US1423233A - Explosive material - Google Patents
Explosive material Download PDFInfo
- Publication number
- US1423233A US1423233A US500663A US50066321A US1423233A US 1423233 A US1423233 A US 1423233A US 500663 A US500663 A US 500663A US 50066321 A US50066321 A US 50066321A US 1423233 A US1423233 A US 1423233A
- Authority
- US
- United States
- Prior art keywords
- explosive
- perchlorate
- methyl
- explosive material
- compounds
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000002360 explosive Substances 0.000 title description 21
- 239000000463 material Substances 0.000 title description 3
- VLTRZXGMWDSKGL-UHFFFAOYSA-N perchloric acid Chemical compound OCl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-N 0.000 description 17
- VLTRZXGMWDSKGL-UHFFFAOYSA-M perchlorate Inorganic materials [O-]Cl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-M 0.000 description 8
- 150000001875 compounds Chemical class 0.000 description 7
- 239000000126 substance Substances 0.000 description 7
- BAVYZALUXZFZLV-UHFFFAOYSA-N Methylamine Chemical compound NC BAVYZALUXZFZLV-UHFFFAOYSA-N 0.000 description 5
- -1 methyl-substituted ammonium Chemical class 0.000 description 5
- 239000000203 mixture Substances 0.000 description 3
- ROSDSFDQCJNGOL-UHFFFAOYSA-N Dimethylamine Chemical compound CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 description 2
- 230000003472 neutralizing effect Effects 0.000 description 2
- QEMXHQIAXOOASZ-UHFFFAOYSA-N tetramethylammonium Chemical compound C[N+](C)(C)C QEMXHQIAXOOASZ-UHFFFAOYSA-N 0.000 description 2
- GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical compound CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 1
- USXDFAGDIOXNML-UHFFFAOYSA-N Fulminate Chemical group [O-][N+]#[C-] USXDFAGDIOXNML-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 241000287181 Sturnus vulgaris Species 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 238000009834 vaporization Methods 0.000 description 1
- 230000008016 vaporization Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C06—EXPLOSIVES; MATCHES
- C06B—EXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
- C06B43/00—Compositions characterised by explosive or thermic constituents not provided for in groups C06B25/00 - C06B41/00
Definitions
- the object of the invention is'to provide an explosive which-has a high explosive power and a high degree of stability which advantageously may be used for any military or civil purpose where explosives are employed.
- Another object of the invention is to provide an explosive of the kind described which which shall be substantially insensible against moistness.
- a further object of the invention is to provide a detonator containing our new explosive.
- the explosive consists of or comprises a erchlorate of a methyl-substituted ammonium compound.
- An explosive of the kind described which has an especially high explosive power is the perchlorate of methvl-amine. Said substance may be produced, say by neutralizing dilute perchloric acid by a solution of methylamin and subsequent vaporization and crystalliza tion. It is found in practice that 0.25 g. of
- the new explosive may be used as an admixture to well known explosives, whereby the efliciency of the latter is increased.
- the new explosive may advan tageously be used as an intermediate charge in detonators, exploders or the like.
- the pure explosive or mixtures of the same may be mixed with carbonates 'or' hydroxydes of sodium, calcium, magnesium or the like in order to neutralize the acid 1.
- An explosive comprising a perchlorate I of methyl-substituted ammoium compound.
- An explosive comprising a compound produced by the action of a perchloric compound upon a methyl-substitutedammonium of a methyl-substituted ammonium comcompound comprising at. least one methyl pound.
Description
metres stares rear erase.
CERISTEN JOHANNES STAUTSBOLL LUNDSGAARD, OF VEJEN, RAJ TOBIAS HERBS'I', OF BRAIBAND, DENMARK. I
EXPLQSIVE MATERIAL.
1,423,233. No Drawing.
To all whom it may concern:
Be it known that we, Cmusrnx J OHANNES STAUTSBOLL LUNDSGAARD and KAJ Tomas HERBST, subjects of the King of Denmark, residing at Vejen, Denmark, and Braband, Denmark, respectively, have invented new and useful Improvements in Explosive Materials; and we do herebydeclare the following to be a full, clear, and exact description of the same.
The object of the invention is'to provide an explosive which-has a high explosive power and a high degree of stability which advantageously may be used for any military or civil purpose where explosives are employed.
Another object of the invention is to provide an explosive of the kind described which which shall be substantially insensible against moistness.
A further object of the invention is to provide a detonator containing our new explosive.
With these and other objects in view the explosive consists of or comprises a erchlorate of a methyl-substituted ammonium compound.
It is a well known fact that eflicient and stable explosives can be produced by the action of perchloric acid or perchloric compounds upon cyclic ammonium compounds. It has also been tried to produce perchlorates of alifatic amino compounds, VIZ, ethylenediamine and diclyan-diamine, for explosive purposes, but so'far as we are aware these substances have not been used in large scale due to their hygroscopic character and high costs of production. It has now been found in practice that eflicient and stable explosives can be obtained by the action of perchloric acid or perchloric compounds upon methylamine, dimethyl-amfine, trimethyl-amine,
tetramethyl-ammonium or compounds con tainin one or more of said substances, where y the corresponding perchlorates are formed. Said perchlorates are rather insensible against moistness except the perchlorate of dimethyl-amine. Thus the perchlorate of methyl-amine certainly is freely soluble in water, but it is only slightly hygroscopic, while the perchlorate of tetramethyl-ammonium dissolves with diiliculty in water. Moreover these substances are Specification of Letters Patent.
Application filed September 14, 1921. Serial No. 500,668.
'without decomposition.
Patented Jul s; was.
very stable. Thus they may be subjected to a temperature of 150 C. for a long period and they maybe stored for several years An explosive of the kind described which has an especially high explosive power is the perchlorate of methvl-amine. Said substance may be produced, say by neutralizing dilute perchloric acid by a solution of methylamin and subsequent vaporization and crystalliza tion. It is found in practice that 0.25 g. of
the resulting perchlorate compressed inacopper cap by a pressure of 1500 kg. 'p'r. cm and ignited by a charge of 0.4 mercuric fulminate forms a hole of a dlameter ofabout 8-9 mm. in a lead plate of 7 mm.
thickness,when the cap is disposed vertically upon the surface of the lead plate. This experiment shows that the substance in question has an exceptional brisant action and efiiciency which partially is due to its rather ideal composition with respect to the proportions of the carbon, hydrogen and .ing and the like purposes) either in pure .55
state or in mixture with other substances.
Preferablythe new explosive may be used as an admixture to well known explosives, whereby the efliciency of the latter is increased. v
Moreover the new explosive may advan tageously be used as an intermediate charge in detonators, exploders or the like. Furthermore the pure explosive or mixtures of the same may be mixed with carbonates 'or' hydroxydes of sodium, calcium, magnesium or the like in order to neutralize the acid 1. An explosive comprising a perchlorate I of methyl-substituted ammoium compound. 2. An explosive comprising a compound produced by the action of a perchloric compound upon a methyl-substitutedammonium of a methyl-substituted ammonium comcompound comprising at. least one methyl pound. I
group. Y In testimony whereof we have affixed 3. An explosive containing mono-methylour signatures in presence of two witnesses.
5 ammomum-perehlomte- CHRISTEN JOHANNES STAUTSBOLL LUNDSGAARD.
4. An explosive oomprlsing a perchlorate KM TOBIAS HERBS-L of a methyl-substltuted ammonlum compound and a substance for neutralizing Witnesses:
acidulous combustion products. FANNY. GEsERsEN,
,0 5. A detonator containing a perchlorate C. V. HOGE'SEE.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US500663A US1423233A (en) | 1921-09-14 | 1921-09-14 | Explosive material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US500663A US1423233A (en) | 1921-09-14 | 1921-09-14 | Explosive material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US1423233A true US1423233A (en) | 1922-07-18 |
Family
ID=23990401
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US500663A Expired - Lifetime US1423233A (en) | 1921-09-14 | 1921-09-14 | Explosive material |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US1423233A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20050040367A1 (en) * | 2001-12-11 | 2005-02-24 | Baerlocher Gmbh | Stabilizer composition, production and use thereof |
-
1921
- 1921-09-14 US US500663A patent/US1423233A/en not_active Expired - Lifetime
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20050040367A1 (en) * | 2001-12-11 | 2005-02-24 | Baerlocher Gmbh | Stabilizer composition, production and use thereof |
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