US1810828A - Method of carbonizing coal - Google Patents
Method of carbonizing coal Download PDFInfo
- Publication number
- US1810828A US1810828A US191877A US19187727A US1810828A US 1810828 A US1810828 A US 1810828A US 191877 A US191877 A US 191877A US 19187727 A US19187727 A US 19187727A US 1810828 A US1810828 A US 1810828A
- Authority
- US
- United States
- Prior art keywords
- coal
- retort
- volatiles
- heat
- carbonizing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000003245 coal Substances 0.000 title description 57
- 238000000034 method Methods 0.000 title description 11
- 238000010000 carbonizing Methods 0.000 title description 10
- 239000003039 volatile agent Substances 0.000 description 23
- 238000009835 boiling Methods 0.000 description 7
- 238000003763 carbonization Methods 0.000 description 6
- 239000002245 particle Substances 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 239000011449 brick Substances 0.000 description 2
- 238000002485 combustion reaction Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000000446 fuel Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 239000002802 bituminous coal Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000003575 carbonaceous material Substances 0.000 description 1
- 239000000571 coke Substances 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
- C10B7/00—Coke ovens with mechanical conveying means for the raw material inside the oven
- C10B7/10—Coke ovens with mechanical conveying means for the raw material inside the oven with conveyor-screws
Definitions
- My invention relates to low temperature carbonization of coal, that is, the treatment of bituminous coal or other coal or carbonaceous material rich in volatiles to drive of the Vvolatiles at a temperature not suiiiciently above the boiling points of the volatiles to cause these volatiles to be converted into permanent gas, and to leave the carbon of the coal free or nearly free from volatiles, the aim of the lower temperature carbonization process being the elimination of volatiles as condensable vapors and the production of char resembling coke and capable of use as a fuel either as it comes from the retort or compressed into briquettes.
- the lighter volatiles may be readily driven off more or less completely at a low temperature the higher temperature necessary to drive olf the volatiles of higher boiling point tends to break up the lighter volatiles into fixed gas. And as the coal is softened by continued heat its particles tend to stick together in a mass and to hold onto the volatiles of higher boiling points making it necessary to either use vhigher heat or to leave such volatiles in the char.
- Figure 1 is a central, vertical, longitudinal, sectional view of apparatus adapted for carrying out my invention
- Figure 2 is an end view of the apparatus shown in Figure l;
- Figure 3 is a vertical Cross Sectional View of F igure 1;
- Figure 4 is a detail view of the reversing gear
- Figure 5 is a diagrammatic view indicating the movement imparted to the screw conveyor
- Figure 6 is a fragmentary, longitudinal, sectional view of the retort showing vthe effect upon the body of coal the advancing movement of the screw conveyor, and
- Figure 7 is a similar viewv showing the effect of the reverse movement of the screw conveyor.
- FIG. 1 indicates a retort suitably supported at its ends in brickwork 2 and having inlet opening 3 for the coal to be carbonized at one end and outlet opening 4 at the other end for discharging the residue remaining after the volatiles, commonly known as char, have been driven off.
- a hopper 5 is connected with the inlet opening 3 and a pipe 6 leads downward from outlet 4 to a suitable receptacle (not shown).
- a top plate 7 Above t-he retort is a top plate 7, which with the brick-work 2 forms an enclosing chamber for the retort, this top plate being, if preferred, of brick continuous with the sides and ends of the chamber which while conveniently formed of brick may be of any heat resisting material.
- rlhe retort may be conveniently formed of iron or steel pipe one foot in diameter and about twenty feet long but need not be of any particular diameter or length provided only that its length is sufliciently greater than its diameter to provide for a considerable travel of the coal being treated.
- a manifold 9 for drawing oil:l the volatiles driven off from the coal by the heat of the retort. 10 indicates the means for heating the retort, here shownas a pipe leading from a suitable supply of fuel or gas and provided with suitable burners 11.
- a pipe 12 leads from the combustion chamber for escape of products of combustion to a stack (not shown) or to the atmosphere.
- a shaft 13 Centrally through the retort extends a shaft 13 supported at its ends in bearings 14 carried by suitable supports 15. On this shaft within the retort .is gerrie@ a screw conf veyor 16 having a diameter nearly thatvof the interior of the retort and so arranged that when rotated in one direction its vanes 17 will push the coal towards the discharge opening Lland rotated in the other direction will push it backward toward the inlet opening 3.
- a sprocket wheel 18 On one end of the shaft 13 is a sprocket wheel 18 which, through sprocket chain 19, is.driven by sprocket wheel 20 carried on shaft 21 which also carries gear 22, the teeth of which are engaged by fins 23 on reversing gear 24 mounted on shaft 25 driven by any suitable source of power.
- These iins 23 of this reversing gear are so arranged as to impart to the gear 22 and through it to sprocket wheel 20, sprocket wheel 18 and shaft 13 of the screw conveyor movement of rotation first in one direction through a predetermined arc, preferably less than. a complete rotation, and then in the other direction through an arc of considerably less than the arc of the first movement.
- tie coal is introduced from hopper 5 through inlet 3 and, the shaft 13 being rotated, is moved by the vanes 17 of the screw conveyor towards the discharge opening 4:.
- the coal is introduced in quantity only sufficient to fill the retort to materially less than full capacity, preferably only to fill it to about the level of the shaft 13, so as to leave ample space above the body of coal for the volatiles driven off to pass ofi' freely and to be drawn off by the pipes 8 and manifold 9.
- a further and important result of the alternate forward movement and rearward movement is that the actual movement of the body of coal within the retort and subjected to its heat being the sum of its forward and rearward movement may thus be several times the distance between the inlet and discharge openings, thus making it possible to secure in a retort of limited length the effective heat treatment which with continuous forward movement would require aretort of such great length that it would be iliicult to heat evenly through its length and difficult to keep in line.
- the process of carbonizing coal which comprises forming a body of coal in a stationary horizontal retort on the bottom thereof, in quantity insufficient to 'ill said retort so that there is a free space in said retort above said body of coal, carbonizing said body of coal in said retort while transferring said body of coal along said retort on said bottom by alternately advancing said body of coal along said retort a distance that is materially shorter than half the length of said retort and retracting said body of coal a distance that is less than the first said distance, heat being applied to said coal from the bottom of the retort during the carbonization.
- the process of carbonizing coal which comprises forming a body of coal in a stationary horizontal retort on the bottom thereof, in quantity insuflicient to fill said retort so that there is a free space in said retort above said body of coal, carbonizing said body of coal in said retort while transferring said body of coal along said retortton said bottom by alternately advancing said body of coal along said retort a distance that is materially shorter than half the length of said retort and retracting said body of coal a distance that is less than the first said distance so as to agitate the body of coal and open it up to facilitate the escape of volatiles into the space above it and to prevent the coal softened by the heat from adhering to the walls of the retort, heat being applied to said coal from the bottom of the retort during the carbonization.
- the process of carbonizing coal which comprises forming a body of coal in a stationary horizontal retort on the bottom thereof, in quantity insuiicient to till said retort so that there is a free space in said retort above said body of coal, carbonizing said body of coal in said retort While transferring said body of coal along said retort on said bottom by alternately advancing said body of coal along said retort a distance that is materially shorter than half the length of said retort and retracting said body of coal a distance that is less than the first said distance so that the aggregate distance travelled by any particular portion of the :body ot coal along the bottom of the retort exceeds the length of the retort.
Description
June 16, 1931. c. HAYES 1,810,828
METHOD OF CARBONIZING COAL Filed Hay 16. 1927 2 Sheets-Sheet l June 16, 1931. Q HAYES 1,810,828
METHOD OF CARBONIZING COAL Filed May l16. 1927 2 Sheets-Sheet 2 Patented June 16, 193i UNITED STATES PATENT ori-ICE CHARLES HAYES, 0F PARIS, FRANCE, ASSIGNOR TO COAL CARBONIZATION COMPANY, A. CORPORATION OF DELAWARE I METHOD OF CARBONIZING COAL Application led May 16,
My invention relates to low temperature carbonization of coal, that is, the treatment of bituminous coal or other coal or carbonaceous material rich in volatiles to drive of the Vvolatiles at a temperature not suiiiciently above the boiling points of the volatiles to cause these volatiles to be converted into permanent gas, and to leave the carbon of the coal free or nearly free from volatiles, the aim of the lower temperature carbonization process being the elimination of volatiles as condensable vapors and the production of char resembling coke and capable of use as a fuel either as it comes from the retort or compressed into briquettes.
While the lighter volatiles may be readily driven off more or less completely at a low temperature the higher temperature necessary to drive olf the volatiles of higher boiling point tends to break up the lighter volatiles into fixed gas. And as the coal is softened by continued heat its particles tend to stick together in a mass and to hold onto the volatiles of higher boiling points making it necessary to either use vhigher heat or to leave such volatiles in the char.
I have discovered that by agitating the coal, opening it up to provide free escape for volatiles and drawing oif the volatiles as formed I am able to extract the volatiles, including those of relatively high boiling points to a nearly complete extent without the use of heat high enough to cause the lighter volatiles to be converted into gas.
With this object in view my invention consists in the method hereinafter described and claimed.
Referring to the drawings which are illustrative only of apparatus adapted to carry out my method and are not intended to restrict the invention to the use of the apparatus shown and described or to any particular apparatus.
Figure 1 is a central, vertical, longitudinal, sectional view of apparatus adapted for carrying out my invention;
Figure 2 is an end view of the apparatus shown in Figure l;
Figure 3 is a vertical Cross Sectional View of F igure 1;
1927. Serial No; 191,877.
Figure 4 is a detail view of the reversing gear;
Figure 5 is a diagrammatic view indicating the movement imparted to the screw conveyor;
Figure 6 is a fragmentary, longitudinal, sectional view of the retort showing vthe effect upon the body of coal the advancing movement of the screw conveyor, and
Figure 7 is a similar viewv showing the effect of the reverse movement of the screw conveyor.
In the drawings 1 indicates a retort suitably supported at its ends in brickwork 2 and having inlet opening 3 for the coal to be carbonized at one end and outlet opening 4 at the other end for discharging the residue remaining after the volatiles, commonly known as char, have been driven off. A hopper 5 is connected with the inlet opening 3 and a pipe 6 leads downward from outlet 4 to a suitable receptacle (not shown). Above t-he retort is a top plate 7, which with the brick-work 2 forms an enclosing chamber for the retort, this top plate being, if preferred, of brick continuous with the sides and ends of the chamber which while conveniently formed of brick may be of any heat resisting material.
rlhe retort may be conveniently formed of iron or steel pipe one foot in diameter and about twenty feet long but need not be of any particular diameter or length provided only that its length is sufliciently greater than its diameter to provide for a considerable travel of the coal being treated. From the upper part of the retort pipes 8 lead to a manifold 9 for drawing oil:l the volatiles driven off from the coal by the heat of the retort. 10 indicates the means for heating the retort, here shownas a pipe leading from a suitable supply of fuel or gas and provided with suitable burners 11. A pipe 12 leads from the combustion chamber for escape of products of combustion to a stack (not shown) or to the atmosphere.
Centrally through the retort extends a shaft 13 supported at its ends in bearings 14 carried by suitable supports 15. On this shaft within the retort .is gerrie@ a screw conf veyor 16 having a diameter nearly thatvof the interior of the retort and so arranged that when rotated in one direction its vanes 17 will push the coal towards the discharge opening Lland rotated in the other direction will push it backward toward the inlet opening 3.
On one end of the shaft 13 is a sprocket wheel 18 which, through sprocket chain 19, is.driven by sprocket wheel 20 carried on shaft 21 which also carries gear 22, the teeth of which are engaged by fins 23 on reversing gear 24 mounted on shaft 25 driven by any suitable source of power. These iins 23 of this reversing gear are so arranged as to impart to the gear 22 and through it to sprocket wheel 20, sprocket wheel 18 and shaft 13 of the screw conveyor movement of rotation first in one direction through a predetermined arc, preferably less than. a complete rotation, and then in the other direction through an arc of considerably less than the arc of the first movement.
In carrying out the method of my invention, the retort being heated to a temperature preferably from 350 C. t0'450 C., that is, within the temperature) commonl used in low temperature carbonization, tie coal is introduced from hopper 5 through inlet 3 and, the shaft 13 being rotated, is moved by the vanes 17 of the screw conveyor towards the discharge opening 4:. The coal is introduced in quantity only sufficient to fill the retort to materially less than full capacity, preferably only to fill it to about the level of the shaft 13, so as to leave ample space above the body of coal for the volatiles driven off to pass ofi' freely and to be drawn off by the pipes 8 and manifold 9. As the screw conveyor is rotated in a direction to advance the coal towards the outlet opening 4 it will cause the coal to pile up forward of the vanes 17 as indicated in Figure 6 and when rotated in the other direction, will cause the coal to be drawn back from the piles and to be piled up in rear of the vanes as indicated in Figure 7. The screw conveyor being rotated through a greater arc in the direction calculated to move the coal towards the discharge opening than in the reverse direction, the body of coal will be eventually moved to the discharge opening. The rotation of the screw conveyor in alternate direction tends to agitate the body of coal andtoturn or tumble the particles of coal over one another, to open up the body of coal so as to permit free escape of volatiles, and to bring all particles of the coal into contact with the heated walls of the retort. This alternate movement also prevents any of the coal softened by the heat of the retort from sticking tothe walls of the retort or other surfaces.
A further and important result of the alternate forward movement and rearward movement isthat the actual movement of the body of coal within the retort and subjected to its heat being the sum of its forward and rearward movement may thus be several times the distance between the inlet and discharge openings, thus making it possible to secure in a retort of limited length the effective heat treatment which with continuous forward movement would require aretort of such great length that it would be iliicult to heat evenly through its length and difficult to keep in line.
Thei retort being only about half filled with are driven off by the heat of the retort the coal i is softened and is reluctant to part with the volatiles of higher boiling point and unless the body of softened coal is agitated and opened up it is difficult to extract these volatiles without the use of excessive heat. By the vmovement above described this reluctance is overcome and the volatiles of higher boiling points may be extracted to any extent desired, provided, of course, that the temperature of the retort is as high as or slightly higher than the boiling points of the volatiles to be eliminated.
Having thus described my invention, what I claim is:
1. The process of carbonizing coal which comprises forming a body of coal in a stationary horizontal retort on the bottom thereof, in quantity insufficient to 'ill said retort so that there is a free space in said retort above said body of coal, carbonizing said body of coal in said retort while transferring said body of coal along said retort on said bottom by alternately advancing said body of coal along said retort a distance that is materially shorter than half the length of said retort and retracting said body of coal a distance that is less than the first said distance, heat being applied to said coal from the bottom of the retort during the carbonization.
2. The process of carbonizing coal which comprises forming a body of coal in a stationary horizontal retort on the bottom thereof, in quantity insuflicient to fill said retort so that there is a free space in said retort above said body of coal, carbonizing said body of coal in said retort while transferring said body of coal along said retortton said bottom by alternately advancing said body of coal along said retort a distance that is materially shorter than half the length of said retort and retracting said body of coal a distance that is less than the first said distance so as to agitate the body of coal and open it up to facilitate the escape of volatiles into the space above it and to prevent the coal softened by the heat from adhering to the walls of the retort, heat being applied to said coal from the bottom of the retort during the carbonization.
3. The process of carbonizing coal which comprises forming a body of coal in a stationary horizontal retort on the bottom thereof, in quantity insuiicient to till said retort so that there is a free space in said retort above said body of coal, carbonizing said body of coal in said retort While transferring said body of coal along said retort on said bottom by alternately advancing said body of coal along said retort a distance that is materially shorter than half the length of said retort and retracting said body of coal a distance that is less than the first said distance so that the aggregate distance travelled by any particular portion of the :body ot coal along the bottom of the retort exceeds the length of the retort.
In testimony whereof, I hereunto aix my signature.
CHARLES HAYES.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US191877A US1810828A (en) | 1927-05-16 | 1927-05-16 | Method of carbonizing coal |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
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US191877A US1810828A (en) | 1927-05-16 | 1927-05-16 | Method of carbonizing coal |
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US1810828A true US1810828A (en) | 1931-06-16 |
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US191877A Expired - Lifetime US1810828A (en) | 1927-05-16 | 1927-05-16 | Method of carbonizing coal |
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Cited By (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4094769A (en) * | 1977-06-13 | 1978-06-13 | Mineral Concentrates & Chemical Company, Inc. | Method and apparatus for retorting oil shale |
US4210491A (en) * | 1976-11-01 | 1980-07-01 | Tosco Corporation | Method and apparatus for retorting a substance containing organic matter |
EP0025319A1 (en) * | 1979-08-30 | 1981-03-18 | Pyro Conversion Incorporated | Method and apparatus for the removal of volatile substances from a starting material |
US4304609A (en) * | 1980-02-28 | 1981-12-08 | Morris James B N | Drill cuttings treatment apparatus and method |
US4453319A (en) * | 1980-02-28 | 1984-06-12 | Morris James B N | Aqueous drill cutting treatment apparatus and method |
US4584060A (en) * | 1983-10-15 | 1986-04-22 | Veba Oel Entwicklungs-Gesellschaft Mbh | Low temperature carbonization process for coal hydrogenation residues |
US20080149471A1 (en) * | 2006-12-26 | 2008-06-26 | Nucor Corporation | Pyrolyzer furnace apparatus and method for operation thereof |
US9045693B2 (en) | 2006-12-26 | 2015-06-02 | Nucor Corporation | Pyrolyzer furnace apparatus and method for operation thereof |
US20160215219A1 (en) * | 2015-01-22 | 2016-07-28 | Clean Energy Technology Association, Inc. | Cooler for carbon-based feedstock processing system |
US9446975B2 (en) | 2011-10-21 | 2016-09-20 | Therma-Flite, Inc. | Gasifying system and method |
EP3551725A4 (en) * | 2016-12-09 | 2020-07-15 | Keshi Technologies Pty Ltd | Hermetically sealed flow-through reactor for non-oxidative thermal degradation of a rubber containing waste |
EP3551724A4 (en) * | 2016-12-09 | 2020-08-19 | Keshi Technologies Pty Ltd | Process for the thermal degradation of rubber containing waste |
-
1927
- 1927-05-16 US US191877A patent/US1810828A/en not_active Expired - Lifetime
Cited By (19)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4210491A (en) * | 1976-11-01 | 1980-07-01 | Tosco Corporation | Method and apparatus for retorting a substance containing organic matter |
US4094769A (en) * | 1977-06-13 | 1978-06-13 | Mineral Concentrates & Chemical Company, Inc. | Method and apparatus for retorting oil shale |
EP0025319A1 (en) * | 1979-08-30 | 1981-03-18 | Pyro Conversion Incorporated | Method and apparatus for the removal of volatile substances from a starting material |
US4304609A (en) * | 1980-02-28 | 1981-12-08 | Morris James B N | Drill cuttings treatment apparatus and method |
US4453319A (en) * | 1980-02-28 | 1984-06-12 | Morris James B N | Aqueous drill cutting treatment apparatus and method |
US4584060A (en) * | 1983-10-15 | 1986-04-22 | Veba Oel Entwicklungs-Gesellschaft Mbh | Low temperature carbonization process for coal hydrogenation residues |
US9045693B2 (en) | 2006-12-26 | 2015-06-02 | Nucor Corporation | Pyrolyzer furnace apparatus and method for operation thereof |
US8444828B2 (en) | 2006-12-26 | 2013-05-21 | Nucor Corporation | Pyrolyzer furnace apparatus and method for operation thereof |
US20080149471A1 (en) * | 2006-12-26 | 2008-06-26 | Nucor Corporation | Pyrolyzer furnace apparatus and method for operation thereof |
US9446975B2 (en) | 2011-10-21 | 2016-09-20 | Therma-Flite, Inc. | Gasifying system and method |
US20160215219A1 (en) * | 2015-01-22 | 2016-07-28 | Clean Energy Technology Association, Inc. | Cooler for carbon-based feedstock processing system |
US10174257B2 (en) * | 2015-01-22 | 2019-01-08 | Clean Energy Technology Association, Inc. | Cooler for carbon-based feedstock processing system |
US10793778B2 (en) | 2015-01-22 | 2020-10-06 | Clean Energy Technology Association, Inc. | Cooler for carbon-based feedstock processing system |
EP3551725A4 (en) * | 2016-12-09 | 2020-07-15 | Keshi Technologies Pty Ltd | Hermetically sealed flow-through reactor for non-oxidative thermal degradation of a rubber containing waste |
EP3551724A4 (en) * | 2016-12-09 | 2020-08-19 | Keshi Technologies Pty Ltd | Process for the thermal degradation of rubber containing waste |
US11162030B2 (en) | 2016-12-09 | 2021-11-02 | Keshi Technologies Pty Ltd | Hermetically sealed flow-through reactor for non-oxidative thermal degradation of a rubber containing waste |
US11168259B2 (en) | 2016-12-09 | 2021-11-09 | Keshi Technologies Pty Ltd | Process for the thermal degradation of rubber containing waste |
US11591522B2 (en) | 2016-12-09 | 2023-02-28 | Keshi Technologies Pty Ltd | Process for the thermal degradation of rubber containing waste |
US11591521B2 (en) | 2016-12-09 | 2023-02-28 | Keshi Technologies Pty Ltd | Hermetically sealed flow-through reactor for non-oxidative thermal degradation of a rubber containing waste |
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