US1839931A - Plating - Google Patents

Plating Download PDF

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Publication number
US1839931A
US1839931A US279617A US27961728A US1839931A US 1839931 A US1839931 A US 1839931A US 279617 A US279617 A US 279617A US 27961728 A US27961728 A US 27961728A US 1839931 A US1839931 A US 1839931A
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United States
Prior art keywords
zinc
cadmium
plating
bath
articles
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US279617A
Inventor
Joseph N Reppen
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bendix Brake Co
Original Assignee
Bendix Brake Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bendix Brake Co filed Critical Bendix Brake Co
Priority to US279617A priority Critical patent/US1839931A/en
Application granted granted Critical
Publication of US1839931A publication Critical patent/US1839931A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D3/00Electroplating: Baths therefor
    • C25D3/02Electroplating: Baths therefor from solutions
    • C25D3/56Electroplating: Baths therefor from solutions of alloys

Definitions

  • This invention relates to. the plating of metallic articles, especially for the purpose of rust-proofing, and has for an important object to provide a plated surface which is bright and pleasing Without requiringbufling or polishing.
  • the bright and pleasing color is secured by using a substantial proportion, but less than one-half, of zinc in the plating, together with another rust-proofing metal such as cadmium making up the balance of the rust-proof coating.
  • cadmium gives a firm and coherent coating, while the zinc adds materially to the brightness and is also much cheaper than cadmium I prefer to use approximately of zinc and 75% of cadmium.
  • the following may be used: 19 oz. potassium cyanide, 7 oz. cadniium oxide, 3 oz. zinc oxide, 2 oz. caustic soda, and 2 oz. ammonium chloride, per gallon of water.
  • This bath is used with anodes of metallic cadmium and metallic zinc, preferably approximately one-fourth of the anode surface being zinc and three-fourths being cadmium, although if desired an alloy of corresponding proportions of zinc and cadmium may be used for the anode.
  • the articles usually of steel plated in the above-described bath with the zinc-cadmiiim anodes, have an unusually bright and pleasing surface of much firmer texture than zinc alone, and of much better appearance than cadmium alone.
  • the bath is kept at the desired concentration during use by adding potassium cyanide and caustic soda as required, preferably to give about 6 oz. free cyanide and 5 oz. metal per gallon of bath.
  • That method of plating metallic articles which comprises immersing the articles in a 1928.
  • That method of plating metallic articles which comprises immersing the articles in a bath containing nineteen ounces of potassium cyanide, seven ounces cadmium oxide, three ounces zinc oxide,'two ounces caustic soda and two ouncesammonium chloride per gallon of water and plating with an anode containing zinc and cadmium in the proportions of seventy-five per cent cadmium and twentyfive per cent zinc.

Description

Patented Jan. 5, 1932 UNlTED STATES PATENT orrice JOSEPH N. REPPEN, OF SOUTH BEND, INDIANA, ASSIGNOR TO BENDIX BRAKE COMPANY,
OF SOUTH BEND, IN DIANA, A
CORPORATION OF ILLINOIS PLATING No Drawing. Application filed Kay 21,
This invention relates to. the plating of metallic articles, especially for the purpose of rust-proofing, and has for an important object to provide a plated surface which is bright and pleasing Without requiringbufling or polishing.
In one desirable manner of carrying out my invention, the bright and pleasing color is secured by using a substantial proportion, but less than one-half, of zinc in the plating, together with another rust-proofing metal such as cadmium making up the balance of the rust-proof coating. The cadmium gives a firm and coherent coating, while the zinc adds materially to the brightness and is also much cheaper than cadmium I prefer to use approximately of zinc and 75% of cadmium.
As one particular bath which may be used in carrying out my invention, the following may be used: 19 oz. potassium cyanide, 7 oz. cadniium oxide, 3 oz. zinc oxide, 2 oz. caustic soda, and 2 oz. ammonium chloride, per gallon of water. This bath is used with anodes of metallic cadmium and metallic zinc, preferably approximately one-fourth of the anode surface being zinc and three-fourths being cadmium, although if desired an alloy of corresponding proportions of zinc and cadmium may be used for the anode.
The articles, usually of steel plated in the above-described bath with the zinc-cadmiiim anodes, have an unusually bright and pleasing surface of much firmer texture than zinc alone, and of much better appearance than cadmium alone.
The bath is kept at the desired concentration during use by adding potassium cyanide and caustic soda as required, preferably to give about 6 oz. free cyanide and 5 oz. metal per gallon of bath.
While one particular bath and one particular proportion have been specifically described, it is not my intention to limit the scope of the invention by that description, or otherwise than by the terms of the appended claims.
I claim: I
1. That method of plating metallic articles which comprises immersing the articles in a 1928. Serial N0. 279,617.
bath containing a relatively large proportion of potassium cyanide, a salt of zinc, a salt of cadmium together with small quantities of ammonium chloride and sodium hydroxide, and plating with an anode containing zinc and said other metal, said anode containing approximately one-fourth of zinc.
2. That method of plating metallic articles which comprises immersing the articles in a bath containing nineteen ounces of potassium cyanide, seven ounces cadmium oxide, three ounces zinc oxide,'two ounces caustic soda and two ouncesammonium chloride per gallon of water and plating with an anode containing zinc and cadmium in the proportions of seventy-five per cent cadmium and twentyfive per cent zinc.
In testimony whereof, I have hereunto signed my name.
JOSEPH N. REPPEN.
US279617A 1928-05-21 1928-05-21 Plating Expired - Lifetime US1839931A (en)

Priority Applications (1)

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US279617A US1839931A (en) 1928-05-21 1928-05-21 Plating

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US279617A US1839931A (en) 1928-05-21 1928-05-21 Plating

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US1839931A true US1839931A (en) 1932-01-05

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US279617A Expired - Lifetime US1839931A (en) 1928-05-21 1928-05-21 Plating

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2484068A (en) * 1943-03-11 1949-10-11 Mallory & Co Inc P R Electrodeposition apparatus

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2484068A (en) * 1943-03-11 1949-10-11 Mallory & Co Inc P R Electrodeposition apparatus

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