US176032A - Improvement in the manufacture of tin and other metal-coated plates - Google Patents

Improvement in the manufacture of tin and other metal-coated plates Download PDF

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US176032A
US176032A US176032DA US176032A US 176032 A US176032 A US 176032A US 176032D A US176032D A US 176032DA US 176032 A US176032 A US 176032A
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grease
plates
coating
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    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C2/00Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor

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  • Figure 1 is a plan
  • Fig. 2 is a trans verse section, of a first tinning or coatingmetal pot with its apparatus arranged according to my invention.
  • a is an annular pot. It is set in brick-work and heated by a furnace. bis a vertical axis, with a worm-wheel :upon it, driven by-a worm on an axis, 0. d d are arms on the axis b, supporting a circular frame, consisting of two sheet-iron cylinders, c c, to which are fixed a number of inclined partitions, ff. One of these partitions is shown separately at Figs. 3. I prefer to make them in cast-iron.
  • the hoops g g are fixed to the bottom edges of the partitions for the plate to rest upon. In this way an open frame is constructed, passing all around the pot, and divided over its entire circumference into cells, each suitable to receive a single plate.
  • More than one plate may be put in a cell; but it is not desirable to do so, for-by arranging the apparatus as shown and described accommodation is provided for a sufficientnumber of plates in the pot at one time. While the plates are kept entirely out of contact the one with the other, and are supported only at a few points by the ridges of the partitions, N g" g" are fixed bars, which are used whencoating with terne metal, to prevent the platesfioating to the surface of the metal.
  • Gone-pulleys may advantageously be provided for regulating the speed, so
  • the plates may be kept in the pot a suitable time for obtaining a complete coating.
  • the time is best adjusted from observation of the process, as it varieswith the heat of the metal and the surface and thickness of the plate in process of coating.
  • the sheets, wet as they-come from washing after pickling, (or it maybe, in some casesffrom a preparatory process of deposition of metal upon them from a solution, as is well understood,) are introduced into the metal through a flux.
  • Chloride of zinc may be-usedas a flux, if care is taken to prevent any trace of it remaining on the surface of the plate after it is removed from the coating-metal.
  • the plates are removed with tongs, and the workman takes care to keep the surface of the metal free from the chloride-of-zinc flux at this point. This care, however, is comparatively unnecessary when grease, or oily or fatty matter, is used as the flux.
  • I When I use grease, or oily or fatty matter, as a flux on the "surface of the coatingmetal, it is contained in a flux-box, as shown at Fig. 4,
  • This flux-box h is of a length to allow the plates to pass down readily through it, and I make it about fifteen inches wide, if I- am coating over the coating-metal.
  • the flux-box is open atthe bottom, and dips down into the molten metal in the pot. Its depth is such as to maintain about six inches of grease
  • There are guides within the flux-box to direct the plates as they are passed down through the grease into the cells of the rotating frame beneath, if cells are used in the first tinning or coating pot, as already described; and index-points are also, in this case, provided on this frame, to indicate to the workmen the arrival of each cell into position to receive a plate.
  • Around the top of the flux-box is a horizontal ledge, h, some inches wide, to give room for the froth forming on the grease to flow freely away.
  • a rim around the ledge except at one end or side of the flux-box, where a lip or outletpipe, 73, is formed, for the froth to flow or pass away and escape through into a cistern or other vessel, 70.
  • This vessel It may be about four times the capacity of the flux-box, with its froth-chamber. It contains a pump, l, which is driven continually by power. This pump draws the grease from the lower part'of the cistern, and returns it to the flux-box by a pipe, m, passing along it just over the surface of the grease which it contains.
  • the quantity of grease raised from the cistern by the pump is capable of regulation, so that it may keep up such a supply of suitable and sufficiently-solid grease in the flux-box as is desirable, while the outflow lip or channel of the flux-box carries away the froth as it is formed in the cistern, thus constantly recovering and righting the grease in the flux-box without unduly coolingit. Occasionally Iadd a little fresh grease to that in the cistern, to make up for loss-and waste. I i,
  • the froth In place of the froth being merely allowed to flow away through a lip or outlet-pipe, as above described, it may be drawn or carried away, as it is formed, by a revolving endless band with blades or buckets upon it, or by a revolving screw above the lip; or other suita ble arrangements may be adopted for constantly removing the froth and discharging it into a convenient receiver, and the froth, as it becomes sufficiently solid or righted, may be continuously pumped or otherwise mechanically passed back into the flux-box, and a supply of suitable and sufficiently-solid grease in the flux-box thus kept up.
  • the coating is not quite so readily effected as with tin, and the coating is facilitated, especially in this case, by passing tne plates into a separate grease-pot before introducing them into the first metal-pot.
  • the plates are introduced into the grease through a box. corresponding with the flux-box, already described, and similarly provided with an overflow or outlet.
  • the overflow or outlet to carry ofl the froth is, in this case, on a level with, or, by preference, slightly below, the grease in the pot, so that the froth may freely pass out, and the froth is received into a cistern to recover itself, as already described, and returned to the pot by a pump.
  • the heat of the grease in this pot is that of the grease in the first grease-pot, in the ordinary mode of tinning.
  • the plates, as they are taken out of this pot and passed into the flux-box of the first metal-pot, will carry over with them some of the grease, and to compensate for this the pump in the receiving-cistern is caused to return some or all of the grease which flows out of this flux-box into the preparatory grease-box.
  • the plates, as they are taken out of the first metal-pot, may be finished by brushing and dipping them, and passing them through rollers revolving in grease, or by other wellknown process.
  • the settling-vessel k in combination with mechanical means for returning, or withdrawing and returning, the flux to the flux-box, all substantially as and for the purpose set forth.

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Coating With Molten Metal (AREA)

Description

E. MOREWOOD. MANUFACTURE OF TIN AND OTHER METAL-COATED PLATES.
Patented April 11, 1876.
UNITED STATES PATENT OEErc EDMUND MOREWOOD, OF LLANELLY, GREAT BRITAIN.
IMPROVEMENT IN THE MANUFACTURE OF TIN AND OTHER METAL-COATED PLATES.
Specification forming part of Letters Patent No. 176,032, dated April 11, 1876; application fil January 21, 1876.
. To all whom it may concern:
- facture of Tin and other Coated Plates, of
which the following is a specification Hitherto, in the process of coating sheets or plates of iron with tin or terne metal, it has been customary to immerse several together in the first tinning or coating pot, and, in consequence, those parts of the iron plates which are fully exposed to the action of the melted coating-metal are longer in contact with it thanis necessary or desirable, and other parts, which press more or less against the surfaces of other plates, have only just, or perhaps scarcely, sufficient time to acquire their coatin g. Therefore I find it advantageous to cause every part of the surface of plates undergoing the process of coating to be in contact with the coating-metal while acquiring their coating. In order to accomplish this, and to give every part of the surface of each plate as short a length of time under the coating'metal as is consistent with giving them a sound coating, I arrange theframing in a round pot, so that each plate shall fall into its separate and allotted space or division, which travels so that each plate is carried round to the exit side of the bath, and contact with any other plate or surface is as much as possible avoided. Further, by this meansany flux or foreign matter has the opportunity of rising from the sur face of the plate to the top of the melted metal. When oil, grease, or fatty matter is used as a flux on the surface of melted coating-metal, the introduction of damp or wet sheets or plates of iron through it into the melted coating-metal causes it to boil up, and the oil, grease, or fatty matter becomes for some time afterward open and spongy, and in this state it does not suflicicutly or suitably take hold of and act upon the surface of the iron plate, so as to fit it for readily and properly taking or receiving the coating when the plate or sheet of iron becomes immersed in the melted coating-metal; and one of my improvements consists in so arranging the apparatus, machinery, or pots for coating-iron with other melted metal that I am enabledto pass damp .or wet plates or sheets to be coated through a flux of oil, grease, or fatty matter into the melted coating-metal while still maintaining sufiiciently non-porous greasy or oily or fatty matter on the surface of the melted metal at the point at which the plates enter into the coating-metal. This I do by keeping upa circulation of the grease by drawing off continually the grease which has becomefrothy or porous, and introducing moresolid non-porous grease. The frothy or porous grease is allowed to stand for a short time,.and is then fit to return to the surface vof thc-coating'metal. I immerse the plates so that they maylie or travel singly or a few togetherunder the coatin g metal, and be removed in rotation out of the melted coating-metal, in order that each plate may be immersed a shorter and more equal length of time in the melted coating-metal than in the old way; and I so arrange the said machinery, apparatus, or pots as to enable the oil, grease, or fatty matter to recover sufliciently from the open, spongy state into which it is thrown by the wet plates or sheets of iron being passed into it, so that the metalpot may be fed with a regular and steady succession of damp plates or sheets, and the oil or fatty matter on itszsurface kept in suitable condition, or the damp plates mayreceive their coating of grease in a first separate grease-pot made in I partitions, so that the plates maybe introduced and removed in'succession, and .kept as far as possible fromcontact with other plates or surfaces while under the grease.
In order that m ysai-dineention may be most fully understood and readily carried into effect, I will proceed to describe the drawings hereunto annexed.
Figure 1 is a plan, and Fig. 2 is a trans verse section, of a first tinning or coatingmetal pot with its apparatus arranged according to my invention.
a is an annular pot. It is set in brick-work and heated by a furnace. bis a vertical axis, with a worm-wheel :upon it, driven by-a worm on an axis, 0. d d are arms on the axis b, supporting a circular frame, consisting of two sheet-iron cylinders, c c, to which are fixed a number of inclined partitions, ff. One of these partitions is shown separately at Figs. 3. I prefer to make them in cast-iron. The hoops g g are fixed to the bottom edges of the partitions for the plate to rest upon. In this way an open frame is constructed, passing all around the pot, and divided over its entire circumference into cells, each suitable to receive a single plate. More than one plate may be put in a cell; but it is not desirable to do so, for-by arranging the apparatus as shown and described accommodation is provided for a sufficientnumber of plates in the pot at one time. While the plates are kept entirely out of contact the one with the other, and are supported only at a few points by the ridges of the partitions, N g" g" are fixed bars, which are used whencoating with terne metal, to prevent the platesfioating to the surface of the metal.
The axis bis driven at a speed of twelve revolutions in the hour, more or less, depending on the surface and gage of the iron plates in process of coating, a thin plate, as a rule, requiring less time in the-' coating-metal than a thicker one. Gone-pulleys may advantageously be provided for regulating the speed, so
' that the plates may be kept in the pot a suitable time for obtaining a complete coating. The time is best adjusted from observation of the process, as it varieswith the heat of the metal and the surface and thickness of the plate in process of coating.
Instead of machinery revolving, as here shown, horizontally, it is obvious that other machinery, revolving in other directions, such as vertically, may be employed, the same objects being kept inviewviz., that thepot is supplied witha regular andsteady supply of wet plates by a revolving frame or wheel, which delivers the plate on one side, and, after keeping it a regulated timeunder the melted metal, brings it over to the other side. I work with the melted coating-metal in this pot at aboutor slightly over the usual heat of the ordinary washmans pot. The sheets, wet as they-come from washing after pickling, (or it maybe, in some casesffrom a preparatory process of deposition of metal upon them from a solution, as is well understood,) are introduced into the metal through a flux. Chloride of zinc may be-usedas a flux, if care is taken to prevent any trace of it remaining on the surface of the plate after it is removed from the coating-metal. At the taking-out point, the plates are removed with tongs, and the workman takes care to keep the surface of the metal free from the chloride-of-zinc flux at this point. This care, however, is comparatively unnecessary when grease, or oily or fatty matter, is used as the flux. When I use grease, or oily or fatty matter, as a flux on the "surface of the coatingmetal, it is contained in a flux-box, as shown at Fig. 4,
fixed to the first coating or tinning pot. This flux-box h is of a length to allow the plates to pass down readily through it, and I make it about fifteen inches wide, if I- am coating over the coating-metal.
plates twenty by fourteen inches in size. The flux-box is open atthe bottom, and dips down into the molten metal in the pot. Its depth is such as to maintain about six inches of grease There are guides within the flux-box, to direct the plates as they are passed down through the grease into the cells of the rotating frame beneath, if cells are used in the first tinning or coating pot, as already described; and index-points are also, in this case, provided on this frame, to indicate to the workmen the arrival of each cell into position to receive a plate. Around the top of the flux-box is a horizontal ledge, h, some inches wide, to give room for the froth forming on the grease to flow freely away. There is a rim around the ledge, except at one end or side of the flux-box, where a lip or outletpipe, 73, is formed, for the froth to flow or pass away and escape through into a cistern or other vessel, 70. This vessel It may be about four times the capacity of the flux-box, with its froth-chamber. It contains a pump, l, which is driven continually by power. This pump draws the grease from the lower part'of the cistern, and returns it to the flux-box by a pipe, m, passing along it just over the surface of the grease which it contains. The quantity of grease raised from the cistern by the pump is capable of regulation, so that it may keep up such a supply of suitable and sufficiently-solid grease in the flux-box as is desirable, while the outflow lip or channel of the flux-box carries away the froth as it is formed in the cistern, thus constantly recovering and righting the grease in the flux-box without unduly coolingit. Occasionally Iadd a little fresh grease to that in the cistern, to make up for loss-and waste. I i,
In place of the froth being merely allowed to flow away through a lip or outlet-pipe, as above described, it may be drawn or carried away, as it is formed, by a revolving endless band with blades or buckets upon it, or by a revolving screw above the lip; or other suita ble arrangements may be adopted for constantly removing the froth and discharging it into a convenient receiver, and the froth, as it becomes sufficiently solid or righted, may be continuously pumped or otherwise mechanically passed back into the flux-box, and a supply of suitable and sufficiently-solid grease in the flux-box thus kept up. When the grease is used in this manner, the passage of the sheets to be coated through sufficicntly-solid, or rather homogeneous, grease into the molten metal is insured, and the grease will be found to act upon the surface of the plates passing through it, so as to cause the coating-metal to take very freely to the plates.
When terne metal is employed, the coating is not quite so readily effected as with tin, and the coating is facilitated, especially in this case, by passing tne plates into a separate grease-pot before introducing them into the first metal-pot. The plates are introduced into the grease through a box. corresponding with the flux-box, already described, and similarly provided with an overflow or outlet. The overflow or outlet to carry ofl the froth is, in this case, on a level with, or, by preference, slightly below, the grease in the pot, so that the froth may freely pass out, and the froth is received into a cistern to recover itself, as already described, and returned to the pot by a pump. The heat of the grease in this pot is that of the grease in the first grease-pot, in the ordinary mode of tinning. The plates, as they are taken out of this pot and passed into the flux-box of the first metal-pot, will carry over with them some of the grease, and to compensate for this the pump in the receiving-cistern is caused to return some or all of the grease which flows out of this flux-box into the preparatory grease-box.
The plates, as they are taken out of the first metal-pot, may be finished by brushing and dipping them, and passing them through rollers revolving in grease, or by other wellknown process.
Having thus described the nature of my invention and the manner of performing the same, I would have it understood that what I claim as my improvements in the manufacture of tin and terne plates is- 1. The annular pot a, vertical axis 1), arms d, and cylinders 6 e, in combination with the partitions f and fixed bars g" g", substantially as and for the purposes set forth.
2. The settling-vessel k, in combination with mechanical means for returning, or withdrawing and returning, the flux to the flux-box, all substantially as and for the purpose set forth.
EDMUND MOREWOOD.
Witnesses:
I. BEACON PHILLIPS,
Bank, Llanelly.
B. WILLIAMS, I
Servant to M1". B. Jones, Llanelly.
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2493769A (en) * 1944-07-08 1950-01-10 Horace C Knerr Machine for lead coating

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2493769A (en) * 1944-07-08 1950-01-10 Horace C Knerr Machine for lead coating

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