US1687118A - Manufacturing fuel gas - Google Patents

Manufacturing fuel gas Download PDF

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Publication number
US1687118A
US1687118A US665221A US66522123A US1687118A US 1687118 A US1687118 A US 1687118A US 665221 A US665221 A US 665221A US 66522123 A US66522123 A US 66522123A US 1687118 A US1687118 A US 1687118A
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Prior art keywords
coke
fuel
gas
air
fuel gas
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US665221A
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Winkler Fritz
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IG Farbenindustrie AG
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IG Farbenindustrie AG
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Priority to US275974A priority Critical patent/US1776876A/en
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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/46Gasification of granular or pulverulent flues in suspension
    • C10J3/48Apparatus; Plants
    • C10J3/482Gasifiers with stationary fluidised bed
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/09Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0913Carbonaceous raw material
    • C10J2300/093Coal
    • C10J2300/0936Coal fines for producing producer gas
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S48/00Gas: heating and illuminating
    • Y10S48/04Powdered fuel injection

Definitions

  • 'Fuel gas such as producer gas or blue water gas or mixed coal and water gas has hitherto usually been made from coke in coarse lumps by allowing steam and air,
  • Pulverulent coal has also been used for producing combustible gases, either in the form of a shower falling down in a current of air or by means of injection with the air.
  • small-sized carbonaceous material such as refuse coke, coke breeze, coke from lignite, and the like, in the form of grits and small pieces of pea size for making fuel as. g My invention.
  • small-sized coal or other carbonaceous' material can be utilized for making fuel gas and consists in charging the small coal material onto a suitable grate or support in a shaft generator, and blowing a gasifying medium, such as air or air and steam through the said coal material either alternately or jointly according to the'kind of fuel gas desired with sufficient pressure to bring about a strong agitation in the form of ,a so-to-say boiling motion of the material.
  • a gasifying medium such as air or air and steam
  • the blast of gas should not be so strong as to carry away the solid fuel and blow it out of the generator.
  • a free passage of the gases is secured and when the layer, or bed, of fuel is not too low the material is thoroughly mixed while its com bustion is not concentrated locally but well distributed throughout the whole mass, a uniform temperature being thereby established.
  • the ashes do not melt together. In many cases, particularly when using lignite, the ashes are carried along with the gases and can be deposited in an adjacent dust chamber.
  • incandescent coke made from lignite for example, coke the grains of which have a size of between and 10 millimetres
  • lignite for example, coke the grains of which have a size of between and 10 millimetres
  • 1000 cubic metres of air are then blown in per hour through the pipe D.
  • the glowing coke is at once agitated throughout so that the charge assumes an appearance similar to that of a boiling liq- 111d.-
  • the temperature of the coke rapidly ncreases and fresh coke made from lignite is suppl ed by the hopper G until the Bed of fuel n the generator A has a height of 150 centimetres.
  • Thls assists the cold coke in sinking down- 1n, and mixing with the mass of glowing fuel which is continuously maintained in the strongly agitated state above compared with a boilin liquid by the gases continuously flowing t rough the charge of the fuel.
  • the similarity of the charge of glowing fuel with a boiling liquid is in fact a very striking one. It may be demonstrated as follows: The body of the generator A is provided in its upper part with an observation window and with an opening about 20 centimetres in diameter which is arranged about 50 centimetresabove the upper level of the incandescentmass. in at D is now reduced to about 300 cubic metres per hour.
  • the slags formed sink down onto the grate similar to the lump of iron in the above described experiments.
  • the fine ashes of the lignite coke are for the most part carried away by the gas current and may be separated from the gases in any suitable manner after they have left the generator. It is characteristic of my invention that the entire bed of fuel is kept in continuous agitation by means of the gas current blown through the charge from below, whether this 1s air or steam or other gasifying medium, and that this state of continuous agitation is maintained merely by the gas current and without any mechanical means.
  • Lignite coke is placed in a cylindrical shaft generator'A, which is conically reduced at its bottom and there contains, as a grate,i. a perforated plate of fireclay B carrying a layer C of pieces of about two inches thickness of fireclay of about nut size.
  • the coke is ignited and air blown in from below through the inlet pipe D first at a moderate pressure, which gradually is raised until the particles. of coke commence to execute a vigorous Whlllll'lg movement so that the mass assumes an appearance of boiling.
  • the gases of combustion or air blast gases containing finally up to 30 per cent, by volume, of carbon monoxid and 2.
  • er cent of carbon dioxid take the light as es along, removing the greater part of the ashes from the gas generating chamber, and then are conveyed through a dust chamber where the ashes are caused to deposit.
  • This dust chamber may be of the usual form and requires no detailed description, and has also been omitted from the drawing.
  • a temperature of about 1100 degrees centigrade is reached, the supply of air is cut off and steam which is admitted through pipe E is blown through the incandescent coke at a similar pressure, or speed, to maintain .ing.
  • Fresh coke is supplied when necessar in a convenient manner from the hopper H is a discharge opening through which ashes may be removed if necessary.
  • Small sized lignite itself may be used instead of lignite coke, or small-sized coke or hard or soft coal.
  • incandescent solid carbonaceous material supported by a grate, consisting in blowing a gas adapted to produce fuel gas throu h said material with sufficient speed to esta lish a boiling action in the material, thereby causing gasification thereof by reaction between the incandescent material and the gas.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Solid Fuels And Fuel-Associated Substances (AREA)

Description

Oct. 9, 1928.
F. WINKLER MANUFACTURING FUEL GAS Filed Sept. 27, 1925 INVENTOR Fri Mink/er flTORNEYS Patented Oct. 9, 192a.
"UNlTED STATES FBITZ WINKLER, OF LUDWTGSHAFEN-ON-THE-RHINE, GERMANY, ASSIGNOR TO I. G.
FARBENINDUSTRIE AK 'TI ENGESELILSCHAFT, 0F
MANY, A'OOBPORATION OI GERMANY.
FRANKFORT-ON-THE-MAIN, GER- MANUI'AGTUBING FUEL GAS Application filed September 27, 1923, Serial No. 665,221, and in Germany September 27, 1922.
'Fuel gas, such as producer gas or blue water gas or mixed coal and water gas has hitherto usually been made from coke in coarse lumps by allowing steam and air,
either alternately or jointly, to react with the said coke, wh1ch is in an. incandescent state. Pulverulent coal has also been used for producing combustible gases, either in the form of a shower falling down in a current of air or by means of injection with the air. According to the usual methods of operation it has not been possible to use small-sized carbonaceous material, such as refuse coke, coke breeze, coke from lignite, and the like, in the form of grits and small pieces of pea size for making fuel as. g My invention. relates to an improved process whereby small-sized coal or other carbonaceous' material can be utilized for making fuel gas and consists in charging the small coal material onto a suitable grate or support in a shaft generator, and blowing a gasifying medium, such as air or air and steam through the said coal material either alternately or jointly according to the'kind of fuel gas desired with sufficient pressure to bring about a strong agitation in the form of ,a so-to-say boiling motion of the material. On the other hand the blast of gas should not be so strong as to carry away the solid fuel and blow it out of the generator. A free passage of the gases is secured and when the layer, or bed, of fuel is not too low the material is thoroughly mixed while its com bustion is not concentrated locally but well distributed throughout the whole mass, a uniform temperature being thereby established. The ashes do not melt together. In many cases, particularly when using lignite, the ashes are carried along with the gases and can be deposited in an adjacent dust chamber.
When the gas generator is .to be set into operation, about one cubic metre of incandescent coke made from lignite, for example, coke the grains of which have a size of between and 10 millimetres, is introduced by means of the hopper G onto the fire-clay layer C resting on the grate B of about one square metre area. 1000 cubic metres of air are then blown in per hour through the pipe D. The glowing coke is at once agitated throughout so that the charge assumes an appearance similar to that of a boiling liq- 111d.- The temperature of the coke rapidly ncreases and fresh coke made from lignite is suppl ed by the hopper G until the Bed of fuel n the generator A has a height of 150 centimetres. By the introduction of the fresh coke the temperature of the fuel bed falls, but uniform temperature throughout the whole mass of fuel is ver soon established, as can be determined a number of suitable thermostats or the li e arranged above the grate and Within the body of the generator A, This is due to the strong a itation of the mass and is also promoted by the higher weight per unit of volume of the cold coke made from lignite in comparison with the glowing coke. While one litre of the glowing coke has a weight of about 500 grams, one litre of the cold coke made from lignite has a weight of about 700 grams. Thls assists the cold coke in sinking down- 1n, and mixing with the mass of glowing fuel which is continuously maintained in the strongly agitated state above compared with a boilin liquid by the gases continuously flowing t rough the charge of the fuel. The similarity of the charge of glowing fuel with a boiling liquid is in fact a very striking one. It may be demonstrated as follows: The body of the generator A is provided in its upper part with an observation window and with an opening about 20 centimetres in diameter which is arranged about 50 centimetresabove the upper level of the incandescentmass. in at D is now reduced to about 300 cubic metres per hour. By means of the observation window it is now seen that the entire charge of coke is in a slightly undulating the charge of the incandescent fuel and the water vapor escaping from the moist woodthrows up a number of small coal particles similar to a fountain. After some minutes the Wood has become charred and now is carried upwards to the surface of the fuel The amount of air blown bed where the lump or lumps of charcoal now swim on the surface of the coke bed, just as wood "swims on water. When through the said opening above the char e of coke a current of air is blown in an o lique direction onto the surface of the charge,
the air current throws up waves just as would be the case with water. It will be obvious from these explanations that the charge of fuel in my generator has a very striking behaviour. Though it is continuously in motion and the single particles of fuel are continuously whirled up and down, the whole mass is rather compact, much more than would be the case for example, when allowing a fine powdery material to fall down in a stagnant or streaming mass of gas. Accordingly each particle of fuel is brought into intimate contact with the gas blownin from below, but not with so much gas that an undue removal of heat and dilution of the reaction product between the gas and the fuel would be caused. Owing to the intense agitation of the fuel particles, the entire charge of fuel has a very uniform temperature. The slags formed sink down onto the grate similar to the lump of iron in the above described experiments. The fine ashes of the lignite coke are for the most part carried away by the gas current and may be separated from the gases in any suitable manner after they have left the generator. It is characteristic of my invention that the entire bed of fuel is kept in continuous agitation by means of the gas current blown through the charge from below, whether this 1s air or steam or other gasifying medium, and that this state of continuous agitation is maintained merely by the gas current and without any mechanical means.
My invention will be more fully explained with reference to the annexed diagrammatical drawing showinga vertical section which explains the manufacture of blue water gas from lignite coke but the invention is not restricted to this example.
Lignite coke is placed in a cylindrical shaft generator'A, which is conically reduced at its bottom and there contains, as a grate,i. a perforated plate of fireclay B carrying a layer C of pieces of about two inches thickness of fireclay of about nut size. The coke is ignited and air blown in from below through the inlet pipe D first at a moderate pressure, which gradually is raised until the particles. of coke commence to execute a vigorous Whlllll'lg movement so that the mass assumes an appearance of boiling. The gases of combustion or air blast gases containing finally up to 30 per cent, by volume, of carbon monoxid and 2. er cent of carbon dioxid, take the light as es along, removing the greater part of the ashes from the gas generating chamber, and then are conveyed through a dust chamber where the ashes are caused to deposit. This dust chamber may be of the usual form and requires no detailed description, and has also been omitted from the drawing. When a temperature of about 1100 degrees centigrade is reached, the supply of air is cut off and steam which is admitted through pipe E is blown through the incandescent coke at a similar pressure, or speed, to maintain .ing. Fresh coke is supplied when necessar in a convenient manner from the hopper H is a discharge opening through which ashes may be removed if necessary. Small sized lignite itself may be used instead of lignite coke, or small-sized coke or hard or soft coal.
"I claim: 1. The process of manufacturing fuel gas in a generator having a bed of small-sized,
incandescent solid carbonaceous material supported by a grate, consisting in blowing a gas adapted to produce fuel gas throu h said material with sufficient speed to esta lish a boiling action in the material, thereby causing gasification thereof by reaction between the incandescent material and the gas.
2. The process of manufacturing fuel gas in a generator having a bed of small-sized, incandescent solid carbonaceous material,
supported by a grate, consisting in blowing air and steam through said material with sufficient speed to establish a boiling action in the material, thereby causing gasification thereof by reaction between the incandescent material and the air and steam.
In testimony whereof I have hereunto set my hand.
FRITZ VVINKLER.
US665221A 1922-09-27 1923-09-27 Manufacturing fuel gas Expired - Lifetime US1687118A (en)

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Cited By (27)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2436938A (en) * 1945-02-22 1948-03-02 Standard Oil Dev Co Method of producing motor fuel
US2445328A (en) * 1945-03-09 1948-07-20 Hydrocarbon Research Inc Conversion process for heavy hydrocarbons
US2482187A (en) * 1944-04-03 1949-09-20 Standard Oil Co Process for producing hydrogencarbon monoxide gas mixtures
US2498088A (en) * 1940-01-03 1950-02-21 Standard Oil Dev Co Conversion of hydrocarbons with suspended catalyst
US2503291A (en) * 1945-03-14 1950-04-11 William W Odell Process of promoting reactions in a fluidized bed comprising a plurality of catalysts
US2527197A (en) * 1945-02-17 1950-10-24 Standard Oil Dev Co Method of producing a carbon monoxide and hydrogen gas mixture from carbonaceous materials
US2538235A (en) * 1945-04-18 1951-01-16 Standard Oil Co Hydrogen manufacture
US2560403A (en) * 1944-04-03 1951-07-10 Standard Oil Co Method for processing carbonaceous solids
US2568660A (en) * 1942-07-16 1951-09-18 Rosen Raphael Fluorination process
US2579398A (en) * 1945-08-08 1951-12-18 Standard Oil Dev Co Method for handling fuels
US2579397A (en) * 1943-05-15 1951-12-18 Standard Oil Dev Co Method for handling fuels
US2588076A (en) * 1945-12-28 1952-03-04 Standard Oil Dev Co Method for gasifying fuels
US2605178A (en) * 1946-09-27 1952-07-29 Standard Oil Dev Co Preparation of gaseous fuel
US2614038A (en) * 1945-12-28 1952-10-14 Standard Oil Dev Co Production of sulfur free water gas
US2631934A (en) * 1946-04-03 1953-03-17 Standard Oil Dev Co Method of manufacturing a gas rich in carbon monoxide
US2682456A (en) * 1949-06-16 1954-06-29 Consolidation Coal Co Gasification of carbonaceous solid fuels
US2682457A (en) * 1949-06-16 1954-06-29 Consolidation Coal Co Gasification of carbonaceous solid fuels
US2682458A (en) * 1950-02-04 1954-06-29 Consolidation Coal Co Gasification of carbonaceous solids
US2776249A (en) * 1949-12-19 1957-01-01 Phillips Petroleum Co Process for conversion of reactant materials with the use of heated pebbles
US2817580A (en) * 1951-03-27 1957-12-24 North Thames Gas Board Process for purifying hydrogen sulphide containing hydrogen cyanide
DE971232C (en) * 1948-12-09 1959-01-29 Zieren Chemiebau Gmbh Dr A Process and device for roasting fine-grain sulfidic ores in the fluidized bed
US2971242A (en) * 1956-02-18 1961-02-14 British Rayon Res Ass Fluidised beds
DE974782C (en) * 1948-01-02 1961-04-27 Exxon Research Engineering Co Process for the production of gaseous or liquid fuels in connection with the production of a catalyst with high adsorption capacity
DE975892C (en) * 1951-03-23 1962-11-22 Metallgesellschaft Ag Device for roasting sulfidic ores
DE976145C (en) * 1951-03-23 1963-03-28 Metallgesellschaft Ag Device for roasting sulfidic ores
US3319586A (en) * 1961-07-10 1967-05-16 Dorr Oliver Inc Treatment and disposal of waste sludges
US3402021A (en) * 1964-11-30 1968-09-17 Kurashiki Rayon Co Fluidized process for producing carbon disulfide

Cited By (27)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2498088A (en) * 1940-01-03 1950-02-21 Standard Oil Dev Co Conversion of hydrocarbons with suspended catalyst
US2568660A (en) * 1942-07-16 1951-09-18 Rosen Raphael Fluorination process
US2579397A (en) * 1943-05-15 1951-12-18 Standard Oil Dev Co Method for handling fuels
US2482187A (en) * 1944-04-03 1949-09-20 Standard Oil Co Process for producing hydrogencarbon monoxide gas mixtures
US2560403A (en) * 1944-04-03 1951-07-10 Standard Oil Co Method for processing carbonaceous solids
US2527197A (en) * 1945-02-17 1950-10-24 Standard Oil Dev Co Method of producing a carbon monoxide and hydrogen gas mixture from carbonaceous materials
US2436938A (en) * 1945-02-22 1948-03-02 Standard Oil Dev Co Method of producing motor fuel
US2445328A (en) * 1945-03-09 1948-07-20 Hydrocarbon Research Inc Conversion process for heavy hydrocarbons
US2503291A (en) * 1945-03-14 1950-04-11 William W Odell Process of promoting reactions in a fluidized bed comprising a plurality of catalysts
US2538235A (en) * 1945-04-18 1951-01-16 Standard Oil Co Hydrogen manufacture
US2579398A (en) * 1945-08-08 1951-12-18 Standard Oil Dev Co Method for handling fuels
US2588076A (en) * 1945-12-28 1952-03-04 Standard Oil Dev Co Method for gasifying fuels
US2614038A (en) * 1945-12-28 1952-10-14 Standard Oil Dev Co Production of sulfur free water gas
US2631934A (en) * 1946-04-03 1953-03-17 Standard Oil Dev Co Method of manufacturing a gas rich in carbon monoxide
US2605178A (en) * 1946-09-27 1952-07-29 Standard Oil Dev Co Preparation of gaseous fuel
DE974782C (en) * 1948-01-02 1961-04-27 Exxon Research Engineering Co Process for the production of gaseous or liquid fuels in connection with the production of a catalyst with high adsorption capacity
DE971232C (en) * 1948-12-09 1959-01-29 Zieren Chemiebau Gmbh Dr A Process and device for roasting fine-grain sulfidic ores in the fluidized bed
US2682456A (en) * 1949-06-16 1954-06-29 Consolidation Coal Co Gasification of carbonaceous solid fuels
US2682457A (en) * 1949-06-16 1954-06-29 Consolidation Coal Co Gasification of carbonaceous solid fuels
US2776249A (en) * 1949-12-19 1957-01-01 Phillips Petroleum Co Process for conversion of reactant materials with the use of heated pebbles
US2682458A (en) * 1950-02-04 1954-06-29 Consolidation Coal Co Gasification of carbonaceous solids
DE975892C (en) * 1951-03-23 1962-11-22 Metallgesellschaft Ag Device for roasting sulfidic ores
DE976145C (en) * 1951-03-23 1963-03-28 Metallgesellschaft Ag Device for roasting sulfidic ores
US2817580A (en) * 1951-03-27 1957-12-24 North Thames Gas Board Process for purifying hydrogen sulphide containing hydrogen cyanide
US2971242A (en) * 1956-02-18 1961-02-14 British Rayon Res Ass Fluidised beds
US3319586A (en) * 1961-07-10 1967-05-16 Dorr Oliver Inc Treatment and disposal of waste sludges
US3402021A (en) * 1964-11-30 1968-09-17 Kurashiki Rayon Co Fluidized process for producing carbon disulfide

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