US1327859A - Explosive - Google Patents
Explosive Download PDFInfo
- Publication number
- US1327859A US1327859A US1327859DA US1327859A US 1327859 A US1327859 A US 1327859A US 1327859D A US1327859D A US 1327859DA US 1327859 A US1327859 A US 1327859A
- Authority
- US
- United States
- Prior art keywords
- explosive
- nitrate
- main
- tho
- salt
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000002360 explosive Substances 0.000 title description 18
- 229910002651 NO3 Inorganic materials 0.000 description 6
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 6
- 150000003839 salts Chemical class 0.000 description 6
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical compound [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 description 6
- SNIOPGDIGTZGOP-UHFFFAOYSA-N Nitroglycerin Chemical compound [O-][N+](=O)OCC(O[N+]([O-])=O)CO[N+]([O-])=O SNIOPGDIGTZGOP-UHFFFAOYSA-N 0.000 description 3
- 239000000006 Nitroglycerin Substances 0.000 description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 229960003711 glyceryl trinitrate Drugs 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 235000010344 sodium nitrate Nutrition 0.000 description 3
- 239000004317 sodium nitrate Substances 0.000 description 3
- SPSSULHKWOKEEL-UHFFFAOYSA-N 2,4,6-trinitrotoluene Chemical compound CC1=C([N+]([O-])=O)C=C([N+]([O-])=O)C=C1[N+]([O-])=O SPSSULHKWOKEEL-UHFFFAOYSA-N 0.000 description 2
- 206010000060 Abdominal distension Diseases 0.000 description 1
- 241000238876 Acari Species 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- 206010019233 Headaches Diseases 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 241001233242 Lontra Species 0.000 description 1
- 101100237803 Mus musculus Mrln gene Proteins 0.000 description 1
- 240000008042 Zea mays Species 0.000 description 1
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 1
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 229910001963 alkali metal nitrate Inorganic materials 0.000 description 1
- 208000024330 bloating Diseases 0.000 description 1
- 238000009924 canning Methods 0.000 description 1
- 210000000078 claw Anatomy 0.000 description 1
- 235000005822 corn Nutrition 0.000 description 1
- 238000005474 detonation Methods 0.000 description 1
- 238000007710 freezing Methods 0.000 description 1
- 230000008014 freezing Effects 0.000 description 1
- 231100000869 headache Toxicity 0.000 description 1
- 229910052734 helium Inorganic materials 0.000 description 1
- 239000001307 helium Substances 0.000 description 1
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 235000012054 meals Nutrition 0.000 description 1
- PSGAAPLEWMOORI-PEINSRQWSA-N medroxyprogesterone acetate Chemical compound C([C@@]12C)CC(=O)C=C1[C@@H](C)C[C@@H]1[C@@H]2CC[C@]2(C)[C@@](OC(C)=O)(C(C)=O)CC[C@H]21 PSGAAPLEWMOORI-PEINSRQWSA-N 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000001473 noxious effect Effects 0.000 description 1
- VLTRZXGMWDSKGL-UHFFFAOYSA-M perchlorate Inorganic materials [O-]Cl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-M 0.000 description 1
- VLTRZXGMWDSKGL-UHFFFAOYSA-N perchloric acid Chemical compound OCl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-N 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C06—EXPLOSIVES; MATCHES
- C06B—EXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
- C06B31/00—Compositions containing an inorganic nitrogen-oxygen salt
- C06B31/02—Compositions containing an inorganic nitrogen-oxygen salt the salt being an alkali metal or an alkaline earth metal nitrate
- C06B31/12—Compositions containing an inorganic nitrogen-oxygen salt the salt being an alkali metal or an alkaline earth metal nitrate with a nitrated organic compound
- C06B31/14—Compositions containing an inorganic nitrogen-oxygen salt the salt being an alkali metal or an alkaline earth metal nitrate with a nitrated organic compound the compound being an aromatic
- C06B31/16—Compositions containing an inorganic nitrogen-oxygen salt the salt being an alkali metal or an alkaline earth metal nitrate with a nitrated organic compound the compound being an aromatic the compound being a nitrated toluene
Definitions
- trinitrotolnol may TIDE 01 1.321859.
- nnnewnnn, 4 ' 0 main object of our nvention m to provide explosive compositions in which nnoer 0.1mm] m wxmiem. n. oftvtmunoroei nmwm M393 n 1 no rum 1:; moons e oom m, or manna-eon. nnnewnnn, 4
- nn er plmive would have the nation:
- An explosive contnlnlng us the main explosivetrinitmtolunl. fmm tq Ul'fi; qf uitmglycerin. and n mm-explmm- Inorganic oxygen-canning salt.
- buatihlq mtemlapitz may he: five till; I ialiout 5 f0 17% 0f m'rbohyllmte ,cqutnihiug salt, fi'mu about 9. -mtmglycerlu, and from nhont L7 to 5")1.
- a. 4 ax e osu'e upntunn us the main explosive trmitmtuhml whim is prgmut tu he eight of at least 1891"; 'l'lltmglverin, mud smluun mtrate.
- nmtuinin from about 30 R150 nmts 0f trlnifl'romlm frum nhnnb 55 to 4-5 pnrtq uf aux alkali-metal nitrate, and about Ii mrts of nituiglycerln.
Landscapes
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Organic Chemistry (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
Description
. trinitrotolnol may TIDE 01 1.321859.
To all whom it concern.-
Be it known that we. Loon O. Bmmx, of
whicllnre similar in their exp naive properties to existing standard grades of lh'namite. 'l'hg 'commerciul explosives in which it has heretofme been Propo ed to ineorponte xaid to full in two main claw. In one chou IN compositions in which a small percentage of trimtxotolllol is used in eon motion with relatively large "percentages 0' nitroglycerin for the of producing the sorcalled lowtlymlmite.
In explosive compositions of the other elm, low percentages-oi trlmtrotoiuol are mod on. relatively h W828 of explosive salts having 'n ql ig 1 oxygen content euch as 'iunmoninm nitrate, ammonium perehlggte pqtassuun ehloi nte or. rohlomte,
or eptlxldlllllg materials 01 xi: eha'rao ter. =,-Tho urpoeeof the trinitrotoluol in this other c has is to sensitize the nmniomum nitrate or other explosive salt In order to make the wmpooitio 'eupeble of detonation with eonunorcml bloating capo.
Explosives -of the two typos described above have curtain ndrun but the) 1180 1mm eel-lulu disadvantages. on the low freezing d mites are to to menuexpenn 'faeture; thev-ahow u tendenny toward erudation or lalcinesa ot the liquideonstitw ants-41nd was on: liable to contract aemie heulacheq by handling the e loslve.
Explosives of the second no: mentioned have three very aunom dead First] the on; relatively inaensitiveto etonntio n ooondly they are very liable to become extremely m'd otter short periods of storage, in which hard condition they are very insenaitive to detonatlon and are also very dillieult to load into bore holes. Thirdly, they are woolly or duty and mnmqueutly dangerous; lo, and unit gieuic to manufacture.
' 0 main object of our nvention m to provide explosive compositions in which nnoer 0.1mm] m wxmiem. n. oftvtmunoroei nmwm M393 n 1 no rum 1:; moons e oom m, or manna-eon. nnnewnnn, 4
age of sodium nitrate or other oxygen ccirrging salt, whit-h, however, is not an elqil'iili'o like nnuupnmm nitrate, ununonium; perchlorate, etc. One example of such nn er plmive would have the nation:
Nitroglycerin 5' Trinitrotoluol h'odimu nitrate 55% a These i1 redients may however hovel-led and. other \gredienm added in order to ob tnin certain desired hamoteristm'such-ns high or low etre t-eloc'ity, 1nd density. For exam le, live typical formulasl'r'e ktllltgfll to standard industrial .dj'mmites .no disclosed for ezonnple in Bureau of Mllfes' Bulletin No. 48,11age 7.
It is understand that the utagee-ef them i tents lnay be varied within certain lllll ts, mid other elmmoterintiu eulistitl or added without .lnptttllltg from the Mp0 of-our invention. Thus we do not limit ourmlves tp'the nseot five g cent. (5%) nitroglycerin, amen do, snofi re-mlta can be obtained from the use of from two to ten per cook-(240%) thereof.
The puqmse ofltlm nitmglyoegm-is to semiitino tho explosive e0 thet t mil surely detonate with conuner anl blu. ea-po even under adverse conditions. It a nets to ovmome the dnstmesoof exploslm con tnining no liquid i enta. The trinitrotoluo in the most important mmstituent of the new com 'tion'nnd following:
lients of similar 05' an qh all , aria. They ,howevar; that ms'omecases fromha ha: lad-without-the user Britten -dled (luring nmmlfuctm'e and the strength which is (haired. Althuugh lhe trinltrotnhml -:wednuiy be either tho pm-a 'm'fimd' product or a low melting cnlde pmduct, we have found the'lgltmr- (mllziugi tendency for the explosive toctgin: tro hlq l The function 'of the oxygen-ca! 'ing all such as soilimn nitrate is to furnl uq'gen in the damned amount and tq', rmfentflth funnation of noxious or deltrwus fiimes. The combustible, nun-explosive materials,
as w are added in some cases to Lmpprt the desind .nlsc ea mcmlly when the stmugthpi'tbe xplodh'e. In plaoo'of wood pulp-and com u leal, 'wa may usp Mlle x! y m kf not limit ouraa'lve to any jgurtlcular peref-com to seventeen (fi 17%) 9; shah Ilia Ex loam-29 iniul in ion as ahbve desm'ihad are thomu ly sensitive to fire, etc. contain erin nd am.donsequently practically 11011 For the same much they my mused by exp osie;
pnq swore headaches art-10m n! nitroglycsalt.
2. An explosive contnlnlng us the main explosivetrinitmtolunl. fmm tq Ul'fi; qf uitmglycerin. and n mm-explmm- Inorganic oxygen-canning salt.
3.111 on alnsivc umuuniu us the mum explosive trmih'ntnlunl whim i present! the extent of at least 1S',-{ mtmg-lycurm, and u non-explosive. inurgann: nxygvn-vartying salt pulp, cornmcpl, -um1 s,nlfur.1
buatihlq mtemlapitzmay he: five till; I ialiout 5 f0 17% 0f m'rbohyllmte ,cqutnihiug salt, fi'mu about 9. -mtmglycerlu, and from nhont L7 to 5")1. of
'miumfnctuwcl, the
of lrinllrntn 4. An. lolsive cnuuiiuing as the main vxplush? tnnitmwluo! which is present to the extent of at leass 18'}. 2 to of qit-rdglyceriiyaml a nun-cxplm lflagmr- An explosive -eqntaining asthe main mn': nitrate; k
(L'An xplusiv cunhijning as the u'mi'n explogsive trinitrotolnuK-Xmm 2 to 101;, of
'izlgi-o' izlly;'cqsrinin94 mlilmf inute.
a. 4 ax e osu'e upntunn us the main explosive trmitmtuhml whim is prgmut tu he eight of at least 1891"; 'l'lltmglverin, mud smluun mtrate.
S. n e vs containing as the main ex extent of atleast 18%, from 2 m 109-; of
. 1 9d sodium nitrate.
:- ll. :exp 'uslvecontaining as tlm muln explosivet1-initrdtoluol,-nitm ycurin, so-
. 'llinm minim: and ambuatib nou-axplo all impartthe-desireddensity to the compilation and to increase: its exsh'e mater:
pluslvo 10.- An e'x'plbsn'e detaining as the main explosive tppitl-otoluol, from 2 to 10% of helium, sodium nitrate, and from materhnl. 11. An c; )loaiva contami from about ls m o hinitrotohiul, min about to 40% of a name. lnsive inorganic oxygen v'ontul ling gmlt, am from qhnutil to 10% 01 'flfll'lL, 1." i
l2- .ln esplusivo contuiuln --f|-om nhoi1't 18 t0 mm pf trinit-rutoluilh qua uboul; 60
' iambic-Oxygento 10% of a mm-exphialvu camlmgatihln material.
18. An uxplmivo, nmtuinin from about 30 R150 nmts 0f trlnifl'romlm frum nhnnb 55 to 4-5 pnrtq uf aux alkali-metal nitrate, and about Ii mrts of nituiglycerln.
H. An exp nah-n mntuinm fmmuh'rmtw to 50 part nf (riuitrotnluol, mm uhuut iii; tn 45 parts nf nu nllmli-mtal nitratv, nhrmt 5 pnrls of uitmgiyccrin. and not more than ahmll. 10 parts uf curlmlmlmte nmturial to impart tho desiml llcnsil-y to the tfllllllOSl tlnn nlul tn invlmu-I! its explosive strvngth.
l5. An vxrlmivu mntninlng almnt'zluyg \ml, about, 641.2,,0! sodium nitrnl'v, guhont 51.1" of nitmglg'mrln. an amount of wuml pulp and corn meal lnmliu about 10'} and a small percentage of chalk.
In tvat-inmuy that we chum tho fmegoing we have hereunto 512tum' hands.
LEON 0. BRYAN, 'ENDEL J R. SWINT.
:sglnslfi trinltnkolupl, pitroglyeerin, and
Publications (1)
Publication Number | Publication Date |
---|---|
US1327859A true US1327859A (en) | 1920-01-13 |
Family
ID=3394398
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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US1327859D Expired - Lifetime US1327859A (en) | Explosive |
Country Status (1)
Country | Link |
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US (1) | US1327859A (en) |
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- US US1327859D patent/US1327859A/en not_active Expired - Lifetime
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