US1591023A - Apparatus for coking coal - Google Patents
Apparatus for coking coal Download PDFInfo
- Publication number
- US1591023A US1591023A US628421A US62842123A US1591023A US 1591023 A US1591023 A US 1591023A US 628421 A US628421 A US 628421A US 62842123 A US62842123 A US 62842123A US 1591023 A US1591023 A US 1591023A
- Authority
- US
- United States
- Prior art keywords
- coal
- chamber
- retort
- gas
- gases
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000003245 coal Substances 0.000 title description 23
- 238000004939 coking Methods 0.000 title description 14
- 239000007789 gas Substances 0.000 description 32
- 238000004821 distillation Methods 0.000 description 13
- 239000000446 fuel Substances 0.000 description 11
- 238000002485 combustion reaction Methods 0.000 description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 10
- 239000000047 product Substances 0.000 description 9
- 239000000571 coke Substances 0.000 description 7
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 6
- 239000002641 tar oil Substances 0.000 description 5
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 3
- 229910002092 carbon dioxide Inorganic materials 0.000 description 3
- 239000001569 carbon dioxide Substances 0.000 description 3
- 229910002091 carbon monoxide Inorganic materials 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 239000002802 bituminous coal Substances 0.000 description 2
- 239000006227 byproduct Substances 0.000 description 2
- 238000009833 condensation Methods 0.000 description 2
- 230000005494 condensation Effects 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 238000005096 rolling process Methods 0.000 description 2
- 239000011269 tar Substances 0.000 description 2
- 238000013019 agitation Methods 0.000 description 1
- 238000010923 batch production Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000000284 extract Substances 0.000 description 1
- 239000002737 fuel gas Substances 0.000 description 1
- 238000002309 gasification Methods 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 206010022000 influenza Diseases 0.000 description 1
- 238000003780 insertion Methods 0.000 description 1
- 230000037431 insertion Effects 0.000 description 1
- 238000005304 joining Methods 0.000 description 1
- 239000003077 lignite Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000005192 partition Methods 0.000 description 1
- 239000003415 peat Substances 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
- C10B7/00—Coke ovens with mechanical conveying means for the raw material inside the oven
- C10B7/06—Coke ovens with mechanical conveying means for the raw material inside the oven with endless conveying devices
Definitions
- Our invention relates to the utilization of bituminous coal and similar fuel substances such as peat, lignite, and various intermediate by-products from the distillation of crude petroleum or coal.
- Another ob ect is the complete gasification of coal .w ere the volatile matter of the coal is distilled out of one zone by the sensible heat contained in the products of com- 'bustion from the discharge zone and the sensible heat of blue water gas made from the coke resulting fromv the primary distillation.
- Another object is the production of the tar oils classified as being low temperatured products of distillation, the characteristics of said tar oils being difierent from tar oils obtained in ordinary distillation processes involvin hi h temperatures.
- Another ob ect is to surround the moving grates with walls that can be heated either by drawing the products of distillation and combustion through them, or by heating them by the gases formed during the distilling processes thereby preventin the condensation of the tar vapors in the coking retort.
- Another object is the more economical use of the heat b carrying on all distillation processes uti 'zing the sensible heat of the gases roduced in the secondary zone by forcing t em through the fuel bed in the primar zone.
- Fig. 2 is a longitudinal section through one type of coking retort
- Fig. 6 is a horizontal section on line 6-6 of Fig. 5;
- Fig. 7 is a horizontal section on line 77 of Fig. 5;
- Fig. 8 is a plan view of the apparatus shown in Fig. 2;
- Fig. 9 is an end view from the coke end
- Fig. 10 is a detail section on line 10-10 of Fig. 3;
- Fig. 11 is a section similar to Fig. 2 of a modification.
- the chain grate 10 conveys a continuous stream of material, which will hereinafter be referred to as coal, from hopper 12 through the coking retort to discharge chute 14.
- a bafile wall 16 divides the space above the grate into two compartments 18 and 20.
- ro ler 21 receives its water supply through the hollow trunnions 22 upon which it is pivoted, and is of star-shaped cross section, so that its ribs 24 will gou e into the bed of fuel moving under the fol er as clearly indicated in Fig3 3.
- This provides a satisfactory air seal etween the two parts of the chamber, and with certain types of fuel, may be made use of to effect a desirable breaking up and agitation of the partially coked coal.
- the resulting gases at a high temperature can be transferred to chamber 18 by the use of an exhaust fan 40 and delivered through conduit 42 extending along both sides of the retort to sections 33 of the wind chest as shown in Figure 6.
- These hot gases containing practically no free oxygen are incapable of supporting combustion and have very low heat value.
- the distillation of the volatile hydrocarbons takes place and the lean low heat value gas from which the sensible heat has been extracted by the green fuel becomes mixed with the products of distillation from chamber 18 and. at certain critical temperatures part of the carbon dioxide is converted'into carbon monoxide.
- the resulting mixed gas is of'satisfactory quality to constitute a fuel gas of a type commonly referred to as producer gas, but-having considerably higher heating value because of the mixture of the high heat value gas resulting from the primary distillation.
- these gases pass through conduit 44, scrubber 46, conduit 48, exhauster 50, and conduit 52 to the gas holder 54, from which they may be withits passage through chamber20, it is sub-' ject to much more lively oxidation, and raised to a fairly high temperature.
- the resultant material entering chute 14 can be coke of very good quality, and much greater uniformity than can be obtained by any batch process.
- Combustion on the chain grate may or may not proceed to completion.
- part 56 functions as a mere ash receiver, while in the second the blue Water gas therefrom will pass back throu h chamber 20 to augment the mass of material and the sensible heat delivered to the green fuel in chamber 18 through conduit 36.
- the equipment illustrated in Fig. 2 includes power means for influencing the flow from chamber to chamber 18. It will be obvious, that under certain conditions of operation, fan 32 and exhauster may be relied upon to maintain the flow through the entire system, and the gases from chamber '20 may be taken through conduit (Fig. 11) devoid of any power means, to chamber 18. While we have illustrated a chain grate with the space beneath it divided by partition 72 to control the delivery of gases to chambers 20 and 18, it will be obvious that other equivalent con veyor means might be substituted.
- a coking retort, conveyormeans for movinla stream of coal 0 wall means di- I through said retort, ba viding. said retort into two parts, movable means having rolling contact with said stream of coal and forming the terminus of said baflle means to afiord a' tight seal, means for supplyi air to carry on combustion on one si of said baflle wall,
Description
July 6,1926. 1,591,023
M. W. DITTO ET AL APPARATUS FOR coKING COAL Filed March 1 23 8 sheets-sheet 1 afia/4 Fay m M. W. DITTO ET AL APPARATUS FOR COKING COAL Filed March 29, 1925 8 She ets She et 2 I cirwenfrb H H m W wmxwd w Mi July 6 1926. 1,591,023
. M. W. DITTO El AL APPARATUS FOR COKING COAL Filed March 29, 1923 8 s t ls 5 July 6,1926. 1,591,023
M. W. DITTO ET AL APPARATUS FOR COKING COAL Filed March 29, 1923 8 She et Lsh t 4 zb k . H 3 W Mb w w N I I n 1, 1 J 9 l 8 sheets she'et 5 Marvzn (U. U127? M. W. DITTO ET AL APPARATUS FOR coxme COAL F1 1ed March 29 1923 M M \y E wig;
I aw E July 6 1926.
- July 6, 1926. 1,591,023
M. W. DlTTO ET! AL APPARATUS FOR COKING COAL Filed March 29, 1923 8 Sheets-Sheet 6 I I a1 2/177 L a wfi ss as. ilfdliam M. Harman I ww;
- M. W. DlTTO ET AL APPARATUS FOR COKING GOAL Filed March 29, 1923 8 Sheets Shet' 7 Ji/M @77221642 {0 11 f: Marvin 11x zmw ii 11/211121: M. Uzmcar/ wmfimx July 6 1926. 1,591,023
M. w. DITTO ET AL APPARATUS FOR comm COAL Filed March 29, 1925 a Sheets Sheet 8.
/ 12/ Mrs,
Patented July 6, 1926.
UNITED STATES I PATENT OFFICE.
IABVIH W. DIT'I'O, 01 NEW YOIB'IK, N. Y., AND WILLIAM H. DUNOAlF, '01 ALTON,
. ILLDVOIS.
arrm'rus r03. ooxme con.
Application filed March 29, 1923. Serial No. 628,421.
Our invention relates to the utilization of bituminous coal and similar fuel substances such as peat, lignite, and various intermediate by-products from the distillation of crude petroleum or coal. V
Among other objects and advantages of the invention may be enumerated the following:
To completely gasify carbonaceous matter such as bituminous coal and save the byproducts.
To produce gas by primary distillation of coal utilizin the sensible heat of the gases of the partia combustion of the coal in one zone to supply heat for distilling the coal in a precedin zone of initial introduction.
Another ob ect is the complete gasification of coal .w ere the volatile matter of the coal is distilled out of one zone by the sensible heat contained in the products of com- 'bustion from the discharge zone and the sensible heat of blue water gas made from the coke resulting fromv the primary distillation.
Another object is to utilize the sensible heat of the blue water gas manufactured for the distillation in the primary zone.
Another object is to mix gases resulting from partial combustion of carbonaceous matter with gases resulting from primary distillation of coal with blue water gas manufactured from the residual coke.
Another object is the ability to operate the apparatus and roduee gas continuously of varying B. T. value at the same time saving the distillate tar oils without exposing them to high temperatures.
Another object is the production of the tar oils classified as being low temperatured products of distillation, the characteristics of said tar oils being difierent from tar oils obtained in ordinary distillation processes involvin hi h temperatures.
Another ob ect is to surround the moving grates with walls that can be heated either by drawing the products of distillation and combustion through them, or by heating them by the gases formed during the distilling processes thereby preventin the condensation of the tar vapors in the coking retort.
Another object is the more economical use of the heat b carrying on all distillation processes uti 'zing the sensible heat of the gases roduced in the secondary zone by forcing t em through the fuel bed in the primar zone.
Fl rt er objects and advantages of the invention will become apparent as the description proceeds.
In the accompanying drawings:-'
Figure 1 is a schematic diagram of a complete plant for producing water gas and producer gas according to our invention;
Fig. 2 is a longitudinal section through one type of coking retort;
Fig. 3 is an enlarged detail section of the seal ng means;
Figs. 4 and 5 are transverse sections on lines 4-4 and 5--5 of Fig. 2;
Fig. 6 is a horizontal section on line 6-6 of Fig. 5;
Fig. 7 is a horizontal section on line 77 of Fig. 5;
Fig. 8 is a plan view of the apparatus shown in Fig. 2;
Fig. 9 is an end view from the coke end;
Fig. 10 is a detail section on line 10-10 of Fig. 3; and
Fig. 11 is a section similar to Fig. 2 of a modification.
In the embodiment of apparatus selected for illustration in Figures 1 to 10, inclusive, the chain grate 10 conveys a continuous stream of material, which will hereinafter be referred to as coal, from hopper 12 through the coking retort to discharge chute 14. A bafile wall 16 divides the space above the grate into two compartments 18 and 20. To provide an effective seal between the chambers, We prefer to terminate baiiie wall 16 in a water jacketed semi-cylindrical shell 19, within which a sealing roller 21, also filled with water, is pivoted. Referrin to Figs. 3 and 10, it will be seen that ro ler 21 receives its water supply through the hollow trunnions 22 upon which it is pivoted, and is of star-shaped cross section, so that its ribs 24 will gou e into the bed of fuel moving under the fol er as clearly indicated in Fig3 3. This provides a satisfactory air seal etween the two parts of the chamber, and with certain types of fuel, may be made use of to effect a desirable breaking up and agitation of the partially coked coal.
The preferable way to operate this apparatus and method is best illustrated in Figure 2. The steam or motor driven blowers 32 having air admission openings 32' force air into the bus flues 30 which supply the tuyeres indicated by 34 on Figure 6. The air flowing through the bed of fuel on top of the travelling grate in the chamber 20 partially consumes the carbonaceous matter in this zone and produces a gas deficient in carbon dioxide and relatively high in carbon monoxide. The temperature of these products of partial combustion is regulated by the amount of air forced into this zone. These gases pass through the conduits 36 and 42 and are discharged into the tuyeres in the primary zone and thence through the carbonaceous bed into chamber 18, the sensible heat of the gases being forced into the primary zone thereby distilling the volatile matter out of the coal or carbonaceous matter in the bed at this point. The gases become intermingled with these products of distillation and are then drawn off through opening 44 by a vacuum pump 50 on Figure 1, together with the tar vapors, passing through the cooling tower 46 which also extracts the tar oils. The rate of flow of gas and air'are determined by the volume and pressure of the air passing into the chamber 20 and by the vacuum maintained in chamber 18. The conduit 36 is provided with a control valve 38. The air passing from chamber 20 has given up most of its oxygen to the carbonaceous matter to form carbon monoxide and carbon dioxide with a relatively small portion of the fuel being consumed.
The resulting gases at a high temperature can be transferred to chamber 18 by the use of an exhaust fan 40 and delivered through conduit 42 extending along both sides of the retort to sections 33 of the wind chest as shown in Figure 6. These hot gases containing practically no free oxygen are incapable of supporting combustion and have very low heat value. As they pass through the green fuel bed in chamber 18, giving up their heatto the fuel at this point, the distillation of the volatile hydrocarbons takes place and the lean low heat value gas from which the sensible heat has been extracted by the green fuel becomes mixed with the products of distillation from chamber 18 and. at certain critical temperatures part of the carbon dioxide is converted'into carbon monoxide. The resulting mixed gas is of'satisfactory quality to constitute a fuel gas of a type commonly referred to as producer gas, but-having considerably higher heating value because of the mixture of the high heat value gas resulting from the primary distillation.
Referring to Fig. 1, these gases pass through conduit 44, scrubber 46, conduit 48, exhauster 50, and conduit 52 to the gas holder 54, from which they may be withits passage through chamber20, it is sub-' ject to much more lively oxidation, and raised to a fairly high temperature. The resultant material entering chute 14 can be coke of very good quality, and much greater uniformity than can be obtained by any batch process.
While this coke may obviously be employed for any one of a variety of uses, it is peculiarly advantageous to let it fall directly into a wate'r-gasproducer In this way, large quantities of heat are con;
served, which would be lost if the coke weretaken out, and conveyed cold to a water gas plant, where it would have to be reheated.
Combustion on the chain grate may or may not proceed to completion. In the first instance, part 56 functions as a mere ash receiver, while in the second the blue Water gas therefrom will pass back throu h chamber 20 to augment the mass of material and the sensible heat delivered to the green fuel in chamber 18 through conduit 36. In
either instance the first and second ob'ects of invention above stated are accomplis ed, whereas the thirdobject is only attained when the fuel is only coked on' the chain grate and finally consumed by making blue water gas in generator 56.
It is highly desirable to avoid the deposition of any condensates on the walls of the coking retort, which would accumulate and form tarry deposits. For this purpose, we construct the coking retort with double walls 58 separated by chambers 60. Near the longitudinal center of the retort a set of apertures 62 is provided for the insertion of gas bumers 62', as shown in Fig. 4.
From this point the products of combustion pass outwardl to the sides of the retort and downwar 1y to exit pipes 64 joining headers 66 leadin to the stack 68. This maintains the wal s of the retort at all times at an appreciably higher temperature than the gases in the retort, and prevents condensation. As the temperature in chamber 20 is somewhat higher than in chamber 18, we preferably heat its walls to a somewhat higher temperature. Upon reference to Fig. 7, it W111 be observed that three exit ipes 64 are rovided for chamber 20 and on y two for c amber 18. The volgoing will so fully explain the gist of the invention, that others may, by applying current knowledge, readily adapt the same for.
use under various conditions of service. For instance, the equipment illustrated in Fig. 2 includes power means for influencing the flow from chamber to chamber 18. It will be obvious, that under certain conditions of operation, fan 32 and exhauster may be relied upon to maintain the flow through the entire system, and the gases from chamber '20 may be taken through conduit (Fig. 11) devoid of any power means, to chamber 18. While we have illustrated a chain grate with the space beneath it divided by partition 72 to control the delivery of gases to chambers 20 and 18, it will be obvious that other equivalent con veyor means might be substituted. These and many other modifications and variations may readily be made without eliminating certain features which may properly be said to constitute the essential items of novelty involved, which items are intended to be defined and secured to us by the followin claims:
e claim 1. In combination, a coking retort, conveyor means for moving a stream of coal through said retort, bafile wall means 61-- viding said retort into two parts, movable means having rolling contact. with said stream of coal and forming the terminus of said bafile means to afford a tight seal, means for supplying air to carry on com-' bustion on one side of said baflie wall, and
means for delivering the products of said combustion to coke the coal on the other side of said baflie wall substantially without combustion. 2. In combination, a coking retort, conveyormeans for movinla stream of coal 0 wall means di- I through said retort, ba viding. said retort into two parts, movable means having rolling contact with said stream of coal and forming the terminus of said baflle means to afiord a' tight seal, means for supplyi air to carry on combustion on one si of said baflle wall,
,means for delivering the products of said In witness whereof, I hereunto subscribe my name this 23rd do. of March, 1923..
subset. a
r w. Drrro.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US628421A US1591023A (en) | 1923-03-29 | 1923-03-29 | Apparatus for coking coal |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US628421A US1591023A (en) | 1923-03-29 | 1923-03-29 | Apparatus for coking coal |
Publications (1)
Publication Number | Publication Date |
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US1591023A true US1591023A (en) | 1926-07-06 |
Family
ID=24518804
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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US628421A Expired - Lifetime US1591023A (en) | 1923-03-29 | 1923-03-29 | Apparatus for coking coal |
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Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2581575A (en) * | 1946-06-27 | 1952-01-08 | Heyden Chemical Corp | Apparatus for the continuous production of water gas |
US2997426A (en) * | 1959-11-02 | 1961-08-22 | Mansfield Vaughn | Method for continuous production of coke and heat |
US3013951A (en) * | 1959-06-15 | 1961-12-19 | Mansfield Vaughn | Method for continuous coke production whiled extracting low temperature volatiles |
US3146175A (en) * | 1960-06-06 | 1964-08-25 | Mansfield Vaughn | Coal processing oven and product recovery system |
US3519540A (en) * | 1968-05-06 | 1970-07-07 | Maurice D Curran | Carbonizing oven having parallel horizontal flues and u-shaped air ducts |
-
1923
- 1923-03-29 US US628421A patent/US1591023A/en not_active Expired - Lifetime
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2581575A (en) * | 1946-06-27 | 1952-01-08 | Heyden Chemical Corp | Apparatus for the continuous production of water gas |
US3013951A (en) * | 1959-06-15 | 1961-12-19 | Mansfield Vaughn | Method for continuous coke production whiled extracting low temperature volatiles |
US2997426A (en) * | 1959-11-02 | 1961-08-22 | Mansfield Vaughn | Method for continuous production of coke and heat |
US3146175A (en) * | 1960-06-06 | 1964-08-25 | Mansfield Vaughn | Coal processing oven and product recovery system |
US3519540A (en) * | 1968-05-06 | 1970-07-07 | Maurice D Curran | Carbonizing oven having parallel horizontal flues and u-shaped air ducts |
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