US1838933A - Electrical treater having dry oil barrier supply - Google Patents

Electrical treater having dry oil barrier supply Download PDF

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Publication number
US1838933A
US1838933A US236090A US23609027A US1838933A US 1838933 A US1838933 A US 1838933A US 236090 A US236090 A US 236090A US 23609027 A US23609027 A US 23609027A US 1838933 A US1838933 A US 1838933A
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fluid
oil
electrode
treated
envelope
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US236090A
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Harmon F Fisher
Woelflin William
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PETROLEUM RECTIFYING Co
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PETROLEUM RECTIFYING CO
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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G33/00Dewatering or demulsification of hydrocarbon oils
    • C10G33/02Dewatering or demulsification of hydrocarbon oils with electrical or magnetic means

Definitions

  • This invention relates to electrical treaters of the characters designed for separating liquids or a solid and a liquid, and it relates particularly to a treater for efiiciently separating water and oil from emulsion.
  • a treater for efiiciently separating water and oil from emulsion.
  • the wet oil or the fluid to be treated is passed through the treating space immediately around the central electrode and treated oil or dry oil is passed through the treating oil around the wet oil to form a dielectric barrier given size, high field intensity electrode is greatly increased and also the commercial quality of the treated oil is improved when the circulation of oil through the shield is aided, augmented or entirely provided by some auxiliary means other than the high velocity of the wet oil jet.
  • One method of securing this auxiliary aid to the circulation of wet oil is to provide a second larger stream or jet of treated oil, surrounding the first or inside jet of wet oil.
  • This second outer nozzle is connected with a suitable dry oil or dielectric barrier supply source.
  • One of the objects of this invention is to provide an electrical treater of this character in which the fluid to be treated is carried throllgh the treating space by a dielectric medium.
  • a further object of theinvention is to provide an electrical treater in which the dielectric medium keeps the fluid to be treated in the proper part of the treating space.
  • a still further object of the invention is to provide a treater'in which the dielectric medium envelops the fluid to be treated.
  • Fig. 1 represents a-vertical cross-section through a preferred embodiment of the invention.
  • Fig. 2 is a cross-section taken on the line 2 2 of Fig. 1.
  • Fig. 3 is an enlarged section showing the nozzle of the invention.
  • the numeral 11 represents a tank having a d oil outlet 12 and a precipitate outlet 13. Supported from the top of the tank 11 is an insulator 14 which carries a spider 15, this spider 15 supporting a live or surrounding electrode 16 of the invention.
  • This surrounding electrode 16 is of annular cross-section and near the lower end thereof is provided with a throat 17. The portion of the electrode 16 below the throat 17 is provided in the form of an apron 18.
  • the barrier medium supply 27 is provided with a fitting 28 which surrounds the vertical leg 20 and which supports the nozzle 26.
  • the lower part of the fitting 28 is provided with a packing 30 which surrounds the vertical leg 20.
  • the transformer 32 has a secondary 33, one side of which is connected by a conductor 34 to the tank 11, in this manner being connected to the central electrode 22, and the other side of the secondary 33 is connected by a conductor 35 to the surrounding electrode 16, this conductor 35 passing through an insulation bushing 36.
  • the tank 11 is first filled with a dielectric barrier which may be dry or treated oil.
  • Fluid to be treated which is in this case emulsion
  • Fluid to be treated is directed into the space between the electrodes 16 and 22 by means of the vertical leg or nozzle 20.
  • an electric field is established in this space.
  • a dielectric medium. or barrier which is preferably a dry or treated oil, is supplied to the nozzle 26 and passes upward into the treating space around the wet oil.
  • the dielectric medium is preferably under a high pressure and issues from the nozzle 26 under considerable velocity, issuing therefrom, as indicated by arrows 4,0 in Fig. l.
  • the wet oil need not be under any considerable pres-' sure, since the action of the dielectric medium is to carry the wet oil through the treating space at the same time confining it to that area around the central electrode 22 which is the ortion of the field of highest potential gradient.
  • the dielectric medium in addition to carrying the wet oil through the field at a proper rate of speed, envelops it and confines it, as previously explained, to the proper treating field.
  • the in]ection of the dielectric medium into the throat 17 causes the dielectric barrier, which is in the tank 11, to circulate into the throat 17, as indicated by arrows 42.
  • the dielectric medium and the dielectric barrier prevent -hort-circuiting between the electrodes 16 and 22, and thus maintain the efficiency of the treater.
  • the elongated path provided by passing around the apron 18 assists materially in promoting the separation of suspended matter from the oil as shown and claimed in a copending application filed by Harmon F. Fisher, Serial No. 233,291.
  • the water particles gravitate to the bottom of the shell 11 and are withdrawn through the pipe 13, the ver dry oil passing to the top of the shell 11 and eing withdrawn through the pipe 12.
  • the rate of treatment is much greater than in a similar treater not having the dielectric medium supply means which supplies a dielectric medium for enveloping the wet oil and carrying it through the treating space.
  • An electrical treater comprisin an innor nozzle; a central electrode exten ing into said innner nozzle; means for supplying a fluid to be treated to said inner nozzle, said fluid being discharged therefrom immediately around said central elctrode; an outer nozzle adapted to discharge an envelope of dielectric medium, said envelope surrounding said fluid discharged from said inner nozzle; a surrounding electrode around said central electrode and around the streams of fluid and dielectric medium discharged from said nozzles; and means for impressing a potential difference between said central and said surrounding electrodes.
  • An electrical treater comprising: a central electrode; an inner nozzle electrically connected to said central electrode and adapted to discharge an envelope of fluid to be treated therearound; an outer nozzle adapted to discharge an envelope of dielectric medium, said envelope of dielectric medium surrounding said fluid discharged from said inner nozzle; a surrounding electrode around said central electrode and around the streams of fluid and dielectric medium discharged from said nozzles; and means for impressing a potential difference between said central and said surrounding electrodes.
  • a method of treating a fluid in an electric field formed between a central electrode and a surrounding electrode which method includes the steps of introducing an envelope of a dielectric medium into said field in spaced relationship with said surrounding electrode, said envelope being concentric with said central electrode; and introducing into said field between said envelope of dielectric medium and said central electrode a fluid to be treated.
  • A' method of treating a fluid in an electric field formed between a 'central electrode and a surrounding electrode which method includes the steps of introducing an envelove of a dielectric medium into said field at a relatively high velocity, said envelope being concentric with said central electrode; and introducing into said field between said envelope of dielectric medium and said central electrode a fluid to be treated, said fluid to be treated being introduced at a relatively lower velocity than said dielectric medium.
  • a method of treating an emulsion which includes thestep of introducing concentric streams of emulsion and a dielectric medium into an electric field at difi'erential pressures, the pressure on said dielectric medium being greater than the pressure on said emulsion.
  • a method of treating a fluid in an electric field formed in a treating space between a central electrode and a surrounding electrode open at its ends whereby said treating space is in communication with a surrounding liquid which method includes the steps of: introducing into said field in spaced relationship with said electrodes an envelope of a dielectric in a manner to draw a portion of said surrounding liquid into the outer portion of said treating space; and simultaneously introducing an envelope of said fluid immediately around said central electrode and between said central electrode and said envelope of dielectric.
  • a method of treating a fluid in an electric field formed between a central electrode and a surrounding electrode which method includes the steps of: introducing an envelope of the fluid to be treated immediately around set our hands at Los Angeles, California, this -1()th day of November, 1927.
  • a method of treating a fluid in an electric field between a central electrode and a surrounding electrode which provides walls converging in a given direction includes the steps of: introducing into I said field the-fluid to be treated in the form of a fluid envelope around said central electrode; and introducing into said field in said given direction an envelope of another material surrounding said envelope of said fluid to be treated, said envelope of said other material being introduced at such a point that said converging walls force it into confining relationship with said envelope of said fluid to be treated.
  • an electrode structure the combination of: a central electrode; an inner nozzle electrically connected to and surrounding

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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Physical Or Chemical Processes And Apparatus (AREA)

Description

29,1931. H. F. FISHER ET AL 1,338,933 ELECTRICAL THEATER HAVING IQRX OIL BARRIER SUPPLY Original Filed Nov. 28, 1927 f N $i s 20 2 M WV 4 M M v @QQ; M V as H 1 26 A 27 $4 l j \t' $1; i :l
[ML/EMTOJBS: Hmemow F." F7SHE/E WILL/HM OELFLl/Y,
I m/M Patented Dec. 29, 1931 UNITED STATES PATENT OFFICE HARMON F. FISHER AND WILLIAM WOELFLIN, OF LONG BEACH, CALIFORNIA, AS-
SIGN OBS T PETROLEUM RECTIFYING COMPANY OF CALIFORNIA, OF LOS'ANGELES, CALIFORNIA, A CORPORATION OF CALIFORNIA ELECTRICAL THEATER HAVING DRY OIL BARRIER SUPPLY Application filedNovember 28, 1927, Serial No. 236,090. Renewed September 4, 1931.
This invention relates to electrical treaters of the characters designed for separating liquids or a solid and a liquid, and it relates particularly to a treater for efiiciently separating water and oil from emulsion. n the co-pending application entitled Dehydrator with means for directing emulsion through a high intensity field, Serial No. 203,253, filed July 2, 1927 of Harmon F. Fisher, there is described a treater which provides a central high intensity electrode and an outer low intensity electrode. The wet oil or the fluid to be treated is passed through the treating space immediately around the central electrode and treated oil or dry oil is passed through the treating oil around the wet oil to form a dielectric barrier given size, high field intensity electrode is greatly increased and also the commercial quality of the treated oil is improved when the circulation of oil through the shield is aided, augmented or entirely provided by some auxiliary means other than the high velocity of the wet oil jet. One method of securing this auxiliary aid to the circulation of wet oil is to provide a second larger stream or jet of treated oil, surrounding the first or inside jet of wet oil. This may be accomplished by placing a second larger diameter nozzle concentric with the smaller wet oil nozzle and pointing directly into the throat of the surrounding electrode so that the outer enveloping jet of circulating oil is moving parallel with and in the same direction as the inner jet of wet oil. This second outer nozzle is connected with a suitable dry oil or dielectric barrier supply source. We have found that by this means the treating capacity of a given treater of this character can be increased from two to ten-fold the capacitv of the simple treater not having the auxiliary aid to circulate the wet oil.
One of the objects of this invention is to provide an electrical treater of this character in which the fluid to be treated is carried throllgh the treating space by a dielectric medium.
A further object of theinvention is to provide an electrical treater in which the dielectric medium keeps the fluid to be treated in the proper part of the treating space.
Further objects of the invention lie in our novel method of electrically treating a fluid by passing this fluid through a treating space in contact with a dielectric medium.
A still further object of the invention is to provide a treater'in which the dielectric medium envelops the fluid to be treated.
Other objects and advantages of the invention will be pointed out in the following description.
In the following description reference will be had to the accompanying drawings in which the invention is diagrammatically illustrated. In the drawings:
Fig. 1 represents a-vertical cross-section through a preferred embodiment of the invention.
Fig. 2 is a cross-section taken on the line 2 2 of Fig. 1. T
Fig. 3 is an enlarged section showing the nozzle of the invention.
Referring to the drawings in detail, the numeral 11 represents a tank having a d oil outlet 12 and a precipitate outlet 13. Supported from the top of the tank 11 is an insulator 14 which carries a spider 15, this spider 15 supporting a live or surrounding electrode 16 of the invention. This surrounding electrode 16 is of annular cross-section and near the lower end thereof is provided with a throat 17. The portion of the electrode 16 below the throat 17 is provided in the form of an apron 18.
Surrounding the vertical leg or nozzle 20 is an outer nozzle 26 which is in communication with a barrier medium supply 27. The barrier medium supply 27 is provided with a fitting 28 which surrounds the vertical leg 20 and which supports the nozzle 26. The lower part of the fitting 28 is provided with a packing 30 which surrounds the vertical leg 20.
An electric field is established between the surrounding and central electrodes 16 and 22 by means of a transformer or other current source indicated by the numeral 32. The transformer 32 has a secondary 33, one side of which is connected by a conductor 34 to the tank 11, in this manner being connected to the central electrode 22, and the other side of the secondary 33 is connected by a conductor 35 to the surrounding electrode 16, this conductor 35 passing through an insulation bushing 36.
In the operation of the invention the tank 11 is first filled with a dielectric barrier which may be dry or treated oil. Fluid to be treated, which is in this case emulsion, is directed into the space between the electrodes 16 and 22 by means of the vertical leg or nozzle 20. Previous to this time, an electric field is established in this space. Simultaneously with the supplying of emulsion to the treating space, a dielectric medium. or barrier, which is preferably a dry or treated oil, is supplied to the nozzle 26 and passes upward into the treating space around the wet oil. The dielectric medium is preferably under a high pressure and issues from the nozzle 26 under considerable velocity, issuing therefrom, as indicated by arrows 4,0 in Fig. l. The wet oil need not be under any considerable pres-' sure, since the action of the dielectric medium is to carry the wet oil through the treating space at the same time confining it to that area around the central electrode 22 which is the ortion of the field of highest potential gradient. The dielectric medium, in addition to carrying the wet oil through the field at a proper rate of speed, envelops it and confines it, as previously explained, to the proper treating field. The in]ection of the dielectric medium into the throat 17 causes the dielectric barrier, which is in the tank 11, to circulate into the throat 17, as indicated by arrows 42. The dielectric medium and the dielectric barrier prevent -hort-circuiting between the electrodes 16 and 22, and thus maintain the efficiency of the treater. The entire mass of treated emulsion or treated wet oil, together with the dielectric medium and dielectric barrier, pass from the upper end of the treating space, as indicated by arrows 43, and pass downward around the apron 18 and pass into the throat 17 in the form of a dielectric barrier. The elongated path provided by passing around the apron 18 assists materially in promoting the separation of suspended matter from the oil as shown and claimed in a copending application filed by Harmon F. Fisher, Serial No. 233,291. The water particles, of course, gravitate to the bottom of the shell 11 and are withdrawn through the pipe 13, the ver dry oil passing to the top of the shell 11 and eing withdrawn through the pipe 12.
In this invention the rate of treatment is much greater than in a similar treater not having the dielectric medium supply means which supplies a dielectric medium for enveloping the wet oil and carrying it through the treating space.
We claim as our invention:
1. An electrical treater comprisin an innor nozzle; a central electrode exten ing into said innner nozzle; means for supplying a fluid to be treated to said inner nozzle, said fluid being discharged therefrom immediately around said central elctrode; an outer nozzle adapted to discharge an envelope of dielectric medium, said envelope surrounding said fluid discharged from said inner nozzle; a surrounding electrode around said central electrode and around the streams of fluid and dielectric medium discharged from said nozzles; and means for impressing a potential difference between said central and said surrounding electrodes.
2. An electrical treater comprising: a central electrode; an inner nozzle electrically connected to said central electrode and adapted to discharge an envelope of fluid to be treated therearound; an outer nozzle adapted to discharge an envelope of dielectric medium, said envelope of dielectric medium surrounding said fluid discharged from said inner nozzle; a surrounding electrode around said central electrode and around the streams of fluid and dielectric medium discharged from said nozzles; and means for impressing a potential difference between said central and said surrounding electrodes.
3. A method of treating a fluid in an electric field formed between a central electrode and a surrounding electrode, which method includes the steps of introducing an envelope of a dielectric medium into said field in spaced relationship with said surrounding electrode, said envelope being concentric with said central electrode; and introducing into said field between said envelope of dielectric medium and said central electrode a fluid to be treated.
4. "A' method of treating a fluid in an electric field formed between a 'central electrode and a surrounding electrode, which method includes the steps of introducing an envelove of a dielectric medium into said field at a relatively high velocity, said envelope being concentric with said central electrode; and introducing into said field between said envelope of dielectric medium and said central electrode a fluid to be treated, said fluid to be treated being introduced at a relatively lower velocity than said dielectric medium.
5. A method of treating an emulsion, which includes thestep of introducing concentric streams of emulsion and a dielectric medium into an electric field at difi'erential pressures, the pressure on said dielectric medium being greater than the pressure on said emulsion.
6. A method of treating a fluid in an electric field formed in a treating space between a central electrode and a surrounding electrode open at its ends whereby said treating space is in communication with a surrounding liquid, which method includes the steps of: introducing into said field in spaced relationship with said electrodes an envelope of a dielectric in a manner to draw a portion of said surrounding liquid into the outer portion of said treating space; and simultaneously introducing an envelope of said fluid immediately around said central electrode and between said central electrode and said envelope of dielectric.
7 A method of treating a fluid in an electric field formed between a central electrode and a surrounding electrode, which method includes the steps of: introducing an envelope of the fluid to be treated immediately around set our hands at Los Angeles, California, this -1()th day of November, 1927.
HARMON F. FISHER. WILLIAM WOELF LIN direction and with such velocity that said envelope of said fluid to be treated is maintained in contact with said central electrode by the confining action of said envelope of other material during a material length of the time in which it is influenced by said electric field. v
8. A method of treating a fluid in an electric field between a central electrode and a surrounding electrode which provides walls converging in a given direction, which method includes the steps of: introducing into I said field the-fluid to be treated in the form of a fluid envelope around said central electrode; and introducing into said field in said given direction an envelope of another material surrounding said envelope of said fluid to be treated, said envelope of said other material being introduced at such a point that said converging walls force it into confining relationship with said envelope of said fluid to be treated.
9. In an electrode structure, the combination of: a central electrode; an inner nozzle electrically connected to and surrounding
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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2513386A (en) * 1940-03-27 1950-07-04 Petrolite Corp Electric treater
US4126537A (en) * 1977-07-15 1978-11-21 Combustion Engineering, Inc. Method and apparatus for separation of fluids with an electric field
US4204934A (en) * 1978-04-03 1980-05-27 Combustion Engineering, Inc. Process for application of electrostatic fields to mixing and separating fluids
RU2452551C1 (en) * 2010-11-09 2012-06-10 Федеральное государственное бюджетное образовательное учреждение высшего профессионального образования "Пензенский государственный университет" (ФГБОУ ВПО "Пензенский государственный университет") Device for separation water-oil emulsions in electric field

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2513386A (en) * 1940-03-27 1950-07-04 Petrolite Corp Electric treater
US4126537A (en) * 1977-07-15 1978-11-21 Combustion Engineering, Inc. Method and apparatus for separation of fluids with an electric field
US4204934A (en) * 1978-04-03 1980-05-27 Combustion Engineering, Inc. Process for application of electrostatic fields to mixing and separating fluids
RU2452551C1 (en) * 2010-11-09 2012-06-10 Федеральное государственное бюджетное образовательное учреждение высшего профессионального образования "Пензенский государственный университет" (ФГБОУ ВПО "Пензенский государственный университет") Device for separation water-oil emulsions in electric field

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