US1677508A - Art of dyeing fibers - Google Patents

Art of dyeing fibers Download PDF

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Publication number
US1677508A
US1677508A US43020A US4302025A US1677508A US 1677508 A US1677508 A US 1677508A US 43020 A US43020 A US 43020A US 4302025 A US4302025 A US 4302025A US 1677508 A US1677508 A US 1677508A
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United States
Prior art keywords
fibers
dyeing
art
iodide
iodine
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
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US43020A
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Winogradoff Alexander
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INECTO Inc
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INECTO Inc
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Priority to US43020A priority Critical patent/US1677508A/en
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Publication of US1677508A publication Critical patent/US1677508A/en
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Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
    • D06P3/02—Material containing basic nitrogen
    • D06P3/04—Material containing basic nitrogen containing amide groups
    • D06P3/30—Material containing basic nitrogen containing amide groups furs feathers, dead hair, furskins, pelts
    • D06P3/305—Material containing basic nitrogen containing amide groups furs feathers, dead hair, furskins, pelts with oxidation dyes
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S8/00—Bleaching and dyeing; fluid treatment and chemical modification of textiles and fibers
    • Y10S8/937—Li ion in dye bath

Definitions

  • My invention includes the use of iodine or any of its compounds capable of liberat ng iodine in an acid solution of the oxidizmg agent employed in connection with any proc- 5 ess of dyeing which depends upon the formation of dyestuif upon the fibers by combination of an oxidizing agent with a dye intermediate.
  • My invention is more particularly directed to an improvement in the art of dyeing fibers such as hair, fur, feathers and the like, with developing colors which are formed on the fibers by the action of an oxidizing agent such, for instance, as hydrogen peroxide, upon a dye leuco-compound such, for instance, as paraphenylene diamine.
  • an oxidizing agent such, for instance, as hydrogen peroxide
  • the speed of dyeing may be greatly increased and the uniformity of shade vastly improved without the use of objectionable salts or injurious oxidizing agents.
  • iodine containing materials for instance, potassium iodide, cadmium iodide or lithium iodide will permit of this increase of speed of dyeing.
  • the method of use may be either by mordanting the fibers in a preliminary bath, or by adding the iodine-containing material directly to the dye bath.
  • the fibers are soaked for fifteen minutes in a solution containing ten parts by weight Application filed July 11,
  • a process for dyeing fibers by developing the dye upon the fibers by oxidation of a dye leuco-compound in the presence of an iodine-containing material.

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Coloring (AREA)

Description

Patented July 17, 1928. I
' UNITED STATES 1 1,677,508 PATENT OFFICE.
ALEXANDER WINOGRADOEF, OF NEW YORK, N. Y., ASSIGNOR TO INECTO, INC., 01'
NEW YORK, N. Y., A CORPORATION OF DELAWARE.
ART OF DYEING FIBERS.
No Drawing.
My invention includes the use of iodine or any of its compounds capable of liberat ng iodine in an acid solution of the oxidizmg agent employed in connection with any proc- 5 ess of dyeing which depends upon the formation of dyestuif upon the fibers by combination of an oxidizing agent with a dye intermediate.
My invention is more particularly directed to an improvement in the art of dyeing fibers such as hair, fur, feathers and the like, with developing colors which are formed on the fibers by the action of an oxidizing agent such, for instance, as hydrogen peroxide, upon a dye leuco-compound such, for instance, as paraphenylene diamine.
- It has long been known that the speed of dyeing and the quality of the color produced in a developing bath may be greatly improved by the use of certain substances, such as heavy metal salts; for instance, copper acetate. The use of these metallic components is often objectionable for many reasons, particularly because of the injurious effect upon the hair texture. I do not wish to necessarily exclude the heavy metal salts but offer the iodide as an inoffensive alternate. An iodide of a heavy metal WOllld'bB capable of exerting a double effect partly due to the' iodide content and partly due to the heavy metal.
By my invention the speed of dyeing may be greatly increased and the uniformity of shade vastly improved without the use of objectionable salts or injurious oxidizing agents. I have found that the use of iodine containing materials, for instance, potassium iodide, cadmium iodide or lithium iodide will permit of this increase of speed of dyeing. The method of use may be either by mordanting the fibers in a preliminary bath, or by adding the iodine-containing material directly to the dye bath.
The mechanism of this action has not'been definitely determined but it is well known that iodides or iodine-containing materials act as catalysts in many types of reactions, and undoubtedly their role in this instance is likewise catalytic, because very smalldifference in speed of reaction.
Examples of the use of my invention are as follows:
The fibers are soaked for fifteen minutes in a solution containing ten parts by weight Application filed July 11,
amounts of iodide may cause a very great,
1925. Serial No. 43,020.
of cadmium iodide in one hundred parts of solution. The fibers are then washed with water and treated with the appropriate mixture of pharaphenylene diamine and hydrogen peroxide for from ten to fifteen minutes, depending upon the depth of shade desired. The fibers are then washed and dried.
.Another method would be to add an iodide to the dye bath containing a mixture of paraing an iodide to a solution of paraphenylene diamine and soaking the material to be dyed therein. The material is then washed and treated with an oxidizing agent, such as hydrogen peroxide, whereupon the color will be developed.
What I claim is 1. In the art of dyeing fibers, treating the fibers with a solution of an inorganic iodide where the color is developed by the oxidation of a leuco-compound.
2. In the art of dyeing fibers, treating the fibers with an oxidizing agent and a dye leuco-compound in the presence of a solution of .an iodine-containing material.
3. In the art of dyeing fibers, treating the fibers with an oxidizing agent and a dye leuco-compound in the presence of a solution of an iodide.
4, In the art of dyeing fibers, treating the fibers with an iodine-containing material capable of liberating iodine from an acid solution when treated with an oxidizing agent, in such a way as to promote the development of dyestufis formed by oxidation upon the fibers.
5. In the art of dyeing fibers, treating the fibers with an iodide in a solution, in such a way as to promote the development of a dyestufl upon the fibers by oxidation.
6. A'process for the rapid development of dye upon fibers, by oxidation of a dye leucocompound in the presence of an iodine-containing material.
- 7. A process for dyeing fibers by using an oxidizing agent and a dye leuco-compound, in conjunction with an iodine-containing material.
8. A process for dyeing fibers, by developing the dye upon the fibers by oxidation of a dye leuco-compound in the presence of an iodine-containing material.
' 9. A process for preparing fibers for dyeing with colors developed by oxidation, by impregnating the fibers With a solution-0f an iodine-containing material.
as my invention, I have signed my name this 9th day of July 1925. i DR. AL EXANDER WINOGRADOFF.
US43020A 1925-07-11 1925-07-11 Art of dyeing fibers Expired - Lifetime US1677508A (en)

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Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3701044A1 (en) * 1986-01-20 1987-07-23 Oreal Dyeing process for keratin fibres with 5,6-dihydroxyindole and hydrogen peroxide following or preceding a treatment with an iodide, and apparatus for use in said process
DE3739028A1 (en) * 1986-11-17 1988-05-19 Oreal METHOD FOR COLORING KERATINIC FIBERS WITH INDOLDER DERIVATIVES IN COMBINATION WITH AN IODIDE, AND MEANS AND DEVICE FOR USE IN THIS METHOD
FR2613221A1 (en) * 1987-04-02 1988-10-07 Oreal PROCESS FOR DYEING KERATINIC FIBERS WITH 5,6-DIHYDROXYINDOLE ASSOCIATED WITH IODIDE AND A HYDROGEN PEROXIDE COMPOSITION WITH ALKALINE PH
FR2615730A1 (en) * 1987-05-25 1988-12-02 Oreal PROCESS FOR DYEING KERATINIC FIBERS WITH COUPLERS AND / OR "FAST" OXIDATION DYES ASSOCIATED WITH IODIDE AND TINCTORIAL COMPOSITION IMPLEMENTED
US4992077A (en) * 1986-08-21 1991-02-12 Goldwell Gmbh Agent for the oxidative dyeing of hair, method for the preparation of the agent and use of the agent
US5006127A (en) * 1986-08-21 1991-04-09 Goldwell Gmbh Agent for the oxidative dyeing of hair, method for the preparation of the agent and use of the agent
US5180399A (en) * 1987-05-25 1993-01-19 L'oreal Process for dyeing keratinous fibres with oxidation bases combined with an iodide and dyeing composition employed
US5180397A (en) * 1987-05-25 1993-01-19 L'oreal Process for dyeing keratinous fibres with couplers and/or "rapid" oxidation dyes combined with an iodide and dyeing composition employed
US5180396A (en) * 1987-12-18 1993-01-19 L'oreal Process for dyeing keratinous fibres with oxidation dyes combined with indole derivatives and dyeing composition employed
US5540738A (en) * 1991-11-26 1996-07-30 Chan; Alexander C. Oxidative hair coloring composition and process for dyeing human keratinous fibers

Cited By (31)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3701026A1 (en) * 1986-01-20 1987-07-23 Oreal COLORING METHOD FOR CERATINAL FIBERS WITH 5,6-DIHYDROXYINDOL IN COMBINATION WITH AN IODIDE AND COLORING AGENTS USED THEREOF
US4808190A (en) * 1986-01-20 1989-02-28 L'oreal Process for dyeing keratinous fibres with 5,6-dihydroxy-indole and hydrogen peroxide, preceded or followed by a treatment with an iodide
DE3701044A1 (en) * 1986-01-20 1987-07-23 Oreal Dyeing process for keratin fibres with 5,6-dihydroxyindole and hydrogen peroxide following or preceding a treatment with an iodide, and apparatus for use in said process
US4804385A (en) * 1986-01-20 1989-02-14 L'oreal Process for dyeing keratinous fibres with 5,6-dihydroxy-indole combined with an iodide and dyeing composition employed
DE3701026C2 (en) * 1986-01-20 1998-03-12 Oreal Keratin fiber coloring method with 5,6-dihydroxyindole in combination with an iodide and kit for use in this method
DE3701044C2 (en) * 1986-01-20 1998-03-12 Oreal A method of coloring hair with 5,6-dihydroxyindole and hydrogen peroxide which is preceded or followed by treatment with an iodide and apparatus for use in said method
US5006127A (en) * 1986-08-21 1991-04-09 Goldwell Gmbh Agent for the oxidative dyeing of hair, method for the preparation of the agent and use of the agent
US4992077A (en) * 1986-08-21 1991-02-12 Goldwell Gmbh Agent for the oxidative dyeing of hair, method for the preparation of the agent and use of the agent
BE1000620A4 (en) * 1986-11-17 1989-02-21 Oreal PROCESS FOR DYEING KERATINIC FIBERS WITH INDOLE DERIVATIVES ASSOCIATED WITH IODIDE.
FR2606636A1 (en) * 1986-11-17 1988-05-20 Oreal PROCESS FOR DYING KERATIN FIBERS WITH INDOLE DERIVATIVES ASSOCIATED WITH IODIDE
DE3739028A1 (en) * 1986-11-17 1988-05-19 Oreal METHOD FOR COLORING KERATINIC FIBERS WITH INDOLDER DERIVATIVES IN COMBINATION WITH AN IODIDE, AND MEANS AND DEVICE FOR USE IN THIS METHOD
US4885006A (en) * 1986-11-17 1989-12-05 L'oreal Process for dyeing keratinous fibres with indole derivatives combined with an iodide
DE3811094A1 (en) * 1987-04-02 1988-10-13 Oreal METHOD FOR COLORING KERATINIC FIBERS WITH 5,6-DIHYDROXYINDOL IN COMBINATION WITH AN IODIDE AND A HYDROGEN PEROXIDE PREPARATION OF ALKALINE PH, AND DEVICE FOR USE IN THIS METHOD
GR880100217A (en) * 1987-04-02 1989-01-31 Oreal Preparation process for keratin fibres dyeing with the 5,6-dihydroxyindole associated with an iodide and with the peroxyde of hydrogen in ph alkaline
FR2613221A1 (en) * 1987-04-02 1988-10-07 Oreal PROCESS FOR DYEING KERATINIC FIBERS WITH 5,6-DIHYDROXYINDOLE ASSOCIATED WITH IODIDE AND A HYDROGEN PEROXIDE COMPOSITION WITH ALKALINE PH
BE1001200A3 (en) * 1987-04-02 1989-08-16 Oreal DYEING METHOD WITH KERATIN FIBRE 5,6-dihydro-XYINDOLE ASSOCIATED WITH AN IODIDE AND COMPOSITION OF HYDROGEN PEROXIDE PH ALKALINE.
US4888027A (en) * 1987-04-02 1989-12-19 L'oreal Process for dyeing keratinous fibers with 5,6-dihydroxyindole in combination with an iodide and a hydrogen peroxide composition at alkaline pH
GR880100346A (en) * 1987-05-25 1989-02-23 Oreal Preparation process for keratin fibres dyeing with oxydation basis associated with iodides dyeing composition and disposition therefor
US5180399A (en) * 1987-05-25 1993-01-19 L'oreal Process for dyeing keratinous fibres with oxidation bases combined with an iodide and dyeing composition employed
BE1001114A3 (en) * 1987-05-25 1989-07-18 Oreal PROCESS FOR DYEING KERATINIC FIBERS WITH '' FAST '' OXIDATION COUPLERS AND / OR DYES ASSOCIATED WITH IODIDE AND TINCTORIAL COMPOSITION IMPLEMENTED.
GR880100347A (en) * 1987-05-25 1989-02-23 Oreal Preparation process for keratin fibres with couplers and or dyeing substances of rapid oxydation associated with iodides and dyeing composition therefor
US4985955A (en) * 1987-05-25 1991-01-22 L'oreal Process for dyeing keratinous fibres with couplers and/or "rapid" oxidation dyes combined with an iodide and dyeing composition employed
DE3817710A1 (en) * 1987-05-25 1988-12-15 Oreal METHOD FOR COLORING KERATINIC FIBERS WITH CLUTCH MATERIALS AND / OR "FAST" OXIDATION DYES IN COMBINATION WITH AN IODIDE, USED COLORING AGENTS AND DEVICES
DE3817687A1 (en) * 1987-05-25 1988-12-15 Oreal METHOD FOR COLORING KERATINIC FIBERS WITH OXIDATION BASES IN COMBINATION WITH AN IODIDE, COLORING AGENT AND DEVICE
BE1001113A3 (en) * 1987-05-25 1989-07-18 Oreal Dyeing method with keratin fibre oxidation bases associated with a iodide, dyeing composition and device used.
US5180397A (en) * 1987-05-25 1993-01-19 L'oreal Process for dyeing keratinous fibres with couplers and/or "rapid" oxidation dyes combined with an iodide and dyeing composition employed
DE3817687C3 (en) * 1987-05-25 2001-11-29 Oreal Process for dyeing keratinic fibers with oxidation bases in combination with an iodide
FR2615730A1 (en) * 1987-05-25 1988-12-02 Oreal PROCESS FOR DYEING KERATINIC FIBERS WITH COUPLERS AND / OR "FAST" OXIDATION DYES ASSOCIATED WITH IODIDE AND TINCTORIAL COMPOSITION IMPLEMENTED
FR2615731A1 (en) * 1987-05-25 1988-12-02 Oreal PROCESS FOR DYING KERATINIC FIBERS WITH OXIDATION BASES ASSOCIATED WITH IODIDE, TINCTORIAL COMPOSITION AND DEVICE THEREFOR
US5180396A (en) * 1987-12-18 1993-01-19 L'oreal Process for dyeing keratinous fibres with oxidation dyes combined with indole derivatives and dyeing composition employed
US5540738A (en) * 1991-11-26 1996-07-30 Chan; Alexander C. Oxidative hair coloring composition and process for dyeing human keratinous fibers

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