US1320168A - Method of producing low temperatures - Google Patents
Method of producing low temperatures Download PDFInfo
- Publication number
- US1320168A US1320168A US1320168DA US1320168A US 1320168 A US1320168 A US 1320168A US 1320168D A US1320168D A US 1320168DA US 1320168 A US1320168 A US 1320168A
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- US
- United States
- Prior art keywords
- gas
- valve
- pipe
- lubricant
- constituents
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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- 239000007789 gas Substances 0.000 description 146
- 150000002430 hydrocarbons Chemical class 0.000 description 56
- 239000000470 constituent Substances 0.000 description 32
- 239000000314 lubricant Substances 0.000 description 32
- 239000004215 Carbon black (E152) Substances 0.000 description 26
- 238000000034 method Methods 0.000 description 18
- 238000001816 cooling Methods 0.000 description 10
- 239000003795 chemical substances by application Substances 0.000 description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 6
- 235000019441 ethanol Nutrition 0.000 description 6
- PEDCQBHIVMGVHV-UHFFFAOYSA-N glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 6
- 235000011187 glycerol Nutrition 0.000 description 6
- 238000007710 freezing Methods 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 239000003345 natural gas Substances 0.000 description 4
- 238000005057 refrigeration Methods 0.000 description 4
- RGCKGOZRHPZPFP-UHFFFAOYSA-N Alizarin Chemical compound C1=CC=C2C(=O)C3=C(O)C(O)=CC=C3C(=O)C2=C1 RGCKGOZRHPZPFP-UHFFFAOYSA-N 0.000 description 2
- 150000001768 cations Chemical class 0.000 description 2
- 108010057108 condensin complexes Proteins 0.000 description 2
- 239000012024 dehydrating agents Substances 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- OKKJLVBELUTLKV-UHFFFAOYSA-N methanol Chemical group OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 2
Images
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25J—LIQUEFACTION, SOLIDIFICATION OR SEPARATION OF GASES OR GASEOUS OR LIQUEFIED GASEOUS MIXTURES BY PRESSURE AND COLD TREATMENT OR BY BRINGING THEM INTO THE SUPERCRITICAL STATE
- F25J3/00—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification
- F25J3/02—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream
- F25J3/0204—Processes or apparatus for separating the constituents of gaseous or liquefied gaseous mixtures involving the use of liquefaction or solidification by rectification, i.e. by continuous interchange of heat and material between a vapour stream and a liquid stream characterised by the feed stream
- F25J3/0219—Refinery gas, cracking gas, coke oven gas, gaseous mixtures containing aliphatic unsaturated CnHm or gaseous mixtures of undefined nature
Definitions
- WITNESSES Au usfe Jafie far is if: 25% 9 A ttorneys INVENTOR at v orrrcn AUGUSTE JEAN PARIS, JR., OF BRADFORD, PENNSYLVANIA.
- PatentedOct. as, rare.
- This invention is a method of producing low temperatures, and, speaking generally, the object of the invention is to cool a gas, or mixture of'gases, or a mixed gas and vapor, for the purpose of condensin some agent or agents in the gas, or for liquefying the gas.
- the invention is particularly applicable to the treatment of natural gas, casing-head gas, oil gas, and analogous gases, for the purpose of separating condensable hydrocarbons therefrom, such as gasolene and analogous products.
- the gas may be under pressure, either natural or artificial, in which case the gas is expanded in the presence of a lubricant which does not unduly congeal or solidify at the low temperature incident to the expansion. Moreover, in the event the gas contains aqueous vapor, the latter mixes with the lubricant and is thereby precluded from congealing or freezing.
- the thus refrigerated and expanded gas may be passed through condensers and employed to condense hydrocarbons or other condensable constituents from gases, while the latter are either under high pressure, or at substantially atmospheric pressure.
- A is a condenser having a gas inlet a, provided with valve 1), and a gas outlet 0, provided with valve 01.
- the gas outlet 0 leads to a separator B having a draw-off pipe 6, provided with valve f, and a gas outlet 9, provided with valve h, which leadsfrom separator 13 to an expan sion cylindervC.
- Pipe 9 is provided with a gas outlet 2', having a manually operated valve j, and an automatic relief valve is.
- Gas pipe 9 is connected with a high pressure gas main D, provided with valve Z.
- E is a pipe for supplying a non-congealable lubricant of the character under consideration to the system, and particularly to the expansion cylinder C.
- Pipe E is provided with a valve m for controlling the supply of lubricant to the cylinder, but, if desired, such lubricant may be introduced into the gas, prior to its admission to the expansion cylinder, through pipe n, provided with valve 0.
- the expanded gas passes from the cylinder through pipe 2 into separator F, where-in certain constituents are trapped out, as hereinafter described, whence it enters through pipe 9, provided with valve 1", into the cooling chamber of condenser A, whereupon it passes out of the system through a pipe 8, provided With valve 25.
- the gas Assuming the gas is under pressure, either a natural or artificial, say from 50 to 300 pounds, it is allowed to enter pipe at, through valve 7), into condenser A.
- the gas is sub jected to a low temperature in condenser A, in the manner hereinafter described, whereupon it passes, through pipe 0, controlled by valve d, into separator B.
- the elfect of refrigerating the gas in condenser A is to liquefy, in whole or in part, any constituents in the gas condensable at the pressure and temperature which obtains under the particular conditions of operation.
- the constituents thus liquefied or condensed are trapped out in separator B, and may be drawn off, as desired, through pipe 0, containing valve 7.
- the comparatively dry gas passes off from separator B, through pipe 9 and enters expansion cylinder C.
- a small quantity of a non-congealing lubricant is introducedinto it from pipe E; in the former case through valve 0, and in the latter through valve m.
- the noncongealing lubricant I may employ glycerin or turkey red oil, though for the low temperatures usually desired, I prefer to mix these agents with methyl or ethyl alcohol.
- the lubrigas Such congelation would, of course, clog the apparatus, particularly the valves, and render it inoperative.
- the temperature 1n the expansion cylinder may range from say 32 degrees F. down to 150 degrees below, or
- the lubricant used not only mixes with the aqueous vapors and reduces its freezing point, as Well as lubricates the metal parts of the mechanism employed, but also acts as a dehydrating agent for the gas in that it removes the aqueous vapor therefrom.
- the gas having been expanded in cylinder E it passes through pipe p into separator F, wherein the lubricant which it carries, as well as any further hydrocarbons separated, as the result of the refrigeration produced in expansion cylinder C, are trapped out and may, as desired, be drawn off therefrom through pipe 6', provided with valve 7.
- the lubricant after separating therefrom the moisture or hydrocarbons, may be re-used.
- the expanded gas passes out of separator F. through pipe q, into the cooling chamber of condenser A, and serves to refrigerate the compressed gas entering the condenser through pipe at.
- the result of the refrigeration in condenser A is to liquefy or condense certain hydrocarbons in the gas, as previously described, and these are trapped out in separator B.
- the introduction of the alcohol and glycerin combined with the refrigerating action of the expanding operation alters the weight of the hydrocarbon vapors in the gas, and renders them more readily removable, and this is necessarily involved in the carrying out of the process.
- the gas may be introduced into condenser A, as previously described, wherein it comes into indirect contact with the counter-current of expanded gas entering the condenser from separator F, through pipe q.
- the gas having been refrigerated, and its liquefiable constituents trapped out in separator B, the residual gas passes off through branch pipe c, manually operated valve j and automatic relief valve is, and may be used for any of its available purposes.
- valve h is closed.
- the power generated in expansion cylinder C may be used for any purposes desired.
- the expanded, refrigerated natural, or other gas may be used not only to treat gases at substantially normal pressures, but, also, any other gas even at high pressure.
Description
A. J. PARIS, JR.
METHOD OF PRODUCING LOW TEMPERATURES.
APPL|CATION FILED MAY 25, 1916.
1 ,32@, l 6 Patented Oct. 28, 1919.
WITNESSES Au usfe Jafie far is if: 25% 9 A ttorneys INVENTOR at v orrrcn AUGUSTE JEAN PARIS, JR., OF BRADFORD, PENNSYLVANIA.
METHOD OF PRODUCING LOW TEMPERATURES.
Specification of Letters Patent.
PatentedOct. as, rare.
Application filed May 25, 1916. Serial No. 99,802.
To all whom it may concern Be it known that I, AUGUSTE JEAN PARIS,
Jr., a citizen of the United States, residing in Bradford, county of McKean, and State 1 of Pennsylvania, have invented a certain new and useful Method of Producing'Low Temperatures, .of which the'following is a specification.
This invention is a method of producing low temperatures, and, speaking generally, the object of the invention is to cool a gas, or mixture of'gases, or a mixed gas and vapor, for the purpose of condensin some agent or agents in the gas, or for liquefying the gas.
The invention is particularly applicable to the treatment of natural gas, casing-head gas, oil gas, and analogous gases, for the purpose of separating condensable hydrocarbons therefrom, such as gasolene and analogous products.
In practising the invention, the gas may be under pressure, either natural or artificial, in which case the gas is expanded in the presence of a lubricant which does not unduly congeal or solidify at the low temperature incident to the expansion. Moreover, in the event the gas contains aqueous vapor, the latter mixes with the lubricant and is thereby precluded from congealing or freezing. The thus refrigerated and expanded gas may be passed through condensers and employed to condense hydrocarbons or other condensable constituents from gases, while the latter are either under high pressure, or at substantially atmospheric pressure. g
The accompanying drawing illustrates one form of apparatus wherein the method may bepractised, but it will be understood that said method may be carried out in apparatus of distinctly different type from that herein shown.
Referring to the drawing, the single figure shows, diagrammatically, an apparatus which, in practice, has proved suitable for carrying out the method forming the subject matter of this application.
In the drawing, A is a condenser having a gas inlet a, provided with valve 1), and a gas outlet 0, provided with valve 01. The gas outlet 0 leads to a separator B having a draw-off pipe 6, provided with valve f, and a gas outlet 9, provided with valve h, which leadsfrom separator 13 to an expan sion cylindervC. Pipe 9 is provided with a gas outlet 2', having a manually operated valve j, and an automatic relief valve is. Gas pipe 9 is connected with a high pressure gas main D, provided with valve Z. E is a pipe for supplying a non-congealable lubricant of the character under consideration to the system, and particularly to the expansion cylinder C. Pipe E is provided with a valve m for controlling the supply of lubricant to the cylinder, but, if desired, such lubricant may be introduced into the gas, prior to its admission to the expansion cylinder, through pipe n, provided with valve 0.
The expanded gas passes from the cylinder through pipe 2 into separator F, where-in certain constituents are trapped out, as hereinafter described, whence it enters through pipe 9, provided with valve 1", into the cooling chamber of condenser A, whereupon it passes out of the system through a pipe 8, provided With valve 25.
Having described the apparatus, from a structural standpoint, its mode of operation will now be detailed in connection with the treatment of natural gas by the method forming the subject matter of this invention.
Assuming the gas is under pressure, either a natural or artificial, say from 50 to 300 pounds, it is allowed to enter pipe at, through valve 7), into condenser A. The gas is sub jected to a low temperature in condenser A, in the manner hereinafter described, whereupon it passes, through pipe 0, controlled by valve d, into separator B. The elfect of refrigerating the gas in condenser A is to liquefy, in whole or in part, any constituents in the gas condensable at the pressure and temperature which obtains under the particular conditions of operation. The constituents thus liquefied or condensed, are trapped out in separator B, and may be drawn off, as desired, through pipe 0, containing valve 7.
The comparatively dry gas passes off from separator B, through pipe 9 and enters expansion cylinder C. Either just before or after the admission of the gas to cylinder C, and before its expansion, a small quantity of a non-congealing lubricant is introducedinto it from pipe E; in the former case through valve 0, and in the latter through valve m. As the noncongealing lubricant, I may employ glycerin or turkey red oil, though for the low temperatures usually desired, I prefer to mix these agents with methyl or ethyl alcohol. The lubrigas. Such congelation would, of course, clog the apparatus, particularly the valves, and render it inoperative. The temperature 1n the expansion cylinder may range from say 32 degrees F. down to 150 degrees below, or
even lower. Moreover, the lubricant used not only mixes with the aqueous vapors and reduces its freezing point, as Well as lubricates the metal parts of the mechanism employed, but also acts as a dehydrating agent for the gas in that it removes the aqueous vapor therefrom.
The gas having been expanded in cylinder E, it passes through pipe p into separator F, wherein the lubricant which it carries, as well as any further hydrocarbons separated, as the result of the refrigeration produced in expansion cylinder C, are trapped out and may, as desired, be drawn off therefrom through pipe 6', provided with valve 7. The lubricant, after separating therefrom the moisture or hydrocarbons, may be re-used.
The expanded gas passes out of separator F. through pipe q, into the cooling chamber of condenser A, and serves to refrigerate the compressed gas entering the condenser through pipe at. The result of the refrigeration in condenser A, is to liquefy or condense certain hydrocarbons in the gas, as previously described, and these are trapped out in separator B. Moreover, the introduction of the alcohol and glycerin combined with the refrigerating action of the expanding operation, alters the weight of the hydrocarbon vapors in the gas, and renders them more readily removable, and this is necessarily involved in the carrying out of the process.
In the event it is desired to utilize expanded gas to refrigerate gas at comparatively low pressure, the gas may be introduced into condenser A, as previously described, wherein it comes into indirect contact with the counter-current of expanded gas entering the condenser from separator F, through pipe q. The gas having been refrigerated, and its liquefiable constituents trapped out in separator B, the residual gas passes off through branch pipe c, manually operated valve j and automatic relief valve is, and may be used for any of its available purposes. In carrying out the operations thus described, it will be understood that valve h is closed.
When operating on the low pressure gas, as described, high pressure gas, under natu- Such lubriral or artificial pressure, is introduced into the expansion cylinder from main D through valve 1. Its treatment with the noncongealing lubricant, and subsequent manipulation, preceding its introduction into' condenser A, is the same as that previously described in operating on high pressure gas entirely.
The power generated in expansion cylinder C may be used for any purposes desired.
It will be understood that minor changes may be made in the specific processes outlined without departing from the spirit of the invention, the scope of which is commensurate with the appended claims.
The apparatus herein described also forms a part of my invention, and I reserve the right to file a divisional application thereon. It will be understood that a plurality of condensers, and likewise a plurality of separators may be used if desired, the present drawing showing one of each in the interest of simplicity.
I desire it understood, also, that the expanded, refrigerated natural, or other gas may be used not only to treat gases at substantially normal pressures, but, also, any other gas even at high pressure.
Having thus fully described the invention, what I claim as new, and desire to secure by Letters Patent, is:
1. The process of recovering hydrocarbons from hydrocarbon gases, which consists in condensing out the heavier hydrocarbon constituents by cooling the gas to a certain degree, thereafter expanding the gas to still further lower the temperature thereof for the purpose of condensing out the lighter hydrocarbons, and carrying on the expanding operation in the presence of a lubricant which prevents congelation of any of the aqueous constituents in the gas and dehydrates said gas.
2. The process of recovering hydrocarbons from hydrocarbon gases, which consists in condensing out the heavier hydrocarbon constituents by cooling the gas to a certain degree, thereafter expanding the gas to still further lower the temperature thereof for the purpose of condensing out the lighter hydrocarbons, carrying on the expanding operation in the presence of a lubricant which prevents congelation of any of the aqueous constituents in the gas and dehydrates said gas, and utilizing the frigid expanded gas for carrying out the first condensing operation on fresh gas passing through the process.
3. The process of removing hydrocarbons from hydrocarbon gases, which consists in cooling compressed hydrocarbon gas to condense oertain liquefiable constituents therein, removing said liquefiable constituents, thereafter passing the gas through an expanding operation to remove additional liquefiable constituents, and carrying on the expanding operation in the presence of a lubricant which prevents congelation of any aqueous constituents in the gas and dehydrates said 4. The process of recovering hydrocarbons from hydrocarbon gases, Which consists in expanding a hydrocarbon gasin the presence of a lubricant which prevents congelation of any aqueous constituents in the gas and dehydrates said gas, and subsequently separating the hydrocarbon products which become liquefied during the expanding operation.
5. The process of recovering liquefiable hydrocarbons from hydrocarbon gases, which consists in expanding a hydrocarbon gas to lower its temperature to a degree whereat liquefiable hydrocarbons will be condensed out of said gas, carrying on the expanding operation in the presence of a lubricant which prevents congelation of any aqueous constituents in the gas, dehydrates 6. The process of recovering liquefiable hydrocarbons from hydrocarbon gases, which consists in expanding the gas to lower the temperature thereof sufiiciently to condense out the liquefiable hydrocarbons therein, and carrying on the expanding operation in the presence of a mixture of glycerin and alcohol, which serves to. prevent the congelation of any aqueous constituents in the gas, dehydrates said gas, and simultaneously lubricate the mechanism employed: o a
In testimony whereof I have signed my name to this specification.
AUGUSTE JEAN PARIS, JR.
Publications (1)
Publication Number | Publication Date |
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US1320168A true US1320168A (en) | 1919-10-28 |
Family
ID=3387637
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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US1320168D Expired - Lifetime US1320168A (en) | Method of producing low temperatures |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2641114A (en) * | 1949-03-30 | 1953-06-09 | Holthaus Paul Wilhelm | Fuel gas treatment |
US2814936A (en) * | 1954-04-09 | 1957-12-03 | Constock Liquid Methane Corp | Method for liquefying natural gas at casing head pressure |
-
0
- US US1320168D patent/US1320168A/en not_active Expired - Lifetime
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2641114A (en) * | 1949-03-30 | 1953-06-09 | Holthaus Paul Wilhelm | Fuel gas treatment |
US2814936A (en) * | 1954-04-09 | 1957-12-03 | Constock Liquid Methane Corp | Method for liquefying natural gas at casing head pressure |
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