US1817205A - Process for producing solvents and emulsifying agents - Google Patents
Process for producing solvents and emulsifying agents Download PDFInfo
- Publication number
- US1817205A US1817205A US215764A US21576427A US1817205A US 1817205 A US1817205 A US 1817205A US 215764 A US215764 A US 215764A US 21576427 A US21576427 A US 21576427A US 1817205 A US1817205 A US 1817205A
- Authority
- US
- United States
- Prior art keywords
- emulsifying agents
- water
- parts
- benzyl alcohol
- solvents
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000002904 solvent Substances 0.000 title description 6
- 239000003995 emulsifying agent Substances 0.000 title description 4
- 238000000034 method Methods 0.000 title description 2
- WVDDGKGOMKODPV-UHFFFAOYSA-N Benzyl alcohol Chemical compound OCC1=CC=CC=C1 WVDDGKGOMKODPV-UHFFFAOYSA-N 0.000 description 18
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
- 235000019445 benzyl alcohol Nutrition 0.000 description 6
- -1 aliphatic alcohols Chemical class 0.000 description 3
- 229930195733 hydrocarbon Natural products 0.000 description 3
- 159000000000 sodium salts Chemical class 0.000 description 3
- ZTFYJIXFKGPCHV-UHFFFAOYSA-N 2-propan-2-ylnaphthalene-1-sulfonic acid Chemical compound C1=CC=CC2=C(S(O)(=O)=O)C(C(C)C)=CC=C21 ZTFYJIXFKGPCHV-UHFFFAOYSA-N 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- 239000000839 emulsion Substances 0.000 description 2
- 239000003925 fat Substances 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 235000019645 odor Nutrition 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 239000000344 soap Substances 0.000 description 2
- BMRVLXHIZWDOOK-UHFFFAOYSA-N 2-butylnaphthalene-1-sulfonic acid Chemical compound C1=CC=CC2=C(S(O)(=O)=O)C(CCCC)=CC=C21 BMRVLXHIZWDOOK-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- RGCKGOZRHPZPFP-UHFFFAOYSA-N alizarin Chemical compound C1=CC=C2C(=O)C3=C(O)C(O)=CC=C3C(=O)C2=C1 RGCKGOZRHPZPFP-UHFFFAOYSA-N 0.000 description 1
- 150000001447 alkali salts Chemical class 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- ZZUFCTLCJUWOSV-UHFFFAOYSA-N furosemide Chemical compound C1=C(Cl)C(S(=O)(=O)N)=CC(C(O)=O)=C1NCC1=CC=CO1 ZZUFCTLCJUWOSV-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000009965 odorless effect Effects 0.000 description 1
- WVDDGKGOMKODPV-ZQBYOMGUSA-N phenyl(114C)methanol Chemical compound O[14CH2]C1=CC=CC=C1 WVDDGKGOMKODPV-ZQBYOMGUSA-N 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 235000007586 terpenes Nutrition 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K23/00—Use of substances as emulsifying, wetting, dispersing, or foam-producing agents
- C09K23/017—Mixtures of compounds
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S516/00—Colloid systems and wetting agents; subcombinations thereof; processes of
- Y10S516/01—Wetting, emulsifying, dispersing, or stabilizing agents
- Y10S516/03—Organic sulfoxy compound containing
Definitions
- Benzyl alcohol and mixtures of benzyl alcohol with ordinary or chlorinated solvent naphtha have proved particularly suitable for the purpose in view.
- Benzyl alcohol has a distinctive character as compared with the alcohols of high molecular weight. which are insoluble in water, such as cyclohexanol amyl alcohol terpene alcohols, since it possesses particular technical advantages, which make it "especially suitable for the purpose in question.
- sodium salt of isopropyl-naphthalene sulfonic acid in the proportion of about 14 parts of benzyl alcohol to 25 parts of the sodium salt.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Description
Patented Aug. 4, 1931 UNITED STATES.
FRIEDRICH POSPIECH,
PATENT OFFICE OF D'RESDEN, GERMANY, ASSIGNOR TO OHEMISCHE FABRIK POTT & 00., OF DRESDEN, GERMANY rnocnss FOR PRODUCING sonvnn'rs AND EMuLsIFYIive Aenn'rs no Drawing. Application filed August 26, 1927, Serial No. 215,764,;nd in Germany February 25, 1926.
Numerous processes have. already been proposed for the production of solvents and emulsifying agents for liquid and solid substances which are themselves insoluble in Water, such as for instance oils, fats, mineral oils, hydrocarbons, waxes and the like.
In addition to the means such as soap and Turkey red oil T which have been used for some time, cyciohexanol or its homologues by themselves'or in combination with hydro: carbons has been converted for instance for this purpose into a form soluble in water by means of soaps. v
It has been found, that particularly good results are obtained, if aromatic or aliphatic alcohols, which are diflicultly soluble or 111-.
soluble in water, are treated, either by themselves or in combination with hydrocarbons, with the alkali salts of aromatic. or hydroaromatic hydrocarbon sulfonic acids or their derivatives as well as also with the corresponding free acids.
Benzyl alcohol and mixtures of benzyl alcohol with ordinary or chlorinated solvent naphtha have proved particularly suitable for the purpose in view.
Benzyl alcohol has a distinctive character as compared with the alcohols of high molecular weight. which are insoluble in water, such as cyclohexanol amyl alcohol terpene alcohols, since it possesses particular technical advantages, which make it "especially suitable for the purpose in question.
The surprising discovery has been made, that it does not affect the frothing capacity of the preparations obtained. It is this fact in particular, which is of pro-eminent importance for cleansing and emulsifying agents; In addition however, benzyl alcohol has the advantage, that it has only a. very slight odor. This fact is also important, because it is particularly desired in the industry to employ products which are as far 1 as possible odorless. as it is difficult to eliminate such odors from the treated textile materials, and inconveniences are thus caused to those dealing therewith.
In this manner productsare obtained,
h which can be used very effectively as solvents and emulsifying agents for fats of all kinds,
Ewamples 1. 15 parts of butyl naphthalene sulphonic acid are dissolved in parts of water, and 28 parts of solvent naphtha are added thereto. The resulting emulsion is converted by means of 8 parts'of normal butyl alcohol into a clear solution,which when mixed with or poured into a considerable amount of water yields finely dispersedv emulsions of the solvent.
2. 25 parts of the sodium salt of isopropylnaphthalene sulphonic acid are dissolved in through several non-homogeneous intermediary stages, a clear'homogeneous liquid is finally obtained, WhlCll when diluted with a considerable amount of water, yields clear solutions of benzyl alcohol, which are not even opalescent. As is well known benzyl alcohol dissolvesvery sparingly in water.
alone.
I cla1m 1'. As a new article ofmanufacture, an
sodium salt of isopropyl-naphthalene sulfonic acid in the proportion of about 14 parts of benzyl alcohol to 25 parts of the sodium salt.
FRIEDRICH POSPIECH.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE1817205X | 1926-02-25 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US1817205A true US1817205A (en) | 1931-08-04 |
Family
ID=7744556
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US215764A Expired - Lifetime US1817205A (en) | 1926-02-25 | 1927-08-26 | Process for producing solvents and emulsifying agents |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US1817205A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3040874A1 (en) * | 1980-10-30 | 1982-05-13 | Arthur Klink Gmbh, 7530 Pforzheim | Tooth sharpening unit for broach - has rim of cup-shaped grinding disc rotated about axis of nearly 90 deg. to broach axis |
-
1927
- 1927-08-26 US US215764A patent/US1817205A/en not_active Expired - Lifetime
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3040874A1 (en) * | 1980-10-30 | 1982-05-13 | Arthur Klink Gmbh, 7530 Pforzheim | Tooth sharpening unit for broach - has rim of cup-shaped grinding disc rotated about axis of nearly 90 deg. to broach axis |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US1817205A (en) | Process for producing solvents and emulsifying agents | |
| GB549386A (en) | Improvements in or relating to the manufacture of soap | |
| US2228598A (en) | Purification of hydrocarbon-sulphur dioxide-chlorine reaction products | |
| US2149661A (en) | Mineral oil sulphonates | |
| US2221933A (en) | Wetting composition | |
| US2227999A (en) | Sulphonation of coal tab distillates | |
| US2061601A (en) | Process of preparing alcohol-amine mineral oil sulphonates | |
| US1843316A (en) | Detergent | |
| US1903879A (en) | Manufacture of emulsifying and wetting-out agents | |
| US1696374A (en) | Manufacture of disperse systems | |
| US2178786A (en) | Purification of alkyl sulphates | |
| DE651879C (en) | Process for the production of condensation products from polyvinyl alcohol and carbonyl compounds | |
| US1853415A (en) | Wetting, cleaning and emulsifying agents | |
| US2111911A (en) | Process for preparing improved acid derivatives of hydrocarbon oils and products thereof | |
| US1596100A (en) | Process of scouring wool and other fibers and fabrics | |
| US1881861A (en) | Production of highly concentrated paraffin wax | |
| US1960828A (en) | Process of obtaining mineral oil sulphonates | |
| US1659782A (en) | Purification of petroleum oils for removal of sulphonated compounds | |
| US1757441A (en) | Cleansing and emulsifying agent | |
| GB650326A (en) | A continuous process for separating alcohols of high molecular weight from the soapsobtained in their preparation | |
| DE843256C (en) | Process for the preparation of alkylarylsulfonic acid pellets | |
| DE408514C (en) | Process for the production of benzoic acid | |
| DE514080C (en) | Process for the preparation of agents for increasing the wetting and emulsifying capacity of aqueous solutions | |
| GB274611A (en) | ||
| US1908376A (en) | Production of sulphonated products |