O)=O)C(O)=C1 WUBBRNOQWQTFEX-UHFFFAOYSA-N 0.000 description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate dianion Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 2
- 206010013710 Drug interaction Diseases 0.000 description 2
- WRUUGTRCQOWXEG-UHFFFAOYSA-N Pamidronic acid Chemical compound NCCC(O)(P(O)(O)=O)P(O)(O)=O WRUUGTRCQOWXEG-UHFFFAOYSA-N 0.000 description 2
- GHMLBKRAJCXXBS-UHFFFAOYSA-N Resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 description 2
- CHHFZZHDXWPJKP-UHFFFAOYSA-N [N+](=[N-])=C1CC=CC=C1.[N+](=O)(O)[O-] Chemical compound [N+](=[N-])=C1CC=CC=C1.[N+](=O)(O)[O-] CHHFZZHDXWPJKP-UHFFFAOYSA-N 0.000 description 2
- 150000001447 alkali salts Chemical class 0.000 description 2
- 229960004909 aminosalicylic acid Drugs 0.000 description 2
- 238000006149 azo coupling reaction Methods 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- 239000001569 carbon dioxide Substances 0.000 description 2
- 229910002092 carbon dioxide Inorganic materials 0.000 description 2
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 229910001873 dinitrogen Inorganic materials 0.000 description 2
- 239000002360 explosive Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000000983 mordant dye Substances 0.000 description 2
- 238000006396 nitration reaction Methods 0.000 description 2
- 230000020477 pH reduction Effects 0.000 description 2
- 125000000843 phenylene group Chemical group C1(=C(C=CC=C1)*)* 0.000 description 2
- 229960001755 resorcinol Drugs 0.000 description 2
- 238000005185 salting out Methods 0.000 description 2
- 238000007127 saponification reaction Methods 0.000 description 2
- 239000001187 sodium carbonate Substances 0.000 description 2
- 229910000029 sodium carbonate Inorganic materials 0.000 description 2
- 239000007858 starting material Substances 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B43/00—Preparation of azo dyes from other azo compounds
Definitions
- reaction is terminated, when it hasdisappeared, that is to say, when a test ofthe solution does no more react upon an azo coupling component, such as jresorcinol (or resorcin) or ,B-naphthol- 3r 6 -dis'ulph-onic acid.
- an azo coupling component such as jresorcinol (or resorcin) or ,B-naphthol- 3r 6 -dis'ulph-onic acid.
- Bulow (Berliner Berichte, Vol. 44, page 601 and following) records the observation that the diazo compound from para-aminobenzene-azo-salicylicacid assumes an intense blue colour on addition ofsodium carbonate solution, that this blue colour is permanent for a long time in the cold, that by passing carbon dioxide into the solution the colour changes from blue to yellow brown and that I the diazo compound in this manner is in no way destroyed. It is not stated what bodies exist in thissolution.
- the nature of the reaction on the diazo group of such bodies must be a different has disappeared.
- the dyestuffs thus obtained constitute brownpowders, being in form of their alkali metal salts soluble in water with brown colour, which solution on the addition of caustic soda lye turns to brown red and from which solution an addition of diluted hydrochloric acid separates out brown-black flakes, said dyestuffs dissolving in concentrated sulphuric acid to a dark violetish-brown toviolet solution and dyeing chromium mordanted fibre fast mainly brown shades.
- salicylic acid (madefor example by inter-- action of the'diazo compound of para-ni- 7 constitutes 'the diazo compound and is fill traniline-ortho sulphonic with salicylic acid and reduction of the nitro group in themonoazo dyestuif h aving.
- the formula are diazotiz ed as usual the diazotization taking'place at the amino group. 7
- the brownish-yellow mass of crystals which is "formed tered and then stirred with water; The mixture is then made alkaline with ammonia and stirred at the ordinary temperature until the deep bluecolour has disappeared and the solution is brown.
- the solution is acidified and the precipitateddyestuff filtered and dried; It dissolves in the form of the free dyestuif acid in water to a brown solution.
- the diazo body is stirred with water and made alkaline with ammonia and stirred at ordinary temperature until the deep blue coloration has disappeared and the solutionis brown.
- The-new dyestuff is salted out, filtered off and dried.
- the diazo compound is filtered, stirred with -wat'er and the mixture maide alkaline. with ammonia.
- the solution is stirred at the ordinary temp erature until the deep blue color has changed to brown;
- The: dyestufi thus formed in contrast withthe products which contain asulphonic group, is sparingly" soluble in the-form of free dyestufi acid and must be isolated in the form of; its alkali salts.
- E wample V I 387 parts of the amino-azo dyestuff made from the diaz ocompound of para-aminosalicylic acid and Cleve-acid (wnaphthylaminee6 or 7 v:sulphonicac'id) having the for are dia'zotized in the usual manner the diazotization taking place at the amino group.
- This diazo body is stirred with water and the mixture made alkaline by addition of a sodium carbonate solution. The whole is stirred at ordinary temperature until the deep blue color has changed to brown and the development of nitrogen gas has ceased.
- R represents a benzene nucleus having a hydroXyl and a carboxyl group in ortho position to each other and wherein R represents a benzene or naphthalene nucleus having an amino group in para position with respect to the azo group, and treating the formed diazo compound with an alkaline agent so as to produce, when its coupling power has disappeared, a new azo dyestuff containing probably besides the nitrogen being present in the azo groups, more nitrogen, but not in form of a chromophoric group.
- R represents a benzene nucleus having a hydroXyl and a carboxyl group in ortho position to each other and wherein R represents a benzene or naphthalene nucleus which contains an amino group in para position with respect to the azo group and has a negative salt forming group in any position, and treating the formed diazo compound with an alkaline agent, so as to produce, when its coupling power has disappeared, a new azo dyestuff containing probably besides the nitrogen being present in the azo groups more wherein R represents a benzene nucleus having a hydroxyl and a carboXyl group in orthoposition to each other and wherein R represents a benzene or naphthalene nucleus which contains an amino group in para position with respect to the azo group and has a sulpho group in any other position, and treating the formed diazo compound with an alkaline agent,so as to produce, when its coupling power has disappeared, anew azo dyestuff
- a process for the manufacture of mordant dyestuffs which consists in diazotizing para-ammo-sulphobenzene-azosahcyhc acid and treating the formed diazo compound with an alkaline-agent, so as to produce, when its coupling power has d1sappeared, a new azo dyestuif containing probably besides the nitrogen being present in the azo groups,
- Aproeess for the manufacture of mordantdyestuffs which consists in diazotizing para-amino-sulpho-benzene-azosalicylic acid and treating the formed diazo compound with ammonia so as to produce, when its coupling power has disappeared, a new azo dyestuff containing probably besides the nitrogen being present in the azo groups more nitrogen, but not in form of a chromophoric group.
- R represents a benzene nucleus having a hydroxyl and a carboxyl group in ortho position to each other and wherein R represents a benzene or naphthalene nucleus having an amino group in para position with respect to the azo group and by treating the formed diazo compound with an alkaline agent, said dyestuffs constituting brown powders being in form' of their alkali metal salts soluble in water with brown colour, which solution on addition of caustic soda lye turns to brown red and from which solution an addition of diluted hydrochloric acid separates out brown-black flakes, said dyestuffs dissolving in concentrated sulphuric acid to a dark violetish brown to violet solution and dyeing chromium mordanted fibre fast mainly brown shades.
- R represents a benzene nucleus having a hydroxyl and a carbonyl group in ortho position to each other and wherein R represents a benzene or naphthalene nucleus having an amino group in para position with respect to the azo group and having a negative salt forming group in any other position and by treating the formed diazo compound withan alkaline; agent; said dyestuffs constituting v 'brovvn powders being in form of their alkali inetal salts soluble .
- Water with brown colour, '5 which solution on addition ofcaustic soda lye turns to brown red and from which solution an addition of diluted hydrochloric acid separates out brown-black flakeasaid dyestuffs V dissolving in concentrated sulphuric acid to 10 a dark violetish brownto violet solution and dyeingchromium mordantedfibre fast mainlybrown shades.
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Coloring (AREA)
Description
Patented Mar. 8, 1932 uurrsn STATES PATENT OFFICE GEORG OSTlERTAG, OF BASEL, SWITZERLAND, ASSIGNOR TO THE FIRM DURAND & HUG-'UENIN S. A., OF BASEL, SWITZERLAND MORDAINT DYESTUFFS AND PROCESS OF MAKING SAME No Drawing. Application filed December 29,1927, Serial No. 243,475, and in Germany lanuary 10, 1927.
It has been. foundthat valuable mordant dyestuffs can be obtained by diazotizing an amino-azo body of the following general formula N==N- V I R2 7 I i 7 i NH2 wherein'R represents a benzene nucleus havin'gra hydroxyl' and a carboXyl group in ortho deep blue solution. This colour disappears after ashort time and a brown solution is finally obtained,from'which the new dyestuff can be separated by acidification or by salting out. By this treatment with an alkaline agent the di'azo compound gradually loses its coupling power. The reaction is terminated, when it hasdisappeared, that is to say, when a test ofthe solution does no more react upon an azo coupling component, such as jresorcinol (or resorcin) or ,B-naphthol- 3r 6 -dis'ulph-onic acid. In this way, for intan'c'e', the amino azo dyestufl': et-amino-Q-sulpho-benz'ene-azosalicyclic acid of the formula:
p QNz-NUCOOH NH: soan' ou can be diazotized and the formed diazo compound be treated with, alkali until it has lost the property of coupling.
C. Bulow (Berliner Berichte, Vol. 44, page 601 and following) records the observation that the diazo compound from para-aminobenzene-azo-salicylicacid assumes an intense blue colour on addition ofsodium carbonate solution, that this blue colour is permanent for a long time in the cold, that by passing carbon dioxide into the solution the colour changes from blue to yellow brown and that I the diazo compound in this manner is in no way destroyed. It is not stated what bodies exist in thissolution.
By Griess (see Annalen der Chemie Vol. 137, pages 78 to 82, 1866) and by Gain (Diazocompounds. pages 67 and 68, 1920) the action of alkalies .on single diazo compounds such as diazobenzene nitrate, sulphate, -perbromide and others has been disclosed. It is pointed out therein, that the materials subjected to such a treatment are decomposed and yield unstable products, more or less explosive and contain besldes others dlazoamino, azlmmo, etc. groups. The present invention, contrarily to the cited researchworks, relates to the treatment with an alkaline agent of specific amino-azo=compouncls, therefore of quite another structure, than the starting materials used by Griess and Cain. The nature of the reaction on the diazo group of such bodies must be a different has disappeared.
The dyestuffs thus obtained constitute brownpowders, being in form of their alkali metal salts soluble in water with brown colour, which solution on the addition of caustic soda lye turns to brown red and from which solution an addition of diluted hydrochloric acid separates out brown-black flakes, said dyestuffs dissolving in concentrated sulphuric acid to a dark violetish-brown toviolet solution and dyeing chromium mordanted fibre fast mainly brown shades.
It has not yet been found exactly what trogen, but not in form of chromophoric group.
The followingexamples illustrate the in-:
vention, the parts being by weight. i
' Eeamp le I:
salicylic acid (madefor example by inter-- action of the'diazo compound of para-ni- 7 constitutes 'the diazo compound and is fill traniline-ortho sulphonic with salicylic acid and reduction of the nitro group in themonoazo dyestuif h aving. the formula are diazotiz ed as usual the diazotization taking'place at the amino group. 7 The brownish-yellow mass of crystals which is "formed tered and then stirred with water; The mixture is then made alkaline with ammonia and stirred at the ordinary temperature until the deep bluecolour has disappeared and the solution is brown. The solution is acidified and the precipitateddyestuff filtered and dried; It dissolves in the form of the free dyestuif acid in water to a brown solution.
.When chromeprinted on cotton it yields reddishfbrowntints of good fa'stness.
mma 11" '257 parts of 4;-amino-benZene-aZo-salicylic acid (made forexample by couplingof the diazo compound of mono acetyl para-phe- .nylene-diamine with salicylic acid and: by saponification of the acetyl group or bycoupling of the diazo compound of para-nitraniline with. salicylic acid and by reduction of the nitro group in the azo dyestufi so ob.- tained) havingthe formula;
are diazotized as usual, the diazotization tak ing 'plac e at the. amino group. The diazo body is stirred with water and made alkaline with ammonia and stirred at ordinary temperature until the deep blue coloration has disappeared and the solutionis brown. The-new dyestuff is salted out, filtered off and dried. I
When printed with chrome mordant on cotton it yields fast brownish tints.
E mample I I I 351 parts of 4-amino-2-sulpho-benzene azo-meta-cresotinic acid (made for example by interaction of the diazo compound of acetyl para phenyl-ene -diamine-sulphonic acid with meta-cresotinic acid and saponifying the acetyl group) having the formula:
V N-IN coon NHr- SOaH on; 01%
. are diazoti'zed'in the usual-manner, the diazotization taking place at the amino Y group. The diazo compound is-filtered, stirred with water and the mixture made alkaline by addition of ammonia; The whole is stirred at the ordinarytemperature until the deep blue colour disappears and a brown solution is produced. The dyestuff is separated by addition of acid; It're's'embles that made according to Example I. In chrome printing it yields a somewhat more reddish tint, however. i
In aquite analogous manner a similar dyestuff is I obtained from l-amino'-2-sulpho- :benzene-azo-ortho-cresotinic acid- ,v I EzmmpZe'IVf I 301 parts of 4-aminoil}carboXyl-benzeneazo-salicylic acid .(made from the lazo dyestuff fromanthranilic acidand salicylic acid by nitration and reduction; of a the nitro groupyhaving the formula:
are diazotized in the usual mannertlie diazotization taking place at the aminogroup.
The diazo compound is filtered, stirred with -wat'er and the mixture maide alkaline. with ammonia. The solution is stirred at the ordinary temp erature until the deep blue color has changed to brown; The: dyestufi thus formed, in contrast withthe products which contain asulphonic group, is sparingly" soluble in the-form of free dyestufi acid and must be isolated in the form of; its alkali salts.
When chrome printed it yields brown tints whichare more yellowish than those obtained with the product made according .to Example I. c
E wample V I 387 parts of the amino-azo dyestuff made from the diaz ocompound of para-aminosalicylic acid and Cleve-acid (wnaphthylaminee6 or 7 v:sulphonicac'id) having the for are dia'zotized in the usual manner the diazotization taking place at the amino group. This diazo body is stirred with water and the mixture made alkaline by addition of a sodium carbonate solution. The whole is stirred at ordinary temperature until the deep blue color has changed to brown and the development of nitrogen gas has ceased.
wherein R represents a benzene nucleus having a hydroXyl and a carboxyl group in ortho position to each other and wherein R represents a benzene or naphthalene nucleus having an amino group in para position with respect to the azo group, and treating the formed diazo compound with an alkaline agent so as to produce, when its coupling power has disappeared, a new azo dyestuff containing probably besides the nitrogen being present in the azo groups, more nitrogen, but not in form of a chromophoric group.
2. A process for the manufacture of mordant dyestufis, which consists in diazotizing an amino-azo compound corresponding to the following formula:
wherein R represents a benzene nucleus having a hydroXyl and a carboxyl group in ortho position to each other and wherein R represents a benzene or naphthalene nucleus which contains an amino group in para position with respect to the azo group and has a negative salt forming group in any position, and treating the formed diazo compound with an alkaline agent, so as to produce, when its coupling power has disappeared, a new azo dyestuff containing probably besides the nitrogen being present in the azo groups more wherein R represents a benzene nucleus having a hydroxyl and a carboXyl group in orthoposition to each other and wherein R represents a benzene or naphthalene nucleus which contains an amino group in para position with respect to the azo group and has a sulpho group in any other position, and treating the formed diazo compound with an alkaline agent,so as to produce, when its coupling power has disappeared, anew azo dyestuff containing probably besides the nitrogen being present in the azo groups, more nitrogen,
but not in form of a chromophoric group.
4. A process for the manufacture of mordant dyestuffs, which consists in diazotizing para-ammo-sulphobenzene-azosahcyhc acid and treating the formed diazo compound with an alkaline-agent, so as to produce, when its coupling power has d1sappeared, a new azo dyestuif containing probably besides the nitrogen being present in the azo groups,
more nitrogen, but not .in form of a chromophoric group;
5. Aproeess for the manufacture of mordantdyestuffs, which consists in diazotizing para-amino-sulpho-benzene-azosalicylic acid and treating the formed diazo compound with ammonia so as to produce, when its coupling power has disappeared, a new azo dyestuff containing probably besides the nitrogen being present in the azo groups more nitrogen, but not in form of a chromophoric group.
6.. As new articles of manufacture the here- 'in described mordant dyestuffs obtained by diazotizing an amino azo compound corresponding to the following formula:
R .N=N.R .NH
wherein R represents a benzene nucleus having a hydroxyl and a carboxyl group in ortho position to each other and wherein R represents a benzene or naphthalene nucleus having an amino group in para position with respect to the azo group and by treating the formed diazo compound with an alkaline agent, said dyestuffs constituting brown powders being in form' of their alkali metal salts soluble in water with brown colour, which solution on addition of caustic soda lye turns to brown red and from which solution an addition of diluted hydrochloric acid separates out brown-black flakes, said dyestuffs dissolving in concentrated sulphuric acid to a dark violetish brown to violet solution and dyeing chromium mordanted fibre fast mainly brown shades.
7. As new articles of manufacture the herein described mordant dyestuffs obtained by diazotizing an amino azo compound corresponding to the following formula:
wherein R represents a benzene nucleus having a hydroxyl and a carbonyl group in ortho position to each other and wherein R represents a benzene or naphthalene nucleus having an amino group in para position with respect to the azo group and having a negative salt forming group in any other position and by treating the formed diazo compound withan alkaline; agent; said dyestuffs constituting v 'brovvn powders being in form of their alkali inetal salts soluble .in Water with brown colour, '5 which solution on addition ofcaustic soda lye turns to brown red and from which solution an addition of diluted hydrochloric acid separates out brown-black flakeasaid dyestuffs V dissolving in concentrated sulphuric acid to 10 a dark violetish brownto violet solution and dyeingchromium mordantedfibre fast mainlybrown shades. V V a f I 8. :As asnew article of manufacture, the V. hereinydescribed mordant dye'stufi obtained by dia'zotizing para-amino-sulpho-benzene- .fazo-s'alicyclioacid and treating the formed diazo'compound with analka-line agent, said 1 dyestuff constituting a brovvn powder being inform of alkali metal salts solubleoin Water 'With'brown; colour, which 'solutionon addiaim ofcaustic soda lye turns to brownlred land from 'which solution. an addition of diluted hydrochloric acidseparates out brown- I -black'fiakes, said dyestfufidissolving in'con- 25 centrated sulphuric acidfltoi a dark violet bro'wn solutionand dyeing chromium 'mor-' 'dantedfibrefast brown shades.
' In witness Whreof I havehereunto signed my name this19t-h day of December, 1927. j H Y GEORGOSTERTAG.
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US1848650A true US1848650A (en) | 1932-03-08 |
Family
ID=3423263
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US1848650D Expired - Lifetime US1848650A (en) | of basel |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US1848650A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2688613A (en) * | 1950-10-18 | 1954-09-07 | Hoechst Ag | Azo-dyestuffs |
| US2690438A (en) * | 1950-10-18 | 1954-09-28 | Hoechst Ag | Azo-dyestuffs |
-
0
- US US1848650D patent/US1848650A/en not_active Expired - Lifetime
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2688613A (en) * | 1950-10-18 | 1954-09-07 | Hoechst Ag | Azo-dyestuffs |
| US2690438A (en) * | 1950-10-18 | 1954-09-28 | Hoechst Ag | Azo-dyestuffs |
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| US1647145A (en) | Boika | |
| US498982A (en) | Benfabriken | |
| US1114750A (en) | Yellow azo dye. |