US1372465A - Distillation process - Google Patents
Distillation process Download PDFInfo
- Publication number
- US1372465A US1372465A US364388A US36438820A US1372465A US 1372465 A US1372465 A US 1372465A US 364388 A US364388 A US 364388A US 36438820 A US36438820 A US 36438820A US 1372465 A US1372465 A US 1372465A
- Authority
- US
- United States
- Prior art keywords
- alcohol
- water
- per cent
- fusel oil
- distillation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/02—Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only
Definitions
- This invention relates todistillation proc- I esses; and it comprises a method of utili'zing alcohol in the production of motor fuels wherein such alcohol is redistilled in the presence of hydrocarbons (benzol or petroleum oils) and fusel oil for the purpose of improving the blending of such alcohol and hydrocarbon and for-the removal of the water contained in such alcohol; all as more fully hereinafter set forth and as claimed. 1
- fusel oil being amply suflicient as a rule. Part of this fusel oil goes with the final dry alcoholic material used for motor purposes while the remaining part remains in other products of distillation. its these other products of distillation go back into the op eration this portion of the fusel oil is reused. The portion which goes into the final alcoholic material used for motor fuel purposes is useful since it acts as a blending agent.
- the alcohol is redistilled to bring it back to its original strength. After a time the dis tillaticn temperature of the mixture suddenly rises above 64 and finally goes to about 78 C. During this period a second fraction of 'the condensed distillate forms which amounts to about 30 per cent. and is composed of alcohol containing'some water and of hydrocarbon in two layers. The separated layer of water alcohol is redistilled to get the alcohol; this alcohol and the hy-- mainly hydrocarbon oil.
- the fuel composed of alcohol treated as just described and admixed with a petroleum oil may be im- 5 per cent. of toluol to proved by a further admixture of say 5 per cent. of ether to give quickened ignition and prevent loss of ether on keeping.
- fusel oil may be any of the commercial grades.
- What I claim is The process of fitting commercial waterontaining alcohol for use in making composite motor fuels which comprises redistilling such alcohol with a hydrocarbon oil and fusel oil and segregating a fraction substantially free of water and consisting mainly of alcohol.
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Solid Fuels And Fuel-Associated Substances (AREA)
- Liquid Carbonaceous Fuels (AREA)
Description
u -urge stares Parent OFF-ICE.
ELBEIDGE W. STEVENS, OF BALTIMORE, MARYLAND, AS$IGNOR T0 CHEMICAL FUEL COMPANY 01? AMERICA, INC., 0]? LOUISVILLE, KENTUCKY, A CORPORATION OF Patented Mar. 22 1921.
Application filed 161510119, 1920. Serial No. 364,388.
' DELAWAEE.
DISTILLATION PROCESS.
(I I 1L 372A65 Specification of Letters Patent.
No Drawing.
land, have invented certain'new and useful improvements in Distillation Processes, of
which the following is a specification.
This invention "relates todistillation proc- I esses; and it comprises a method of utili'zing alcohol in the production of motor fuels wherein such alcohol is redistilled in the presence of hydrocarbons (benzol or petroleum oils) and fusel oil for the purpose of improving the blending of such alcohol and hydrocarbon and for-the removal of the water contained in such alcohol; all as more fully hereinafter set forth and as claimed. 1
Tn the manufacture of composite motor fuels it is desirable to use ordinary alcohol (ethyl alcohol or grain alcohol) as one component and a hydrocarbon as another component. Difficulties arise however in the mixing of these bodies. Urdiharily alcohol as it comes into commerce as a result of the fermentation and distillation of molasses, sugars, etc, is not readily miscible with most of the hydrocarbon oils desirable for use in this connection. TVith most petroleum oils it hardly mines at all in the absence of some third'body adapted to dissolve both (or to dissolve in both) acting as a cosolvent. With pure benzol it is more miscible, but the low grade tar oils contain ingbenzol which are desirable for fuel purposes do not mix as readily. In part, this difficulty in mixing arises from the presence of water in the alcohol. Ordinary methods of distillation do not remove all the water from alcohol-water mixtures; and commercial alcohol (except the special grade known as absolute alcohol) usually contains from 5 water. Apart from the difiiculties, the presence of undesirable in a to 8 per cent. of matter of mixing this water is, of course, fuel.
The reason that water can not be completely removed from alcohol by distillation is ing no water has a slightly higher boilmg point than alcohol containin a llttle water and the latter is conse uent y the product delivered by the still. I however alcoholof the strength'which is delivered by ordinary fractional the fact that alcohol c0ntaindistillation be redistilled in the presence of lVnBs'rERNvarious hydrocarbons, distilling conditions change and the bulk of the water contained the alcohol can be removed as a separate fraction. This'is done in the present invention.
I have found that in the presence of a little fusel oil the distillatory separations' become much sharper; this being particularly the case where' petroleum ydrocarbons, such as kerosene, gasolene, etc., are
used. The quantity requlred for this purpose is quite small; 0.25 to 1 per cent. of fusel oil being amply suflicient as a rule. Part of this fusel oil goes with the final dry alcoholic material used for motor purposes while the remaining part remains in other products of distillation. its these other products of distillation go back into the op eration this portion of the fusel oil is reused. The portion which goes into the final alcoholic material used for motor fuel purposes is useful since it acts as a blending agent.
in a typical embodiment of the present in mention a mixture of about all parts (39.25) of commercial watencontaining alcohol of 92 to 94 per cent. strength, 0.25 parts of commercial fusel oil and 60 parts of bencol (gasolene or kerosene or tar oils may be used instead) is distilled in any ordinary. apparatus having means for fractionation. The mixture begins to distil at a low temperature which rises to about 64 C. and remains at this point for some time. The condensate during this period amounts to'about 40 per cent.- and is (benzol or gasolenc) and alcohol containing more water than the original alcohol used. These form two layers, which, on standing. separate from each other. The hydrocarbon oil goes back into the process for reuse. The alcohol is redistilled to bring it back to its original strength. After a time the dis tillaticn temperature of the mixture suddenly rises above 64 and finally goes to about 78 C. During this period a second fraction of 'the condensed distillate forms which amounts to about 30 per cent. and is composed of alcohol containing'some water and of hydrocarbon in two layers. The separated layer of water alcohol is redistilled to get the alcohol; this alcohol and the hy-- mainly hydrocarbon oil.
tillation of the remaining 30 per cent. and the formation of a third condensate of alcohol and hydrocarbon practically free of Water. This condensate is used for making compound motor fuels. One typical condensate made in the manner just described on analysis gave 89.5 per cent. alcohol, 10 per cent. benzol and but 0.38 per cent. Water. lVith this proportion of benzol the alcohol is denatured, and it is rendered substantially non-hygroscopic on exposure to the air. The material blends readily with petroleum hydrocarbons, partly because of the absence of Water and partly because of the presence of benzol. In making a motor fuel it may be so blended with any suitable petroleum distillate giving a permanent non-hy ro scopic mixture; say in the proportion o parts of this material to 75 partsof the petroleum distillate.
For motor purposes the fuel composed of alcohol treated as just described and admixed with a petroleum oil may be im- 5 per cent. of toluol to proved by a further admixture of say 5 per cent. of ether to give quickened ignition and prevent loss of ether on keeping. Where low-grade or unrectified alcohols containing substantial quantities of fusel oil can be obtained no further addition of fusel oil ma be needed. This of course however depends upon the amount of fusel oil present. Where fusel oil is added it may be any of the commercial grades.
What I claim is The process of fitting commercial waterontaining alcohol for use in making composite motor fuels which comprises redistilling such alcohol with a hydrocarbon oil and fusel oil and segregating a fraction substantially free of water and consisting mainly of alcohol.
In testimony whereof I afiix my signature hereto.
ELBRIDGE W. STEVENS.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US364388A US1372465A (en) | 1920-03-09 | 1920-03-09 | Distillation process |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US364388A US1372465A (en) | 1920-03-09 | 1920-03-09 | Distillation process |
Publications (1)
Publication Number | Publication Date |
---|---|
US1372465A true US1372465A (en) | 1921-03-22 |
Family
ID=23434316
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US364388A Expired - Lifetime US1372465A (en) | 1920-03-09 | 1920-03-09 | Distillation process |
Country Status (1)
Country | Link |
---|---|
US (1) | US1372465A (en) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2591713A (en) * | 1947-09-16 | 1952-04-08 | Standard Oil Dev Co | Extractive distillation of alcoholcontaining mixtures |
US4243493A (en) * | 1978-02-03 | 1981-01-06 | Mannesmannrohren-Werke A.G. | Process for transportation and distillation of petroleum with methanol |
US4568356A (en) * | 1978-11-09 | 1986-02-04 | Chambers John M | Process for making anhydrous alcohol for mixing with gasoline to make gasohol motor fuel |
US4585461A (en) * | 1984-08-01 | 1986-04-29 | Gorman Jeremy W | Method of manufacturing a diesel fuel additive to improve cetane rating |
US6679975B2 (en) * | 2001-01-09 | 2004-01-20 | Institut Francais Du Petrole | Process for recovering the methanol contained in a liquid hydrocarbon feed |
-
1920
- 1920-03-09 US US364388A patent/US1372465A/en not_active Expired - Lifetime
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2591713A (en) * | 1947-09-16 | 1952-04-08 | Standard Oil Dev Co | Extractive distillation of alcoholcontaining mixtures |
US4243493A (en) * | 1978-02-03 | 1981-01-06 | Mannesmannrohren-Werke A.G. | Process for transportation and distillation of petroleum with methanol |
US4568356A (en) * | 1978-11-09 | 1986-02-04 | Chambers John M | Process for making anhydrous alcohol for mixing with gasoline to make gasohol motor fuel |
US4585461A (en) * | 1984-08-01 | 1986-04-29 | Gorman Jeremy W | Method of manufacturing a diesel fuel additive to improve cetane rating |
US6679975B2 (en) * | 2001-01-09 | 2004-01-20 | Institut Francais Du Petrole | Process for recovering the methanol contained in a liquid hydrocarbon feed |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US1372465A (en) | Distillation process | |
US1813636A (en) | Process of separating formic acid from acetic acid | |
US2456561A (en) | Azeotropic separation of xylene isomers | |
US2204215A (en) | Manufacture of motor fuel | |
US2192137A (en) | Denatured materials | |
US1524192A (en) | Method for dehydrating organic liquids | |
US1079004A (en) | Process for separating mixtures of liquids. | |
US2143870A (en) | Polyfurcous fuel | |
JPS62243685A (en) | Production of aromatic substance concentrate proper for use as compounding component for caburator | |
US1587899A (en) | Motor fuel | |
US2414252A (en) | Solvent separation of hydrocarbons | |
US2055455A (en) | Process for manufacturing motor fuel | |
US2194495A (en) | Motor fuel | |
US1699355A (en) | Fuel and process of making the same | |
US2124171A (en) | Motor fuels | |
US1578201A (en) | Fuel | |
US1388531A (en) | Motor-fuel | |
US1363870A (en) | Method of forming a liquid fuel | |
DE1026461B (en) | Process for the production of gasoline | |
USRE20596E (en) | Process fob | |
US2078736A (en) | Motor fuel | |
US2417355A (en) | Distillation of hydrocarbons with addition of acetone-methyl alcohol | |
DE1041727B (en) | Motor fuel | |
US2192119A (en) | Denaturant | |
GB600551A (en) | Improvements relating to the production of aviation or motor fuels |