US1847555A - Treatment of aluminum - Google Patents
Treatment of aluminum Download PDFInfo
- Publication number
- US1847555A US1847555A US516215A US51621531A US1847555A US 1847555 A US1847555 A US 1847555A US 516215 A US516215 A US 516215A US 51621531 A US51621531 A US 51621531A US 1847555 A US1847555 A US 1847555A
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- US
- United States
- Prior art keywords
- aluminum
- treatment
- gas
- inclusions
- dross
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B21/00—Obtaining aluminium
- C22B21/06—Obtaining aluminium refining
- C22B21/064—Obtaining aluminium refining using inert or reactive gases
Definitions
- the invention relates to a method of improving the internal structure and mechanical properties of aluminum and its alloys and the elimination from these metals of gases, 5 dross, oxide films, and other or similar inclusions.
- Aluminum as used herein and in the appended claims includes not only pure aluminum and aluminum in all grades of commercial purity but also aluminum base alloys containing more than about 50 per cent of aluminum.
- titanium chloride in gaseous form may be advantageously used to treat molten aluminum and remove therefrom the gases, oxide films, dross, and other properties than those of which such alloys chloride, and titanium tetrachloride, I pre Application filed February 16, 1931. Serial No. 518,215.
- any of these three compounds may, however, be usedand, under ordinary foundry conditions, none of them are injurious to the operator nor are they explosive or inflammable. Moreover, they do not injuriously react with the molten metal.
- the treatment of the metal with titanium chloride has a beneficial eflect even when the metalis cast under the most favorable commercial conditions and that if the metal treated with titanium chloride gas be allowed to solidify and be again remelted, the beneficial eflect caused by the treatment is not lost but is in some cases even accentuated.
- Titanium tetrachloride the preferred compound, is obtainable commercially as a liquid and is stable in this form up to about 136 centigrade as long as it is kept from free contact with the atmosphere.
- the preferred compound is obtainable commercially as a liquid and is stable in this form up to about 136 centigrade as long as it is kept from free contact with the atmosphere.
- the compound may be heated to about 136 centi- 7 grade in the immediate vicinity of the molten metal and the gaseous product allowed to bubble through the molten metal, the gas being carried beneath the surface of the metal by means of a tube formed from some heatresistant material.
- the amount of gas supplied, or the time of treatment is by no means critical since there is a gradual improvement which begins when the gas is first introduced into the molten metal and which ends when the metal. is substantially free from gas and undesirable inclusions.
- Test specimens cast from a heat of an are obtained by aluminum alloy containing 4 per cent of copper and lesser amounts of silicon and iron had, before treatment with titanium tetrachloride, a tensile strength of 29,800 pounds per square inch and an elongation of 9 per cent in 2 inches. After the heat had been treated for about 4 minutes with titanium tetrachloride gas, test specimens cast therefrom had a tensile strength of 31,800 pounds per square inch and an elongation of 10.5 per cent in 2 inches. Some of the treated metal was allowed to solidify and was then re melted, after which specimens cast therefrom had a tensile strength of 34,200 pounds per square inch and an elongation of 12 per cent in 2 inches.
- test specimens may not, and usually do not, contain large gas cavities or dross inclusions which may be present in larger castings.
- inclusions cause service failures in such castings and the removal of these inclusions is one of the major benefits of my invention.
- the beneficial efi'ect of treating'aluminum with titanium chloride as noted by an improvement in the physical properties of the aluminum is important, but other beneficial efiects, such as the production of aluminum products free from laminations. surface blisters, or segregated inclusions adequate in size to cause localized mechanical failure are other benefits of equal or greater importance which the practice of my invention.
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- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Manufacture And Refinement Of Metals (AREA)
Description
Patented Mar. 1, 1932 UNITED. STATES PATENT OFFICE.
FRANCIS O.'FRABY, .OF OAKMONT, PENNSYLVANIA, ALSSIGNOR TO ALUMINUM COM- PANY 01E AMERICA, 01 PITTSBURGH, PENNSYLVANIA; A. COBIOBATION 01' PENN- SYLVANIA TREATMENT OF ALUMINUM No Drawing.
The invention relates to a method of improving the internal structure and mechanical properties of aluminum and its alloys and the elimination from these metals of gases, 5 dross, oxide films, and other or similar inclusions. Aluminum as used herein and in the appended claims includes not only pure aluminum and aluminum in all grades of commercial purity but also aluminum base alloys containing more than about 50 per cent of aluminum.
It is known in the art that a number of causes contribute towards the development in aluminum'base alloys of lower mechanical are inherently capable. Chief among these causes are gases, dross, and oxide films, or mechanical inclusions held in solution or mechanical suspension beneath the surface of the molten metal. Likewise the presence of gas, dross, oxide film, and these mechanical inclusions causes defects in products fabricatedv from either aluminum or aluminum base alloys. These defects usually take the form of laminations, surface blisters, etc. and, in some cases at least, uneven grain size of the fabricated products has been attributed and traced tothe presence of gas, dross, oxide film, and other inclusions in the metal. Various fluxes and methods of treatment of themetal have been heretofore devised in attempts'to eliminate these defects. Of these fluxes, some have been ineffective, others have been attended by the generation of noxious gases and odors, others have been inflammable and explosive, while still others react with the molten metal to an injurious extent. Some of these fluxes have had a measure of success.
I have discovered that titanium chloride in gaseous form may be advantageously used to treat molten aluminum and remove therefrom the gases, oxide films, dross, and other properties than those of which such alloys chloride, and titanium tetrachloride, I pre Application filed February 16, 1931. Serial No. 518,215.
fer to use the tetrachloride because it is comparatively inexpensive. Any of these three compounds may, however, be usedand, under ordinary foundry conditions, none of them are injurious to the operator nor are they explosive or inflammable. Moreover, they do not injuriously react with the molten metal.
I have also discovered that the treatment of the metal with titanium chloride has a beneficial eflect even when the metalis cast under the most favorable commercial conditions and that if the metal treated with titanium chloride gas be allowed to solidify and be again remelted, the beneficial eflect caused by the treatment is not lost but is in some cases even accentuated.
Titanium tetrachloride, the preferred compound, is obtainable commercially as a liquid and is stable in this form up to about 136 centigrade as long as it is kept from free contact with the atmosphere. In treating molten aluminum with titanium tetrachloride, the
compound may be heated to about 136 centi- 7 grade in the immediate vicinity of the molten metal and the gaseous product allowed to bubble through the molten metal, the gas being carried beneath the surface of the metal by means of a tube formed from some heatresistant material. The amount of gas supplied, or the time of treatment, is by no means critical since there is a gradual improvement which begins when the gas is first introduced into the molten metal and which ends when the metal. is substantially free from gas and undesirable inclusions. We have obtained satisfactory results with a gas treatment of of 'treatment.- However, I'have found thatunder ordinary conditionsa treatment with the gas for a few minutessay 3 to 8 minutes-is entirely satisfactory.
Test specimens cast from a heat of an are obtained by aluminum alloy containing 4 per cent of copper and lesser amounts of silicon and iron had, before treatment with titanium tetrachloride, a tensile strength of 29,800 pounds per square inch and an elongation of 9 per cent in 2 inches. After the heat had been treated for about 4 minutes with titanium tetrachloride gas, test specimens cast therefrom had a tensile strength of 31,800 pounds per square inch and an elongation of 10.5 per cent in 2 inches. Some of the treated metal was allowed to solidify and was then re melted, after which specimens cast therefrom had a tensile strength of 34,200 pounds per square inch and an elongation of 12 per cent in 2 inches. The improvement in this case, while substantial, does not truly reflect the beneficial efiect produced since test specimens may not, and usually do not, contain large gas cavities or dross inclusions which may be present in larger castings. Such inclusions, however, cause service failures in such castings and the removal of these inclusions is one of the major benefits of my invention. The beneficial efi'ect of treating'aluminum with titanium chloride as noted by an improvement in the physical properties of the aluminum is important, but other beneficial efiects, such as the production of aluminum products free from laminations. surface blisters, or segregated inclusions suficient in size to cause localized mechanical failure are other benefits of equal or greater importance which the practice of my invention.
1 claim:
1. The method of removing gas, dross, oxide films, and other detrimental inclusions from aluminum consisting in contacting the molten metal with titanium tetrachloride in gaseous form.
The method of removing gas, dross, oxide films,and other detrimental inclusions from aluminum'consisting in contacting the molten metal with titanium chloride in gaseous form.
FRANCIS C. FRARY.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US516215A US1847555A (en) | 1931-02-16 | 1931-02-16 | Treatment of aluminum |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US516215A US1847555A (en) | 1931-02-16 | 1931-02-16 | Treatment of aluminum |
Publications (1)
Publication Number | Publication Date |
---|---|
US1847555A true US1847555A (en) | 1932-03-01 |
Family
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Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US516215A Expired - Lifetime US1847555A (en) | 1931-02-16 | 1931-02-16 | Treatment of aluminum |
Country Status (1)
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US (1) | US1847555A (en) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2707679A (en) * | 1951-01-04 | 1955-05-03 | Westinghouse Electric Corp | Methods of producing zirconium and titanium |
US2745735A (en) * | 1953-04-28 | 1956-05-15 | Kaiser Aluminium Chem Corp | Method of producing titanium |
US2779672A (en) * | 1953-10-30 | 1957-01-29 | Dow Chemical Co | Method of treating molten magnesium |
US2826489A (en) * | 1953-12-18 | 1958-03-11 | Nyby Bruk Ab | Method for the manufacture of gas-pure metals and alloys |
US3975187A (en) * | 1975-02-13 | 1976-08-17 | Reynolds Metals Company | Treatment of carbothermically produced aluminum |
-
1931
- 1931-02-16 US US516215A patent/US1847555A/en not_active Expired - Lifetime
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2707679A (en) * | 1951-01-04 | 1955-05-03 | Westinghouse Electric Corp | Methods of producing zirconium and titanium |
US2745735A (en) * | 1953-04-28 | 1956-05-15 | Kaiser Aluminium Chem Corp | Method of producing titanium |
US2779672A (en) * | 1953-10-30 | 1957-01-29 | Dow Chemical Co | Method of treating molten magnesium |
US2826489A (en) * | 1953-12-18 | 1958-03-11 | Nyby Bruk Ab | Method for the manufacture of gas-pure metals and alloys |
US3975187A (en) * | 1975-02-13 | 1976-08-17 | Reynolds Metals Company | Treatment of carbothermically produced aluminum |
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