US135028A - Improvement in metallic compounds for coating cutlery - Google Patents
Improvement in metallic compounds for coating cutlery Download PDFInfo
- Publication number
- US135028A US135028A US135028DA US135028A US 135028 A US135028 A US 135028A US 135028D A US135028D A US 135028DA US 135028 A US135028 A US 135028A
- Authority
- US
- United States
- Prior art keywords
- cutlery
- coating
- compound
- improvement
- metallic compounds
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 150000001875 compounds Chemical class 0.000 title description 16
- 239000011248 coating agent Substances 0.000 title description 8
- 238000000576 coating method Methods 0.000 title description 8
- 229910000765 intermetallic Inorganic materials 0.000 description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 14
- NLXLAEXVIDQMFP-UHFFFAOYSA-N ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 8
- 235000019270 ammonium chloride Nutrition 0.000 description 8
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 8
- 229910052709 silver Inorganic materials 0.000 description 8
- 239000004332 silver Substances 0.000 description 8
- 239000005864 Sulphur Substances 0.000 description 6
- 239000002253 acid Substances 0.000 description 6
- 238000004140 cleaning Methods 0.000 description 6
- 229910052751 metal Inorganic materials 0.000 description 6
- 239000002184 metal Substances 0.000 description 6
- 150000002736 metal compounds Chemical class 0.000 description 6
- 238000007747 plating Methods 0.000 description 6
- NINIDFKCEFEMDL-UHFFFAOYSA-N sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 6
- HCHKCACWOHOZIP-UHFFFAOYSA-N zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 6
- 239000011701 zinc Substances 0.000 description 6
- 229910052725 zinc Inorganic materials 0.000 description 6
- VEXZGXHMUGYJMC-UHFFFAOYSA-N HCl Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 4
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 4
- 229910052797 bismuth Inorganic materials 0.000 description 4
- 235000011167 hydrochloric acid Nutrition 0.000 description 4
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 4
- 229910052753 mercury Inorganic materials 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 229910052759 nickel Inorganic materials 0.000 description 4
- 229910052718 tin Inorganic materials 0.000 description 4
- ATJFFYVFTNAWJD-UHFFFAOYSA-N tin hydride Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 4
- 229910001018 Cast iron Inorganic materials 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 239000003245 coal Substances 0.000 description 2
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 2
- 239000010699 lard oil Substances 0.000 description 2
- 229910001338 liquidmetal Inorganic materials 0.000 description 2
- 239000010742 number 1 fuel oil Substances 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 235000011149 sulphuric acid Nutrition 0.000 description 2
- 239000001117 sulphuric acid Substances 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/009—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
- C09D5/10—Anti-corrosive paints containing metal dust
Definitions
- the nature of this invention relates to a certain metallic compound for coating or covering articles of cutlery, and other like purposes, to arrest oxidation of the metal thus coated over, and to give the efiect and appearance of silver-plating at much less cost than silver.
- I will proceed and describe one formula for preparing this metal compound and the process of using the same in plating articles.
- I use fifty pounds tin, (banco tinbeingpreferred,) three ounces silver, twelve ounces nickel, three ounces bismuth, one-half ounce sulphur, (roll sulphur preferred,) two ounces sal-ammoniac, and one-half ounce mercury, which are combined as hereinafter set forth, forming a new metallic compound.
- the tin is put into a castiron vessel first and melted over an ordinary coal fire; then the silver is added; next in order is the nickel, bismuth, sulphur, sal-ammoniac, and, last, mercury.
- the article to be coated or plated by said compound is first cleaned from rust, dirt, &c., byapreparation or compound of two pounds of sulphuric acid and one gallon of water, in which the article remains from ten to thirty minutes, depending upon the condition of the article; when it is taken from this acid bath the article is washed in clean water, to cleanse it from the acid of thebath.
- the next step is a as set forth.
- the article After the article has been dipped into the meta1 compound, it is then immersed in coal-oil, and next washed in a solution of water and sal-ammoniac of about the proportions of two pounds sal-ammoniac to one gallon of water. The plating of the article is then completed by washing in clean water, leaving it bright and smooth, and requiring no rubbing or varnishing to give an appearance much like polished silver.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Ceramic Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Structural Engineering (AREA)
- Chemically Coating (AREA)
Description
UNITED STATES PATENT OEEIoE.
JOHN ZIMMER, OF CLEVELAND, OHIO, ASSIGNOR OF TWO-THIRDS HIS RIGHT TO ROBERT SANDERSON AND SAMUEL CURTIS, OF SAME PLACE.
IMPROVEMENT IN METALLlC COMPOUNDS FOR COATING CUTLERY, &c.
Specification forming part of Letters Patent No. 135,028, dated January 21, 1873.
To all whom it may concern:
Be it known that I, JOHN ZIMZMER, of Cleveland, in the county of Cuyahoga and State of Ohio, have invented a certain new Metallic Compound for Coating or Covering Cutlery and other articles; and I do hereby declare that the following is a clear and exact description of the process of making said compound and mode of using the same:
The nature of this invention relates to a certain metallic compound for coating or covering articles of cutlery, and other like purposes, to arrest oxidation of the metal thus coated over, and to give the efiect and appearance of silver-plating at much less cost than silver.
I will proceed and describe one formula for preparing this metal compound and the process of using the same in plating articles. As one example or formula for said compound, I use fifty pounds tin, (banco tinbeingpreferred,) three ounces silver, twelve ounces nickel, three ounces bismuth, one-half ounce sulphur, (roll sulphur preferred,) two ounces sal-ammoniac, and one-half ounce mercury, which are combined as hereinafter set forth, forming a new metallic compound. The tin is put into a castiron vessel first and melted over an ordinary coal fire; then the silver is added; next in order is the nickel, bismuth, sulphur, sal-ammoniac, and, last, mercury. These several articles follow each other in order as the preceding ones melt and amalgamate by heat, forming a new metal or compound.
The article to be coated or plated by said compound is first cleaned from rust, dirt, &c., byapreparation or compound of two pounds of sulphuric acid and one gallon of water, in which the article remains from ten to thirty minutes, depending upon the condition of the article; when it is taken from this acid bath the article is washed in clean water, to cleanse it from the acid of thebath. The next step is a as set forth.
preparation or compound of muriatic acid, zinc and water, the proportions of which are about one gallon muriatic acid to one pound of zinc, to which is added one gallon of water. After the acid and zinc have combined in this solution, the article is immersed and immediately withdrawn, and then plunged into the liquid metal compound before set forth and directly withdrawn. On withdrawing the article from the first bath of the metallic compound, it is again dipped into another like metal compound to the first, but having upon its surface a film of or covering of lard oil, or its equivalent, enough to cover over the metal surface about one-sixteenth of an inch in depth.
After the article has been dipped into the meta1 compound, it is then immersed in coal-oil, and next washed in a solution of water and sal-ammoniac of about the proportions of two pounds sal-ammoniac to one gallon of water. The plating of the article is then completed by washing in clean water, leaving it bright and smooth, and requiring no rubbing or varnishing to give an appearance much like polished silver.
I do not confine myself to the exact proportion herein given for the said metallic com pound, but propose to vary the same within the limits of the invention.
What I claim as my invention, and desire to secure by Letters Patent, is-
1. The metallic compound, substantially as and for the purpose set forth.
2. The coating or covering articles of cutlery, &c., with the metallic compound herein described, by the means or mode substantially JOHN ZIMMER.
l/Vit-nesses:
J. H.BURRIDGE, A. F. CORNELL.
Publications (1)
Publication Number | Publication Date |
---|---|
US135028A true US135028A (en) | 1873-01-21 |
Family
ID=2204444
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US135028D Expired - Lifetime US135028A (en) | Improvement in metallic compounds for coating cutlery |
Country Status (1)
Country | Link |
---|---|
US (1) | US135028A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2530413A (en) * | 1945-10-29 | 1950-11-21 | Crown Cork & Seal Co | Container |
US20190074460A1 (en) * | 2017-03-08 | 2019-03-07 | Boe Technology Group Co., Ltd. | Flexible display panel and manufacturing method thereof, and flexible display device |
-
0
- US US135028D patent/US135028A/en not_active Expired - Lifetime
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2530413A (en) * | 1945-10-29 | 1950-11-21 | Crown Cork & Seal Co | Container |
US20190074460A1 (en) * | 2017-03-08 | 2019-03-07 | Boe Technology Group Co., Ltd. | Flexible display panel and manufacturing method thereof, and flexible display device |
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