US1310478A - Sdtfabis w - Google Patents
Sdtfabis w Download PDFInfo
- Publication number
- US1310478A US1310478A US1310478DA US1310478A US 1310478 A US1310478 A US 1310478A US 1310478D A US1310478D A US 1310478DA US 1310478 A US1310478 A US 1310478A
- Authority
- US
- United States
- Prior art keywords
- furnace
- carbo
- nitrogen
- nitrid
- gas
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000007789 gas Substances 0.000 description 48
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 40
- 238000000034 method Methods 0.000 description 28
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 24
- 239000000203 mixture Substances 0.000 description 20
- 229910052757 nitrogen Inorganic materials 0.000 description 20
- OKTJSMMVPCPJKN-UHFFFAOYSA-N carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 16
- 229910052799 carbon Inorganic materials 0.000 description 12
- 239000000571 coke Substances 0.000 description 12
- 229910052742 iron Inorganic materials 0.000 description 12
- 239000000463 material Substances 0.000 description 12
- 238000010079 rubber tapping Methods 0.000 description 12
- UGFAIRIUMAVXCW-UHFFFAOYSA-N carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 10
- 238000009833 condensation Methods 0.000 description 10
- 230000005494 condensation Effects 0.000 description 10
- 230000001603 reducing Effects 0.000 description 8
- 239000002253 acid Substances 0.000 description 6
- 239000003245 coal Substances 0.000 description 6
- 239000000446 fuel Substances 0.000 description 6
- 239000001301 oxygen Substances 0.000 description 6
- MYMOFIZGZYHOMD-UHFFFAOYSA-N oxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 6
- 229910052760 oxygen Inorganic materials 0.000 description 6
- 150000003839 salts Chemical class 0.000 description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 6
- 239000002893 slag Substances 0.000 description 6
- 239000011780 sodium chloride Substances 0.000 description 6
- 239000006227 byproduct Substances 0.000 description 4
- CURLTUGMZLYLDI-UHFFFAOYSA-N carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 239000010433 feldspar Substances 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 150000002830 nitrogen compounds Chemical class 0.000 description 4
- -1 nitrogenous compound Chemical class 0.000 description 4
- PNEYBMLMFCGWSK-UHFFFAOYSA-N AI2O3 Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 2
- VKYKSIONXSXAKP-UHFFFAOYSA-N Hexamethylenetetramine Chemical compound C1N(C2)CN3CN1CN2C3 VKYKSIONXSXAKP-UHFFFAOYSA-N 0.000 description 2
- 235000015450 Tilia cordata Nutrition 0.000 description 2
- 235000011941 Tilia x europaea Nutrition 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 229910052783 alkali metal Inorganic materials 0.000 description 2
- 150000001340 alkali metals Chemical class 0.000 description 2
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium monoxide Chemical compound [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 2
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 2
- 238000002485 combustion reaction Methods 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 230000005611 electricity Effects 0.000 description 2
- 230000004907 flux Effects 0.000 description 2
- 238000005755 formation reaction Methods 0.000 description 2
- 239000003517 fume Substances 0.000 description 2
- 229910052738 indium Inorganic materials 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- VBMVTYDPPZVILR-UHFFFAOYSA-N iron(2+);oxygen(2-) Chemical compound [O-2].[Fe+2] VBMVTYDPPZVILR-UHFFFAOYSA-N 0.000 description 2
- 239000004571 lime Substances 0.000 description 2
- 239000000395 magnesium oxide Substances 0.000 description 2
- 229910044991 metal oxide Inorganic materials 0.000 description 2
- 150000004706 metal oxides Chemical class 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- 230000001590 oxidative Effects 0.000 description 2
- BPQQTUXANYXVAA-UHFFFAOYSA-N silicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01C—AMMONIA; CYANOGEN; COMPOUNDS THEREOF
- C01C3/00—Cyanogen; Compounds thereof
- C01C3/16—Cyanamide; Salts thereof
- C01C3/18—Calcium cyanamide
Definitions
- New York city in the county of l lew llorlr and. State of New York, have i1 ed certain new and useful lniproveuiems in.
- This invention relates to a, 'gjn'ocess for effooting the fixation of etnwspheric nitrogen as a byproduct in ine-nufactiuiug producer gas, and has for its object we provide method which will be'iiuore exjoe llilflus and less costly than, has hereofcre been proposed, I
- limate or carbo-nitrid is more or less condensed by the cold charge at the furnace top, and iscarried down with the descending charge until it reaches a temperature high enough to combine with the silicious slag making material of the furnace charge but not high enough to cause the nitrogen compound to'sublime.
- a silicate of the carbo-nitrid metal is formed with the evolution of free nitrogen.
- I avoid the foregoing objections and obtain carbonitrids from either a blast or a producer type of furnace by proceeding as follows I charge the furnace with feldspar and coke, or lime and coke, or magnesia and coke, or other oXid (capable of forming a salt with an acid) and coke, precisely as an iron blast furnace, or gas producer is charged, and I make producer gas, usinga hot blast. In some cases, suitable fluxes may also be added to the charge, for the purpose of conveniently removing such materials as silica from the-furnace as a molten slag. I prefer, however, to finely grind the coke'and the oXid containing salt or mineral,
- reaction velocities are of courseincases to the successful operation of the process.
- gas which finally exits from the settlers or scrubbers is found to be a high grade producer gas suitable for use in internal combustion engines.
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Waste-Gas Treatment And Other Accessory Devices For Furnaces (AREA)
Description
- April 6, l
EU 6') VEEING F:
Hall 35 1013133)? G ll/CHRIST, OF NEW Be it known ihol; l, EDWARD d HASLUP, a citizenof the United States, residing el;
New York city, in the county of l lew llorlr and. State of New York, have i1 ed certain new and useful lniproveuiems in. lProcesses of Recovering Fixed Nitrogen; and l: do hereby declare he follmvii to be :2 full, clear, and exact description oi die inveneion, such us will enable others skilled in the to which it apperiains lo make and use the same.
This invention relates to a, 'gjn'ocess for effooting the fixation of etnwspheric nitrogen as a byproduct in ine-nufactiuiug producer gas, and has for its object we provide method which will be'iiuore exjoe llilflus and less costly than, has hereofcre been proposed, I
With this and other, chic in View the invention consists in Llie novel steps and combinations of steps ooi'isiitu-tiug the proc ess, ell as will more fully h reinafter l1sclosed and particularly point d col; in the claims. I e
In order thee; the pre ise neiure oi the or went-ion inuy be more cieeriy understood 1i) is said I .ltis uown um when free or com loined alkuii cities or alka i cart metal oxide cepelile of feminine; selts'with acids ere exposed ic carbon and heated to suiiicien'tly high temperate in on atmosphere of nitrogen freeof oriidizing such as oxygen, carlion dicxid, old, that nit]? zen carlvcn con. ining compound is forined, which ct its is of :llormeiion volatile, or at least has the physicel"prop erties of a sublimete.
Processes u tiliaing ill is principle have been made "(he subjec' of .1 scents :gbldllsill; #133 32.-
glfrldfie; 13; each dated Peecoclit.
lo, end issued to Samuel But in. following the proceduie of s'eid pebents, ii: is tool; only to lfil'lTlDVG the subliined nitrogenous compound or carbonitrid from a furnace chamber necz. erily sealed from the air, to prevent do oyiug the compound, but the car l'iocii values music he colleclcd and cooled c1 contact with ihe air, by some menus, and in such a iemperature as will. precludetheir i, 7i')illpO- Specification oi Patented July 22, 319%).
fwplieaiion filed npril #3, 1912;. Eerie No $327,316.
sieion upon contact with oxygen, and all in a continuous industrial operation.
Ti lie mechanical problem thus presented in ceriying one an industrial procedure is evidenlily a, very difiiculi; one In practice all processes of this kind for such nitrogen fixei ion have been limited in their operation to the use of electrically generated heat, in one form or another, for electricity seemed '00 fuz' nish the only means of readily obtaining the desired temyieraturein a sealed fur- But electrically genera-ted heat is comparatively costly. In fact, the heat equive-len" of a kilowatt year which may cost from say 2825 to $100 is found in less then three thousand pounds of ordinary steam coal. is true that there sue a few localities where hydro-electric power may be obtained at a cost. of approximately $15 per kilowatt year; but, it is also true that there are a greater number of locations Where 8000 pounds of coal would ost from sayvthree to four dollars only. Hence, it obvious that a procedure which enable the use of directly generated heat from coal in such nitrogen fixation processes would be an economic gain. New, 1t is' Well known, in the operation of e carbon monoxid gas producer, or in the operation of a blast furnace "that if one examines the furnace or twyers, he will find the furnace gases to contain neither free oxygen, carbon dioxid, nor other readily oxidizing gases, and that the gaseous nitrogen present; ranges from say "no 66 per cent. of the total volume. iihelempemture of the furnace gases at this pointalso, will oe foundito be very. high, nly alcove 1060" C, while the temperainure oi? the coke and inorganic bodies in this zone of high temperature exceeds say 14l0O C, In ordinary blast furnace, at such lemperaiures, "most oxide in contact with carbon and in the presence of gaseous nisrogen, form a, nitrogen containing compound, or cairbo-nitricl, which has approximately the proportional formula RCN and which when hearted with water produces ammonia. But, unless prevented, these com-- contact with the air, producing a white cloud of fume consisting of oxids and carbonates of, the combined metals present in a state of very fine sub-division. If an iron blast furnace is used, the action of the carbon monoxid of the furnace gases upon the iron oxid present results in the formation of metallic iron and carbon dioxid, and
limate or carbo-nitrid, is more or less condensed by the cold charge at the furnace top, and iscarried down with the descending charge until it reaches a temperature high enough to combine with the silicious slag making material of the furnace charge but not high enough to cause the nitrogen compound to'sublime. As a result, a silicate of the carbo-nitrid metal is formed with the evolution of free nitrogen.
It does not seem to have occurred to any one prior to my invention that if the furnace gases be removed from an exit located so low in the furnace that no substantial condensation of said carbo-nitrids will occur, and too low for the usual reducing effect to take place, that said carbo-nitrids could be tapped out and recovered. The reason why no one seems to have suggested such a procedure, probably resides in the fact that the tapping of the furnace gases in any such fashion from an iron blast furnace would render the latter inoperative; and the tapping of the furnacegases in such manner from a producer gas furnace would be a useless procedure, for no earbo-nitrids would be present.
One the other hand, were not these two objections present, it would be perfectly feasible to employ either a blast furnace, or a producer furnace in the manner stated, and to obtain carbo-nitrids of the character disclosed in the patents above referred to.
In carrying out this invention, I avoid the foregoing objections and obtain carbonitrids from either a blast or a producer type of furnace by proceeding as follows I charge the furnace with feldspar and coke, or lime and coke, or magnesia and coke, or other oXid (capable of forming a salt with an acid) and coke, precisely as an iron blast furnace, or gas producer is charged, and I make producer gas, usinga hot blast. In some cases, suitable fluxes may also be added to the charge, for the purpose of conveniently removing such materials as silica from the-furnace as a molten slag. I prefer, however, to finely grind the coke'and the oXid containing salt or mineral,
and briquet the same for furnace treatment. The following four chemical equations, stated in proportional formulas, illustrate the substantial reactions that take place In all four of these illustrations, the re action involves a high temperature zone of not less than say MOO C. If this temperature is raised to 1600O. the alumina of the feldspar is also converted to the nitrogen compound. I
In carrying out the access the use of a hot blast is very desirable in most cases, in order to keep the charge sufficiently molten to secure a readily flowing slag. As no iron oxids are to be reduced no objection is encountered in tapping oil the furnace gases at a suitable point near the twyers, or where the carbo'nitrids are found to be richest, and this I do. Ordinarily such a point in a blast furnace is found to be at the usual reducing zone. After the furnace gases have been thus led from. the reducing zone, they are carried out of contact with the air to any suitable scrubber, or collector, where the carbo nitrids contained therein are cooled down to a point where contact will the air does not affect them, and recovered without substantial loss.
It will now be clear that by making producer gas in a regular producer gas furnace, or in an iron blast type of furnace, and by having present in such furnaces a material containing an oxid of an alkali metal, or of an alkali-earth metal, during the process of making saidproducer gas, I am enabled to not only fix atmospheric nitrogen as a byproduct, without the use of electric heat, but I am enabled to continuously'ta it directly from the reducing zones of said furnaces and thus avoid its condensation on the cooler portions ofsaid furnaces, and on their charge material; I am also enabled to cool said carbonitrids without exposure to the air; results that have not been heretofore attained in so faras I am aware.
The reaction velocities are of courseincases to the successful operation of the process. The gas which finally exits from the settlers or scrubbers is found to be a high grade producer gas suitable for use in internal combustion engines.
What I claim is:
1.. The process of producing a volatile carbo-nitrid which consists in'preparing a mixture of an oXid bearing material and carbon; subjecting said mixturein a fuel fed furnace and in an atmosphere of producer gas to a temperature suificient to produce said carbo-nitrid; tapping out said carbo-nitrid and said producer gas-from a region of said furnace too 4 nace ata temperatureand under conditions suitable for forming "a, mixture of producer gas and a volatile carbo-nitrid; tapping off said mixture out of contact'with the air from a point in said furnace at which the temperature is sufiicient to prevent the condensation of said carbo-nitrid; and recovering the latter, substantially as described.
3. The process of fixing atmospheric nitrogen which consists in preparing a mixture of carbon and a material containing an oxid capable of forming a salt with an acid; heating said mixture under conditions suitable for forming a second mixture of carbon monoxid gas and a volatile carbo-nitrid;
leading off said mixture out of contact with "the air before sa1d carbo-nitrid has condensed; and recovering the latter, substantially as described. a
4. The process of fixing atmospheric nitrogen in a fuel fed furnace which consists in charging said furnace with a mixture containing calcium oXid and carbon; heating said mixture under conditions suitable for formin producer gas and a volatile carbo-nitri tapping said furnace at a point the temperature of which is too high to permit the condensation of said carbo-nitrid;
and cooling the latter out of contact with the air substantiall as described.
.'5. The process making and recovering volatile carbo-nitrids which consists in producing said carbo-nitrids in an atmosphere of carbon monoxid gas in a fuel fed furn'ace; and withdrawing said carbo-nitrids before condensation along with a ortion of said carbon monoxid gas, substantially as described. p
In testimony whereof I afiix my signature, in presence of two Witnesses.
EDWARD W. HASLUP.
Witnesses:
M. O. WALSH, M. M. MURPHY DREW.
Publications (1)
Publication Number | Publication Date |
---|---|
US1310478A true US1310478A (en) | 1919-07-22 |
Family
ID=3377985
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US1310478D Expired - Lifetime US1310478A (en) | Sdtfabis w |
Country Status (1)
Country | Link |
---|---|
US (1) | US1310478A (en) |
-
0
- US US1310478D patent/US1310478A/en not_active Expired - Lifetime
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US3262771A (en) | Recovery of steel and zinc from waste materials | |
US2675307A (en) | Process for coking-calcining complete smelting charge aggregates | |
US1755845A (en) | Process of and apparatus for smelting ores and recovering by-products therefrom | |
US1310478A (en) | Sdtfabis w | |
US2453050A (en) | Process of smelting titaniferous ore | |
US2096779A (en) | Process for reducing oxidized ores of zinc | |
US2143001A (en) | Producing phosphorus | |
US2039297A (en) | Separating phosphorus | |
US2526659A (en) | Continuous smelting process | |
US2086201A (en) | Ore roasting | |
US1821208A (en) | Barium silicorferrite and process of preparing the same | |
US2117301A (en) | Apparatus for producing phosphorus | |
GB359478A (en) | Improvements in or relating to the burning of pyrites, or iron sulphide and the production of iron oxide | |
US1551615A (en) | Process of reducing alumina | |
US1334004A (en) | Process for the treating of titaniferous iron ore | |
US283241A (en) | James hendebson | |
US1310479A (en) | Edwasd w | |
US2011400A (en) | Process of treating zinciferous iron ores | |
US874391A (en) | Process of making steel. | |
US1291498A (en) | Process of making magnesium carbonated in blast-furnaces. | |
US1652184A (en) | Process and apparatus for extracting zinc | |
US660094A (en) | Process of treating kryolith. | |
US1744213A (en) | Smelting of ferrc-alloys in blast furnaces | |
US2745736A (en) | Process for the production and recovery of zinc in metallic form by reduction of materials containing zinc in oxide form | |
US1606319A (en) | Process of producing phosphorus pentoxide |