US1240523A - Production of sulfonic-acid salts from mineral-oil waste liquors. - Google Patents
Production of sulfonic-acid salts from mineral-oil waste liquors. Download PDFInfo
- Publication number
- US1240523A US1240523A US15160617A US15160617A US1240523A US 1240523 A US1240523 A US 1240523A US 15160617 A US15160617 A US 15160617A US 15160617 A US15160617 A US 15160617A US 1240523 A US1240523 A US 1240523A
- Authority
- US
- United States
- Prior art keywords
- sulfonic
- mineral
- alcohol
- oil
- production
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C309/00—Sulfonic acids; Halides, esters, or anhydrides thereof
- C07C309/01—Sulfonic acids
- C07C309/62—Sulfonated fats, oils or waxes of undetermined constitution
Definitions
- My invention relates to the treatment of mineral oil waste liquors and more especially to the production of alkali-metal sulfonates therefrom.
- the sulfonic acids thus obtained are useful in splitting up fats, the quantity of sulfuric acid to be added for this purpose being far greater than the quantity admixed with the sulfonic acid in the refining process mentioned above.
- no pure sulfonate of sodium can be obtained t only a mixture of sodium sulfonates and of sodium sulfates.
- the mass will get greasy to a high degree. For these reasons the normal method described Patented Sept. 18, 1917.
- the sulfonic acid containing a certain percentage of sulfuric acid is dissolved in alcohol and digested with sodium carbonate free of water until a neutral reaction is attained. It is rather astonishing to find that complete neutralization ensues although the sodium carbonate is not employed in a dissolved state.
- the sodium sulfate is precipitated as an insoluble deposit which is the more as tonishing as sodium carbonate free of water is absolutely insoluble in alcohol and it would therefore seem quite impossible to obtain complete neutralization in this way.
- the precipitate After neutralization with alkali-metal carbonate, has been effected the precipitate is allowed to settle and after filtration, if necessary, the spirit is removed by distillation.
- the alkali-metal salts of sulfonic acids derived from petroleum are obtained in a pure stateand with-neutral reaction. They are easily soluble in water and can be employed with advantage in the treat ment of textile goods and leather.
- lfhe method which consists in treating the alcoholic alkaline waste liquor obta'iw bin in refining mineral. oil with dilute suluric acid to remove the oil and salts dis solving the impure sulfonic acid obtained in alcohol, neutralizing the solution With alkali-metal. carbonate free oflwater and evaporating the alcohol from the sulfonate solution obtained.
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Fats And Perfumes (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Description
UNITED STATES PATENT OFFICE.
ALBERT WOLFE, F HAMBURG, GERMANY.
PRODUCTION SULFONIC ACID SALTS FROM MINERAL-OIL WASTE LIQUOR-S.
No Drawing.
To all whom it may concern.-
Be it known that I, Dr. ALBERT WoLrF,
. Sulfonic-Acid Salts from Mineral-Oil Waste Liquors, of which the following is a specification.
My invention relates to the treatment of mineral oil waste liquors and more especially to the production of alkali-metal sulfonates therefrom.
As is well known to those conversant'with the art of refining mineral oil with the aid of sulfuric acid, after the acid resin has been removed, an acid oil is obtained which is then treated with caustic alkali and alcohol in suitable proportion in order to remove the acid constituents. The waste liquor thus obtained, which will hereinafter be referred to as alcoholic alkaline waste liquor, is then treated with sodium chlorid and a concentrated liquor is obtained which contains on the average per cent. of sulfonates of sodium, 30 per cent. of mineral oil and varying quantities of salt and free alkali.
No method has been found, however, for making pure sulfonates of sodium on a commercial scale, althou h owing to the valuable properties of the 'sai product such a method would present the greatest interest. The first step in the production of pure sulfonates of sodium is the removal of the mineral oil and the undesirable salts. According to prior methods the oil may be removed by adding alcohol, and in order to get rid of the salts repeated washing with dilute sulfuric acid of about per cent. has proved eiiective. In this way sulfonic acids free of mineral oil and of salts, such as sodium sulfate, are obtained, said acids containing about 5 per cent, of sulfuric acids. The sulfonic acids thus obtained are useful in splitting up fats, the quantity of sulfuric acid to be added for this purpose being far greater than the quantity admixed with the sulfonic acid in the refining process mentioned above. However in neutralizing the mixture of sulfonic and sulfuric acid with alkali no pure sulfonate of sodium can be obtained t only a mixture of sodium sulfonates and of sodium sulfates. On the other hand the mass will get greasy to a high degree. For these reasons the normal method described Patented Sept. 18, 1917.
Application filed February 28, 1917. Serial No. 151,606
is unfit for practical use and the following method was adopted instead:
The sulfonic acid containing a certain percentage of sulfuric acid is dissolved in alcohol and digested with sodium carbonate free of water until a neutral reaction is attained. It is rather astonishing to find that complete neutralization ensues although the sodium carbonate is not employed in a dissolved state. The sodium sulfate is precipitated as an insoluble deposit which is the more as tonishing as sodium carbonate free of water is absolutely insoluble in alcohol and it would therefore seem quite impossible to obtain complete neutralization in this way.
After neutralization with alkali-metal carbonate, has been effected the precipitate is allowed to settle and after filtration, if necessary, the spirit is removed by distillation. By this method the alkali-metal salts of sulfonic acids derived from petroleum are obtained in a pure stateand with-neutral reaction. They are easily soluble in water and can be employed with advantage in the treat ment of textile goods and leather.
Contrary to the method of removing the oil before the free sulfonic acid is produced, I prefer removing it afterward. I further prefer repeatedly washing the sulfonic acid obtained beforehand with dilute sulfuric acid in order to remove the salts, such as sodium sulfate, and to prevent crystalline deposits from being formed upon the addition of alcohol, such deposits tending to render the formation of different layers diflicult.
' In practising my invention I may for instance proceed as follows:
100 kgs. of the alcoholic alkaline waste liquor obtainable in the refining of mineral oil, said liquor containing about 6 to 7 per cent. of alcohol, is intimately mixed by agitation with 25 kgs. of sulfuric acid (50 per cent), the mixture being heated all the while to 50 to degr. C. After having allowed the whole to settle completely, the sulfonic acid formed is treated two or three times more in the same way with sulfuric acid of 50 per cent. In this way the alcohol present in the liquor is washed out also. In the case where it should prove worth while to recover the alcohol, it may be ob tained by distillation before the sulfuric acid treatment. After washing with sulfuric acid the quantity of alcohol of 95 per cent. required for removing the oil (on the G arcra e from 100 to 150 cent,
Weight of the mineral oil as well as quantity of alcohol employed the mineral oil will separate either as the upper or as the lower layer After having removed the oil the alcoholic solution of sulfonic acid is Well mixed and agitated With sodium carbonate free of Water until it is no longer able to turn congo paper blue. The carbon ate in excess and the sodium sulfate formed are allowed to settle the liquid is then separated from them by decantation and filtratioru if necessary, and is evaporated, the sulfonates of sodium neing ohtained as a mass which is liquid, While hot, and solidi ties in the cold l claim:---
1, 'l hr rngtlmtl. o SlQPRTg'iiilDi! sult'urir: avlli "from :1 sulfnn c acid with which it is UL. 5 which comprises dissolving the mixture in alcohol, adding to the solution substantially dry alkalinietal carbonate to precipitate the sulfuric acid as sulfate, and removing the precipitate.
2. The method which consists in removing from the alcoholic alkaline Waste liquor obtainable in refining mineral oil the oil and salts ordinarily contained therein, dissolving the impure sulfonic acid. obtained in alcohoh neutralizing the solution with alkaliunetal carbonate free from Water, removing the resulting precipitate. and evapcrating the alcohol from the sulfonate solu tion obtained.
3. lfhe method which consists in treating the alcoholic alkaline waste liquor obta'iw bin in refining mineral. oil with dilute suluric acid to remove the oil and salts dis solving the impure sulfonic acid obtained in alcohol, neutralizing the solution With alkali-metal. carbonate free oflwater and evaporating the alcohol from the sulfonate solution obtained.
4. The method Which consists in decomposing the alcoholic alkaline Waste liquor obtainable in refining mineral oil by aid of dilute sulfuric acid repeatedly Washing the sulfonic acid obtained With dilute sulfuric acid to remove the salt, dissolving the impure sulfonic acid obtained in alcohol, neutralizing the solution With alkali-metal. carbonate free of Water and evaporating the alcohol iron: the sul'fouate solution obtained.
'lhe method which consists in heating; and agitating the alcoholic alkaline WilStE liquor obtainable in refining mineral oil With dilute sulfuric acid, repeatedly Washing the sulfonic acid obtained with dilute sulfuric acid, adding the quantity of alcohol required for dissolving the oil still present, separating the layers thus formed, neutralizing the sulfonic acid solution with so dium carbonate free of Water, removing the deposit and evaporating the liquid In testimony whereof I afiix my signature in presence of two Witnesses.
DR. ALBERT YVOLFF.
Witnesses:
FRANCIS R. STEWART, M. BRINEMAN.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US15160617A US1240523A (en) | 1917-02-28 | 1917-02-28 | Production of sulfonic-acid salts from mineral-oil waste liquors. |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US15160617A US1240523A (en) | 1917-02-28 | 1917-02-28 | Production of sulfonic-acid salts from mineral-oil waste liquors. |
Publications (1)
Publication Number | Publication Date |
---|---|
US1240523A true US1240523A (en) | 1917-09-18 |
Family
ID=3308333
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US15160617A Expired - Lifetime US1240523A (en) | 1917-02-28 | 1917-02-28 | Production of sulfonic-acid salts from mineral-oil waste liquors. |
Country Status (1)
Country | Link |
---|---|
US (1) | US1240523A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2810745A (en) * | 1955-07-05 | 1957-10-22 | Sun Oil Co | Purifying mahogany sulfonic acids |
US2843625A (en) * | 1955-09-09 | 1958-07-15 | Exxon Research Engineering Co | Low temperature sulfonation process |
-
1917
- 1917-02-28 US US15160617A patent/US1240523A/en not_active Expired - Lifetime
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2810745A (en) * | 1955-07-05 | 1957-10-22 | Sun Oil Co | Purifying mahogany sulfonic acids |
US2843625A (en) * | 1955-09-09 | 1958-07-15 | Exxon Research Engineering Co | Low temperature sulfonation process |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US1240523A (en) | Production of sulfonic-acid salts from mineral-oil waste liquors. | |
US1901383A (en) | Process for recovering the oil-soluble sulphonic compounds formed in the acid refining of mineral oils | |
US1396320A (en) | Method of obtaining a sodium salt from a hydrocarbon monosulfonic acid | |
US2153286A (en) | Process for preparing wetting | |
US1937521A (en) | Process for the manufacture of sulphonic acids or their salts | |
US1481197A (en) | Purification of hydrocarbons | |
US1594547A (en) | Production of alpha-nitronaphthalene-beta-sulphonic acids | |
US1998411A (en) | Process of producing metal alkyl sulphates | |
US2214037A (en) | Purification of oil soluble sulphonate | |
US2121032A (en) | Detergent and wetting agent and process of producing the same | |
US1547186A (en) | Sulphonation of benzene | |
US1278257A (en) | Cream of tartar from wine-lees. | |
US2809209A (en) | Manufacturing mahogany sulfonates | |
US1996262A (en) | Purification of naphthalene | |
US1207798A (en) | Process of manufacturing sodium salts of sulfonic acids. | |
US2049055A (en) | Method for preparing improved soaps and products thereof | |
US2127641A (en) | Process for obtaining high grade sulphuric acid esters | |
US2192713A (en) | Detergent aid and method of | |
US1265800A (en) | Process of producing 1:2:4 methyl-hydroxy-isopropyl benzene. | |
US1836429A (en) | Manufacture of water soluble sulphonic acids of mineral oils | |
US458647A (en) | Joseph van ruymbeke | |
US1301360A (en) | Process of sulfonation of aromatic hydrocarbons. | |
US1308757A (en) | Alexis c | |
US371127A (en) | Albeet domeiee and otto cheistian hagemann | |
US1406745A (en) | Manufacture of resorcinol |