US1327859A - Explosive - Google Patents

Description

. trinitrotolnol may TIDE 01 1.321859.

To all whom it concern.-

Be it known that we. Loon O. Bmmx, of

whicllnre similar in their exp naive properties to existing standard grades of lh'namite. 'l'hg 'commerciul explosives in which it has heretofme been Propo ed to ineorponte xaid to full in two main claw. In one chou IN compositions in which a small percentage of trimtxotolllol is used in eon motion with relatively large "percentages 0' nitroglycerin for the of producing the sorcalled lowtlymlmite.

In explosive compositions of the other elm, low percentages-oi trlmtrotoiuol are mod on. relatively h W828 of explosive salts having 'n ql ig 1 oxygen content euch as 'iunmoninm nitrate, ammonium perehlggte pqtassuun ehloi nte or. rohlomte,

or eptlxldlllllg materials 01 xi: eha'rao ter. =,-Tho urpoeeof the trinitrotoluol in this other c has is to sensitize the nmniomum nitrate or other explosive salt In order to make the wmpooitio 'eupeble of detonation with eonunorcml bloating capo.

Explosives -of the two typos described above have curtain ndrun but the) 1180 1mm eel-lulu disadvantages. on the low freezing d mites are to to menuexpenn 'faeture; thev-ahow u tendenny toward erudation or lalcinesa ot the liquideonstitw ants-41nd was on: liable to contract aemie heulacheq by handling the e loslve.

Explosives of the second no: mentioned have three very aunom dead First] the on; relatively inaensitiveto etonntio n ooondly they are very liable to become extremely m'd otter short periods of storage, in which hard condition they are very insenaitive to detonatlon and are also very dillieult to load into bore holes. Thirdly, they are woolly or duty and mnmqueutly dangerous; lo, and unit gieuic to manufacture.

' 0 main object of our nvention m to provide explosive compositions in which nnoer 0.1mm] m wxmiem. n. oftvtmunoroei nmwm M393 n 1 no rum 1:; moons e oom m, or manna-eon. nnnewnnn, 4

age of sodium nitrate or other oxygen ccirrging salt, whit-h, however, is not an elqil'iili'o like nnuupnmm nitrate, ununonium; perchlorate, etc. One example of such nn er plmive would have the nation:

Nitroglycerin 5' Trinitrotoluol h'odimu nitrate 55% a These i1 redients may however hovel-led and. other \gredienm added in order to ob tnin certain desired hamoteristm'such-ns high or low etre t-eloc'ity, 1nd density. For exam le, live typical formulasl'r'e ktllltgfll to standard industrial .dj'mmites .no disclosed for ezonnple in Bureau of Mllfes' Bulletin No. 48,11age 7.

It is understand that the utagee-ef them i tents lnay be varied within certain lllll ts, mid other elmmoterintiu eulistitl or added without .lnptttllltg from the Mp0 of-our invention. Thus we do not limit ourmlves tp'the nseot five g cent. (5%) nitroglycerin, amen do, snofi re-mlta can be obtained from the use of from two to ten per cook-(240%) thereof.

The puqmse ofltlm nitmglyoegm-is to semiitino tho explosive e0 thet t mil surely detonate with conuner anl blu. ea-po even under adverse conditions. It a nets to ovmome the dnstmesoof exploslm con tnining no liquid i enta. The trinitrotoluo in the most important mmstituent of the new com 'tion'nnd following:

lients of similar 05' an qh all , aria. They ,howevar; that ms'omecases fromha ha: lad-without-the user Britten -dled (luring nmmlfuctm'e and the strength which is (haired. Althuugh lhe trinltrotnhml -:wednuiy be either tho pm-a 'm'fimd' product or a low melting cnlde pmduct, we have found the'lgltmr- (mllziugi tendency for the explosive toctgin: tro hlq l The function 'of the oxygen-ca! 'ing all such as soilimn nitrate is to furnl uq'gen in the damned amount and tq', rmfentflth funnation of noxious or deltrwus fiimes. The combustible, nun-explosive materials,

as w are added in some cases to Lmpprt the desind .nlsc ea mcmlly when the stmugthpi'tbe xplodh'e. In plaoo'of wood pulp-and com u leal, 'wa may usp Mlle x! y m kf not limit ouraa'lve to any jgurtlcular peref-com to seventeen (fi 17%) 9; shah Ilia Ex loam-29 iniul in ion as ahbve desm'ihad are thomu ly sensitive to fire, etc. contain erin nd am.donsequently practically 11011 For the same much they my mused by exp osie;

pnq swore headaches art-10m n! nitroglycsalt.

2. An explosive contnlnlng us the main explosivetrinitmtolunl. fmm tq Ul'fi; qf uitmglycerin. and n mm-explmm- Inorganic oxygen-canning salt.

3.111 on alnsivc umuuniu us the mum explosive trmih'ntnlunl whim i present! the extent of at least 1S',-{ mtmg-lycurm, and u non-explosive. inurgann: nxygvn-vartying salt pulp, cornmcpl, -um1 s,nlfur.1

buatihlq mtemlapitzmay he: five till; I ialiout 5 f0 17% 0f m'rbohyllmte ,cqutnihiug salt, fi'mu about 9. -mtmglycerlu, and from nhont L7 to 5")1. of

'miumfnctuwcl, the

of lrinllrntn 4. An. lolsive cnuuiiuing as the main vxplush? tnnitmwluo! which is present to the extent of at leass 18'}. 2 to of qit-rdglyceriiyaml a nun-cxplm lflagmr- An explosive -eqntaining asthe main mn': nitrate; k

(L'An xplusiv cunhijning as the u'mi'n explogsive trinitrotolnuK-Xmm 2 to 101;, of

'izlgi-o' izlly;'cqsrinin94 mlilmf inute.

a. 4 ax e osu'e upntunn us the main explosive trmitmtuhml whim is prgmut tu he eight of at least 1891"; 'l'lltmglverin, mud smluun mtrate.

S. n e vs containing as the main ex extent of atleast 18%, from 2 m 109-; of

. 1 9d sodium nitrate.

:- ll. :exp 'uslvecontaining as tlm muln explosivet1-initrdtoluol,-nitm ycurin, so-

. 'llinm minim: and ambuatib nou-axplo all impartthe-desireddensity to the compilation and to increase: its exsh'e mater:

pluslvo 10.- An e'x'plbsn'e detaining as the main explosive tppitl-otoluol, from 2 to 10% of helium, sodium nitrate, and from materhnl. 11. An c; )loaiva contami from about ls m o hinitrotohiul, min about to 40% of a name. lnsive inorganic oxygen v'ontul ling gmlt, am from qhnutil to 10% 01 'flfll'lL, 1." i

l2- .ln esplusivo contuiuln --f|-om nhoi1't 18 t0 mm pf trinit-rutoluilh qua uboul; 60

' iambic-Oxygento 10% of a mm-exphialvu camlmgatihln material.

18. An uxplmivo, nmtuinin from about 30 R150 nmts 0f trlnifl'romlm frum nhnnb 55 to 4-5 pnrtq uf aux alkali-metal nitrate, and about Ii mrts of nituiglycerln.

H. An exp nah-n mntuinm fmmuh'rmtw to 50 part nf (riuitrotnluol, mm uhuut iii; tn 45 parts nf nu nllmli-mtal nitratv, nhrmt 5 pnrls of uitmgiyccrin. and not more than ahmll. 10 parts uf curlmlmlmte nmturial to impart tho desiml llcnsil-y to the tfllllllOSl tlnn nlul tn invlmu-I! its explosive strvngth.

l5. An vxrlmivu mntninlng almnt'zluyg \ml, about, 641.2,,0! sodium nitrnl'v, guhont 51.1" of nitmglg'mrln. an amount of wuml pulp and corn meal lnmliu about 10'} and a small percentage of chalk.

In tvat-inmuy that we chum tho fmegoing we have hereunto 512tum' hands.

LEON 0. BRYAN, 'ENDEL J R. SWINT.

:sglnslfi trinltnkolupl, pitroglyeerin, and